基于氢氧同位素与水化学的潮白河流域地下水水循环特征

为了研究变化环境下潮白河流域地下水水循环规律,通过现场调查,结合环境同位素及水化学应用,对潮白河流域浅层和深层地下水采样,测定其氢、氧环境同位素及水化学成分,通过分析其变化特征判明地下水的补给来源以及各含水层的相互联系。降水和地下水中的环境同位素δD和δ¹⁸O组成分析表明,降水是山前地下水的主要补给源,山区浅层地下水受蒸发影响非常强烈。水化学研究结果表明,山区地下水水质以 Ca²⁺和 HCO^-₃为主,属Ca²⁺-Mg²⁺-HCO^-₃型地下水。山前地下水类型为Ca²⁺-Mg²⁺-HCO^-₃、 Na⁺-K⁺-HCO^-₃、Mg²⁺-Ca²⁺-HCO^-₃和 Ca²⁺-Mg²⁺-Cl^--SO^2-₄。平原区地下水为Mg²⁺, Na⁺和HCO^-₃。滨海冲积海积平原为Ca²⁺-Mg²⁺-HCO^-₃型和Ca²⁺-Mg²⁺-Cl^--SO^2-₄型地下水。水化学分析证实了越流补给的存在。Ca²⁺ 和 HCO^-₃离子均呈山区高、山前和平原低、而滨海增高的趋势。沿潮白河流向地下水类型变化为:Ca²⁺-Mg²⁺-HCO^-₃ Na⁺＝K⁺-HCO^-₃ Ca²⁺-Mg²⁺-HCO^-₃。     

藏南普莫雍错流域水体离子组成与空间分布及其环境意义(英文)

The chemistry of major cations (Mg²⁺, Ca²⁺, Na⁺, and K⁺) and anions (HCO₃ ⁻, SO₄ ²⁻, and Cl⁻) in the water of Lake Pumayum Co and its inflow river was studied, revealing the obvious ionic difference among various inflow rivers and the lake. The chemical type of the lake water was Mg²⁺-Ca²⁺-HCO₃ ⁻-SO₄ ²⁺, but the major ions of the main inflow rivers were Ca²⁺-Mg²⁺-HCO₃ ⁻. In the lake inlet of Jiaqu River, the main inflow river, there was significant variance of water chemistry within the depth less than 2 m. However, it was almost homogeneous at other area of the lake. Therefore, with the evidence of distribution of water chemistry and oxygen isotope of lake water, a conclusion can be outlined that Jiaqu River had a distinct effect on the hydrochemistry of the water on the submerged delta, whereas this is not the case for other rivers. The Gibbs plot revealed that the dominant mechanism responsible for controlling chemical compositions of the lake water was rocks weathering in the drainage area. Ion ratios and ternary plots further explored the main processes controlling the water chemistry of the catchment, i.e., carbonate weathering, pyrite weathering, and silicate weathering. The different hydrochemistry characteristics between river water and lake water may result from the CaCO₃ precipitation. The findings will benefit the explanation of the environmental significance of carbonate in paleolimnological studies in the lake.     

Hydrochemical Characteristics and Sodification of Groundwater in the Shirin Sou, Hamedan, Western Iran

Salinity and sodicity of groundwater are the principal water quality concerns in irrigated areas of arid and semi-arid regions. The hydrochemical characteristics and sodicity of groundwater in the Shirin Sou area, western Iran were investigated in this study by chemical analyses of groundwater samples from 49 wells. Chemical analysis of the groundwater showed that the mean concentration of the cations was in the order: Na⁺ > Ca²⁺ > Mg²⁺ > K⁺, while that for anions was SO₃ ²⁻ > Cl⁻ > HCO₃ ⁻ > NO₃ ⁻. The most prevalent water type is Na–SO₄ followed by water types Na–Cl and Ca–SO₄. The chemical evolution of groundwater is primarily controlled by water–rock interactions: mainly weathering of aluminosilicates, dissolution of sulfate minerals, and cation exchange reactions. Sulfate dissolution and pyrite weathering may both contribute to the SO₄ ²⁻ load of the groundwater. High Na⁺ concentrations in groundwater participate in ion-exchange processes, resulting in the displacement of base cations into solution and raised concentrations in groundwater. The principal component analysis (PCA) performed on groundwater identified three principal components controlling variability of groundwater chemistry. Electrical conductivity, Ca²⁺, Mg²⁺, Na⁺, SO₄ ²⁻, and Cl⁻ content were associated in the same component (PC1) (salinity), most likely linked to anthropogenic activities.     

基于SOFM网络的巴丹吉林沙漠湖泊聚类及其地下水补给来源推断

引入湖泊经纬度、海拔、湖水温度、湖水pH值以及湖水Na⁺、K⁺、Mg²⁺、Ca²⁺、Cl^-、 SO₄^2-、CO₃^2-、HCO₃^-浓度等13个基本变量作为聚类指标,构建了自组织特征映射（SOFM）网络,对巴丹吉林沙漠南部共计105个常年积水湖泊进行了非线性聚类,并与基于类平均法的线性聚类分析结果作对比,得到两种聚类分析方法的结果大体一致,即以雅布赖山北东—南西走向断裂带为界,湖泊呈较明显的二聚类分布,断裂带北部的湖泊聚集一类,接近断裂带以及断裂带南部的湖泊聚为一类,这与实地考察结果相互印证。对聚类结果进行判别后发现,SOFM网络的聚类结果更为准确可靠,其在识别地理现象微小差异方面更具优势。而根据断裂带两侧不同类型湖泊的分布,可以推断巴丹吉林沙漠南部湖泊群地下水源补给空间上的非同源性,以及地下岩层组分和结构上的空间差异性。     

Geochemistry of waters and brines from the Salinas Grandes basin,Córdoba,Argentina. I. Geomorphology and hydrochemical characteristics

This paper reports on hydrochemical features of diluted waters in the source areas and the brine end-members dominant in the playa of the Salinas Grandes Basin, Córdoba, Argentina. Special emphasis was placed on the study of the relationship between geomorphology and the resulting hydrochemical fractionation. Inflow is from springs and mountain streams which disappear before reaching the saline complex. The playa and intermittent saline lakes are mainly fed by groundwater flow and a few moderately saline and perennial springs. Conversely, ephemeral lakes are fed by atmospheric precipitation and groundwater, whereas small ponds are only fed by atmospheric precipitation. The absence of a clear linkage between geomorphological units and water types was evident in the source areas. Up to four types of water were recognized in a given geomorphological unit. From the sandflat downward towards the playa, the correspondence between geomorphological units and water types was clear, coinciding with a decreased hydrochemical heterogeneity. In this subenvironment, I have recognized two dominant types of water (SO ₄ ^2– –Cl^––HCO ₃ ^– –Na⁺ and Cl^––SO ₄ ^2– –HCO ₃ ^– –Na⁺), which can be considered the original members of the neutral brine in the playa (Cl^––SO ₄ ^2– –Na⁺ where Ca²⁺+Mg²⁺ do not surpass 5 meq per cent), and an intermediate type in the mudflat (Cl^––SO ₄ ^2– –Na⁺ where the contribution of Ca²⁺+Mg²⁺ reaches up to 15 meq per cent). It seems evident that in the zone between the source areas and the sandflat, hydrochemistry is governed by chemical weathering. In stream floodplains and in the distal alluvial plain, close to the saline complex, the increase in water types as well as the increase of HCO ₃ ^– with respect to SO ₄ ^2– , were explained by the mixture of aquifers controlled by the Salinas Grandes-Salinas de Ambargasta fracture. In the saline complex, the more concentrated end-members are the result of evaporation of the two more frequent water-types in the sandflat subenvironment, and salt dissolution of ancient evaporite deposit.     

藏南羊卓雍错流域水化学区域差异及其成因

特殊的地理环境造成青藏高原高寒区水化学性质及其动态的特殊性。本文通过对藏南羊卓雍错流域进行水样采集、分析与测定, 探讨了该流域水化学性质的区域差异及其成因。结果表明, 羊卓雍错流域水化学性质区域差异明显主要是自然因素综合作用的结果, 而人类活动对区域水化学性质亦有所贡献。首先, 在特殊的高寒气候条件下, 流域内各湖泊水化学性质差异的根本原因是其水文条件不同。其次, 羊卓雍错西南部湖水样品中硼和锂含量偏高说明该区域湖相沉积中可能存在硼酸盐矿物和含锂菱镁矿。第三, 流域东部和西部河水化学性质差异明显的主因是河流所经地区地质条件不同;羊卓雍错南岸和北岸地下水化学性质差异的关键则是区域水系发育程度不同。此外, 巴纠错、嘎马林河和羊卓雍错南岸水井样品的总氮含量较高, 这反映了人类活动对区域水化学性质的影响。     

Chemical composition of saline and subsaline lakes of the northern Great Plains,western Canada

The northern Great Plains of Canada stretch from the Precambrian Shield near Winnipeg, Manitoba, westward for ∼1,700 km to the Rocky Mountains foothills. This vast region of flat to gently rolling terrain contains a very large number of salt lakes. Major ion chemical data on ∼500 of them are available. Although the average brine (salinity, 37 ppt) is a Na⁺−SO₄ ²⁻ type of water, the lakes exhibit a wide range of salinities and ionic compositions. This diversity is confirmed by Q-mode cluster analysis; it identified thirteen major water chemistry types. Most ions display distinct trends, both spatially and with increasing salinity. All dissolved components increase with increasing salinity, but at different rates. The relative proportions of Ca²⁺ and HCO₃ ⁻+CO₃ ²⁻ ions show a strong decrease with increasing brine salinity, whereas SO₄ ²⁻ ions increase with increasing salinity. The ionic proportions of Na⁺, Mg²⁺, K⁺ and Cl⁻ exhibit no significant relationship with salinity. R-mode factor analysis of the lake water chemistry, combined with selected environmental parameters, identifies groundwater composition, climate, and the elevation of the lake within the drainage system as most important in controlling brine chemistry and salinity on a regional basis. Variability in source of ions, reaction processes and products are undoubtedly key factors in helping to explain brine chemistry of an individual basin or variation from a local perspective, but these factors are generally poorly understood and not quantified on a regional basis. Palliser Triangle Global Change Project Contribution Number 3.     

Multivariate Statistical Analysis in the Assessment of Hydrochemistry of the Northern Korinthia Prefecture Alluvial Aquifer System (Peloponnese,Greece)

The application of multivariate statistical analyses of hydrochemical data has proved to bemost successful in the assessment of groundwater hydrochemistry, especially in situationswhere numerous samples are available. Fifteen (15) hydrochemical parameters were considered(pH, E.C., T.D.S., T.H, Ca, Mg, Na, K, HCO₃, Cl, SO₄, NO₃, NO₂, NH₄, PO₄) in 131 samplescollected from the alluvial aquifer of NE Korinthia, during May 1997. Simple and multipleregression, factor, and trend-surface analyses were applied in order to examine the importance ofeach parameter, investigate correlations among them, and separate them into groups. Statisticalfactors were selected and their geographical distribution was mapped. It was concluded thatuse of such methods reveal the prevailing evolutionary mechanisms of the studied system,thus enabling accurate and relatively quick hydrochemical assessments.     

Characteristics and source of aerosols at Shiyi Glacier,Qilian Mountains, China

Aerosol samples were collected in the Shiyi Glacier,Qilian Mountains from July 24 to August 19,2012 and analyzed for major water-soluble ionic species(F^-,Cl^-,NO₂^-,NO₃^-,SO₄^2-,Na⁺,NH₄⁺,K⁺,Mg²⁺ and Ca²⁺) by ion chromatography. SO₄^2- and NH₄⁺ were the most abundant components of all the anions and cations,with average concentrations of 94.72 and 54.26 neq/m³,respectively,accounting for 34% and 20% of the total water-soluble ions analyzed.These mean ion concentrations were generally comparable with the background conditions in remote sites of the Qilian Mountains,but were much lower than those in certain cities in China.The particles were grouped into two dominant types according to their morphology and EDX signal:Si-rich particles and Fe-rich particles.Backward air mass trajectory analysis suggested that inland cities may contribute some anthropogenic pollution to this glacier,while the arid and semi-arid regions of central Asia were the primary sources of the mineral particles.     

中国内陆干旱、半干旱区苦咸水分布特征

通过大量野外调查、水样采集和化验分析,对中国内陆干旱、半干旱区的苦咸水和高氟水分布特征进行了初步研究。采集到的地表和地下水样中,分别有51.0%和41.5%属于苦咸水;55%和59%水样氟化物含量超标,属于高氟水。研究区的苦咸水以Cl^--Na⁺和HCO₃^--Na⁺为主要离子类型,SO₄^2--Mg²⁺和SO₄^2--Ca²⁺为次要离子类型。苦咸水和高氟水主要分布在内陆河流域下游尾闾、封闭内流区低洼湖盆低地、北部准平原化干燥剥蚀低山残丘间冲积洼地、沙漠低洼湖盆和黄土高原中西部径流系数较小的河流及部分露头潜水等区域,并具有区域富集性分布特点。季节性降水、季节性河流或渠系灌溉对苦咸水的季节性或年际间变化和空间分布有较大影响。较高浓度基质含盐量、水文地质结构、气候条件和特定的水文地球化学环境是苦咸水和高氟水形成与富集分布的主要原因。     

Investigation of Chemical Composition of Atmospheric Aerosol in Ulaanbaatar During 2005–2014

Results from investigating atmospheric aerosols in Ulaanbaatar (Mongolia) 2005–2014 are presented. It is found that the largest sources of suspended particles are represented by fuel combustion and the concomitant exhaust gases, thermal power generation, industrial facilities and mineral dust transport; the main components of aerosol particles are SO ₄ ^2- , NO ₃ ^- , Cl^–, NH ₄ ⁺ , Ca²⁺ and Na⁺. It is determined that in the wintertime, as a result of an increase in fuel consumption, calm weather and orographic characteristics of topography which contribute to accumulation of contaminants in the urban atmosphere, the average sum of ions increases to 43.9–114.6 μg/m³ against 7.44–18.48 μg/m³ during a warm season. Interannual differences in aerosol composition were noted; the total ion content averaged 43.9 μg/m³ during December 2011, 114.6 μg /m³ during December 2012, 68.7 μg/m³ during December 2013, and 64.7 μg/m³ during December 2014. It was found that the concentration of the sum of ions in the aerosol during the winter period is by a factor of 6 higher than during the summer. The highest exceedance of the concentrations was observed for the alkaline earth ions Na⁺, K⁺, Ca²⁺ and Mg²⁺ (by a factor of more than 20) forming part of the ash components. There is a difference in the chemical composition of the aerosol sampled in the center of the city and on its outskirts. It is established that the aerosol composition and concentration in Ulaanbaatar during the winter period are comparable the aerosol composition in the industrial cities of China.     

四元体系(LiCl + NaCl + Li2SO4 + Na2SO4 + H2O)在75℃等温蒸发相平衡实验与理论研究

梯度太阳能池技术在盐湖化工中是一种经济分离无机盐产品的方法,本文创新性的采用等温蒸发法,模拟四元体系(LiCl + NaCl + Li2SO4 + Na2SO4 + H2O)在75℃等温蒸发相平衡,指导太阳池深池积温分离提取锂盐产品。实验测定了溶解度和溶液密度、pH值等物化性质,并绘制了干盐相图、水图和物化性质组成图。在该四元体系干盐相图中包含3个四元共饱点,7条单变量蒸发曲线和5个结晶区,分别为NaCl,Na2SO4,复盐Li2SO4·Na2SO4,Li2SO4·H2O和LiCl·H2O。采用 Pitzer模型和改进的HMW公式,拟合出该四元体系在75℃时的Pitzer单盐参数、混合离子作用参数和平衡固相的热力学平衡常数,并计算给该四元体系的相图,计算相图和实验相图有较大区别。等温蒸发相图能真实的反应盐湖中盐类沉积规律,并对指导太阳池分离盐类具有重要指导意义。     

Water chemistry and its diversity in relation to local factors in the Latnjavagge drainage basin, arctic–oceanic Swedish Lapland

The chemistry of precipitation, snow pack and surface water has been analysed on 205 samples collected during the 2001 field season at 25 selected sites within the Latnjavagge drainage basin in arctic–oceanic northern Swedish Lapland. Additionally, daily discharge and yield of dissolved solids have been calculated for several subcatchments and the entire Latnjavagge catchment during the years 2000, 2001 and 2002. Chemical water analysis included the components Ca²⁺, Mg²⁺, Na⁺, K⁺, Fe²⁺, Mn²⁺, Cl⁻, NO₃⁻, SO₄²⁻ and PO₄³⁻, with SO₄²⁻ and Ca²⁺ being the dominant ones in the surface water. Solute concentrations and chemical denudation were low, but showed significant differences within the basin. In areas of shade, longer snow cover, frozen ground and thin regolith, concentrations over the summer were perceptible but so low that solutes brought into the basin from precipitation could be detected in the surface water. In one locality, it was even found that lake water could reflect snowmelt to such an extent that the solute concentration was less than that of summer precipitation. The highest concentrations were found at a radiation-exposed, W-facing, vegetated, moderately steep slope with relatively thick regolith that was thawed at the time of snowmelt in early June. In such well-drained sites with continuous subsurface water flow, a maximum of contact between water and mineral particles could take place. The concentration values revealed differences in the rate of thawing of frozen ground between shaded areas and/or areas at higher altitude on the one hand and radiation-exposed areas on the other. A comparison with published results from Kärkevagge a few kilometres to the northwest as well as from other periglacial locations indicates that the chemical denudation values from Latnjavagge are more representative of periglacial oceanic environments than the values from the Kärkevagge catchment, which shows especially high chemical denudation rates. The investigation in Latnjavagge stresses the importance of spatial variability within even small catchments of homogeneous lithology as it demonstrates that solute concentrations from different subbasins can differ substantially dependent on exposure to radiation, duration of snow cover and frozen ground conditions, regolith thickness and possibly also to vegetation cover and slope angle as factors steering water turbulence and retention of drainage.     

Effective environmental factors in the distribution of vegetation types in Poshtkouh rangelands of Yazd Province (Iran)

The objective of this research was to study the relationships between environmental factors and vegetation in order to find the most effective factors in the separation of the vegetation types in Poshtkou rangelands of Yazd province. Sampling of soil and vegetation were performed with randomized-systematic method. Vegetation data including density and cover percentage were estimated quantitatively within each quadrat, and using the two-way indicator species analysis (TWINSPAN), and vegetation was classified into different groups. The topographic conditions were recorded in quadrat locations. Soil samples were taken in 0–30 and 30–60 cm depths in each quadrat. The measured soil variables included texture, lime, saturation moisture, gypsum, acidity (pH), electrical conductivity, sodium absorption ratio, and soluble ions (Na⁺, K⁺, Mg²⁺, Cl⁻, CO₃²⁻, HCO₃⁻ and SO₄²⁻). Multivariate techniques including principal component analysis (PCA) and canonical correspondence analysis (CCA) were used to analyse the collected data. The results showed that the vegetation distribution pattern was mainly related to soil characteristics such as salinity, texture, soluble potassium, gypsum, and lime. Totally, considering the habitat conditions, ecological needs and tolerance range each plant species has a significant relation with soil properties.     

柴达木盆地中西部背斜构造深层卤水水化学特征与成因

柴达木盆地西部背斜构造深层卤水资源勘查和评价成果显示,第三系背斜构造赋存深层卤水,具有良好的资源成矿条件,且潜力大。采集柴达木盆地中西部(一里坪拗陷和三湖拗陷)9处背斜构造深层卤水,分析了其水化学特征与成因。结果表明,深层卤水矿化度一般低于150 g/L,水化学类型均为氯化物型;K⁺、Na⁺、Mg²⁺含量较低,不具找矿价值;而B₂O₃、Li⁺含量普遍高于评价指标,Br-、I-含量普遍高于综合评价指标,为主要成矿元素;卤水的元素特征系数和分布规律及微量离子组成揭示,深层卤水是大气降水溶滤盆地周缘岩浆岩和火山岩及火山热泉的补给后,汇入古近纪—新近纪湖盆经蒸发浓缩封存在地层中的沉积卤水。     

Plants as soil indicators along the Saudi coast of the Arabian Gulf

Soils of different vegetation types of the Saudi Arabian Gulf coast, dominated by mangrove, salt marsh and desert plant communities have been analysed for their soil profiles, texture, salinity, pH, water content and ionic concentration (Ca²⁺, Cl⁻, K⁺, Na⁺, SO₄²⁻). The results show some important relationships between soils and plants. Special emphasis was given to the dominant intertidal plantsAvicennia marina, Arthrocnemum macrostachyum, Salicornia europaea, Halocnemum strobilaceum, Halopeplis perfoliata, Limonium axillare, the terrestrialZygophyllum qatarense, and non-vegetated sabkhas.     

Present Limnological Conditions and Recent (ca. 340 yr) Palaeolimnology of a Tropical Lake in the Sierra de Los Tuxtlas, Eastern Mexico

The Sierra de Los Tuxtlas is a recently active volcanic field, with eruptions in 1664 and 1792. It holds one of the reserves of tropical evergreen forest in Mexico, as well as several maar lakes. One of them, Lago Verde, was chosen for a three-fold study (1) on its present limnological conditions, (2) on the algal community living in the water column and preserved in the surface sediments; and (3) on its recent history (ca. 340 yr). The palaeolimnological study was based on multiproxy analyses on core material dated by ²¹⁰Pb, ¹³⁷Cs and ¹⁴C. Lago Verde is a small, shallow lake with dilute, slightly alkaline water (CO₃²⁻ + HCO₃⁻ > Cl⁻ > SO₄²⁻, Na⁺ + K⁺ > Ca²⁺ > Mg²⁺). It is turbid, eutrophic, with high phosphorus levels. It is a warm polymictic lake, with thermal and oxygen stratification establishing by midday during the warm months. The lake does not stratify in winter. Diatoms dominate the phytoplankton community in the cold ‘nortes’ season, Cyanobacteria in summer, and Chlorophyta in autumn. Cyanobacteria (Chroococcales) are not well preserved in the surface sediments while Chlorophyta are better preserved. Sedimentary diatoms are well preserved, dominated by the three most abundant species in the water column: Achnanthidium minutissimum, Fragilaria capucina and Aulacoseira granulata. The base of the studied sequences is constrained by the historic eruption of 1664. The period from 1664 to 1963 is characterised by a meso-eutrophic lake. Tropical Forest vegetation reaches maximum values between ca. 1800 and 1963. Between ca. 1785 and 1885 the lake was slightly shallower than in the rest of the 1664–1963 period, probably recording climatic variability. An early pulse of anthropogenic disturbance was recorded by ca. 1921 and after ca. 1963 intense forest clearance and high erosion rates led to a more turbid, more productive, nutrient-rich lake. The highest anthropogenic impact was reached by ca. 1988; afterwards the lake and its basin reached a new balance, with the establishment of the present modern conditions.     

Chemical weathering and CO2 consumption in the Xijiang River basin, South China

Monthly samples of riverine water were collected and analyzed for the concentrations of major ions (Ca²⁺, Mg²⁺, K⁺, Na⁺, HCO₃⁻, SO₄²⁻, Cl⁻, NO₃⁻), dissolved silicon, and total dissolved solids (TDS) at Wuzhou hydrological station located between the middle and lower reaches of the Xijiang River (XJR) from March 2005 to April 2006. More frequent sampling and analysis were carried out during the catastrophic flooding in June 2005. Stoichiometric analysis was applied for tracing sources of major ions and estimating CO₂ consumption from the chemical weathering of rocks. The results demonstrate that the chemical weathering of carbonate and silicate rocks within the drainage basin is the main source of the dissolved chemical substances in the XJR. Some 81.20% of the riverine cations originated from the chemical weathering processes induced by carbonic acid, 11.32% by sulfuric acid, and the other 7.48% from the dissolution of gypsum and precipitates of sea salts within the drainage basin. The CO₂ flux consumed by the rock chemical weathering within the XJR basin is 2.37 × 10¹¹ mol y^− 1, of which 0.64 × 10¹¹ mol y^− 1 results from silicate rock chemical weathering, and 1.73 × 10¹¹ mol y^− 1 results from carbonate rock chemical weathering. The CO₂ consumption comprises 0.38 × 10¹¹ mol during the 9-d catastrophic flooding. The CO₂ consumption from rock chemical weathering in humid subtropical zones regulates atmospheric CO₂ level and constitutes a significant part of the global carbon budget. The carbon sink potential of rock chemical weathering processes in the humid subtropical zones deserves extra attention.     

四元体系Li2SO4+Na2SO4+K2SO4+H2O298.2 K相平衡研究

为了获取锂钠钾共存硫酸盐体系298.2 K下各盐结晶形式,采用等温溶解平衡法研究了298.2 K下四元体系Li₂SO₄₊Na₂SO₄₊K₂SO₄₊H₂O的相平衡关系,测定了该体系的溶解度和密度,采用X-ray粉晶衍射法测定了平衡固相组成,并绘制了相应的稳定相图和多温对比图。研究表明,298.2 K下该四元体系为复杂四元体系,有复盐2Li₂SO₄·Na₂SO₄·K₂SO₄、Li₂SO₄·3Na₂SO₄·12H₂O、LiKSO₄、Na₂SO₄·3K₂SO₄生成。其稳定相图由6个四元共饱点、12条单变量曲线以及7个结晶区组成。其中,复盐Na₂SO₄·3K₂SO₄结晶区最大,表明其在该体系中最易结晶析出;Li₂SO₄·H₂O结晶区最小。对比273.2 K、288.2 K、298.2 K、323.2 K、373.2 K四元体系多温相图可知,273.2 K时未发现复盐Na₂SO₄·3K₂SO₄和2Li₂SO₄·Na₂SO₄·K₂SO₄结晶形式;Na₂SO₄·10H₂O和Li₂SO₄·3Na₂SO₄·12H₂O结晶形式在323.2 K和373.2 K时转变为Na₂SO₄和Li₂SO₄·Na₂SO₄。288.2~373.2 K时随温度升高,K₂SO₄和Na₂SO₄·10H₂O结晶相区减小,Li₂SO₄·H₂O、Na₂SO₄、LiKSO₄和Li₂SO₄·Na₂SO₄结晶相区增大;Na₂SO₄·3K₂SO₄结晶相区先增大后减小,在298.2 K时结晶相区最大;2Li₂SO₄·Na₂SO₄·K₂SO₄结晶相区先减小后增大,298.2 K时结晶相区最小。     

盐生植物长叶红砂泌盐特性的研究

长叶红砂（Reaumuria trigyna Maxim.）为东阿拉善-西鄂尔多斯种,属我国特有,是古地中海残遗珍稀植物。通过对长叶红砂野外生存环境、泌盐结构以及泌盐特点的研究,结果显示:长叶红砂是一种具有多细胞盐腺的向外泌盐的泌盐盐生植物;长叶红砂植物体内、盐腺分泌物中盐分离子组分与生存土壤的离子组分一致,均含有Na+、K+、Ca2+、Mg2+、SO2-4和Cl-等离子,但含量差异较大,其中土壤中阳离子以Na+或以Na+和Ca2+为主,阴离子以Cl-或SO2-4为主;植物的根、茎、叶中阳离子却以K+为主,且6种离子含量的基本趋势均是:根＜茎＜叶;分泌物中Na+ 、Cl-的含量最高,其次是SO2-4;盐腺的分泌速率表现为:上午的分泌量高于下午,白昼高于夜间,这些结果说明盐腺的分泌选择性与其保持植物体内适当的盐分和养分浓度以适应野生生境有关。