Delayed geochemical hazard: Concept, digital model and case study

Delayed Geochemical Hazard (DGH briefly) presents the whole process of a kind of serious ecological and environmental hazard caused by sudden reactivation and sharp release of long-term accumulated pollutant from stable species to active ones in soil or sediment system due to the change of physical-chemical conditions (such as temperature, pH, Eh, moisture, the concentrations of organic matters, etc.) or the decrease of environment capacity. The characteristics of DGH are discussed. The process of a typical DGH can be expressed as a nonlinear polynomial. The points where the derivative functions of the first and second orders of the polynomial reach zero, minimum and maximum are keys for risk assessment and harzard pridication.The process and mechanism of the hazard is due to the transform of pollutant among different species principally. The concepts of "total releasable content of pollutant", TRCP, and "total concentration of active specie", TCAS, are necessarily defined to describe the mechanism of DGH. The possibility of the temporal and spatial propagation is discussed. Case study shows that there exists a transform mechanism of "gradual release" and "chain reaction" among the species of the exchangeable and the bounds to carbonate, iron and manganese oxides and organic matter, thus causing the delayed geochemical hazard.     

New concepts in ecological risk assessment: where do we go from here?

Through the use of safety factors, the use of single-species test data has been adequate for use in protective hazard assessments and criteria setting but, because hazard quotients do not consider the presence of multiple species each with a particular sensitivity or the interactions that can occur between these species in a functioning community, they are ill-suited to environmental risk assessment. Significant functional redundancy occurs in most ecosystems but this is poorly considered in single-species tests conducted under laboratory conditions. A significant advance in effects assessment was the use of the microcosm as a unit within which to test interacting populations of organisms. The microcosm has allowed the measurement of the environmental effect measures such as the NOAEC(community) under laboratory or field conditions and the application of this and other similarly derived measures to ecological risk assessment (ERA). More recently, distributions of single-species laboratory test data have been used for criteria setting and, combined with distributions of exposure concentrations, for risk assessment. Distributions of species sensitivity values have been used in an a priori way for setting environmental quality criteria such as the final acute value (FAV) derived for water quality criteria. Similar distributional approaches have been combined with modeled or measured concentrations to produce estimates of the joint probability of a single species being affected or that a proportion of organisms in a community will be impacted in a posteriori risk assessments. These techniques have not been widely applied for risk assessment of dredged materials, however, with appropriate consideration of bioavailability and spatial and nature of the data these techniques can be applied to soils and sediments.     

Water-Management and Environmental Problems of the Lower Volga and Ways to Their Solution

The key water-management and environmental problems of the Lower Volga are considered. The items discussed include the characteristics of intake and utilization of water resources and wastewater discharges in Lower Volga Region from 1990 to 2013. The current state of the key participants of water management complex is analyzed. The quality of Lower Volga water and ecosystems is shown, and the problems of maintaining the biodiversity are discussed. The key regional programs pertaining to the rational use and protection of water resources, as well as the development of water-management complex are considered.     

Environmental corrections to gamma-ray log data: Strategies for geophysical logging with geological and technical drilling

Correction concepts for the elimination of environmental influences on gamma-ray logs have been published in a number of articles and in guidelines by service companies. However, these widely-used processing rules for open- and cased-hole measurement conditions have been presented in different forms using different assumptions. For a detailed comparison, these concepts were reduced to simple analytical formula with the application of the same units and scaling to common, standardised conditions. For geological and technical drilling, environmental influences like borehole geometry, casing configuration and material, as well as mud density have turned out to represent the most important effects for a characterisation of environmental conditions. Typical case histories show that correction processing may lead to differing results, depending on the chosen presumptions. A thorough analysis of different types of influences and a careful choice of adequate correction procedures substantially improve the quality of gamma-ray log data. Further implications of these analytical correction rules permit also the quantitative interpretation of logs in dry cased-hole intervals and with the presence of tool joints or casing collars. The latter effect is widely underrated but is proven here to be a necessary step in precise gamma-ray log processing.     

太湖流域水环境变化及缘由分析

太湖水环境质量在最近的十年中下降1－2个等级,1990年86．5％的水体为Ⅱ、Ⅲ类,到2000年太湖水体87％Ⅳ类;1990年太湖水体为中－富营养化,2000年太湖水体以富营养化为主,本文通过分析经济社会发展和水环境变化,认为太湖流域工业化与城市化及居民生活水平的提高,吧及不合理的农业生产方式,使水环境面临巨大的压力,环保意识落后、治理能力不足、管理体制不合理是太湖目前水环境恶化的根本原因。     

Direct and Inverse Problems in a Variational Concept of Environmental Modeling

A concept of environmental forecasting based on a variational approach is discussed. The basic idea is to augment the existing technology of modeling by a combination of direct and inverse methods. By this means, the scope of environmental studies can be substantially enlarged. In the concept, mathematical models of processes and observation data subject to some uncertainties are considered. The modeling system is derived from a specially formulated weak-constraint variational principle. A set of algorithms for implementing the concept is presented. These are: algorithms for the solution of direct, adjoint, and inverse problems; adjoint sensitivity algorithms; data assimilation procedures; etc. Methods of quantitative estimations of uncertainty are of particular interest since uncertainty functions play a fundamental role for data assimilation, assessment of model quality, and inverse problem solving. A scenario approach is an essential part of the concept. Some methods of orthogonal decomposition of multi-dimensional phase spaces are used to reconstruct the hydrodynamic background fields from available data and to include climatic data into long-term prognostic scenarios. Subspaces with informative bases are constructed to use in deterministic or stochastic-deterministic scenarios for forecasting air quality and risk assessment. The results of implementing example scenarios for the Siberian regions are presented.     

固城湖冬季生物资源现状及环境质量与资源利用评价

根据1999年冬季对固城湖生物资源现状的调查,分析了固城湖冬季生物资源的群落组成和结构特征,探讨了固城湖水质的演变趋势和湖泊供养殖能力.结果表明,固城湖水质虽达到国家Ⅲ类饮用水标准,但固城湖水质已呈现明显的富营养化趋势.当前固城湖可自然提供的渔产潜力约为81.4×104kg.为保障固城湖渔业生产和水资源质量,应做好水生植物资源改良和保护,调整湖泊渔业结构.     

Environmental capacity of nitrogen and phosphorus pollutions in Jiaozhou Bay, China: modeling and assessing

In recent years, with the development of society and economy of Qingdao, environment and ecosystem problems, for instance, red ties, become more and more serious in Jiaozhou Bay, China, because of the increasing pollutants discharged into it. In order to solve these problems, an eco-hydrodynamic model is constructed to estimate the marine environmental capacity of nitrogen and phosphorus nutrients in Jiaozhou Bay, whose simulation results are rational for the bay. According to the model, if the target is set to achieve water quality (grade II) in Jiaozhou Bay, the environmental capacity of dissolved inorganic nitrogen and phosphorus in one year are approximately 7800 and 840 tons, respectively. Thus our research offers necessary scientific foundation to the total loads control efforts in this area.     

On the Problem of Differential Payment for the Use of Different-Quality Surface Waters in Ukraine

The evolution of views and practical decisions regarding the problem of collecting payment for the use of surface waters with regard to their quality in the former USSR and present-day Ukraine is discussed. A simple and feasible method is proposed for differentitation of regional (basin) rates of payment for the use of surface water in Ukraine with allowance made for its quality assessed based on a system of environmental classifications.     

Qualitätsanforderungen an Oberflächengewässer: Zielvorgaben,Qualitätsziele und chemische Gewässergüteklassifizierung

Quality Requirements for Fresh Waters: Water Quality Targets, Water Quality Objectives, and Chemical Water Quality Classification In the Federal Republic of Germany, water quality requirements for the protection of inland surface waters against hazardous substances are formulated on the basis of a quality targets derivation concept developed jointly by the Federal Government and the Federal States. The quality requirements were termed “water quality targets” in order to make it clear that the values derived are orientational values rather than legally binding limit values. The international comparison of quality requirements for surface waters shows that, on the whole, the national quality targets ensure a high level of protection. According to present scientific knowledge, impairments of uses, such as supply of drinking water, or risks to aquatic communities need not to be expected if the quality targets are complied with. A comparison of water quality data with the water quality targets makes it possible, on the one hand, to identify those substances whose inputs must be further reduced; on the other hand, it also shows that, for a number of substances, there is no need at present for concern over their adversely water quality. A further differentiation of the aquatic hazard potential of pollutants allows a water quality classification system to be developed on the basis of the quality targets derivation concept. The basic elements of this water quality classification system are presented, and its application is explained by way of examples.     

Environmental capacity of nitrogen and phosphorus pollutions in Jiaozhou Bay,China: Modeling and assessing

In recent years, with the development of society and economy of Qingdao, environment and ecosystem problems, for instance, red ties, become more and more serious in Jiaozhou Bay, China, because of the increasing pollutants discharged into it. In order to solve these problems, an eco-hydrodynamic model is constructed to estimate the marine environmental capacity of nitrogen and phosphorus nutrients in Jiaozhou Bay, whose simulation results are rational for the bay. According to the model, if the target is set to achieve water quality (grade II) in Jiaozhou Bay, the environmental capacity of dissolved inorganic nitrogen and phosphorus in one year are approximately 7800 and 840 tons, respectively. Thus our research offers necessary scientific foundation to the total loads control efforts in this area.     

天然胶体的水环境行为

胶体是一种分散相粒子具有特定粒径(通常为1 nm~1μm)的混合物,天然水体中的胶体通常是指水环境中普遍存在,而又符合“胶体”形态定义的物质的总和.因为具有特殊的表面性质以及独特的水动力学特点,天然水体中的胶体被认为是一种重要的污染物载体,尤其在促进重金属类的污染物迁移以及性质转化的过程中具有重要作用.本文归纳总结了水环境研究领域中胶体概念的提出与发展,讨论了现有研究中对胶体的定义与理解,比较了当前几种主要的胶体提取手段的特点.同时,针对胶体在水环境中的环境行为,详细归纳了河湖水体中胶体的物质组成、特征以及相应的检测手段,重点总结了胶体在水环境中对污染物的结合作用、胶体污染物的生物效应、胶体自身的团聚规律以及胶体对污染物迁移的影响机制.本文提出了胶体在水环境中复杂的组成成分与动态变化在胶体研究中的重要性,并对进一步揭示胶体环境效应的研究思路以及方法手段进行了展望.     

Compartmentalisation and groundwater–surface water interactions in a prospective shale gas basin: Assessment using variance analysis and multivariate statistics on water quality data

An environmental concern with hydraulic fracturing for shale gas is the risk of groundwater and surface water contamination. Assessing this risk partly involves the identification and understanding of groundwater–surface water interactions because potentially contaminating fluids could move from one water body to the other along hydraulic pathways. In this study, we use water quality data from a prospective shale gas basin to determine: if surface water sampling could identify groundwater compartmentalisation by low-permeability faults; and if surface waters interact with groundwater in underlying bedrock formations, thereby indicating hydraulic pathways. Variance analysis showed that bedrock geology was a significant factor influencing surface water quality, indicating regional-scale groundwater–surface water interactions despite the presence of an overlying region-wide layer of superficial deposits averaging 30–40 m thickness. We propose that surface waters interact with a weathered bedrock layer through the complex distribution of glaciofluvial sands and gravels. Principal component analysis showed that surface water compositions were constrained within groundwater end-member compositions. Surface water quality data showed no relationship with groundwater compartmentalisation known to be caused by a major basin fault. Therefore, there was no chemical evidence to suggest that deeper groundwater in this particular area of the prospective basin was reaching the surface in response to compartmentalisation. Consequently, in this case compartmentalisation does not appear to increase the risk of fracking-related contaminants reaching surface waters, although this may differ under different hydrogeological scenarios.     

Probabilistic assessment of aggregate risk for bisphenol A by integrating the currently available environmental data

Bisphenol A (BPA) is an endocrine disruptor widely used in the production of polycarbonate plastics and epoxy resins. Exposures to BPA have been associated with reproductive, developmental, and cardiovascular effects. In this study, the CalTOX model was used to assess the aggregate health risks on BPA by integrating the currently available BPA data in various environmental media in Taiwan. Local parameters such as chemical properties, local landscape data, and exposure factors were used as model inputs under the continuous source mode. A reference dose (RfD) of 50 μg/kg-day was adopted in this assessment. Monte Carlo simulation was used to simulate great variability of the environmental data. Our results show that an upper limit of 95 % confidence interval of aggregate exposures for the adults (19–64 years old) was 1.05 μg/kg-day, corresponding to a hazard index (HI) of 0.021. The chemical properties (BPA half-life in surface water), intake rates (fruit, vegetable, and fluid intake), and landscape data (average depth of surface waters and leaf wet density) are critical parameters. Finally, HI value would approach to 1 as BPA concentrations in ambient air, surface water, and sediment was greater than 20 ng/m³, 100 μg/L, and 3.3 mg/kg. The quality of the risk assessment on BPA can be further improved by reduction of uncertainty of the abovementioned critical parameters as well as considering additional BPA exposures from canned and packaged goods.     

Comparison of environmental tracers including organic micropollutants as groundwater exfiltration indicators into a small river of a karstic catchment

Understanding groundwater–surface water (GW–SW) interactions is vital for water management in karstic catchments due to its impact on water quality. The objective of this study was to evaluate and compare the applicability of seven environmental tracers to quantify and localize groundwater exfiltration into a small, human-impacted karstic river system. Tracers were selected based on their emission source to the surface water either as (a) dissolved, predominantly geogenic compounds (radon-222, sulphate and electrical conductivity) or (b) anthropogenic compounds (predominantly) originating from wastewater treatment plant (WWTP) effluents (carbamazepine, tramadol, sodium, chloride). Two contrasting sampling approaches were compared (a) assuming steady-state flow conditions and (b) considering the travel time of the water parcels (Lagrangian sampling) through the catchment to account for diurnal changes in inflow from the WWTP. Spatial variability of the concentrations of all tracers indicated sections of preferential groundwater inflow. Lagrangian sampling techniques seem highly relevant for capturing dynamic concentration patterns of WWTP-derived compounds. Quantification of GW inflow with the finite element model FINIFLUX, based on observed in-stream Rn activities led to plausible fluxes along the investigated river reaches (0.265 m³ s⁻¹), while observations of other natural or anthropogenic environmental tracers produced less plausible water fluxes. Important point sources of groundwater exfiltration can be ascribed to locations where the river crosses geological fault lines. This indicates that commonly applied concepts describing groundwater–surface water interactions assuming diffuse flow in porous media are difficult to transfer to karstic river systems whereas concepts from fractured aquifers may be more applicable. In general, this study helps selecting the best suited hydrological tracer for GW exfiltration and leads to a better understanding of processes controlling groundwater inflow into karstic river systems.     

Environmental flow requirements assessment in the Halda River,Bangladesh

Abstract

Environmental flows have scarcely been considered in river water management in Bangladesh. This study attempts to assess the environmental flow requirements in the Halda River, Bangladesh. Thus, the objectives are to estimate the Halda River flow with different return periods/probabilities, which was done using the log-Pearson Type III distribution (LPIII), and to mitigate the environmental problems in the Halda River using the building block method. The LPIII distribution was used to estimate the expected extreme and satisfactory flows for fish habitat at Panchpukuria station and the expected extreme water levels at Panchpukuria, Narayanhat, Telpari and Enayethat stations. It was found that floods are likely to occur at least once in 2.1, 1.02, 1.75 and 1.25 years at Panchpukuria, Narayanhat, Telpari and Enayethat stations, respectively. The results of flow and water quality analyses suggest that environmental flow requirements cannot be achieved in this river throughout the year. The environmental flow requirements and conservation of fish resources can be achieved by implementing the suggestions provided in conjunction with a comprehensive awareness programme, investigations and trade-off analyses being among the suggestions.

Editor Z.W. Kundzewicz; Associate editor B. Sivakumar

Citation Akter, A. and Ali, Md. H., 2012. Environmental flow requirements assessment in the Halda River, Bangladesh. Hydrological Sciences Journal, 57 (2), 326–343.     

New methodology for urban seismic risk assessment from a holistic perspective

The seismic risk evaluation usually works with a fragmented concept of risk, which depends on the scientific discipline in charge of the assessment. To achieve an effective performance of the risk management, it is necessary to define risk as the potential economic, social and environmental consequences due to a hazardous phenomenon in a period of time. This article presents a methodology which evaluates the seismic risk from a holistic perspective, which means, it takes into account the expected physical damage and also the conditions related to social fragility and lack of resilience, which favour the second order effects when a hazard event strikes an urban centre. This seeks to obtain results which are useful in the decision making process for risk reduction. The proposed method for urban seismic risk evaluation uses the fuzzy sets theory in order to handle qualitative concepts and variables involved in the assessment, the physical risk level and aggravation level, related to the social fragility and the lack of resilience, are evaluated and finally a total risk level is determinate.     

Tannery Effluents: Current Practices,Environmental Consequences,Human Health Risks,and Treatment Options

The tannery industry influences the gross domestic product/economic activity of any country, but the uncontrolled release of tannery effluents causes environmental degradation and increases health risks to human. The reason for the toxicity of tannery effluents is the presence of high concentrations of organic and inorganic chemicals used in the production of leather goods. Untreated or partially treated effluents discharged into surface water results in an increase in both chemical and biological oxygen demand as well as in an increase in the levels of total suspended solids, dissolved solids, and toxic metals in environmental bodies, especially in soil, water bodies, and water sediments. Various treatment techniques, such as physicochemical, biological, and advanced oxidation methods, which include chemical precipitation, electrocoagulation, aerobic or anaerobic treatment, wetland construction, and Fenton, electro-Fenton, and photo-Fenton processes are also described. This review also discusses the technical appropriateness and economic feasibility of reducing the effluent pollution load and solid waste emanating from the tannery industry. Considering the enhanced health risks in the tannery waste treatment and management regime, some green and advanced technologies should be explored. A sustainable green technology that avoids the use of toxic chemicals in the tanning process is seen well for ecological health.     

Engineering-geological substantiation of water resource protection in the zones of oil and gas fields

The hydrochemical background and the specific features of pollution of geological environmental components by hydrocarbons and chemical components in the industrial sites of oil and gas fields is characterized for two types of natural-anthropogenic environments with different hydrogeological conditions. A methodology is proposed for comprehensive environmental-hydrogeological studies for the development of information support for the assessment of the hazard and risk for the environmental conditions, organization of complex environmental monitoring, and projecting of measures for protection of water resources.     

Seismic Hazard Assessment: Issues and Alternatives

Seismic hazard and risk are two very important concepts in engineering design and other policy considerations. Although seismic hazard and risk have often been used interchangeably, they are fundamentally different. Furthermore, seismic risk is more important in engineering design and other policy considerations. Seismic hazard assessment is an effort by earth scientists to quantify seismic hazard and its associated uncertainty in time and space and to provide seismic hazard estimates for seismic risk assessment and other applications. Although seismic hazard assessment is more a scientific issue, it deserves special attention because of its significant implication to society. Two approaches, probabilistic seismic hazard analysis (PSHA) and deterministic seismic hazard analysis (DSHA), are commonly used for seismic hazard assessment. Although PSHA has been proclaimed as the best approach for seismic hazard assessment, it is scientifically flawed (i.e., the physics and mathematics that PSHA is based on are not valid). Use of PSHA could lead to either unsafe or overly conservative engineering design or public policy, each of which has dire consequences to society. On the other hand, DSHA is a viable approach for seismic hazard assessment even though it has been labeled as unreliable. The biggest drawback of DSHA is that the temporal characteristics (i.e., earthquake frequency of occurrence and the associated uncertainty) are often neglected. An alternative, seismic hazard analysis (SHA), utilizes earthquake science and statistics directly and provides a seismic hazard estimate that can be readily used for seismic risk assessment and other applications.