Using magnetic susceptibility to assess soil degradation in the Eastern Rif,Morocco

The soil in the Rif, Morocco, is at serious risk because increasing anthropogenic pressures are gradually transforming large natural areas into farmland. The distribution of magnetic minerals within the soil profile can be used to assess soil development and degradation. The soils in the study area are severely eroded because of a combination of highly erodible soils, intense rainstorms and scarce vegetation cover. To sample of representative soil profiles, lithology, slope gradient and land use were considered. The ranges of magnetic susceptibility in the soil profiles distinguished between two primary soil groups. Magnetic susceptibility varied in the soil profile and along the soil toposequence, and the variations were related to the differences in the original magnetic composition and the influence of main erosion factors. Lithology is the main factor contributing to the variation in magnetic susceptibility. The magnetic susceptibility values in soils on Tertiary marls (χ = 13·5 × 10^?8 m³ kg^?1) differed significantly from those on Quaternary terraces (χ = 122·1 × 10^?8 m³ kg^?1). Slope affected the distribution of magnetic susceptibility because of the continuous loss of topsoil in some parts of the slope and the deposition of eroded soil in others. Elimination of the natural vegetation cover and a shift to cultivated land for cereals has had a negative impact on soil development and, on similar slopes and substrates, magnetic susceptibility decreased significantly in cultivated soils. The soils on steep slopes that had natural vegetation cover retained the magnetic minerals better than did those on gentler slopes that were under cultivation. Grazing, clearing and, especially, tilling has weakened the soil and made it much more vulnerable to erosion. An analysis of the main factors causing erosion will help to promote rational use of the land and to establish conservation strategies in such fragile agroecosystems. Copyright © 2009 John Wiley & Sons, Ltd.     

Vertical and horizontal distribution of magnetic susceptibility and metal contents in an industrial district of central Iran

This study was conducted to determine the vertical and horizontal distribution of selected metals and magnetic susceptibility (χlf) in an industrial site located in Isfahan province, central Iran. For this purpose, we used a grid sampling methodology and excavated 202 profiles. Soil samples were then collected from 0–30, 60–90, and 120–150 cm depths. The mass magnetic susceptibility (χ) of the soil samples was measured at both low and high frequencies (χlf and χhf) using the Bartington MS2 dual frequency sensor; and χfd was also calculated. Soil samples were also analyzed for iron (Fe), manganese (Mn), lead (Pb), zinc (Zn), copper (Cu), nickel (Ni), chromium (Cr) and cobalt (Co) concentrations. The results showed that there were positive significant correlations among selected metals including Zn, Pb, Fe and Mn, which were mainly added through coal fly ash from an iron smelting factory at the studied site, while the concentration of Ni, Cr and Co was mainly controlled by the parent material of the soils. The trends in results at the site of study were similar in vertical and horizontal distribution for the industrial originated metals as judged by pollution load index (PLI) using χlf. The results of SEM/EDX also confirmed the presence of spheroid of magnetic particles in the surface soil samples taken in close proximity of the factory. Based on the results using the contamination factors (CF) determined for selected metals, the following order was observed: Pb > Zn > Mn > Fe > Cu > Ni ≥ Co > Cr. The results also suggested that magnetic methods could be used to estimate the metal contamination from anthropogenic sources in industrial soils.     

Broadband soil susceptibility measurements for EMI applications

When seeking low-metal targets, the success rate of an electromagnetic induction (EMI) system is often determined by the susceptibility of the soil near the object. In this paper, we begin the process of characterizing a random soil in terms of its effect on EMI sensor readings. After providing a brief review of the theory behind how soil susceptibilities affect EMI measurements, we measure the susceptibilities of 43 samples of soil from the United States, Puerto Rico, Iraq, and Afghanistan using a custom susceptibility sensor. We define a set of metrics and give the distribution of values for how magnetically active the soils are, how dispersive they are, and how well the commonly used log model fits to their susceptibility as a function of frequency. All measurements taken in the study are consistent with the log model of susceptibility if one accounts for the noise floor of the sensor. The sensor used for the measurements is described briefly and validated using a set of magnetic salts.     

Relationships between magnetic susceptibility and heavy metals in urban topsoils in the arid region of Isfahan, central Iran

Electromagnetic induction (EMI) method results are shown for vertical magnetic dipole (VMD) configuration by using the EM38 equipment. Performance in the location of metallic pipes and electrical cables is compared as a function of instrumental drift correction by linear and quadratic adjusting under controlled conditions. Metallic pipes and electrical cables are buried at the IAG/USP shallow geophysical test site in São Paulo City, Brazil. Results show that apparent electrical conductivity and magnetic susceptibility data were affected by ambient temperature variation. In order to obtain better contrast between background and metallic targets it was necessary to correct the drift. This correction was accomplished by using linear and quadratic relation between conductivity/susceptibility and temperature intending comparative studies. The correction of temperature drift by using a quadratic relation was effective, showing that all metallic targets were located as well deeper targets were also improved.     

Inter-laboratory calibration of low-field magnetic and anhysteretic susceptibility measurements

Inter-laboratory and absolute calibrations of rock magnetic parameters are fundamental for grounding a rock magnetic database and for semi-quantitative estimates about the magnetic mineral assemblage of a natural sample. Even a dimensionless ratio, such as anhysteretic susceptibility normalized by magnetic susceptibility (K_a/K) may be biased by improper calibration of one or both of the two instruments used to measure K_a and K. In addition, the intensity of the anhysteretic remanent magnetization (ARM) of a given sample depends on the experimental process by which the remanence is imparted. We report an inter-laboratory calibration of these two key parameters, using two sets of artificial reference samples: a paramagnetic rare earth salt, Gd₂O₃ and a commercial “pozzolanico” cement containing oxidized magnetite with grain size of less than 0.1 μm according to hysteresis properties. Using Gd₂O₃ the 10 Kappabridges magnetic susceptibility meters (AGICO KLY-2 or KLY-3 models) tested prove to be cross-calibrated to within 1%. On the other hand, Kappabridges provide a low-field susceptibility value that is ca. 6% lower than the tabulated value for Gd₂O₃, while average high-field susceptibility values measured on a range of instruments are indistinguishable from the tabulated value. Therefore, we suggest that Kappabridge values should be multiplied by 1.06 to achieve absolute calibration. Bartington Instruments magnetic susceptibility meters with MS2B sensors produce values that are 2-13% lower than Kappabridge values, with a strong dependence on sample centering within the sensor. The K_a/K ratio of ca. 11, originally obtained on discrete cement samples with a 2G Enterprises superconducting rock magnetometer and a KLY-2, is consistent with reference parameters for magnetites of grain size <0.1 μm. On the other hand, K_a values from a 2G Enterprises magnetometer and K values from a Bartington Instruments MS2C loop sensor for u-channel and discrete cement samples, will produce average K_a/K values that are unrealistically high if not properly corrected for the nominal volume detected by the sensors for these instruments. Inter-laboratory measurements of K and K_a for standard paleomagnetic plastic cubes filled with cement indicate remarkable differences in the intensity of the newly produced ARMs (with a standard deviation of ca. 21%), that are significantly larger than the differences observed from the calibration of the different magnetometers employed in each laboratory. Differences in the alternating field decay rate are likely the major source of these variations, but cannot account for all the observed variability. With such large variations in experimental conditions, classical interpretation of a “King plot” of K_a versus K would imply significant differences in the determination of grain size of magnetite particles on the same material.     

On the standardization of measurements of the anisotropy of magnetic susceptibility

The magnetic anisotropy of several artificially constructed samples has been measured with different types of instruments in several laboratories. Susceptibility bridge determinations have given consistent results, but the magnitude of the anisotropy determined by the Digico anisotropy delineator is incorrect. For future measurements with this instrument it is necessary to make either a simple calibration change or to make a minor change in the associated computer program. A set of equations for correcting the old published data is given.     

Assessment of heavy metal pollution in Xuzhou urban topsoils by magnetic susceptibility measurements

The concentrations of four selected heavy metals (Pb, Zn, Ni and Cr) were measured on 167 topsoil samples collected from the city of Xuzhou, China via inductively coupled plasma mass spectroscopy (ICP-MS). It was found that Pb and Zn were principally derived from anthropogenic inputs whereas Cr and Ni distributions were mainly controlled by parent materials. The spatial distribution patterns of Pb, and Zn were similar to that from low field magnetic susceptibility (χlf), suggesting interaction among them. Two threshold values for magnetic susceptibility and frequency-dependent susceptibility percentage (χfd) were applied to discriminate between polluted and unpolluted samples according to their magnetic susceptibility, resulting in 109 samples populating the “polluted” subset. The Pb and Zn concentrations of the “polluted” subset were statistically significantly higher than those measured in the “unpolluted” one. The heavy metal concentrations were also investigated varying the magnetic susceptibility thresholds to change the “polluted” subset.     

A portable magnetic susceptibility meter for measurements on rocks in situ and in laboratory

Summary An instrument for the measurement of the magnetic susceptibility of rocks in situ or in the laboratory has been described. The instrument is a completely portable and transistorised unit having a range from 5 to 50000×10^–6 CGS units of volume susceptibility. The accuracy of measurements is ±5%. It is rapid and simple in operation.This paper is published by the kind permission of the Director General, Geological Survey of India.     

重磁三维反演伊犁盆地中部密度和磁性结构

伊犁盆地中部区域地处多个构造单元的交汇区,构造复杂,缺乏高精度地质资料,制约了对盆地构造演化的进一步认识.本文联合使用多种先验信息作为约束条件,利用高精度重磁数据反演获得了研究区地下海拔-10 km以浅的三维密度和磁性结构,增强了反演结果的可靠性.结果揭示以白石墩次凸为中心发育了一个"北断南超"的南西-北东向不对称型凹陷,北部沉积厚度大于南部;区内主要断裂具有高角度特征,生烃中心受断裂控制,阿吾拉勒山前凹陷浅部可能发育逆掩断裂;火成岩以侵入的基性火成岩为主,伴有部分喷出火成岩和中酸性火成岩.     

Flow and emplacement direction determined for selected basaltic bodies using magnetic susceptibility anisotropy measurements

Low-field anisotropy of magnetic susceptibility (AMS) has been determined for a total of 248 basaltic specimens taken from cross sections between the cooling interfaces of 6 subaerial lavas, 6 deep-sea lavas, and 6 intrusives (5 dikes and 1 sill). Statistically significant AMS clusters are exhibited by all the dikes examined and, based upon these clusters, derivation of emplacement direction becomes possible. Two lavas are observed to have statistically significant AMS clusters which can be used for flow direction determinations. The methods of emplacement and flow direction analysis are discussed as well as the statistics used. It is concluded that most of the dikes examined have low angle emplacement directions. A classification scheme for AMS data distributions is presented.The AMS analysis shows that intrusives and deep-sea lavas can be distinguished from subaerial lavas approximately 80% of the time by the random AMS ellipsoid orientations exhibited in subaerial lavas. Contrasts in the fluid properties, degassing, wall effects with subsequent distortion of the fluid, and grain interaction during the extrusion of subaerial lavas can be expected to distort magnetic grain alignment. Further effects such as convection and secondary processes contribute to yield the random distributions observed for most of these bodies.     

Comparative study of top soil magnetic susceptibility variation based on some human activities

An investigation of the effect of some human activities on the magnetic susceptibility and frequency dependent susceptibility was conducted on top soil samples from, a commercial area, a motor park and a school environment in Jalingo, Taraba State, N-E Nigeria. The purpose was to assess the variation of magnetic susceptibility with different land use, detect pollution hotspots using magnetic proxy parameters and evaluate the contribution of superparamagnetic (SP) grain size contribution to the magnetic susceptibility from calculation of the frequency dependence of magnetic susceptibility (MS). The results of the mass specific low frequency magnetic susceptibility measurements showed significant enhancement with values ranging from 67.8 − 495.3 × 10⁻⁸ m³kg⁻¹ with a mean value of 191.61 × 10⁻⁸ × m³kg⁻¹ for the Jalingo College of Education (JCOE) data; 520.1 − 1612.8 × 10⁻⁸ m³kg⁻¹ with a mean value of 901.34 × 10⁻⁸ m³kg⁻¹ for the Jalingo main Market (JMM) and 188.5 − 1203.6 × 10⁻⁸m³kg⁻¹ with an average value of 574 92 × 10⁻⁶ m³kg⁻¹ for the Jalingo Motor Park (JMP). The significant magnetic enhancement indicates high concentration of ferrimagnetic minerals in the soil and hence increased pollution. The magnetic susceptibility of the different land use studied decreased in the order commercial area (market) > motor park > school premises. The results of the percentage frequency dependence susceptibility showed that most of the samples had a mixture of SP and coarse multi domain grains or SP grains < 0.05 µm. The value of χ_fd% range from 2.68 to 13.80% with an average value of 8.67% in the JCOE samples, 0.49 to 10.04% with an a-verage of 5.05% in the JMM samples and 0.56 to 13.04% with an average value of 5.86% in the JMP samples.     

羌塘盆地中部中上地壳三维密度和磁性结构及构造意义

羌塘盆地位于青藏高原中部,经历了多期复杂构造运动,是研究青藏高原演化的良好窗口.本文利用1 ∶ 20万重力和磁力数据,基于1 ∶ 50万地表地质信息约束,反演获得了羌塘盆地中部区域中上地壳的三维密度和磁性结构,揭示了南、北羌塘坳陷、班公湖—怒江缝合带、可可西里—金沙江缝合带和龙木错—双湖缝合带的密度和磁性特征.根据反演结果,认为：主要构造单元与密度和磁化率异常有良好的对应关系,下地壳和上地幔是羌塘盆地大范围低值重力异常的重要来源;可可西里—金沙江缝合带向下切割较深,引起磁异常的岩浆岩大量存在于中地壳;双湖至唐古拉山一线不存在贯穿羌塘盆地的“中央隆起带”;北羌塘广泛分布的火山岩主要存在于上地壳,来源可能是下地壳和上地幔的低密度岩浆岩体;印度板块俯冲的前缘可能影响到了羌塘盆地下方.

     

Field-induced anisotropy of magnetic susceptibility in rocks

Summary An induced anisotropy of magnetic susceptibility results from the domain alignment which is produced by treating stationary specimens in a strong alternating field. Appreciable domain re-orientation occurs in fields as low as 50 oersteds and the effect must therefore normally be an important part of the process of alternating field demagnetization. Induced anisotropy has been measured in a number of igneous rocks with a range of palaeomagnetic stabilities and in magnetite powders of controlled grain sizes, dispersed in plaster or kaolin specimens which were mechanically deformed to produce instrinsic magnetic anisotropy by grain alignment. The saturation magnitude of the induced anisotropy is not a function of grain size but the saturating field required increases with decreasing grain size. In the larger grains, induced anisotropy is a function of grain orientation.     

Sources of magnetic susceptibility in a slate

Magnetic susceptibility and its anisotropy in the Borrowdale Volcanic slates at Kentmere in the English Lake District are attributed largely to preferred orientation of a paramagnetic chlorite of diabantite-ripidolite composition. In units of 10⁻⁶ cgs/g, the principal susceptibilities for the slates are 9.61; 9.42; 8.69 and for the chlorite grains the minimum anisotropy is represented by principal susceptibilities of 11.57; 11.22 and 9.15. Because the magnetic susceptibility is carried by a tightly packed, matrix-forming mineral that has recrystallised during the deformation it is not possible to imagine simple grain rotation as being responsible for the anisotropy of susceptibility.     

Origin of layering in cumulate gabbros in the Oman ophiolite: Insights from magnetic susceptibility measurements in the Wadi Sadm area

Abstract   Magnetic susceptibility and the anisotropy of magnetic susceptibility were measured on an 800-cm-thick succession of cumulate gabbro in the Sadm area of the Oman ophiolite. The section contained three distinct cumulate units. The susceptibility tends to decrease upward in each from a melanocratic layer (several tens of centimeters thick) to a leucocratic layer (a few meters thick). The susceptibility decreases in accordance with the decreasing number of magnetite grains, which are the alteration product mainly of olivine minerals. This suggests the cyclic downward accumulation of olivine in the cumulate gabbro. The apparent strain deduced from the patterns of magnetic and grain fabrics was the result mostly of simple shear, so that the layering of gabbro is understood to be formed primarily by a crystal cumulus process followed by simple shear deformation.     

Seasonal reorganization of subglacial drainage inferred from measurements in boreholes

The effect of the formation of a major subglacial drainage channel on the behaviour of the subglacial drainage system of Haut Glacier d'Arolla, Switzerland, was investigated using measurements of borehole water level and the electrical conductivity and turbidity of basal meltwaters. Electrical conductivity profiles were also measured within borehole water columns to identify the water sources driving water level changes, and to determine patterns of water circulation in boreholes. Prior to channel formation, boreholes showed idiosyncratic and poorly coordinated behaviour. Diurnal water level fluctuations were small and driven by supraglacial/englacial water inputs, even when boreholes were connected to a subglacial drainage system. This system appeared to consist of hydraulically impermeable patches interspersed with storage spaces, and transmitted a very low water flux. Drainage reorganization, which occurred around 31 July, 1993, in response to rapidly rising meltwater and rainfall inputs, seems to have involved the creation of a connection between an incipient channel and a well-established channelized system located further down-glacier. Once a major channel existed within the area of the borehole array, borehole water level fluctuations were forced by discharge-related changes in channel water pressure, although a diversity of responses was observed. These included (i) synchronous, (ii) damped and lagged, (iii) inverse, and (iv) alternating inverse/lagged responses. Synchronous responses occurred in boreholes connected directly to the channel, while damped and lagged responses occurred in boreholes connected to it by a more resistive drainage system. Pressure variations within the channel resulted in diurnal transfer of mechanical support for the ice overburden between connected and unconnected areas of the bed, producing inverse and alternating patterns of water level response. © 1998 John Wiley & Sons, Ltd.     

Dependence of air pollution on meteorological conditions based on magnetic susceptibility measurements: a case study from Warsaw

This study reports systematic analysis of air pollution concentration by particulate matter (PM) in relation to annual changes of metrological conditions. The concentration of PM collected on filters was evaluated by magnetic properties. Long series of filters collected during 1977, 1980, 1981 and 1985 in Warsaw have been used for measurement. Such long time series allowed a better determination of correlation between seasonal susceptibility changes and meteorological conditions and to verify the repeatability of annual behavior. The magnetic susceptibility normalized by mass (??) has been used as a proxy of pollution. Monthly variations of ?? (??_m) demonstrated slow and small seasonal changes disturbed by quick, high peaks. The filters with high susceptibilities contain a mixture of magnetic single and multidomain grains which is characteristic for anthropogenic pollution, with the frequency-dependent susceptibility ??_fd being less than 4%. The low susceptibility samples are characterized by admixture of small amount of pseudo-single domain (PSD) and possible small amount of superparamagnetic (SP) grains. Detailed analysis of reduced mean monthly susceptibility ??_R revealed that temperature and absolute humidity correlate positively in cold period of year and negatively in warm months. The linear correlation coefficients range from 0.7 to 0.9 and from 0.3 to 0.4 for negative and positive linear correlation, respectively. The dispersion of pollutants in a city depends on the way of ventilation. The big cities like Warsaw are urban heat islands which act the most effective way for the warm period and for the cold time. The correlation of ??_R with absolute humidity is similar to that for temperature but for different reasons. The presence of big amount of water vapor particles in the atmosphere can favor the adhesion of smaller ferromagnetic grains to their surface which can accelerate the process of falling down of such agglomerates. Such a process can take place during wintertime. We do not observe clear correlation between ??_R and precipitation.     

Factors influencing magnetic susceptibility in the southern Pyrenees

We analyse paramagnetic, ferrimagnetic and frequency-dependent susceptibility in the southern Pyrenees and northern Ebro basin. The analyzed rocks show a wide range of values for the three parameters within the different lithological groups. Sandstones, shales and marls exhibit middle to high values of paramagnetic susceptibility while mudstones usually show low values. However, a general correlation can be established for the different rock types with a wide variability for each group (for example, Eocene marls show average values of paramagnetic susceptibility of 82% but within a range between 12 and 99%, or Flysch materials, with mean values of 47–52% within a range between 15 and 90%). These changes in the paramagnetic contribution to the susceptibility are due to the change in the ferrimagnetic susceptibility. This wide variability is independent of the sedimentological characteristics and can be related to the higher ferrimagnetic contribution to the susceptibility with similar ferrimagnetic mineral phase assemblages. The ferrimagnetic and superparamagnetic contributions, independent of site location with respect to individual macrostructures (thrusts and nappes), show a sharp increase at the occurrence of the macroscopic regional Pyrenean cleavage, probably relating both aspects with changes in pressure-temperature (P-T) conditions.     

The magnetic susceptibility measurements of turbidity current sediments from Fuxian Lake of Yunnan Province and their correlations with earthquakes

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Grandient measurements in the interpretation of magnetic anomalies due to two-dimensional prism-shaped bodies

Summary A direct method of interpreting magnetic anomalies due to two-dimensional prisms is presented here. Measurement of the first vertical derivative supplies additional information concerning the parameters. The normal ground magnetic profile, as well as the gradient profile will have symmetrical points whose distances from the origin are related to the width, depth and height of a two dimensional prism shaped body.