The effect of the crystal size in sample on the trace-element concentration

The dependence of trace-element concentration on the size of crystal in sample is experimentally studied by the example of gold distribution among single crystals of different sizes of hydrothermally grown pyrite, As-pyrite, and magnetite. The effect is modeled on the assumption that the Au uptake is due to a nonautonomous phase (NAP) at crystal surface. The structurally bound gold admixture is estimated from the dependence of the average content of evenly distributed gold on the specific surface of average crystal (1.5, 0.5, and 0.7 ppm for pyrite, As-pyrite with 0.02–0.08 wt.% As, and magnetite, respectively). The gold concentrations in hypothetical “pure” NAPs have been estimated by the extrapolation of the concentration dependence to the characteristic size of an NAP. The coefficients of fractionation of Au into an NAP relative to the bulk phase are 1.1 × 10³, 3.5 × 10³, and 2.4 × 10³ for pyrite, As-pyrite, and magnetite, respectively. Thus, the above effect is comparable in magnitude with the known effect of trace-element trapping by defects of crystal structure. Arsenic admixture favors the fractionation of gold into an NAP. We also considered other manifestations of this effect and its significance for solving problems of experimental geochemistry and analytical chemistry of trace elements and mineral processing. The data obtained substantiate the new mechanism of uptake of incompatible elements (including noble metals) during endogenic ore formation as more common and more effective than classical adsorption, including reducing adsorption of mercury and noble metals on mineral phases.     

Determining the optimum cell size of digital elevation model for hydrologic application

Scale is one of the most important but unsolved issues in various scientific disciplines that deal with spatial data. The arbitrary choice of grid cell size for contour interpolated digital elevation models (DEM) is one of the major sources of uncertainty in the hydrologic modelling process. In this paper, an attempt was made to identify methods for determining an optimum cell size for a contour interpolated DEM in prior to hydrologic modelling. Twenty-meter interval contour lines were used to generate DEMs of five different resolutions, viz., 30, 45, 60, 75, and 90 m using TOPOGRID algorithm. The obtained DEMs were explored for their intrinsic quality using four different methods, i.e., sink analysis, fractal dimension of derived stream network, entropy measurement and semivariogram modelling. These methods were applied to determine the level artifacts (interpolation error) in DEM surface as well as derived stream network, spatial information content and spatial variability respectively. The results indicated that a 90 m cell size is sufficient to capture the terrain variability for subsequent hydrologic modelling in the study area. The significance of this research work is that it provides methods which DEM users can apply to select an appropriate DEM cell size in prior to detailed hydrologic modelling.     

Changes in concentration and size distribution of aerosols during fog over the south Indian Ocean

Measurements of the concentration and size distribution of aerosol particles in the size-ranges of 0.5–20 μm and 16–700 nm diameters were made during six fog episodes over the south Indian Ocean. Observations show that concentrations of particles of all sizes start decreasing 1–2 hours before the occurrence of fog. This decrease is more prominent for coarse particles of >1 μm diameter and continues until 10–20 minutes before the onset of fog when particle concentrations in all size ranges rapidly increase by one/two orders of magnitude in ∼20 minutes. Thereafter, concentrations of particles of all sizes gradually decrease until the dissipation of fog. After the fog dissipation, concentrations of coarse mode particles rapidly increase and restore to their pre-fog levels but concentrations of the Aitken mode particles decrease slowly and reach their pre-fog levels only after 1–2 hours. The net effect of fog is to change the bimodal size distributions of aerosols with a coarse mode at 1.0 μm and an accumulation mode at 40–60 nm to a power law size distribution. It is proposed that the preferential growth and sedimentation of the coarse mode hygroscopic particles in the initial phase cause a large decrease in the aerosol surface area. As a result, the low vapour pressure gases which were initially being used for the growth of coarse mode particles, now accelerate the growth rates of the accumulation and Aitken mode particles.     

The geographical space of big companies

During its active life a large firm adopts several representations of the space with which it is in contact. The author is concerned with the recognition of the principal traits of these representations, based upon the results of questionnaires and interviews with representatives of a dozen French companies of international standing.Industrial space is signified by the distribution of productive forces, analysed and enumerated by classical geography. It has served as the basis of a systematisation aimed at the construction of a science of localisation. Nevertheless the factors compared are not of constant value.Commercial space which guides the sale-effort is structured by town centres and their level of attractiveness. Largely influenced by political geography it escapes complete domination because of the flux of commercial relationships.The thoughts of directors are exercised periodically at the level of world markets, monetary zones and tariffs, and the poles of decision that determine the march of events. In the last analysis strategic space thus perceived is financial space.     

基于ANSYS的液压卡盘胶筒的应力分析与优化

针对以往液压卡盘的胶筒在设计中用经验方法确定的安全系数难于保证胶筒结构的可靠性问题,通过有限元分析方法,对胶筒式液压卡盘的胶筒进行了应力分析,确定了对胶筒应力、应变有较大影响的因素。结果表明,在保证足够夹紧力的前提下,减小胶筒外直径,胶筒长度相应增加,并适当增加胶筒肩部倒角,可以有效改善胶筒的受力条件,提高胶筒使用的可靠性,从而可简化卡盘的结构,提高卡盘的可靠性。     

Relationships between DOC concentration,molecular size and fluorescence properties of DOM in a stream

The patterns of dissolved organic matter (DOM) fluorescence properties were examined in a Precambrian shield stream over a seven-month field study. Unique spatial and temporal patterns of simultaneous changes were observed in dissolved organic carbon concentration (DOC), humic-like fluorescence intensity, maximum excitation and emission wavelengths and fluorescence index (the ratio of the emission intensity at a wavelength of 450 nm to that at 500 nm at an excitation wavelength of 370 nm). The spatial change indicates the alteration of DOM along the length of the stream, and temporal change corresponded to a drought event in August. In contrast to humic-like fluorescence, the protein-like fluorescence shows considerable variability, suggesting its ephemeral nature. There were strong relationships between humic-like fluorescence intensity, fluorescence index, maximum Ex/Em wavelengths, DOC concentration and molecular size of DOM. This study has significant implications to the understanding of the nature and biogeochemical cycling of DOM.     

The impact of shipping on the invasion of alien plants to Norway

Important agencies responsible for the invasion of alien plants to Norway by means of shipping were ballast thrown ashore from sailing ships and contaminants in imported grain. Most ballast-plants were casuals, which disappeared when the ballast traffic ceased at the time of World War I. Changes in the origin of imported grain are reflected in the grain mill flora.     

计算最优化离散波数的优化算法

在阐述用最优化方法计算离散波数的基础上,对波数初值的给定及偏导数矩阵的计算方法作了进一步的改进,使其在数学推理上更加严密;在计算量和计算精度方面也有了很大的改善,并简化了程序设计。通过试算发现,反付氏变换的均方误差随波数个数的变化规律,即在变化曲线上存在转折点,在转折点之后误差趋于平稳变化。选取转折点处的波数个数作为反付氏变换的波数个数,这样在正演、反演过程中,既保证了计算精度,又节约了计算时间。     

The European system of capital cities

Capital cities reflect the nature and organization of the states they control. Their functional role is higher in centralized systems, societies where the state is the source of all legitimacy, and countries using Continental Law. It is lower in federal systems, pillarized societies and countries, which are ruled according to a Common Law. The symbolic status of capital cities is higher when the state is the source of all legitimacy, lower in consociationalist societies. Theses processes were responsible for the development of two types of political capital cities and one type of economic and cultural capital cities during the nineteenth century. A partial standardization of the functions and statuses of capital cities occurred later. The European Union is neither a state nor a super-state since its main responsibilities are still in the economic field, it lacks a huge administrative bureaucracy and does not have definitive territorial limits. The European Union has officially three capital cities, Strasbourg, Luxembourg and Brussels. The really important one is Brussels. Its functions are nevertheless quite different from those of national capital cities during the first half of the twentieth century. European capital cities are thriving because most of them managed to become economic metropolises. The result is that the European Union has a complex and rapidly evolving system of capital cities.     

The cityscapes of European capital cities

Capital cities are politico-administrative centers. They are command centers, they symbolize authority and also the unit that is governed. Primarily they are capitals of states, but other governance systems may also have capitals. In the European context there are now regional capital cities and at least the concept of a European capital. Particularly on account of their symbolic function but also for the uses made of its appearance in political life, the cityscape of capital cities is an interesting topic for research. There are different types of capital cities in Europe that give rise to different cityscapes. Existing urban networks and types of political regime are important in this respect. Although cityscapes are pretty stable, they are differently perceived over time and uses made of them also change. A research agenda for this intersection of historical, cultural and political geography should concentrate on the evolution of these cityscapes, their perception and the uses made of them in the acting out of politics.     

The integration of China's port system into global container shipping

There are many controversial issues concerning the relationships between container shipping lines, international port operators and the evolution of China's port system. We first present the factors linked with the transformation of the Pacific Rim transport environment resulting from increase container trade. This is followed by an analysis of China's port system. We argue that China is characterized by a ‘divided’ maritime transport system composed of three regions. The Chinese port system is marked by four interrelated transformations: port privatization, port expansion, modification of transactional networks and the emergence of a new business environment. The paper concludes on the need to upgrade China's port development policies. This revised version was published online in July 2006 with corrections to the Cover Date.     

滑石的最小及最佳纳米粒子的结构表征与计算

从纳米科技的角度出发 ,阐述了滑石纳米化研究的必要性。为了更充分地了解纳米滑石的性质 ,开拓纳米滑石应用的新领域 ,以矿物晶体结构、晶体化学理论为基础 ,根据滑石的晶胞参数、原子排列的特点等 ,提出了其最小纳米微粒的假设。通过对滑石微粒的晶胞数、原子数、平行 (0 0 1)面表面原子数及其比例的计算 ,分析讨论了它们与滑石微粒尺度的相关规律 ,同时在理论上对滑石微粒的最佳纳米尺度进行了确定     

Suspended sediment concentration and particle size distribution,and their relationship with heavy metal content

This paper aims at assessing the feasibility of suspended sediment concentration (SSC) estimation by using predictor variables of heavy metal concentration (HMC, viz., iron, chromium, zinc and nickel) transported in solution and solid. The study was conducted in the Research and Educational Forest Watershed of the Tarbiat Modares University (Kojour) which comprises an area of ca. 50000 ha. For this study, suspended sediment samples were collected from the left bank of the Kojour River twice a week, as well as during runoff events from November 2007 to June 2008. The samples were then prepared through direct digestion and finally analyzed by atomic absorption spectrophotometry (AAS). The relationship between SSC and particle size distribution (PSD) were correlated with HMC by using bivariate and multivariate regression models. Proposed models were then selected based on statistical criteria. The results showed high correlation between dissolved and particulate chromium content with efficiency coefficients beyond 77% (P < 0.001). However, a lower relationship was found between SSC and nickel content. From these results, it is clearly shown that the HMC can practically be estimated by SSC in watersheds with different accuracy and vice versa. It is also understood that heavy metal pollution can be easily managed by controlling SSC.     

Emplacement and the dispossessions of cosmopolitan capital

Ananya Roy’s theorization of the urban land question in terms of ‘dis/possessive collectivism’ is a powerful, eloquent intervention at a pivotal moment of intensified, planetary urban land inequalities. In this commentary, we evaluate Roy’s call to identify sites of “strategic illegality” from which to challenge the racial and class inequalities of capitalist colonization of urban land and property. Our analysis focuses on three transformations – evolving jurisdictional geographies, expanded proliferations of disparate impact, and reinforced infrastructures of monetized universalization – in which old, familiar exploitations are produced through the new multicultural meritocracies of an increasingly transnational, cosmopolitan capitalism.     

Metal concentration and particle size distribution of stream and river water polluted from copper rolling mill industry

Concentrations of heavy metals, pH, and particle size distribution parameters were measured in Dragica stream and Djetinja River water receiving wastewaters from copper rolling mill industry, Sevojno. The concentrations of copper, zinc, lead, and mercury were determined for water samples collected in summer 2009. It was found that Copper Rolling Mill Sevojno was the significant source of water pollution with copper and zinc. Considering that copper rolling mill industry, one of the larger emitters of sulfur dioxide, pollutes the area, the water pH was surprisingly alkaline. The particle size analysis results showed that particles from oil-in-water emulsion evidently got into stream water in spite of the purification devices used. In order to assess the possible relations between the measured parameters, a correlation analysis was performed. The correlation analysis showed a significant positive correlation between the total metal concentrations of copper and zinc, as well as between particle size distribution parameters and the concentration of lead and copper.     

The consumption of space: Land, capital and place in the New Zealand wine industry

Geographers have developed a keen interest in the social production of space - in the way meanings and values are ascribed to places as a result of changing social, cultural and political processes. There is a need to explore this approach further, seeing how social and economic values of places are inter-related and how these values are constructed in often deliberate and concerted ways. There is also a need to explore how such values are consumed: how the values in place are traded, appropriated and redistributed, both through the products of places and in land markets. This paper examines the New Zealand wine industry where certain wine regions have been identified and developed in ways which attempt to emphasise their distinctiveness in terms of wine quality and thus enhance the value of the wine produced. Different strategies have been employed in this process of place construction and this reflects the differential role of capital, striving on the one hand to increase the price and marketability of the products of distinctive places but, on the other, careful not to over-inflate land values and thus restrict further expansion. The paper suggests that the issue of consumption of space, involving a complex relationship amongst land, capital and place, is worthy of further exploration.     

Water and the entrepreneurial city: The territorial expansion of public utility companies from Colombia and the Netherlands

Since the mid-1980s, liberalization has motivated numerous water supply reforms. Among these, privatization has received the most attention. Yet, its actual scope has been limited. Beyond privatization, the territorial expansion of municipally owned water corporations into new service areas can be witnessed in countries as diverse as Italy, South Africa, Canada, Colombia and the Netherlands. Generally, the activities of public water corporations are analyzed through the lens of commercialization. This framework is central to understanding recent shifts in water supply. Yet, while it addresses the effects of commercialization on service quality and access, it rarely integrates the influence of shifts in social reproduction and collective consumption in structuring reform. Drawing on theories of urban entrepreneurialism, I attempt to advance a broader analytical framework that is more amenable to integrating the diversity of processes involved, including but not limited to commercialization. At the same time, the territorial expansion of municipally owned water corporations suggests ways to rethink urban entrepreneurialism: it is not only commercial, it is also social, and it is Schumpeterian. To make these points, this article examines the efforts of two public water corporations to go international: EPM of Medellín, Colombia and WMD of Drenthe, the Netherlands.