Hydrochemical facies of groundwater in the Gaza Strip,Palestine / Faciès hydrochimiques de l’eau souterraine dans la Bande de Gaza,Palestine

Abstract

Abstract Groundwater in the Gaza Strip is the only source of water for domestic, agricultural and industrial uses. Extensive pumping has caused serious quantitative and qualitative problems in the aquifer. The hydrochemical facies are evaluated using the trilinear diagram for 200 water samples. Groundwater in the north and west is mostly characterized by Ca-Mg-HCO₃ facies (alkaline water), and in the south and east by Na-Cl-SO₄ facies (saline water). Sand dunes and rainfall are the major factors controlling the distribution of hydrochemical facies. The eastern edge of the sand dune belt is considered the barrier that separates the two major facies. Brackish water flowing from the east is mixed with rainwater which infiltrates through the sand dunes to the aquifer. Other factors, e.g. seawater intrusion and extensive pumping, play a minor role in the distribution of the hydrochemical facies.     

Numerical groundwater modelling as an effective tool for management of water resources in arid areas

Abstract

Groundwater, possibly of fossil origin, is used for water supply in some arid regions where the replenishment of groundwater by precipitation is low. Numerical modelling is a helpful tool in the assessment of groundwater resources and analysis of future exploitation scenarios. To quantify the groundwater resources of the East Owienat area in the southwest of the Western Desert, Egypt, the present study assesses the groundwater resources management of the Nubian aquifer. Groundwater withdrawals have increased in this area, resulting in a disturbance of the aquifer’s natural equilibrium, and the large-scale and ongoing depletion of this critical water reserve. Negative impacts, such as a decline in water levels and increase in salinity, have been experienced. The methodology includes application of numerical groundwater modelling in steady and transient states under different measured and abstraction scenarios. The numerical simulation model developed was applied to assess the responses of the Nubian aquifer water level under different pumping scenarios during the next 30 years. Groundwater management scenarios are evaluated to find an optimal management solution to satisfy future needs. Based on analysis of three different development schemes that were formulated to predict the future response of the aquifer under long-term water stress, a gradual increase in groundwater pumping to 150% of present levels should be adopted for protection and better management of the aquifer. Similar techniques could be used to improve groundwater management in other parts of the country, as well as other similar arid regions.

Editor D. Koutsoyiannis; Associate editor X. Chen     

Sustainable groundwater management of the stressed Coastal aquifer in the Gaza region

Abstract

This study proposes an empirical approach that can lead to the sustainable management of groundwater resources. This approach enables a comprehensive understanding of an aquifer, delineates distinct hydrological scenarios, and recommends a set of operational activities for each sub-region of the aquifer. The paper focuses on the Coastal aquifer of the Gaza Strip region which has been divided into three sub-regions. The southern sub-region (WSW) is classified as scenario “+a2”, which indicates that it can be used as a multi-annual groundwater reservoir. The northern sub-region (NW-E) is designated scenario “-a2”, where the recommended operational measures include injection of freshwater in wells and cleaning of the surface environment. The third sub-region (CSE), is classified as scenario “-b2”, which requires severe management measures to correct both a negative hydrological and environmental situation. The approach also involves on-going monitoring of the aquifer, and can be considered as an empirical tool to provide preliminary guidelines for long-term groundwater management.     

Asymmetric abstraction and allocation: the Israeli-Palestinian water pumping record

The increased attention given to international transboundary aquifers may be nowhere more pressing than on the western bank of the Jordan River. Hydropolitical analysis of six decades of Israeli and Palestinian pumping records reveals how ground water abstraction rates are as asymmetrical as are water allocations. The particular hydrogeology of the region, notably the variability in depth to ground water, variations in ground water quality, and the vulnerability of the aquifer, also affect the outcome. The records confirm previously drawn conclusions of the influence of the agricultural lobby in maintaining a supply-side water management paradigm. Comparison of water consumption rates divulges that water consumed by all sectors of the farming-based Palestinian economy is less than half of Israeli domestic consumption. The overwhelming majority of "reserve" flows from wet years are sold at subsidized rates to the Israeli agricultural sector, while very minor amounts are sold at normal rates to the Palestinian side for drinking water. An apparent coevolution of water resource variability and politics serves to explain increased Israeli pumping prior to negotiations in the early 1990s. The abstraction record from the Western Aquifer Basin discloses that the effective limit set by the terms of the 1995 Oslo II Agreement is regularly violated by the Israeli side, thereby putting the aquifer at risk. The picture that emerges is one of a transboundary water regime that is much more exploitative than cooperative and that risks spoiling the resource as it poisons international relations.     

Development of saline ground water through transpiration of sea water

As vegetation usually excludes salt during water uptake, transpiration will increase the salinity of the residual water. If the source water is sea water, then the residual water may become highly saline. In the unconfined coastal aquifer of the tropical Burdekin River delta, northeastern Australia, areas of highly saline ground water with chloride concentrations up to almost three times that of sea water occur up to 15 km from the present coastline, and are attributed to transpiration by mangrove vegetation during periods of high sea level. Radiogenic ((14)C) carbon isotope analyses indicate that ground water with chloride concentrations between 15,000 and 35,000 mg/L is mostly between 4000 and 6000 years old, at which time sea level was 2 to 3 m higher than present. Stable isotope analyses of oxygen-18 and deuterium show no evidence for evaporative enrichment of this water. Oxygen-18, deuterium, and stable (delta(13)C) carbon isotope analyses of ground water and soil water point to a recharge environment beneath the mangrove forests during this postglacial sea level high stand. During that period, transpiration of the mangrove forests would have led to high chloride concentrations in the residual ground water, without inducing isotopic fractionation. Due to the higher density, this hypersaline water moved downward through the aquifer by gravity and has formed lenses of highly saline ground water at the bottom of the unconfined aquifer.     

Optimal and sustainable extraction of groundwater in coastal aquifers

Four examples are investigated for the optimal and sustainable extraction of groundwater from a coastal aquifer under the threat of seawater intrusion. The objectives and constraints of these management scenarios include maximizing the total volume of water pumped, maximizing the profit of selling water, minimizing the operational and water treatment costs, minimizing the salt concentration of the pumped water, and controlling the drawdown limits. The physical model is based on the density-dependent advective-dispersive solute transport model. Genetic algorithm is used as the optimization tool. The models are tested on a hypothetical confined aquifer with four pumping wells located at various depths. These solutions establish the feasibility of simulating various management scenarios under complex three-dimensional flow and transport processes in coastal aquifers for the optimal and sustainable use of groundwater.     

Coastal aquifer response to extreme storm events in Emilia‐Romagna,Italy

With global warming and sea level rise, many coastal systems will experience increased levels of inundation and storm flooding, especially along sandy lowland coastal areas, such as the Northern Adriatic coast (Italy). Understanding how extreme events may directly affect groundwater hydrology in shallow unconfined coastal aquifers is important to assess coastal vulnerability and quantify freshwater resources. This study investigates shallow coastal aquifer response to storm events. The transitory and permanent effects of storm waves are evaluated through the real time monitoring of groundwater and soil parameters, in order to characterize both the saturated and unsaturated portions of the coastal aquifer of Ravenna and Ferrara (southern Po Delta, Italy). Results highlight a general increase in hydraulic head and soil moisture, along with a decrease in groundwater salinity and pore water salinity due to rainfall infiltration during the 2 days storm event. The only exceptions are represented by the observation wells in proximity to the coastline (within 100 m), which recorded a temporary increase in soil and water salinity caused by the exceptional high waves, which persist on top of the dune crest during the storm event. This generates a saline plume that infiltrates through the vadose zone down to the saturated portion of the aquifer causing a temporary disappearance of the freshwater lens generally present, although limited in size, below the coastal dunes. Despite the high hydraulic conductivity, the aquifer system does not quickly recover the pre‐storm equilibrium and the storm effects are evident in groundwater and soil parameters after 10 days past the storm overwash recess.     

Using Alternate Pumping and Cooperative Game Theory to Reduce Sea Water Intrusion

In this article, alternate pumping is studied as a means used to reduce the salinity concentration in coastal aquifers, pumped using a system of wells. This approach has been applied to a hypothetical confined coastal aquifer. Flow has been modeled, using SEAWAT. Two strategies are proposed based on cooperative game theory, to promote alternate pumping. In both strategies an external player will compensate the users that will pump during an unpopular pumping period. In the first strategy it is supposed that this external player aims at protecting a critical well, e.g. a municipal well, reducing its maximum salinity concentration by pumping alternately. In the second strategy proposed, the target is to reduce the overall salinity of the water pumped by the wells. In applying the cooperative game theory, the Shapley value is used to distribute the benefits of cooperation between the players (well users), according to their marginal contribution. Overall, well users can reduce sea water intrusion by cooperatively changing their pumping time schedules. The game theoretical model developed is a useful tool to promote cooperation toward this direction. The methods applied in the hypothetical aquifer, can be tested in actual aquifers to reduce sea water intrusion.     

A simple method for locating the fresh water-salt water interface using pressure data

Salt water intrusion is a key issue in dealing with exploitation, restoration, and management of fresh ground water in coastal aquifers. Constant monitoring of the fresh water-salt water interface is necessary for proper management of ground water resources. This study presents a simple method to estimate the depth of the fresh water-salt water interface in coastal aquifers using two sets of pressure data obtained from the fresh and saline zones within a single borehole. This method uses the density difference between fresh water and saline water and can practically be used at coastal aquifers that have a relatively sharp fresh water-salt water interface with a thin transition zone. The proposed method was applied to data collected from a coastal aquifer on Jeju Island, Korea, to estimate the variations in the depth of the interface. The interface varied with daily tidal fluctuations and heavy rainfall in the rainy season. The estimated depth of the interface showed a good agreement with the measured electrical conductivity profile.     

Approximate analysis of upconing

The change of the salinity distribution in coastal aquifers due to pumpage is often described as an upconing of the interface between saline and fresh water. Sea and fresh water are miscible fluids, however. Therefore, dispersion of salinity in the aquifer affects the upconing process. An estimate of the effect of salinity dispersion on the dynamics of the flow as well as on the salinity distribution in the aquifer is presented in this study. The phenomenon is described as a migration of a sharp interface perturbed by small disturbances due to salinity dispersion. The creation of the mixing zone between fresh and saline water is described as a formation of a boundary layer in the vicinity of the sharp interface. This method is primarily recommended for flow fields in which simple representation of the sharp interface migration is obtainable.     

Predicting conductance due to upconing using neural networks

Artificial neural networks (ANNs) were developed to accurately predict highly time-variable specific conductance values in an unconfined coastal aquifer. Conductance values in the fresh water lens aquifer change in response to vertical displacements of the brackish zone and fresh water-salt water interface, which are caused by variable pumping and climate conditions. Unlike physical-based models, which require hydrologic parameter inputs, such as horizontal and vertical hydraulic conductivities, porosity, and fluid densities, ANNs can "learn" system behavior from easily measurable variables. In this study, the ANN input predictor variables were initial conductance, total precipitation, mean daily temperature, and total pumping extraction. The ANNs were used to predict salinity (specific conductance) at a single monitoring well located near a high-capacity municipal-supply well over time periods ranging from 30 d to several years. Model accuracy was compared against both measured/interpolated values and predictions were made with linear regression, and in general, excellent prediction accuracy was achieved. For example, although the average percent change of conductance over 90-d periods was 39%, the absolute mean prediction error achieved with the ANN was only 1.1%. The ANNs were also used to conduct a sensitivity analysis that quantified the importance of each of the four predictor variables on final conductance values, providing valuable insights into the dynamics of the system. The results demonstrate that the ANN technology can serve as a powerful and accurate prediction and management tool, minimizing degradation of ground water quality to the extent possible by identifying appropriate pumping policies under variable and/or changing climate conditions.     

Coupled flow and salinity transport modelling in semi-arid environments: The Shashe River Valley,Botswana

Numerical groundwater modelling is used as the base for sound aquifer system analysis and water resources assessment. In many cases, particularly in semi-arid and arid regions, groundwater flow is intricately linked to salinity transport. A case in point is the Shashe River Valley in Botswana. A freshwater aquifer located around an ephemeral stream is depleted by the combined effect of transpiration and pumping. Quantitative system analysis reveals that the amount of water taken by transpiration is far more than the quantities pumped for water supply. Furthermore, the salinity distribution in and around Shashe River Valley as well as its temporal dynamics can be satisfactorily reproduced if the transpiration is modelled as a function of groundwater salinity. The location and dynamics of the saltwater–freshwater interface are highly sensitive to the parameterization of evaporative and transpirative salt enrichment. An existing numerical code for coupled flow/transport simulations (SEAWAT) was adapted to this situation. Model results were checked against a large set of field data including water levels, water chemistry, isotope data and ground and airborne geophysical data. The resulting groundwater model was able to reproduce the long-term development of the freshwater lens located in Shashe River Valley as well as the decline in piezometric heads observed over the last decade. Furthermore, the old age of the saline water surrounding the central freshwater lens could be explained.     

Ground water discharge and nitrate flux to the Gulf of Mexico

Ground water samples (37 to 186 m depth) from Baldwin County, Alabama, are used to define the hydrogeology of Gulf coastal aquifers and calculate the subsurface discharge of nutrients to the Gulf of Mexico. The ground water flow and nitrate flux have been determined by linking ground water concentrations to 3H/3He and 4He age dates. The middle aquifer (A2) is an active flow system characterized by postnuclear tritium levels, moderate vertical velocities, and high nitrate concentrations. Ground water discharge could be an unaccounted source for nutrients in the coastal oceans. The aquifers annually discharge 1.1 +/- 0.01 x 10(8) moles of nitrate to the Gulf of Mexico, or 50% and 0.8% of the annual contributions from the Mobile-Alabama River System and the Mississippi River System, respectively. In southern Baldwin County, south of Loxley, increasing reliance on ground water in the deeper A3 aquifer requires accurate estimates of safe ground water withdrawal. This aquifer, partially confined by Pliocene clay above and Pensacola Clay below, is tritium dead and contains elevated 4He concentrations with no nitrate and estimated ground water ages from 100 to 7000 years. The isotopic composition and concentration of natural gas diffusing from the Pensacola Clay into the A3 aquifer aids in defining the deep ground water discharge. The highest 4He and CH4 concentrations are found only in the deepest sample (Gulf State Park), indicating that ground water flow into the Gulf of Mexico suppresses the natural gas plume. Using the shape of the CH4-He plume and the accumulation of 4He rate (2.2 +/- 0.8 microcc/kg/1000 years), we estimate the natural submarine discharge and the replenishment rate for the A3 aquifer.     

Quantifying the impact of urban area expansion on groundwater recharge and surface runoff

ABSTRACT

In this surface water modelling study, a new spatial evaluation for assessing the impact of urbanization was applied for the semi-arid watersheds intersecting with the Gaza coastal aquifer. The SWAT model was calibrated and validated in a semi-automated approach for streamflow in the main watersheds. The results show that the model could simulate water budget components adequately within the complex semi-arid watersheds. Linear relationships between the change in urban area and the corresponding change in surface runoff or percolation were concluded for the urbanized sub-basins. The urban-surface runoff index (USI) and the urban-percolation index (UPI) were developed to represent a micro-level evaluation of different urban change scenarios in the sub-basins. The global urban-surface runoff index (GUSI) and the global urban-percolation index (GUPI) were derived as macro-level factors reflecting the influence on the overall Gaza coastal aquifer due to urban area expansion.

Editor D. Koutsoyiannis Associate editor E. Rozos     

Integrated water resource management in a major canal command in eastern India

The present rice‐dominated cropping system in the Hirakud canal command (eastern India) is under severe threat due to imbalance between irrigation water supply and demand. The canal water supply, which is the only source of irrigation, only meets 54% of the demand at 90% probability of exceedance (PE). In order to mitigate the irrigation water deficit from canal water, groundwater is considered as a supplemental source. Quasi‐three‐dimensional groundwater flow simulation modelling was, therefore, carried out by using Visual MODFLOW to detect the change in hydraulic head due to transient pumping stresses. The simulation model was calibrated and validated satisfactorily. Sensitivity analysis of the model parameters shows that groundwater recharge is most sensitive followed by aquifer hydraulic conductivity at almost all the sites of the command area, whereas the model is comparatively less sensitive to specific storage and specific yield. Enhanced pumping scenarios showed that groundwater extraction can be increased up to 50 times of the existing pumping without causing any adverse effect to the aquifer but the aquifer does not permit to exploit water in order to fulfill the irrigation water demand even at 10% PE. Hence, it is imperative to develop an optimal land and water resources management plan of the command area. Copyright © 2011 John Wiley & Sons, Ltd.     

Concurrent Salinization and Development of Anoxic Conditions in a Confined Aquifer,Southern Israel

An ancient, brackish, anoxic, and relatively hot water body exists within the Yarqon‐Tanninim Aquifer in southern Israel. A hydrogeological‐geochemical conceptual model is presented, whereby the low water quality is the outcome of three conditions that are met simultaneously: (1) Presence of an organic‐rich unit with low permeability that overlies and confines the aquifer; the confining unit contains perched horizons with relatively saline water. (2) Local phreatic/roofed conditions within the aquifer that enable seepage of the organic‐rich brackish water from above. The oxidation of the dissolved organic matter in the seeping water consumes the dissolved oxygen and continues through bacterial sulfate reduction, with H₂S as a product. These exothermic reactions result in some heating. (3) The seeping water comprises a relatively large portion of the water volume. In the presented case study, the latter condition first developed in the Late Pleistocene following climate change, which led to a dramatic decline in recharge. Consequently, water flow in the local basin has nearly ceased, as evident by old water ages, specific isotopic composition, and nearly equipotential water levels. The continuous seepage from above into the almost stagnant water body has resulted in degraded water quality. Seepages of organic‐rich brackish water exist at other sites throughout the aquifer but have limited impact on the salinity and redox conditions due to the dynamic water flow, which flushes the seeping water, that is, the third condition is not met. The coexistence of the above three conditions may explain the development of anoxic and saline groundwater in other aquifers worldwide.     

Formation of a salt plume in the Coastal Plain aquifer of Israel: the Be''er Toviyya region

The formation and development of a salt plume (salinity up to 800 mg Cl 1⁻¹) in the inner part of the Coastal Plain aquifer of Israel is analyzed. Massive groundwater exploitation during the 1950s caused a large drop in the water level and formation of a hydrologic depression in the Be'er Toviyya-Kefar Warburg area. The depression reached a maximal depth during the late 1960s; thereafter a reduction in the rate of pumpage led to restoration of water levels and shallowing of the depression, until its complete disappearance towards the end of the 1980s. A spot of high salinity first appeared in 1956, following a deep drawdown in the water levels. This saline plume has been continuously expanding with increasing salinity concentrations (200–800 mg Cl 1⁻¹) in its center. The average rate of radial expansion was about 50 m year⁻¹. The expansion and salinization did not cease as the depression disappeared. Rather, equalization of water levels in wells situated within the plume area with those of situated along its margins resulted in the salinization of the latter within a period of 1 year.

Mass balances for water and chloride contents were made for the period 1967–1990. Taking into consideration the storage change, pumpage, natural replenishment and artificial recharge, the lateral inflow to the depression is estimated as 60 × 10⁶ m³. Upon addition of the chloride balance, and taking into consideration the chloride concentrations of the surrounding fresh water and the apparent possible end-member of the saline source (based on geochemical considerations), the saline inflow is estimated as (40–60) × 10⁶ m³. These estimates indicate that a large amount of saline water penetrated into the aquifer, of about half of the natural replenishment of the study area, with an estimated salinity of 1900–2700 mg Cl 1⁻¹.

It is suggested that the salt plume was formed as a result of a drop in water level combined with a flow of underlying saline water bodies from deeper strata. The chemical composition of the groundwater points to the existence of two saline water bodies of Ca-chloride composition and a marine Br/Cl ratio: (1) saline water with low Na/Cl (0.6), So₄/Cl, and B/Cl ratio; (2) saline water with higher Na/Cl (> 0.6), So₄/Cl, and B/Cl ratios. These chemical compositions resemble Ca-chloride saline waters found in other locations in the Coastal Plain aquifer and in underlying formations. The saline water bodies may occur in either pockets at the bottom of the aquifer or lumachelle and sandstone layers of high hydraulic conductivity in underlying sediments.     

Sources of salinity in ground water from Jericho area, Jordan Valley

One of the major problems in the lower Jordan Valley is the increasing salinization (i.e., chloride content) of local ground water. The high levels of salinity limit the utilization of ground water for both domestic and agriculture applications. This joint collaborative study evaluates the sources and mechanisms for salinization in the Jericho area. We employ diagnostic geochemical fingerprinting methods to trace the potential sources of the salinity in (1) the deep confined subaquifer system (K2) of Lower Cenomanian age; (2) the upper subaquifer system (K1) of Upper Cenomanian and Turonian ages; and (3) the shallow aquifer system (Q) of Plio-Pleistocene ages. The chemical composition of the saline ground water from the two Cenomanian subaquifers (K1 and K2) point to a single saline source with Na/Cl approximately 0.5 and Br/Cl approximately 7 x 10(-3). This composition is similar to that of thermal hypersaline spring that are found along the western shore of the Dead Sea (e.g., En Gedi thermal spring). We suggest that the increasing salinity in both K1 and K2 subaquifers is derived from mixing with deep-seated brines that flow through the Rift fault system. The salinization rate depends on the discharge volume of the fresh meteoric water in the Cenomanian Aquifer. In contrast, the chemical composition of ground water from the Plio-Pleistocene Aquifer shows a wide range of Cl- (100-2000 mg/L), Na/Cl (0.4-1.0), Br/Cl (2-6 x 10(-3)), and SO4/Cl (0.01-0.4) ratios. These variations, together with the high SO4(2-), K+, and NO3- concentrations, suggest that the salinity in the shallow aquifer is derived from the combination of (1) upconing of deep brines as reflected by low Na/Cl and high Br/Cl ratios; (2) leaching of salts from the Lisan Formation within the Plio-Pleistocene Aquifer, as suggested by the high SO4(2-) concentrations; and (3) anthropogenic contamination of agriculture return flow and sewage effluents with distinctive high K+ (80 mg/L) and NO3- (80 mg/l) contents and low Br/Cl ratios (2 x 10(-3)). Our data demonstrates that the chemical composition of salinized ground water can be used to delineate the sources of salinity and hence to establish the conceptual model for explaining salinization processes.     

Monitoring strategies at phreatic wellfields: a 3D travel time approach

Ground water quality networks for monitoring phreatic drinking water wellfields are generally established for two main purposes: (1) the short-term safeguarding of public water supply and (2) signaling and predicting future quality changes in the extracted ground water. Six monitoring configurations with different well locations and different screen depths and lengths were evaluated using a numerical model of the 3D ground water flow toward a partially penetrating pumping well in a phreatic aquifer. Travel times and breakthrough curves for observation and pumping wells were used to judge the effectiveness of different design configurations for three monitoring objectives: (1) early warning; (2) prediction of future quality changes; and (3) evaluation of protection measures inside a protection zone. Effectiveness was tested for scenarios with advective transport, first-order degradation, and linear sorption. It is shown that the location and especially the depth of the observation wells should be carefully chosen, taking into account the residence time from the surface to the observation well, the residual transit times to the extraction well, and the transformation and retardation rates. Shallow monitoring was most functional for a variety of objectives and conditions. The larger the degradation rates or retardation, the shallower should the monitoring be for effective early warning and prediction of future ground water quality. The general approach followed in the current study is applicable for many geohydrological situations, tuning specific monitoring objectives with residence times and residual transit times obtained from a site-specific ground water flow model.     

Application of international law of water quality to recent Middle East water agreements

This paper examines the fit between water and environmental quality issues as articulated in the Law of the Non-navigational Uses of International Watercourses approved by the United Nations General Assembly in 1997 and the water provisions that were included in the Israel–Jordan Treaty of 1994 and the Israel–Palestinian Authority Accord of 1995. It also examines the differences and commonalities of the two agreements with regard to these issues and examines the process of implementation to date.