The transformation of the runoff of the suspended load in Kamchatkan rivers due to volcanism

This paper considers the influence of volcanic eruptions on the variation in the characteristics of the runoff of the suspended river load (suspended sediment concentration, discharge, rate of runoff, and grain-size distribution) on a variety of space–time scales (daily, seasonal, and long-term). The main factors that affect the yield of suspended load in rivers that flow in volcanic areas include the water runoff, drainage area, and the abundance of unconsolidated volcanic deposits. The areas of recent volcanism in Kamchatka are characterized by the maximum values of potential scour of particles, the mean long-term suspended sediment concentration, and specific suspended sediment yield. The largest increment in the transport of suspended river load in areas of volcanic activity is observed after major eruptions. The daily variations in the transport of suspended load are controlled by the water regime of rivers on the slopes of active volcanoes, namely, periodic cessations of surface runoff because of filtering into volcanic deposits.     

Numerical 3D modeling of the magnetotelluric field in Kamchatka

We consider the key features in the responses of magnetic tippers and MTS curves to the sharp contrast in electric conductivity at the interface between the land and the sea waters of the Sea of Okhotsk and the Pacific bounding Kamchatka. The zones with different intensity of the coast effect are revealed. Stronger manifestations of the effect are found to occur in the East Kamchatka, which is related to the induction effects of the electric currents concentrated in the Kuril-Kamchatka trench. Indentation of the coastline resulted in the appearance of three-dimensional (3D) effects in the magnetotelluric field of the eastern Kamchatka. These effects in the variations of the geomagnetic field are vanishing with an increasing period, giving room to low-frequency effects in the MT field, which are associated with the flow of electric currents around Kamchatka (the around-flow effect). It is shown that the transverse MTS curves over the entire region of Kamchatka suffer from the S effect at low frequencies and do not characterize the deep geoelectric structure. Only in the middle segments of the West and Central Kamchatka, the longitudinal MTS curves are weakly subjected to the induction effects and thus reflect the distribution of the deep electric conductivity. On the eastern coast of Kamchatka both the longitudinal and transverse MTS curves are strongly distorted by the 3D effects caused by the abundant capes and bays. The interpretation of MTS data in this region should necessarily invoke the 3D modeling of an MT field.     

Transport and deposition of plutonium in the ocean: evidence from Gulf of Mexico sediments

A study of sediments in the Gulf of Mexico shows dramatic gradients in Pu content and isotope ratios from the continental shelf to the Sigsbee Abyssal Plain. In terms of predicted direct fallout inventory of Pu, one shelf core contains 745% of the predicted inventory, while abyssal plain sediments contain only 15–20% of the predicted value. Absolute Pu concentrations of shelf sediments are also conspicuously high, up to 110 dpm/kg, compared to 13.5 dpm/kg in Mississippi River suspended sediment. There is no evidence of Pu remobilization in Gulf of Mexico shelf sediments, based on comparison of Pu profiles with Mn/Al and Fe/Al profiles. Horizontal transport of fallout nuclides from the open ocean to removal sites in ocean margin sediments is concluded to be the source of both the high concentrations and high inventories of Pu reported here.The shelf sediments show²⁴⁰Pu/²³⁹Pu ratios close to 0.179, the average stratospheric fallout value, but the ratios decrease progressively across the Gulf to low values of 0.06 in abyssal plain sediments. The source of low-ratio Pu in deep-water sediments may be debris from low yield tests transported in the troposphere. Alternatively, it may represent a fraction of the Pu from global stratospheric fallout which has been separated in the water column from the remainder of the Pu in the ocean. In either case, the low-ratio material must have been removed rapidly to the sea floor where it composes a major fraction of the Pu in abyssal plain sediments. Pu delivered by global atmospheric fallout from the stratosphere has apparently remained for the most part in the water or has been transported horizontally and removed into shallow-water sediments.     

Space and time variations of the runoff of Kamchatka Krai rivers

The current features of the space and time variations of river runoff in Kamchatka Krai have been considered. Two relatively long cycles have been shown to exist in water runoff variations in the major portion of the examined rivers. The renewable water resources were increasing until 1970–1980, while in the following years (up to 2010), they were gradually decreasing. Current data on river runoff were used to prove the existence of three zonal types of water regime in Kamchatka Krai; five azonal types of annual runoff distribution are characterized. One of them (nearly uniform annual distribution caused by the predominance of groundwater recharge) has been theoretically predicted in the classification proposed by M.I. L’vovich, though without factual confirmation. The specific features of water regime of rivers whose basins lie on the slopes of active volcanoes are considered for the first time. This type of regime typically shows alternating periods of the presence and absence of surface runoff in river channels, corresponding to the inflow of snowmelt or rainfall runoff at high level of subsoil water (when channel deposits are fully saturated with water) or at its low position (when moisture is deficient).     

Concentrations and annual fluxes of sediment‐associated chemical constituents from conterminous US coastal rivers using bed sediment data

Coastal rivers represent a significant pathway for the delivery of natural and anthropogenic sediment‐associated chemical constituents to the Atlantic, Pacific and Gulf of Mexico coasts of the conterminous USA. This study entails an accounting segment using published average annual suspended sediment fluxes with published sediment‐associated chemical constituent concentrations for (1) baseline, (2) land‐use distributions, (3) population density, and (4) worldwide means to estimate concentrations/annual fluxes for trace/major elements and total phosphorus, total organic and inorganic carbon, total nitrogen, and sulphur, for 131 coastal river basins. In addition, it entails a sampling and subsequent chemical analysis segment that provides a level of ‘ground truth’ for the calculated values, as well as generating baselines for sediment‐associated concentrations/fluxes against which future changes can be evaluated. Currently, between 260 and 270 Mt of suspended sediment are discharged annually from the conterminous USA; about 69% is discharged from Gulf rivers (n = 36), about 24% from Pacific rivers (n = 42), and about 7% from Atlantic rivers (n = 54). Elevated sediment‐associated chemical concentrations relative to baseline levels occur in the reverse order of sediment discharges: Atlantic rivers (49%) > Pacific rivers (40%) > Gulf rivers (23%). Elevated trace element concentrations (e.g. Cu, Hg, Pb, Zn) frequently occur in association with present/former industrial areas and/or urban centres, particularly along the northeast Atlantic coast. Elevated carbon and nutrient concentrations occur along both the Atlantic and Gulf coasts but are dominated by rivers in the urban northeast and by southeastern and Gulf coast (Florida) ‘blackwater’ streams. Elevated Ca, Mg, K, and Na distributions tend to reflect local petrology, whereas elevated Ti, S, Fe, and Al concentrations are ubiquitous, possibly because they have substantial natural as well as anthropogenic sources. Almost all the elevated sediment‐associated chemical concentrations found in conterminous US coastal rivers are lower than worldwide averages. Copyright © 2012 John Wiley & Sons, Ltd.     

Osmium isotope geochemistry in the Mackenzie River basin

The Cenozoic marine osmium isotope record is largely driven by changes in the continental input. We aid its interpretation by supplying direct measurements of present day riverine Os in known geological and environmental settings. We analyzed Os concentrations and isotopic ratios in the dissolved, suspended, and bed materials of the Mackenzie River in Canada and smaller rivers draining the Western Cordillera into the Pacific Ocean. Rhenium content was measured for suspended and bed materials to provide further constraint. Dissolved ¹⁸⁷Os/¹⁸⁸Os ratios range from 0.74 to 4.5 and are controlled to first order by age and lithology of the bedrock. The rivers draining Jurassic volcanic rocks are unradiogenic, as low as 0.74, and those draining the Precambrian Canadian Shield are radiogenic, as high as 3.5. The headwaters of the Mackenzie left bank tributaries draining metamorphic carbonates in the Eastern Cordillera and Paleozoic black and gray shales in the Transition zone and the Interior Platform are especially radiogenic (3.0-4.5) with relatively high concentrations of Os. These latter rivers are responsible for the Mackenzie being above world average in Os concentration and yield (mol Os/km²/year) as well as in ¹⁸⁷Os/¹⁸⁸Os. The dissolved load is more radiogenic than the suspended or bed loads and constitutes a significant fraction of total fluvial Os.     

Effects of placer mining on suspended sediment budget: case study of north of Russia’s Kamchatka Peninsula

Abstract

Placer mines are located in river valleys, along river benches, or along the pathways of ancient channels. Open-pit mining alters the stream hydrology and enhances sediment transport. The present study focuses on sediment transport in the area of the platinum placer mining located at the north of Russia’s Kamchatka Peninsula (Seynav-Galmoenan placer deposits). Based on hydrological field investigations, a conceptual model was derived to assess anthropogenic effects on the total sediment budget of rivers. The model illustrates key processes controlling sediment dynamics in the Vyvenka River basin. Field work included water-discharge and sediment-load measurements, assessment of annual channel change in rivers in mining site areas, and evaluation of the relative importance of sediment sources and transport processes. In this study, we estimated total sediment delivery from opencast placer mining of 60 t year^-1; the annual mass wasting rate ranges from 2 to 5.5 kg m^-2 year^-1, which is three orders of magnitude higher than from non-mined streams. Mass wasting dominates surface erosion on the hillslopes and produces significant wastewater effluents; however, erosion of the artificially stratified channel reaches is the primary contributor to the annual sediment yield of the mined rivers (21.4%).

Editor D. Koutsoyiannis

Citation Chalov, S.R., 2014. Effects of placer mining on suspended sediment budget: case study of north of Russia’s Kamchatka Peninsula. Hydrological Sciences Journal, 59 (5), 1081–1094.     

Uranium and thorium isotopes in the rivers of the Amazonian basin: hydrology and weathering processes

Two expeditions (October 1989 and May 1992) were carried out to two points of the main Amazon River channel and four tributaries. The Solimões and Madeira rivers, taking their origin in the Andes, are whitewater rivers. The Negro River is a typical acid, blackwater river. The Trombetas River flows through bauxite‐rich areas, and is characterized by low concentrations of dissolved humic substances. The ²³⁸U, ²³⁴U, ²³²Th and ²³⁰Th activities were recorded from dissolved, suspended particulate phases and river bank sediments. The latter were analysed for their ²²⁶Ra, ²²⁸Ra and ²¹⁰Pb contents, and also subjected to leaching with 0·2 M hydroxylamine–hydrochloride solution to determine the concentrations of radionuclides bound to amorphous Fe hydroxides and Mn oxides and hydroxides. The dissolved U average concentration in the Amazon system is ten times lower than the mean world river concentration. The uranium concentration observed at Óbidos in the lower Amazon (0·095 µg L^?1), where the U content in the river bank sediments and suspended matter is lowest, suggests U release from the solid phase during river transport. About 485 t of U are transported annually to the Amazon delta area in dissolved form, and 1943 t bound to suspended particulate matter. Total U and Th concentrations in the river bank sediments ranged from 1·59 to 7·14 µg g^?1 and from 6·74 to 32 µg g^?1, respectively. The highest concentrations were observed in the Trombetas River. The proportion extracted by means of the hydroxylamine solution (HL) was relatively high for U in the Trombetas river bank sediment (31%) and for Th in the Solimões sediment (30%). According to the alpha recoil effects, the ²³⁴U/²³⁸U activity ratios of the Andean river waters and downstream Amazon water (Óbidos) were >1, but were <1 in the Negro River (at Manaus). The activity ratios of dissolved U correlate with pH and also with the U activity ratios in the river bank sediment hydroxylamine extracts. As expected, the ²³⁴U/²³⁸U activity ratios in river bank sediments were <1 in the Andean rivers and in the downstream Amazon, but they were >1 in the Trombetas and Negro rivers. Such ratios probably result from the binding of dissolved uranium to solid sediment. The ²²⁸Th/²³²Th ratios of river bank sediments were close to unity (except for the Negro River, where it is lower), suggesting no significant Th exchanges between the river water and the sediment. The ²²⁶Ra/²³²Th activity ratios were <1, and the ²²⁶Ra/²²⁸Ra activity ratios generally were significantly higher than the activity ratios of their respective parents. This perhaps is the result of easier leaching of the ²²⁶Ra parent, ²³⁰Th, from solid material (owing to the alpha recoil effect) than of the ²²⁸Ra parent. Uranium and thorium isotopes were used as tools to evaluate the chemical weathering rate of rocks in the Amazon system, which was estimated to be 2·7 cm 1000 year^?1 s^?1. Copyright © 2002 John Wiley & Sons, Ltd.     

Modern (<100 years) sedimentation in the Taiwan Strait: Rates and source-to-sink pathways elucidated from radionuclides and particle size distribution

A large number of sediment cores collected during 2005-2010 from the Taiwan Strait were analyzed for radionuclides (²¹⁰Pb, ¹³⁷Cs and ⁷Be) to elucidate sedimentation dynamics in this all-important gateway linking two largest marginal seas in the western Pacific (namely, the South China Sea and the East China Sea). Apparent sediment accumulation rates derived from ²¹⁰Pb and ¹³⁷Cs profiles vary from <0.1 to >2 cm/yr, averaging ∼0.4 cm/yr and showing a spatial pattern closely related to hydrodynamics and sediment source-to-sink pathways. Spatial-temporal variation of ⁷Be activity in surface sediments off Taiwan’s west coast indicates episodic deposition of flood layers and their mobility from river estuaries toward the north. In conjunction with particle size distribution in surface sediments and the structure of sediment strata revealed by sub-bottom echo images; the radionuclide data can be used to outline three different sediment source-to-sink dispersal systems. Based on sediment loads of surrounding rivers and the distribution of sediment accumulation rates, lateral transport is required to account for the budget and size distribution of sediments in the strait.     

Accumulation,solid partitioning and remobilisation of 99Tc in subtidal and intertidal sediments in the Irish Sea

Recent studies have shown that accumulation of ⁹⁹Tc in seabed sediments labelled by authorised radioactive liquid discharges into the NE Irish Sea from the Sellafield reprocessing complex is greater than previously thought. In this paper, new data on ⁹⁹Tc concentration profiles in subtidal and intertidal sediments from the eastern and western Irish Sea are provided with a view to elucidating the processes responsible for the incorporation and retention of ⁹⁹Tc in the seabed. The data show that substantial amounts of ⁹⁹Tc have accumulated in the fine-grained subtidal sediments off the Cumbrian coast, particularly after increased releases from Sellafield following the commissioning of the Enhanced Actinide Removal Plant (EARP) in 1994. In all the cores taken in this area, ⁹⁹Tc has been found to be present to depths in excess of 30 cm. Analysis of ¹³⁷Cs and ²⁴¹Am profiles, together with other supporting geochemical data, show a high degree of homogenisation of the sediments down to these depths as a result of physical and biological processes, and confirm that incorporation of ⁹⁹Tc into the sediment compartment is actually the result of mixing and reworking, rather than active sediment accumulation. In contrast, active deposition of material transported from this mixed pool of sediment appears to be the dominant mechanism controlling ⁹⁹Tc profiles in intertidal areas close to the Sellafield discharge outfall.Data obtained from the analysis of subtidal sediment cores from the western Irish Sea mud basin suggest that similar mixing processes to those occurring in the subtidal sediments of the eastern Irish Sea are also active in this area. Time-series data on ⁹⁹Tc concentrations in surficial sediments from this basin, gathered in the period 1988–2004, inclusive, show a clear increase in concentrations, by a factor of ～2, between samples collected pre-EARP and post-EARP. The constancy of ⁹⁹Tc concentrations in surface sediments throughout the 1980s and the early-1990s suggests that little redissolution and export of ⁹⁹Tc occurred over this extended period. A similar observation applies to the post-EARP period, when concentrations remained relatively constant despite the reported steady decrease in ⁹⁹Tc concentrations in the overlying waters.This apparent lack of remobilisation is consistent with data from sequential extraction analyses, which indicate that the bulk of the ⁹⁹Tc is strongly bound to non-labile geochemical phases, with only a small proportion associated with exchangeable and acido-soluble phases. Further, these analyses show that ⁹⁹Tc is not associated with oxygen-sensitive and highly-reactive acid-volatile sulphides (AVS) to any significant extent.     

Sediment dispersal from a typical Mediterranean flood: The Têt River,Gulf of Lions

This paper describes an integrated study of a typical Mediterranean flood event in the Gulf of Lions. A flood with a 5-year return interval occurred in the Têt River basin and adjacent inner-shelf in the Gulf of Lions, northwest Mediterranean, during April 2004. Data were collected during this flood as part of event-response investigations of the EU-funded Eurostrataform (European Margin Strata Formation) project. Southeasterly storm winds led to a flood which directly modified the inner-shelf hydrodynamics. Sediment delivery to the coastal zone during this flood represented more than half of the mean annual discharge of the Têt River to the Gulf of Lions. This river transported a large amount of sand in suspension, representing 25% of the total suspended load, and as bedload representing 8% of the total load, during this event. Sand introduced in the nearshore was transported northwards during the peak storm and nourished a small delta. Fine sediments were separated from coarse sediments at the river mouth, and were advected southwards and seawards by the counter-clockwise general circulation. Fine-grained sediments were transported via a hypopycnal plume along the coast towards the southern tip of the Gulf of Lions and the Cap Creus canyon. The along-shore currents, which intensified from north to south of the Gulf of Lions, particularly between the Cap Creus promontory and the Cap Creus canyon, favoured the transfer of fine-grained sediments from the continental shelf of the Gulf of Lions towards the continental slope. Our results show that floods with a few-year return interval in small coastal rivers can play a significant role in the transport of sediments on microtidal continental margins and their export from the shelf through canyons.     

The Ganges and Brahmaputra rivers in Bangladesh: basin denudation and sedimentation

Every year the Ganges and Brahmaputra rivers in Bangladesh transport 316 and 721 million tonnes of sediment, respectively. These high loads of suspended sediment reflect the very high rate of denudation in their drainage basins. The average mechanical denudation rate for the Ganges and Brahmaputra basins together is 365 mm 10³ yr⁻¹. However, the rate is higher in the Brahmaputra Basin than that in the Ganges Basin. Several factors, including mean trunk channel gradient, relief ratio, runoff, basin lithology and recurring earthquakes are responsible for these high denudation rates. Of the total suspended sediment load (i.e. 1037 million tonnes) transported by these rivers, only 525 million tonnes (c. 51% of the total load) are delivered to the coastal area of Bangladesh and the remaining 512 million tonnes are deposited within the lower basin, offsetting the subsidence. Of the deposited load, about 289 million tonnes (about 28% of the total load) are deposited on the floodplains of these rivers. The remaining 223 million tonnes (about 21% of the total load) are deposited within the river channels, resulting in aggradation of the channel bed at an average rate of about 3·9 cm yr⁻¹. Although the Brahmaputra transports a higher sediment load than the Ganges, the channel bed aggradation rate is much higher for the Ganges. This study also documents a wide range of interannual, seasonal and daily variation in suspended sediment transport and water discharge. Interannual variation in sediment deposition within the basin is also suggested. Copyright © 1999 John Wiley & Sons, Ltd.     

Estimation of suspended sediment loads and delivery in an incised upland headwater catchment,south‐eastern Australia

Historically upland headwater catchments in south‐eastern Australia have undergone extensive gully erosion that has removed large amounts of sediment to lowlands. Recent research suggests these upland areas may continue to dominate fine sediment loads in lowland rivers. Improved understanding of sediment transfer through upland headwater catchments may have implications for interpreting downstream sediment supply. In this study a nested catchment design was utilized to examine suspended sediment yields and delivery from a small tributary sub‐catchment (1·64 km²) to the study catchment outlet (53·5 km²). Monitoring of suspended sediment concentration and discharge was undertaken for a period of nearly two years and used to estimate suspended sediment loads. Estimated total suspended sediment exports over the period of monitoring were 24·16 t from the sub‐catchment and 550·3 t from the catchment, which are generally less than previous reported small catchment yields in south‐eastern Australia. The extent of sediment delivery was examined using between‐site ratios of specific sediment yield per unit area and incised channel length. Sediment delivery was high under average rainfall conditions, but seasonally dependent. Both suspended sediment yields and the extent of delivery peaked over spring months, supplemented by remobilization of sediment stored during summer months in the main catchment channel. The findings of this study suggest much of the suspended sediment exported from small incised upland sub‐catchments (1–2 km²) may be delivered to downstream reaches under average rainfall conditions, which, in conjunction with the findings of previous research supports the potential importance of contributions from these areas to suspended sediment loads in lowland rivers during high flow periods. Copyright © 2007 John Wiley & Sons, Ltd.     

Dynamics of suspended sediment transport and yield in a large agricultural catchment,southwest France

The dynamics of suspended sediment transport were monitored continuously in a large agricultural catchment in southwest France from January 2007 to March 2009. The objective of this paper is to analyse the temporal variability in suspended sediment transport and yield in that catchment. Analyses were also undertaken to assess the relationships between precipitation, discharge and suspended sediment transport, and to interpret sediment delivery processes using suspended sediment‐discharge hysteresis patterns. During the study period, we analysed 17 flood events, with high resolution suspended sediment data derived from continuous turbidity and automatic sampling. The results revealed strong seasonal, annual and inter‐annual variability in suspended sediment transport. Sediment was strongly transported during spring, when frequent flood events of high magnitude and intensity occurred. Annual sediment transport in 2007 yielded 16 614 tonnes, representing 15 t km^?2 (85% of annual load transport during floods for 16% of annual duration), while the 2008 sediment yield was 77 960 tonnes, representing 70 t km^?2 (95% of annual load transport during floods for 20% of annual duration). Analysis of the relationships between precipitation, discharge and suspended sediment transport showed that there were significant correlations between total precipitation, peak discharge, total water yield, flood intensity and sediment variables during the flood events, but no relationship with antecedent conditions. Flood events were classified in relation to suspended sediment concentration (SSC)–discharge hysteretic loops, complemented with temporal dynamics of SSC–discharge ranges during rising and falling flow. The hysteretic shapes obtained for all flood events reflected the distribution of probable sediment sources throughout the catchment. Regarding the sediment transport during all flood events, clockwise hysteretic loops represented 68% from river deposited sediments and nearby source areas, anticlockwise 29% from distant source areas, and simultaneity of SSC and discharge 3%. Copyright © 2010 John Wiley & Sons, Ltd.     

Source area and seasonal 87Sr/86Sr variations in rivers of the Amazon basin

We report the results of a detailed study of dissolved Sr isotopes in the Solimões and Beni‐Madeira Rivers of the Amazon basin. This study developed data collected over 8 years indicating large spatial and temporal variations in dissolved Sr isotopes among the rivers of the Amazon basin. The large ⁸⁷Sr/⁸⁶Sr variations were found to be correlated with the geology of the source areas of the suspended sediments. The Beni‐Madeira River displays a high average ⁸⁷Sr/⁸⁶Sr ratio and large ⁸⁷Sr/⁸⁶Sr fluctuations during the hydrological cycle. This large average value and fluctuations were related to the presence of Precambrian rocks and Ordovician sediments in the source area of the suspended sediment of the river. In contrast, the Solimões River displays a narrow range of Sr isotope ratio variations and an average value close to 0.709. This river drains mostly Phanerozoic rocks of northern Peru and Ecuador that are characterized by low Sr isotope ratios. The isotopic fluctuations in the Beni‐Madeira River were observed to propagate downstream at least as far as Óbidos. This signal is characterized by an inverse relationship between the concentration of elemental Sr and its isotopic ratios. We further demonstrate that the Sr isotopic composition and content in the Beni‐Madeira River is controlled by suspended sediments derived from the Andes. Despite draining areas underlain by Precambrian rocks and having high ⁸⁷Sr/⁸⁶Sr ratios, such rivers as the Negro and Tapajós play a minor role in the total Sr budget of the Amazon basin. Copyright © 2013 John Wiley & Sons, Ltd.     

An investigation of the spatial variability of the grain size composition of floodplain sediments

River floodplains have been widely recognized as important sinks for storing suspended sediment and associated contaminants transported by river systems. The grain size composition of floodplain deposits exerts an important influence on contaminant concentrations, and commonly exhibits significant spatial variability in response to the dynamic nature of overbank flow and sediment transport. Information on the spatial variability of the grain size composition of overbank deposits is therefore essential for developing an improved understanding of the processes controlling sediment transport on floodplains, and for investigating the fate of sediment-associated contaminants. Such information is also important for validating existing floodplain sedimentation models. This paper reports the results of a study aimed at investigating the spatial variability of the grain size composition of floodplain sediments at different spatial scales, through analysis of surface sediment samples representative of contemporary floodplain deposits collected from frequently inundated floodplain sites on five British lowland rivers. Significant lateral and downstream variations in the grain size composition of the sediment deposits have been identified in the study reaches. An attempt has been made to relate the observed spatial distribution of the grain size composition of the overbank deposits to the local floodplain geometry and topography. The importance of the particle size characteristics of the suspended sediment transported by the rivers in influencing the spatial variability of the grain size composition of the overbank sediments deposited on these floodplains is also considered. © 1998 John Wiley & Sons, Ltd.     

Particulate carbon and nitrogen dynamics in a headwater catchment in Northern Thailand: hysteresis,high yields,and hot spots

Rivers of South and Southeast Asia disgorge large suspended sediment loads, reflecting exceptionally high rates of erosion promoted by natural processes (tectonic and climatic) and anthropogenic (land‐use change) activities that are characteristic of the region. While particulate carbon and nitrogen fluxes have been characterized in some large Asian rivers, less is known about the headwater systems where much sediment and organic material are initially mobilized. This study, conducted in the 74‐km² Mae Sa Experimental Catchment in northern Thailand, shows that the Sa River is an important source for particulate organic carbon (POC) and particulate organic nitrogen (PON) transported to larger river systems and downstream reservoirs. However, the yields during three years of investigation varied greatly: 5.0–22.3 Mg POC km^?2 y^?1 and 0.48–2.02 Mg PON km^?2 y^?1. The 22.3 Mg POC km^?2 y^?1 yield is the highest reported for any river on the Asian continent. Stream samples collected during 12 storms showed that almost 3% of the total suspended solid load is POC 0.7 µm to 2.0 mm in size. This percentage is higher than other values for most large rivers on the continent. Further, we documented a strong pulse hysteretic behaviour in the stream, whereby peak fluxes of POC and PON are often delayed (anticlockwise hysteresis) or accelerated (clockwise hysteresis) relative to stream flow peaks (or are complex), complicating the prediction of storm‐based or annual particulate carbon and nitrogen fluxes. Stream turbidity and total suspended sediment are reasonable proxies for POC and PON concentrations, while stream discharge is not a good predictor variable. Observed C:N ratios for measured particulate samples range from 3 to 83, with the high‐end values likely associated with fresh (non‐decomposed) vegetative material greater than 2 mm in diameter. The C:N ratio (weighted based on three sediment sizes) for 12 events ranges from 7.5 to 15.3. These modest values reflect the relatively low C:N ratios for small size fractions (0.7–0.63 µm) that comprise 50–90% of the TSS load in the events. Overall, organic material <0.63 µm contribute about 75% of the total POC load and 80% of the PON load. The annual C:N ratio for the river is approximately 10–11. Collectively, our findings indicate the occasionally high yields make the Sa River—and potentially other similar headwater rivers—a hot spot for POC and PON transported to downstream water bodies. Complex hysteresis patterns and high year‐to‐year variability hinders our ability to calculate and predict these yields without continuous, automated monitoring of discharge and turbidity. Copyright © 2016 John Wiley & Sons, Ltd.     

Large-volume silicic volcanism in Kamchatka: Ar–Ar and U–Pb ages,isotopic, and geochemical characteristics of major pre-Holocene caldera-forming eruptions

The Kamchatka Peninsula in far eastern Russia represents the most volcanically active arc in the world in terms of magma production and the number of explosive eruptions. We investigate large-scale silicic volcanism in the past several million years and present new geochronologic results from major ignimbrite sheets exposed in Kamchatka. These ignimbrites are found in the vicinity of morphologically-preserved rims of partially eroded source calderas with diameters from ～ 2 to ～ 30 km and with estimated volumes of eruptions ranging from 10 to several hundred cubic kilometers of magma. We also identify and date two of the largest ignimbrites: Golygin Ignimbrite in southern Kamchatka (0.45 Ma), and Karymshina River Ignimbrites (1.78 Ma) in south-central Kamchatka. We present whole-rock geochemical analyses that can be used to correlate ignimbrites laterally. These large-volume ignimbrites sample a significant proportion of remelted Kamchatkan crust as constrained by the oxygen isotopes. Oxygen isotope analyses of minerals and matrix span a 3‰ range with a significant proportion of moderately low-δ¹⁸O values. This suggests that the source for these ignimbrites involved a hydrothermally-altered shallow crust, while participation of the Cretaceous siliceous basement is also evidenced by moderately elevated δ¹⁸O and Sr isotopes and xenocryst contamination in two volcanoes. The majority of dates obtained for caldera-forming eruptions coincide with glacial stages in accordance with the sediment record in the NW Pacific, suggesting an increase in explosive volcanic activity since the onset of the last glaciation 2.6 Ma. Rapid changes in ice volume during glacial times and the resulting fluctuation of glacial loading/unloading could have caused volatile saturation in shallow magma chambers and, in combination with availability of low-δ¹⁸O glacial meltwaters, increased the proportion of explosive vs effusive eruptions. The presented results provide new constraints on Pliocene–Pleistocene volcanic activity in Kamchatka, and thus constrain an important component of the Pacific Ring of Fire.     

Water exchange between the subpolar and subtropical North Pacific in an OGCM

The water exchange between the subpolar and subtropical gyres of the North Pacific is demonstrated by the simulation of chlorofluorocarbon (CFC) using an ocean general circulation model. The simulated CFC concentration in the North Pacific is in good agreement with observations. The water exchange is clearly illustrated by the tongues of CFC concentration. The subpolar waters with high CFC are transported southward into the eastern subtropical gyre, whereas the subtropical waters with low CFC are transported northward into the western subpolar gyre. The simulated exchange transport along 42°N in the layer of σθ< 26.8 indicates that the northward mass transport is about 15 Sv (1 Sv = 106 m3·s-1) west of 165°E, and about 5 Sv between 175°W and 150°W. The southward mass transport is about 5 Sv between 165°E and 175°W, and about 2 Sv east of 150°W.     

Investigation of river network evolution using luminescence dating and heavy mineral analysis of Late-Quaternary fluvial sands from the Great Hungarian Plain

To reconstruct the evolution of Late-Quaternary river network in the southeastern part of the Great Hungarian Plain, we have used optically stimulated luminescence (OSL) and heavy mineral analysis of 25 sand samples from the upper 2–8 m of the fluvial units, complemented by four radiocarbon ages. The estimated OSL depositional ages vary between 10 and 47 ka. The heavy mineral composition of the OSL samples was compared to the compositional data of recent river sediments using cluster analysis. The new OSL and heavy mineral data show that from 47 to 10 ka ago the sediments were transported mainly from the northeast direction into the southeastern part of the Great Hungarian Plain by the ancestor of the Tisza river and its northern tributaries, and probably by another large river which also flowed northeast–southwest, parallel to the modern Tisza. Between 23 and 14 ka sediments periodically came from the east and reached the eastern part of our study area. Between 15 and 12 ka ago, sands transported from the southeast also occur in the southeastern and central part of the study area. These data suggest that the modern rivers occupied their present courses only in the last 10 ka.