Variability of Thermocline Characteristics in the Range of the Black Sea Rim Current

Doklady Earth Sciences - The data collected in the course of the drifter experiment within the Rim Current zone allowed preliminary estimates of the thermocline response to a changing current...     

Seasonal Variability of Vertical Fluxes of Dispersed Sedimentary Matter in the Black Sea

Doklady Earth Sciences - The main aim of this work is to obtain new data on the seasonal variability of the vertical flux of sedimentary matter, its composition, and its transformation during...     

Intermediate Waters in the Irminger Sea during Deep Convection: Variability and the Role of Circulation Mechanisms

Doklady Earth Sciences - The spatial structure, interannual variability, and pathways of the Labrador Sea water (LSW) in the Irminger Sea were analyzed during period of deep convection in...     

The Equation of State for Caspian Sea Waters

The density ρ of Caspian Sea waters was measured as a function of temperature (273.15–343.15) K at conductivity salinities of 7.8 and 11.3 using the Anton-Paar Densitometer. Measurements were also made on one of the samples (S = 11.38) diluted with water as a function of temperature (T = 273.15–338.15 K) and salinity (2.5–11.3). These latter results have been used to develop an equation of state for the Caspian Sea (σ = ±0.007 kg m⁻³)

The Response of Macrobenthic Communities to Environmental Variability in Tropical Coastal Waters

The relative contributions of spatial and temporal fluctuations are different in shaping natural communities in a tropical coastal/estuarine system. Understanding how coastal communities respond to these fluctuations is still equivocal, and thus, available data are rare. Here, multiple analytical approaches were used to identify key spatial and temporal factors, and to quantify their relative roles in shaping a macrobenthic community through space (contamination degree, physical parameters, and sediment characteristics) and time (climatic factors, season, and year). A dataset of eight sampling times was analyzed over a period of 2 years, in which macrobenthic species abundances were sampled. A total of 33 species were identified, including 18 bivalves, 5 gastropods, and 4 crustaceans. The other taxa were less diverse. The results show that there were no significant temporal changes of macrobenthic community structure, but spatial changes were significant and synchronized with environmental factors (i.e., sediment characteristics, water depth, and the distance from anthropogenic sources). This study demonstrates that spatial factors played a primary role in structuring of macrobenthic assemblages, whereas the influence of temporal factors appeared less across geographically distinct sites. Thus, temporal variation of a coastal macrobenthic community appears to be controlled by partly different processes at different scales.     

Messinian events in the Black Sea

Past hydrological interactions between the Mediterranean Sea and Black Sea are poorly resolved due to complications in establishing a high‐resolution time frame for the Black Sea. We present a new greigite‐based magnetostratigraphic age model for the Mio‐Pliocene deposits of DSDP Hole 380/380A, drilled in the southwestern Black Sea. This age model is complemented by ⁴⁰Ar/³⁹Ar dating of a volcanic ash layer, allowing a direct correlation of Black Sea deposits to the Messinian salinity crisis (MSC) interval of the Mediterranean Sea. Proxy records divide these DSDP deposits into four intervals: (i) Pre‐MSC marine conditions (6.1–6.0 Ma); (ii) highstand, fresh to brackish water conditions (~6.0–5.6 Ma); (iii) lowstand, fresh‐water environment (5.6–5.4 Ma) and (iv) highstand, fresh‐water conditions (5.4–post 5.0 Ma). Our results indicate the Black Sea was a major fresh‐water source during gypsum precipitation in the Mediterranean Sea. The introduction of Lago Mare fauna during the final stage of the MSC coincides with a sea‐level rise in the Black Sea. Across the Mio‐Pliocene boundary, sea‐level and salinity in the Black Sea did not change significantly.     

The Multiple Sources and Patterns of Methane inNorth Sea Waters

The methane concentration in the atmosphere andsurface water was surveyed along 58° N acrossthe North Sea. In addition, the vertical methanedistribution in the water column was determined at sixstations along the transect. The methane contents ofthe surface water as well as in the water column wereextremely inhomogeneous. Input by freshwater fromriver discharge and injection of methane from thesediment were both observed. The survey continued fromthe western side of the North Sea to the Elbe Riverestuary. The Elbe River appears to have low methaneconcentrations compared to other European rivers, itsaverage input into the North Sea is estimated to be70 nmol s-1 of methane. Near 58° N,1°40' E, an abandoned drill site releases about 25 % ofthe North Sea's emission of methane to the atmosphere.The advective methane transport induced by watercirculation was assessed for May 16, 1994, using a 3-DNorth Sea circulation model. For the period of thissurvey, the North Sea's source strength foratmospheric methane is estimated using in situwind velocities. In comparison to the advectivetransport by the water circulation, the gas flux tothe atmosphere appears to be the dominant sink ofNorth Sea methane. This flux is estimated to bebetween 1500 · 106 mol a-1 and 3100 ·106mol a-1, depending on the relationbetween wind speed and gas transfer velocity.     

Seasonal Variability of Adsorption and Exchange Equilibria in Soil Waters

Chemical analyses for major ions have been conducted on waters,collected on an approximately weekly basis over the period April, 1993 toNovember, 1996, that drain three small experimental ecosystems(sandboxes) at Hubbard Brook, New Hampshire. One sandbox is planted withpine trees, another with grass, and the third is left bare (actually itis covered sporadically by bryophytes and lichens). Results show linearcorrelations, independent of discharge, between the concentrations ofdissolved Na⁺ and K⁺ on the one hand andCa⁺⁺ and Mg⁺⁺ on the other for all threesandboxes. No correlations between singly charged and doubly chargedcations were found. These correlations are interpreted to represent cationexchange equilibria between soil waters and clay minerals plus soil organicmatter. The correlation slope, representing the exchange constant, for Na vsK is different for the pine-covered sandbox than for the other two whereasfor Ca vs Mg the correlation is independent of the presence or absence oftrees. We interpret this as representing a shift of cation exchangeequilibria in the pine sandbox by the activities of growing trees.Concentrations of Na, K, Ca, Mg, and H₄SiO₄from the barren and grass-lined sandboxes were found to vary seasonally witha marked sinusoidal pattern which was independent of the discharge from eachsandbox. (The discernment of a similar pattern in the tree lined sandbox wasdifficult due to a lack of discharge over much of the year.) Concentrationmaxima occurred in August and minima in February, and there is a closeparallelism with soil temperature. We interpret this as representingtemperature induced variations in cation exchange equilibria and silicaadsorption. Independence from highly varying water discharge, e.g.,. thataccompanying severe rainstorms, indicates rapidly re-attained equilibrium.Variations in the concentrations of cations are likely due to exchange withunmeasured cations, probably H⁺ or dissolved Al species, as aresult of possible seasonal changes in internal acid production and externalinput of acid rain to the sandboxes. Internal production may represent aresponse to seasonal changes in respiration rate as it responds toseasonally varying temperature. Added to this is the effect of temperatureon exchange equilibrium. Seasonal variations in dissolved silica are mostlikely due to the dependence of adsorption/desorption equilibria ontemperature. The temperature dependence of a number of silica-consumingreactions are consistent with the measured values.     

格陵兰海海冰外缘线变化特征分析

格陵兰海作为北冰洋的边缘海之一,容纳了北极输出的海冰,其海冰外缘线的变化既受北极海冰输出量的影响,也受局地海冰融化和冻结过程的影响。利用2003年1月到2011年6月AMSR-E卫星亮温数据反演的海冰密集度产品,对格陵兰海海冰外缘线的变化特征进行了分析。结果表明,格陵兰海海冰外缘线不仅存在一年的变化周期,还存在比较显著的半年变化周期,与海冰在春秋两季向岸收缩有关。格陵兰海冬季的海冰外缘线极大值呈逐年下降的趋势,体现了北极增暖导致的冬季海冰范围减小;而夏季海冰外缘线离岸距离的极小值呈上升趋势,表明夏季来自北冰洋的海冰输出量增大。2003—2004年是格陵兰海夏季海冰融化最严重的2年。2007年北冰洋夏季海冰覆盖范围达到历史最小;而格陵兰海夏季的最小海冰范围最大,表明2007年北冰洋海冰的输出量大于其他年份。此外,夏季格陵兰岛冰雪融化形成的地表径流对海冰外缘线有一定的影响。对海冰外缘线影响最大的不是格陵兰海的局地风场,而是弗拉姆海峡(Fram Strait)区域的经向风,它直接驱动了北冰洋海冰向格陵兰海的输运,进而对格陵兰海海冰外缘线的分布产生滞后的影响。     

Numerical Modeling of the Long-Term Transport, Dispersion, and Accumulation of Black Sea Pollutants into the North Aegean Coastal Waters

This study investigates the long-term capacity of the North Aegean coastal systems to transport and store conservative pollutants that originate from the Black Sea. Emphasis is placed on modeling the dispersion and accumulation of a passive tracer that represents a Black Sea pollutant (BSP) substance that continuously discharges from the Dardanelles exit into the North Aegean, for a long period of time (16?years). The effects of the Black Sea water (BSW) inflows, meteorological forcing, and seasonal stratification are assessed with a 3D hydrodynamic model (Estuary, Lake and Coastal Ocean Model), after validation with available field data. The salinity, water temperature, and discharge from the Dardanelles Strait are taken to be seasonally varied. According to the authors' best knowledge, the present paper constitutes the first numerical modeling attempt in the literature that apart from the long-term hydrodynamic characteristics that have also been studied in previous works, a suitable tracer is introduced in order to predict the long-term fate, distribution, and accumulation of pollutants that originate from the Black Sea into the North Aegean coastal regions. The overall results of the present investigation indicate that the BSP concentration is very high at the coastal waters of Thassos, Samothraki, and Limnos islands, as well as along the mainland coastal waters between Alexandroupolis and Strymonikos Gulf, during summer and autumn when strong water column stratification occurs. In general, the BSP concentration in the North Aegean surface waters reaches considerable high values (47?C58?% of the initial pollutant concentration at Dardanelles inflow) within 16?years. Even for depths more than 500?m the BSP concentration is still remarkable, slightly increasing with time. The increase of the BSP concentration with respect to time at various depths (from free surface up to 750?m) is also investigated.     

The Structure and Long-Term Variability of the Bottom Layer in the Irminger Sea

This paper shows the important role that circulation can play in the long-term variability of thermohaline properties of the bottom layer in the Irminger Sea, and the increase in salinity in the 21st century in spite of intense ice melting in the Arctic and freshening of the upper and intermediate layers that started over the last 5–7 years in the North Atlantic.     

Variscan orogeny in the Black Sea region

International Journal of Earth Sciences - Two Gondwana-derived Paleozoic belts rim the Archean/Paleoproterozoic nucleus of the East European Platform in the Black Sea region. In the north is a belt...     

Sulfur speciation in the upper Black Sea sediments

We report solid phase sulfur speciation of six cores from sediments underlying oxic, suboxic and anoxic-sulfidic waters of the Black Sea. Our dataset includes the five sulfur species [pyrite-sulfur, acid volatile sulfides (AVS), zerovalent sulfur (S(0)), organic polysulfides (RS_x), humic sulfur] together with reactive iron and manganese, as quantified by dithionite extraction, and total organic carbon. Pyrite – sulfur was the major phase in all cores [200-400 µmol (g dry wt)^- 1] except for the suboxic core. However, zerovalent sulfur and humic sulfur also reached very significant levels: up to about 109 and 80 µmol (g dry wt)^- 1, respectively. Humic sulfur enrichment was observed in the surface fluff layers of the eastern central basin sediments where Unit-1 type depositional conditions prevail. Elemental sulfur accumulated as a result of porewater sulfide oxidation by reactive iron oxides in turbidities from the anoxic basin margin and western central basin sediments. The accumulation of elemental sulfur to a level close to that of pyrite-S in any part of central Black Sea sediments has never been reported before and our finding indicates deep basin turbidites prevent the build-up of dissolved sulfide in the sediment. This process also contributes to diagenetic pyrite formation whereas in the non-turbiditic parts of the deep basin water column formed (syngenetic) pyrite dominates the sulfur inventory. In slope sediments under suboxic waters, organic sulfur (humic sulfur + organic polysulfides) account for 33-42% of total solid phase S, indicating that the suboxic conditions favor organosulfur formation. Our study shows that the interactions between depositional patterns (Unit 1 vs. turbidite), redox state of overlying waters (oxic-suboxic-sulfidic) and organic matter content determine sulfur speciation and enable the accumulation of elemental sulfur and organic sulfur species close to a level of pyrite-S.     

Seasonal and Interannual Variability of Phytoplankton in the Black Sea on the Basis of Remote Sensing Data and In Situ Measurements of Chlorophyll-a

Doklady Earth Sciences - The patterns of the seasonal and interannual variability in the development of phytoplankton, including coccolithophores, were studied in the northeastern part of the Black...     

The sedimentation model of the Tuapse Trough (Black Sea)

Based on the new 2D and 3D seismic data from the Tuapse Trough (Black Sea), the principle peculiarities of sedimentation have been studied in detail. A sedimentation model of the focused Maikop and Karagan-Chokrak intervals of the geological section has been suggested. A system of fan complexes referred to Maikop age has been found.     

Atmospheric circulation and storm events in the Black Sea and Caspian Sea

Extreme sea storms are dangerous and a potential source of damage. In this study, we examine storm events in the Black Sea and Caspian Sea, the atmosphere circulation patterns associated with the sea storm events, and their changes in the present (1961–2000) and future (2046–2065) climates. A calendar of storms for the present climate is derived from results of wave model SWAN (Simulating WAves Nearshore) experiments. On the basis of this calendar, a catalog of atmospheric sea level pressure (SLP) fields was prepared from the NCEP/NCAR reanalysis dataset for 1961–2000. The SLP fields were subjected to a pattern recognition algorithm which employed empirical orthogonal decomposition followed by cluster analysis. The NCEP/NCAR reanalysis data is used to evaluate the occurring circulation types (CTs) within the ECHAM5-MPI/OM Atmosphere and Ocean Global Circulation Model (AOGCM) for the period 1961–2000. Our analysis shows that the ECHAM5-MPI/OM model is capable of reproducing circulation patterns for the storm events. The occurrence of present and future ECHAM5-MPI/OM CTs is investigated. It is shown that storm CTs are expected to occur noticeably less frequently in the middle of the 21^st century.     

Internal Waves of Mode 2 in the Black Sea

Doklady Earth Sciences - The results of the first observations of mode 2 internal waves in the Black Sea are presented. The measurements were carried out on the Crimean shelf from the MGI platform...     

Vertical Mixing in the Active Layer of the Black Sea

The averaged parameters of vertical turbulent mixing in the active layer of the Black Sea are discussed according to small-scale synchronous measurements of the profiles of current velocity and conditional density.