Gem corundum deposits of Madagascar: A review

Madagascar is one of the most important gem-producing countries in the world, including ruby and sapphires. Gem corundum deposits formed at different stages in the geological evolution of the island and in contrasting environments. Four main settings are identified: (1) Gem corundum formed in the Precambrian basement within the Neoproterozoic terranes of southern Madagascar, and in the volcano-sedimentary series of Beforona, north of Antananarivo. In the south, high-temperature (700 to 800 °C) and low-pressure (4 to 5 kbar) granulites contain deposits formed during the Pan-African orogenesis between 565 and 490 Ma. They accompany mafic and ultramafic complexes (ruby deposits of the Vohibory group), skarns at the contact between Anosyan granites and the Proterozoic Tranomaro group (sapphire deposits of the Tranomaro–Andranondambo district), and shear-zone corridors cross-cutting feldspathic gneisses, cordieritites and clinopyroxenites in the Tranomaro, Vohimena and Androyan metamorphic series (biotite schist deposits of Sahambano and Zazafotsy, cordieritites of Iankaroka and Ambatomena). The circulation of fluids, especially along discontinuities, allowed in-situ alkaline metasomatism, forming corundum host rocks related to desilicified granites, biotitites, “sakenites” and “corundumites”. (2) Gem corundum also occurs in the Triassic detrital formations of the Isalo group, as giant palaeoplacers in the Ilakaka–Sakaraha area. Here, sapphires and rubies may come from the metamorphic granulitic terranes of southern Madagascar. (3) Gem corundum deposits occur within the Neogene-Quaternary alkali basalts from Ankaratra (Antsirabe–Antanifotsy area) and in the Ambohitra Province (Nosy Be, Ambato and Ambondromifehy districts). Primary deposits are rare, except at Soamiakatra where ruby in gabbroic and clinopyroxenite xenoliths within alkali-basalts probably derive from mantle garnet peridotites. The blue-green-yellow sapphires typical of basaltic fields are always recovered in palaeoplacer (in karst formed upon Jurassic limestones from the Montagne d'Ambre, Antsiranana Province) and alluvial and soil placers (Ankaratra volcanic massif). (4) Deposits occur within Quaternary eluvial, colluvial and alluvial concentrations, such as high-quality rubies from the Andilamena and Vatomandry deposits.     

Marble-hosted ruby deposits from Central and Southeast Asia: Towards a new genetic model

Marble-hosted ruby deposits represent the most important source of colored gemstones from Central and South East Asia. These deposits are located in the Himalayan mountain belt which developed during Tertiary collision of the Indian plate northward into the Eurasian plate. They are spatially related to granitoid intrusions and are contained in platform carbonates series that underwent high-grade metamorphism. All occurrences are located close to major tectonic features formed during Himalayan orogenesis, directly in suture zones in the Himalayas, or in shear zones that guided extrusion of the Indochina block after the collision in South East Asia. Ar–Ar dating of micas syngenetic with ruby and U–Pb dating of zircon included in ruby gives evidence that these deposits formed during Himalayan orogenesis, and the ages document the extensional tectonics that were active, from Afghanistan to Vietnam, between the Oligocene and the Pliocene.The petrography shows that ruby-bearing marbles formed in the amphibolite facies (T = 610 to 790 °C and P ~ 6 kbar). A fluid inclusion study defines the conditions of gem ruby formation during the retrograde metamorphic path (620 < T < 670 °C and 2.6 < P < 3.3 kbar) for the deposits of Jegdalek, Hunza and northern Vietnam.Whole rock analyses of non-ruby-bearing marbles indicate that they contain enough aluminum and chromiferous elements to produce all the ruby crystals that they contain. In addition, (C, O)-isotopic analyses of carbonates from the marbles lead to the conclusion that the marbles acted as a metamorphic closed fluid system that were not infiltrated by externally-derived fluids. The carbon isotopic composition of graphite in marbles reveals that it is of organic origin and that it exchanged C-isotopes with the carbonates during metamorphism. Moreover, the O-isotopic composition of ruby was buffered by metamorphic CO₂ released during devolatilisation of marble and the H-isotopic composition of mica is consistent with a metamorphic origin for water in equilibrium with the micas. The (C, O, H)-isotopic compositions of minerals associated with marble-hosted ruby are all in agreement with the hypothesis, drawn from the unusual chemistry of CO₂–H₂S–COS–S₈–AlO(OH)-bearing fluids contained in fluid inclusions, that gem ruby formed at P ~ 3 kbar and 620 < T < 670 °C, during thermal reduction of evaporite by organic matter, at high temperature-medium pressure metamorphism of platform carbonates during the Tertiary India–Asia collision. The carbonates were enriched in Al- and chromiferous-bearing detrital minerals, such as clay minerals that were deposited on the platform with the carbonates, and in organic matter. Ruby formed during the retrograde metamorphic path, mainly by destabilization of muscovite or spinel. The metamorphic fluid system was rich in CO₂ released from devolatilisation of carbonates, and in fluorine, chlorine and boron released by molten salts (NaCl, KCl, CaSO₄). Evaporites are key to explaining the formation of these deposits. Molten salts mobilized in situ Al and metal transition elements contained in marbles, leading to crystallization of ruby.     

Detrital footprint of the Mozambique ocean: U–Pb SHRIMP and Pb evaporation zircon geochronology of metasedimentary gneisses in eastern Madagascar

The southern East African Orogen is a collisional belt where the identification of major suture zones has proved elusive. In this study, we apply U–Pb isotopic techniques to date detrital zircons from a key part of the East African Orogen, analyse their possible source region and discuss how this information can help in unravelling the orogen.U–Pb sensitive high-mass resolution ion microprobe (SHRIMP) and Pb evaporation analyses of detrital zircons from metasedimentary rocks in eastern Madagascar reveal that: (1) the protoliths of many of these rocks were deposited between 800 and 550 Ma; and (2) these rocks are sourced from regions with rocks that date back to over 3400 Ma, with dominant age populations of 3200–3000, 2650, 2500 and 800–700 Ma.The Dharwar Craton of southern India is a potential source region for these sediments, as here rocks date back to over 3400 Ma and include abundant gneissic rocks with protoliths older than 3000 Ma, sedimentary rocks deposited at 3000–2600 Ma and granitoids that crystallised at 2513–2552 Ma. The 800–700 Ma zircons could potentially be sourced from elsewhere in India or from the Antananarivo Block of central Madagascar in the latter stages of closure of the Mozambique Ocean. The region of East Africa adjacent to Madagascar in Gondwana reconstructions (the Tanzania craton) is rejected as a potential source as there are no known rocks here older than 3000 Ma, and no detrital grains in our samples sourced from Mesoproterozoic and early Neoproterozoic rocks that are common throughout central east Africa. In contrast, coeval sediments 200 km west, in the Itremo sheet of central Madagascar, have detrital zircon age profiles consistent with a central East African source, suggesting that two late Neoproterozoic provenance fronts pass through east Madagascar at approximately the position of the Betsimisaraka suture. These observations support an interpretation that the Betsimisaraka suture separates rocks that were derived from different locations within, or at the margins of, the Mozambique Ocean basin and therefore, that the suture is the site of subduction of a strand of Mozambique Ocean crust.     

Tectonic framework of the Precambrian of Madagascar and its Gondwana connections: a review and reappraisal

The Precambrian of Madagascar is divided into two sectors by the north-west trending sinistral Ranotsara shear zone, which continues in the Mozambique belt, probably as the Surma shear zone, and in Southern India as the Achankovil shear zone. South of Ranotsara six north-south trending tectonic belts are recognized that consist largely of granulite and high amphibolite facies paragneisses, phlogopite diopsidites, concordant granites and granulites. North of Ranotsara the central-northern segment is traversed by a north-trending axial 100–150 km wide dextral shear zone of probable Pan-African age, which was metamorphosed under granulite and high amphibolite facies conditions and which has reworked older basement. This shear zone continues across southern India as the Palghat-Cauvery shear zone. Major stratiform basic -ultrabasic complexes occur in the axial zone and in the basement to the west. Well preserved low grade continental margin-type sediments (quartzites, mica schists and stromatolitic marbles) of Kibaran age are present in western Madagascar. Two partly greenschist grade sedimentary groups lie unconformably on high grade basement in north-east Madagascar. Isotopic age data suggest the presence in Madagascar of Archaean, Early and Mid-Proterozoic crustal material that was extensively reworked in Pan-African times.     

Tectonic setting of the Balaram-Kui-Surpagla-Kengora granulites of the South Delhi Terrane of the Aravalli Mobile Belt,NW India and its implication on correlation with the East African Orogen in the Gondwana assembly

Granulites are developed in various tectonic settings and during different geological periods, and have been used for continental correlation within supercontinent models. In this context the Balaram-Kui-Surpagla-Kengora granulites of the South Delhi Terrane of the Aravalli Mobile Belt of northwestern India are significant. The granulites occur as shear zone bounded lensoidal bodies within low-grade rocks of the South Delhi Terrane and comprise pelitic and calcareous granulites, a gabbro-norite-basic granulite suite and multiple phases of granites of the Ambaji suite. The granulites have undergone three major phases of folding and shearing. The F₁ and F₂ folds are coaxial along NE-SW axis, and F₃ folds are developed across the former along NW-SE axis. Thus, various types of interference patterns are produced. The granulite facies metamorphism is marked by a spinel–cordierite–garnet–sillimanite–quartz assemblage with melt phase and is synkinematic to the F₁ phase of folding. The peak thermobarometric condition is set at ≥850 °C and 5.5–6.8 kb. The granulites have been exhumed through thrusting along multiple ductile shear zones during syn- to post-F₂ folding. Late-stage shearing has produced cataclasites and pseudotachylites. Sensitive High Resolution Ion MicroProbe (SHRIMP) U–Pb dating of zircon from pelitic granulites and synkinematically emplaced granites indicate that: (1) the sedimentary succession of the South Delhi Terrane was deposited between 1240 and 860 Ma with detritus derived from magmatic sources with ages between 1620 and 1240 Ma; (2) folding and granulite metamorphism have taken place between ca. 860 and 800 Ma, and exhumation at around ca. 800–760 Ma; and (3) the last phase of granitic activity occurred at ca. 759 Ma. This shows, for the first time, that the granulites of the South Delhi Terrane are much younger than those of the Sandmata Granulite Complex of the northern part of the Aravalli Mobile Belt, the Saussar granulites of the Central India Mobile Belt and the Eastern Ghats Mobile Belt. Instead, they show similarities to the Neoproterozoic granulites of the Circum Indian Orogens that include the East African Orogen (East Africa and Madagascar), the Southern Granulite Terrane of India and much of Sri Lanka. We suggest that the South Delhi Basin probably marks a trace of the proto-Mozambique Ocean in NW India within Gondwana, that closed when the Marwar Craton, arc fragments (Bemarivo Belt in Madagascar and the Seychelles) and components of the Arabian-Nubian Shield collided with the Aravalli-Bundelkhand Protocontinent at ca. 850–750 Ma.     

Metamorphism and Isotopic Evolution of Granulites of Southern India: Reference to Neoproterozoic Crustal Evolution

Granulites are important component of high-grade metamorphic rocks reflecting intense conditions observed for crustal rocks in terms of temperature, and pressure. This review paper demonstrates how these high-grade granulites are critical to understanding the evolution of the lower continental crust with special reference to southern India. Geothermobarometric traverse across different granulite blocks in southern India shows wide ranging P-T conditions of metamorphism (700–1000 ° C, and 5–10 kbar). The sapphirine-, orthopyroxene-sillimanite, and spinel -bearing quartz-deficient granulites recognised from parts of southern granulite terrain (Ganguvarpatti, Kiranur, and Palani hill ranges etc.) show oriented sillimanite aggregates pseudomorph after course twinned kyanite, staurolite + kyanite assemblages, and corroded blebs of gedrite within orthopyroxene, suggesting a prograde stage of a clockwise P-T evolution. Evidence of ITD history comes from the textures in which an early Mg-rich garnet (X_Mg 52–60) with orthopyroxene (up to 10% Al₂O₃) involving sillimanite breakdown forming variety of symplectites having combinations of orthopyroxene, sapphirine, cordierite, and spinel. These spectacular reaction textures, and mineralogic sensors from the high-grade rocks establish a prograde clockwise P-T-t path with notable decompressive history (ITD) in the southern granulite terrain. The inferred P-T-t paths have been further integrated with the recent geochronological, and isotopic data to constrain the timing, and duration of metamorphism, emplacement of the magmatic protolith for characterising the evolution of the granulites, and their bearing on the geodynamic implications. Based on the emerging evidence for Neoproterozoic tectonothermal imprints in the southern granulite terrain, history of the assembly of dispersed fragments is also addressed within the East Gondwana framework.     

Juxtaposition of India and Madagascar: A Perspective

Proterozoic terrains in South India and Madagascar provide important clues in understanding the Gondwanaland tectonics, especially the assembly of this mega-continent during the Pan-African period. The Archaean terrains in both Madagascar and India are characterized by N-S trending greenstone belts occurring within gneissose granitic rocks in the northern part. Extensive development of K-rich granitic rocks of ca. 2.5 Ga is also characteristic in both areas. Such a broad age zonation of younger Dharwar (ca 2.6–3.0 Ga) in the north and the older Sargur (ca 3.0–3.4 Ga) in the south as in South India remains to be identified in future studies from Madagascar. The occurrence of greenschist facies rocks in the northeastern part and higher grade rocks in most of other parts in the north-central terrain of Madagascar is comparable with the general tendency of increasing metamorphic grade from northwestern to southern areas ranging from greenschist to granulite facies in South India. The Proterozoic crystalline rocks in both continents show pronounced lithological similarity with the wide occurrence of graphite-bearing khondalite in association with charnockitic rocks. While the Archaean-Proterozoic boundary is well defined in southern India by the Palghat-Cauvery or the KKPT shear zones as recently identified, this boundary is ill-defined in Madagascar due to extensive Pan-African overprinting, as well as the development of the Proterozoic cover sequence, the Itremo Group. There is also a possible general correlation between the Mesoproterozoic cover sequences in Madagascar and India, such as between the Itremo Group of west-central Madagascar and the Kaladgi and Cuddapah sequences of South India. The Pan-African granulite facies metamorphism of ca. 0.5 Ga extensively developed in both India and Madagascar is generally comparable in intensity and extent. P-T conditions and P-T-t paths also appear comparable, with the general range of ca. 700–1000°C and 6–9 kb, and near-isothermal decompressional paths. A-type granite plutons and alkaline rocks including anorthosites and mafic plutonic rocks of ca. 500–800 Ma develop in both terrains, provide strong basis for the correlation of both terrains, and define a Pan-African igneous province within East Gondwanaland. Major shear zones in both continents are expected to play a critical role in the correlation, albeit are still poorly constrained. Detailed elucidation of the tectonic history of the shear zones, and the timing of various events along the shear zones would provide important constraints on the correlation of the two continental fragments.     

Geology of the High Grade Proterozoic Terrains of Sri Lanka, and the Assembly of Gondwana: an Update on Recent Developments

Nd model ages determined for the high-grade rocks of Sri Lanka delineate three crustal units, viz., the Highland Complex (HC), the Wanni Complex WC), and the Vijayan Complex (VC). The distribution of these three units differs considerably from the three geological divisions demarcated previously on the basis of geological mapping. The centrally located HC comprises mainly granulite grade charnockitic rocks, and metasediments characterized by older Nd model ages (2.0–3.4 Ga). The Highland sedimentary pile was thickened by intermittent granitoid intrusions, most of which are now charnockitic gneiss, and granulites, and basaltic sills, and dikes. All these metaigneous rocks now occur as conformable bands or layers due to intense polyphase deformation. The HC is bounded on the east by the amphibolite grade VC, composed mainly of granitic gneisses, basic gneisses, and migmatites, and they have ‘younger’ Nd model ages (1.1–1.8 Ga). The isotopic, and geochemical characteristics identify the precursors to the Vijayan rocks as I-type calc-alkaline granitoids originated at an ‘arc’-related tectonic environment. Thus, the earlier interpretation that the Vijayan rocks represent reworked HC was rejected. The granulite inliers within the VC, earlier considered as “resisters” to re-working, are now shown as overthrust klippen or rotated rafts of the HC. The WC, demarcated on the basis of Nd model ages (1.1–1.8 Ga) similar to those of the VC, lies west of the HC. It consists mainly of granitic gneisses, charnockitic gneisses, and migmatites, and the metamorphic grade ranges from amphibolite to granulite.Comprehensive geothermobarometric surveys constrain the P-T evolution of the three crustal units, and indicate that both the HC, and WC underwent near isobaric cooling, followed by a decompression with decreasing temperature. Extensive isotopic studies (U-Pb, Pb-Pb, Sm-Nd, Rb-Sr) have established a new geochronological framework for these high-grade rocks of Sri Lanka. The new framework has bracketed the age of high grade metamorphism in the three crustal units at 550–600 Ma.The recent advances in knowledge of the geology of Sri Lanka favour a strong geological correlation of the HC, and the VC of Sri Lanka, respectively, with the Lutzöw-Holm Complex, and the Yatmato-Belgica Complex in the East Antarctica. The geology of the WC suggests a possible correlation with Madagascar, and East Africa. The amalgamation of the three crustal units of Sri Lanka, is apparently related to the two distinct orogenic events that resulted in the assembly of the Gondwana supercontinent.     

A classification of gem corundum deposits aimed towards gem exploration

This classification of gem corundum (ruby and sapphire) deposits takes into consideration petrographic data, and the mode of genesis of the deposits. It is aimed at being practical and useful in the field, particularly for prospecting purposes.Deposits are classified into primary and secondary deposits. Primary deposits include igneous and metamorphic deposits. Igneous gem corundum deposits are rare and include sapphire-bearing syenites from Kenya. Emphasis is put on metamorphic deposits, that are subdivided into metamorphic s.s., metasomatic, and anatectic deposits. Many gem corundum deposits result from metasomatic processes. Small-scale metasomatism mostly involves desilication reactions between silico-aluminous rocks (pegmatites, gneisses, etc) and silica-poor rocks (ultramafites, meta-carbonates), and leads to the formation of limited-size deposits. Large-scale (diffuse) metasomatism is usually more difficult to characterize, and therefore is not separated from isochemical metamorphism in this classification. In metamorphic deposits, gem corundum results from transformation of an Al-rich and/or Si-poor protolith. Such deposits include ruby-bearing mafic granulites, ruby-bearing meta-limestones, and ruby/sapphire-bearing gneisses and granulites. An intermediate category includes anatectic deposits. Secondary deposits encompass sedimentary and volcanic (xenoclastic) occurrences. In sedimentary deposits, gem corundum occurs as clasts originating from other lithologies. In volcanic deposits, gem corundums are xenocrysts that have a range of origins.The proposed classification outlines geological environments favorable to the crystallization and distribution of gem corundum, thus facilitating prospecting and mining of this gemstone.     

Oxygen isotope systematics of gem corundum deposits in Madagascar: relevance for their geological origin

The oxygen isotopic composition of gem corundum was measured from 22 deposits and occurrences in Madagascar to provide a gemstone geological identification and characterization. Primary corundum deposits in Madagascar are hosted in magmatic (syenite and alkali basalt) and metamorphic rocks (gneiss, cordieritite, mafic and ultramafic rocks, marble, and calc-silicate rocks). In both domains the circulation of fluids, especially along shear zones for metamorphic deposits, provoked in situ transformation of the corundum host rocks with the formation of metasomatites such as phlogopite, sakenite, and corundumite. Secondary deposits (placers) are the most important economically and are contained in detrital basins and karsts. The oxygen isotopic ratios (¹⁸O/¹⁶O) of ruby and sapphire from primary deposits are a good indicator of their geological origin and reveal a wide range of δ¹⁸O (Vienna Standard Mean Ocean Water) between 1.3 and 15.6‰. Metamorphic rubies are defined by two groups of δ¹⁸O values in the range of 1.7 to 2.9‰ (cordieritite) and 3.8 to 6.1‰ (amphibolite). “Magmatic” rubies from pyroxenitic xenoliths contained in the alkali basalt of Soamiakatra have δ¹⁸O values ranging between 1.3 and 4.7‰. Sapphires are classified into two main groups with δ¹⁸O in the range of 4.7 to 9.0‰ (pyroxenite and feldspathic gneiss) and 10.7 to 15.6‰ (skarn in marble from Andranondambo). The δ¹⁸O values for gem corundum from secondary deposits have a wide spread between −0.3 and 16.5‰. The ruby and sapphire found in placers linked to alkali basalt environments in the northern and central regions of Madagascar have consistent δ¹⁸O values between 3.5 and 6.9‰. Ruby from the placers of Vatomandry and Andilamena has δ¹⁸O values of 5.9‰, and between 0.5 and 4.0‰, respectively. The placers of the Ilakaka area are characterized by a huge variety of colored sapphires and rubies, with δ¹⁸O values between −0.3 and 16.5‰, and their origin is debated. A comparison with oxygen isotope data obtained on gem corundum from Eastern Africa, India, and Sri Lanka is presented. Giant placer deposits from Sri Lanka, Madagascar, and Tanzania have a large variety of colored sapphires and rubies with a large variation in δ¹⁸O due to mingling of corundum of different origin: mafic and ultramafic rocks for ruby, desilicated pegmatites for blue sapphire, syenite for yellow, green, and blue sapphire, and skarn in marbles for blue sapphire.     

SHRIMP U–Pb zircon geochronology of high-grade rocks and charnockites from the eastern Amery Ice Shelf and southwestern Prydz Bay, East Antarctica: Constraints on Late Mesoproterozoic to Cambrian tectonothermal events related to supercontinent assembly

The eastern Amery Ice Shelf (EAIS) and southwestern Prydz Bay are situated near the junction between the Late Neoproterozoic/Cambrian high-grade complex of the Prydz Belt and the Early Neoproterozoic Rayner Complex. The area contains an important geological section for understanding the tectonic evolution of East Antarctica. SHRIMP U–Pb analyses on zircons of felsic orthogneisses and mafic granulites from the area indicate that their protoliths were emplaced during four episodes of ca. 1380 Ma, ca. 1210–1170 Ma, ca. 1130–1120 Ma and ca. 1060–1020 Ma. Subsequently, these rocks experienced two episodes of high-grade metamorphism at > 970 Ma and ca. 930–900 Ma, and furthermore, most of them (except for some from the Munro Kerr Mountains and Reinbolt Hills) were subjected to high-grade metamorphic recrystallization at ca. 535 Ma. Two suites of charnockite, i.e. the Reinbolt and Jennings charnockites, intrude the Late Mesoproterozoic/Early Neoproterozoic and Late Neoproterozoic/Cambrian high-grade complexes at > 955 Ma and 500 Ma, respectively. These, together with associated granites of similar ages, reflect late- to post-orogenic magmatism occurring during the two major orogenic events. The similarity in age patterns suggests that the EAIS–Prydz Bay region may have suffered from the same high-grade tectonothermal evolution with the Rayner Complex and the Eastern Ghats of India. Three segments might constitute a previously unified Late Mesoproterozoic/Early Neoproterozoic orogen that resulted from the long-term magmatic accretion from ca. 1380 to 1020 Ma and eventual collision before ca. 900 Ma between India and the western portion of East Antarctica. The Prydz Belt may have developed on the eastern margin of the Indo-Antarctica continental block, and the Late Neoproterozoic/Cambrian suture assembling Indo-Antarctica and Australo-Antarctica continental blocks should be located southeastwards of the EAIS–Prydz Bay region.     

Osumilite-sapphirine-quartz granulites from Enderby Land,Antarctica: P-T conditions of metamorphism,implications for garnet-cordierite equilibria and the evolution of the deep crust

Osumilite-sapphirine-quartz granulites from Enderby Land, Antarctica (Ellis et al. 1980) were metamorphosed at 8–10 kb pressure, 900°-980° C under very low conditions. Retrograde mineral coronas in these rocks record subsequent cooling from the peak of metamorphism at approximately constant pressure. The inferredP-T cooling-uplift path differs markedly from that evident in many other granulite terrains.Present garnet-cordierite geothermometers imply equilibration at temperatures of 500°–600° C, well within the kyanite stability field. These temperatures are inconsistent with the presence of sillimanite and the high temperature stability fields of the actual mineral assemblages. Examination of available garnetcordierite experimental data suggests a possible large increase in the Gt-Cd Fe-MgK _D with increasingX _Mg of the cordierite (and pressure). New experiments designed to test this possibility were inconclusive because of the failure to attain satisfactory equilibrium, even at 1,000° C.Possible reasons for the exposure of these unusual granulites in Enderby Land are considered. Although they formed at much higher temperatures than other granulites exposed on a regional scale, suchP-T conditions are not exceptional for the base of the crust. Instead, the unusual isobaric cooling to low temperatures followed by uplift to the surface which these granulites are inferred to have undergone is considered of importance. The unusual tectonic conditions are reflected in the disctinctive type of mineral reaction coronas found in these rocks. The common occurrence elsewhere of mineral reaction during uplift, and the role of anatexis during uplift in obliterating such high temperature assemblages elsewhere in the world are considered.     

Geochronology of the khondalite belt of Trivandrum Block, Southern India: Electron probe ages and implications for Gondwana tectonics

In a comprehensive U–Pb electron microprobe study of zircon and monazite from the khondalite belt of Trivandrum Block in southern Kerala, we present age data on five key metapelite locations (Nedumpara, Oottukuzhi, Kulappara, Poolanthara and Paranthal). The rocks here, characterized by the assemblage of garnet–sillimanite–spinel–cordierite–biotite–K–feldsapr–plagiocalse–quartz–graphite, have been subjected to granulite facies metamorphism under extreme thermal conditions as indicated by the stability of spinel + quartz and the presence of mesoperthites that equilibrated at ultrahigh-temperature (ca. 1000 °C) conditions. The oldest spot age of 3534 Ma comes from the core of a detrital zircon at Nedumpara and is by far the oldest age reported from this supracrustal belt. Regression of age data from several spot analyses in single zircons shows “isochrons” ranging from 3193 ± 72 to 2148 ± 94 Ma, indicating heterogeneous population of zircons derived from multiple provenance. However, majority of zircons from the various localities shows Neoproterozoic apparent ages with sharply defined peaks in individual localities, ranging between 644–746 Ma. The youngest zircon age of 483 Ma was obtained from the outermost rim of a grain that incorporates a relict core displaying ages in the range of 2061–2543 Ma.The cores of monazites also show apparent older ages of Palaeo-Mesoproterozoic range, which are mantled by late Neoproterozoic/Cambrian rims. The oldest monazite core has an apparent age of 2057 Ma. Extensive growth of new monazite during latest Neoproterozoic to Cambrian–Ordovician times is also displayed by grain cores with apparent ages up to 622 Ma. The homogeneous core of a sub-rounded monazite grain yielded a maximum age of 569 Ma, markedly younger than the 610 Ma age reported in a previous study from homogenous and rounded zircon core from a metapelite in Trivandrum Block. These younger ages from abraded grains that have undergone fluvial transport are interpreted to indicate that deposition within the khondalite belt was as young as, or later than, this range. Probability density plots indicate that majority of the monazite grain population belong to Late Proterozoic/Cambrian age (ca. 560–520 Ma) with major peaks defining sharp spikes in individual localities.The age data presented in this study indicate that the metasediments of the Trivandrum Block sourced from Archaean and Paleo-Mesoproterozoic crustal fragments that were probably assembled in older supercontinents like Ur and Columbia. The largest age population of zircons belong to the Neoproterozoic, and are obviously related to orogenies during the pre-assembly phase of Gondwana, possibly from terrains belonging to the East African Orogen. Several prominent age spikes within the broad late Neoproterozoic–Cambrian age range displayed by monazites denote the dynamic conditions and extreme thermal perturbations attending the birth of Gondwana. Our study further establishes the coherent link between India and Madagascar within the East Gondwana ensemble prior to the final assembly of the Gondwana supercontinent.     

Textures and phase relationships in ferrous granulites from Tidjenouine (Hoggar, Algeria): fayalite–ferrossilite–quartz secondary assemblage

Ferrous granulites in the area of Tidjénouine (Central Hoggar) exhibit a remarkable mineralogical composition characterized by the association orthoferrossilite–fayalite–quartz. These granulites are metamorphosed mafic igneous rocks showing the juxtaposition of different metamorphic parageneses. Peak paragenesis with garnet–clinopyroxene–amphibole–plagioclase–quartz reach to assemblage with orthopyroxene–plagioclase₂. Secondary orthopyroxene reacted with garnet to produce symplectites with fayalite + plagioclase + quartz. The latest stage corresponds to an orthopyroxene–fayalite–quartz–plagioclase assemblage. The metamorphic history of the ferrous granulites is inferred by combining the study of phase relations with the construction of a petrogenetic grid and pseudosection in the CFMASH and CFAS systems using the Thermocalc program of [J. Metamorph. Geol. 6 (1988) 173]. The evolution of paragenetic minerals indicates a metamorphic P–T path through the following conditions: 7.1 ± 1 kbar at 880 °C, 4.9 ± 1.6 kbar at 750 °C and 3–4 kbar at 700 °C, which is consistent with a clockwise P–T path recorded throughout the area.     

African, southern Indian and South American cratons were not part of the Rodinia supercontinent: evidence from field relationships and geochronology

We discuss the question whether the late Mesoproterozoic and early Neoproterozoic rocks of eastern, central and southern Africa, Madagascar, southern India, Sri Lanka and South America have played any role in the formation and dispersal of the supercontinent Rodinia, believed to have existed between about 1000 and 750 Ma ago. First, there is little evidence for the production of significant volumes of ˜1.4–1.0 Ga (Kibaran or Grenvillian age) continental crust in the Mozambique belt (MB) of East Africa, except, perhaps, in parts of northern Mozambique. This is also valid for most terranes related to West Gondwana, which are made up of basement rocks older than Mesoproterozoic, reworked in the Brasiliano/Pan-African orogenic cycle. This crust cannot be conclusively related to either magmatic accretion processes on the active margin of Rodinia or continental collision leading to amalgamation of the supercontinent. So far, no 1.4–1.0 Ga rocks have been identified in Madagascar. Secondly, there is no conclusive evidence for a ˜1.0 Ga high-grade metamorphic event in the MB, although such metamorphism has been recorded in the presumed continuation of the MB in East Antarctica. In South America, even the Sunsas mobile belt, which is correlated with the Grenville belt of North America, does not include high-grade metamorphic rocks. All terranes with Mesoproterozoic ages seem to have evolved within extensional, aulacogen-type structures, and their compressional deformation, where observed, is normally much younger and is related to amalgamation of Gondwana. This is also valid for the Trans-Saharan and West Congo belts of West Africa.Third, there is also no evidence for post-1000 Ma sedimentary sequences that were deposited on the passive margin(s) of Rodinia. In contrast, the MB of East Africa and Madagascar is characterized by extensive structural reworking and metamorphic overprinting of Archaean rocks, particularly in Tanzania and Madagascar, and these rocks either constitute marginal parts of cratonic domains or represent crustal blocks (terranes or microcontinents?) of unknown derivation. This is also the case for most terranes included in the Borborema/Trans-Saharan belt of northeastern Brazil and west-central Africa, as well as those of the Central Goíás Massif in central Brazil and the Mantiqueira province of eastern and southeastern Brazil.Furthermore, there is evidence for extensive granitoid magmatism in the period ˜840 to <600 Ma whose predominant calc-alkaline chemistry suggests subduction-related active margin processes during the assembly of the supercontinent Gondwana. The location of the main Neoproterozoic magmatic arcs suggests that a large oceanic domain separated the core of Rodinia, namely Laurentia plus Amazonia, Baltica and West Africa, from several continental masses and fragments now in the southern hemisphere, such as the São Francisco/Congo, Kalahari and Rio de La Plata cratons, as well as the Borborema/Trans-Saharan, Central Goiás Massif and Paraná blocks. Moreover, many extensional tectonic events detected in the southern hemisphere continental masses, but also many radiometric ages of granitois that are already associated with the process of amalgamation of Gondwana, are comprised within the 800–1000 age interval. This seems incompatible with current views on the time of disintegration of Rodinia, assumed to have occurred at around 750 Ma.     

Pleistocene raised marine deposits on Wrangel Island, northeast Siberia and implications for the presence of an East Siberian ice sheet

Two previously undocumented Pleistocene marine transgressions on Wrangel Island, northeastern Siberia, question the presence of an East Siberian or Beringian ice sheet during the last glacial maximum (LGM). The Tundrovayan Transgression (459,000–780,000 yr B.P.) is represented by raised marine deposits and landforms 15–41 m asl located up to 18 km inland. The presence of high sea level 64,000–73,000 yr ago (the Krasny Flagian Transgression) is preserved in deposits and landforms 4–7 m asl in the Krasny Flag valley. These deposits and landforms were mapped, dated, and described using amino acid geochronology, radiocarbon, optically stimulated luminescence, electron spin resonance, oxygen isotopes, micropaleontology, paleomagnetism, and grain sizes. The marine deposits are eustatic and not isostatic in origin. All marine deposits on Wrangel Island predate the LGM, indicating that neither Wrangel Island nor the East Siberian or Chukchi Seas experienced extensive glaciation over the last 64,000 yr.     

Distribution of Precambrian iron and gold deposits on the southwestern East European Platform reflected in underlying transcrustal structure and current river systems

The East European Platform is underlain by Archaean and Proterozoic complexes of the East European Craton. In the southwest these are locally exposed in the Ukrainian Shield and the Voronezh Massif on either side of the ca. 2000 km long ESE-striking late Palaeozoic Pripyat–Dniepr–Donets rift. Evaluation with Landsat imagery of 1 : 1,000,000 scale published maps of the Precambrian complexes [Zaritsky, A.I., Galetsky, L.S. (Eds.), 1992. Geology and Metallogeny of the Southwest of the East-European Platform Map Series, 1 : 1,000,000, Ukrainian State Committee on Geology and Utilization of Mineral Resources, Kiev.] is largely obstructed by a cover of post-Palaeozoic sediments and soils of variable thickness. This obstruction is aggravated by an almost continuous patchwork of farmlands. However, analysis of the current drainage patterns in the Dniepr River basin and surrounding regions reveals a spatial coincidence of numerous stream courses and watersheds with previously inferred steep, transcrustal discontinuities of most probably Precambrian age.Transcrustal dislocations constituted important pathways for heat and fluids as is indicated by the distribution of a large proportion of assumed Early Proterozoic hydrothermal iron and gold deposits along them. This distribution is underpinned by the spatial coincidence of mineralization and elongate areas of highly irregular magnetization attributed to uneven distribution of hydrothermal magnetite in banded iron formation. In view of the extent of these dislocations, both vertically and laterally, the generation of hydrothermal fluid flow, emplacement of mantle-sourced magma and associated mineral potential away from banded iron formation complexes is likely. A second group of gold deposits, of Archaean age, is known to occur in association with still recognizable volcanic edifices in greenstone complexes. It is not known if and to what extent such Archaean gold deposits are related to these major transcrustal discontinuities. The kinematics and dynamics of these dislocations and pathways appear largely unknown and deserve high-priority investigation. The geological longevity of the transcrustal dislocation framework till the present day inferred from the current drainage systems is corroborated, however, by repeated regional topographical levelling surveys.     

Tectonic controls on metamorphism, partial melting, and intrusion: timing and duration of regional metamorphism and magmatism in the Ni de Massif, Turkey

Mafic high-pressure granulite, eclogite and pyroxenite xenoliths have been collected from a Mesozoic volcaniclastic diatreme in Xinyang, near south margin of the Sino-Korean Craton (SKC). The high-pressure granulite xenoliths are mainly composed of fine-grained granoblasts of Grt+Cpx+Pl+Hbl±Kfs±Q±Ilm with relict porphyritic mineral assemblage of Grt+Cpx±Pl±Rt. P–T estimation indicates that the granoblastic assemblage crystallized at 765–890 °C and 1.25–1.59 GPa, corresponding to crustal depths of ca. 41–52 km with a geotherm of 75–80 mW/m². Calculated seismic velocities (V_p) of high-pressure granulites range from 7.04 to 7.56 km/s and densities (D) from 3.05 to 3.30 g/cm³. These high-pressure granulite xenoliths have different petrographic and geochemical features from the Archean mafic granulites. Elevated geotherm and petrographic evidence imply that the lithosphere of this craton was thermally disturbed in the Mesozoic prior to eruption of the host diatreme. These samples have sub-alkaline basaltic compositions, equivalent to olivine– and quartz–tholeiite. REE patterns are flat to variably LREE-enriched (La_N/Yb_N=0.98–9.47) without Eu anomaly (Eu/Eu*=0.95–1.11). They possess 48–127 ppm Ni and 2–20 ppm Nb with Nb/U and La/Nb ratios of 13–54 and 0.93–4.75, respectively, suggesting that these high-pressure granulites may be products of mantle-derived magma underplated and contaminated at the base of the lower crust. This study also implies that up to 10 km Mesozoic lowermost crust was delaminated prior to eruption of the Cenozoic basalts on the craton.     

Proterozoic magmatic and tectonometamorphic evolution of the Taratash complex, Central Urals, Russia

The Taratash Complex (TC) in the northernmost Bashkirian Anticlinorium (Middle Urals) is unique among the pre-Uralian polymetamorphic complexes along the eastern margin of the East European Craton because it experienced granulite facies peak metamorphic conditions (850–900°C/10 kbar). Herein, we constrain the post-granulite facies polystage evolution of the complex, which records various increments of the geodynamic history of the East European continental margin. Formation of granite and migmatite associated with amphibolite facies events are dated at 2,344±29 and 2,044±8 Ma (U–Pb, zircon) in different structural units. At 1,810±41 Ma, the TC was affected by a greenschist facies retrogressive metamorphism which was probably related to a stage of granite formation in the eastern part of the East European Craton. This is confirmed by a U–Pb–zircon age of 1,848±8 Ma obtained from a sheared granite in the adjacent Alexandrovskiy Complex (AC). Greenschist facies shear zones which separate different structural units of the TC formed before 1,350 Ma. Partial re-equilibration of Rb–Sr- and K–Ar-isotope systems between 1,350 Ma and 1,200 Ma is attributed to fluid flow probably induced by anorogenic magmatism in the Bashkirian Anticlinorium. Meso- to Neoproterozoic basaltic dykes indicate that the TC had been exhumed to upper crustal levels at that time. Evidence for a Grenvillian event or for the Timanian orogeny which affected other pre-Uralian complexes in the Urals is lacking. Uralian orogenic shortening and thrusting on Devonian limestones is recorded by shear zones in the AC to the east of the TC and has been dated at 300 Ma (Rb–Sr, ⁴⁰Ar/³⁹Ar).     

Advances in our understanding of the gem corundum deposits of the West Pacific continental margins intraplate basaltic fields

Recent discoveries over the last decade of new gemfields, exploitation of new and existing deposits, and application of relatively new techniques have greatly increased our knowledge of the basalt-derived gem sapphire–ruby–zircon deposits. In this paper we focus on the Late Mesozoic to Cenozoic intraplate basaltic fields of the West Pacific continental margins. We review advances made in understanding the genesis of these deposits, based on the application of newer techniques. We also critically review existing data on the gem corundum deposits, in order to further refine a model for their origin.In some of the intraplate basaltic fields, corundum-bearing xenoliths have been found showing a range of PT formation conditions from 790 °C at 0.85 GPa to as much as 1100 to 1200 °C at 1.0 to 2.5 GPa. Although most magmatic sapphires contain syngenetic inclusions of columbite-group phases, zircon, spinel and rutile, some contain additional nepheline and K-feldspar, suggesting crystallization from more undersaturated alkaline magma while the Weldborough field of NE Tasmania also contains molybdenite and beryl, suggesting at least some interaction with more fractionated ‘granitic-type’ magmas. There is a large range in PT conditions calculated for the metamorphic rubies (from 780 to 940 °C, through 800 to 1150 °C up to 1000 to 1300 °C). Fluid/melt inclusion studies on magmatic corundums generally suggest that they formed in a CO₂-rich environment from a ‘syenitic’ melt under a range of T conditions from 720 to 880 °C up to 1000 to 1200 °C. Oxygen isotope studies reveal that typical magmatic corundums have values of + 4.4 to 6.9‰, whereas metamorphic corundums from the same basaltic host have lower values of + 1.3 to 4.2‰.Geochronological studies have shown that some fields produced a simple eruptive and zircon/corundum crystallization event while others had multiple eruptive events but only one or two zircon crystallization events. For a few fields, some corundums/zircons crystallized in storage regions and then remained relatively inert for periods of 200 to 400 Ma without significant change before transport to the surface in the Cenozoic. Tectonic studies of the Australian region suggest that many of the corundums crystallized from magmas related to episodic basaltic volcanism in a tectonic regime of extension, associated with the opening of the Tasman and Coral Seas. For the Asian region, the magmatic–polygenetic corundums within the basaltic fields largely crystallized in a tectonic regime of distributed E–W extension, whereas the metamorphic-metasomatic corundums crystallised in a transpressional regime associated with the collision of the Indian Plate with the Eurasian Plate (e.g., [Garnier, V., Giuliani, G., Maluski, H., Ohnenstetter, D., Deloule, E., 2003. Ar–Ar and U–Pb ages of marble-hosted ruby deposits from Central and South-east Asia. Geophysical Research Abstracts 5, 03751; Garnier, V., Giuliani, G., Ohnenstetter, D., and Schwarz, D., 2004. Les gisements de corindon: classification et genese. Les placers a corindon gemme. Le Regne Mineral 55, 7-47; Garnier, V., Ohnenstetter, D., Giuliani, G., Maluski, H., Deloule, E., Phan Trong, T., Pham Van, L., Hoang Quang, V., 2005a. Age and significance of ruby-bearing marble from the Red River Shear Zone, Northern Vietnam. Canadian Mineralogist 43, 1315–1329]).