The constancy of galactic cosmic rays as recorded by cosmogenic nuclides in iron meteorites

We measured the He, Ne, and Ar isotopic concentrations and the ¹⁰Be, ²⁶Al, ³⁶Cl, and ⁴¹Ca concentrations in 56 iron meteorites of groups IIIAB, IIAB, IVA, IC, IIA, IIB, and one ungrouped. From ⁴¹Ca and ³⁶Cl data, we calculated terrestrial ages indistinguishable from zero for six samples, indicating recent falls, up to 562 ± 86 ka. Three of the studied meteorites are falls. The data for the other 47 irons confirm that terrestrial ages for iron meteorites can be as long as a few hundred thousand years even in relatively humid conditions. The ³⁶Cl‐³⁶Ar cosmic ray exposure (CRE) ages range from 4.3 ± 0.4 Ma to 652 ± 99 Ma. By including literature data, we established a consistent and reliable CRE age database for 67 iron meteorites. The high quality of the CRE ages enables us to study structures in the CRE age histogram more reliably. At first sight, the CRE age histogram shows peaks at about 400 and 630 Ma. After correction for pairing, the updated CRE age histogram comprises 41 individual samples and shows no indications of temporal periodicity, especially not if one considers each iron meteorite group separately. Our study contradicts the hypothesis of periodic GCR intensity variations (Shaviv 2002, 2003), confirming other studies indicating that there are no periodic structures in the CRE age histogram (e.g., Rahmstorf et al. 2004; Jahnke 2005). The data contradict the hypothesis that periodic GCR intensity variations might have triggered periodic Earth climate changes. The ³⁶Cl‐³⁶Ar CRE ages are on average 40% lower than the ⁴¹K‐K CRE ages (e.g., Voshage 1967). This offset can either be due to an offset in the ⁴¹K‐K dating system or due to a significantly lower GCR intensity in the time interval 195–656 Ma compared to the recent past. A 40% lower GCR intensity, however, would have increased the Earth temperature by up to 2 °C, which seems unrealistic and leaves an ill‐defined ⁴¹K‐K CRE age system the most likely explanation. Finally, we present new ²⁶Al/²¹Ne and ¹⁰Be/²¹Ne production rate ratios of 0.32 ± 0.01 and 0.44 ± 0.03, respectively.     

Monte Carlo simulation of GCR neutron capture production of cosmogenic nuclides in stony meteorites and lunar surface

Abstract— A purely physical model based on a Monte Carlo simulation of galactic cosmic ray (GCR) particle interaction with meteoroids is used to investigate neutron interactions down to thermal energies. Experimental and/or evaluated excitation functions are used to calculate neutron capture production rates as a function of the size of the meteoroid and the depth below its surface. Presented are the depth profiles of cosmogenic radionuclides ³⁶Cl, ⁴¹Ca, ⁶⁰Co, ⁵⁹Ni, and ¹²⁹I for meteoroid radii from 10 cm up to 500 cm and a 2π irradiation. Effects of bulk chemical composition on n‐capture processes are studied and discussed for various chondritic and lunar compositions. The mean GCR particle flux over the last 300 ka was determined from the comparison of simulations with measured ⁴¹Ca activities in the Apollo 15 drill core. The determined value significantly differs from that obtained using equivalent models of spallation residue production.     

Accelerator mass spectrometry measurements and model calculations of iron-60 production rates in meteorites

Abstract— The cosmogenic radionuclide ⁶⁰Fe (T_1/2 = 1.49 Ma) was measured in two iron meteorites as well as in the magnetic fractions of a stony-iron and a stony meteorite by means of accelerator mass spectrometry (AMS). The measured ⁶⁰Fe/Fe ratios range from 1.5 × 10-¹⁴ to 6.3 × 10-¹⁴ and show a significant correlation to the respective concentrations of Ni, which is the main target element. The resulting ⁶⁰Fe specific activities correspond to production rates in meteorites in the order of 1 dpm/kg Ni. In addition, model calculations of depth- and size-dependent ⁶⁰Fe production rates were performed. Although there are no experimental data for the production cross sections, our measurements are in surprisingly good agreement with the theoretical predictions using production cross sections that were determined by computer model calculations.     

On the production of cosmogenic nuclides in meteoroids by galactic protons

Abstract— A purely physical model is presented describing the depth- and size-dependence of the production of cosmogenic nuclides in meteoroids with radii up to 85 cm and in planetary surfaces by galactic cosmic ray protons. The model is based on Monte Carlo calculations of the intra- and internuclear cascades, by which depth- and size-dependent spectra of primary and secondary protons and of secondary neutrons are derived, and on experimental and theoretical thin-target cross sections of the underlying nuclear reactions. Model calculations are presented for production rates of ⁵³Mn, ²⁶Al, ²²Ne, and ²¹Ne in H- and L-chondrites and of ⁵³Mn and ²⁶Al in lunar surface material and compared with experimental data. From the analysis of ⁵³Mn and ²⁶Al in the Apollo 15 lunar drill core and in the L-chondrite Knyahinya GCR p-spectra and integral particle fluxes at 1 A.U. and in the meteoroid orbits averaged over the last 10 Ma are derived. An analysis of experimental depth profiles in four H- and L-chondrites demonstrates, that the new model is well capable of describing depth- and size-dependences of production rates of cosmogenic nuclides. Moreover, it is possible to determine exposure ages for these meteorites on the basis of the theoretical ²¹Ne production rates. The model calculations further explain the depth- and size-dependence of ²²Ne/²¹Ne-ratios and the dependences on these ratios of ²¹Ne, ²⁶Al and ⁵³Mn production rates. The future requirements for model calculations of cosmogenic nuclide production rates in extraterrestrial matter are outlined.     

Cosmogenic nuclides in stony meteorites revisited

Abstract— We present new model calculations for depth and size dependent cosmogenic production rates in ordinary and carbonaceous chondrites by galactic cosmic rays. This model, essentially that of Leya et al. (2000a), folds together particle spectra and cross sections for the relevant nuclear reactions, but has been significantly improved due to major improvements in the neutron cross section database and better Monte Carlo modeling of the primary and the secondary particle spectra. The data presented here replace (and extend) the results of our earlier model predictions. Here we give for ordinary and carbonaceous chondrites elemental production rates for the cosmogenic radionuclides 10Be, 14C, 26Al, 36Cl, 41Ca, 53Mn, 60Fe, and 129I as well as for the noble gas isotopes 3He, 4He, 20Ne, 21Ne, 22Ne, 36Ar, and 38Ar. Using the new data and expressing size and depth scales to the unit [g/cm2], we are able to demonstrate that the matrix effect for both chondrite types is negligible for all target product combinations, except for those which are dominated by thermal or very low energy neutron reactions. Based on the new model predictions, we present a variety of elemental and isotopic production rate ratios allowing for a reliable determination of preatmospheric sizes, shielding depths, cosmic‐ray exposure ages, and diffusive losses.     

Metallographic cooling rates of group IIF iron meteorites

Abstract— Metallographic cooling rates have been calculated for all five members of the iron meteorites group IIF using two different techniques. We have determined cooling rates of ～5 °C/Ma based on Ni profiles through the taenite rim enclosing kamacite spindles. Ni profiles through the kamacite phase are less precise cooling rate indicators, but suggest a cooling rate of ～1 °C/Ma within an order of magnitude at lower temperatures (360–400 °C). Based on the kamacite bandwidth and the Ni profiles through the taenite, we estimate that the kamacite nucleated 130–200 °C below the temperature predicted from the phase diagram. The size of and the distance between the large kamacite spindles is found to be consistent with the thermal history that we have determined on the basis of Ni profiles in kamacite and taenite. We find that previously published kamacite bandwidth cooling rates for the five group IIF members are most likely in error because of the presence of large schreibersite spindles in some kamacite spindles and because undercooling of kamacite was ignored. Contrary to previous workers we find that the metallographic cooling rates are consistent with cooling in a common core.     

The production of cosmogenic nuclides in stony meteoroids by galactic cosmic‐ray particles

Abstract— We present a purely physical model for the calculation of depth‐ and size‐dependent production rates of cosmogenic nuclides by galactic cosmic‐ray (GCR) particles. besides the spectra of primary and secondary particles and the excitation functions of the underlying nuclear reactions, the model is based on only one free parameter—the integral number of gcr particles in the meteoroid orbits. We derived this value from analysis of radionuclide data in Knyahinya. We also show that the mean GCR proton spectrum in the meteoroid orbits has been constant over about the last 10 Ma. For the major target elements in stony meteoroids, we present depth‐ and size‐dependent production rates for ¹⁰Be, ¹⁴C, ²⁶Al, ³⁶Cl, and ⁵³Mn as well as for the rare gas isotopes ³He, ²⁰Ne, ²¹Ne, ²²Ne, ³⁶Ar, and ³⁸Ar. The new data differ from semi‐empirical estimates by up to a factor of 4 but agree within ～20% with results obtained by earlier parametric or physical approaches. The depth and size dependence of the shielding parameter ²²Ne/²¹Ne and the correlations ²⁶Al vs. ¹⁰Be, ²⁶Al vs. ⁵³Mn, ¹⁰Be/²¹Ne vs. ²²Ne/²¹Ne, and ³⁶Ar vs. ³⁶Cl for deciphering preatmospheric sizes, shielding depths, terrestrial residence times, and exposure histories are also discussed.     

The effects of impacts on the cooling rates of iron meteorites

Iron meteorites provide a record of the thermal evolution of their parent bodies, with cooling rates inferred from the structures observed in the Widmanstätten pattern. Traditional planetesimal thermal models suggest that meteorite samples derived from the same iron core would have identical cooling rates, possibly providing constraints on the sizes and structures of their parent bodies. However, some meteorite groups exhibit a range of cooling rates or point to uncomfortably small parent bodies whose survival is difficult to reconcile with dynamical models. Together, these suggest that some meteorites are indicating a more complicated origin. To date, thermal models have largely ignored the effects that impacts would have on the thermal evolution of the iron meteorite parent bodies. Here we report numerical simulations investigating the effects that impacts at different times have on cooling rates of cores of differentiated planetesimals. We find that impacts that occur when the core is near or above its solidus, but the mantle has largely crystallized can expose iron near the surface of the body, leading to rapid and nonuniform cooling. The time period when a planetesimal can be affected in this way can range between 20 and 70 Myr after formation for a typical 100 km radius planetesimal. Collisions during this time would have been common, and thus played an important role in shaping the properties of iron meteorites.     

Calibrating a physical model based on Geant4 to calculate cosmogenic nuclide production rates on lunar surface

A physical model based on the open‐source toolkit Geant4 for production rates of cosmogenic nuclei on the lunar surface is proposed and calibrated. The fluxes of proton and neutron beneath the lunar surface are obtained by simulating the physical processes between the cosmic‐ray particles and the lunar surface material. By combining the experimental proton cross sections and the a posteriori neutron cross sections, we calculate the production rate depth profiles of long‐lived nuclei (¹⁰Be, ¹⁴C, ²⁶Al, ³⁶Cl, and ⁵³Mn). Through comparing experimental and theoretical data for these nuclei, we find that for all the selected nuclei, experimental and theoretical production rate depth profiles agree well with each other by introducing a single normalization factor. It means that the physical model based on Geant4 can also reproduce the depth profiles of cosmogenic nuclei, and that this model can be used by everyone worldwide. In addition, we predict the production rates of three stable nuclei (²¹Ne, ²²Ne, and ³⁸Ar).     

The production of cosmogenic nuclides by galactic cosmic‐ray particles for 2π exposure geometries

Abstract— We present a purely physical model for the calculation of depth‐dependent production rates in 2π exposure geometries by galactic cosmic rays (GCR). Besides the spectra of primary and secondary particles and the excitation functions of the underlying nuclear reactions, the model is based on the integral number of GCR particles in the lunar orbit. We derived this value from adjusting modeled depth profiles for ¹⁰Be, ²⁶Al, and ⁵³Mn to measured data from the Apollo 15 drill core. The J_0,GCR value of 4.54 cm^?2 s^?1 and the solar modulation parameter of M = 490 MeV determined this way for 1 AU is in reasonable agreement with the J_0,GCR value derived recently for the meteoroid orbits (Leya et al., 2000b). We also show that the mean GCR proton spectrum in the lunar orbit has not changed substantially over about the last 10 Ma. For the major target elements we present depth‐dependent production rates for ¹⁰Be, ¹⁴C, ²⁶Al, ³⁶Cl and ⁵³Mn, as well as for the rare gas isotopes ^20,21,22Ne. In addition we present production rates for ^36,38Ar from Fe and Ni. The new results are consistent with the data for stony meteoroids presented recently by our group (Leya et al., 2000b), but for the rare gas isotopes the new production rates sometimes differ significantly from earlier estimates. The applicability of the ²²Ne/²¹Ne ratio as a shielding parameter is also discussed.     

Isotopic composition of trapped and cosmogenic noble gases in several Martian meteorites

Abstract— Isotopic abundances of the noble gases were measured in the following Martian meteorites: two shock glass inclusions from Elephant Moraine (EET) 79001, shock vein glass from Shergotty and Yamato (Y) 793605, and whole-rock samples of Allan Hills (ALH) 84001 and Queen Alexandra Range (QUE) 94201. These glass samples, when combined with literature data on a separate single glass inclusion from EET 79001 and a glass vein from Zagami, permit examination in greater detail of the isotopic composition of Ne, Ar, Kr, and Xe trapped from the Martian atmosphere. The isotopic composition of Martian Ne, if actually present in these glasses, remains poorly defined. The ⁴⁰Ar/³⁶Ar ratio of trapped Martian atmospheric Ar is probably considerably lower than the nominal ratio of 3000 measured by Viking, and data on impact glasses suggest a value of ～1900. The atmospheric ³⁶Ar/³⁸Ar ratio is ≤4.0. Martian atmospheric Kr may be enriched in lighter isotopes by ～0.5%/amu compared to both solar-wind Kr and to the Martian composition previously reported. The isotopic composition of Xe in these glasses agrees with that previously reported in the literature. The Martian atmospheric ³⁶Ar/¹³²Xe and ⁸⁴Kr/¹³²Xe elemental ratios are higher than those reported by Viking by factors of ～2.5–1.6 (depending on the ⁴⁰Ar/³⁶Ar ratio adopted) and ～1.8, respectively, and are discussed in a separate paper. Cosmogenic gases indicate space exposure ages of 2.7 ± 0.6 Ma for QUE 94201 and Shergotty and 14 ± 1 Ma for ALH 84001. Small amounts of ²¹Ne produced by energetic solar protons may be present in QUE 94201 but are not present in ALH 84001 or Y-793605. The space exposure age for Y-793605 is 4.9 ± 0.6 Ma and appears to be distinctly older than the ages for basaltic shergottites. However, uncertainties in cosmogenic production rates still makes somewhat uncertain the number of Martian impact events required to produce the exposure ages of Martian meteorites.     

Effects of solar activity on production rates of short‐lived cosmogenic radionuclides

The solar activity can be quantified by solar modulation parameter Φ that affects the heliospheric magnetic field. This activity influences the intensity of the galactic cosmic ray (GCR) particle flux within the solar system, and consequently, the differential primary particle spectra depend on the solar modulation parameter Φ (MeV). The modulation parameter Φ shows spatial and temporal variations (Leya and Masarik 2009). Some of the solar activity variations are cyclic and result in measurable effects as for example the 11‐year solar cycle. Variations in solar activity only induce small effects on the production of long‐lived cosmogenic radionuclides. This is due to the fact that activities measured in meteorites usually correspond to saturation values and represent long‐term average values. Long‐lived radionuclides often require millions of years of irradiation by GCR to reach saturation and therefore activity cycles average out. In contrast, one can expect strongly pronounced variations for saturation values caused by primary flux intensity variations, if short‐lived radionuclides with half‐lives ranging from days to a few years are investigated. Short‐lived cosmogenic nuclides were the subject of many experimental and theoretical investigations (e.g., Evans et al. 1982; Spergel et al. 1986; Neumann et al. 1997; Komura et al. 2002; Laubenstein et al. 2012). The aim of this work is to develop formulae for calculating production rates of radionuclides with short half‐life, taking into account temporal variations in the primary cosmic ray intensity. The developed formulae were applied to the Kosice and Chelyabinsk meteorites. The results for the Ko?ice meteorite were already published (Povinec et al. 2015). Here, we give a full explanation of underlying model.     

53Mn and 60Fe in iron meteorites—New data,model calculations

We measured specific activities of the long‐lived cosmogenic radionuclides ⁶⁰Fe in 28 iron meteorites and ⁵³Mn in 41 iron meteorites. Accelerator mass spectrometry was applied at the 14 MV Heavy Ion Accelerator Facility at ANU Canberra for all samples except for two which were measured at the Maier‐Leibnitz Laboratory, Munich. For the large iron meteorite Twannberg (IIG), we measured six samples for ⁵³Mn. This work doubles the number of existing individual ⁶⁰Fe data and quadruples the number of iron meteorites studied for ⁶⁰Fe. We also significantly extended the entire ⁵³Mn database for iron meteorites. The ⁵³Mn data for the iron meteorite Twannberg vary by more than a factor of 30, indicating a significant shielding dependency. In addition, we performed new model calculations for the production of ⁶⁰Fe and ⁵³Mn in iron meteorites. While the new model is based on the same particle spectra as the earlier model, we no longer use experimental cross sections but instead use cross sections that were calculated using the latest version of the nuclear model code INCL. The new model predictions differ substantially from results obtained with the previous model. Predictions for the ⁶⁰Fe activity concentrations are about a factor of 2 higher, for ⁵³Mn, they are ~30% lower, compared to the earlier model, which gives now a better agreement with the experimental data.     

The phosphates of IIIAB iron meteorites

Abstract— Thirteen phosphate minerals are found in IIIAB iron meteorites. Four of these (sarcopside, graftonite, johnsomervilleite, and galileiite) constitute the majority of occurrences. The IIIB iron meteorites are confined to occurrences of only these four phosphates. The IIIA iron meteorites may contain one or more of these four phases; they may also contain other rarer phosphates, and silica (in two instances) and a silicate rock (in one instance). Thus, the IIIA lithophile chemistry is more varied than that of the IIIB meteorites. Based on petrographic relations, sarcopside appears to be the first phosphate to form. Graftonite is probably formed by recrystallization of sarcopside. Johnsomervilleite and galileiite exsolved as enclaves in sarcopside or graftonite at lower temperatures, although some of these also nucleated as separate crystals. The IIIAB phosphates are carriers of a group of incompatible lithophile elements: Fe, Mn, Na, Ca, and K, and, rarely, Mg as well as Pb. These elements (and O) were concentrated in a residual, S-rich liquid during igneous fractional crystallization of the IIIAB core mass. The phosphates formed by oxidation of P as the core solidified and excluded O, which increased its partial pressure in the residual liquid. The trace siderophile trends in bulk IIIAB metal are paralleled by a mineralogical trend of the phosphate minerals that formed. For IIIAB meteorites with low-Ir contents in the metal, the phosphates are mainly Fe-Mn phases; at intermediate Ir values, more Na-bearing phosphates appear; at the highest Ir values, the rarer Na-, K-, Mg-, Cr-, and Pb-bearing phosphates appear. The absence of significant amounts of Mg, Si, Al, and Ti suggest depletion of these elements in the core by the overlying mantle.     

New Chilean iron meteorites: Medium octahedrites from Northern Chile are unique

Abstract— We report data on three new iron meteorites from Northern Chile and propose names. All are unnamed iron meteorites from the meteorite collection at the Universidad de La Serena. For two, the provenance is unknown; for the third, the presumed discovery site is in the countryside east of Iquique. The three meteorites have been analyzed by instrumental neutron activation analysis (INAA) and their structures examined with a binocular microscope. La Serena is a complete 663 g iron, a new member of group IIICD; it is not paired with any other iron. Elqui has a mass of 260 g; two faces are fractures, possibly produced by human actions, but fusion crust appears to be present on some of the remaining surface. It is a hexahedrite and a member of group IIAB, but its composition differs from that of all other Chilean hexahedrites. The third iron, Pozo Almonte, is a medium octahedrite member of group IIIAB, one of the most common meteorite groups. To find out whether it is paired, we assembled a full set of IIIAB iron meteorites from Northern Chile. Our compositional data show that Pozo Almonte is not paired with any other IIIAB iron, and that there are no pairings within the full set with the possible exception of Joel's Iron and Sierra Sandon, which differ only in their contents of Ir, 0.39 and 0.34 μg/g, respectively. However, Buchwald's (1975) structural observations rule out this possible pairing. We find appreciable differences in Cu, As and Au between the previously paired IIIAB irons Chañaral and Ilimaës and conclude that these should not be paired.     

The Cu isotopic composition of iron meteorites

Abstract– High‐precision Cu isotopic compositions have been measured for the metal phase of 29 iron meteorites from various groups and for four terrestrial standards. The data are reported as the δ⁶⁵Cu permil deviation of the ⁶⁵Cu/⁶³Cu ratio relative to the NIST SRM 976 standard. Terrestrial mantle rocks have a very narrow range of variations and scatter around zero. In contrast, iron meteorites show δ⁶⁵Cu approximately 2.3‰ variations. Different groups of iron meteorites have distinct δ⁶⁵Cu values. Nonmagmatic IAB‐IIICD iron meteorites have similar δ⁶⁵Cu (0.03 ± 0.08 and 0.12 ± 0.10, respectively), close to terrestrial values (approximately 0). The other group of nonmagmatic irons, IIE, is isotopically distinct (?0.69 ± 0.15). IVB is the iron meteorite group with the strongest elemental depletion in Cu and samples in this group are enriched in the lighter isotope (δ⁶⁵Cu down to ?2.26‰). Evaporation should have produced an enrichment in ⁶⁵Cu over ⁶³Cu (δ⁶⁵Cu >0) and can therefore be ruled out as a mechanism for volatile loss in IVB meteorites. In silicate‐bearing iron meteorites, Δ¹⁷O correlates with δ⁶⁵Cu. This correlation between nonmass‐dependent and mass‐dependent parameters suggests that the Cu isotopic composition of iron meteorites has not been modified by planetary differentiation to a large extent. Therefore, Cu isotopic ratios can be used to confirm genetic links. Cu isotopes thus confirm genetic relationships between groups of iron meteorites (e.g., IAB and IIICD; IIIE and IIIAB); and between iron meteorites and chondrites (e.g., IIE and H chondrites). Several genetic connections between iron meteorites groups are confirmed by Cu isotopes, (e.g., IAB and IIICD; IIIE and IIIAB); and between iron meteorites and chondrites (e.g., IIE and H chondrites).     

Variations in impact effects among IIIE iron meteorites

Group‐IIIE iron meteorites can be ordered into four categories reflecting increasing degrees of shock alteration. Weakly shocked samples (Armanty, Colonia Obrera, Coopertown, Porto Alegre, Rhine Villa, Staunton, and Tanokami Mountain) have haxonite within plessite, unrecrystallized kamacite grains containing Neumann lines or possessing the ? structure, and sulfide inclusions typically consisting of polycrystalline troilite with daubréelite exsolution lamellae. The only moderately shocked sample is NWA 4704, in which haxonite has been partially decomposed to graphite; the majority of the kamacite in NWA 4704 is recrystallized, and its sulfide inclusions were partly melted. Strongly shocked samples (Cachiyuyal, Kokstad, and Paloduro) contain graphite and no haxonite, suggesting that pre‐existing haxonite fully decomposed. Also present in these rocks are recrystallized kamacite and melted troilite. Residual heat from the impact caused annealing and recrystallization of kamacite as well as the decomposition of haxonite into graphite. Severely shocked samples (Aliskerovo and Willow Creek) have sulfide‐rich assemblages consisting of fragmental and subhedral daubréelite crystals, 1–4 vol% spidery troilite filaments, and 30–50 vol% low‐Ni kamacite grains, some of which contain up to 6.0 wt% Co; haxonite in these inclusions has fully decomposed to graphite. The wide range of impact effects in IIIE irons is attributed to one or more major collision(s) on the parent asteroid that affected different group members to different extents depending on their proximity to the impact point.     

Nitrogen components in IAB/IIICD iron meteorites

Abstract— Isotopic variations have been reported for many elements in iron meteorites, with distinct N signatures found in the metal and graphite of IAB irons. In this study, a dozen IAB/IIICD iron meteorites (see Table 1 for new classifications) were analyzed by stepwise pyrolysis to resolve nitrogen components. Although isotopic heterogeneity has been presumed to be lost in thermally processed parent objects, the high‐resolution nitrogen isotopic data indicate otherwise. At least one reservoir has a light nitrogen signature, δ¹⁵N = ?(74 ± 2)‰, at 900 °C to 1000 °C, with a possible second, even lighter, reservoir in Copiapo (δ¹⁵N ≤ ?82‰). These releases are consistent with metal nitride decomposition or low‐temperature metal phase changes. Heavier nitrogen reservoirs are observed in steps ≤700 °C and at 1200 °C to 1400 °C. The latter release has a δ¹⁵N signature with a limit of ≥?16‰. Xenon isotopic signatures are sensitive indicators for the presence of inclusions because of the very low abundances of Xe in metal. The combined high‐temperature release shows ¹³¹Xe and ¹²⁹Xe excesses to be consistent with shifts expected for Te(n,γ) reaction in troilite by epithermal neutrons, but there are also possible alterations in the isotopic ratios likely due to extinct ¹²⁹I and cosmic‐ray spallation. The IAB/IIICD iron data imply that at least one light N component survived the formation processes of iron parent objects which only partially exchanged nitrogen between phases. Preservation of separate N reservoirs conflicts with neither the model of impact‐heating effects for these meteorites nor reported age differences between metal and silicates.     

Calibration of cosmogenic noble gas production in ordinary chondrites based on 36Cl‐36Ar ages. Part 1: Refined produced rates for cosmogenic 21Ne and 38Ar

We measured the concentrations and isotopic compositions of He, Ne, and Ar in bulk samples and metal separates of 14 ordinary chondrite falls with long exposure ages and high metamorphic grades. In addition, we measured concentrations of the cosmogenic radionuclides ¹⁰Be, ²⁶Al, and ³⁶Cl in metal separates and in the nonmagnetic fractions of the selected meteorites. Using cosmogenic ³⁶Cl and ³⁶Ar measured in the metal separates, we determined ³⁶Cl‐³⁶Ar cosmic‐ray exposure (CRE) ages, which are shielding‐independent and therefore particularly reliable. Using the cosmogenic noble gases and radionuclides, we are able to decipher the CRE history for the studied objects. Based on the correlation ³He/²¹Ne versus ²²Ne/²¹Ne, we demonstrate that, among the meteorites studied, only one suffered significant diffusive losses (about 35%). The data confirm that the linear correlation ³He/²¹Ne versus ²²Ne/²¹Ne breaks down at high shielding. Using ³⁶Cl‐³⁶Ar exposure ages and measured noble gas concentrations, we determine ²¹Ne and ³⁸Ar production rates as a function of ²²Ne/²¹Ne. The new data agree with recent model calculations for the relationship between ²¹Ne and ³⁸Ar production rates and the ²²Ne/²¹Ne ratio, which does not always provide unique shielding information. Based on the model calculations, we determine a new correlation line for ²¹Ne and ³⁸Ar production rates as a function of the shielding indicator ²²Ne/²¹Ne for H, L, and LL chondrites with preatmospheric radii less than about 65 cm. We also calculated the ¹⁰Be/²¹Ne and ²⁶Al/²¹Ne production rate ratios for the investigated samples, which show good agreement with recent model calculations.     

Light noble gases and cosmogenic radionuclides in Estherville,Budulan, and other mesosiderites: Implications for exposure histories and production rates

Abstract— We report measurements of ²⁶AI, ¹⁰Be, ⁴¹Ca, and ³⁶Cl in the silicate and metal phases of 11 mesosiderites, including several specimens each of Budulan and Estherville, of the brecciated meteorite Bencubbin, and of the iron meteorite Udei Station. Average production rate ratios (atom/atom) for metal phase samples from Estherville and Budulan are ²⁶Al/¹⁰Be = 0.77 ± 0.02; ³⁶Cl/¹⁰Be = 5.3 ± 0.2. For a larger set of meteorites that includes iron meteorites and other mesosiderites, we find ²⁶Al/¹⁰Be = 0.72 ± 0.01 and ³⁶Cl/¹⁰Be = 4.5 ± 0.2. The average ⁴¹Ca/³⁶Cl production rate ratio is 1.10 ± 0.04 for metal separates from Estherville and four small iron falls. The ⁴¹Ca activities in dpm/(kg Ca) of various silicate separates from Budulan and Estherville span nearly a factor of 4, from <400 to >1600, indicating preatmospheric radii of >30 cm. After allowance for composition, the activities of ²⁶Al and ¹⁰Be (dpm/kg silicate) are similar to values measured in most ordinary chondrites and appear to depend only weakly on bulk Fe content. Unless shielding effects are larger than suggested by the ³⁶Cl and ⁴¹Ca activities of the metal phases, matrix effects are unimportant for ¹⁰Be and minor for ²⁶Al. Noble gas concentrations and isotopic abundances are reported for samples of Barea, Emery, Mincy, Morristown, and Marjalahti. New estimates of ³⁶Cl/³⁶Ar exposure ages for the metal phases agree well with published values. Neon‐21 production rates for mesosiderite silicates calculated from these ages and from measured ²¹Ne contents are consistently higher than predicted for L chondrites despite the fact that the mesosiderite silicates have lower Mg contents than L chondrites. We suggest that the elevation of the ²¹Ne production rate in mesosiderite silicates reflects a “matrix effect,” that is, the influence of the higher Fe content of mesosiderites, which acts to enhance the flux of low‐energy secondary particles and hence the ²¹Ne production from Mg. As ¹⁰Be production is relatively insensitive to this matrix effect, ¹⁰Be/²¹Ne ages give erroneously low production rates and high exposure ages. By coincidence, standard ²²Ne/²¹Ne based “shielding” corrections give fairly reliable ²¹Ne production rates in the mesosiderite silicates.