秦岭东段主要类型金红石矿床的稀土元素地球化学特征

秦岭东段主要原生金红石矿床均受不同程度的变质作用形成。通过对该区四种主要金红石矿床稀土元素地球化学特征的分析及对含矿原岩的恢复，认为本区不同类型金红石矿床的∑ＲＥＥ、ＬＲＥＥ／ＨＲＥＥ、δＥｕ值等特征有很大差别，并显示出了本区金红石矿床成因的多样性和复杂性；稀土元素与Ｔｉ的富集关系的研究结果表明：任何一种类型矿床中，稀土越富集，轻、重稀土分异程度越高，δＥｕ值越大，越有利于Ｔｉ的富集。     

新西兰地热系统中稀土元素的行为

位于新西兰北岛Ｔｕａｐｏ火山带地热系统内的热液蚀变流纹岩的稀土元素（ＲＥＥ）模式为我们提供了ＲＥＥ活动的证据。未蚀变流纹岩的ＲＥＥ分配趋势是中等程度富集ＬＲＥＥ（Ｌａ／Ｌｕ）ｃｏ＾＊＝３．８４￣５．６２）以及Ｅｕ具明显的负异常。相比之下，热液蚀变流纹岩的ＲＥＥ分配型式则明显不同，并可分为四种不同的岩石化学类型。含粘土矿物＋石英＋长石＋方解石（土沸石、绿帘石、榍石、绿泥石、不透明矿物）矿物组合的岩石     

热水沉积电气石岩稀土元素地球化学特征

阐述了辽东元古宙大陆型裂谷内层状硫化物矿床中伴生的电气岩稀土元素特征。含矿建造内的电气石岩具有ＲＥＥ总量低，较强的Ｅｕ正异常和Ｃｅ负异常，稀土元素属（ＬＲＥＥ／ＨＲＥＥ）Ｎ＞１．３的富集型，为热水沉积的产物。纹层状电气石岩的ＲＥＥ研究证明，成矿流体来自富含挥发份的深源。     

云南会泽铅锌矿床构造控矿及断裂构造岩稀土元素组成特征

云南会泽超大型铅锌矿床是川滇黔铅锌成矿区大型富铅锌矿床的典型代表,本文在研究矿区成矿地质背景,划分断裂构造岩类型及构造体系的基础上,提出ＮＥ构造带（华夏系）是会泽铅放离主要的成矿构造体系,概括了构造控矿特征,以控矿断裂带中的构造岩、矿及为主要研究对象,分析不同方向断裂的构造岩的稀土元素组成特征,按其特征和酝酿民分模式,将构造岩（矿石）划分为７种类型：Ｅｕ富集－开阔“Ｗ”型、Ｃｅ富集－Ｅｕ弱亏损－平缓型、平缓型、ＨＲＥＥ－ＬＲＥＥ较富集－开阔“Ｖ”字型、Ｅｕ强亏损－下斜型,Ｅｕ亏损－下斜型、Ｅｕ亏损－平缓型、其中ＮＥ向断裂带中的Ｃｅ富集－Ｅｕ弱亏损－平缓型与Ｅｕ富集－平缓型模式的构造岩是成矿预测的微观标志之一。     

也谈大兴安岭南段前进场岩体成因类型和形成环境

前进场岩体在岩石地球化学方面以过铝、富集ＬＲＥＥ、具中等负Ｅｕ异常为特征，∑ＲＥＥ介于１０７．８１－１４３．２４μｇ／ｇ之间，结合其野外地质特征和区域构造分析，本文认为该岩体为板块碰撞期间于晚石炭世由沉积物质部分熔融而形成的Ｓ型花岗岩。     

滇东南南秧田两种不同成因类型白钨矿的稀土元素地球化学特征

滇东南南秧田白钨矿矿石类型有两种：矽卡岩型和石英脉型。研究结果表明,不同矿石类型中的白钨矿,在ΣＲＥＥ、ＬＲＥＥ／ＨＲＥＥ比值、δＥｕ值和（Ｌａ／Ｙｂ）Ｎ比值等地球化学参数方面有着明显的差异,反应出矿石矿物形成于不同的地质地球化学环境。而且,根据白钨矿中稀土元素的组成特征和Ｌａ、Ｃｅ和Ｙ的含量可有效地判别不同矿石类型的成因和物质来源。     

622铀矿主档与虎圩金矿床REE特征对比

本文通过赣杭火山岩带中的铀矿床和金矿床的ＲＥＥ特征对比，认为产铀矿和金矿的火山岩均属ＬＲＥＥ富集型，但前 者明显的铕亏损；铀矿石与金矿石ＲＥＥ特征差别大，前者∑ＲＥＥ和ＨＲＥＥ大大增高，铕强烈亏损，后者∑ＲＥＥ降低，铕呈弱异常或无异常。ＲＥＥ贫富程度和分布模式可作为矿床评价因素。     

中国大陆科学钻探主孔高钛与低钛榴辉岩地球化学特征对比及其对金红石成矿的指示意义

榴辉岩型金红石矿床是我国原生金红石矿床的最重要类型。本文以中国大陆科学钻探主孔0～2000m范围内揭露的榴辉岩为对象,通过对榴辉岩中TiO2与其它元素协变关系的全面分析,同时结合我国原生榴辉岩型金红石矿床TiO2的平均品位,将榴辉岩区分为高钛榴辉岩（TiO2〉2％）和低钛榴辉岩（TiO2〈2％）,并据此系统对比了二类榴辉岩地球化学组成的差异。研究结果表明,高钛榴辉岩相对贫硅、贫钾、富铁,Al2O3／TiO2比值和全碱（K2O＋Na2O）含量总体偏低,Cs、Rb、Ba等大离子亲石元素和Zr、Hf等高场强元素不同程度亏损,而放射性元素Th、U则相对富集,并总体具有较低的轻重稀土比值。榴辉岩型金红石矿床的形成主要受原岩因素制约,原岩的源区组成、产出环境、起源深度、部分熔融程度和随后的结晶分异过程对Ti的初始富集均具重要影响,富钛基性原岩是榴辉岩型金红石矿床形成的物质基础,高压区域变质作用是这类矿床形成的必要条件。     

长江中下游地区若干Cu(Au)、Cu-Fe(Au)和Fe矿床中钙质夕卡岩的稀土元素地球化学

本区夕卡岩的稀土元素（ＲＥＥ）分布模式表现为富集轻稀土元素（ＬＲＥＥ）的直线型和以Ｃｅ、Ｐｒ或Ｎｄ为峰值的折线型。夕卡岩全岩中ＲＥＥ分布模式基本上受石榴子石中ＲＥＥ的分配行为控制。石榴子石富集ＬＲＥＥ可能是承袭形成它们的初始物中ＲＥＥ丰度和分配行为的反映。石榴子石中ＲＥＥ（尤其是Ｌａ）分布的不均匀性、石榴子石微裂隙及包裹体中ＲＥＥ的丰度可能是导致直线型和过渡型ＲＥＥ分布模式的主要原因。石榴子石中折线型ＲＥＥ分布模式可能受石榴子石晶体化学和晶体结构的控制。具有这种ＲＥＥ分布模式的钙铁－钙铝榴石可能代表相对平衡条件下岩浆结晶分异产物。     

华北克拉通基性火山岩高场强元素对Ar—Pt界限及新 …

华北克拉通不同时代基性火山岩存在向富集方向演化的趋势,并出现明显的Ａｒ－Ｐｔ界面和新生代异常,元古宙基性火山岩比太古宙富集大部分高场强元素（ＨＦＳＥ）和轻稀土元素（ＬＲＥＥ）,ＲＥＥ分异程度显著增加,而且相容性接近的不相容元素（如Ｎｂ,Ｔａ）的相对不相容性发生了改变,新生代玄武岩ＨＦＳＥ及Ｎｉ高度富集,ＲＥＥ强烈分异,δ（Ｅｕ）值最高,Ａｒ－Ｐｔ界面可能与地幔熔融时期物理条件（如氧逸度）的改变和地     

Rare—Earth Element Geochemistry of Elogites from the Ultra—High Pressure Metamorphic Belt in Central China

Based on their REE contents and REE patterns,eclogites from the ultra-high pressure metamorphic belt in central China may be roughly divided into xis types including LREE-rich.LREE-rich positive Eu anomaly,LREE-rich negative Eu anomaly,REE pattern-smooth,MREE-rich and HREE-rich.The LREE_rich,LREE-rich positive Eu anomaly and LREE-rich negative Eu anomaly types of eclogites are dominant .REE types of eclogites in different areas can be compared and the REE feactures of the same REE type of eclogites in different areas are similar.The results of reconstruction of the primary rocks show that the primary rocks of eclogites possibly are dominated by continental tholeiites which are the product of partial melting of relatively fertile mantle and the rocks of tholeiite crystallization-differentiation.There is perfect evolution relationship among the primary rocks of the LREE-rich, LREE-rich positive Eu anomaly and LREE-rich negative Eu anomaly types of eclogites and among those of the REE pattern smooth and MREE-rich types of eclogites,the former three types were deried from continental settings and the latter two from nearly oceanic settings.Meanwhile,it is concluded that the mantle sources of primary rocks of the eclogites are inhomogeneous and the primary rocks of eclogites in this area appear to have undergone varying degree of crustal contamination.     

REE Geochemical Characteristics of Apatite,Sphene and Zircon from Alkaline Rocks

The accessory minerals apatite and sphene are the main carriers of REE in alkaline rocks.Their chondrite-normalized REE patterns decline sharply to the right as those of the host rocks,In the patterns an obvious negative Eu anomaly and a positive Ce anomaly can be seen in apatite and sphene,respectively.Zircon from alkaline rocks is different in REE pattern,I,e,. a nearly symmetric“V“-shaped pattern with a maximum negative Eu anomaly.Compared with the equivalents from granites,apatite,sphene and zircon from alkaline rocks are all characterized by higher (La/Yb)N ratio and less Eu depletion,As to the relative contents of REE in minerals,apatite,sphene and zircon are enriched in LREE,MREE and HREE respectively,depending on their crystallochemical properties.     

黔西南晴隆锑矿区萤石的稀土元素地球化学特征

对与辉锑矿共生萤石的稀土元素地球化学特征研究表明，所有萤石均具有Ce负异常，其稀土配分模式存在3种类型：Eu弱亏损型、Eu正常型、Eu富集型。从成矿早期至晚期，萤石的稀土配分从Eu弱亏损型向富集型演化，稀土总量逐渐降低，并由中稀土富集向轻稀土富集演化。成矿流体可能主要属于盆地流体，具有十分低的稀土总量，在成矿作用过程中，成矿流体由早期的还原条件转化为晚期的氮化条件，由中稀土富集向轻稀土富集演化。     

哀牢山金矿带成矿流体稀土元素地球化学

本项研究测定了矿石、蚀变围岩和相应未蚀变岩石的稀土元素组成。通过对这些地质体稀土元素地球化学特征的对比研究发现,在成矿流体的演化过程中,镇沅和墨江两个金矿床成矿流体的稀土模式具明显的变化,而大坪金矿成矿流体的稀土模式则保持相对不变。因此,大坪金矿的稀土模式（轻稀土高度富集、弱负Ｅｕ异常和较强负Ｃｅ异常）可以代表初始成矿流体的稀土模式。研究表明,具有这种稀土模式的流式,可能是由地幔去气作用产生的地幔     

REE Geochemistry of Precambrian Metamorphic Rocks in Wutaishan Region

The metasedimentary-volcanic series of the Wutai and Hutuo groups experienced regional metamorphism and thus turned into moderate-to low-grade metamorphic rocks.REE abundances and REE distribution patterns in the Shizui and Taihuai Subgroup metasedimentary-volcanic rocks are typical of the Archean,whereas the Gaofan Subgroup and the Hutuo Group show post-Archean REE geochemical char-acteristics.Five types of REE distribution pattern are distinguished:(1)rightward inclined smooth curves with little REE anomaly(Eu/Eu*=0.73-0.95) and heavy REE depletion (e.g.the Late Archean metasedimentary rocks);(2)rightward inclined V-shaped curves with sharp Eu anoma-ly (Eu/Eu*=0.48-0.76) and slightly higher ∑REE (e.g.the post-Archean metasedimentary rocks);(3) rightward inclined steep curves with negative Eu anomaly(Eu/Eu*=0.73-0.76) and the lowest ∑REE (e.g.the post-Archean dolomites);(4)rightward inclined,nearly smooth curves with both positive Eu anomaly and unremarkable positive Eu anomaly(Eu/Eu*=0.95-1.25)(e.g.the meta-basic volcanic rocks);and (5) rightward inclined curves with Eu anomaly(Eu/Eu*=1.09-1.19)and heavy REE depletion(e.g.the meta-acid volcanic rocks).Strata of the two groups are considered to have been formed in an island-arc belt-an instable continental petrogenetic environment.     

Petrogenetic significance of rare-earth element behavior in the basement rocks of southern Obudu Plateau, Bamenda Massif, southeastern Nigeria

Rock samples representing various igneous and metamorphic rocks of southern Obudu Plateau were analyzed for rare-earth element ( REE ) behavior by ICP-MS. Results of the analyses indicate a range of REE abundances and distinctive patterns from highly fraetionated patterns with negative Eu anomalies in granitic rocks to relatively low abundances and less REE fractionated flat patterns with little Eu anomaly in some paragneisses, schists, enderbites and dolerites to unfractionated patterns with positive Eu anomalies in some paragneisses and charnockites. Over all, there are low to high ∑ REE contents with negative to positive Eu anomalies. The ratios of different parameters, especially La/Yb and Ce/Yb, show behaviors consistent with crustal to mantle derivation. The heterogeneity of REE abundances and REE patterns reflects mantle to crustal petrogenetic variations of different rock suites on the Plateau. The LREE content is higher than the HREE content in the highly differentiated rocks, as evidenced by their La/Yb,Ce/Yb and La/Sm ratios, which are normally higher in residual products than in primary melts. The dominantly intermediate nature of the source rock of the orthogneisses is suggested by the generally low ∑ REE. The granites enriched in LREE and depleted in HREE and some of the charnockites with negative Eu anomalies were probably formed by partial melting and crystallization.     

新疆金矿火山岩微量及稀土元素地球化学特征

金矿火山岩微量元素以Th和Zr的明显正异常及Nb和Ti的明显负异常为特征。微量元素比值蛛网图模式曲线均呈微向左倾斜的多峰多谷曲线。过渡元素以Cr和Ni的明显负异常及Sc,Co,Cu明显正常为特征。过渡元素球粒陨石标准化曲线，也均呈微向右倾斜的W形曲线。稀土元素以稀土总量偏低，轻稀土富集，重稀土亏损，Eu具微弱异常至微弱正常为特征。稀土元素配分模式均呈微向右倾斜和近于水平的平滑曲线，陆相火山作用两类成矿岩浆建造－陆相火山岩与潜火山杂岩具有基本一致的微量元素和稀土元素地球化学特征。     

内蒙古新巴尔虎右旗地区塔木兰沟组火山岩地球化学特征及其构造意义

新巴尔虎右旗地区塔木兰沟组火山岩为玄武岩-玄武粗安岩-玄武安山岩组合。该套火山岩属高硅钙碱性系列,偏铝质,镁指数小;富集大离子亲石元素(Rb、Ba、Sr)和轻稀土元素(LREE),亏损重稀土元素和高场强元素(Nb、Ta、Ti等),稀土元素配分模式呈左高右低缓倾斜分布,轻重稀土分馏较强,弱的Eu负异常(δEu=0.73~0.83)。综合前人及笔者同位素测年结果显示,塔木兰沟组火山岩形成于中侏罗世末期—晚侏罗世,成岩年龄为166~133 Ma。塔木兰沟组火山岩岩浆来源于受俯冲流体交代的大陆岩石圈地幔熔融,与地壳物质发生混染作用。结合区域构造演化,塔木兰沟组火山岩的形成与蒙古-鄂霍茨克洋闭合造山后岩石圈伸展有关。     

Geochemistry of eclogites from the Dabie–Sulu terrane, eastern China: New insights into protoliths and trace element behaviour during UHP metamorphism

The major and trace element compositions of nine eclogites from the Dabie–Sulu ultrahigh pressure (UHP) metamorphic terrane in eastern China were determined for both whole rock and the main constituent minerals, garnet and clinopyroxene. The results indicate that the eclogite protoliths originated from a basaltic magma, which formed in a continental setting as shown by isotopic and immobile element data. Based on the garnet REE characteristics, the eclogites can be roughly divided into two groups. Group 1 has LREE enrichment with no Eu anomaly for whole rock, and smooth LREE depletion but HREE enrichment pattern for garnet, whereas group 2 shows a depletion of LREE with a pronounced positive Eu anomaly and flat HREE pattern for both whole rock and garnet. From these features, we suggest that the protoliths for group 2 are Fe–Ti–gabbros with relatively high cumulus plagioclase and Fe–Ti oxide, whereas the group 1 eclogites are probably from basalts. Therefore, the unusual garnet REE pattern observed in group 2 can be considered as an important signature for identifying gabbro protoliths for eclogites. The identification of gabbro protoliths from the eclogites in the Dabie–Sulu terrane provides evidence for Neoproterozoic rift magmatism in the northern margin of the Yangtze craton. During ultrahigh pressure metamorphism in the Dabie–Sulu terrane, LILEs (including Ba, Rb, Th, U, K) had high mobility, but REEs and HFSEs were immobile, and trace element distribution equilibrium was approached between garnet and clinopyroxene. An estimate of mass balance indicates that garnet and clinopyroxene host the majority of HREEs and Y, and clinopyroxene is a significant host for Sr, but minor and accessory minerals predominantly account for LREEs, Th, U, and Zr.     

REE and Trace Element Geochemistry of Yinachang Fe-Cu-REE Deposit, Yunnan Province, China

1IntroductionThebehaviorsoftherare earthelements (REE)duringmagmatism ,metamorphismandmeta somationareofgreatgeologicalinterestbecauseoftheirapplicationsingeochronologyandgeochemi caltracing (e .g .reviewsbyFaure ,1 986;LipinandMckay ,1 989) .Becauseoftheirsimilargeo chemicalbehaviorsandlowsolubilitiesinwater,theREEshaveprovedthemselvestobeapowerfultoolforthecharacterizationofprovenanceswhenappliedtosedimentaryrocks (McDanieletal.,1 994) .Althoughtheirbehaviorsunderhydrothermalconditionsar…