Comparing methods and sediment contaminant indicators for determining produced water fate in a Louisiana estuary

Produced water is a high salinity by-product resulting from oil and gas production. Disposal methods include surface water discharge. The current field method used to determine its fate in estuarine systems involves extending a compass oriented transect (COT) from the point source discharge--a method designed for a uniformly dispersing effluent discharged into a uniform offshore environment that may be inappropriate for the hydrologic and geomorphologic complexities found in estuarine systems. Prior research established the viability of the salinity stratification transect (SST) method. Both COT and SST methods were used in a small open bay to determine which more accurately detected effluent dispersion. Determination was based on sediment contaminant indicators (SCIs), including interstitial salinity, hydrocarbons, metals, and radium concentrations. Additionally, SCIs were evaluated for their ability to serve as indicators of effluent dispersion. The data revealed that SST stations exhibited higher contaminant concentrations and that this approach was more accurate in tracking the produced water plume. The data also suggested that SCIs varied in their ability to serve as indicators. Good indicators included interstitial salinity, total targeted aromatic hydrocarbons substantiated with a modified fossil fuel pollution index value, certain metals, and radium-228.     

Modelling of hydrodynamics and cohesive sediment transport in Tanshui River estuarine system,Taiwan

A laterally averaged two-dimensional numerical model is used to simulate hydrodynamics and cohesive sediment transport in the Tanshui River estuarine system. The model handles tributaries as well as the main stem of the estuarine system. Observed time series of salinity data and tidally averaged salinity distributions have been compared with model results to calibrate the turbulent diffusion coefficients. The overall model verification is achieved with comparisons of residual currents and salinity distribution. The model reproduces the prototype water surface elevation, currents and salinity distributions. Comparisons of the suspended cohesive sediment concentrations calculated by the numerical model and the field data at various stations show good agreement. The validated model is applied to investigate the tidally averaged salinity distributions, residual circulation and suspended sediment concentration under low flow conditions in the Tanshui River estuarine system. The model results show that the limit of salt intrusion in the mainstem estuary is located at Hsin-Hai bridge in Tahan Stream, 26 km from the River mouth under Q75 flow. The null point is located at the head of salt intrusion, using 1 ppt isohaline as an indicator. The tidally averaged sediment concentration distribution exhibits a local maximum around the null point.     

Crustacean assemblages in a polluted estuary from South-Western Spain

The spatial-temporal variation in crustacean assemblages of the Odiel-Tinto estuary, one of the most polluted areas in the world, was studied in 2000, 2002 and 2004. The crustacean assemblages were mainly established according to the natural gradient from estuarine to marine environment (based on water and sediment characteristics such as dissolved oxygen, salinity, granulometry or organic content). Pollutants such as copper, zinc or phosphates could also explain partially this pattern based on BIOENV and canonical correspondence analyses. However, there were clear symptoms of perturbation, mainly in the inner areas, such as a low number of species and a low abundance, especially in relation to the typical estuarine species (e.g. Cyathura carinata, Corophium spp.). This study provides baseline information which can be used as a reference point in a long-term perspective.     

The role of salinity in fluvio-deltaic morphodynamics: A long-term modelling study

Salinity difference between terrestrial river discharge and oceanic tidal water plays a role in modifying the local flow field and, as a consequence, estuarine morphodynamics. Although widely recognized, recent numerical studies exploring the long-term morphological evolution of river-influenced estuaries with two-dimensional, depth-averaged models have mostly neglected salinity. Using a three-dimensional morphodynamic model, we aim to gain more insight into the effect of salinity on the morphodynamics of fluvio-deltaic systems. Model results indicate that the resultant estuarine morphology established after 600 years differs remarkably when a salinity gradient is included. A fan-shaped river-mouth delta exhibits less seaward expansion and is cut through by narrower channels when salinity is included. The inclusion of salinity tends to generate estuarine circulation, which favours landward sediment transport and hence limits the growth of the delta while enhancing the development of intertidal areas. The formation of deltaic channel–shoal patterns resulting from morphodynamic evolution tends to strengthen salinity stratification, which is characterized by an increased gradient Richardson number. The direction of the depth-averaged residual sediment transport over a tide may be opposite to the direction of residual velocity, indicating the significant influence of baroclinic effects on the net sediment transport direction (and hence morphological change). The effect of salinity on morphological evolution becomes less profound when the strength of tidal or fluvial forcing is dominant over the other. The effects of sediment type and flocculation, which are particularly important when salinity gradients are present, are also discussed. Overall, this study highlights that neglecting salinity to simulate long-term estuarine morphodynamics requires more careful justification, particularly when the environment is characterized by fine sediment types (favouring suspended transport), and relatively large river discharge and estuarine depth (favouring baroclinic effects). © 2020 John Wiley & Sons, Ltd.     

Estuarine modification of nutrient and sediment exports to the Great Barrier Reef Marine Park from the Daintree and Annan River catchments

Nutrient and suspended sediment concentrations were measured in the dry season and during the rising and falling stages of flood events in the Annan and Daintree rivers to estimate catchment exports. These flood events were also sampled along the salinity gradient in the estuary and nearshore shelf to quantify the modification of terrestrial sediment and nutrient loads as they pass through estuaries into the Great Barrier Reef lagoon. In the Daintree River TSS concentrations were found to increase between the catchment and the estuary plume. The source of TSS may have been scour of the estuarine channel or from land use in the catchment of the lower estuary. In the dry season nitrogen enters the Annan and Daintree estuaries predominantly in the form of PON and DON in roughly equal proportions. Nitrogen exports to the GBR are mostly in the form of DON. In the wet season the majority of nitrogen enters the estuaries as DON and leaves as PON. Nitrogen removal in the estuaries and plumes appears to be biologically mediated once suspended sediment concentrations decrease to a point where phytoplankton growth is not light limited. In the dry season phosphorus enters and leaves the estuaries primarily in organic form. PIP is the dominant form of phosphorus in river water, but leaves the estuary more evenly distributed between all forms. These estuarine processes result in less nitrogen and phosphorus being delivered to the GBR lagoon than is exported from the catchment. The differences between these estuaries highlights the need for further work to explore modifications in estuaries that drain into the Great Barrier Reef lagoon.     

Trace metals and radium in the Gulf of Mexico: An evaluation of river and continental shelf sources

Several studies have provided evidence for the enrichment of trace elements in coastal waters, particularly for copper. These enrichments have been attributed to diffusion from continental shelf sediments and to an influx of river water. We attempted to resolve between these sources by undertaking an extensive suite of measurements of trace metals (Cu, Ni, Cd), ²²⁶Ra and ²²⁸Ra in the surface waters of the Gulf of Mexico, along with trace metal profiles at 6 stations (April 1981 and December 1982). These data establish that enrichments of copper, nickel and cadmium occur in the shallow waters of the Gulf of Mexico. On the Mississippi continental shelf, high trace element concentrations (Cu, Ni: ～ 9 nmol/kg; Cd: ～ 200 pmol/kg) in lower-salinity waters (26‰) are similar to those observed in the Mississippi plume at the same salinity. This evidence suggests a river water source. On the other hand, trace element enrichments are also observed in the northern Gulf (Cu: +0.4 nmol/kg; Ni: +0.5 nmol/kg; Cd: +20 pmol/kg) which coincide with an increase in ²²⁸Ra but are not accompanied by decreased salinity. The excess of evaporation over precipitation in this region makes it possible that this water could be evaporated estuarine water; therefore, hydrographic observations cannot distinguish readily between river and shelf sources. A regional flux balance shows that most of the excess copper in the surface waters of the Florida Current can be supplied by the river-borne dissolved copper flux. Within the uncertainties of such calculations, the continental shelf copper flux must be less than or equal to the river flux.     

The history of water salinity in the Pearl River estuary,China, during the Late Quaternary

This research reconstructed the Late Quaternary salinity history of the Pearl River estuary, China, from diatom records of four sedimentary cores. The reconstruction was produced through the application of a diatom–salinity transfer function developed based on 77 modern surface sediment samples collected across the estuary from shallow marine environment to deltaic distributaries. The statistical analysis indicates that the majority of sediment samples from the cores has good modern analogues, thus the reconstructions are reliable. The reconstructed salinity history shows the older estuarine sequence formed during the last interglacial was deposited under similar salinity conditions to the younger estuarine sequence, which was formed during the present interglacial. Further analysis into the younger estuarine sequence reveals the interplays between sea level, monsoon‐driven freshwater discharge, and deltaic shoreline movement, key factors that have influenced water salinity in the estuary. In particular, a core from the delta plain shows the effects of sea‐level change and deltaic progradation, while cores from the mouth region of the estuary reveal changes of monsoon‐driven freshwater discharge. This study demonstrates the advantages of quantitative salinity reconstructions to improve the quality of reconstruction and allow direct comparison with other quantitative records and the instrumentally observed values of salinity. Copyright © 2010 John Wiley & Sons, Ltd.     

Coprostanol as sewage tracer in McMurdo Sound, Antarctica

Sediment cores from the vicinity of sewage outfalls off McMurdo Station as well as surface grab samples from different locations in the McMurdo Sound, Antarctica were analysed for coprostanol (5β-cholestan-3β-ol) and epicoprostanol (5β-cholestan-3-ol) to assess the degree of sewage addition to the Sound. Sediment samples close to the point source contain as much as 3 mg g⁻¹ dry sediment of coprostanol, whereas samples farther from the source, for example from New Harbour and Granite Harbour, contain only trace levels to 40 ng g⁻¹. Coprostanol in the sediments of latter locations most likely originates from seals rather than from sewage outfalls. It appears that sewage particles are very quickly incorporated into the sediment layers close to the discharge point in the eastern Sound. However, significant levels (930 ng g⁻¹) of fecal sterols were detected in Cape Armitage surface sediments, indicating that the sewage plume could also have reached the seawater intake station, situated in between the outfall and Cape Armitage sampling site. These results suggest the need for a sound environmental monitoring and assessment of the existing wastewater practices in the region.     

IndoTROPICS studies on the plume of the Mamberamo river into the Bismarck Sea, West Papua, Indonesia

The tropical river ocean processes in coastal settings (TROPICS) program in Indonesia (Indotropics) was carried out in the Mamberamo estuary on May–June 1999 and August 2000. The Mamberamo River flows northward from the high mountains of West Papua to the narrow and steep continental slope of the Pacific Ocean. The data for the 1999 Mamberamo estuary cruises show the dispersal of fresh water coming out of the Mamberamo River into the Bismarck Sea, and the plume is clearly defined by the pattern of salinity, turbidity, and nutrient distribution. The Mamberamo River and other nearby rivers supply high concentrations of phosphate and nitrate to the New Guinea Coastal Current, so that nutrient concentrations are higher in the surface estuarine plume, compared to offshore areas. The distribution of fishes and benthic animals were also sampled over this area.     

MAXIMUM INFORMATION ENTROPY THEORY OF EFFLUENT BAND IN OPEN CHANNEL UNIFORM FLOW

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Kinetic partitioning of Co,Mn, Cs,Fe, Ag,Zn and Cd in fresh waters (Loire) mixed with brackish waters (Loire estuary): experimental and modelling approaches

To simulate the behavior of radionuclides along a salinity gradient, in vitro sorption and desorption kinetics of Co, Mn, Cs, Fe, Ag, Zn and Cd were studied in Loire river water and the macrotidal Loire estuarine water over two different seasons. Partitioning between the dissolved phase and suspended solids were followed up over 100 h after adding radioactive tracers to freshly collected freshwater (sorption stage); this stage was followed by desorption in fresh and estuarine waters. A kinetic model describing the interactions between trace metals and particles under a salinity gradient was developed and calibrated. Among parameters and/or processes that control the fate and behavior of contaminated particles during their transfer in estuarine systems, this study shows that the speciation of trace metals is controlled by: (i) the chemical water composition: for all the elements except for Fe, desorption increased with salinity; however, the amplitude of such an effect strongly depended on the element and/or on the composition of the particulate phase (and consequently on the season); (ii) the possibility for a given element to form (or not) stable surface particle moieties such as oxides or inner-sphere complexes; (iii) the distribution of a given element among different types of sites characterised by different binding forces that can lead (or not) to re-adsorption processes after mixing of contaminated particles with uncontaminated water.Our model enabled the quantification of the contribution and the characteristic time of reactions that took place over short and long periods on the global partitioning between particulate and dissolved phases during sorption and desorption and to determine the extent to which these reactions were modified by the salinity.     

Effects of bottom slope, flocculation and hindered settling on the coupled dynamics of currents and suspended sediment in highly turbid estuaries, a simple model

This study aims at gaining basic understanding about two specific phenomena that are observed in the highly turbid estuaries tidal Ouse, Yangtze and Ems, i.e. (1) the accumulation of suspended matter in the deeper parts of the estuaries and (2) the relatively high values of turbidity near the surface in the area of the turbidity maximum. A semi-analytical model is analysed to verify the hypothesis that these phenomena result from bottom slope-induced turbidity currents and from hindered settling, respectively. The model governs the dynamics of residual flow, driven by fresh water discharge, salinity gradients and turbidity gradients. It further uses the condition of morphodynamic equilibrium (no divergence of net sediment transport) to compute the residual sediment concentration. New aspects are that depth variations on flow and mixing processes, as well as flocculation and hindered settling of sediment, are explicitly accounted for. Tides act as a source of mixing and erosion of sediment only, thus processes like tidal pumping are not considered. Model results show that the estuarine turbidity maximum (ETM) shifts in the down-slope direction, compared to the case of a constant depth. Slope-induced turbidity currents, which are directed down-slope near the bottom and up-slope near the surface, are responsible for this shift, thereby confirming the first part of the hypothesis above. The down-slope shift of the ETM is reduced by currents resulting from gradients in depth-dependent mixing, which counteract turbidity currents, but which are always weaker. Including flocculation and hindered settling yields increased surface sediment concentrations in the area of the turbidity maximum, compared to the situation of a constant settling velocity, thereby supporting the second part of the hypothesis. Sensitivity experiments reveal that the conclusions are not sensitive to the values of the model parameters.     

Use of Rhodamine water tracer in the marshland upwelling system

Rhodamine water tracer (RWT) was used to characterize the migration of waste water within the saline subsurface of a marshland upwelling system (MUS), which is an alternative on-site waste water treatment system for coastal areas. Field tracer studies were performed to investigate the fresh waste water plume movement within the saline ground water. Pore velocities were calculated using first detection times and ranged from 0.68 to 10.7 x 10(-4) cm/sec for the loamy sandy soil matrix present at the site. Use of RWT in the field also allowed determination of main and preferential flowpaths. One- and two-dimensional laboratory experiments were performed using silica sand to investigate the interactions of the organically rich waste water with RWT within the zone surrounding the point of injection (one-dimensional) and the impact of background salinity on plume movement (two-dimensional). The results from these studies were used to help explain the field data. One-dimensional breakthrough curves revealed retardation factors for the RWT in the waste water mixture of 1.73 to 1.90. These results were similar to other researchers, indicating little interaction between the waste water and RWT. Variations in pore water salinity (5, 15, 25, and 35 ppt) were found to have a significant effect on pore water velocities of the fresh water plume (two-dimensional), indicating the need to incorporate background salinities into the design process for MUS.     

Estimation of ecologically significant circulation features of the Columbia River estuary and plume using a reduced-dimension Kalman filter

A data assimilation method was used to estimate the variability of three ecologically significant features of the Columbia River estuary and plume: the size of the plume, the orientation of the plume, and the length of the salinity intrusion in the estuary. Our data assimilation method was based on a reduced-dimension Kalman filter that enables fast data assimilation of nonlinear dynamics in the estuary and plume. The assimilated data included measurements of salinity, temperature, and water levels at 13 stations in the estuary and at five moorings in the plume.     

Hydrographic variability on a coastal shelf directly influenced by estuarine outflow

Hydrographic variability on the Alabama shelf just outside of Mobile Bay, a major source of river discharge into the Gulf of Mexico, is examined using time series of water column temperature and surface and bottom salinity from a mooring site with a depth of 20 m in conjunction with a series of across-shelf CTD surveys. The time series data show variability in a range of time scales. The density variation is affected by both salinity and temperature, with its relatively strong annual signal mostly determined by temperature and its year to year variability mostly determined by salinity. Seasonal mean structures of temperature, salinity, and density show a transition from estuarine to shelf conditions in which three regions with distinct seasonal characteristics in their horizontal and vertical gradient structures are identified. Correlation analysis with the available forcing functions demonstrates the influence of Mobile Bay on the variability at the mooring site. At low frequencies, river discharge from Mobile Bay has a varying influence on salinity, which is absent during the periods with unusually low discharge. At shorter synoptic time scales, both the estuarine response to the across-shelf wind stress and the shelf response to the along-shelf wind stress are significantly correlated with temperature/salinity variability: the former becoming important for the surface layer during winter whereas the latter for the bottom layer during both winter and summer. These forcing functions are important players in determining the estuarine-shelf exchange, which in turn is found to contribute to the shelf hydrographic structure.     

Implementation of a wetting-and-drying model in simulating the Kennebec–Androscoggin plume and the circulation in Casco Bay

A high-resolution coastal ocean model was developed to simulate the temporal/spatial variability of the Kennebec–Androscoggin (K–A) river plume and the circulation in Casco Bay. The model results agree favorably with the moored and shipboard observations of velocity, temperature, and salinity. The surface salinity gradient was used to distinguish the plume from the ambient coastal water. The calculated plume thickness suggests that the K–A plume is surface trapped. Its horizontal scales correlate well with Q ^0.25, where Q is the volume discharge of the rivers. Directional spreading is affected by the wind with the upwelling favorable wind transporting the plume water offshore. Both the wind and the tide also enhance mixing in the plume. The inclusion of a wetting-and-drying (WAD) scheme appears to enhance the mixing and entrainment processes near the estuary. The plume becomes thicker near the mouth of the estuary, the outflow velocity of the plume is weaker, and the radius of the river plume shrinks. The flow field in the model run with the WAD is noisier, not only in shallow areas of Casco Bay but also in the plume and even on the shelf. We speculate that the WAD processes can affect much larger areas than the intertidal zones, especially via a river plume that feeds into a coastal current.     

The occurrence and distribution of pharmaceutical compounds in the effluents of a major sewage treatment plant in Northern Taiwan and the receiving coastal waters

The pharmaceutical residues in waste water from the largest sewage treatment plant (STP) in Northern Taiwan and in seawater around the effluent discharged area were determined. An environmental risk assessment for the marine environment was conducted based on the environment risk quotient (ERQ). The concentrations of the analyzed compounds in STP influent and effluent were generally higher than those found in coastal seawater. Relatively higher values were found at the estuarine mouth and the discharged area, suggesting that the STP effluent is a point source. The removal efficiency and half life of the analyzed compounds were 6.3-46.8% and 3-18 days, respectively. The ERQ value theoretical calculation was generally greater than 1. However, when the measured concentrations replaced the predicated concentrations, the ERQ values were considerably lower than 1. Therefore, our results call for a re-evaluation of the risks posed by pharmaceuticals to coastal marine ecosystems in Northern Taiwan.     

Fate and Behavior of Organochlorine Pesticides in the Indonesian Tropical Climate: A Study in the Segara Anakan Estuarine Ecosystem

The fate and behavior of organochlorine pesticides (OCPs) in the Segara Anakan Estuarine ecosystem was studied in the Indonesian tropical climate, which is characterized by heavy rainfall in the rainy season and low rainfall in the dry season. Since OCPs have high affinity for soil, a field study on the dissipation and degradation pattern of soil‐applied 1,1,1‐trichloro‐2,2‐bis (4‐chlorophenyl) ethane (p,p′‐DDT) and 1,1‐dichloro‐2,2‐bis (4‐chlorophenyl) ethylene (p,p′‐DDE) as model OCPs was carried out. They occurred at a faster rate in the biphasic mode in wet conditions and at a slower rate in dry conditions. In wet conditions, the conversion from p,p′‐DDT to p,p′‐DDE and p,p′‐DDD (1,1‐dichloro‐2,2‐bis (4‐chlorophenyl) ethane) was governed by a parallel reaction. In dry conditions, only p,p′‐DDE was formed. The fate and behavior of OCPs in sediment estuary are similar to those in soil under wet conditions, except that their sorption‐desorption constants are influenced by estuarine surface water salinity. In the dry season, due to high salinity, the sediment acts as an OCP sink and a secondary source for the ecosystem, causes higher OCP concentration of local bio‐monitors, i. e., Geloina spp. and Mugil spp. In the rainy season, high water inflow washed the desorbed OCP pesticides out of the estuarine ecosystem, and caused lower concentrations of bio‐monitors. A risk evaluation for the uptake of OCP pesticides during the dry season suggests that adult fish meal consumers are safe, but risk management is required for pregnant woman.     

The location of deep salinity sources in the Israeli Coastal aquifer

The salinization process of the Israeli Coastal aquifer has led to an average concentration of about 200 mgCl/l with a significant number of discrete salinity plumes in the middle and southern regions. The salinity of these plumes is high (500–1000 mgCl/l) and is increasing rapidly. Geochemical evidence has suggested that the salinity source in the Be'er Tuvia plume (in the south part of the aquifer) is at the bottom of the aquifer. This paper describes a solution of the source inverse problem and its application in the Be'er Tuvia plume. A transient two-dimensional finite element model was solved and the source terms were computed at each node in a 14×14 km² area. An error analysis has shown that when no errors are introduced in the input data the reconstruction is perfect. The results of a sensitivity analysis are presented and the actual reconstruction errors are estimated. Applying the model in the Be'er Tuvia region indicates that a salinity source exists about 1 km to the west and 1.5 km to the north of the center of the salinity plume. This source is believed to be the plume source.     

Seasonal variation of water column structure and sediment transport in a mud depo-center off the Zhejiang-Fujian coast in China

Two surveys were conducted in December, 2008, and August, 2009, in the mud depo-center off the Zhejiang-Fujian coast (MDZFC) in the inner shelf of East China Sea to depict the seasonal variation of the water column structure and analyze the factors responsible for the variation. The results were also used to discuss the sediment transport process and formation mechanism of the MDZFC. The water column structures varied significantly between the two surveys, with respect to the temperature, salinity, and turbidity. The summer water body, with relatively high temperatures and salinities, was evidently stratified with respect to the temperature, whereas the salinity remained constant throughout the water column. The stratification restricts sediment resuspension and transport. From the north to the south, the temperature in the middle-bottom water layer slightly increased, whereas the salinity remained mostly constant. In winter, the water body, with relatively low temperatures and salinities, was well mixed vertically. The temperature and salinity both increased from the surface to the bottom toward the east (deep water) and the south. A wedge-shaped water mass, which appears as a coastal upwelling, with relatively low temperature and high salinity in summer and relatively high temperature and high salinity in winter, spread landward along the sea floor, from the sea deeper than 50 m, whereas the extension was relatively stronger in winter. The water turbidity in winter was clearly higher than in summer. In the surface layer, the turbidity was generally greater than 5 FTU in winter and less than 1 FTU in summer. In the bottom layer, the turbidity was much greater than 200 FTU in winter and slightly greater than 50 FTU in summer. Moreover, the turbid water layer close to the sea floor in winter can reach into an area deeper than 50 m with a thickness of over 10 m; however, it was only limited to only 30-m-deep water with a thickness of 5 m in summer. The differences of marine sedimentary environment in the MDZFC were attributed to the seasonal variations of hydrodynamics environment, weather conditions, sediment supplies, and seasonal circulations. The results suggest that winter is the key season for particle transportation and deposition. The bottom turbid layer is the primarily channel of sediment transport, and the upwelling currents and the oceanic front systems play an important role in the sediment deposit processes and the formation of the MDZFC.