Loss on ignition: a qualitative or quantitative method for organic matter and carbonate mineral content in sediments?

Since the publication of the paper of , loss on ignition (LOI) has been widely used as a method to estimate the amount of organic matter and carbonate mineral content (and indirectly of organic and inorganic carbon) in sediments. The relationships between LOI at 550 °C (LOI₅₅₀) and organic carbon (OC) content and between LOI at 950 °C (LOI₉₅₀) and inorganic carbon (IC) content are currently accepted as a standard. However, the comparison of 150 analyses of samples of diverse lithologies, collected from a single core, reveals that these relationships are affected by sediment composition (presence of clays, salts, and the variable content of organic carbon). This results in an incremental error on the estimation of carbon content from LOI values that invalidates the use of LOI values as a quantitative method for estimating carbon content. Conversely, the general trends of LOI₅₅₀ and LOI₉₅₀ show a good correlation with carbon content (both organic and inorganic) allowing use of LOI as a qualitative test for carbon content. Similarly, in our case, LOI at 105 °C (LOI₁₀₅) is a good qualitative proxy for the trends in gypsum content.     

Loss on ignition as a method for estimating organic and carbonate content in sediments: reproducibility and comparability of results

Five test runs were performed to assess possible bias when performing the loss on ignition (LOI) method to estimate organic matter and carbonate content of lake sediments. An accurate and stable weight loss was achieved after 2 h of burning pure CaCO₃ at 950 °C, whereas LOI of pure graphite at 530 °C showed a direct relation to sample size and exposure time, with only 40-70% of the possible weight loss reached after 2 h of exposure and smaller samples losing weight faster than larger ones. Experiments with a standardised lake sediment revealed a strong initial weight loss at 550 °C, but samples continued to lose weight at a slow rate at exposure of up to 64 h, which was likely the effect of loss of volatile salts, structural water of clay minerals or metal oxides, or of inorganic carbon after the initial burning of organic matter. A further test-run revealed that at 550 °C samples in the centre of the furnace lost more weight than marginal samples. At 950 °C this pattern was still apparent but the differences became negligible. Again, LOI was dependent on sample size.An analytical LOI quality control experiment including ten different laboratories was carried out using each laboratory's own LOI procedure as well as a standardised LOI procedure to analyse three different sediments. The range of LOI values between laboratories measured at 550 °C was generally larger when each laboratory used its own method than when using the standard method. This was similar for 950 °C, although the range of values tended to be smaller. The within-laboratory range of LOI measurements for a given sediment was generally small. Comparisons of the results of the individual and the standardised method suggest that there is a laboratory-specific pattern in the results, probably due to differences in laboratory equipment and/or handling that could not be eliminated by standardising the LOI procedure.Factors such as sample size, exposure time, position of samples in the furnace and the laboratory measuring affected LOI results, with LOI at 550 °C being more susceptible to these factors than LOI at 950 °C. We, therefore, recommend analysts to be consistent in the LOI method used in relation to the ignition temperatures, exposure times, and the sample size and to include information on these three parameters when referring to the method.     

烧失法测定有机质和碳酸盐的精度控制

利用水系沉积物参考样M-278和KMF,研究了温度在550℃烧灼时沉积物样品的烧失量,测定结果表明:样品在马弗炉中位置的不同,能显著影响测量结果。为减少样品因位置的差异而引起的分析误差,样品应尽量避免放置在炉门附近。但是,对于靠近炉门附近的样品,它们的测量值可以通过乘上校正系数r1=1.057和r2=0.97分别校正测定有机质和碳酸盐含量的误差。     

Estimation of carbonate, total organic carbon, and biogenic silica content by FTIR and XRF techniques in lacustrine sediments

Major components of lacustrine sediments, such as carbonates, organic matter, and biogenic silica, provide significant paleoenvironmental information about lake systems. Fourier transform infrared spectroscopy (FTIR) and scanning X-ray fluorescence (XRF) techniques are fast, cost effective, efficient methods to determine the relative abundances of these components. We investigate the potential of these techniques using sediments from two large lakes, Lake Malawi in Africa and Lake Qinghai in China. Our results show statistically significant correlations of conventionally measured concentrations of carbonate (%CaCO₃), total organic carbon (%TOC), and biogenic silica (%BSi), with absorbance in the corresponding FTIR spectral regions and with XRF elemental ratios including calcium:titanium (Ca/Ti), incoherent:coherent X-ray scatter intensities (Inc/Coh), and silicon:titanium (Si/Ti), respectively. The correlation coefficients (R) range from 0.66 to 0.96 for comparisons of FTIR results and conventional measurements, and from 0.70 to 0.90 for XRF results and conventional measurements. Both FTIR and XRF techniques exhibit great potential for rapid assessment of inorganic and organic contents of lacustrine sediments. However, the relationship between XRF-ratios or FTIR-absorbances and abundances of corresponding sedimentary components can vary with sediment source and lithology.     

A brief introduction to recent applications of several sediment-analysis techniques in palaeolimnological studies-dry bulk density and water content, mineral magnetism, carbonate content, and content of total organic carbon, nitrogen content and c

ChalacteriStics of lacustrine sediments are often capable of ~ring the hydrological regales of the lakeand its environment and human achvihes in itS catclunent during the sedimentahon of these sedimentS.Therefore, by identifying these characteristics of sedimentS, it is likely to postUlate the physicalconditions in and around the lake during geological periods. Such reconstrUction of palaeoenvironmentshas become an increasingly important branch of ear sciences as there has been an expanded n…     

Determination of carbon, carbonate, nitrogen, and phosphorus in freshwater sediments by near-infrared reflectance spectroscopy: Rapid analysis and a check on conventional analytical methods

Sediments are typically analyzed for C, N, and P for characterization, sediment quality assessment, and in nutrient and contaminant studies. Cost and time required for analysis of these constituents by conventional chemical techniques can be limiting factors in these studies. Determination of these constituents by near-infrared reflectance spectroscopy (NIRS) may be a rapid, cost-effective method provided the technology can be applied generally across aquatic ecosystems. In this study, we explored the feasibility of using NIRS to predict total C, CO₃ ^–2 organic C, N, and P in deep-water sediment cores from four Canadian lakes varying over 19 degrees of latitude. Concentration ranges of constituents in the samples (dry weight basis) were total C, 12-55; CO₃ ^–2, 6-26; organic C, 7-31; N, 0.6-3.1; and P, 0.22-2.1 mg g^–1. Coefficients of determination, r2, between results from conventional chemical analysis and NIR-predicted concentrations, based on calibrations across all the four lakes, were 0.97-0.99 for total C, organic C, and N. Prediction for CO₃ ^–2 was good for the hard water lake from a calibration across all four lakes, but this constituent in the three soft water lakes was better predicted by a calibration across the soft water lakes. The NIR calibration for P fell below acceptable levels for the technique, but proved useful in the identification of outliers from the chemical method that were later removed with the re-analysis of several samples. This study demonstrated that NIRS is useful for rapid, simultaneous, cost-effective analysis of total C, CO₃ ^–2, organic C, N, and P in dried sediments from lakes at widely varying latitudes. Also, this study showed that NIRS is an independent analytical tool useful for the identification of outliers that may be due to error during the analysis or to distinctive composition of the samples.     

Using attributes of electromagnetic waves to determine the water content and frost table in a permafrost area

The thawing-melting of the permafrost damages the subground of highways on the Qinghai-Tibet Plateau. With the application of ground-penetrating-radar (GPR) technology, the maximum permafrost melting interface can be effectively distinctly differentiated and imaged. A hierarchical feature of the permafrost region is shown clearly on the imaging profile of GPR data. The complete ablation zone or part of it is displayed distinctly. In addition, the details of subsurface layers can be effectively characterized by GPR attribute-analysis technology. With the attribute calculation and filter, the instantaneous amplitude, instantaneous frequency, and relative wave impedance can be applied in a more efficient way to divide the complete ablation zone, part of the ablation and non-ablation interface. The relative distribution of water content in a seasonally thawing permafrost region can be obtained through a comprehensive GPR attribute analysis.     

Relationship between C:N ratios of lake sediments, organic matter sources, and historical deforestation in Lake Pleasant, Massachusetts, USA

The C:N ratios of lake sediments may reflect proportions of terrestrial and algal carbon contributing to accumulation of sediment. This possibility was tested in Lake Pleasant, Massachussetts, USA which underwent watershed deforestation in about 1780 A.D. The C:N profile of a 70-cm sediment core clearly reflected deforestation through a rise in C:N ratio caused by an increase in watershed contributions to sedimentary carbon. Spatial variability of C:N in modern surficial sediments is small compared to the change caused by deforestation.     

Oxygen isotope ratios of organic matter in arctic lakes as a paleoclimate proxy: field and laboratory investigations

Paleoclimate research based on the stable isotopic composition of lake sediments is often hampered by the lack of preservation of suitable material for isotopic analysis. We examined organic material as a proxy for past water isotopic composition in a series of experiments. First, we cultured aquatic moss under constant illumination, temperature, and water ¹⁸O, and show that new cellulose records source water ¹⁸O precisely (r² = 0.9997). Second, we analyzed paired lakewater and vegetation samples collected from sites spanning strong climatic gradients. In field conditions, the relationship between organic ¹⁸O and water ¹⁸O is more variable, though it is still controlled by environmental water isotopic composition. However, terrestrial mosses in the arctic are often significantly enriched in ¹⁸O relative to aquatic mosses in nearby lakes due to their use of different water sources. Third, we measured ¹⁸O of cellulose extracted from disseminated sedimentary organic material. In the majority of the middle- to high-arctic lakes in this study, the ¹⁸O of disseminated sediment cellulose is greatly enriched relative to the expected values based on lakewater ¹⁸O, suggesting a significant component of terrestrial cellulose. This interpretation is supported by radiocarbon dates from a Holocene sediment core in which ¹⁴C ages of sediment cellulose are 700-5000 yrs older than the enclosing sediments. We conclude that aquatic cellulose can be used as a reliable tracer of lakewater isotope ratios, but terrestrial cellulose often dominates the sedimentary cellulose pool in places such as Baffin Island where sedimentation rates are low enough to allow the degradation of aquatic cellulose. Care must be taken when interpreting sediment cellulose ¹⁸O records where diagenesis has played a role, because terrestrial cellulose is more resistant to degradation, and therefore can predominate in environments with low organic carbon burial.     

Catastrophic hurricane history revealed by organic geochemical proxies in coastal lake sediments: a case study of Lake Shelby,Alabama (USA)

We developed a new method for reconstructing millennia-long hurricane records from coastal environments that uses Organic Geochemical Proxies (OGPs) of organic carbon and nitrogen concentrations and their δ¹³C and δ¹⁵N compositions. The new method is independent of presence/absence of sand layers and improves significantly the severe-storm history resolution. The subject of this investigation is a 1.5 m long sediment core raised at 2.8 m water depth from the center of Lake Shelby, Alabama, a freshwater lake located approximately 250 m from the Gulf of Mexico, from which an overwash sand-layer based record was previously derived. The core contains two distinct sediment units; an upper 62 cm thick, fine-grained, organic-rich lacustrine sapropel (gyttja) that shows no visible structures except one sand lamina at 23.7 cm depth, and an underlying 90 cm thick, organic-poor lagoon/estuary clay unit. The sapropel unit was deposited over a 682 ± 30 cal year time interval (1320–2002 A.D.) with a mean sedimentation rate of 0.79 ± 0.04 mm/year. Lake Shelby’s water column exhibits two contrasting states based on water chemistry surveys (i) an “isolated”, stratified, mode under calm weather conditions with a relatively low trophic state, and (ii) a “flooded” mode occurring during storm surges when nutrient-rich seawater floods the lake. Statistically significant δ¹³C and δ¹⁵N positive excursions in organic matter, up to maximum values of −25 (‰ PDB) and 4 (‰ Air N₂), respectively, are interpreted as geochemical responses to the marine intrusions that fertilize the lake, increase light availability, and cause eutrophication spikes. Detailed OGPs analyses crossing a sand layer that offers visual evidence of a catastrophic hurricane overwash event at 1717 A.D. exhibit large δ¹³C and δ¹⁵N positive shifts bounded by rapid returns to base values, thus confirming the validity of the hurricane identification by the OGPs model. Our data indicate that 11 catastrophic hurricanes hit the Alabama coast over the past 682 years with a rough recurrence interval of one in 62 years.     

Taking varves to bits: Scanning electron microscopy in the study of laminated sediments and varves

Conventional high resolution studies of varved sediments are able to identify clastic and biogenic laminae, but are often unable to resolve the nature of fine-scale lamination contained therein. This intra-annual signal provides us with the highest potential resolution from the sedimentary record and can be resolved using scanning electron microscopy (SEM). Six case studies from lacustrine and marine settings are presented to illustrate the combination of clastic and biogenic fabric types typically found in laminated sediments. Clastic laminae fabrics include those which originate through grain settling and those which are event deposits. The correct identification of event deposits is essential if varves are to be used chronologically. SEM-based biogenic laminae fabric studies have identified seasonal faunal successions where individual laminae may be less than 100 thick and most recently, deep chlorophyll maxima (DCM) summer diatom floras, providing an insight into seasonal scale processes. High resolution lamina fabric studies can provide a basis for generating records of seasonal and inter-annual variability, thus contributing to our understanding of lacustrine and marine processes and palaeoenvironmental interpretation.     

传统村落的集体记忆研究——对纪录片《记住乡愁》进行内容分析为例

传统村落的集体记忆承载着村庄的文化传统与人们的乡愁情感。但随着城镇化及其带来的大规模人口迁徙,使得这些记忆正面临巨大冲击。就此展开研究,对于乡村规划和发展、乡村记忆保存和传承等意义重大。归纳出集体记忆的社会选择性、动态重构性、媒介依赖性等属性后,构建传统村落集体记忆三要素的研究框架,即主体（记忆者）、客体（记忆对象）、时间,借助大型纪录片《记住乡愁》,选取60个典型的中国传统村落,采用内容分析等方法,探讨主体诉求及其相应的情感特征、客体如何承载传统价值以及时间演变中村落发展阶段划分等问题。并初步分析了随着生产生活方式的变迁,这三者是如何发生变化的,最后结合乡村规划和乡村旅游提出建议。     

Assessing the abilities of intrinsic and specific vulnerability models to indicate groundwater vulnerability to groups of similar pesticides: a comparative study

With continued population growth and increasing use of fresh groundwater resources, protection of this valuable resource is critical. A cost effective means to assess risk of groundwater contamination potential will provide a useful tool to protect these resources. Integrating geospatial methods offers a means to quantify the risk of contaminant potential in cost effective and spatially explicit ways. This research was designed to compare the ability of intrinsic (DRASTIC) and specific (Attenuation Factor; AF) vulnerability models to indicate groundwater vulnerability areas by comparing model results to the presence of pesticides from groundwater sample datasets. A logistic regression was used to assess the relationship between the environmental variables and the presence or absence of pesticides within regions of varying vulnerability. According to the DRASTIC model, more than 20% of the study area is very highly vulnerable. Approximately 30% is very highly vulnerable according to the AF model. When groundwater concentrations of individual pesticides were compared to model predictions, the results were mixed. Model predictability improved when concentrations of the group of similar pesticides were compared to model results. Compared to the DRASTIC model, the AF model more accurately predicts the distribution of the number of contaminated wells within each vulnerability class.     

Assessing the natural component of the external load due to organic matter and biogenic elements on the water bodies in Northwestern Russia

We suggest the method to calculate the natural component of the external loads due to organic matter and biogenic elements on the unexplored lakes using the removal rate moduli for these elements, and indices of the lakes’ specific catchments. The schematic map has been generated for the distribution of natural moduli of removal on the catchment of the Gulf of Finland. We calculated the external natural loads for 94 lakes in landscapes with a high percentage of lakes.     

Impacts of settlement,damming, and hydromanagement in two boreal lakes: a comparative paleolimnological study

Namakan Lake, located in shared border waters in northeastern Minnesota and northwestern Ontario, was subjected to several anthropogenic impacts including logging, damming, water-level manipulations, and perhaps climate change. We used paleolimnology to determine how these stressors impacted Namakan Lake in comparison to a control lake (Lac La Croix) that was not subject to damming and hydromanagement. One core was retrieved from each lake for ²¹⁰Pb dating and analysis of loss-on-ignition and diatom composition. ²¹⁰Pb-derived chronologies from the cores indicated that sediment accumulation increased after logging and damming in Namakan Lake; Lac La Croix showed no significant change. Loss-on-ignition analysis also showed an increase in concentration and accumulation of inorganic material after damming in Namakan Lake; again, minimal changes were observed in Lac La Croix. Diatom communities in both lakes displayed community shifts at the peak of logging. Simultaneous, post-1970s diatom community changes may reflect regional climate warming. Taxonomic richness in Namakan Lake decreased sharply after damming and the peak of logging, and was followed by a slow recovery to taxonomic richness similar to that prior to damming. Ecological variability among post-damming diatom communities, however, was greater in Namakan Lake than in Lac La Croix. A diatom calibration set was used to reconstruct historical conductivity and total phosphorus (TP). Lac La Croix showed little historical change in conductivity and TP. In contrast, conductivity increased for several decades in Namakan Lake after damming, possibly in relation to several large fires and flooding. Total phosphorus also increased in Namakan Lake after damming, with a possible decrease in the last decade to pre-damming TP levels.     

怀旧消费空间地方建构的比较研究——以广州怀旧餐厅为例

在全球化深入发展的今天,都市怀旧消费风潮已渗透至社会文化生活诸多领域。许多怀旧餐厅也应运而生,形成以城市怀旧为主题的特殊消费空间和文化空间。全球与地方在消费文化转化中相互促进,地方文化形态正在发生变化,不同怀旧消费空间的地方建构是否存在差异?本文选择广州太平馆、巴打怀旧茶餐厅两个不同特点的怀旧餐厅为案例,通过参与式观察、深度访谈、问卷调查和文本分析等研究方法,收集相关媒体报道和网上讨论作为研究的文本资料。从物质空间和情感空间两个方面对比分析了怀旧餐厅的地方建构和认同。研究表明,透过记忆的呈现和展示,记忆凝视下的传统再造和怀旧消费导向下的再造传统都是适应全球文化潮流过程中不同的消费物质空间建构形式。从消费者角度来看,怀旧地方又是其情感空间的建构和地方记忆的再生产,表现在地方依恋和地方认同等方面。由于怀旧地方建构中"真实地方"和"构想地方"交集的差异,其地方认同感也存在不同,在很大程度上受到地方根植性、市场机制和后现代消费特征等因素的影响。本文有助于从新文化地理学视角理解怀旧消费空间的地方建构,对指导怀旧消费空间生产和实践有积极的现实意义。     

Seasonal variability of Holocene climate: a palaeolimnological study on varved sediments in Lake Jues (Harz Mountains, Germany)

Studies combining sedimentological and biological evidence to reconstruct Holocene climate beyond the major changes, and especially seasonality, are rare in Europe, and are nearly completely absent in Germany. The present study tries to reconstruct changes of seasonality from evidence of annual algal successions within the framework of well-established pollen zonation and ¹⁴C-AMS dates from terrestrial plants. Laminated Holocene sediments in Lake Jues (10°20.7′ E, 51°39.3′ N, 241 m a.s.l.), located at the SW margin of the Harz Mountains, central Germany, were studied for sediment characteristics, pollen, diatoms and coccal green algae. An age model is based on 21 calibrated AMS radiocarbon dates from terrestrial plants. The sedimentary record covers the entire Holocene period. Trophic status and circulation/stagnation patterns of the lake were inferred from algal assemblages, the subannual structure of varves and the physico-chemical properties of the sediment. During the Holocene, mixing conditions alternated between di-, oligo- and meromictic depending on length and variability of spring and fall periods, and the stability of winter and summer weather. The trophic state was controlled by nutrient input, circulation patterns and the temperature-dependent rates of organic production and mineralization. Climate shifts, mainly in phase with those recorded from other European regions, are inferred from changing limnological conditions and terrestrial vegetation. Significant changes occurred at 11,600 cal. yr. BP (Preboreal warming), between 10,600 and 10,100 cal. yr. BP (Boreal cooling), and between 8,400 and 4,550 cal. yr. BP (warm and dry interval of the Atlantic). Since 4,550 cal. yr. BP the climate became gradually cooler, wetter and more oceanic. This trend was interrupted by warmer and dryer phases between 3,440 and 2,850 cal. yr. BP and, likely, between 2,500 and 2,250 cal. yr. BP.     

重大事件游客消费行为及偏好的中外比较研究——以2010上海世博会为例

通过对上海世博会大样本游客调研数据的分析与处理,研究中外游客消费行为特征、偏好差异及其产业影响。研究表明:(1)国内游客住宿以经济型饭店为主,住宿地集中在世博园区周边及城郊区域,入境游客以星级饭店为主,住地集中城市商业中心附近区域。(2)中外游客在世博园区餐饮消费以快餐及地方特色餐饮为主,消费偏好维度中游客最关注的是菜肴维度与服务维度,国内游客更关注菜肴,入境游客更关注服务。(3)国内游客购买世博商品主要留作纪念,入境游客主要用于馈赠,消费偏好维度中国内游客最为关注是商品主题文化属性和设计加工维度,入境游客最为关注商品的商业维度和功能效用维度。(4)国内游客市内游憩空间区域集中程度高于入境游客;中外游客市内交通以公共交通为主,入境游客选择出租车出行较多;国内游客晚间活动以游览世博园为主,入境游客选择其他娱乐活动较多。对世博游客行为特征与消费偏好进行深入比较研究,理论上丰富了重大事件旅游研究内容,实践上对于重大事件旅游市场开发与目的地产业建设具有重要的指导意义。     

Unraveling the multi-scalar residential segregation and socio-spatial differentiation in China: A comparative study based on Nanjing and Hangzhou

Residential segregation is a dual process of socio-spatial differentiation in residents and spatio-temporal heterogeneity in dwelling.However,most of the existing studies are es-tablished from the single perspective of urban residents based on demographic data,which is difficult to reveal the dynamics and complex spatial reconstruction within and between cities.With the characteristics of both stability and timeliness,the rapidly changing housing market is one of the processes and results of socio-spatial reconfiguration,and it is undoubtedly a better lens to observe residential segregation.This paper adopts methods such as multi-group segregation index,multi-scalar segregation profiles,and decomposition of segregation index,with Nanjing and Hangzhou as case cities,and establishes multi-scalar segregation profiles and comparative models based on three geographical scales of census tract,block and grid,and different residential types.A quantitative study was conducted on the degree and pattern of multi-scalar residential segregation in Nanjing and Hangzhou from 2009 to 2018.The pa-per found that the spatial segregation index is an improvement of the non-spatial segregation index.There are differences between Nanjing and Hangzhou in the evolution process of residential segregation.Nanjing has a higher degree of spatial differentiation as a whole,among which spatial components have a more significant impact.     

Reconstruction of the recent history of a large deep prealpine lake (Lake Bourget,France) using subfossil chironomids,diatoms, and organic matter analysis: towards the definition of a lake-specific reference state

This paper presents the recent history of a large prealpine lake (Lake Bourget) using chironomids, diatoms and organic matter analysis, and deals with the ability of paleolimnological approach to define an ecological reference state for the lake in the sense of the European Framework Directive. The study at low resolution of subfossil chironomids in a 4-m-long core shows the remarkable stability over the last 2.5 kyrs of the profundal community dominated by a Micropsectra-association until the beginning of the twentieth century, when oxyphilous taxa disappeared. Focusing on this key recent period, a high resolution and multiproxy study of two short cores reveals a progressive evolution of the lake’s ecological state. Until AD 1880, Lake Bourget showed low organic matter content in the deep sediments (TOC less than 1%) and a well-oxygenated hypolimnion that allowed the development of a profundal oxyphilous chironomid fauna (Micropsectra-association). Diatom communities were characteristic of oligotrophic conditions. Around AD 1880, a slight increase in the TOC was the first sign of changes in lake conditions. This was followed by a first limited decline in oligotrophic diatom taxa and the disappearance of two oxyphilous chironomid taxa at the beginning of the twentieth century. The 1940s were a major turning point in recent lake history. Diatom assemblages and accumulation of well preserved planktonic organic matter in the sediment provide evidence of strong eutrophication. The absence of profundal chironomid communities reveals permanent hypolimnetic anoxia. From AD 1995 to 2006, the diatom assemblages suggest a reduction in nutrients, and a return to mesotrophic conditions, a result of improved wastewater management. However, no change in hypolimnion benthic conditions has been shown by either the organic matter or the subfossil chironomid profundal community. Our results emphasize the relevance of the paleolimnological approach for the assessment of reference conditions for modern lakes. Before AD 1900, the profundal Micropsectra-association and the Cyclotella dominated diatom community can be considered as the Lake Bourget reference community, which reflects the reference ecological state of the lake.