First astronomical detection of the cumulene carbon chain molecule H2C6 in TMC-1

The cumulene carbenes are important components of hydrocarbon chemistry in low-mass star-forming cores. Here we report the first astronomical detection of the long-chain cumulene carbene H2C6 in the interstellar cloud TMC-1, from observations of two of its rotational transitions: J(K,K') = 7(1,7) --> 6(1,6) at 18.8 GHz and 8(1,8) --> 7(1,7) at 21.5 GHz, using NASA's Deep Space Network 70 m antenna at Goldstone, California. In addition we also observed the shorter cumulene carbene H2C4 at the same position. The fractional abundance of H2C6 relative to H2 is about 4.7 x 10(-11) and that of H2C4 is about 4.1 x 10(-9). The abundance of H2C6 is in fairly good agreement with gas-phase chemical models for young molecular cloud cores, but the abundance of H2C4 is significantly larger than predicted.     

Calculations concerning interstellar isomeric abundance ratios for C3H and C3H2

The syntheses of interstellar c-C3H2, H2CCC, c-C3H, and HCCC, where "c" stands for the cyclic isomer, are thought to proceed via dissociative recombination of the precursor ions c-C3H3+ and H2CCCH+, which are themselves produced mainly via the radiative association reaction between C3H+ and H2. We have utilized ab initio methods to study the potential energy surface (PES) for the association of the linear ion C3H+ and H2 to form the isomers c-C3H3+ and H2CCCH+. The overall rate coefficient for radiative association has been calculated as a function of temperature via the phase space method. Our ab initio calculations show that the H2CCCH+ isomer is formed directly without an activation barrier from reactants, and that isomerization between the two isomers can occur readily via a low-energy pathway consisting of two transition states (saddle points on the PES) and one intermediate (local minimum on the PES). Calculations of the equilibrium coefficient for the isomerization H2CCCH+ <-> c-C3H3+ as a function of energy shows that equal abundances of these two ions should be produced as relaxation proceeds, in agreement with experimental measurements at high pressure. Our results confirm the important point that a simple ion-molecule association reaction can produce a cyclic hydrocarbon. If dissociative recombination reactions involving c-C3H3+ and H2CCCH+ maintain the carbon skeletal structure of the ions and produce roughly similar C3H/C3H2 branching ratios, then abundance ratios of unity are produced between the cyclic and noncyclic isomers of C3H and C3H2 via this mechanism. The large abundance ratio of c-C3H2 to H2CCC observed in TMC-1 can then be explained by differential destruction rates.     

Statistical algorithms for identification of astronomical X‐ray sources

Observations of present and future X‐ray telescopes include a large number of ipitous sources of unknown types. They are a rich source of knowledge about X‐ray dominated astronomical objects, their distribution, and their evolution. The large number of these sources does not permit their individual spectroscopical follow‐up and classification. Here we use Chandra Multi‐Wavelength public data to investigate a number of statistical algorithms for classification of X‐ray sources with optical imaging follow‐up. We show that up to statistical uncertainties, each class of X‐ray sources has specific photometric characteristics that can be used for its classification. We assess the relative and absolute performance of classification methods and measured features by comparing the behaviour of physical quantities for statistically classified objects with what is obtained from spectroscopy. We find that among methods we have studied, multi‐dimensional probability distribution is the best for both classifying source type and redshift, but it needs a sufficiently large input (learning) data set. In absence of such data, a mixture of various methods can give a better final result.We discuss some of potential applications of the statistical classification and the enhancement of information obtained in this way. We also assess the effect of classification methods and input data set on the astronomical conclusions such as distribution and properties of X‐ray selected sources. (© 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

The hydrocarbon ring C3H2 is ubiquitous in the Galaxy

We report the discovery of a strong microwave (lambda 1.6 cm) spectral line, the carrier of which is common and widespread throughout the Galaxy. A survey of a large number of sources shows that the line appears in emission in cold dust clouds, in absorption in the direction of the Galactic center, and exhibits complex profiles toward H II regions. Toward Cas A and distant H II regions, intervening "spiral arm" clouds produce absorption. For almost all cases, the absorption features show a striking 1 : 1 radial velocity correspondence with those seen, e.g., in H2CO spectra of the same objects. The data indicate that the line arises between low-lying energy states of rather polar molecule. Recent work by Thaddeus, Vrtilek, and Gottlieb, reported in 1985 incorporating the present data, shows that the line in question is the 1(10)-1(01) transition of the small hydrocarbon ring C3H2.     

The rate of the reaction between C2H and C2H2 at interstellar temperatures

The reaction between the radical C2H and the stable hydrocarbon C2H2 is one of the simplest neutral-neutral hydrocarbon reactions in chemical models of dense interstellar clouds and carbon-rich circumstellar shells. Although known to be rapid at temperatures > or = 300 K, the reaction has yet to be studied at lower temperatures. We present here ab initio calculations of the potential surface for this reaction and dynamical calculations to determine its rate at low temperature. Despite a small potential barrier in the exit channel, the calculated rate is large, showing that this reaction and, most probably, more complex analogs contribute to the formation of complex organic molecules in low-temperature sources.     

Observations of CH4, C2H6, and C2H2 in the stratosphere of Jupiter

We have performed high-resolution spectral observations at mid-infrared wavelengths of CH4 (8.14 micrometers), C2H6 (12.16 micrometers), and C2H2 (13.45 micrometers) on Jupiter. These emission features probe the stratosphere of the planet and provide information on the carbon-based photochemical processes taking place in that region of the atmosphere. The observations were performed using our cryogenic echelle spectrometer CELESTE, in conjunction with the McMath-Pierce 1.5-m solar telescope between November 1994 and February 1995. We used the methane observations to derive the temperature profile of the jovian atmosphere in the 1-10 mbar region of the stratosphere. This profile was then used in conjunction with height-dependent mixing ratios of each hydrocarbon to determine global abundances for ethane and acetylene. The resulting mixing ratios are 3.9(+1.9)(-1.3) x 10(-6) for C2H6 (5 mbar pressure level), and 2.3 +/- 0.5 x 10(-8) for C2H2 (8 mbar pressure level), where the quoted uncertainties are derived from model variations in the temperature profile which match the methane observation uncertainties.     

Astronomical identification of the C3H radical

The C3H radical, a linear carbon chain with a 2 pi electronic ground state, has been identified in the millimeter-wave spectra of two astronomical sources, IRC +10216 and TMC-1, and conclusively confirmed (accompanying Letter) in a laboratory glow discharge. In IRC +10216 four rotational transitions have been observed, three in the lower fine-structure ladder (2 pi 1/2) and one in the upper (2 pi 3/2), each a resolved or partially resolved lambda-doublet. In TMC-1, both lambda components of the lowest lying 3/2 --> 1/2 transition of the 2 pi 1/2 ladder have been observed, each with well-resolved hfs. In IRC +10216 the excitation of C3H is similar to that of SiCC: the rotational temperature Trot within the 2 pi 1/2 ladder is low (8.5 K), owing to rapid radiative decay, while Trot across the ladders is high (approximately 52 K) because interconnecting far-IR radiative transitions are only weakly permitted. The column density of C3H in IRC +10216 averaged over the estimated source diameter of 84" is 2.8 x 10(13) cm-2, an order of magnitude less than that of C2H and C4H. A determination of the spectroscopic constraints of C3H that permitted the entire radio spectrum of this molecule to be calculated to high accuracy has been derived from analysis of the combined astronomical and laboratory data presented in the accompanying Letter.     

The C3H2 2(20)-2(11) transition: absorption in cold dark clouds

The first observations of the 2(20)-2(11) transition of cyclopropenylidene (C3H2) at 21.6 GHz are described. In all cases where it has been detected, the line appears in absorption, showing that this transition is "refrigerated" (i.e., Tex < 2.7 K) in cold dust clouds. These results are compared with those for the 1(10)-1(01) transition of C3H2, and the consequences for the excitation of C3H2 qualitatively discussed.     

Flares of H2O maser radio line in the sources GDD 25 and Sgr B2

Special Astrophysical Observatory, USSR Academy of Sciences; Byurakan Astrophysical Observatory. Translated from Astrofizika, Vol. 30, No. 1, pp. 121–127, January–February, 1989.     

Heterogeneous distribution of H2O in the Martian interior: Implications for the abundance of H2O in depleted and enriched mantle sources

We conducted a petrologic study of apatite within 12 Martian meteorites, including 11 shergottites and one basaltic regolith breccia. These data were combined with previously published data to gain a better understanding of the abundance and distribution of volatiles in the Martian interior. Apatites in individual Martian meteorites span a wide range of compositions, indicating they did not form by equilibrium crystallization. In fact, the intrasample variation in apatite is best described by either fractional crystallization or crustal contamination with a Cl‐rich crustal component. We determined that most Martian meteorites investigated here have been affected by crustal contamination and hence cannot be used to estimate volatile abundances of the Martian mantle. Using the subset of samples that did not exhibit crustal contamination, we determined that the enriched shergottite source has 36–73 ppm H₂O and the depleted source has 14–23 ppm H₂O. This result is consistent with other observed geochemical differences between enriched and depleted shergottites and supports the idea that there are at least two geochemically distinct reservoirs in the Martian mantle. We also estimated the H₂O, Cl, and F content of the Martian crust using known crust‐mantle distributions for incompatible lithophile elements. We determined that the bulk Martian crust has ~1410 ppm H₂O, 450 ppm Cl, and 106 ppm F, and Cl and H₂O are preferentially distributed toward the Martian surface. The estimate of crustal H₂O results in a global equivalent surface layer (GEL) of ~229 m, which can account for at least some of the surface features on Mars attributed to flowing water and may be sufficient to support the past presence of a shallow sea on Mars' surface.     

Preparation,collisional decay and transfer of alignment in C2H2 21

Stimulated Raman scattering is used to prepare ensembles of aligned acetylene molecules in thev ₂=1 excited vibrational level. Decay and transfer of the alignment is followed by laser induced fluorescence. Measurements of the initially excited alignment agree well with theoretical calculations. The rate constants for decay decrease as the rotational quantum numberJ of the excited level increases.     

IRAS 02232+6138的13CO、C18O、HCO+和N2H+的观测研究

利用中国科学院紫金山天文台德令哈观测站13．7米望远镜在IRAS 02232 6138方向进行了13CO,C18O,HCO 和N2H 的观测．随着探针分子的激发密度从13CO到N2H 逐渐增加, IRAS02232 6138云核的尺度从13CO的2．40 pc减小到N2H 的0．54pc,云核的维里质量从13CO的2．2×103M⊙减小到N2H 的5．1×102M⊙．研究发现,该方向区域内存在双极分子外流．对云核的空间密度结构用幂函数n(r)αr-α的形式进行拟合分析,得到α=2．3-1．2;随着探测密度的增加,该指数逐渐变平．分析得到, 13CO／C18O分子丰度比值为12．4±6．9,与暗云的11．8±5．9及大质量核的9．0-15．6值一致;N2H 丰度是3．5±2．5×10-10,与暗云核的1．0-5．0×10-10和大质量核的1．2-12．8×10-10值一致;HCO 丰度为0．9±0．5×10-9,接近大质量核的1．6-2．4×10-9值,没有发现HCO 丰度增长．结合IRAS数据,得到云核的光度质量比范围为37-163(L／M)⊙,由IRAS光度估计, IRAS 02232 6138方向云核内嵌埋的大约是一颗主序O7．5星．     

NOBLE GASES IN THE BELLS (C2) AND SHARPS (H3) CHONDRITES

Bells and Sharps have some mineralogical and chemical peculiarities that make their classification uncertain. For Bells, the⁴⁰ Ar content at 890 × 10^?8 cm³ STP/g is greater than the highest C1 chondrite value (Ivuna; 640), but close to the mean value for C2's (880). The²¹ Ne-exposure age of 0.38 ± 0.07 Ma is very short, and coincides with the distinctive cluster of five C2's (0.17 to 0.76 Ma). Very likely Bells belongs to the same cluster, in which case it comes from the C2 parent body. Hence the C2 parent body seems to contain transitional C1-C2 material, like Bells, within a few km of the region of C2 chondrites proper. Thus the radiogenic and especially the cosmogenic gases link Bells to the C2 group. For Sharps, the elemental concentrations of primordial Ar, Kr and Xe (127, 0.76 and 0.59, all 10^?8 cc/g) are ～ 3 x higher than for any other H3 chondrite. While Sharps is classified as 3.4 based on five indicators of metamorphism, the very high concentration of remaining two parameters of the Sears et al. (1980) scheme — C and primordial³⁶ Ar — (together with the high concentration of the volatile trace elements Bi, In and Tl) implies a classification of 3.0 for its volatile element content. The²¹ Ne-exposure age is 25.5 ± 2.5 Ma, placing Sharps in the second largest peak of the H-chondrite distribution. The nominal K-Ar and U, Th-He ages are 4.6 ± 0.2 and 4.2 ± 1.5 Ga, suggesting that Sharps has remained at low temperatures since its beginnings.     

C_2H, HC_3N and HNC observations in OMC-2/3

For the first time, the OMC-2/3 region was mapped in C2H (1-0), HC3N (10-9) and HNC (1-0) lines. In general, the emissions from all the three molecular species reveal an extended filamentary structure. The distribution of C2H cores almost follows that of the 1300μm condensations, which might suggest that C2H is a good tracer to study the core structure of molecular clouds. The core masses traced by HNC are rather ?at, ranging from 18.8 to 49.5 M , while also presenting a large span for those from C2H, rangi...     

15-GHz variability of 9C sources

We present results from a 3-yr study of the 15-GHz variability of 51 9C sources. 48 of these sources make up a subsample of a larger one complete to 25 mJy in 9C, and as the sources are selected pseudo-randomly the results should be representative of the complete sample. 29 per cent of this subsample are found to be variable above the flux calibration uncertainties of ∼6 per cent. 50 per cent of the flat-spectrum objects are variable whilst none of the steep-spectrum objects or the objects with convex spectra peaking below 5 GHz are variable. Nine of the objects studied have convex spectra and peak frequencies above 5 GHz; eight of these were found to vary at 15 GHz, suggesting that the high-frequency peaking class in this sample is largely populated by objects with jets aligned close to the line of sight whose emission is dominated by beamed components.     

Photometry of Venus below 2200 Å from the orbiting astronomical observatory-2

Spectrophotometry of Venus from 2170 to about 1950 Å has been obtained by OAO-2 at 10 Å resolution. The new data confirm and extend previous indications that the geometric albedo decreases continuously below 2500 Å. Secular changes in either the amount or distribution, or both, of absorbing constituents in the upper atmosphere are strongly suggested. A narrow absorption feature is found near 2145 Å, confirming an earlier report by Anderson et al. [J. Atmos. Sci.26 (1969), 874–888]. Absorption by trace amounts of nitrogen-bearing molecules, including N₂O, HNO₃ in aqeous solution, and possibly also NO, together with Rayleigh scattering from CO₂, can account for the variation in albedo below 3200 Å, but other explanations are not excluded. For example, H₂S may contribute to or be responsible for the decrease in albedo below 2500 Å.     

A novel method of lossless compression for 2-D astronomical spectra images

A novel method of lossless compression for astronomical spectra images is proposed in this paper. Firstly, Integer Wavelet Transform is adopted to perform decorrelation of the data. Afterwards, Embedded Zero-tree Wavelet encoder is employed to describe the zero-tree structure of wavelet coefficients, and then the resulting stream put through Embedded Zero-tree Wavelet encoder can be transformed to character string including only five characters that is easily compressed by entropy coding. Finally, Arithmetic encoder is chosen as the entropy coder here. Groups of simulation data based on LAMOST and observation data from SDSS are used in the experiment to demonstrate the new method, and the experimental results are much better than those of GZIP and JPEG2000.     

Improvement of photomultiplier performance in astronomical applications

The physics of an EMI 9558 Å photomultiplier has been investigated in some detail, and this study has led to a gain of more than thirty times in the signal-to-noise obtainable in a given observation time when used in receiver noise limited conditions. The importance of giant pulses in limiting performance is demonstrated.     

Identification of C4H5, C4H4, C3H3 and CH3 radicals produced from the reaction of atomic carbon with propene: Implications for the atmospheres of Titan and giant planets and for the interstellar medium

We observed the products C₄H₅, C₄H₄, C₃H₃ and CH₃ of the C(³P) + C₃H₆ reaction using product time-of-flight spectroscopy and selective photoionization. The identified species arise from the product channels C₄H₅ + H, C₄H₄ + 2H and C₃H₃ + CH₃. Product isomers were identified via measurements of photoionization spectra and calculations of adiabatic ionization energy. Product C₄H₅ probably involves three isomers HCCCHCH₃, H₂CCCCH₃ and H₂CCCHCH₂. In contrast, products C₄H₄ and C₃H₃ involve exclusively HCCCHCH₂ and H₂CCCH, respectively. Reaction mechanisms are unraveled with crossed-beam experiments and quantum-chemical calculations. The ³P carbon atom attacks the π orbital of propene (C₃H₆) to form a cyclic complex c-H₂C(C)CHCH₃ that rapidly opens the ring to form H₂CCCHCH₃ followed by decomposition to HCCCHCH₃/H₂CCCCH₃/H₂CCCHCH₂ + H and H₂CCCH + CH₃; the corresponding branching ratios are 7:5:10:78 predicted with RRKM calculations at collision energy 4 kcal mol^?1. Nascent C₄H₅ with enough internal energy further decomposes to HCCCHCH₂ + H. Ratios of products C₄H₅, C₄H₄ and C₃H₃ are experimentally evaluated to be 17:8:75. This work provides a comprehensive look at product channels of the title reaction and gives implications for the formation of hydrocarbons in extra-terrestrial environments such as Titan and carbon-rich interstellar media. We suggest that the title reaction, hitherto excluded in any chemical networks, needs to be taken into account at least in the atmosphere of Titan and carbon-rich molecular clouds where rapid neutral–neutral reactions are dominant and carbon atoms and propene are abundant.