Real-time application of an oil spill movement prediction system

This paper deals with the prediction, in real time, of the motion of experimental oil slicks. The experiments were conducted during September 1983 offshore near Halifax on the east coast of Canada. The objectives of the experiments were (i) to determine the suitability of oil spill dispersants as countermeasures and (ii) the testing and verification of oil spill trajectory models and systems.The Atmospheric Environment Service (AES) participated in the experiments to test the capability of its oil spill motion prediction system in providing real-time trajectory forecasts. The experiment consisted of three sets of spills. Each set had a control slick and a test slick. Sixteen barrels of crude oil were used in each spill. The test slicks were used to test the effectiveness of various dispersants, the control slicks were used to verify trajectory forecasts.The spill trajectories and oil weathering information obtained from the system during the experiments demonstrated the relative ease with which the system could handle the required input and provide timely forecasts. The accuracy of these forecast trajectories was confirmed by observations, and their utility was demonstrated by their application in the operational decision-making process.     

Application of an oil spill vulnerability index to the shoreline of lower Cook Inlet,Alaska

Offshore tracts in Alaska's lower Cook Inlet are scheduled to be opened for exploratory petroleum drilling in the near future. Because of the potential for oil spills resulting from this activity, a field study of the coastal zone was conducted in June 1976. A total of 1216 km of shoreline was classified into 3 types: erosional (45 percent), neutral (38 percent), and depositional (17 percent). These were further subdivided into 16 subclasses on the basis of small scale morphological features. This classification was used in conjunction with a vulnerability index of potential oil spill damage, developed through study of three major oil spills, to predict the longevity of oil in the different coastal environments of the Inlet. On a scale from 1 to 10, 45 percent of the shoreline has low values of 1 to 4, which means that oil would be dispersed by natural processes within less than six months after a spill on these coasts. Values from 4 to 6 were assigned to 13.4 percent of the shoreline, where oil residence time may be up to one year. A 6 to 10 rating was assigned to 41.5 percent of the shoreline, where oil contamination may remain for periods of two to ten years, or possibly longer should no major clean-up procedures be initiated. We propose that the use of this type of vulnerability indexing, in conjunction with a biological susceptibility index and oil spill trajectory models, would provide a rational basis for decision making concerning the location of on- and off-shore oil facilities and the design of oil spill contingency plans.     

A social assessment of the Hebei-Spirit oil spill

This paper examines the early social consequences of the largest oil spill in Korea from December 2007 up to May 2008. The focus is on the social impact of the oil spill and its social implications in three major areas of oil spill response: (1) clean-up operations, (2) compensation, and (3) ecological impact. The paper highlights both the positive and negative consequences of the spill and the significance of the early social assessment to understand subsequent responses and adaptation in the long run.     

Simulation of the movement and dispersion of oil slicks in the Arabian Gulf

The extensive oil drilling and transportation activities in the Arabian Gulf increased the possibility of oil spills and the consequent threat of oil pollution to the regional ecology. The available literature concerning the main aspects of the physical oceanographic characteristics affecting the movement and spreading of oil spill in the Gulf are reviewed. It is concluded that evaporation, wind-driven currents, and sandfall are important as weathering processes, while tidal currents cause lateral spreading of the slick. Oil spill modelling has shown some usefulness in estimating the trajectories of few major spills illustrated by reference to three models developed for the Gulf. The performance of these models, their capabilities and limitations are reviewed. Recommendations are made to gather more data on the behavior of oil spills in this particular environment.     

Locating oil spill response equipment and facilities: A cluster analysis approach

The response to marine accidental spillage of oil requires careful advance planning to ensure that the impact of an oil spill is minimized. In this paper a binary integer mathematical model based on the cluster analysis approach is developed to aid in determining the optimal sites for locating oil spill response equipment and facilities within a semienclosed waterway. The application of the model has been illustrated through a numerical example using hypothetical but representative data to determine optimal sites for locating oil spill response equipment and facilities in the Arabian Gulf region.     

Hydrocarbon-Degrading Bacteria and Paraffin from Polluted Seashores 9 Years after the Nakhodka Oil Spill in the Sea of Japan

Pollution of petroleum hydrocarbons, in particular oil spills, has attracted much attention in the past and recent decades. Oil spills influence natural microbial community, and physical and chemical properties of the affected sites. The biodegradation of hydrocarbons by microorganisms is one of the primary ways by which oil spill is eliminated from contaminated sites. One such spill was that of the Russian tanker the Nakhodka that spilled heavy oil into the Sea of Japan on January 2, 1997. The impact of the Nakhodka oil spill resulted in a viscous sticky fluid fouling the shores and affected natural ecosystems. This paper describes the weathering of hydrocarbon-degrading bacteria （genus Pseudomonas） and crystallized organic compounds from the Nakhodka oil spill-polluted seashores after nine years. The Nakhodka oil has hardened and formed crust of crystalline paraffin wax as shown by XRD analysis （0.422, 0.377, and 0.250 nm d-spacing） in association with graphite and calcite after 9 years of bioremediation. Anaerobic reverse side of the oil crust contained numerous coccus typed bacteria associated with halite. The finding of hydrocarbon-degrading bacteria and paraffin wax in the oil crust may have a significant effect on the weathering processes of the Nakhodka oil spill during the 9- year bioremediation.     

Coupled solution of oil slick and depth averaged tidal currents on three-dimensional geometry of Persian Gulf

In this paper, simulation of oil spill due to tidal currents in Persian Gulf is performed by coupled solution of the hydrodynamics equations and an equation for convection and diffusion of the oil. The hydrodynamic equations utilized in this work consist of depth average equations of continuity and motion in two dimensional horizontal planes. The effect of evaporation is considered in the continuity equation and the effects of bed slope and friction, as well as the Coriolis effects are considered in two equations of motion. The overlapping cell vertex finite volume method is applied for solving the governing equations on triangular unstructured meshes. Using unstructured meshes provides great flexibility for modeling the flow in arbitrary and complex geometries, such as Persian Gulf flow domain. The results of the hydrodynamic model for tidal currents in Persian Gulf domain is examined by imposing tidal fluctuations to the main flow boundary during a limited period of time. Finally, the developed model is used to simulate an accidental oil spill from a point in Persian Gulf.     

Response of the phoxocephalid amphipod,Rhepoxynius abronius,to a small oil spill in Yaquina Bay,Oregon

A spill of approximately 284,000 liters of Bunker C and diesel fuel oils occurred at the entrance of Yaquina Bay, Oregon, following the wreck of the freighterBlue Magpie on 19 November 1983. A portion of this oil entered the lower estuary and was deposited on subtidal benthic habitats occupied by the phoxocephalid amphipodRhepoxynius abronius. This species is particularly sensitive to contaminants in sediment and its life history had previously been studied at the same sites affected by the spill. The oil was initially present as small, sand-coated globules at the study site, and persisted in association with detritus and sediment for months. Bioassays withRhepoxynius abronius showed that the oil globules were not acutely toxic unless mixed into the sediment at concentrations of 1.0 parts per thousand or greater. A series of 10-d bioassays before and after the spill showed that sediment collected from oiled subtidal sites did not become acutely toxic to this species. Although the density of theR. abronius population declined by 75% after the spill, similar declines of the same population were observed at this site in fall 1980. Oil-exposedR. abronius from Yaquina Bay were slightly more sensitive to cadmium in sediment than individuals from Whidbey Island, Puget Sound, Washington. Although mean fecundity was greater in 1984 than in 1981, recruitment following the spill was lower than in the 1980–1981 study. Thus, there is limited evidence for a small impact of the oil spill on this sensitive amphipod.     

Availability of barley straw application on oil spill clean up

Oil spills are a global concern due to the environmental and economical impact. Various commercial systems have been developed to control these spills, including the use of fibers as sorbents. However, most sorbents end up in landfills or in cineration after single use. These options either produce another source of pollution or increase the oil recovery cost. Plant biomass is renewable resource that can be converted into useful materials and energy. Barley straw, an agricultural waste, was used as sorbent material. The present study examines the absorption capacity of raw barley straw for different petroleum products and water pick up. The investigate revealed that the capacity of fibers to remove crude oil from sea water was related to the surface properties of the fibers, concentration of the oil, size of the fiber, amount of the fibers, as well as the temperature of the crude oil. Cyclic sorption / desorption studies indicated that a simple squeezing operation was enough to remove most of the oil sorbed and that recycling was feasible.     

Particulate oil spill recovery. I,Oil sorption properties of plastic foams

Reusable, reticulated, polyurethane foams are broadcast at sea, absorb oil in the presence of water, are recovered, oil removed and foam particles rebroadcast. Combining dimensional and mathematical analysis with experimental data, a mathematical model of foam sorption efficacy and rate is developed showing the system to be practical. Oil viscosity, wave height, recovery ship speed, and system geometry influence foam selection.     

Evolution of the Moxizhuang Oil Field, Central Junggar Basin, Northwest China

Current oil saturation in the Moxizhuang (莫西庄) Oil Field in central Janggar (准噶尔) basin was evaluated by logging interpretation and measured on core samples, and the paleo-oil saturation in both the pay zones and water zones was investigated by graln-containing-oil inclusion (GOI) analysis.The pay zones in this field have low oil saturation and display low resistivity and small contrast between pay zones and water zones, and are classified as low-porosity, low oil saturation, and low resistivity reservoirs. Both the current low oil-saturation pay zones and the water zones above 4 365 m have high GOI values (up to 38%), suggesting high paleo-oil saturation. The significant difference between current oil saturation from both logging interpretation and core sample measurement and paleo-oil saturation indicated by GOI analysis suggests that this low oil-saturation field evolved from a high oil-saturation pool. Lateral re-migration and spill of formally trapped oil owing to changes in structural configuration since Neogene was the most plausible mechanism for oil loss in the Moxizhuang Oil Field.The combined effects of differential accumulation in the charge phase and the differential re-migration and spill of accumulated oil in Neogene are responsible for the complicated correlation between residual oil saturation and porosity/permeability of the reservoir sandstones and the distribution of low oil-saturation pay zones and paleo-oil zones (current water zones).     

North Indian Ocean warming and sea level rise in an OGCM

The variability in the long-term temperature and sea level over the north Indian Ocean during the period 1958–2000 has been investigated using an Ocean General Circulation Model, Modular Ocean Model version 4. The model simulated fields are compared with the sea level observations from tide-gauges, Topex/Poseidon (T/P) satellite, in situ temperature profile observations from WHOI moored buoy and sea surface temperature (SST) observations from DS1, DS3 and DS4 moored buoys. It is seen that the long (6–8 years) warming episodes in the SST over the north Indian Ocean are followed by short episodes (2–3 years) of cooling. The model temperature and sea level anomaly over the north Indian Ocean show an increasing trend in the study period. The model thermocline heat content per unit area shows a linear increasing trend (from 1958–2000) at the rate of 0.0018 × 10¹¹ J/m² per year for north Indian Ocean. North Indian Ocean sea level anomaly (thermosteric component) also shows a linear increasing trend of 0.31 mm/year during 1958–2000.     

热点作用背景下的洋中脊跃迁和扩展作用:印度洋盆地张开过程探讨

在《印度洋底大地构造图》的基础上,分析了印度洋盆构造格局和洋盆演化重大事件序列,并从印度洋盆初始裂解机制、扩张中心跃迁与热点作用、洋中脊扩展作用等方面讨论了印度洋盆的张开过程,提出以下几点认识:(1)现今印度洋洋中脊可分为两个系统:东南印度洋中脊-中印度洋中脊-卡斯伯格洋脊系统(东支)和西南印度洋中脊系统(西支),前者是太平洋洋中脊扩展作用的产物,后者是太平洋-东南印度洋中脊与大西洋中脊之间构造调节的产物;(2)印度洋盆最初裂解受地幔柱垂向挤压-水平伸展作用控制,沿前寒武造山带等地壳薄弱带发育;(3)印度洋盆经历两次扩张中心的跃迁,其趋向性跃迁方向与热点相对板块的运动方向具有一致性,显示两者存在内在联系。(4)大西洋和太平洋洋中脊在印度洋交汇,于古近纪连通,末端伴随陆块持续发生碎裂化、裂解化,可称为鱼尾构造模式,表明印度洋盆衔接和调节了三大洋盆的发育和演化过程,具有全球洋盆枢纽的关键意义。     

Tracing subsurface oil pollution leakage using 2D electrical resistivity tomography

This study provides an evaluation of the subsurface oil contaminant flow in an oil production field at the Wadi Feiran fan, along the Gulf of Suez, Egypt. The 2D electrical resistivity tomography technique has been applied along four profiles surrounding the spill location of oil dump site. Theoretical soil resistivity response versus fluid resistivity for different cation exchange capacity values has been studied. Then, a physical model for the current situation of flowing the oil over the groundwater (sea invaded water) of saturated fluvial sediments has been introduced. It was supposed that the crude oil has higher resistivity values and turned to be conductive far away from the oil spill source under the effect of microbial biodegradation. Such conditions of contaminated distribution and its resistivity values have been considered during the inversion and interpretation of the acquired data sets. The processed 2D resistivity profiles reveal that oil plumes are accumulated in the seawater invasion direction, whereas it has low signatures along the profiles parallel to the shore line.     

Multimedia environmental analysis of PCBs fate and transport mechanism through a case study of transformer oil leakage

Transformer oil leakage having large quantity of PCBs is one of the most deplorable incidents resulting in huge negative impacts on the environment. In this paper, two different models, i.e. CHEMCAN and the hydrocarbon spill screening models, were applied to the case study adapted from a real case of PCBs in transformer oil spill in Montreal. The oil migration was examined in three dimensions including site-specific data, soil characteristics and hydrogeological properties. This study aims to investigate the fate, transport and transformation rates of PCB in the soil, the unsaturated and the saturated zones. The proposed modelling concept helps to define the processes to be used in characterization of soil and subsurface environment as a receptor of transformer oil spill. This study includes the simulation techniques for assessing the effect of PCBs on groundwater and soil. Results from multimedia environmental model and HSSM model verify with each other, and both show that 92.7 % of PCBs were found in soil as compared to groundwater. Considering decay and sorption processes at spill location, concentration of PCBs in soil was >50 mg/kg. This study can serve as a basis for further analysis and assist in selection of remediation technique.     

Numerical modeling of two-phase fluid flow and oil slick transport in estuarine water

Oil spills is one of the most important hazards in the estuarine and coastal water. In recent decades, engineers try to predict the status of oil slick to manage the pollution spreading. The prediction of oil slick transport is carried out mainly by means of numerical models. In the current study, the development and application of a two-phase fluid flow model to simulate oil transport in the marine environment are presented. Different transport and fate processes are included in the developed model. The model consists of the Lagrangian method for the advection process, the Random Walk technique for horizontal diffusion process and the empirical equations for the fate processes. The major forces for driving oil particles are fluid current, wind speed and turbulent flow. Therefore, the multi-component hydrocarbon method has been included to the developed model in order to predict fate processes. As prediction of particle velocity components is of major importance for oil slick advection, therefore the binomial interpolation procedure has been chosen for the particle velocity components computations. In addition, shoreline boundary condition is included in the developed model to simulate shore response to oil slick transport near the beaches. The results of the model applications are compared with the analytical solutions, experimental measurements and other numerical models cited in literature. Comparisons of different sets of results represent the capability of developed model to predict the oil slick transport. In addition, the developed model is tested for two oil spill cases in the Persian Gulf.     

Natural attenuation and bioremediation of Prestige fuel oil along the Atlantic coast of Galicia (Spain)

Heavy fuel oil spilled from the oil tanker Prestige in November 2002 affected hundreds of km of Spanish shoreline. We carried out a two year study at two highly contaminated sites in order to monitor natural attenuation of the residues coating shore rocks and to test the effectiveness of bioremediation with an oleophilic fertilizer (S200). The methodology included an innovative approach for oil load calculation (based on image analysis techniques), the analysis of the fate of hydrocarbons by means of chemical biomarkers and different microbiological techniques for isolating and examining hydrocarbon degraders.Considerable hydrocarbon depletion from shorelines (≈100% for light-medium linear alkanes and ≈35% for aromatics such as pyrene) was observed within the first months after the spill. However, this natural attenuation effect dramatically slowed down in the following year, although partial enhancement (especially for the aromatic fraction) was attained as a result of the application of S200 to stimulate indigenous microorganisms. In addition, one of the main outcomes of this work concerns the remarkable hydrocarbon depletion achieved at points where fresh water flowed through the shore rocks. The study of samples collected where this natural attenuation phenomenon took place made it possible to isolate heterotrophic bacteria and fungi that are likely to cooperate with cyanobacteria in hydrocarbon biodegradation. The overall results strongly advocate the implementation of new bioremediation approaches, including alternatives such as the use of natural fresh water to irrigate polluted areas.     

Methane production and consumption monitored by stable H and C isotope ratios at a crude oil spill site,Bemidji, Minnesota

Stable isotopic ratios of C and H in dissolved CH₄ and C in dissolved inorganic C in the ground water of a crude-oil spill near Bemidji, Minnesota, support the concept of CH₄ production by acetate fermentation with a contemporaneous increase in HCO₃⁻ concentration. Methane concentrations in the saturated zone decrease from 20.6 mg L⁻¹ to less than 0.001 mg L⁻¹ along the investigated flow path. Dissolved N₂ and Ar concentrations in the ground water below the oil plume are 25 times lower than background; this suggests that gas exsolution is removing dissolved CH₄ (along with other dissolved gases) from the ground water. Oxidation of dissolved CH₄ along the flow path seems to be minimal because no measurable change in isotopic composition of CH₄ occurs with distance from the oil body. However, CH₄ is partly oxidized to CO₂ as it diffuses upward from the ground water through a 5- to 7-m thick unsaturated zone; theδ¹³C of the remaining CH₄ increases, theδ¹³C of the CO₂ decreases, and the partial pressure of CO₂ increases.Calculations of C fluxes in the saturated and unsaturated zones originating from the degradation of the oil plume lead to a minimum estimated life expectancy of 110 years. This is a minimum estimate because the degradation of the oil body should slow down with time as its more volatile and reactive components are leached out and preferentially oxidized. The calculated life expectancy is an order of magnitude estimate because of the uncertainty in the average linear ground-water velocities and because of the factor of 2 uncertainty in the calculation of the effective CO₂ diffusion coefficient.     

Insights into oil cracking based on laboratory experiments

The objectives of this pyrolysis investigation were to determine changes in (1) oil composition, (2) gas composition and (3) gas carbon isotope ratios and to compare these results with hydrocarbons in reservoirs. Laboratory cracking of a saturate-rich Devonian oil by confined, dry pyrolysis was performed at T=350–450 °C, P=650 bars and times ranging from 24 h to 33 days. Increasing thermal stress results in the C₁₅₊ hydrocarbon fraction cracking to form C_6–14 and C_1–5 hydrocarbons and pyrobitumen. The C_6–14 fraction continues to crack to C_1–5 gases plus pyrobitumen at higher temperatures and prolonged heating time and the δ ¹³C_ethane–δ¹³C_propane difference becomes greater as oil cracking progresses. There is considerable overlap in product generation and product cracking. Oil cracking products accumulate either because the rate of generation of any product is greater than the rate of removal by cracking of that product or because the product is a stable end member under the experimental conditions. Oil cracking products decrease when the amount of product generated from a reactant is less than the amount of product cracked. If pyrolysis gas compositions are representative of gases generated from oil cracking in nature, then understanding the processes that alter natural gas composition is critical.     

鄂尔多斯盆地油页岩的主要地质特征及资源潜力

前人及笔者最近研究结果表明:鄂尔多斯盆地除赋存有大量的石油、天然气、煤、煤层气、地下水及铀矿而外,还赋存着巨量的油页岩资源.油页岩分别赋存于早二叠世山西组、中-晚三叠世延长组、晚三叠世瓦窑堡组及中侏罗世早期延安组、中侏罗世晚期安定组地层中;在空间上,油页岩多呈层状展布于盆地内部而隐伏于地下.中、晚三叠世延长组和中侏罗世早期延安组是主要含油页岩层位.早二叠世油页岩形成于海陆交互的滨海环境,中-晚三叠世延长组中的油页岩形成于陆相深湖或半深湖环境,晚三叠世瓦窑堡组油页岩、中侏罗世早期延安组油页岩形成于陆相湖泊三角洲湖沼环境,与煤层共生,而中侏罗世晚期安定组油页岩仅局限于陆相半深湖环境.通过对陕西铜川北部和宁夏固原炭山典型油页岩矿的剖析,查明鄂尔多斯油页岩矿层厚度一般为4～36 m,含油率一般为1.5%～13.7%(下限略低于3.5%这一油页岩矿的最低工业品位,本次低于部分暂不参加资源量的计算);发热量一般为1.66～20.98 MJ/kg,视比重1.55～2.46.埋藏2000 m以上的页岩油资源量(334)达2000×108 t以上,其中探明储量(121)1×108t,显示了巨大的资源前景.盆地东南部及西部的油页岩埋藏浅,部分地段探明程度高,交通条件好,如果及时开发利用,不仅可以获得初步经济效益,同时也可为鄂尔多斯油页岩的开发利用获取开拓性的宝贵经验.