Cyanopolyynes in hot cores: modelling G305.2+0.2

We present results from a time-dependent gas-phase chemical model of a hot core based on the physical conditions of G305.2+0.2. While the cyanopolyyne HC₃N has been observed in hot cores, the longer chained species, HC₅N, HC₇N and HC₉N, have not been considered as the typical hot-core species. We present results which show that these species can be formed under hot core conditions. We discuss the important chemical reactions in this process and, in particular, show that their abundances are linked to the parent species acetylene which is evaporated from icy grain mantles. The cyanopolyynes show promise as 'chemical clocks' which may aid future observations in determining the age of hot core sources. The abundance of the larger cyanopolyynes increases and decreases over relatively short time-scales,  ∼10^2.5 yr  . We present results from a non-local thermodynamic equilibrium statistical equilibrium excitation model as a series of density, temperature and column density dependent contour plots which show both the line intensities and several line ratios. These aid in the interpretation of spectral-line data, even when there is limited line information available. In particular, non-detections of HC₅N and HC₇N in Walsh et al. are analysed and discussed.     

The chemistry of transient dense cores

We investigate the chemistry of a transient density fluctuation, with properties similar to those of a dense core within a molecular cloud. We run a multipoint chemical code through a core's condensation from a diffuse medium to its eventual dispersion, over a period of ∼1 Myr. We find a significant enhancement of the chemical composition of the core material on its return to diffuse conditions, whilst the expansion of the core as it disperses moves this material out to large distances from the core centre. This process transports molecular species formed in the high-density regions out into the diffuse medium. Chemical enrichment of the cloud as a whole also occurs, as other cores of various sizes, life-spans and separations evolve throughout. Enrichment is strongly affected by freeze-out on to dust grains, which takes place in high-density, high visual extinction regions. As the core disperses after reaching its peak density and the visual extinction drops below a critical value, grain mantles are evaporated back into the gas phase, initiating more chemistry. The influence of the sizes, masses and cycle periods of cores will be large both for the level of chemical enrichment of a dark cloud and ultimately for the low-mass star formation rate. We also consider the case of a self-gravitating core, by holding its peak density conditions for a further 0.4 Myr. We find that the differences are generally small, and the resultant column densities do not provide definitive criteria for detection of this condition. However, increases in fractional abundances due to reinjection of mantle-borne species may provide a criterion for a negative detection.     

New models of interstellar gas–grain chemistry – II. Surface photochemistry in quiescent cores

The photodissociation of surface species, caused by photons from the cosmic-ray-induced and background interstellar radiation fields, is incorporated into our combined gas-phase and grain-surface chemical models of quiescent dense interstellar cores. For the cores studied here, only cosmic-ray-induced photons are important. We find that photodissociation alters gas-phase and surface abundances mainly at large cloud ages (≳ 10^6–7 yr). The abundances of those surface species, such as H₂O, that are readily reproduced on the surface following photodissociation are not strongly affected at any time. The abundances of surface species that are, on the other hand, reformed slowly via surface reactions possessing activation energy (e.g. CH₃OH) are reduced, while the abundances of associated surface photoproducts (e.g. CO) increase. In the gas phase, inclusion of surface photodissociation tends to increase molecular abundances at late times, slightly improving the agreement with observation for TMC-1.     

The initial conditions of isolated star formation – VII. Spitzer mapping of pre-stellar cores

We have retrieved Spitzer archive data of pre-stellar cores taken with the Multiband Imaging Photometer for Spitzer (MIPS) at a wavelength of 160 μm. Seventeen images, containing 18 cores, were constructed. Flux densities were measured for each core, and background estimates were made. Mean off-source backgrounds were found to be 48 ± 10 MJy sr⁻¹ in Taurus and 140 ± 55 MJy sr⁻¹ in Ophiuchus. Consistency was found between the MIPS 170-μm and ISOPHOT 160-μm calibrations. Fourteen cores were detected both by MIPS and by our previous submillimetre surveys. Spectral energy distributions were made for each core, using additional 24- and 70-μm data from the Spitzer data archive, as well as previous infrared and submillimetre data. Previous temperature estimates were refined, and new temperature estimates were made where no Infrared Space Observatory ( ISO ) data exist. A temperature range of 8–18 K was found for the cores, with most lying in the range 10–13 K. We discount recent claims that a large number of pre-stellar cores may have been misclassified and in fact contain low-luminosity protostars detectable only by Spitzer . We find no new protostars in our sample other than that previously reported in L1521F. It is shown that this has a negligible effect on pre-stellar lifetime estimates.     

Observational characteristics of dense cores with deeply embedded young protostars

Class 0 objects, which are thought to be the youngest protostars, are identified in terms of NIR or radio emission and/or the presence of molecular outflows. We present combined hydrodynamic and radiative transfer simulations of the collapse of a star‐forming molecular core, which suggest two criteria for identifying dense cores with deeply embedded very young protostars that may not be observable in the NIR or radio with current telescopes. We find that cores with protostars are relatively warm (T > 15 K) with their SEDs peaking at wavelengths <170 µm, and they tend to appear circular. (© 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Desorption from interstellar ices

The desorption of molecular species from ice mantles back into the gas phase in molecular clouds results from a variety of very poorly understood processes. We have investigated three mechanisms: desorption resulting from H₂ formation on grains, direct cosmic ray heating and cosmic ray-induced photodesorption. Whilst qualitative differences exist between these processes (essentially deriving from the assumptions concerning the species selectivity of the desorption and the assumed threshold adsorption energies, E _t), all the three processes are found to be potentially very significant in dark cloud conditions. It is therefore important that all three mechanisms should be considered in studies of molecular clouds in which freeze-out and desorption are believed to be important.
Employing a chemical model of a typical static molecular core and using likely estimates for the quantum yields of the three processes, we find that desorption by H₂ formation probably dominates over the other two mechanisms. However, the physics of the desorption processes and the nature of the dust grains and ice mantles are very poorly constrained. We therefore conclude that the best approach is to set empirical constraints on the desorption, based on observed molecular depletions – rather than try to establish the desorption efficiencies from purely theoretical considerations. Applying this method to one such object (L16 89B) yields upper limits to the desorption efficiencies that are consistent with our understanding of these mechanisms.     

Limited diversity of the interstellar extinction law

We have applied the method of investigating extinction curves using statistically meaningful samples that was proposed by us 25 years ago. The extensive data sets of the ANS (Astronomical Netherlands Satellite) and 2MASS (Two Micron All Sky Survey) were used, together with UBV photometry to create average extinction curves for samples of OB stars. Our results demonstrate that in the vast majority of cases the extinction curves are very close to the mean galactic extinction curve. Only a few objects were found to be obviously discrepant from the average. The latter phenomenon may be related to nitrogen chemistry in translucent interstellar clouds (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Gas cooling by dust during dynamical fragmentation

We suggest that the abrupt switch, from hierarchical clustering on scales ≳ 0.04 pc, to binary (and occasionally higher multiple) systems on smaller scales, which Larson has deduced from his analysis of the grouping of pre-main-sequence stars in Taurus, arises because pre-protostellar gas becomes thermally coupled to dust at sufficiently high densities. The resulting change — from gas cooling by molecular lines at low densities to gas cooling by dust at high densities — enables the matter to radiate much more efficiently, and hence to undergo dynamical fragmentation. We derive the domain in which gas cooling by dust facilitates dynamical fragmentation. Low-mass (∼ M⊙) clumps — those supported mainly by thermal pressure — can probably access this domain spontaneously, albeit rather quasi-statically, provided that they exist in a region in which external perturbations are few and far between. More massive clumps probably require an impulsive external perturbation, for instance a supersonic collision with another clump, in order for the gas to reach sufficiently high density to couple thermally to the dust. Impulsive external perturbations should promote fragmentation, by generating highly non-linear substructures which can then be amplified by gravity during the subsequent collapse.     

Submillimetre continuum observations of pre-protostellar cores

Results are outlined of a JCMT submillimetre continuum survey of Myers cores that have no known infrared associations - the so-called starless cores. Detailed parameters are calculated, such as temperature, mass, luminosity and radial density dependence. On the basis of lifetime and luminosity arguments, the cores are found to be pre-protostellar in nature, undergoing the ambipolar diffusion phase prior to protostellar collapse. The cores do not follow the r^–2 density dependence predicted by the standard model, but are consistent with a recent model of magnetic support of cloud cores.     

Photometric distances to nine dark globules

Distances to nine dark globules are determined by a method using optical ( VRI ) and near-infrared (near-IR) ( JHK ) photometry of stars projected towards the field containing the globules. In this method, we compute intrinsic colour indices of stars projected towards the direction of the globule by dereddening the observed colour indices using various trial values of extinction   A _V   and a standard extinction law. These computed intrinsic colour indices for each star are then compared with the intrinsic colour indices of normal main-sequence stars and a spectral type is assigned to the star for which the computed colour indices best match with the standard intrinsic colour indices. Distances ( d ) to the stars are determined using the   A _V   and absolute magnitude  ( M_V )  corresponding to the spectral types thus obtained. A distance versus extinction plot is made and the distance at which   A _V   undergoes a sharp rise is taken to be the distance to the globule. All the clouds studied in this work are in the distance range 160–400 pc. The estimated distances to dark globules LDN 544, LDN 549, LDN 567, LDN 543, LDN 1113, LDN 1031, LDN 1225, LDN 1252 and LDN 1257 are  180 ± 35, 200 ± 40, 180 ± 35, 160 ± 30, 350 ± 70, 200 ± 40, 400 ± 80, 250 ± 50  and 250 ± 50 pc, respectively. Using the distances determined, we have estimated the masses of the globules and the far-IR luminosity of the IRAS sources associated with them. The mass of the clouds studied are in the range  10–200 M_⊙  .