Benthic fluxes of dissolved inorganic carbon in the Tinto–Odiel system (SW of Spain)

The benthic fluxes (diffusive and with chambers) of dissolved inorganic carbon (DIC), dissolved oxygen (DO) and total alkalinity (TA) have been calculated in summertime in the estuary system formed by the mouths of the Tinto and Odiel rivers (SW of Spain). An increase of DIC in interstitial water with depth was found for all stations showing values of up to 28 mM at a depth of 5 cm. The diffusive fluxes of DIC and TA obtained ranging between 1.8–7.8 and 1.5–7.3 mmol m⁻² d⁻¹, respectively. These intervals are in agreement with those found for other coastal systems. Considering the plots of DIC vs. alkalinity (ΔDIC/ΔTA) in the first 30 cm of interstitial water, it was deduced that sulphate reduction and the oxidation of sulphides seem to have special relevance in the sediments of the stations studied. The benthic fluxes of inorganic carbon and DO measured by benthic chambers were variable, presenting elevated values (309–433 mmol DIC m⁻² d⁻¹ and 50–120 mmol DO m⁻² d⁻¹). The most elevated fluxes of DIC were seen at the stations with high anthropogenic influence (close to populated areas and industrial discharges). A great proportion of these fluxes are due to CaCO₃ dissolution processes, which constitute an estimated 49% of total DIC flux. DIC and DO benthic flux quotients were far in excess of unity, indicating the significance processes of anaerobic degradation of organic material at the stations studied.     

Large microplastic particles in sediments of tributaries of the River Thames,UK – Abundance,sources and methods for effective quantification

Sewage effluent input and population were chosen as predictors of microplastic presence in sediments at four sites in the River Thames basin (UK). Large microplastic particles (1 mm–4 mm) were extracted using a stepwise approach to include visual extraction, flotation and identification using Raman spectroscopy. Microplastics were found at all four sites. One site had significantly higher numbers of microplastics than other sites, average 66 particles 100 g^? 1, 91% of which were fragments. This site was downstream of a storm drain outfall receiving urban runoff; many of the fragments at this site were determined to be derived of thermoplastic road-surface marking paints. At the remaining three sites, fibres were the dominant particle type. The most common polymers identified included polypropylene, polyester and polyarylsulphone. This study describes two major new findings: presence of microplastic particles in a UK freshwater system and identification of road marking paints as a source of microplastics.

Runoff reconstruction for the Bailong River from tree rings back to AD 1601, reveals changing hydrological signals of China north–south transition zone

We present a runoff reconstruction for the Bailong River based on the composite chronology developed from four sampling sites of Pinus tabulaeformis in the China north–south transition zone. The runoff reconstruction, spanning 1601–2013 CE, was developed by calibrating tree-ring data with the instrumental runoff record. Runoff reconstruction accounted for 44.3% of the actual runoff variance during the common period 1958–2010 and provided a long-term perspective on hydrological change in the China north–south transition zone. In the past 413 years, high- and low-runoff years accounted for 15.50% and 15.98%, respectively. Of all the 17 extreme hydrological events, 14 of them are extremely high-flow years, and 17th century was the wettest period during the past 413 years. The preliminary analysis results show that there is a relationship between our runoff reconstruction and the Atlantic multidecadal oscillation at multidecadal scale. Since the 1990s, runoff in the China north–south transition zone has also seen a significant decrease as a result of dry trends of the source region.     

Carbon sinks/sources in the Yellow and East China Seas—Air-sea interface exchange,dissolution in seawater,and burial in sediments

The sinks/sources of carbon in the Yellow Sea(YS) and East China Sea(ECS), which are important continental shelf seas in China, could exert a great influence on coastal ecosystem dynamics and the regional climate change process. The CO_2 exchange process across the seawater-air interface, dissolved and particulate carbon in seawater, and carbon burial in sediments were studied to understand the sinks/sources of carbon in the continental shelf seas of China. The YS and the ECS generally have different patterns of seasonal air-sea CO_2 exchange. In the YS, regions west of 124°E can absorb CO_2 from the atmosphere during spring and winter, and release CO_2 to the atmosphere during summer and autumn. The entire YS is considered as a CO_2 source throughout the year with respect to the atmosphere, but there are still uncertainties regarding the exact air-sea CO_2 exchange flux. Surface temperature and phytoplankton production were the key controlling factors of the air-sea CO_2 exchange flux in the offshore region and nearshore region of the YS, respectively. The ECS can absorb CO_2 during spring, summer, and winter and release CO_2 to the atmosphere during autumn. The annual average exchange rate in the ECS was-4.2±3.2 mmol m~(-2) d~(-1) and it served as an obvious sink for atmospheric CO_2 with an air-sea exchange flux of 13.7×10~6 t. The controlling factors of the air-sea CO_2 exchange in the ECS varied significantly seasonally. Storage of dissolved inorganic carbon(DIC) and dissolved organic carbon(DOC) in the YS and the ECS were 425×10~6 t and 1364×10~6 t, and 28.2×10~6 t and 54.1×10~6 t,respectively. Long-term observation showed that the DOC content in the YS had a decreasing trend, indicating that the "practical carbon sink" in the YS was decreasing. The total amount of particulate organic carbon(POC) stored in the YS and ECS was10.6×10~6 t, which was comparable to the air-sea CO_2 flux in these two continental shelf seas. The amounts of carbon sequestered by phytoplankton in the YS and the ECS were 60.42×10~6 t and 153.41×10~6 t, respectively. Artificial breeding of macroalgae could effectively enhance blue carbon sequestration, which could fix 0.36×10~6–0.45×10~6 t of carbon annually. Organic carbon(OC) buried in the sediments of the YS was estimated to be 4.75×10~6 t, and OC of marine origin was 3.03×10~6 t, accounting for5.0% of the TOC fixed by phytoplankton primary production. In the ECS, the corresponding depositional flux of OC in the sediment was estimated to be 7.4×10~6 t yr~(-1), and the marine-origin OC was 5.5×10~6 t, accounting for 5.4% of the phytoplankton primary production. Due to the relatively high average depositional flux of OC in the sediment, the YS and ECS have considerable potential to store a vast amount of "blue carbon."     

Comparison of Pb(Ⅱ) and Cd(Ⅱ) micro-interfacial adsorption on fine sediment in the Pearl River Basin,China

The complex micro-interfacial interaction theories of heavy metal ions such as Pb(Ⅱ)and Cd(Ⅱ)adsorption on fine sediment in aqueous solution were not systematically investigated.The aim of this work was to reflect the micro-interfacial adsorption characteristics.Sediment samples were collected from an estuary.The Isothermal and kinetics adsorption experiment were done to acquire the data.Isothermal,kinetics,film diffusion and intraparticle diffusion models were adopted to fit the adsorption experimental data.The results indicated that the Langmuir,Freundlich and Temkin models were suitable for analyzing the isothermal experimental data.The maximum adsorption capacities of Pb(Ⅱ)and Cd(Ⅱ)on the sediment were 1.1377 and 0.9821 mg·g-1,respectively.The qm and KL of the Langmuir model,Kf and nF of the Freundlich model,and b and A of the Temkin model all exhibited a power function relationship with the initial adsorbate concentration.The pseudo-second-order model provided a better fit for the experimental kinetics data compared with the fit of the pseudo-first-order and Elovich models.The pseudo-second-order parameters k2 and qe of Pb(Ⅱ)and qe of Cd(Ⅱ)both had a power function relationship with adsorption time,additionally,the k2 of Cd(Ⅱ)had an exponential function relationship with adsorption time.The liquid-film diffusion parameters kfd of Pb(Ⅱ)and Cd(Ⅱ)were 0.0569 and 0.1806 min
1,respectively.The intraparticle diffusion parameter kid values of Pb(Ⅱ)and Cd(Ⅱ)were 0.0055 mg$g
1$min1/2 and 0.0049 mg$g
1$min1/2,respectively.The physical significance of the model parameters showed that Pb(Ⅱ)adsorption on sediment was stronger than Cd(Ⅱ).The results of this study provided a theoretical reference for the micro-interfacial mechanism of heavy metal ion adsorption on sediment.     

Impact of land-use change on hydrological processes in the Maying River basin, China

Since the 1960s, dramatic changes have taken place in land-use patterns characterized by the persistent expansion of cultivated land and a continuous decrease in natural woodland and grassland in the arid inland river basins of China. It is very important to assess the effects of such land-use changes on the hydrological processes so vital for water resource management and sustainable development on the catchment scale. The Maying River catchment, a typical arid inland watershed located in the middle of the Hexi Corridor in northwest China, was the site chosen to investigate the hydrological responses to land-use changes. The annual runoff, base flow, maximum peak flow, and typical seasonal runoff in both spring and autumn flood periods were selected as the variables in the hydrological processes. Statistical-trend analysis and curvilinear regression were utilized to detect the trends in hydrological variables while eliminating the climatic influence. The relationship between cultivated land-use and hydrological variables was analyzed based on four periods of land-use variation data collected since 1965. A runoff model was established composed of two factors, i.e., cultivated land use and precipitation. The impact of land use changes, especially in the large ar- eas of upstream woodland and grassland turned into cultivated lands since 1967, has resulted in a mean annual runoff decrease of 28.12%, a base flow decline of 35.32%, a drop in the maximum peak discharge of 35.77%, and mean discharge decreases in spring and autumn of 36.05% and 24.87% respectively, of which the contribution of cultivated land expansion to the influence of annual runoff amounts to 77%-80%, with the contribution to the influence of spring discharge being 73%-81%, and that to the influence of base flow reaching 62%-65%. Thus, a rational regulation policy of land use patterns is vitally important to the sustainable use of water resources and the proper development of the entire catchment.     

Magnetostratigraphy of Plio–Pleistocene fossiliferous cave sediments in the Bubing Basin,southern China

Our understanding of the chronological sequence of Pleistocene land mammal faunas (including hominids) preserved in caves and fissures in the karstic terrain of subtropical southern China has been greatly impeded by the discontinuous nature of the strata yielding the fossils. A contributory issue is the lack of suitable elements for numerical dating, especially for the Early Pleistocene cave sediments. Here we present new magnetostratigraphic dating results for five cave sedimentary sequences in the Bubing Basin, Guangxi Zhuang Autonomous Region, which contain the typical Pleistocene Gigantopithecus fauna and Ailuropoda–Stegodon fauna of southern China. The five karstic caves are situated at elevations ranging from 252 m to 191 m above sea level. The integrated dating results reveal that the five cave sedimentary sequences span an age range from the late Gauss normal Chron to the early Brunhes normal Chron. The faunas are assigned to >2.6 Ma (Mohui–houshan Cave), 1.95–1.78 Ma (Mohui Cave), 0.99–0.78 Ma (Baolai Cave) and ∼0.7 Ma (Upper Wuyun and Ganxian Caves). Furthermore, by combining our new magnetostratigraphy work with previously published magnetostratigraphic, U–series and electron spin resonance dating results, a chronological sequence of the Plio–Pleistocene mammalian faunas from cave sites in southern China has been established. The chronological sequence contributes to an improved understanding of the evolutionary processes of Plio–Pleistocene land mammals, as well as of early humans in subtropical southern China.     

Temporal and spatial variation and stability of the oasis in the Sangong River Watershed, Xinjiang, China

The unique ecological landscapes are composed of the mountain systems with the obviousvertical differentiation, vast natural desert systems, and oasis systems on which the human beings rely for the existence in the arid areas in West China. Oases are the …     

Comparison of Pb(Ⅱ) and Cd(Ⅱ) micro-interfacial adsorption on ?ne sediment in the Pearl River Basin,China

The complex micro-interfacial interaction theories of heavy metal ions such as Pb(II) and Cd(II)adsorption on fine sediment in aqueous solution were not systematically investigated. The aim of this work was to reflect the micro-interfacial adsorption characteristics. Sediment samples were collected from an estuary. The Isothermal and kinetics adsorption experiment were done to acquire the data.Isothermal, kinetics, film diffusion and intraparticle diffusion models were adopted to fit the adsorption experimental data. The results indicated that the Langmuir, Freundlich and Temkin models were suitable for analyzing the isothermal experimental data. The maximum adsorption capacities of Pb(II) and Cd(II)on the sediment were 1.1377 and 0.9821 mg·g_(-1), respectively. The q_m and K_L of the Langmuir model, K_f and n_F of the Freundlich model, and b and A of the Temkin model all exhibited a power function relationship with the initial adsorbate concentration. The pseudo-second-order model provided a better fit for the experimental kinetics data compared with the fit of the pseudo-first-order and Elovich models.The pseudo-second-order parameters k_2 and q_e of Pb(II) and q_e of Cd(II) both had a power function relationship with adsorption time, additionally, the k_2 of Cd(II) had an exponential function relationship with adsorption time. The liquid-film diffusion parameters k_(fd) of Pb(II) and Cd(II) were 0.0569 and 0.1806 min_(-1), respectively. The intraparticle diffusion parameter k_(id) values of Pb(II) and Cd(II) were0.0055 mg·g_(-1)·min_(1/2) and 0.0049 mg·g_(-1)min_(1/2), respectively. The physical significance of the model parameters showed that Pb(II) adsorption on sediment was stronger than Cd(II). The results of this study provided a theoretical reference for the micro-interfacial mechanism of heavy metal ion adsorption on sediment.     

Assessment of heavy metal contamination in the sur?cial sediments from the lower Meghna River estuary,Noakhali coast,Bangladesh

Sediment samples were collected from ten selected sites of the lower Meghna River estuary, and six heavy metals were analyzed with Atomic Absorption Spectrophotometry(AAS) to assess the contamination level and the metals' association with sediment grain size. The current results revealed that the mean concentrations of the studied metals were ranked in descending order of iron(Fe)(1.29 ? 103 mg/kg) zinc(Zn)(42.41 mg/kg) lead(Pb)(12.48 mg/kg) chromium(Cr)(10.59 mg/kg) copper(Cu)(6.22 mg/kg) cadmium(Cd)(0.28 mg/kg). The geo-accumulation, contamination, and pollution load indexes suggested that the lower Meghna river estuary was not contaminated by Fe, Zn, Pb, Cr, and Cu.The mean size of the sediment ranged from 28.92 to 126.2 mm, and the Pearson correlation coefficient showed a significant association between Fe and Pb(coefficient of determination, r2? 0.836; p 0.05),and no significant correlation was found between individual metals and grain size, indicating no or low influence on the metals distribution.     

Southeastern extension of the Red River fault zone (RRFZ) and its tectonic evolution significance in western South China Sea

The tectonic evolution features in the western South China Sea (SCS) are directly related to the Tethys tectonic province. The Red River fault zone (RRFZ) comprises a large part of the Tethys tectonic province and is the boundary between the Europe Block and the India-Asia Block[1]. It serves as the contact between the uplift of the Qinghai-Tibet Plateau and the SCSopening. The RRFZ, which is an important dividing line in the geology of the SE Asia, is about 1000 km long in the co…     

Strain and shear types of the Louzidian ductile shear zone in southern Chifeng, Inner Mongolia, China

The Louzidian ductile shear zone at the south of Chifeng strikes NE-SW and dips SE at low-medium- angles. This ductile shear zone is mainly composed of granitic mylonite, which grades structurally upward into a chloritized zone, a microbreccia zone, a brittle fault and a gouge zone. All these zones share similar planar attitudes, but contain different linear attitudes and kinematic indicators. Finite strain measurements were performed on feldspar porphyroclasts using the Fry method. These meas- urements yield Fulin indexes of 1.25―3.30, Lode's parameters of -0.535―-0.112 and strain parameters of 0.41―0.75 for the protomylonite, respectively. These data are plotted within the apparent constric- tional field in Fulin and Hossack diagrams. In contrast, for the mylonite, corresponding parameters are 0.99―1.43, -0.176―-0.004 and 0.63―0.82, respectively, and located in the apparent constrictional field close to the plane strain. The mean kinematic vorticity numbers of the protomylonite and mylonite by using three methods of polar Mohr circle, porphyroclast hyperbolic and oblique foliation, are in the range of 0.67―0.95, suggesting that the ductile shearing is accommodated by general shearing that is dominated by simple shear. Combination of the finite strain and kinematic vorticity indicates that shear type was lengthening shear and resulted in L-tectonite at the initial stage of deformation and the shear type gradually changed into lengthening-thinning shear and produced L-S-tectonite with the uplifting of the shear zone and accumulating of strain. These kinds of shear types only produce a/ab strain facies, so the lineation in the ductile shear zone could not deflect 90° in the progressively deformation.     

Annual variation of carbon flux and impact factors in the tropical seasonal rain forest of Xishuangbanna, SW China

Two years of eddy covariance measurements of above- and below-canopy carbon fluxes and static opaque chamber and gas chromatography technique measurements of soil respiration for three treatments (bare soil, soil litterfall, soil litterfall seedling) were carried out in a tropical seasonal rain forest. In addition, data of photosynthesis of dominant tree species and seedlings, leaf area index, litter production and decomposing speed, soil moisture, soil temperature and photosynthetic photon flux density within the forest were all measured concurrently. Data from January 2003 to December 2004 are used to present annual variability of carbon flux and relationships between carbon flux and impact factors. The results show that carbon flux of this forest presented unusual tendency of annual variation; above-canopy carbon fluxes were negative in the dry season (November-April) and mainly positive in the rainy season, but overall the forest is a carbon sink. Carbon flux has obviously diurnal variation in this tropical seasonal rain forest. Above-canopy carbon fluxes were negative in the daytime and absolute values were larger in the dry season than that in the rainy season, causing the forest to act as a carbon sink; at night, carbon fluxes were mainly positive, causing the forest to act as a carbon source. Dominant tree species have greater photosynthesis capability than that of seedlings, which have a great effect on above-canopy carbon flux. There was a significant correlation between above-canopy carbon flux and rate of photosynthesis of tree species. There was also a significant correlation between above-canopy carbon flux and rate of photosynthesis of seedlings; however, the below-canopy carbon flux was only significantly correlated with rate of photosynthesis of seedlings during the hot-dry season. Soil respiration of the three treatments displayed a markedly seasonal dynamic; in addition, above-canopy carbon fluxes correlated well with soil respiration, litterfall production, litterfall decomposition rate, precipitation, and soil moisture and temperature. A primary statistical result of this study showed that above-canopy carbon flux in this forest presented carbon source or sink effects in different seasons, and it is a carbon sink at the scale of a year.     

Spatial and temporal characteristics of changes in precipitation during 1957�C2007 in the Haihe River basin, China

The present study explores the spatial and temporal changing patterns of the precipitation in the Haihe River basin of North China during 1957–2007 at annual, seasonal and monthly scales. The Mann–Kendall and Sen’s T tests are employed to detect the trends, and the segmented regression is applied to investigate possible change points. Meanwhile, Sen’s slope estimator is computed to represent the magnitudes of the temporal trends. The regional precipitation trends are also discussed based on the regional index series of four sub-basins in the basin. Serial correlation of the precipitation series is checked prior to the application of the statistical test to ensure the validity of trend detection. Moreover, moisture flux variations based on the NCEP/NCAR reanalysis dataset are investigated to further reveal the possible causes behind the changes in precipitation. The results show that: (1) Although the directions of annual precipitation trends at all stations are downward, only seven stations have significant trends at the 90% confidence level, and these stations are mainly located in the western and southeastern Haihe River basin. (2) Summer is the only season showing a strong downward trend. For the monthly series, significant decreasing trends are mainly found during July, August and November, while significant increasing trends are mostly observed during May and December. In comparison with the annual series, more intensive changes can be found in the monthly series, which may indicate a shift in the precipitation regime. (3) Most shifts from increasing trends to decreasing trends occurred in May–June, July, August and December series, while opposed shifts mainly occurred in November. Summer is the only season displaying strong shift trends and the change points mostly emerged during the late 1970s to early 1980s. (4) An obvious decrease in moisture flux is observed after 1980 in comparison with the observations before 1980. The results of similar changing patterns between monthly moisture budget and precipitation confirmed that large-scale atmospheric circulation may be responsible for the shift in the annual cycle of precipitation in the Haihe River basin. These findings are expected to contribute to providing more accurate results of regional changing precipitation patterns and understanding the underlying linkages between climate change and alterations of hydrological cycles in the Haihe River basin.     

Do model parameters change under changing climate and land use in the upstream of the Lancang River Basin,China?

ABSTRACT

Hydrological model parameters may vary under the impacts of climate and land-use change. This study proposes a hydrological modelling framework based on the Soil and Water Assessment Tool (SWAT) to investigate the variability of model parameters in three different experiments and to assess the impacts of climate and/or land-use change on these parameters in the upstream of the Lancang River Basin, China. In Experiment 1 (E1), most parameters show clear temporal trends under changing climate and land use, implying that model parameters are strongly influenced by their combined effects. Experiments 2 (E2) and 3 (E3) investigate the separate impacts of land-use change and climate change, respectively. Due to the almost invisible changes in land use in E2, there is no change detected in the model parameters. Temporal trends are found in most parameters in E3 and over half of them show consistent trends with E1, which indicates that climate change has greater impacts on model parameter variability. The simulated extreme streamflow and sediment fluxes vary substantially with time-variant parameters, implying that the variations in model parameters do matter for hydrological prediction.     

Spatial distribution and temporal variation of reference evapotranspiration during 1961–2006 in the Yellow River Basin,China

Abstract

To explore the spatial and temporal variations of the reference evapotranspiration (ET_ref) is helpful to understand the response of hydrological processes to climate changes. In this study, ET_ref was calculated by the Penman-Monteith method (P-M method) using air temperature, wind speed, relative humidity and sunshine hours at 89 meteorological stations during 1961–2006 in the Yellow River Basin (YRB), China. The spatial distribution and temporal variations of ET_ref were explored by means of the kriging method, the Mann-Kendall (M-K) method and the linear regression model, and the causes for the variations discussed. The contribution of main meteorological variables to the variations of ET_ref was explored. From the results we found that: (1) the spatial distributions of ET_ref display seasonal variation, with similar spatial patterns in spring, summer and autumn; (2) temporal trends for ET_ref showed large variation in the upper, middle and lower regions of the basin, most of the significant trends (P?=?0.05) were detected in the middle and lower regions, and, in particular, the upward and downward trends were mainly detected in the middle region and lower region of the basin, respectively; and (3) sensitivity analysis identified the most sensitive variable for ET_ref as relative humidity, followed by air temperature, sunshine hours and wind speed at the basin scale.

Citation Yang, Zhifeng, Liu, Qiang & Cui, Baoshan (2011) Spatial distribution and temporal variation of reference evapotranspiration during 1961–2006 in the Yellow River Basin, China. Hydrol. Sci. J. 56(6), 1015–1026.     

Natural Radionuclides 238U, 226Ra,and 222Rn in the Surface Water of the El’konskii Uranium Ore Region,Southern Yakutia

Water Resources - Surface water chemistry and content of radionuclides 238U, 226Ra, and 222Rn were studied in both natural and technogenic landscapes of Southern Yakutia. The technogenically...     

The December 26, 2004, tsunami on Sumatra Island as a source of internal gravity waves in the earth’s atmosphere

Records of the coastal mareographs during the December 26, 2004, tsunami are used to study the fine structure of the tsunami wave power spectra. It is shown that a series of maxima is observed in their spectra near the source in a range of internal gravity wave frequencies of 0.2–1.2 mHz, which coincides with the frequencies of the natural oscillations of the Earth. This experimental finding enables us to propose a possible physical mechanism for the formation of tsunami waves as a result of oscillations in the sea bottom at these frequencies. Internal gravity waves in the Earth’s atmosphere excited in this way are found in the variations of the total electron content that resulted from this powerful earthquake.