<Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar dating of the eruptive history of Mount Erebus,Antarctica: summit flows,tephra, and caldera collapse

Eruptive activity has occurred in the summit region of Mount Erebus over the last 95 ky, and has included numerous lava flows and small explosive eruptions, at least one plinian eruption, and at least one and probably two caldera-forming events. Furnace and laser step-heating ⁴⁰Ar/³⁹Ar ages have been determined for 16 summit lava flows and three englacial tephra layers erupted from Mount Erebus. The summit region is composed of at least one or possibly two superimposed calderas that have been filled by post-caldera lava flows ranging in age from 17 ± 8 to 1 ± 5 ka. Dated pre-caldera summit flows display two age populations at 95 ± 9 to 76 ± 4 ka and 27 ± 3 to 21 ± 4 ka of samples with tephriphonolite and phonolite compositions, respectively. A caldera-collapse event occurred between 25 and 11 ka. An older caldera-collapse event is likely to have occurred between 80 and 24 ka. Two englacial tephra layers from the flanks of Mount Erebus have been dated at 71 ± 5 and 15 ± 4 ka. These layers stratigraphically bracket 14 undated tephra layers, and predate 19 undated tephra layers, indicating that small-scale explosive activity has occurred throughout the late Pleistocene and Holocene eruptive history of Mount Erebus. A distal, englacial plinian-fall tephra sample has an age of 39 ± 6 ka and may have been associated with the older of the two caldera-collapse events. A shift in magma composition from tephriphonolite to phonolite occurred at around 36 ka.Editorial responsibility: Julie Donnelly-Nolan     

Refinement of the late Quaternary geologic history of Erebus volcano,Antarctica using Ar/Ar and Cl age determinations

Six new ⁴⁰Ar/³⁹Ar and three cosmogenic ³⁶Cl age determinations provide new insight into the late Quaternary eruptive history of Erebus volcano. Anorthoclase from 3 lava flows on the caldera rim have ⁴⁰Ar/³⁹Ar ages of 23 ± 12, 81 ± 3 and 172 ± 10 ka (all uncertainties 2σ). The ages confirm the presence of a second, younger, superimposed caldera near the southwestern margin of the summit plateau and show that eruptive activity has occurred in the summit region for 77 ± 13 ka longer than previously thought. Trachyte from “Ice Station” on the eastern flank is 159 ± 2 ka, similar in age to those at Bomb Peak and Aurora Cliffs. The widespread occurrences of trachyte on the eastern flank of Erebus suggest a major previously unrecognized episode of trachytic volcanism. The trachyte lavas are chemically and isotopically distinct from alkaline lavas erupted contemporaneously in the summit region < 5 km away.     

<Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar ages of the<Emphasis Type="Italic"> AD</Emphasis> 79 eruption of Vesuvius,Italy

The Italian volcano, Vesuvius, erupted explosively in AD 79. Sanidine from pumice collected at Casti Amanti in Pompeii and Villa Poppea in Oplontis yielded a weighted-mean ⁴⁰Ar/³⁹Ar age of 1925±66 years in 2004 (1σ uncertainty) from incremental-heating experiments of eight aliquants of sanidine. This is the calendar age of the eruption. Our results together with the work of Renne et al. (1997) and Renne and Min (1998) demonstrate the validity of the ⁴⁰Ar/³⁹Ar method to reconstruct the recent eruptive history of young, active volcanoes.     

The occurrence of Mt Barca flank eruption in the evolution of the NW periphery of Etna volcano (Italy)

Geological surveys, tephrostratigraphic study, and ⁴⁰Ar/³⁹Ar age determinations have allowed us to chronologically constrain the geological evolution of the lower NW flank of Etna volcano and to reconstruct the eruptive style of the Mt Barca flank eruption. This peripheral sector of the Mt Etna edifice, corresponding to the upper Simeto valley, was invaded by the Ellittico volcano lava flows between 41 and 29 ka ago when the Mt Barca eruption occurred. The vent of this flank eruption is located at about 15 km away from the summit craters, close to the town of Bronte. The Mt Barca eruption was characterized by a vigorous explosive activity that produced pyroclastic deposits dispersed eastward and minor effusive activity with the emission of a 1.1-km-long lava flow. Explosive activity was characterized by a phreatomagmatic phase followed by a magmatic one. The geological setting of this peripheral sector of the volcano favors the interaction between the rising magma and the shallow groundwater hosted in the volcanic pile resting on the impermeable sedimentary basement. This process produced phreatomagmatic activity in the first phase of the eruption, forming a pyroclastic fall deposit made of high-density, poorly vesicular scoria lapilli and lithic clasts. Conversely, during the second phase, a typical strombolian fall deposit formed. In terms of hazard assessment, the possible occurrence of this type of highly explosive flank eruption, at lower elevation in the densely inhabited areas, increases the volcanic risk in the Etnean region and widens the already known hazard scenario.     

The eruptive history of the Tequila volcanic field, western Mexico: ages, volumes, and relative proportions of lava types

The eruptive history of the Tequila volcanic field (1600 km²) in the western Trans-Mexican Volcanic Belt is based on ⁴⁰Ar/³⁹Ar chronology and volume estimates for eruptive units younger than 1 Ma. Ages are reported for 49 volcanic units, including Volcán Tequila (an andesitic stratovolcano) and peripheral domes, flows, and scoria cones. Volumes of volcanic units 1 Ma were obtained with the aid of field mapping, ortho aerial photographs, digital elevation models (DEMs), and ArcGIS software. Between 1120 and 200 kyrs ago, a bimodal distribution of rhyolite (~35 km³) and high-Ti basalt (~39 km³) dominated the volcanic field. Between 685 and 225 kyrs ago, less than 3 km³ of andesite and dacite erupted from more than 15 isolated vents; these lavas are crystal-poor and show little evidence of storage in an upper crustal chamber. Approximately 200 kyr ago, ~31 km³ of andesite erupted to form the stratocone of Volcán Tequila. The phenocryst assemblage of these lavas suggests storage within a chamber at ~2–3 km depth. After a hiatus of ~110 kyrs, ~15 km³ of andesite erupted along the W and SE flanks of Volcán Tequila at ~90 ka, most likely from a second, discrete magma chamber located at ~5–6 km depth. The youngest volcanic feature (~60 ka) is the small andesitic volcano Cerro Tomasillo (~2 km³). Over the last 1 Myr, a total of 128±22 km³ of lava erupted in the Tequila volcanic field, leading to an average eruption rate of ~0.13 km³/kyr. This volume erupted over ~1600 km², leading to an average lava accumulation rate of ~8 cm/kyr. The relative proportions of lava types are ~22–43% basalt, ~0.4–1% basaltic andesite, ~29–54% andesite, ~2–3% dacite, and ~18–40% rhyolite. On the basis of eruptive sequence, proportions of lava types, phenocryst assemblages, textures, and chemical composition, the lavas do not reflect the differentiation of a single (or only a few) parental liquids in a long-lived magma chamber. The rhyolites are geochemically diverse and were likely formed by episodic partial melting of upper crustal rocks in response to emplacement of basalts. There are no examples of mingled rhyolitic and basaltic magmas. Whatever mechanism is invoked to explain the generation of andesite at the Tequila volcanic field, it must be consistent with a dominantly bimodal distribution of high-Ti basalt and rhyolite for an 800 kyr interval beginning ~1 Ma, which abruptly switched to punctuated bursts of predominantly andesitic volcanism over the last 200 kyrs.Electronic Supplementary Material Supplementary material is available in the online version of this article at Editorial responsility: J. Donnelly-NolanThis revised version was published online in January 2005 with corrections to Tables 1 and 3.An erratum to this article can be found at     

Holocene volcanic activity at Koniuji Island,Aleutians

Reconnaissance mapping and ⁴⁰Ar/³⁹Ar age determinations establish an eruptive chronology for Koniuji Island in the central Aleutian island arc. Koniuji is a tiny 0.95 km² island that rises only 896 ft above the Bering Sea. Previous accounts describe Koniuji as a mostly submerged, deeply eroded, dormant stratovolcano. However, new ⁴⁰Ar/³⁹Ar ages constrain the duration of subaerial eruptive activity from 15.2 to 3.1 ka. Furnace incremental heating experiments on replicate groundmass separates from two samples of a 30–50 m thick basaltic andesite flow at the southernmost point of the island gave a weighted mean ⁴⁰Ar/³⁹Ar age of 15.2 ± 5.0 (2σ). The next phase of eruptive activity includes a series of 5.8–4.6 ka basaltic andesitic to andesitic lava flows preserved along the western shoreline. The basal lavas contain numerous mafic enclaves and dioritic cumulates suggesting a major disturbance in the plumbing system during the initial stages of emplacement. The 5.8–4.6 ka lavas are truncated by an andesitic dome complex that includes hornblende-bearing domes, flows and pyroclastics which extruded into the center of the island and comprise the majority of the subaerial eruptive volume. An angular block from within the dome complex yielded ⁴⁰Ar/³⁹Ar age of 3.1 ± 1.9 ka, thereby making it one of the youngest island arc volcanics to be dated using the ⁴⁰Ar/³⁹Ar method. Overall, the ⁴⁰Ar/³⁹Ar data indicate that Koniuji is a nascent stratovolcano that has only recently emerged above sea level, not a glacially-eroded, long-lived volcanic complex like those found on many other central Aleutian Islands.     

Geology and eruptive history of Unzen volcano, Shimabara Peninsula, Kyushu, SW Japan

During the past 500 thousand years, Unzen volcano, an active composite volcano in the Southwest Japan Arc, has erupted lavas and pyroclastic materials of andesite to dacite composition and has developed a volcanotectonic graben. The volcano can be divided into the Older and the Younger Unzen volcanoes. The exposed rocks of the Older Unzen volcano are composed of thick lava flows and pyroclastic deposits dated around 200–300 ka. Drill cores recovered from the basal part of the Older Unzen volcano are dated at 400–500 ka. The volcanic rocks of the Older Unzen exceed 120 km³ in volume. The Younger Unzen volcano is composed of lava domes and pyroclastic deposits, mostly younger than 100 ka. This younger volcanic edifice comprises Nodake, Myokendake, Fugendake, and Mayuyama volcanoes. Nodake, Myokendake and Fugendake volcanoes are 100–70 ka, 30–20 ka, and <20 ka, respectively. Mayuyama volcano formed huge lava domes on the eastern flank of the Unzen composite volcano about 4000 years ago. Total eruptive volume of the Younger Unzen volcano is about 8 km³, and the eruptive production rate is one order of magnitude smaller than that of the Older Unzen volcano.     

Post-caldera activity in the Alban Hills volcanic district (Italy): 40Ar/39Ar geochronology and insights into magma evolution

We present 24 ⁴⁰Ar/³⁹Ar ages for the youngest volcanic products from the Alban Hills volcanic district (Rome). Combined with petrological data on these products, we have attempted to define the chronology of the most recent phase of activity and to investigate the magma evolution of this volcanic district. The early, mainly explosive activity of the Alban Hills spanned the interval from 561±1 to 351±3 ka. After approximately 50-kyr of dormancy, a mainly effusive phase of activity took place, accompanied by the strombolian activity of a small central edifice (Monte delle Faete). This second phase of activity spanned the interval 308±2 to 250±1 ka. After another dormancy period of approximately 50-kyr, a new, hydromagmatic phase of activity started at 200 ka at several centers located to the southwest of the Monte delle Faete edifice. After an initial recurrence period of approximately 50-kyr, which also characterized this new phase of activity, the longest dormancy period (approximately 80-kyr) in the history of the volcanic district preceded the start of the activity of the Albano and Giuturna centers at 70±1 ka. Results of our study suggest a quasi-continuous magmatic activity feeding hydromagmatic centers with a new acme of volcanism since around 70 ka. Based on data presented in this paper, we argue that the Alban Hills should not be considered an extinct volcanic district and a detailed re-assessment of the volcanic hazard for the area of Rome is in order. Published online: 4 April 2003 Editorial responsibility: J. Donnelly-Nolan     

A 13 ± 3 ka age determination of a tholeiite,Pinacate volcanic field,Mexico, and improved methods for Ar/Ar dating of young basaltic rocks

Among the youngest lava flows of the Pinacate volcanic field, Sonora, Mexico, is a large outpouring of tholeiite, the Ives flow. This tube-fed pahoehoe flow contrasts sharply with other Pinacate lavas in its great volume, alkali-poor composition and morphologic features, which include novel small structures named “spatter tubes.” Despite its K-poor character, young age, and the presence of excess ⁴⁰Ar, we determined a ⁴⁰Ar/³⁹Ar age on samples of this flow at 13 ± 3 ka. Such an age determination is made possible via careful monitoring of the mass discrimination of the mass spectrometer and by stacking results from multiple incremental-heating experiments into a single, composite isochron. This age is among the youngest ever to be determined with such precision by the ⁴⁰Ar/³⁹Ar method on a K-poor tholeiite.     

Matuyama-Brunhes reversal and Kamikatsura event on Maui: paleomagnetic directions, Ar/Ar ages and implications

Eighty-nine basaltic lava flows from the northwest wall of Haleakala caldera preserve a concatenated paleomagnetic record of portions of the Matuyama-Brunhes (M-B) reversal and the preceding Kamikatsura event as well as secular variation of the full-polarity reversed and normal geomagnetic field. They provide the most detailed volcanic record to date of the M-B transition. The 24 flows in the transition zone show for the first time transitional virtual geomagnetic poles (VGPs) that move from reverse to normal along the Americas, concluding with an oscillation in the Pacific Ocean to a cluster of VGPs east of New Zealand and back finally to stable polarity in the north polar region. All but one of the 16 Kamikatsura VGPs cluster in central South America. The full-polarity flows, with ⁴⁰Ar/³⁹Ar ages spanning a total of 680 kyr, pass a reversal test and give an average VGP insignificantly different from the rotation axis, with standard deviation consistent with that for other 0-5 Ma lava flows of similar latitude. Precise ⁴⁰Ar/³⁹Ar dating consisting of 31 incremental heating experiments on 12 transitional flows yields weighted mean ages of 775.6±1.9 and 900.3±4.7 ka for the M-B and Kamikatsura transitional flows, respectively. This Matuyama-Brunhes age is ∼16 kyr younger than ages for M-B flows from the Canary Islands, Tahiti and Chile that were dated using exactly the same techniques and standards, suggesting that this polarity transition may have taken considerably longer to complete and been more complex than is generally believed for reversals.     

Eruptive history and tectonic setting of Medicine Lake Volcano,a large rear-arc volcano in the southern Cascades

Medicine Lake Volcano (MLV), located in the southern Cascades ∼ 55 km east-northeast of contemporaneous Mount Shasta, has been found by exploratory geothermal drilling to have a surprisingly silicic core mantled by mafic lavas. This unexpected result is very different from the long-held view derived from previous mapping of exposed geology that MLV is a dominantly basaltic shield volcano. Detailed mapping shows that < 6% of the ∼ 2000 km² of mapped MLV lavas on this southern Cascade Range shield-shaped edifice are rhyolitic and dacitic, but drill holes on the edifice penetrated more than 30% silicic lava. Argon dating yields ages in the range ∼ 475 to 300 ka for early rhyolites. Dates on the stratigraphically lowest mafic lavas at MLV fall into this time frame as well, indicating that volcanism at MLV began about half a million years ago. Mafic compositions apparently did not dominate until ∼ 300 ka. Rhyolite eruptions were scarce post-300 ka until late Holocene time. However, a dacite episode at ∼ 200 to ∼ 180 ka included the volcano's only ash-flow tuff, which was erupted from within the summit caldera. At ∼ 100 ka, compositionally distinctive high-Na andesite and minor dacite built most of the present caldera rim. Eruption of these lavas was followed soon after by several large basalt flows, such that the combined area covered by eruptions between 100 ka and postglacial time amounts to nearly two-thirds of the volcano's area. Postglacial eruptive activity was strongly episodic and also covered a disproportionate amount of area. The volcano has erupted 9 times in the past 5200 years, one of the highest rates of late Holocene eruptive activity in the Cascades. Estimated volume of MLV is ∼ 600 km³, giving an overall effusion rate of ∼ 1.2 km³ per thousand years, although the rate for the past 100 kyr may be only half that. During much of the volcano's history, both dry HAOT (high-alumina olivine tholeiite) and hydrous calcalkaline basalts erupted together in close temporal and spatial proximity. Petrologic studies indicate that the HAOT magmas were derived by dry melting of spinel peridotite mantle near the crust mantle boundary. Subduction-derived H₂O-rich fluids played an important role in the generation of calcalkaline magmas. Petrology, geochemistry and proximity indicate that MLV is part of the Cascades magmatic arc and not a Basin and Range volcano, although Basin and Range extension impinges on the volcano and strongly influences its eruptive style. MLV may be analogous to Mount Adams in southern Washington, but not, as sometimes proposed, to the older distributed back-arc Simcoe Mountains volcanic field.     

Paleomagnetism,magnetic fabric,and <Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar dating of Pliocene and Quaternary ignimbrites in the Arequipa area,southern Peru

⁴⁰Ar/³⁹Ar ages and paleomagnetic correlations using characteristic remanent magnetizations (ChRM) show that two main ignimbrite sheets were deposited at 4.86 ± 0.07 Ma (La Joya Ignimbrite: LJI) and at 1.63 ± 0.07 Ma (Arequipa Airport Ignimbrite: AAI) in the Arequipa area, southern Peru. The AAI is a 20–100 m-thick ignimbrite that fills in the Arequipa depression to the west of the city of Arequipa. The AAI is made up of two cooling units: an underlying white unit and an overlying weakly consolidated pink unit. Radiometric data provide the same age for the two units. As both units record exactly the same well-defined paleomagnetic direction (16 sites in the white unit of AAI: Dec = 173.7; Inc = 31.2; α95 = 0.7; k = 2749; and 10 sites in the pink unit of AAI; Dec = 173.6; Inc = 30.3; α95 = 1.2; k = 1634), showing no evidence of secular variation, the time gap between emplacement of the two units is unlikely to exceed a few years. The >50 m thick well-consolidated white underlying unit of the Arequipa airport ignimbrite provides a very specific magnetic zonation with low magnetic susceptibilities, high coercivities and unblocking temperatures of NRM above 580°C indicating a Ti-poor titanohematite signature. The Anisotropy of Magnetic Susceptibility (AMS) is strongly enhanced in this layer with anisotropy values up to 1.25. The fabric delineated by AMS was not recognized neither in the field nor in thin sections, because most of the AAI consists in a massive and isotrope deposit with no visible textural fabric. Pumices deformation due to welding is only observed at the base of the thickest sections. AMS within the AAI ignimbrite show a very well defined pattern of apparent imbrications correlated to the paleotopography, with planes of foliation and lineation dipping often at more than 20° toward the expected vent, buried beneath the Nevado Chachani volcanic complex. In contrast with the relatively small extent of the thick AAI, the La Joya ignimbrite covers large areas from the Altipano down the Piedmont. Ti-poor titanomagnetites are the dominant magnetic carriers and AMS values are generally lower than 1.05. Magnetic foliations are sub horizontal and lineations directions are scattered in the LJI. The AMS fabrics are probably controlled by post-depositional compaction and welding of the deposit rather than transport dynamics. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

<Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar chronology and geochemistry of high-K volcanic rocks in the Mangkang basin,Tibet

Our two newly obtained high-quality ⁴⁰Ar/³⁹Ar ages suggest that the high-K volcanic rocks of the Lawuxiang Formation in the Mangkang basin, Tibet were formed at 33.5 ± 0.2 Ma. The tracing of elemental and Pb-Sr-Nd isotopic geochemistry indicates that they were derived from an EM2 enriched mantle in continental subduction caused by transpression. Their evidently negative anomalies in HFSEs such as Nb and Ta make clear that there is an input of continental material into the mantle source. The high-K rocks at 33.5 ± 0.2 Ma in the Mangkang basin may temporally, spatially and compositionally compare with the early one of two-pulse high-K rocks in eastern Tibet distinguished by Wang J. H. et al., implying that they were formed in the same tectonic setting.     

<Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar dating of tuff vents in the Campi Flegrei caldera (southern Italy): toward a new chronostratigraphic reconstruction of the Holocene volcanic activity

The Campi Flegrei hosts numerous monogenetic vents inferred to be younger than the 15 ka Neapolitan Yellow Tuff. Sanidine crystals from the three young Campi Flegrei vents of Fondi di Baia, Bacoli and Nisida were dated using ⁴⁰Ar/³⁹Ar geochronology. These vents, together with several other young edifices, occur roughly along the inner border of the Campi Flegrei caldera, suggesting that the volcanic conduits are controlled by caldera-bounding faults. Plateau ages of ∼9.6 ka (Fondi di Baia), ∼8.6 ka (Bacoli) and ∼3.9 ka (Nisida) indicate eruptive activity during intervals previously interpreted as quiescent. A critical revision, involving calendar age correction of literature ¹⁴C data and available ⁴⁰Ar/³⁹Ar age data, is presented. A new reference chronostratigraphic framework for Holocene Phlegrean activity, which significantly differs from the previously adopted ones, is proposed. This has important implications for understanding the Campi Flegrei eruptive history and, ultimately, for the evaluation of related volcanic risk and hazard, for which the inferred history of its recent activity is generally taken into account.     

Mount Etna eruptions of the last 2,750 years: revised chronology and location through archeomagnetic and <Superscript>226</Superscript>Ra-<Superscript>230</Superscript>Th dating

A careful re-examination of the well-known written documents pertaining to the 2,750-year-long historical period of Mount Etna was carried out and their interpretation checked through the high-accuracy archeomagnetic method (>1,200 large samples), combined with the ²²⁶Ra-²³⁰Th radiochronology. The magnetic dating is based upon secular variation of the direction of the geomagnetic field (DGF) and estimated to reach a precision of  ±40 years for the last 1,200 years, and ±100 to 200 years up to circa 150 B.C. Although less precise, the ²²⁶Ra-²³⁰Th method provides a unique tool for distinguishing between historic and prehistoric lavas, which in some cases might have similar DGFs. We show that despite the abundance of details on ancient historical eruptions, the primary sources of information are often too imprecise to identify their lava flows and eruptive systems. Most of the ages of these lavas, which are today accepted on the geological maps and catalogues, were attributed in the 1800s on the basis of their morphology and without any stratigraphical control. In fact, we found that 80% of the “historically dated” flows and cones prior to the 1700s are usually several hundreds of years older than recorded, the discrepancies sometimes exceeding a millennium. This is proper the case for volcanics presumed of the “1651 east” (actually ∼1020), “1595” (actually two distinct flows, respectively, ∼1200 and ∼1060), “1566” (∼1180), “1536” (two branches dated ∼1250 and ∼950), “1444” (a branch dated ∼1270), “1408” (lower branches dated ∼450 and ∼350), “1381” (∼1160), “1329” (∼1030), “1284” (∼1450 and ∼700), “1169 or 812” (∼1000) eruptions. Conversely, well-preserved cones and flows that are undated on the maps were produced by recent eruptions that went unnoticed in historical accounts, especially during the Middle Ages. For the few eruptions that are recorded between A.D. 252 and 750 B.C., none of their presumed lava flows shows a DGF in agreement with that existing at their respective dates of occurrence, most of these flows being in fact prehistoric. The cinder cones of Monpeloso (presumed “A.D. 252”) and Mt. Gorna (“394 B.C.”), although roughly consistent magnetically and radiochronologically with their respective epochs, remain of unspecified age because of a lack of precision of the DGF reference curve at the time. It is concluded that at the time scale of the last millennia, Mount Etna does not provide evidence of a steady-state behavior. Periods of voluminous eruptions lasting 50 to 150 years (e.g., A.D. 300–450, 950–1060, 1607–1669) are followed by centuries of less productive activity, although at any time a violent outburst may occur. Such a revised history should be taken into account for eruptive models, magma output, internal plumbing of the volcano, petrological evolution, volcano mapping and civil protection.     

Major ash eruptions of Barren Island volcano (Andaman Sea) during the past 72 kyr: clues from a sediment core record

Barren Island (Andaman Sea) is the northernmost active volcano of the Indonesian Arc. To construct the eruptive history of this little studied volcano, we measured ¹⁴C dates of inorganic carbon in sediment beds, and Sr and Nd isotopic ratios of seven discrete ash layers, in a marine sediment core collected from 32 km southeast of the volcano. The study reveals that the volcano had seven major ash eruptions at ~70, 69, 61, 24, 19, 15, and 10 ka. The ash layers erupted from 70 ka through 19 ka have highly uniform Nd isotopic composition, and since the ~15 ka eruption to the present the isotopic composition has been highly variable. Between ~24 ka and ~10 ka, the volcano had large ash eruptions spaced at 4,500 year intervals. Isotopically correlating the precaldera lavas and ash exposed on the volcano to the uppermost ash layer in the core, we infer that the caldera of Barren Island volcano is younger than 10 ka.     

40Ar/39Ar constraints on the temporal evolution of Graciosa Island, Azores (Portugal)

Lava flows spanning the eruptive record of Graciosa Island (Azores archipelago) and a gabbro xenolith were dated by ⁴⁰Ar/³⁹Ar in order to constrain the Pleistocene and Holocene volcanic evolution of the island. The results range from 1.05 Ma to 3.9 ka, whereas prior published K–Ar and ¹⁴C ages range from 620 to 2 ka. The formation of the Serra das Fontes shield volcano started at minimum 1.05 Ma, and the magmatic system was active for ca. 600 ky, as suggested by the formation of the gabbro xenolith by magmatic differentiation. Evolved magmas making up the Serra das Fontes–Serra Branca composite volcano were generated at ca. 450 ka. After a period of ca. 110 ky of volcanic inactivity and erosion of volcanic edifices, volcanism was reactivated with the formation of the Vitória Unit NW platform. Later, the development of the Vulcão Central Unit started with the formation of monogenetic cones located to the south of the Serra das Fontes–Serra Branca–Vitória Unit. This volcanism became progressively more evolved and was concentrated in a main eruptive center, forming the Vulcão Central stratovolcano with an age older than 50 ka. The caldera related to this stratovolcano is older than 47 ka and was followed by effusion of basaltic magmas into the caldera, resulting in the formation of a lava lake, which ultimately spilled over the caldera rim at ca. 11 ka. The most recent eruptions on Graciosa formed two small pyroclastic cones within the caldera and the Pico do Timão cone within the Vitória Unit at ca 3.9 ka.     

The <Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar geochronology constraint and geological significance of mylonites in Shangyi-Chicheng fault belt on the north of North China Craton

A dating of two biotite samples taken from the meso- and low-temperature mylonites within the Shangyi-Chicheng fault belt on the north of the North China Craton yields ⁴⁰Ar/³⁹Ar isotopic ages of (399 ± 1) Ma and (263 ± 2) Ma, respectively. These data reflect an Early Devonian deformation and a Late Carboniferous retrograde metamorphism event along the fault, suggesting that the tectonic activities of the North China Craton in Paleozoic should be reconsidered.     

First Ar/Ar age of the Ceprano man (central Italy)

The Ceprano calvarium, found in 1994 in Italy and attributed to Homo cepranensis, is one of the most celebrated hominin remains of Europe. It was considered at least 700 ka-old until a recent investigation incorporating magnetostratigraphy and K-Ar ages from the literature assigned to the calvarium an age of ∼450 (+50, −100) ka. Here we pin down the age of the Ceprano calvarium to 353 ± 4 ka (±1σ external) by means of new ⁴⁰Ar/³⁹Ar dating on K-feldspars retrieved from the sediments that hosted the skull. In absence of evidence of reworking, this refined age sinks the conviction that H. cepranensis belonged to human evolution at the Brunhes–Matuyama boundary (c.a. 781 ka). Our refined age indicates that H. cepranensis lived in central Italy probably during the cold period of marine isotope stage (MIS) 10, and that despite his archaic morphology and lack of Neanderthal traits, he was contemporaneous with more advanced species such as H. heidelbergensis.     

The rhyolitic–andesitic eruptive history of Cotopaxi volcano,Ecuador

At Cotopaxi volcano, Ecuador, rhyolitic and andesitic bimodal magmatism has occurred periodically during the past 0.5 Ma. The sequential eruption of rhyolitic (70–75% SiO₂) and andesitic (56–62% SiO₂) magmas from the same volcanic vent over short time spans and without significant intermingling is characteristic of Cotopaxi’s Holocene behavior. This study documents the eruptive history of Cotopaxi volcano, presenting its stratigraphy and geologic field relations, along with the relevant mineralogical and chemical nature of the eruptive products, in order to determine the temporal and spatial relations of this bimodal alternation. Cotopaxi’s history begins with the Barrancas rhyolite series, dominated by pumiceous ash flows and regional ash falls between 0.4 and 0.5 Ma, which was followed by occasional andesitic activity, the most important being the ample andesitic lava flows (∼4.1 km³) that descended the N and NW sides of the edifice. Following a ∼400 ka long repose without silicic activity, Cotopaxi began a new eruptive phase about 13 ka ago that consisted of seven rhyolitic episodes belonging to the Holocene F and Colorado Canyon series; the onset of each episode occurred at intervals of 300–3,600 years and each produced ash flows and regional tephra falls with DRE volumes of 0.2–3.6 km³. Andesitic tephras and lavas are interbedded in the rhyolite sequence. The Colorado Canyon episode (4,500 years BP) also witnessed dome and sector collapses on Cotopaxi’s NE flank which, with associated ash flows, generated one of the largest cohesive debris flows on record, the Chillos Valley lahar. A thin pumice lapilli fall represents the final rhyolitic outburst which occurred at 2,100 years BP. The pumices of these Holocene rhyolitic eruptions are chemically similar to those of older rhyolites of the Barrancas series, with the exception of the initial eruptive products of the Colorado Canyon series whose chemistry is similar to that of the 211 ka ignimbrite of neighboring Chalupas volcano. Since the Colorado Canyon episode, andesitic magmatism has dominated Cotopaxi’s last 4,400 years, characterized by scoria bomb and lithic-rich pyroclastic flows, infrequent lava flows that reached the base of the cone, andesitic lapilli and ash falls that were carried chiefly to the W, and large debris flows. Andesitic magma emission rates are estimated at 1.65 km³ (DRE)/ka for the period from 4,200 to 2,100 years BP and 1.85 km³ (DRE)/ka for the past 2,100 years, resulting in the present large stratocone.