CARBONATE EROSION RATES IN SOUTHWESTERN WISCONSIN

Between 1977 and 1979 three sets of erosional weight loss tablets were em-placed in the karst of southwestern Wisconsin to measure both potential and actual rates of carbonate erosion. Tablets of Jamaican White Limestone, which has been used in many other karst areas, were used to gauge relative erosion potential while tablets of the local bedrock, Prairie du Chien dolomite, were used to assess absolute rates. Tablets of Yugoslavian limestone were emplaced as part of a world-wide study of comparative rates. Tablets were recovered in 1983 and 1984. Although potential erosion rates are similar to those in other carbonate areas, the sluggish dissolution of the indigenous dolomite retards karst development. Soil cover increases erosion rates and rates at a given depth are consistent over sites of up to 10 m². The highest erosion rates were recorded by the Yugoslavian tablets but betweensite variations caution that results based on a single site may be unrepresentative. Over 37% of all tablets were affected by mechanical weathering processes, probably freeze-thaw action.     

Effects of Fe3+ on Dissolution Dynamics of Carbonate Rocks in a Shallow Burial Reservoir

Dissolution of carbonates in acidic fluids, which has attracted much research attention in recent years, is of great significance for the formation of high-quality reservoirs. The dissolution stage under low temperature and low pressure in shallow burial is one of the most important processes of reservoir dissolution and transformation. However, the dissolution dynamics of carbonate rocks in shallow burial and their formation have been controversial for a long time, and there are still disputes in the dissolution processes about how associated minerals and accessory minerals (e.g., pyrite) in carbonate reservoirs influence the formation of secondary pores. Additional metal ions in acidic fluids can change fluid properties and dissolution processes, and consequently affect reservoir quality. However, there are few laboratory studies done on the effect of associated minerals on the dissolution dynamics of carbonates. To clarify the specific impact of Fe-bearing associated minerals and Fe³⁺ on the dissolution of carbonates in shallow burial reservoirs, six samples of typical carbonate rocks in the Zigui area of Hubei Province, China were studied. The dissolution kinetics of carbonates in dilute hydrochloric acid and sulfuric acid solutions containing metal ions (Fe³⁺/Ca²⁺/Mn²⁺) at ambient temperature and pressure (T?=?25 °C, P?=?1 atm) were studied, by laboratory dissolution experiments combined with numerical simulations using PHREEQC. The results show that the Fe³⁺ is of great significance on the dissolution of carbonate rocks, while the influences of Ca²⁺ and Mn²⁺ are relatively weak. The dissolutions degrees of micritic limestone (ZG-L25), dolomitic limestone (ZG-L7) and dolomite (ZG-D9) were better than the other carbonates under the influence of metal ions (Fe³⁺/Ca²⁺/Mn²⁺) in acid solutions. Therefore, the dolomite reservoir of the Cambrian Qinjiamiao Formation, the dolomitic limestone reservoir of the Tianheban Formation and the limestone reservoir of the Triassic Daye Formation in the Zigui area are potential high-quality reservoirs. The carbonate reservoirs associated with Fe-bearing minerals were easier to dissolve and formed secondary pores under shallow burial. This process is beneficial to the formation of high-quality reservoirs. Moreover, the addition of Fe³⁺ into hydrochloric acid solution may be conducive to improving the reservoirs acidizing effect. Furthermore, the results gave innovative results from multiple perspectives of geo-material science and computational geosciences, which may provide new avenues for in-depth study of carbonate dissolution in shallow burial based on water–rock reaction, chemical dissolution, computational simulation, and geological background.

     

A large daylight geodesic dome for quantification of whole-ecosystem CO2 and water vapour fluxes in arid shrublands

We designed, constructed, calibrated and field-tested a lightweight (30 kg), 4.2 m diameter, 16.4 m³ polyethylene-covered dome static chamber ecosystem gas exchange cuvette that can quantify ecosystem CO₂ and water vapour fluxes as low as 0.1 μmol CO₂ m⁻² s⁻¹ and 0.1 mmol H₂O m⁻² s⁻¹ with little impact on environmental conditions. Fluxes measured in May 2001 in an intact Great Basin sagebrush ecosystem at midday were significantly higher than in an adjacent post-wildfire successional ecosystem, with observed ranges from –0.71 to 1.49 μmol CO₂ m⁻² s⁻¹ for CO₂ and from –0.09 to 0.53 mmol H₂O m⁻² s⁻¹ for water vapour.     

Weathering characteristics of arctic islands in northern Norway

The arctic islands of the Lofoten-Vesterålen archipelago in northern Norway have a wide distribution of weathered land surfaces commonly located above 250 m with several apparent similarities. In order to investigate the characteristics of (deep) weathering in this region, northern Langøya and Hadseløya were chosen for in-depth analyses. Eight weathering profiles were excavated from various surfaces, and the stratigraphies were logged in detail. Material was collected throughout the weathering horizons, and all samples were subsequently analysed for clay mineralogy (< 63 μm fraction) and grain size distribution. The sampling strategy was complemented by samples from additional saprolites and other landforms such as moraines and rock glaciers. The XRD results indicate that the presence of secondary minerals, such as gibbsite (Al(OH)₃) and kaolinite (Al₂Si₂O₅(OH)₄), are very common throughout the profiles. Gibbsite is an extreme end product of silicate weathering and usually associated with a warmer and more humid climate, as found in Scandinavia during the Tertiary. The grain size analyses (< 63 μm) show that the finer silt fractions (< 8 μm) tend to be high in the profiles (20–40%), with significant amounts of clay (5–15%) demonstrating that the regolith itself is susceptible to frost sorting mechanisms.¹⁰Be exposure dates from in situ quartz knobs on tors and boulders of local origin suggest > 40,000 years of subaerial conditions. Considering the steady surface erosion, this figure should be viewed as an absolute minimum age estimate. Mapping of the superficial sediments and geomorphological features of the study areas has revealed several common morphological features, which indicate dominance of glacial and periglacial processes in the areas lying below the lower boundary of blockfields (c. 250 m). The weathering mantles are not a periglacial end product, but rather a relict tertiary landform that were modulated by permafrost processes as well as biological processes at later stages. The regolith cover constrain the vertical extension of warm-based Quaternary ice sheets challenging the notion of a parabolic ice mass consuming every mountain top of Lofoten and Vesterålen.     

Cosmogenic He exposure ages of Pleistocene debris flows and desert pavements in Capitol Reef National Park, Utah

The Quaternary history of the Capitol Reef area, Utah, is closely linked to the basaltic-andesite boulder deposits that cover much of the landscape. Understanding the age and mode of emplacement of these deposits is crucial to deciphering the Quaternary evolution of this part of the Colorado Plateau. Using cosmogenic ³He exposure age dating, we obtained apparent exposure ages for several key deposits in the Capitol Reef area. Coarse boulder diamicts capping the Johnson Mesa and Carcass Creek Terraces are not associated with the Bull Lake glaciation as previously thought, but were deposited 180±15 to 205±17 ka (minimum age) and are the result of debris flow deposition. Desert pavements on the Johnson Mesa surface give exposure ranging from 97±8 to 159±14 ka and are 34–96 kyears younger than the boulder exposure ages. The offset between the boulder and pavement exposure ages appears to be related to a delay in pavement formation until the penultimate glacial/interglacial transition or periodic burial and exposure of pavement clasts since debris flow deposition. Incision rates for the Capitol Reef reach of the Fremont River calculated from the boulder exposure ages range from 0.40 to 0.43 m kyear⁻¹ (maximum rates) and are some of the highest on the Colorado Plateau.     

Beach–dune interactions on the dry–temperate Danube delta coast

Beach–dune seasonal elevation changes, aeolian sand transport measurements, bathymetric surveys and shoreline evolution assessments were used to investigate annual and seasonal patterns of dune development on Sfântu Gheorghe beach, the Danube delta coast, from 1997 to 2004. Dune volume increased consistently (1.96 m³ m^− 1 y^− 1 to 5.1 m³ m^− 1 y^− 1) over this 7-year period with higher rates in the southward (downdrift) direction. Dune aggradation is periodically limited by storms, each of which marks a new evolutionary phase of the beach–dune system. As a consequence of the variable beach morphology and vegetation density during a year, foredune growth occurs during the April–December interval while between December and April a slightly erosive tendency is present. The pattern of erosion and deposition shown by the topographical surveys is in good agreement with the sand transport measurements and demonstrates the presence of a vigorous sand flux over the foredunes which is 20–50% smaller than on the beach. This high sand flux, due to low precipitation and sparse vegetation cover, creates an aerodynamically efficient morphology on the seaward dune slope. The seaward dune face accretes during low to medium onshore winds (5.5–12 m s^− 1) and erodes during high winds (> 12 m s^− 1).     

Quaternary bedrock erosion and landscape evolution in the Sør Rondane Mountains, East Antarctica: Reevaluating rates and processes

Rates and processes of rock weathering, soil formation, and mountain erosion during the Quaternary were evaluated in an inland Antarctic cold desert. The fieldwork involved investigations of weathering features and soil profiles for different stages after deglaciation. Laboratory analyses addressed chemistry of rock coatings and soils, as well as ¹⁰Be and ²⁶Al exposure ages of the bedrock. Less resistant gneiss bedrock exposed over 1 Ma shows stone pavements underlain by in situ produced silty soils thinner than 40 cm and rich in sulfates, which reflect the active layer thickness, the absence of cryoturbation, and the predominance of salt weathering. During the same exposure period, more resistant granite bedrock has undergone long-lasting cavernous weathering that produces rootless mushroom-like boulders with a strongly Fe-oxidized coating. The red coating protects the upper surface from weathering while very slow microcracking progresses by the growth of sulfates. Geomorphological evidence and cosmogenic exposure ages combine to provide contrasting average erosion rates. No erosion during the Quaternary is suggested by a striated roche moutonnée exposed more than 2 Ma ago. Differential erosion between granite and gneiss suggests a significant lowering rate of desert pavements in excess of 10 m Ma^− 1. The landscape has been (on the whole) stable, but the erosion rate varies spatially according to microclimate, geology, and surface composition.     

Modeling urban leaf area index with AISA+ hyperspectral data

This study used simple multiple regression to model urban leaf area index (LAI) in Terre Haute, Indiana, USA as a function of AISA+ hyperspectral radiance and its derivative features. Regression R² values ranging from 0.27 to 0.73 were obtained from the various models. Features appearing most frequently in the models included radiance at 0.727, 0.753, 0.848, 0.870, 0.900 and 0.917 μm. The best single predictor of LAI was the absolute difference in radiance between 0.777 and 0.673 μm. The best models performed well at low and intermediate LAI levels, but were less accurate with LAI values between 5.0 and 8.0.     

Holocene Lake Level Fluctuations Recorded in the Sediment Compositionof Lake Juusa,Southeastern Estonia

The main aim of this study was to reconstruct the history of water level fluctuations of a small dimictic lake during the Holocene based on the lithological and geochemical composition of sediments. We studied lithological and geochemical parameters in sediment cores extracted along a transect through Lake Juusa in southeastern Estonia. Analysis revealed that LOI₅₅₀ and CaCO₃ content in the accumulated sediment are dependent on water depth. At depths greater than 3 m, the relationship between organic carbon and CaCO₃ is inverse, whereas no relationship exists at shallower depths. Lake-level changes are well depicted on the grain-size distribution profiles and macrofossil composition. An increase in the >‰315μm fraction appeared during the initial phases of water level fluctuations, followed by an increase in the 100–315μm fraction. The >‰36μm fraction dominated the silt fraction. Higher OC/N ratios in shallow water sediments reflect the dominance of macrophytes vegetation.     

The effects of seasonal changes to in-stream vegetation cover on patterns of flow and accumulation of sediment

In-stream macrophytes are typically abundant in nutrient-rich chalk streams during the spring and summer months and modify the in-stream environment by altering river flows and trapping sediments. We present results from an inter-disciplinary study of two river reaches in the River Frome catchment, Dorset (UK). The investigation focused on how Ranunculus (water crowfoot), the dominant submerged macrophyte in the study reaches, modified patterns of flow and sediment deposition. Measurements were taken on a monthly basis throughout 2003 to determine seasonal patterns in macrophyte cover, associated changes in the distributions of flow velocities and the character and amount of accumulated fine sediment within stands of Ranunculus.Maximum in-stream cover of macrophytes exceeded 70% at both sites. Flow velocities were less than 0.1 m s^− 1 within the stands of Ranunculus and accelerated to 0.8 m s^− 1 outside the stands. During the early stages of the growth of Ranunculus, fine sediment mostly accumulated within the upstream section of the plant but the area of fine sediment accumulation extended into the downstream trailing section of the plant later in the growing season. The fine sediment accumulations were dominated by sand (63–1000 μm) with silts and clays (0.37–63 μm) comprising < 10% by volume. The content of organic matter in the accumulated sediments varied within stands, between reaches and through the growing season with values ranging between 9 and 105 mg g^− 1 dry weight. At the reach scale the two sites exhibited different growth forms of Ranunculus which created distinctive patterns of flow and fine sediment deposition.     

Statistical properties of the Transantarctic Mountains (TAM) micrometeorite collection

Micrometeorites have been recovered from traps located at the summit of nunataks in the Transantarctic Mountains (TAM), Antarctica. They constitute the TAM micrometeorite collection. Micrometeorites accumulated by direct infall for hundreds of thousands of years. This long collection duration is confirmed by the wide range of weathering by dissolution of olivine in the stony micrometeorites from the TAM collection. A statistical study of the size distribution and frequency by type of this collection, and comparison with other Antarctic micrometeorite collections (the South Pole Water Well collection and the Walcott Névé collection), suggest that the TAM collection is essentially unbiased. Thanks to the very long exposure of the traps, large diameter (>1000 μm) micrometeorites are present in sufficiently large numbers to allow a statistically meaningful estimate of their size distribution in this size range for the first time. We found that the slope of the size distribution remains constant in the 100–1600 μm size range. Therefore, the size distribution of micrometeorites in this size range is controlled by a single process.     

Size fraction and class composition of phytoplankton in the Antarctic marginal ice zone along the 140°E meridian during February–March 2003

We investigated the size fraction and pigment-derived class compositions of phytoplankton within the euphotic zone of the Antarctic marginal ice zone between 63.3°S and 66.5°S along the 140°E meridian on two consecutive cruises in the late austral summer and early austral autumn of 2003. We observed significant temporal and spatial variations in phytoplankton size and taxonomic composition, although chlorophyll a concentrations were generally below 1 μg l⁻¹ during both periods. Microphytoplankton (>20 μm), mainly diatoms, were prominent in the euphotic zone in the southernmost area around 66.5°S during late summer. In the rest of the study area during both cruises, the phytoplankton community was dominated by pico- and nano-sized populations (<20 μm) throughout the euphotic zone. The small-size populations mostly consisted of diatoms and haptophytes, although chlorophytes were dominant in extremely cold water (−1.5°C) below the overlying warm water around 65.5°S during late summer. From late summer to early autumn, chlorophytes declined in abundance, probably due to increasing temperature within the euphotic zone (−1 to 0°C). These pico- and nano-phytoplankton-dominated populations were often accompanied by relatively high concentrations of ammonium, suggesting the active regeneration of nutrients within the small-size plankton community.     

Sensitivity analysis of pediment development through numerical simulation and selected geospatial query

Dozens of references recognizing pediment landforms in widely varying lithologic, climatic, and tectonic settings suggest a ubiquity in pediment forming processes on mountain piedmonts worldwide. Previous modeling work illustrates the development of a unique range in arid/semiarid piedmont slope (< 0.2 or 11.3°) and regolith thickness (2–4 m) that defines pediments, despite varying the initial conditions and domain characteristics (initial regolith thickness, slope, distance from basin to crest, topographic perturbations, and boundary conditions) and process rates (fluvial sediment transport efficiency and weathering rates). This paper expands upon the sensitivity analysis through numerical simulation of pediment development in the presence of spatially varying rock type, various base level histories, various styles of sediment transport, and various rainfall rates to determine how pediment development might be restricted in certain environments. This work suggests that in landscapes characterized by soil and vegetation types that favor incisive fluvial sediment transport styles coupled with incisive base level conditions, pediment development will be disrupted by the roughening of sediment mantled surfaces, thereby creating spatial variability in topography, regolith thickness, and bedrock weathering rates. Base level incision rates that exceed the integrated sediment flux along a hillslope derived from upslope weathering and sediment transport on the order of 10^− 3 m y^− 1 restrict pediment development by fostering piedmont incision and/or wholesale removal (stripping) of regolith mantles prior to footslope pediment development. Simulations illustrate an insensitivity to alternating layers of sandstone and shale 3–15 m thick oriented in various geometric configurations (vertical, horizontal, and dip-slope) and generating different regolith hydrologic properties and exhibiting weathering rate variations up to 3-fold. Higher fluxes and residence times of subsurface groundwater in more humid environments, as well as dissolution-type weathering, lead to a thickening of regolith mantles on erosional piedmonts on the order of 10¹ m and an elimination of pediment morphology. An initial test of the model sensitivity analysis in arid/semiarid environments, for which field reconnaissance and detailed geomorphic mapping indicate the presence of pediments controlled by climatic conditions (soil hydrologic properties, vegetation characteristics, and bedrock weathering style) that are known and constant, supports our modeling results that pediments are more prevalent in hydrologically-open basins.     

Growth response of three globose cacti to radiation and soil moisture: An experimental test of the mechanism behind the nurse effect

Cactus seedlings often establish under nurse plants which modify environmental conditions by increasing moisture and decreasing solar radiation, which may cause beneficial and detrimental effects, respectively, on seedling growth. Three soil moisture treatments (5%, 25% and 60%) and two solar radiation levels (100% exposure=243 μmol m⁻² s⁻¹, and 40%=102 μmol m⁻² s⁻¹) were used in a factorial design to analyze seedling growth response of three rare cactus species (Mammillaria pectinifera, Obregonia denegrii and Coryphantha werdermannii). The variables evaluated were relative growth rate (RGR), root/shoot ratio (R/S), and K (RGR_roots/RGR_shoot), obtained from an initial seedling harvest (6-month-old seedlings) and a final harvest 6 months after treatment application. All three species had slow RGRs (0.002–0.012 g g⁻¹ day⁻¹). O. denegrii had the lowest RGR values, but was the only species for which R/S and K varied with soil moisture. While all seedlings responded markedly to soil moisture, no response was observed to radiation treatments. The latter might have been related to the relatively low solar radiation levels present in the greenhouse. Yet, our results suggest that the main benefit nurse plants offer to seedlings is the increase in soil moisture.     

Inland saline lakes of Wadi El Natrun depression, Egypt

The morphology and geochemistry of saline lakes in the Wadi El Natrun depression were studied. All lakes had pH values of 8.5--9.5 and a salinity from 283 to 540 g/L. The main ionic components were sulphate, chloride, carbonate and sodium. Traces of magnesium were also present. The water of the lakes is of the Cl^– to SO ₄ ^2– -Cl^– type. Increased Cl^– in Wadi El Natrun brines can increase metal solubility due to the formation of soluble chloro-complexes of trace elements. The metal concentrations decrease in the order: Pb > Cu > Cd > Ni > Zn > Fe > Mn. The characteristics of Wadi El Natrun saline lakes are compared with those from other saline lakes.     

New constraints on the late Cenozoic incision history of the New River, Virginia

The New River crosses three physiogeologic provinces of the ancient, tectonically quiescent Appalachian orogen and is ideally situated to record variability in fluvial erosion rates over the late Cenozoic. Active erosion features on resistant bedrock that floors the river at prominent knickpoints demonstrate that the river is currently incising toward base level. However, thick sequences of alluvial fill and fluvial terraces cut into this fill record an incision history for the river that includes several periods of stalled downcutting and aggradation. We used cosmogenic ¹⁰Be exposure dating, aided by mapping and sedimentological examination of terrace deposits, to constrain the timing of events in this history. ¹⁰Be concentration depth profiles were used to help account for variables such as cosmogenic inheritance and terrace bioturbation. Fill-cut and strath terraces at elevations 10, 20, and 50 m above the modern river yield model cosmogenic exposure ages of 130, 600, and 600–950 ka, respectively, but uncertainties on these ages are not well constrained. These results provide the first direct constraint on the history of alluvial aggradation and incision events recorded by New River terrace deposits. The exposure ages yield a long-term average incision rate of 43 m/my, which is comparable to rates measured elsewhere in the Appalachians. During specific intervals over the last 1 Ma, however, the New River's incision rate reached 100 m/my. Modern erosion rates on bedrock at a prominent knickpoint are between 28 and 87 m/my, in good agreement with rates calculated between terrace abandonment events and significantly faster than 2 m/my rates of surface erosion from ancient terrace remnants. Fluctuations between aggradation and rapid incision operate on timescales of 10⁴− 10⁵ year, similar to those of late Cenozoic climate variations, though uncertainties in model ages preclude direct correlation of these fluctuations to specific climate change events. These second-order fluctuations appear within a longer-term signal of dominant aggradation (until 2 Ma) followed by dominant incision. A similar signal is observed on other Appalachian rivers and may be the result of sediment supply fluctuations driven by the increased frequency of climate changes in the late Cenozoic.     

Chemical weathering and CO2 consumption in the Xijiang River basin, South China

Monthly samples of riverine water were collected and analyzed for the concentrations of major ions (Ca²⁺, Mg²⁺, K⁺, Na⁺, HCO₃⁻, SO₄²⁻, Cl⁻, NO₃⁻), dissolved silicon, and total dissolved solids (TDS) at Wuzhou hydrological station located between the middle and lower reaches of the Xijiang River (XJR) from March 2005 to April 2006. More frequent sampling and analysis were carried out during the catastrophic flooding in June 2005. Stoichiometric analysis was applied for tracing sources of major ions and estimating CO₂ consumption from the chemical weathering of rocks. The results demonstrate that the chemical weathering of carbonate and silicate rocks within the drainage basin is the main source of the dissolved chemical substances in the XJR. Some 81.20% of the riverine cations originated from the chemical weathering processes induced by carbonic acid, 11.32% by sulfuric acid, and the other 7.48% from the dissolution of gypsum and precipitates of sea salts within the drainage basin. The CO₂ flux consumed by the rock chemical weathering within the XJR basin is 2.37 × 10¹¹ mol y^− 1, of which 0.64 × 10¹¹ mol y^− 1 results from silicate rock chemical weathering, and 1.73 × 10¹¹ mol y^− 1 results from carbonate rock chemical weathering. The CO₂ consumption comprises 0.38 × 10¹¹ mol during the 9-d catastrophic flooding. The CO₂ consumption from rock chemical weathering in humid subtropical zones regulates atmospheric CO₂ level and constitutes a significant part of the global carbon budget. The carbon sink potential of rock chemical weathering processes in the humid subtropical zones deserves extra attention.     

Tracking of saltating sand trajectories over a flat surface embedded in an atmospheric boundary layer

Saltation is a major mechanism for the transport of soil particles. In the present study, we carried out wind tunnel tests to examine the saltating trajectories of two types of natural sand collected from a beach (diameter, d = 300–500 μm and 200–300 μm respectively) as well as sand from the Taklimakan desert (d = 100–125 μm) in an atmospheric boundary layer. Consecutive images of saltating particles were recorded using a high-speed digital camera at a rate of 2000 fps with a spatial resolution of 1024 × 1024 pixels. The high temporal resolution of the acquired images enabled us to study the particle motion very close to the surface. The saltating particle trajectories were reconstructed from consecutive images, and the physical quantities characterizing the initial and final stages of the particle flight in the windward direction at friction velocities of about 10%–25% above the threshold friction velocity (u / u_t = 1.11–1.26) were analyzed statistically. In addition, the transverse deviation of the saltating particles from the main streamwise direction was evaluated. The results shed new light on the complicated motions involved in sand saltation and should prove useful in the evaluation and formulation of theoretical models.     

Extractable and total Fe and Mn contents of three sand dune soils in NW Nigeria

The profile distribution of total, diethylene triamine penta-acetic acid (DTPA)- and 0·1 HCl-extractable Fe and Mn were determined in 12 pedons formed on three contiguous sand dunes in the semi-arid savanna of Nigeria. The total Fe and Mn contents varied from 100 to 3750 and 40 to 11,375 μg g⁻¹, respectively. Values of 0·1 HCl-extractable Fe and Mn varied from 8·0 to 123 and 1·5 to 43·5 μg g⁻¹, respectively. The corresponding values of DTPA-extractable Fe and Mn were 4·5 to 16·0 and 1·0 to 38·8 μg g⁻¹. Total Fe and Mn correlated significantly with clay in nearly all the dunes (p≤ 0·01) but were not significantly correlated with organic matter. The 0·1 HCl-extractable Mn had a positive significant correlation with soil pH (r= 0·58*) in Illela dunes but a negative significant correlation with pH in the Sangiwa dunes (r= −0·75***). The values of extractable Fe and Mn in the sand dune soils are above the critical limits reported in other literature, thus deficiencies of these micronutrients do not pose a problem to crop production in the study area.     

Holocene paleoclimatic evidence and sedimentation rates from a core in southwestern Lake Michigan

Preliminary results of a multidisciplinary study of cores in southwestern Lake Michigan suggest that the materials in these cores can be interpreted in terms of both isostatically and climatically induced changes in lake level. Ostracodes and mollusks are well preserved in the Holocene sediments, and they provide paleolimnologic and paleoclimatic data, as well as biogenic carbonate for stable-isotope studies and radiocarbon dating. Pollen and diatom preservation in the cores is poor, which prevents comparison with regional vegetation records. New accelerator-mass spectrometer ¹⁴C ages, from both carbon and carbonate fractions, provide basin-wide correlations and appear to resolve the longstanding problem of anomalously old ages that result from detrital organic matter in Great Lakes sediments.Several cores contain a distinct unconformity associated with the abrupt fall in lake level that occurred about 10.3 ka when the isostatically depressed North Bay outlet was uncovered by the retreating Laurentide Ice Sheet. Below the unconformity, ostracode assemblages imply deep, cold water with very low total dissolved solids (TDS), and bivalves have ¹⁸O (PDB) values as light as — 10 per mil. Samples from just above the unconformity contain littoral to sublittoral ostracode species that imply warmer, higher-TDS (though still dilute) water than that inferred below the unconformity. Above this zone, another interval with ¹⁸O values more negative than — 10 occurs. The isotopic data suggest that two influxes of cold, isotopically light meltwater from Laurentide ice entered the lake, one shortly before 10.3 ka and the other about 9 ka. These influxes were separated by a period during which the lake was warmer, shallower, but still very low in dissolved solids. One or both of the meltwater influxes may be related to discharge from Lake Agassiz into the Great Lakes.Sedimentation rates appear to have been constant from about 10 ka to 5 ka. Bivalve shells formed between about 8 and 5 ka have ¹⁸O values that range from-2.3 to-3.3 per mil and appear to decrease toward the end of the interval. The ostracode assemblages and the stable isotopes suggest changes that are climatically controlled, including fluctuating water levels and increasing dissolved solids, although the water remained relatively dilute (TDS < 300 mg/l).A dramatic decrease in sedimentation rates occurred at about 5 ka, about the time of the peak of the Nippissing high lake stage. This decrease in sedimentation rate may be associated with a large increase in effective wave base as the lake approached its present size and fetch. A dramatic reduction in ostracode and mollusk abundances during the late Holocene is probably due to this decrease in sedimentation rates, which would result in increased carbonate dissolution. Ostracode productivity may also have declined due to a reduction in bottom-water oxygen caused by increased epilimnion algal productivity.Woods Hole Oceanographic Institute Contribution No. 7492