Permeability distribution in the Quaternary of the Upper Rhine glacio-fluvial aquifer

An extraordinarily large and geographically extensive 3D dataset has allowed us to relate permeability to detailed geological features. Permeability data derived from several thousand pumptests in Quaternary sediments (thickness < 120 m) of the Upper Rhine valley vary from K = 4.5 × 10⁻⁷ m s⁻¹ to K = 2.7 × 10⁻¹ m s⁻¹. The geometric mean of the data is K = 2.25 × 10⁻³ m s⁻¹. The permeability distribution maps for four different stratigraphic levels show that the highest values are found in sections beneath recent and historic fluvial systems. Fossil fans of small rivers from the Black Forest can be identified in the Rhine valley on the basis of the permeability pattern. The average hydraulic conductivity decreases S–N along the flow direction which corresponds to a decrease in grain-size of the fluvial sediments.     

Identification of Quaternary thrusts, folds and faults in a low seismicity area: examples in the Southern Alps (France)

In low seismicity areas, folds, faults and striated pebbles in recent alluvial deposits can demonstrate the Quaternary activity of tectonic structures and can reveal their kinematics. In the Digne nappe (Southern Alps), an out-of-sequence thrust occurred in the late Quaternary in response to WSW-trending compression. The presence of late Quaternary compressional deformation in the Valavoire thrust could have resulted from the activity of the underlying Durance flexure with a maximum Pliocene–Quaternary uplift rate of about 0.1 mm yr⁻¹. The Quaternary top surface of the Valensole basin, that truncates SW-vergent thrust propagation folds, is folded above the Lambruissier anticline. Exceptional conditions resulted in the local preservation of this Quaternary fold morphology created with a minimum uplift-rate of 0.05 mm yr⁻¹ under a NE-trending compression. At the front of the Digne nappe the deformation is characterized by WSW to WNW trends of compression and low strain rates during the Quaternary period.     

Thermoluminescence dating of Dimlington Stadial deposits in eastern England

The loess component of a solifluction deposit of the Dimlington Stadial exposed at the inland site of Eppleworth in eastern England gave a thermoluminescence date of 17.5 ± 1.6 × 10³ years. The solifluction deposit is overlain by a slightly weathered till correlated with the Skipsea Till of coastal exposures. which lies between organic horizons with radiocarbon dates of 18,500–18,240 B.P. and 13,045 B.P. Although the till must have been deposited during the Dimlington Stadial (after 18,240 B.P. at Dimlington and after 17,500 B.P. at Epplcworth), it gave apparent TL dates of 42.1 ± 3.6 × 10³ years at Eppleworth and 102 ± 9 × 10³ years at Dimlington, indicating that the components of the till were not exposed to light immediately before deposition.     

AMS dating Swedish varved clays of the last glacial/interglacial transition and the potential/difficulties of calibrating Late Weichselian 'absolute' chronologies

The increasing focus on the chronology of environmental and climatic changes of the last glacial-interglacial transition has led to several independent attempts to try to calibrate the ¹⁴C time-scale beyond the Holocene. The Late Weichselian Gotiglacial varved clays of the Swedish Time Scale could potentially be used for this purpose. The reliability of the Swedish Time Scale is discussed as well as different ways of using the Swedish varved clays for calibrating the ¹⁴C chronology. The strategy and initial results from an ongoing calibration project are presented. They show clearly that, if the right strategy is adopted, varved clay may be dated by accelerator mass spectrometry (AMS) ¹⁴C measurement of terrestrial macrofossils. A Late Weichselian 'event stratigraphy', including the Vedde Ash fall-out, is established for south Scandinavia using three dating categories: clay varve measurements, terrestrial macrofossil measurement, and lake sediment (including aquatic mosses) measurements. It suggests that a ¹⁴C chronology based on terrestrial organic remains is not consistent with the traditional Late Weichselian chronostratigraphy based on lake-sediment samples, and that 'clay varve years' exceed 'terrestrial ¹⁴C years' by c. 900 years at the end of, and by 1100–1200 years at the beginning of the Younger Dryas Chronozone. Further back in time, the time-scales appear to converge. These results are compared with other recently published calibration studies.     

AMS 14C measurements and macrofossil analyses of a varved sequence near Pudozh, eastern Karelia, NW Russia

The laminated sediments at Pudozh in eastern Karelia are generally assumed to have been deposited between 13 000 and 16 000 ¹⁴C yr BP and have been used to date the recession of the active ice margin. However, 17 AMS ¹⁴C measurements performed on terrestrial plant macrofossils contained in these sediments show that deposition began during the late Allerφd, when the ice margin had already receded to the northern part of Lake Onega. Based on an age model, we assume that the 1933-year-long varved sequence covers the time period between c. 12 900 and 11 000 calendar years BP. During this period, which comprises the later part of the Late Weichselian and the early Holocene, the local vegetation consisted of open, tree-less dwarf shrub heaths. Increased soil erosion may have occurred before 12 550 calendar years BP.     

Chronology and organic chemistry of the Black Creek Swamp Megafauna site (Late Pleistocene), Kangaroo Island, Australia

The timing of the extinction of the Australian Megafauna and whether it was simultaneous and widespread has been a much researched topic in Quaternary geoscience. The Black Creek Swamp Megafauna site on Kangaroo Island was thought to be a refugium for Megafauna; however, recent and multidiscipline age determinations have established that the fossils are considerably older than the well-quoted extinction age of 45 kyr. Further radiocarbon age determinations, δ¹³C isotope analysis and ¹³C-NMR spectroscopy of the fossil containing organic matter demonstrates that it is highly soluble and accumulated as recently as 31–18 cal. kyr BP. These radiocarbon ages are much younger than the 100–50 kyr age bracket ascertained for the fossil material itself, implying separate episodes of death, deposition and burial. The soluble nature of the organic matter and increasing radiocarbon ages with depth suggests lateral accumulation, probably transported by subsurface waters from elevated areas proximal to the low-lying swamp. Such depositional conditions and ¹⁴C age range implies that the site may have experienced an unusually wet Last Glacial Maximum, due maybe to its proximity to the continental shelf and thus to maritime conditions. C3 vegetation dominates the Black Creek Swamp and its organic matter (δ¹³C; −30‰ and −23‰); however, variations in δ¹³C may indicate climatic shifts. ¹³C-enrichment and an abundance of salt-tolerant gastropods within the site's final phase of sediment accumulation (<6 cal. kyr BP) suggest that conditions during this most recent period were not as wet as those of the Last Glacial Maximum.     

Quantitative temperature-time information from retrograde diffusion zoning in garnet: constraints for the P–T–t history of the Central Black Forest, Germany

Garnet from a kinzigite, a high-grade gneiss from the central Black Forest (Germany), displays a prominent and regular retrograde diffusion zoning in Fe, Mn and particularly Mg. The Mg diffusion profiles are suitable to derive cooling rates using recent datasets for cation diffusion in garnet. This information, together with textural relationships, thermobarometry and thermochronology, is used to constrain the pressure–temperature–time history of the high-grade gneisses. The garnet–biotite thermometer indicates peak metamorphic temperatures for the garnet cores of 730–810  °C. The temperatures for the outer rims are 600–650  °C. Garnet–Al₂SiO₅–plagioclase–quartz (GASP) barometry, garnet–rutile–Al₂SiO₅–ilmenite (GRAIL) and garnet–rutile–ilmenite–plagioclase–quartz (GRIPS) barometry yield pressures from 6–9  kbar. U–Pb ages of monazite of 341±2  Ma date the low- P high- T metamorphism in the central Black Forest. A Rb/Sr biotite–whole rock pair defines a cooling age of 321±2  Ma. The two mineral ages yield a cooling rate of about 15±2  °C Ma⁻¹. The petrologic cooling rates, with particular consideration of the f O₂ conditions for modelling retrograde diffusion profiles, agree with the geochronological cooling rate. The oldest sediments overlying the crystalline basement indicate a minimum cooling rate of 10  °C Ma⁻¹.     

Occurrence of varved lake sediment sequences in Varmland, west central Sweden: lake characteristics, varve chronology and AMS radiocarbon dating

Varved lake sediments can be used to set multiple environmental proxies within a calendar year time scale. We undertook a systematic survey of lakes in the Province of Värmland, west central Sweden, with the aim of finding continuous varved lake sediment sequences covering the majority of the Holocene. In Fennoscandia, such sediments have previously only been recorded in northern Sweden and in southern and central Finland. By following a selective process and fieldwork we discovered three new varved sites (i.e. Furskogstjärnet, Mötterudstjärnet and Kälksjön). We found that lakes with varved sediments have several common lake morphometry properties and lake catchment characteristics such as maximum water depth, maximum water depth/lake surface area ratio, catchment soil types, altitude and number of inflows. Varve chronologies, supported by AMS-¹⁴C dating and tephrochronology were established for two of the sediment profiles. These varve chronologies are the longest geological records with an annual resolution known to exist in Sweden. In Furskogstjärnet, the AMS- ¹⁴C dates based on terrestrial plant macrofossils at several levels deviate significantly from the varve based time-depth curve. In Motterudstjarnet, a fully reasonable time-depth model based on the ¹⁴C dates gives older ages in the lower part of the sequence compared to the varve chronology. These results highlight that seemingly acceptable AMS radiocarbon dates may be erroneous. They also point to the fact that varved lake sediments are reliable geological archives with respect to chronological control and accuracy. Thus, these archives should be of prime interest for studies of climate and environmental change undertaken with the aim of providing sub-decadal resolution proxy data sets.     

Quantitative study of the distributary braidplain of the Preboreal ice-contact Gardermoen delta complex, southeastern Norway

This raised delta structure is an ice-contact deltaic complex with a volume of c. 4.4.10⁹ m³, deposited c . 9500 yr BP in a shallow wide 'fjord' during the retreat of the Scandinavian ice cap. The delta plain lies at an altitude of 200–223 m. It aggraded c . 20 m above the contemporaneous sea level during a regional marine regression. The braidplain palaeochannel characteristics indicate a peak meltwater discharge of 7–9 10³ m³/s. Calculations based on a glacial ablation model indicate a mid-summer discharge of c . 5.5 10³ m³/s. However, the fluvial topset of the delta has an erosive base whose altitude decreases upstream and indicates stream incision by more the 6 m below the contemporaneous sea level. The deep scour is ascribed to episodic floods over the relatively short delta plain, which exceeded direct ablation-associated discharges. The depositional time-span of the delta is assessed to have been 70 years, calculated from coastal gradient and shoreline displacement curves. The average sedimentation rate of the delta is thereby inferred to have been extremely high, c . 6. 10⁷ m³/yr. The sedimentation is thought to reflect 'extreme' ice-margin conditions, where the sediment and water discharge was maximized by full-scale ablation, with simultaneous subglacial, englacial and supraglacial sediment and water supply. These conditions might further coincide with an abundant rainfall in the catchment area or the drainage of dammed waters, initiating episodic floods which eroded deep beneath sea level. As a whole, the study illustrates the hydrological conditions of proglacial sedimentation at the front of the rapidly retreating last Scandinavian ice cap.     

Rate of late Quaternary ice-cap thinning on King George Island, South Shetland Islands, West Antarctica defined by cosmogenic 36Cl surface exposure dating

Glacial landforms on the Barton and Weaver peninsulas of King George Island in the South Shetland Islands, West Antarctica were mapped and dated using terrestrial cosmogenic ³⁶Cl methods to provide the first quantitative terrestrial record for late Quaternary deglaciation in the South Shetland Islands. ³⁶Cl ages on glacially eroded and striated bedrock surfaces range from 15.5±2.5 kyr to 1.0±0.7 kyr. The ³⁶Cl ages are younger with decreasing altitude, indicating progressive downwasting of the southwestern part of the Collins Ice Cap at a rate of ∼12 mm yr⁻¹ since 15.5±2.5 kyr ago, supporting the previously published marine records for the timing and estimate of the rate of deglaciation in this region.     

Uranium Concentration in Altered Brown Coals Located under Burnt Rocks from the Kansk-Achinsk Basin, West Siberia

West Siberian brown coals from the Kansk-Achinsk basin and their combustion products are generally characterized by a low uranium content. In some places where brown coal has been altered (losing density, becoming cracked or friable), the uranium content has increased by concentrations ranging from 1001000 μg g⁻¹. At these locations distinct signs of underground fires are visible. The uranium distribution patterns suggest that the burnt organic matter was a source of uranium and altered varieties of coal serve as a geochemical barrier to uranium transport.     

40Ar/39Ar Constraints on the tectonic history and architecture of the ultrahigh-pressure Sulu orogen

New ⁴⁰Ar/³⁹Ar ages are presented from the giant Sulu ultrahigh-pressure (UHP) terrane and surrounding areas. Combined with U-Pb ages, Sm-Nd ages, Rb-Sr ages, inclusion relationships, and geological relationships, they help define the orogenic events before, during and after the Triassic collision between the Sino–Korean and Yangtze Cratons. In the Qinling microcontinent, tectonism occurred between 2.0 and 1.4 Ga. The UHP metamorphism occurred in the Yangtze Craton between 240 and 222 Ma; its thermal effect on the Qinling microcontinent was limited to partial resetting of K-feldspar ⁴⁰Ar/³⁹Ar ages. Subsequent unroofing at rates of 5–25 km Myr⁻¹ brought the UHP terrane to crustal levels where it underwent a relatively short amphibolite facies metamorphism. The end of that metamorphism is marked by ⁴⁰Ar/³⁹Ar ages in the 219–210 Ma range, implying cooling at crustal depths at rates of 50–200 °C Myr⁻¹. Ages in the 210–170 Ma range may reflect protracted cooling or partial resetting by Jurassic or Cretaceous magmatism. Jurassic 166–149 Ma plutonism was followed by cooling at rates of c. 15 °C Myr⁻¹, suggesting relatively deep crustal conditions, whereas Cretaceous 129–118 Ma plutonism was succeeded by cooling at rates of c. 50 C Myr⁻¹, suggesting relatively shallow crustal depths.     

Anthropogenic CO2 in Southern Ocean surface waters: evidence from stable organic carbon isotopes

We present an approach for tracing the fate of anthropogenic CO₂, compiling a large data set of stable organic carbon isotope ratios from surface sediments, plankton, and sinking matter in the Atlantic Ocean. The δ¹³C values of sinking matter are generally lower by 0.5–4.6‰ compared to the surface sediments. This difference increases with increasing latitude, which is explained by a stronger modern increase in surface water [CO₂ (aq)] in the Southern Ocean relative to the Tropical/Subtropical Ocean. Preindustrial dissolved CO₂ concentrations in Atlantic surface waters, estimated from the δ¹³C_org of surface sediments, are compared to recently measured surface water [CO₂ (aq)] values taken from literature. We obtain only a slight increase in [CO₂ (aq)] at lower latitudes but a significant change of about 7 ± 2 μ m in high latitudinal surface waters which we attribute to anthropogenic perturbation. Our results suggest that CO₂ released by human activities has been stored in Southern Ocean surface waters.     

The isotopic composition of oxygen and carbon in the subfossil mollusc shells of the Baltic Sea as an indicator of palaeosalinity

The carbon (δ¹³ C) and oxygen (δ¹⁸O) isotopic composistion in mollusc shells in mainly determined by the isotopic composition of water and dissolved bicarbonate. The δ¹⁸O values of water show a good correlation with the salinity of the Baltic. This correlation served as a basis for reconstructing palaeosalinity and for stratifying the marine sediments according to the δ¹⁸O values of the carbonate skeletons of subfossil shells. The δ¹³C values in shells are mainly determined by the isotopic composition of land-originating bicarbonate, especially in the carbonate skeleton of Lymnaea balthica , which inhabits the immediate coastal zone. According to the δ¹⁸O data, salinity in the investigated area (the coastal area of W and NW Estonia) was highest (about 9–11%) during the Littorina stage. The Limnae a stage had, in general, a salinity similar to the contemporary one, but during some phases possibly exceeding it by 2–3%.     

Sedimentation in a deep glacier-fed lake—Lake Tekapo, New Zealand

ABSTRACT Surface sediments, cores and seismic reflection profiling delineate sedimentary environments and processes of sedimentation in Lake Tekapo. Sedimentation is dominated by the Godley River which forms an extensive delta in the northern third of the lake. Delta growth accounts for 55% of annual sediment deposition. In winter sandy muds are deposited at the top of the delta slope, where they may move under gravity as a surficial slide. Oversteepening of the upper slope also generates deep seated failures. The entire 20 km² of delta slope is subjected to rotational slumping which episodically reworks large volumes of sediment. Down the delta slope sedimentation rates decrease, surface sediments get finer and varves become better developed.
In the lake basin sediments are parallel bedded varves, which contain typical winter-summer annual cycles as well as minor, non-annual flood varves. Annual varve thickness and semi-annual varve frequency are determined by variations in the discharge of the Godley River. Sedimentation in the basin accounts for 40% of the budget and sedimentation rates decrease with distance from the delta, except at the distal end of the basin, where turbid underflows are stopped by the rising lake floor. Beyond the basin, sedimentation rates decrease abruptly. Coriolis deflection of inflowing river water increases sedimentation rates down the eastern shore. The remaining 5% of the sediment is deposited on the lateral slopes and shoulders where sediments form a thin muddy veneer over basement, which occasionally slumps to the basin floor.     

Organic sulphur fixation in freshwater lake sediments and the implication for US ratios

A comparative analysis of two sediment cores from perialpine lakes (L. Zürich and L. Geneva) helped to clarify pathways of sulphur fixation in freshwater sediments. Despite greater than three-fold differences in lake water sulphate concentration equal amounts of sulphur are fixed in the sediments. The maximum sedimentary sulphur concentrations attain 1% (dry weight) which is similar to the sulphur content of modem, near-shore marine sediments. This is also expressed in low C _org/S_tot ratios which range from 2.5–8.
An analysis of the sulphur pools showed that organic sulphur compounds are the main components of the sedimentary sulphur, accounting for ˜ 80% and ˜ 60% of the total sulphur in Lakes Zürich and Geneva, respectively. The largest single sulphur pool is the sulphate-esters, which comprise 40–60% of the total sedimentary sulphur. Substantial amounts of the organic sulphur compounds must be formed within the sediment by boundary-layer microbial communities at the oxic-anoxic transition zone. This possibly suggests rapid recycling of sulphur in suboxic zones. Because of low concentration of SO²₄-_- in the watermass, the zone of sulphate reduction is very thin. This coupled with the mobility of some sulphide oxidizing microbial colonies (e.g. Beggiutoa ) potentially results in an almost complete recycling of the sulphur pool near the sediment-water interface. Reduced sulphur caught in this cycling process is unavailable for sedimentary pyrite formation. The C_org/S_pyriteratios for these sediments are thus high. If organically bound sulphur is not completely transformed into pyrite during late diagenesis, the C_org/ S_pyrite ratio can serve as a sensitive indicator for the salinities of anaent depositional environments.     

Pressure–temperature conditions and retrograde paths of eclogites, garnet–glaucophane rocks and schists from South Sulawesi, Indonesia

High-pressure metamorphic rocks exposed in the Bantimala area, c . 40  km north-east of Ujung Pandang, were formed as a Cretaceous subduction complex with fault-bounded slices of melange, chert, basalt, turbidite, shallow-marine sedimentary rocks and ultrabasic rocks. Eclogites, garnet–glaucophane rocks and schists of the Bantimala complex have estimated peak temperatures of T  =580–630 °C at 18  kbar and T  =590–640 °C at 24  kbar, using the garnet–clinopyroxene geothermometer. The garnet–omphacite–phengite equilibrium is used to estimate pressures. The distribution coefficient K _D1=[( X _pyr)³( X _grs)⁶/( X _di)⁶]/[(Al/Mg)_M2,wm (Al/Si)_T2,wm]³ among omphacite, garnet and phengite is a good index for metamorphic pressures. The K _D1values of the Bantimala eclogites were compared with those of eclogites with reliable P–T  estimates. This comparison suggests that peak pressures of the Bantimala eclogites were P =18–24  kbar at T  =580–640 °C. These results are consistent with the P–T  range calculated using garnet–rutile–epidote–quartz and lawsonite–omphacite–glaucophane–epidote equilibria.     

Late Quaternary basin evolution of the Gulf of Corinth: Sequence stratigraphy, sedimentation, fault–slip and subsidence rates

The Gulf of Corinth is a graben, which has undergone extension during the Late Quaternary. The subsidence rate is rapid in the currently marine part whereas uplift now affects a large part of the initially subsiding area in the North Peloponnese. In this paper, we document the rates of subsidence/uplift and extension based on new subsurface data, including seismic data and long piston coring in the deepest part of the Gulf. Continuous seismic profiling data (air gun) have shown that four (at least) major oblique prograding sequences can be traced below the northern margin of the central Gulf of Corinth. These sequences have been developed successively during low sea level stands, suggesting continuous and gradual subsidence of the northern margin by 300 m during the Late Quaternary (last 250 ka). Subsidence rates of 0.7–1.0 m kyr^− 1 were calculated from the relative depth of successive topset to foreset transitions. The differential total vertical displacement between the northern and the southern margins of the Corinth graben is estimated at about 2.0–2.3 m kyr^− 1.

Sequence stratigraphic interpretation of seismic profiles from the basin suggests that the upper sediments (0.6 s twtt thick) in the depocenter were accumulated during the last 250 ka at a mean rate of 2.2–2.4 m kyr^− 1. Long piston coring in the central Gulf of Corinth basin enabled the recovery of lacustrine sediments, buried beneath 12–13.5 m of Holocene marine sediments. The lacustrine sequence consists of varve-like muddy layers interbedded with silty and fine sand turbidites. AMS dating determined the age of the marine–lacustrine interface (reflector Z) at about 13 ka BP. Maximum sedimentation rates of 2.4–2.9 m kyr^− 1 were calculated for the Holocene marine and the last glacial, lacustrine sequences, thus verifying the respective rates obtained by the sequence stratigraphic interpretation. Recent accumulation rates obtained by the ²¹⁰Pb-radiometric method on short sediment box cores coincide with the above sedimentation rates. Vertical fault slip rates were measured by using fault offsets of correlated reflector Z. The maximum subsidence rate of the depocenter (3.6 m kyr^− 1) exceeds the maximum sedimentation rate by 1.8 m kyr^− 1, which, consequently, corresponds to the rate of deepening of the basin's floor. The above rates indicate that the 2.2 km maximum sediment thickness as well as the 870 m maximum depth of the basin may have formed during the last 1 Ma, assuming uniform mean sedimentation rate throughout the evolution of the basin.     

Seismic stratigraphy of the Quaternary and its substratum in southeastern Kattegat, Scandinavia

Based on c. 1500 km reflection seismic profiles, the Quaternary formations and their pre-Quaternary substratum in the southeastern Kattegat are described and a geological interpretation is suggested. The major volume of Quaternary deposits is found in a broad north-northwest south-southeast trending topographic depression. The substratum consists of Upper Cretaceous limestone in the region north of the Sorgenfrei–Tornquist Zone, and inside this zone older Mesozoic sedimentary rocks and Precambrian crystalline rocks are found. The Quaternary is divided into four seismic units. No direct stratigraphic control is available, but the units are assumed to represent a period ranging from Late Saalian to Holocene. The oldest unit (unit 3) is composed of deposits of supposed Late Saalian to Middle Weichselian age. This unit was severely eroded probably by the Late Weichselian ice sheets in a zone extending 40–50 km from the Swedish coast. Unit 2 represents the Late Weichselian till deposits. North and east of the island of Anholt unit 3 is cut by a system of channels eroded by glacial meltwater. By the erosion a relief up to c. 100 m was formed. After the recession of the Late Weichselian ice, an up to 100 m thick sequence of water-lain sediments (unit 1) was deposited in the erosional basin and channels. Holocene deposits (unit 0) of considerable thickness have only been identified in the channels in the northern part of the area.