Hydrocarbons and other volatile components in alkaline rocks from the Ukrainian shield and Kola Peninsula

Gas chromatography and other analytical techniques (EMR, PMR, and IR spectroscopy) were used to examine volatile components (CH₄, C₂-C₃, CO₂, CO, H₂, H₂O, and others) in alkaline rocks and minerals from the Ukrainian Shield (eight massifs and dikes of grorudites) and from the Khibina and Lovozero massifs in the Baltic Shield. The alkaline rocks from the Ukrainian Shield are mostly of Proterozoic (1.7–2.1 Ga) age. The alkaline rocks from the Kola Peninsula were confirmed to be rich in methane (21 ± 14 μl/g on average) and other hydrocarbons, whereas the analogous rocks from the Ukrainian Shield are poor in methane (2.1 ± 1.6 μl/g on average at a maximum of 14 μl/g). The latter rocks are richer in CO₂, which is one of the major volatile components of alkaline rocks, including agpaitic nepheline syenites from the Kola Peninsula. The rocks from the Ukrainian Shield often have elevated contents of nitrogen (up to 20 μl/g). The reasons for the differences in the composition of volatile components of rocks from the Kola Peninsula and Ukrainian Shield are as follows: the agpaitic crystallization trends of large massifs in the Kola Peninsula and much less clearly pronounced agpaitic trends in the small massifs in the Ukrainian Shield, the affiliation of these rocks with different complexes, the deeper erosion levels of the Ukrainian alkaline massifs, different ages of these rocks, etc.     

Metamorphic rocks of the Araya Peninsula,Eastern Venezuela

Two grades of metamorphism, both subfacies of the greenschist facies of regional metamorphism, were mapped on the Araya Peninsula: 1. the quartzalbite-epidote-almandine subfacies, consisting mainly of a sequence of garnet and kyanite quartz-mica schists, interlayered with quartzites; and 2. the quartzalbite-muscovite-chlorite subfacies, which consists of chloritic phyllites, quartzmica schists and phyllites, metaconglomerates, calcareous quartz-mica schists, limestones and marbles, and calcareous epidote schists of volcanic origin. The two subfacies are separated by faults. The probable age of these rocks ranges from Triassic(?)-Jurassic to Lower and Middle Cretaceous. Serpentinites intrude rocks of the lower metamorphic grade, and are interpreted as tectonically emplaced. The foliation of these rocks is highly folded by mesoscopic folds, whose axes trend east-northeast and which are overturned to the south-southeast. Lineations parallel to the fold axes and thrusting to the south-southeast are common. These structures reflect a macroscopic structure of antiforms and synforms, all affected by a dominant north-northwest to south-southeast tectonic transport. A system of high-angle or vertical longitudinal faults crosses the peninsula from west-southwest to east-northeast. Evidence of recent strike-slip movement was found, although vertical movement has also been important along these faults. Two tectonic styles exist in the metamorphic rocks. The older one is characterized by compression and thrusting in a south-southeast direction. The younger one is represented by longitudinal faults oriented in an east-northeast direction, with vertical and strike-slip movement. They probably reflect the eastward movement of the Caribbean region with respect to South America.     

Metamorphic evolution of the archean eclogite-like rocks of the Shirokaya and Uzkaya Salma area (Kola Peninsula): Geochemical features of zircon,composition of inclusions,and age

Zircon from the eclogite-like rocks of the Shirokaya and Uzkaya Salma area (Kola Peninsula) was studied using a complex of mineralogical and geochemical methods (CL, BSE, microprobe, and REE distribution). Different zones distinguished within zircon crystals were dated on a SHRIMP-II mass spectrometer. Mineral and chemical compositions of inclusions in the zircons were analyzed. Based on these studies, the following stages of the formation and transformation of the rocks were determined: (1) formation of basic protolith of the eclogite-like rocks of the Shirokaya and Uzkaya Salma area 2.94–2.93 Ga ago; (2) the granulite-facies metamorphism of the eclogite-like rocks of the Shirokaya Salma 2.72 Ga ago; (3) the onset of decompressional cooling with formation of Cpx-Pl symplectites at 2.70 Ga ago; and (4) final metamorphic reworking together with surrounding TTG under the amphibolite-facies conditions at 1.89 Ga ago. The studied rocks and minerals revealed no isotope-geochemical or geochronological signs of eclogite metamorphism. Geochemistry of the primary magmatic zircons showed that the protolith of eclogite-like rocks was gabbro rather than MOR basalts. The formation of garnet in the rocks of the Uzkaya and Shirokaya Salma area is dated at 2.70 and 1.89 Ga ago, which is consistent with petrological observations of later formation of garnet relative to omphacite. Obtained data led us to prefer a magmatogenic model, which suggests that omphacite in the rocks of the Shirokaya and Uzkaya Salma was presumably formed during crystallization from basic melt, rather than during eclogite-facies metamorphism.     

Globular ferropicritic rocks at Pechenga, Kola Peninsula (Russia): Liquid immiscibility versus alteration

The uppermost volcanic unit of the early Proterozoic Pechenga Group comprises ferropicritic volcanic and hypabyssal rocks which possess well-developed, light-weathering globular (up to 10 cm in size) or layer-like structures mesoscopicly similar to those found in some Archean ocellar komatiites. These structures are superficially reminiscent of features attributed to liquid immiscibility including spheroidal aggregates in all stages of coalescence. However, several lines of field, microscopical, mineralogical and chemical evidence argue against the immiscibility hypothesis. These include identical modal proportions, grain sizes, morphologies and orientations of crystalline phases in the globules and matrix, as strikingly demonstrated, for example, by the spinifex-textured varieties of the globular rocks. A solid-state hydrothermal/metamorphic diffusional process that affected the originally glassy mesostasis is concluded to be the only feasable mechanism for the formation of the globular structures in the Pechenga ferropicrites.     

Native elements in rocks of the banded iron formation,Kola Peninsula

Eleven native minerals and intermetallic alloys were identified in rocks of the banded iron formation (BIF) in the Kola Peninsula: copper, silver, gold, electrum, auricupride, cuproauride, tetraauricupride, bismuth, sulfur, tellurium, and graphite. Graphite is a common mineral of sulfide-bearing BIF and gneiss. Sulfur occurs in supergene-altered sulfide-bearing BIFs together with Fe- and Ca-sulfates. Gold of low fineness (electrum) in association with electrum, acanthite, auricupride, volynskite, hessite, cervelleite, pavonite, petzite, and bismuth is related to the areas of hydrothermally altered skarnoids with greenalite, chamosite, aegirine, and Na-Ca amphibole. Redeposited gold of high fineness associated with auricupride, hessite, silver, electrum, kostovite, cuproauride, tetraauricupride, and sperrylite occurs in low-temperature zonal hydrothermal segregations hosted in aluminous gneiss and which formed under the effect of alkalized, highly siliceous solutions at the regressive stage of BIF metamorphism.     

Spinel-group minerals in rocks of the Khibiny alkaline pluton,Kola Peninsula

Seven spinel-group minerals in various geological settings have been revealed in the rocks of the Khibiny pluton. Hercynite, gahnite, and vuorelainenite occur only in xenoliths of hornfels after volcanic and sedimentary rocks, whereas spinel and magnesiochromite occur in alkaline ultramafic rocks of dike series. Franklinite has been discovered in a low-temperature hydrothermal vein. Ubiquitous magnetite is abundant in foyaite, foidolites, alkaline ultrabasic rocks, and pegmatite and hydrothermal veins and may even be the main mineral in some foidolite varieties. The spinel-group minerals are characterized by various chemical compositions due to the fractionation of nepheline syenites resulting in formation of the Main ring of foidolites and apatite-nepheline ore. Like most other minerals found throughout the pluton, magnetite is characterized by variation in the chemical composition along the radial line from the contact with country Proterozoic volcanic rocks to the geometric center of the pluton. Toward the center, the total Ti and Mn contents in magnetite increase from 5–15 up to 40 at %.     

Corundum-group minerals in rocks of the Khibiny alkaline pluton,Kola Peninsula

Five minerals of the corundum group have been identified in the Khibiny pluton with certainty. Corundum proper and karelianite occur only in hornfels after volcanic and sedimentary rocks. Xenoliths of hornfels mark the ring faults that bound foidalite within the field of foyaite. Hematite occurs in hydrothermally altered nepheline syenite and crosscutting hydrothermal veins related to the ring faults. Minerals of the ilmenite-pyrophanite series are present in all rocks of the pluton, including veins. Accessory ilmenite in foyaite varies from the manganese variety and pyrophanite in the inner and outer parts of the pluton to manganese-free ilmenite in zone of the Main Ring Fault. In xenoliths of volcanic rocks and alkaline ultramafic rocks, ilmenite is enriched in magnesium. The zoning in distribution of the above-mentioned minerals and the character of variation in their compositions from margins of the pluton to its center are consistent with the petrochemical zoning formed as a result of foyaite alteration of near ring faults.     

Metamorphic evolution of mineral assemblages in the layered unit and its host rocks of the eastern part of the Pana Massif,Kola Peninsula

The paper presents data on the mineral assemblages and chemical composition of minerals in rocks from the eastern part of the Pana Massif, Kola Peninsula, and the results obtained by studying the amphibolization of rocks of this massif genetically related to metamorphism. The rocks contain four amphibole populations, which can be used as good indicators for metamorphic facies. The amphiboles show broad compositional variability. Their evaluated P-T crystallization conditions indicate that the prograde stage of the overprinted metamorphic processes occurred at temperatures increasing from 382 to 473°C and pressures from 1.7 to 4.3 kbar. The retrograde stage (biotitization, chloritization, silification, and carbonatization) took place at temperatures of about 370°C and pressures of approximately 1 kbar. The fluid regime of the metamorphic transforms was also controlled by the temperature: the fluids were oxidizing early in the course of the process and gradually became more reducing with decreasing temperature.     

A catastrophic holocene event in the lake bottom sediments of the Kola region (northeastern Fennoscandian shield)

Horizons with seismogenic sediments are revealed in the bottom sediments of the lake basins in the southwestern Kola Peninsula. In the borehole cores, they are represented by material that sharply differs from the overlying and underlying sediments: fragments of gyttia, siltstone, wood, sand, and peat that are embedded in the sapropelic matrix and look like breccia. These sediments reflect a strong catastrophic event from the Holocene that occurred 6000–5400 ¹⁴C yr BP. The seismic events that happened in the middle Holocene in the northeastern Fennoscandian shield indicate a significant role of the tectonic component in the damping process of relaxation of the Earth’s crust in the unloading of the recent glacier cover.     

Leaching rare-earth and radioactive elements from alkaline rocks of the Lovozero Massif,Kola Peninsula

The paper presents data on the leaching efficiency of rare-earth (La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu) and radioactive (Th and U) elements by various reagents from alkaline rocks of the Lovozero Massif. Element concentrations were analyzed by ICP-MS and instrumental neutral activation (INAA). A new complex technique is suggested for analyzing elements on the solid phase of polymer hydrogels. This technique makes it possible to enhance the sensitivity and selectivity of INAA when these elements are simultaneously contained in rocks. Data are presented on the selective leaching of trace elements and the application of environmentally safe reagents.     

Chromium mineralization in the Khibiny alkaline massif (Kola Peninsula,Russia)

This paper presents new data on chromium mineralization in a fenitized xenolith in Mt. Kaskasnyunchorr in the Khibiny alkaline massif (Kola Peninsula, Russia) and summarizes data on Cr mineralogy in the Khibiny Mountains. Protolith silicates that contained Cr³⁺ admixture are believed to be the source of this element in the fenite. Cr-bearing (maximum Cr₂O₃ concentrations, wt %, are in parentheses) aegirine (5.8), crichtonite-group minerals (2.1), muscovite (1.3), zirconolite (1.1), titanite (1.0), fluorine-magnesioarfvedsonite (0.8), biotite (0.8), ilmenite (0.6), and aenigmatite (0.6) occur in the fenite. The late-stage spinellides of the FeTi-chromite-CrTi-magnetite series, which are very poor in Mg and Al and which formed after Crrich aegirine and ilmenite, are the richest in Cr (up to 42% Ct₂O₃). Cr concentrations grew with time during the fenitization process. Unlike minerals in the Khibiny ultramafic rocks where Cr is associated with Mg, Al (it is isomorphic with Cr), and with Ca, chromium in the fenites is associated with Fe, Ti, and V (with which Cr³⁺ is isomorphic) and with Na in silicate minerals. Cr³⁺ Mobility of Cr³⁺ and the unique character of chromium mineralization in the examined fenites were caused by high alkalinity of the fluid.     

Loparite-(Ce) from the Khibiny Alkaline Pluton,Kola Peninsula,Russia

Data on the occurrence, morphology, anatomy, composition, and formation conditions of loparite-(Ce) in the Khibiny alkaline pluton are given. Loparite-(Ce), (Na,Ce,Sr)(Ce,Th)(Ti,Nb)2O6, resulted from metasomatic alteration and assimilation of metamorphic host rocks at the contact with foyaite as well as foyaite on the contact with foidolite. This alteration was the highest in pegmatite, and albitite developed there. A decrease in temperature resulted in enrichment of the perovskite and tausonite endmembers in loparite-(Ce) owing to a decrease in the loparite and lueshite endmembers. La and Ce sharply predominate among rare earth elements in the composition of loparite-(Ce).     

The first discovery of abnormal (Y+REE)-enriched zircons in rocks of the Baltic shield

Zircons with an anomalously high content of Y and REEs in rims were first found in rocks of the Baltic shield (in a pegmatite vein in the Gridino eclogite-bearing melange and in quartz syenites of the North-Karelian greenstone belt); the total content reaching 17 wt %. The presence of such an amount of nonformula elements is caused by the isomorphic occurrence of them in zircon and is not associated with microinclusions of accessory minerals. The age of formation of these rims was determined as the Svecofennian, although the direct dating yields underestimated values of the age, which are void of geological sense.