松辽盆地松科2井早白垩世沙河子组天文年代标尺

对松辽盆地白垩纪国际大陆科学钻探工程——松科2井的沙河子组自然伽马测井数据(GR)开展了详细的旋回地层学研究。频谱分析结果揭示, 沙河子组上段(3336~4727 m)具有142~188 m、44~57 m、14 m和7~9 m的沉积旋回; 下段(4727~5960 m)具有170~205 m、44~61 m、16~18 m和7.5~11.5 m的沉积旋回。这些沉积旋回的周期之比近似早白垩世天文轨道周期之比20:5:2:1, 将这些沉积旋回依次解释为405 ka长偏心率、约100 ka短偏心率、约37 ka斜率和约20 ka岁差旋回。相关系数法(COCO)通过统计检验获得上、下段地层沉积速率约为40 cm/ka和56 cm/ka, 支持了该天文周期的解释。对405 ka长偏心率沉积旋回信号进行带通滤波, 并以松科2井3961 m处凝灰岩样品的锆石U-Pb二次离子探针年龄(U-Pb SIMS)113.9±0.9 Ma为锚点, 建立了松科2井沙河子组(112.3~118.2)±0.4 Ma的"浮动"天文年代标尺, 其持续时间约为5.92±0.4 Ma。本研究为确定早白垩世升温过程中松辽盆地重大环境和地质事件的年代提供了新的年代学约束, 为该时期全球海、陆相地质事件对比提供了年代学基础。     

松辽盆地科学钻探工程松科二井东孔上白垩统地球物理测井科学成果

松辽盆地科学钻探工程是围绕地球深部资源、古环境与古气候等一系列重要地球科学问题而实施的重大科学工程。作为该工程的主体钻孔, 松科二井东孔设计为松辽盆地最深钻孔, 设计深度6 400.0 m, 计划穿透白垩系地层、钻至盆地基底。由于上白垩统井段取心量非常少, 因此地球物理测井的作用尤为重要。该孔正式开钻后, 采用先进的成像测井设备对一开和二开钻井井段(上白垩统井段)先后实施4次裸眼井综合测井和套管井测井作业, 并系统地开展测井综合评价, 取得以下科学成果: (1)原位获取了常规测井、特殊测井和固井质量检查测井资料共20种, 资料丰富、质量优良, 建立了上白垩统连续的岩石物理参数标准剖面; (2)完成了上白垩统地层划分、岩性识别、沉积和构造精细解释; (3)识别出泉头组油气储层、嫩江组和青山口组烃源岩层、嫩江组高放射性异常层, 以及上白垩统地热开发潜力层; (4)探索了青山口组古气候分析的有利测井指标; (5)及时提供准确的井径、钻孔轨迹和固井质量等关键钻探工程信息。研究成果对于松辽盆地地球物理勘探科学“标尺”建立、古环境与古气候研究、钻探工程施工起到至关重要的作用, 为整个钻探工程科学目标的实现奠定良好基础。     

中国东北松辽盆地晚白垩世青山口组浮动天文年代标尺的建立

松辽盆地上白垩统青山口组主要由深湖相黑色泥岩、页岩组成,是大庆油田最重要的烃源岩之一,但长期以来对其年代学框架存在很大争议。对松辽盆地"松科1井"南井(茂206井)自然伽马测井和密度测井数据进行小波分析和连续滑动窗口频谱分析,表明茂206井青山口组记录了稳定的Milankovitch旋回。由长、短偏心率、地轴斜率和岁差周期造成的地层旋回厚度分别为39、13.5~9、5~3.8和2.5~1.7m。茂206井青山口组沉积速率变化不大,平均沉积速率为9.63cm/ka,沉积时限为5.16Ma。通过对长、短偏心率周期进行高斯带通滤波,建立了茂206井青山口组的"浮动"天文年代标尺。青山口组共记录了12.7个长偏心率周期和47.7个短偏心率周期。确定出青山口组1段下部油页岩层段对应的古湖泊缺氧事件(LAE1)持续时间约为250ka,与白垩纪Cenomanian-Turonian时期第二次大洋缺氧事件(OAE2)的持续时间接近。青山口组天文年代标尺的确立为约束青山口组沉积期各种地质事件的持续时间提供了年代学依据。     

松辽盆地晚白垩世古气候变化的测井替代指标

寻求指示古气候变化的测井替代指标是近年来古气候研究的重要途径和方向。测井曲线是地层岩 石学、岩石物理学、岩石地球化学特征的综合反映,具有连续性好、纵向分辨率高的特点,为反演古气候变化 提供了新的手段。松科１井作为专门为研究松辽盆地晚白垩世重大地质事件与古气候变化而部署的一口科学探 索井,具有系统的岩心资料和较完整的测井系列资料。文中在对松科１井南孔自然伽马能谱测井资料进行统计 的基础上,结合放射性元素地球化学分析结果,论证了钍／钾比（Th/K） 可以作为指示气候变化良好替代指标 的可行性,并据此对松辽盆地青山口组-嫩江组沉积时期的气候干湿变化进行了反演。结果表明：松辽盆地从 泉头组３段-嫩江组２段沉积时期气候总体表现为从潮湿向半干旱转化的趋势,垂向上可划分为３个完整的干 湿变化旋回。这一研究结论与前人在松辽盆地南部采用古生物学以及元素地球化学分析得出的结论相吻合,表 明根据自然伽马能谱资料统计得出的Yh/K值可以作为反演古气候变化的替代指标。     

High-precision geochronology of the Early Cretaceous Yingcheng Formation and its stratigraphic implications for Songliao Basin,China

The Songliao Basin in Northeast Asia is the largest and longest-lived rift basin and preserves a near-continuous continental succession of the most of the Cretaceous period, providing great material to investigate the adaption of the terrestrial systems to the Cretaceous greenhouse climate and tectonic events. However, the paucity of precise and accurate radioisotopic ages from the Early Cretaceous strata of the Songliao Basin has greatly held back the temporal and causal correlation of the continental records to the global Early Cretaceous records. Three tuff layers intercalated in the Yingcheng Formation have been intercepted by the SK-2 borehole, which offer excellent materials for radioisotopic dating and calibration of the chronostratigraphy of the Lower Cretaceous sequence of Songliao Basin. Moreover, the Yingcheng Formation recorded the largest and the last of the two major volcanic events in Songliao Basin, which also represents a turning point in the basin evolution history of Songliao from syn-rift stage to post-rift stage. Here we report high-precision U–Pb zircon geochronology by the CA-ID-TIMS technique on three tuff samples from the Yingcheng Formation of the SK-2 borehole in the Songliao Basin to construct a greatly improved, absolute age framework for the Yingcheng Formation and provide crucial age constraints for the Songliao Lower Cretaceous Strata. The new CA-ID-TIMS geochronology constrained the Yingcheng Formation at 102.571 + 0.320/?2.346 Ma to ca. 113 Ma, correlating to the Albian Stage. Combined with the previous published Songliao geochronology, the Quantou Formation is constrained to between 96.442 + 0.475/?0.086 Ma and 91.923 + 0.475/?0.086 Ma; the Denglouku Formation is constrained to between 102.571 + 0.320/?2.346 Ma and 96.442 + 0.475/?0.086 Ma; the age of the Shahezi Formation is estimated at ca. 113 Ma to ca. 118 Ma, which could extend to ca. 125 Ma in some locations in Songliao Basin. The major unconformity between the Yingcheng Formation and the Denglouku Formation, which represents the transition of the basin from syn-rift to post-rift is thus confined to between 102.571 + 0.320/?2.346 Ma and 96.442 + 0.475/?0.086 Ma. This is roughly contemporaneous with the change in the direction of the paleo-Pacific plate motion from west-southwest to north or northwest in mid-Cretaceous, suggesting their possible connections.     

松辽盆地北部晚白垩世陆相沟鞭藻及疑源类特征与沉积环境研究

通过对松辽盆地北部晚白垩世青山口组和嫩江组一段、二段中沟鞭藻及疑源类化石形态、丰度、分异度、优势度和组合等古生态特征研究 ,以及对微量元素硼含量、相当硼含量、锶钡比和硼镓比等地球化学特性的分析 ,得出在盆地北部沟鞭藻及疑源类化石的古生态、微量元素的分布规律与盆地内沉积相带的展布三者之间具有较好的相关性 ,说明松辽盆地的沟鞭藻及疑源类的发育和分布是由自生环境决定的。同时 ,通过专门对所谓“海侵”通道上的微体古生物和微量元素特征进行综合分析 ,未发现任何能证明海侵通道存在的证据 ,从而认为此海侵通道并不存在。     

Deep Continental Scientific Drilling Engineering Project in Songliao Basin: progress in Earth Science research

The Songke No.2 well (eastern hole) (referred to as Well SK-2), one of the “two wells and four holes” of the Deep Continental Scientific Drilling Engineering Project in the Songliao Basin, is in Anda City, Heilongjiang Province, and was officially completed on May 26, 2018. The scientific goals of Well SK-2 cover four aspects: paleoclimate research, resource and energy exploration, primary geological research, and development of deep earth exploration techniques. Since the official commencement of drilling in 2014, the Well SK-2 scientific drilling engineering team has organized and implemented drilling for coring, in situ logging, chemical analysis of core elements, and deep structural exploration around the well. Currently, the following preliminary scientific research progress has been made: 4334.81 m in situ core data has been obtained; the centimeter-level high-resolution characterization of the most complete and continuous Cretaceous continental strata ever unearthed has been completed, and the standard profile of continental strata has been initially established; the unconventional natural gas resources and basin-type hot dry rocks in the deep Songliao Basin were found to have good prospects for exploration and development; the climatic evolutionary history of the Cretaceous continental strata was rebuilt for the first time, covering hundreds of thousands to millions of years, and the major events of Cretaceous climate fluctuations have been discovered; all these reveal strong evidence for the subduction and aggregation of paleo-ocean plates, providing a theoretical basis for the re-recognition of the genesis of the Songliao Basin and for deep earth oil and gas exploration. The implementation of the Deep Continental Scientific Drilling Engineering Project in the Songliao Basin is of great significance for exploring the mysteries of the Earth and solving major problems such as those related to the deep energy environment. It is a solid step along the road of “going deep into the Earth”.     

Ostracod Biostratigraphy of the Late Cretaceous Qingshankou Formation in the Songliao Basin

An ostracod biostratigraphic study was performed on 425 samples from the composite geological section constructed by using cores taken from five selected wells drilled in the Late Cretaceous Qingshankou Formation in the Songliao basin.A total of 19 ostracod zones are established in the formation,of which 3 are newly established and 3 are revised.The 19 ostracod zones are described in detail.This study provides a basis for the detailed stratigraphic division and correlation of the Qingshankou Formation and the Gaotaizi oil reservoir in the oilfield in the Songliao basin.     

Late Cretaceous marine fossils and seawater incursion events in the Songliao Basin,NE China

The Songliao Basin is the largest non-marine oil-bearing basin in China. Because of the absence of substantial evidence, the hypothesis of seawater incursion events into the Songliao Basin remains controversial. The presence of marine fossils could provide direct proof to support this supposition. Here, we report new discoveries of foraminifera, calcareous nannofossils, brackish dinoflagellates, and other marine and brackish-water fossils to support the suggestion of seawater incursion events in the Songliao Basin. Relatively abundant benthic and planktonic foraminifera, calcareous nannofossils, marine and brackish-water dinoflagellates, fish, and bivalves have been discovered in Members 1 and 2 of the Nenjiang Formation, a few foraminifera and brackish-water dinoflagellates have been found in the lower Qingshankou Formation, and just a few brackish-water bivalves have been found in the uppermost Qingshankou Fm. Based on the presence of marine molecular fossils and other evidence, we suggest that relatively large seawater incursion events occurred during the sedimentation of the lower Nenjiang Fm., relatively smaller seawater incursions occurred during the deposition of the lower Qingshankou Fm., and possibly a very small seawater incursion occurred during the sedimentation of the uppermost Qingshankou Fm. These seawater incursion events in the Songliao Basin were controlled by regional tectonic activity, evolution of the palaeo Songliao Lake, and global sea level change. These periodic seawater incursions brought marine biota into the palaeo Songliao Lake.     

松辽盆地上白垩统陆相遗迹化石及其沉积环境

松辽盆地上白垩统中含有丰富的遗迹化石,通过对该盆地20余口取心井岩心的详细观察,发现了6大类动物遗迹化石15属20种。根据这些遗迹化石的分布规律,在松辽盆地上白垩统中划分出5种遗迹化石组合：（1）Scoyenia遗迹组合,主要成分有Scoyenia gracilis、Skolithos和Planolites,偶见停息迹化石,反映的是遭受周期性暴露的极浅水环境;（2）Skolithos遗迹组合,主要以Skolithos和Cylindricum十分发育为特征,分异度小,丰度高,反映的是高能动水环境。（3）Arenicolites遗迹组合,主要以Arenicolites和Polykladichnus大量发育为特征,还见有Skolithos、Planolites、Thalassinoides和逃逸迹等化石,分异度较高,反映了水流能量较低的浅水环境;（4）Planolites遗迹组合,以密集分布的Planolites十分发育为特征,分异度小,丰度高,见有少量指示缺氧环境的Chondrites化石,反映了水体较平静的还原环境;（5）Fuersichnus遗迹组合,主要由Fuersichnus、Glockeria、Gordia、Megagrapton和Planolites等遗迹分子构成,反映了相对平静的深水环境。     

Characterizing the Micropores in Lacustrine Shales of the Late Cretaceous Qingshankou Formation of Southern Songliao Basin, NE China

Micropores of shale are significant to the gas content and production potential of shale, which has been verified in the research of marine shale gas; while, few studies have been conducted on lacustrine shales. This study collected 42 samples from three wells in the Late Cretaceous Qingshankou Formation of the southern Songliao Basin, NE China, and investigated these samples by the focused ion beam-scanning electron microscope (FIB–SEM) and nitrogen adsorption analysis techniques. Four types of micropores were identified in the samples, i.e., intergranular pore, intracellular pore, organic matter pore and microfracture. The pore structure type is characterized by open slit pores and “ink type” pores which are mainly 1.5–5 nm in diameter with mesopores as the main pores. The mesopores account for 74.01% of the pore volume and 54.68% of the pore surface area. Compared with the lacustrine shales from the Triassic Yanchang Formation in the Ordos Basin and Xujiahe Formation in the Sichuan Basin, the intergranular clay mineral interlayer pores are considered to be the main reservoir space for shale gas storage in the study area, followed by intraparticle pores, organic matter pores and microfractures. Maturity and micropore are the key controlling factors which affect the shale gas content of the Qingshankou Formation in southern Songliao Basin.     

松辽盆地断陷期白垩纪营城组的时代归属

本文结合生物地层,同位素年代学,古地磁及地层序列的最新研究成果,探讨了松辽盆地断陷期营城组的时代归属。营城组孢粉组合多繁盛于白垩纪早—中期的Hauterivian期—Albian期;营城组同位素年龄分布表现出两个峰值135 ~ 120Ma和115 ~ 110Ma,结合采样层位及地层序列特征认为135~130Ma代表营城组下段中基性火山岩的年龄,130 ~ 120Ma代表营城组一段酸性火山岩的年龄,115~110Ma代表营城组三段基性火山岩及顶部酸性火山岩的年龄;古地磁研究表明在Hauterivian期底界偏上的135Ma发生过磁性的倒转以及松辽盆地的快速北移。这些特征表明营城组的时代为Hauterivian期—Albian早期,同位素年龄为135 ~ 110Ma。     

Late Cretaceous chronostratigraphy （Turonian-Maastrichtian）： SK1 core Songliao Basin, China

Non-marine ostracodes,charophytes and palynomorphs are abundant in most Cretaceous lacustrine basins of East Asia.However,their ranges are not directly integrated with marine biota that defines the Cre...     

Late Cretaceous lithoevents in the Bohemian Cretaceous Basin, Czechoslovakia

Facies evolution and vertical changes within the Late Cretaceous sequence of the Bohemian Cretaceous Basin reveal fluctuations of intra- and extrabasinal circumstances. Evidence of periodic oscillations is recognized and two categories of aperiodic event indications are distinguished according to their significance and lateral persistence. Several lithoevents may be related to eustatic changes, while others indicate the independent evolution of the basin, influenced by epeirogenetic movements of segments of the Bohemian Massif.     

松辽盆地姚家组-嫩江组地层层序及沉积演化

松辽盆地姚家组-嫩江组是晚白垩世形成的一套完整的水进-水退沉积旋回,分为2个二级层序,6个三级层序,持续时间约4Ma。嫩江组二段最大湖泛期在底部形成了盆地范围内稳定分布的油页岩,其不仅是层序及地层对比的标准界面,而且是重要的烃源岩层和盖层。姚家组与嫩江组一段是水进期大型退积型三角洲沉积,嫩江组三段是水退期大型湖泊与快速进积大型三角洲沉积。嫩江组在水进期长轴物源方向发育大型重力流水道及末端浊积扇,水道延伸距离64km,最大宽度600m;在水退初期短轴方向发育滑塌浊积扇,扇体有复合式和单体式,滑塌最小古坡度为5%~12‰,表面均发育弧状滑塌波纹,波纹密度4~10条/km,最小滑移距离2~10km。     

The Cretaceous volcanic succession around the Songliao Basin,NE China: relationship between volcanism and sedimentation

With volume ratio of 8:1:1.5 amongst acidic, intermediate and basaltic rocks, the Cretaceous volcanics around the Songliao Basin are a series of high‐K or medium‐K, peraluminous or metaluminous, calc‐alkaline rocks, lacking typical basalts and peralkaline members of typical rift‐related types. Their eruption ages range between 133 and 127 Ma, 124 and 122 Ma and 117 and 113 Ma respectively. They are high in total (Rare earth element) REE contents (96.1–326 ppm), enriched in LREE and depleted in HREE (LREE/HREE = 4.6–13.8), with negative Eu and Ce anomalies (Eu/Eu* = 0.04–0.88; Ce/Ce* = 0.60–0.97). They have enriched large‐ion lithophile elements (e.g. K, Ba, Th) and depleted high field strength elements (e.g. Nb, Ti and Y), suggesting a subduction‐related tectonic setting. The volcanic activities migrated from south to north, forming a successively northward‐stepping volcanic series and showing a feature significantly different from the overlying sedimentary sequence striking northeast. Thus, an overlap basin model was proposed. Accompanied by opening of the basin, the volcanogenic succession was formed at the block‐faulting stage (131–113 Ma) owing to the closure of the Mongolia–Okhotsk ocean in the Jurassic and early Cretaceous, while the overlying sedimentary sequence was unconformably deposited at the spreading stage (Albian–Maastrichtian) owing to the oblique subduction of the Pacific plate under the Eurasian plate. The volcanic succession constitutes the lower unit of basin filling and is the forerunner of further basin spreading. Copyright © 2002 John Wiley & Sons, Ltd.     

松辽盆地松科1井上白垩统嫩江组三～五段沉积序列厘米级精细刻画：岩性·岩相·旋回

中国白垩纪大陆科学钻探松科1井连续取嫩江组三～五段岩心长532．07rn,岩心收获率为94．8％,是迄今获取的最连续完整的沉积记录。文章对此进行了厘米级沉积地质描述（分层厚度2～5cm）。嫩三～五段沉积时期与坎潘阶中期对应。通过对松科1井嫩三～五段岩心的精细描述,揭示其岩性一岩相一旋回的沉积序列及其过程。嫩三～五段识别...     

Characterization of a Lacustrine Shale Reservoir and the Evolution of its Nanopores: A Case Study of the Upper Cretaceous Qingshankou Formation in the Songliao Basin,Northeastern China

The Songliao Basin is one of the most important petroliferous basins in northern China. With a recent gradual decline in conventional oil production in the basin, the exploration and development of unconventional resources are becoming increasingly urgent. The Qingshankou Formation consists of typical Upper Cretaceous continental strata, and represents a promising and practical replacement resource for shale oil in the Songliao Basin. Previous studies have shown that low-mature to mature Qingshankou shale mainly preserves type Ⅰ and type Ⅱ1 organic matter, with relatively high total organic carbon(TOC) content. It is estimated that there is a great potential to explore for shale oil resources in the Qingshankou Formation in this basin. However, not enough systematic research has been conducted on pore characteristics and their main controlling factors in this lacustrine shale reservoir. In this study, 19 Qingshankou shales from two wells drilled in the study area were tested and analyzed for mineral composition, pore distribution and feature evolution using Xray diffraction(XRD), scanning electron microscopy(SEM), low-pressure nitrogen gas adsorption(N2-GA), and thermal simulation experiments. The XRD results show that clay, quartz, and feldspar are the dominant mineral constituents of Qingshankou shale. The clay minerals are mostly illite/smectite mixed layers with a mean content of 83.5%, followed by illite, chlorite, and kaolinite. There are abundant deposits of clay-rich shale in the Qingshankou Formation in the study area, within which many mineral and organic matter pores were observed using SEM. Mineral pores contribute the most to shale porosity;specifically, clay mineral pores and carbonate pores comprise most of the mineral pores in the shale. Among the three types of organic matter pores, type B is more dominant the other two. Pores with diameters greater than 10 nm supply the main pore volume;most are half-open slits and wedge-shaped pores. The total pore volume had no obvious linear relationship with TOC content, but had some degree of positive correlation with the content of quartz + feldspar and clay minerals respectively. However, it was negatively correlated with carbonate mineral content. The specific surface area of the pores is negatively related to TOC content, average pore diameter, and carbonate mineral content. Moreover, it had a somewhat positive correlation with clay mineral content and no clear linear relationship with the content of quartz + feldspar. With increases in maturity, there was also an increase in the number of carbonate mineral dissolution pores and organic matter pores, average pore diameter, and pore volume, whereas there was a decrease in specific surface area of the pores. Generally, the Qingshankou shale is at a low-mature to mature stage with a TOC content of more than 1.0%, and could be as thick as 250 m in the study area. Pores with diameters of more than 10 nm are well-developed in the shale. This research illustrates that there are favorable conditions for shale oil occurrence and enrichment in the Qingshankou shale in the study area.     

松辽盆地晚白垩世青山口组缺氧事件层的地质地球化学特征

松辽盆地白垩系青山口组下部广泛分布一套富含有机碳的黑色泥岩、页岩沉积,是全盆地地层划分对比的一级标志。茂206井是中国白垩纪大陆科学钻探工程井,全井获取了青山口组497.02 m的岩心资料。茂206井青山口组具有相对高的有机碳、干酪根碳同位素正偏、重排甾烷含量低以及普遍存在伽马蜡烷生物标志化合物等有机地球化学特征,表征为白垩纪温室效应时间窗内古湖泊缺氧事件的产物。结合生物地层研究成果,认为青山口期缺氧事件层大体可与白垩纪古海洋Cenomanian-Turonian界线事件层进行对比,进一步证实了青山口组的地质时代属晚白垩世晚Cenomanian-Turonian期的观点。     

松辽盆地白垩纪青山口阶的同位素地层标志及其与海相Cenomanian阶的对比

本研究利用大庆油田在松辽盆地中部的岩心样品进行了青山口组有机碳稳定同位素的测试,通过化学地层和生物地层研究提出了青山口阶的顶底标志。在青山口组底部同位素值最低,为- 32 .2‰,与介形虫Cypridea elliptica的消失界面吻合。同位素值随后迅速上升,形成底界之上的第一个峰值,为- 2 8.1‰。随后的4个峰值自下而上分别是- 2 8‰、- 2 7.8‰、- 2 7.3‰和- 2 6 .6‰,相间的低峰值一般处于- 30‰～- 2 9‰左右。最为重要的是,有机碳稳定同位素值在青山口组顶部出现一个明显的异常,由- 2 9.5‰急剧升为- 2 3.1‰,随后又迅速降为- 30 .12‰,形成一个明显的正向峰值。这一正向偏移的位置与介形类Cypridea panda和Triangulicyprisfusiformis的消失界面基本吻合,并与全球Cenom anian- Turonian界线稳定同位素事件表现一致。据此,将这一稳定同位素正向偏移确定为青山口阶顶界的化学标志。通过这一标志可以将青山口阶的顶界与海相Cenom anian阶顶界进行对比。研究结果表明,化学地层标志是陆相与海相地层的对比的渠道。青山口阶的有机碳稳定同位素值具有全球一致的意义,与我国西藏南部海相地层,乃至全球重要地区Cenomanian- Turonian阶稳定同位素界线均具有可比性。