The catalogue of Quaternary volcanoes of the Greater Caucasus based on geochronological,volcanological and isotope-geochemical data

A catalogue of Quaternary volcanoes of the Greater Caucasus has been compiled based on recent geological, petrological-geochemical and isotope-geochronological data obtained in the last decades. This catalogue provides insight into the evolution of the youngest magmatism in this part of the Alpine-Himalayan fold belt at the modern level of knowledge. The catalogue is given as a set of tabular data on 74 volcanic edifices that have been found and described in literature in varying detail, including their coordinates, absolute height, type of edifice and the predominant type of eruption, age, as well as main petrographic, isotope-geochemical characteristics, and the chemical composition of the products of magmatic activity. For the sake of convenience, the volcanoes of the Kazbek and Elbrus neovolcanic areas representing two main areals of young magmatism at the Greater Caucasus are described separately. In addition, data on the Kazbek area are grouped by traditionally distinguished volcanic centers. Text presents general information on the Quaternary volcanic activity within the Greater Caucasus, its geochronology, spatiotemporal distribution, and petrogenesis of the youngest volcanic rocks.     

Structure and evolution of the Rockeskyllerkopf Volcanic Complex, West Eifel Volcanic Field, Germany

The Rockeskyllerkopf Volcanic Complex (RVC) comprises three overlapping monogenetic volcanic centers: Southeast Lammersdorf (SEL), Mäuseberg (M) and Rockeskyllerkopf (RKK). Each volcanic center comprises proximal wall deposits with a well defined crater wall unconformity and crater fill deposits that partially to completely cover the outer crater wall. The SEL Center is a phreatomagmatic tuff ring composed of lithic rich tephra deposited by pyroclastic falls and surges. The second center, Mäuseberg, with its crater to the northwest of the SEL Center is predominantly magmatic. Topographic and outcrop patterns suggest that this center may have formed a series of overlapping scoria cones along a N–S trending fissure. The youngest center, RKK, which lies on a poorly developed palaeosol within the earlier Mäuseberg deposits, comprises a well developed proximal crater wall sequence. This sequence of magmatic, likely Strombolian, fall and grain avalanche deposits passes upward into a crater fill sequence that comprises variably welded bombs. The final eruptions in the center were massive lava flows that were ponded within the RKK crater. Ar–Ar age dating of reequilibrated fragments of phlogopite megacrysts in the SEL lavas indicates volcanic activity began at 474?±?39 ka. Literature K–Ar dates for the youngest lava flows in the RKK Center give ages of 360?±?60 to 470 ka. Our interpretation of the age data and the presence of the poorly developed palaeosol between the Mäuseberg and RKK centers indicates that volcanism in the RVC began around 470 ka with the eruption of the SEL and Mäuseberg centers followed a few thousand years later by the eruption of the RKK Center.     

Inverse differentiation pathway by multiple mafic magma refilling in the last magmatic activity of Nisyros Volcano, Greece

Based on detailed field, petrographic, chemical, and isotopic data, this paper shows that the youngest magmas of the active Nisyros volcano (South Aegean Arc, Greece) are an example of transition from rhyolitic to less evolved magmas by multiple refilling with mafic melts, triggering complex magma interaction processes. The final magmatic activity of Nisyros was characterized by sub-Plinian caldera-forming eruption (40?ka), emplacing the Upper Pumice (UP) rhyolitic deposits, followed by the extrusion of rhyodacitic post-caldera domes (about 31–10?ka). The latter are rich in magmatic enclaves with textural and compositional (basaltic–andesite to andesite) characteristics that reveal they are quenched portions of mafic magmas included in a cooler more evolved melt. Dome-lavas have different chemical, isotopic, and mineralogical characteristics from the enclaves. The latter have lower ⁸⁷Sr/⁸⁶Sr and higher ¹⁴³Nd/¹⁴⁴Nd values than dome-lavas. Silica contents and ⁸⁷Sr/⁸⁶Sr values decrease with time among dome-lavas and enclaves. Micro-scale mingling processes caused by enclave crumbling and by widespread mineral exchanges increase from the oldest to the youngest domes, together with enclave content. We demonstrate that the dome-lavas are multi-component magmas formed by progressive mingling/mixing processes between a rhyolitic component (post-UP) and the enclave-forming mafic magmas refilling the felsic reservoir (from 15?wt.% to 40?wt.% of mafic component with time). We recognize that only the more evolved enclave magmas contribute to this process, in which recycling of cumulate plagioclase crystals is also involved. The post-UP end-member derives by fractional crystallization from the magmas leftover after the previous UP eruptions. The enclave magma differentiation develops mainly by fractional crystallization associated with multiple mixing with mafic melts changing their composition with time. A time-related picture of the relationships between dome-lavas and relative enclaves is proposed, suggesting a delay between a mafic magma input and the relative dome outpouring. We also infer that the magma viscosity reduction by re-heating allows dome extrusion without explosive activity.     

Crustal structure, evolution, and volcanic unrest of the Alban Hills, Central Italy

 The Alban Hills, a Quaternary volcanic center lying west of the central Apennines, 15–25 km southeast of Rome, last erupted 19 ka and has produced approximately 290 km³ of eruptive deposits since the inception of volcanism at 580 ka. Earthquakes of moderate intensity have been generated there at least since the Roman age. Modern observations show that intermittent periods of swarm activity originate primarily beneath the youngest features, the phreatomagmatic craters on the west side of the volcano. Results from seismic tomography allow identification of a low-velocity region, perhaps still hot or partially molten, more than 6 km beneath the youngest craters and a high-velocity region, probably a solidified magma body, beneath the older central volcanic construct. Thirty centimeters of uplift measured by releveling supports the contention that high levels of seismicity during the 1980s and 1990s resulted from accumulation of magma beneath these craters. The volume of magma accumulation and the amount of maximum uplift was probably at least 40×10⁶ m³ and 40 cm, respectively. Comparison of newer levelings with those completed in 1891 and 1927 suggests earlier episodes of uplift. The magma chamber beneath the western Alban Hills is probably responsible for much of the past 200 ka of eruptive activity, is still receiving intermittent batches of magma, and is, therefore, continuing to generate modest levels of volcanic unrest. Bending of overburden is the most likely cause of the persistent earthquakes, which generally have hypocenters above the 6-km-deep top of the magma reservoir. In this view, the most recent uplift and seismicity are probably characteristic and not precursors of more intense activity. Received: 15 April 1997 / Accepted: 9 August 1997     

ESR dating of quartz phenocrysts in the El Cajete and Battleship Rock Members of Valles Rhyolite, Valles Caldera, New Mexico

The electron spin resonance (ESR) dating method was employed on quartz phenocrysts separated from pumice of the El Cajete and Battleship Rock Members of the Valles Rhyolite in the Valles caldera, New Mexico. The results of heating experiments indicate that Ti impurity centers have two components; a thermally stable one and a less stable, temperature sensitive one. ESR dates using the stable Ti center yield eruption ages of 59 ± 6 ka for the Battleship Rock Member and 53 ± 6 ka for the El Cajete Member while recent ¹⁴C dates (S. Reneau and J. Gardner, unpub. data) from carbonized logs in the El Cajete pumice indicate that its age is older than 50 ka. Our results indicate that volcanism in the Valles caldera is much younger than previously thought (≥ 130 ka) and that recent revisions to the post-0.5 Ma stratigraphy of Valles caldera are probably in error. The results suggest that ESR dating of quartz may be a useful method for obtaining ages of units in other Quaternary volcanic areas.     

The rate of fluvial incision during the Late Quaternary period in the Abukuma Mountains, northeast Japan, deduced from tephrochronology

Abstract River incision into bedrock results in the decrease of burial depths, which can be of critical importance, for example, in the safe long‐term storage of high‐level radioactive waste. For the long‐term prediction of river erosion, it is essential to know the rate of incision during the Late Quaternary period. In the Abukuma Mountains on the forearc side of northeast Japan, a low‐relief peneplain that was uplifted in the Pliocene period is widely developed. Degradational fluvial terraces that are discontinuously distributed along draining rivers are scattered in the study area. The fluvial sediments were mainly transported from the summit regions as debris flows or hyperconcentrated flows. The terrace deposits are capped by a series of eolian veneers containing key tephra beds. From the oldest to the youngest, these tephra beds are the 150–125 ka Iizuna–Kamitaru tephra, the 135–125 ka Hiuchigatake–Tagashira tephra, the 120 ka Adatara–Dake tephra, the 70–80 ka Bandai–Hayama‐2 tephra, the 45 ka Numazawa–Mizunuma tephra and the 42 ka Bandai–Hayama‐1 tephra. Using tephrochronological data, the terraces are divided into three groups: higher, middle and lower. The ages of formation of the higher, middle and lower terraces are estimated to be within marine isotope stage (MIS) 6, MIS 5.4–5.2 and MIS 3 to MIS 2, respectively. The incision rate, calculated from the relative height between the terrace surface and present‐day valley floor fill, is 1.5–0.8 m/10 000 years in the elevations from 350 to 700 m. The calculated rate does not show significant differences between the higher, middle and lower terraces. All the relative heights decrease with increasing elevation, because the erosional rates of streams in the upper reaches are lower than those in downstream reaches where the discharge rates are higher. This value can be regarded as an estimate of the rate of incision in granitic mountains where there is no volcanic or distinct tectonic activity.     

The geochemistry and petrogenesis of the volcanic rocks of Carriacou,Grenadine Islands,West Indies

Carriacou is small volcanic island located near the southern end of the Lesser Antillean chain. Field relationships, petrography and geochemistry of the Tertiary lavas, outcropping in the southern half of the island, are used to identify the rocks present and to determine their petrogenesis and assess their significance within the island arc.Six main volcanic units are present. From oldest to youngest, these are the clinopyroxene-phyric basalt (CPB) sequence, the amphibole-phyric andesite (APA) sequence, the clinopyroxene-megaphyric basalt (CMB) sequence, the olivine-microphyric basalt (OMB) sequence, the clinopyroxene phyric andesite (CPA) sequence, and the amphibole-megaphyric andesite (AMA) sequence. Volcaniclastic deposits are associated with the APA, CMB, and AMA sequences. The APA sequence is calcalkaline, whereas the other five sequences are tholeiitic.Sr isotope and rare earth element (REE) data suggest that these volcanic rocks were derived from partial melts of garnet-peridotite generated deep within the mantle. The OMB lavas have the highest temperature assemblages of intratelluric minerals and the least evolved chemical characteristics, and are considered to be closest in composition to a parental melt. Phenocryst assemblages and chemical variation suggest that the andesite sequences have been derived from the mafic melts by low pressure fractional crystallization of approximately 20% clinopyroxene and 20% olivine, plus smaller amounts of plagioclase and amphibole. The high concentrations of incompatible and compatible elements and the high⁸⁷Sr/⁸⁶Sr ratios may indicate that subduction is slower in the southern part of the arc, and fluids released during slab dehydration rich in Incompatible trace elements, in Radiogenic strontium, and in Silica (IRS), have modified the parental melts.     

GPS-based crustal deformations in Azerbaijan and their influence on seismicity and mud volcanism

Using Shen’s method (Shen et al., 1996), deformations of the Earth’s crust in Azerbaijan were studied based on GPS measurements. For estimating the rate of deformation, we used the field of velocity vectors for Azerbaijan, Iran, Georgia, and Armenia that were derived from GPS measurements during 1998–2012. It is established that compression is observable along the Greater Caucasus, in Gobustan, the Kura depression, Nakhchyvan Autonomous Republic, and adjacent areas of Iran. The axes of compression/contraction of the crust in the Greater Caucasus region are oriented in the S-NE direction. The maximum strain rate (approximately 200 × 10^?9 per annum) is documented in the zone of mud volcanism at the SHIK site (Shykhlar), which is marked by a sharp change in the direction of the compression axes (SW-NE). It is revealed that the deformation field also includes the zones where strain rates are very low approximating 5 × 10^?9 per annum. These zones include the Caspian-Guba and northern Gobustan areas, characterized by extensive development of mud volcanism. The extension zones are confined to the Lesser Caucasus and are revealed in the Gedabek (GEDA) and Shusha (SHOU) areas, as well as in the zone located between the DAMO and PIRM sites (Iran), where the deformation rate amounts to 100 × 10^?9 per annum. It is concluded that the predominant factor responsible for the eruption of mud volcanoes is the intensity of gas-generation processes in the earth’s interior, while deformation processes play the role of a trigger. The zone of the epicenters of strong earthquakes is correlated to the gradient zone in the crustal strain rates.     

Eruptive history and petrologic evolution of the Albano multiple maar (Alban Hills, Central Italy)

A comprehensive volcanological study of the Albano multiple maar (Alban Hills, Italy) using (i) ⁴⁰Ar/³⁹Ar geochronology of the most complete stratigraphic section and other proximal and distal outcrops and (ii) petrographic observations, phase analyses of major and trace elements, and Sr and O isotopic analyses of the pyroclastic deposits shows that volcanic activity at Albano was strongly discontinuous, with a first eruptive cycle at 69±1 ka producing at least two eruptions, and a second cycle with two peaks at 39±1 and 36±1 ka producing at least four eruptions. Contrary to previous studies, we did not find evidence of magmatic or hydromagmatic eruptions younger than 36±1 ka. The activity of Albano was fed by a new batch of primary magma compositionally different from that of the older activity of the Alban Hills; moreover, the REE and ⁸⁷Sr/⁸⁶Sr data indicate that the Albano magma originated from an enriched metasomatized mantle. According to the modeled liquid line of descent, this magma differentiated under the influence of magma/limestone wall rock interaction. Our detailed eruptive and petrologic reconstruction of the Albano Maar evolution substantiates the dormant state of the Alban Hills Volcanic District. Electronic Supplementary Material Supplementary material is available for this article at Editorial responsibility: J. Donnelly-Nolan An erratum to this article can be found at     

The behavior of light lithophile and halogen elements in felsic magma: geochemistry of the post-caldera Valles Rhyolites, Jemez Mountains Volcanic Field, New Mexico

Post-collapse rhyolite lava domes, lava flows and pyroclastic rocks from Valles caldera (1140 ka), erupted from 1133 ka to approximately 520-60 ka, have been sampled to study variations of light lithophile (Li, Be, B) and halogen (F, Cl) elements. Our principal objectives were: (1) to examine the mobility of these elements during post-eruptive devitrification and hydration; and (2) to study their behavior during magma differentiation. Compared to fresh glassy samples, devitrified rocks from the same dome are depleted in B, Li, F and Cl, but not in Be. During devitrification, Be was immobile while the other elements were progressively more mobile in the order B < Li < Cl < F, fluorine being the most mobile element. Considering only fresh glassy samples, Li, Be and B were enriched in residual liquids and behaved incompatibly during differentiation of successive magma batches at 973-787 ka and 557-521 ka. The rhyolites have low B/Be ratios of 2–3 which decrease slightly with increasing Be; these values suggest a small fractionation of B from Be during evolution of the magmas. While F behaves like the light lithophile elements, Cl shows (1) much smaller temporal enrichment during differentiation at 973-787 ka and (2) depletion with time from 557 to 521 ka. At the same time, the Cl/Be ratio declines progressively from ˜250 in the oldest rhyolites to ˜ 100 in the youngest rhyolites. These data suggest that (1) a magmatic fluid phase continuously extracted Cl from fluid-saturated magmas and (2) some of the magmatic Cl lost could have been incorporated into the Valles hydrothermal system.     

Thermal diffusivity of rhyolitic glasses and melts: effects of temperature, crystals and dissolved water

Thermal diffusivity (D) was measured using laser-flash analysis on pristine and remelted obsidian samples from Mono Craters, California. These high-silica rhyolites contain between 0.013 and 1.10?wt% H₂O and 0 to 2?vol% crystallites. At room temperature, D _glass varies from 0.63 to 0.68?mm²?s^?1, with more crystalline samples having higher D. As T increases, D _glass decreases, approaching a constant value of ??0.55?mm²?s^?1 near 700?K. The glass data are fit with a simple model as an exponential function of temperature and a linear function of crystallinity. Dissolved water contents up to 1.1?wt% have no statistically significant effect on the thermal diffusivity of the glass. Upon crossing the glass transition, D decreases rapidly near ??1,000?K for the hydrous melts and ??1,200?K for anhydrous melts. Rhyolitic melts have a D _melt of ??0.51?mm²?s^?1. Thermal conductivity (k?=?D·??·C _P) of rhyolitic glass and melt increases slightly with T because heat capacity (C _P) increases with T more strongly than density (??) and D decrease. The thermal conductivity of rhyolitic melts is ??1.5?W?m^?1?K^?1, and should vary little over the likely range of magmatic temperatures and water contents. These values of D and k are similar to those of major crustal rock types and granitic protoliths at magmatic temperatures, suggesting that changes in thermal properties accompanying partial melting of the crust should be relatively minor. Numerical models of shallow rhyolite intrusions indicate that the key difference in thermal history between bodies that quench to obsidian, and those that crystallize, results from the release of latent heat of crystallization. Latent heat release enables bodies that crystallize to remain at high temperatures for much longer times and cool more slowly than glassy bodies. The time to solidification is similar in both cases, however, because solidification requires cooling through the glass transition in the first case, and cooling only to the solidus in the second.     

The K–Ar Cassignol–Gillot technique applied to western Martinique lavas: A record of Lesser Antilles arc activity from 2 Ma to Mount Pelée volcanism

We present 23 new ages from three volcanic complexes of the Lesser Antilles arc in Martinique Island (French West Indies). These ages obtained with the K–Ar Cassignol–Gillot technique are distributed within the whole Quaternary. They allowed us to reconstruct a detailed history of successive volcanic growth and flank collapse stages. Trois Ilets Volcanism has been active during at least 2 Ma, between 2.35 ± 0.03 Ma and 346 ± 27 ka, with monogenetic volcanoes of basaltic-andesite to andesitic compositions. We here propose that magma mixing, which characterizes this volcanism, could have been initiated between 617 and 346 ka by the activation of arc-parallel and arc-transverse fault systems. Meanwhile, the Carbet complex was active 25 km to the north from 998 ± 14 to 322 ± 6 ka, and was partially destroyed by a flank collapse after 602 ± 10 ka. Together with geochemical data, our ages show that Mount Conil and Mount Pelée volcanoes are parts of the same edifice sharing a single magmatic reservoir. Mount Conil started to emerge before 543 ± 8 ka, and andesites erupted until 127 ± 2 ka, when a flank collapse destroyed the western flank of the edifice, probably triggering the emplacement of Piton Marcel, the last eruption of this first stage. We note that this collapse occurred during the transition from oxygen stages 6 to 5, i.e. during glacial to interglacial change, when eustatic level rapidly increased. After that, and until present, Mount Pelée volcano was built with periods of cone growth intercalated by flank collapse events. We here show that a peak of activity occurred between 550 and 330 ka in western Martinique within the three complexes, which are spaced of 15–25 km. Since 330 ka volcanic activity is limited to the northernmost Mount Conil–Mount Pelée complex. Our data are in agreement with the regional scale observations that the whole recent Lesser Antilles arc was subject to a high volcanic activity since 600 ka, probably linked to an increase in magma production. This permanent establishment of rising magma in regularly spaced batches and tectonically controlled, could explain the individual chemical evolution of each edifice and the different eruptive dynamisms occurring at the same time along the recent arc.     

The eruptive rate and history of Kuju volcano in Japan during the past 15,000 years

The eruptive history of Kuju volcano on Kyushu, Japan, during the past 15,000 years has been determined by tephrochronology and ¹⁴C dating. Kuju volcano comprises isolated lava domes and cones of hornblende andesite together with aprons of pyroclastic-flow deposits on its flanks. Kuju volcano produced tephras at roughly 1000-yr intervals during the past 5000 years and 70% of the domes and cones have formed during the past 15,000 years. The youngest magmatic activity of Kuju volcano was the 1.6 km³ andesite eruption about 1600 years ago which emplaced a lava dome and block-and-ash flow. Kuju volcano shows a nearly constant long-term eruption rate (0.7–0.4 km³ for 1000 years) during the past 15,000 years. This rate is within the range of estimated average eruption rates of late Quaternary volcanoes in the Japanese Arc, but is about one order of magnitude higher than the eruption rate of Unzen volcano. Kuju volcano has been in phreatic eruption since October 1995. The late Quaternary history of Kuju indicates that it poses a significant volcanic hazard, primarily due to block-and-ash flows from collapsing lava domes.     

The space-time relationships between volcanic associations of different alkalinities: The Belogolovskii massif in Kamchatka’s Sredinnyi Range. Part 1. The geology,mineralogy, and petrology of volcanic rocks

We proposed a geological and petrologic model for the generation of the Belogolovskii Late Pliocene to Early Pleistocene volcanic massif. We identified two petrochemical series of rocks with varying alkalinities, viz., normal and moderate. The evolution of volcanic products and the mineralogic composition of rocks of varying alkalinities provide evidence that the sources of parent magmas are spatially independent and reside at different depths. Crystallization differentiation is the leading process that is responsible for the generation of the initial melts that give rise to the range of rocks within a series. The evolution of the alkaline basaltic magma occurred stepwise, producing autonomous daughter melts with the following compositions: trachybasalt-trachyandesite-trachyte-trachyrhyolite and comendite. These melts were localized in inter-mediate magma chambers at different depths.     

Age, geology, geophysics, and geochemistry of Mahukona Volcano, Hawai`i

The size, shape, and magmatic history of the most recently discovered shield volcano in the Hawaiian Islands, Mahukona, have been controversial. Mahukona corresponds to what was thought to be a gap in the paired sequence (Loa and Kea trends) of younger Hawaiian volcanoes (<4?Ma). Here, we present the results of marine expeditions to Mahukona where new bathymetry, sidescan sonar, gravity data, and lava samples were collected to address these controversies. Modeling of bathymetric and gravity data indicate that Mahukona is one of the smallest Hawaiian volcanoes (～6,000?km³) and that its magmatic system was not focused in a long-lived central reservoir like most other Hawaiian volcanoes. This lack of a long-lived magmatic reservoir is reflected by the absence of a central residual gravity high and the random distribution of cones on Mahukona Volcano. Our reconstructed subsidence history for Mahukona suggests it grew to at least ～270?m below sea level but probably did not form an island. New ⁴⁰Ar–³⁹Ar plateau ages range from 350 to 654?ka providing temporal constraints for Mahukona’s post-shield and shield stages of volcanism, which ended prematurely. Mahukona post-shield lavas have high ³He/⁴He ratios (16–21?Ra), which have not been observed in post-shield lavas from other Hawaiian volcanoes. Lava compositions range widely at Mahukona, including Pb isotopic values that straddle the boundary between Kea and Loa sequences of volcanoes. The compositional diversity of Mahukona lavas may be related to its relatively small size (less extensive melting) and the absence of a central magma reservoir where magmas would have been homogenized.     

Effusive history of the Grande Découverte Volcanic Complex, southern Basse-Terre (Guadeloupe, French West Indies) from new K–Ar Cassignol–Gillot ages

The Grande Découverte Volcanic Complex (GDVC), active since at least 0.2 Ma, is the most recent volcanic complex of the Basse-Terre Island (Guadeloupe, Lesser Antilles Arc). A detailed geochronological study using the K–Ar Cassignol–Gillot technique has been undertaken in order to reconstruct the history of effusive activity of this long-lived volcanic system. Twenty new ages permit to suggest that the GDVC experienced at least six main effusive stages, from 200 ka to present time. To the north of the GDVC, the GDS (Grande Découverte–Soufrière volcano) has been active since at least 200 ka, and to the south, the TRMF (Trois-Rivières–Madeleine Field), started to be emplaced 100 ka. Morphological investigations suggest that the whole TRMF volcanism was emitted from vents distinct from the GDS, most probably a large E–W fissure network linked to the Marie-Galante rift. The mean age of 62 ± 5 ka, obtained for the E–W Madeleine–Le Palmiste alignment suggests that a fissure-opening event occurred at that time. However, whole-rock major and trace element signatures are similar for both systems, suggesting that a common complex magma-plumbing system has fed the overall GDVC. We report very young ages for lava flows from the TRMF, which implies that < 10 ka volcanic activity is now identified for both massifs. Although hazards associated with such effusive volcanism are much lower than those associated with potential flank-collapse of the Soufrière lava dome or a magmatic dome eruption with explosive phases within the GDS, the emplacement of relatively large Holocene age lava flows (3–1 × 10⁸ m³) suggests that a revised integrated volcanic hazard assessment for Southern Basse-Terre should now consider the potential for renewed future activity from two Holocene volcanic centers including the TRMF.     

40Ar/39Ar constraints on the temporal evolution of Graciosa Island, Azores (Portugal)

Lava flows spanning the eruptive record of Graciosa Island (Azores archipelago) and a gabbro xenolith were dated by ⁴⁰Ar/³⁹Ar in order to constrain the Pleistocene and Holocene volcanic evolution of the island. The results range from 1.05 Ma to 3.9 ka, whereas prior published K–Ar and ¹⁴C ages range from 620 to 2 ka. The formation of the Serra das Fontes shield volcano started at minimum 1.05 Ma, and the magmatic system was active for ca. 600 ky, as suggested by the formation of the gabbro xenolith by magmatic differentiation. Evolved magmas making up the Serra das Fontes–Serra Branca composite volcano were generated at ca. 450 ka. After a period of ca. 110 ky of volcanic inactivity and erosion of volcanic edifices, volcanism was reactivated with the formation of the Vitória Unit NW platform. Later, the development of the Vulcão Central Unit started with the formation of monogenetic cones located to the south of the Serra das Fontes–Serra Branca–Vitória Unit. This volcanism became progressively more evolved and was concentrated in a main eruptive center, forming the Vulcão Central stratovolcano with an age older than 50 ka. The caldera related to this stratovolcano is older than 47 ka and was followed by effusion of basaltic magmas into the caldera, resulting in the formation of a lava lake, which ultimately spilled over the caldera rim at ca. 11 ka. The most recent eruptions on Graciosa formed two small pyroclastic cones within the caldera and the Pico do Timão cone within the Vitória Unit at ca 3.9 ka.     

A petrologic re-investigation of the Adak volcanic center, central Aleutian arc, Alaska

The Adak volcanic center is located in the central part of the Aleutian arc and consists of three main volcanic vents. Andrew Bay Volcano, the oldest center, has been mostly removed by erosion. The next youngest vent, Mount Adagdak, was built in three major volcanic stages whereas Mount Moffett, the largest volcanic edifice, consists of a main cone and a parasitic cone each with several magmatic phases. Adak is unique compared to other modern Aleutian volcanic centers in that it contains two xenolith suites (Conrad and Kay, 1984; Debari et al., 1987). One suite consisting predominantly of mafic xenoliths occurs on Mount Moffett whereas an assemblage of ultramafic and mafic xenoliths is found on Mount Adagdak. Lavas erupted at Adak span the compositional range from 48.4 to 65.0 wt.% SiO₂ and are characterized by significant variations in Al₂O₃, MgO, Sr, Ni and Cr. On Harker diagrams, this variability produces compositional trends with significant scatter. The Adak suite has total REE contents that vary from 32 to 154 ppm but do not correlate systematically with silica. ( )_n ratios range from 2.41 to 21.72 with the majority of lavas between 2.41 and 6.06. On process identification diagrams, the Adak suite plots as steeply sloping trends that contrast with the horizontal patterns of most other Aleutian centers. Measured isotopic ranges are large and nearly equal to those for the entire arc. Although they span similar silica ranges, subtle geochemical and isotopic differences distinguish the different volcanic vents of Adak. On Mount Moffett, a geochemically and isotopically distinct group of andesites (55.5–57.9 SiO₂), the mafic andesites, occur on its NE flank. These lavas have elevated MgO, Ni and Cr but are depleted in Al₂O₃ relative to other Mount Moffett andesites with similar silica. They also have more heterogeneous REE abundances and isotopic ratios than most of the other andesites. Significant compositional differences exist between Adak and the other volcanic centers of the central Aleutian arc. Although these differences are characteristic of all geochemical systems, they are greatest for major and rare-earth elements and isotopic ratios. The lack of coherent relationships on major- and trace-element Harker diagrams, the isotopic variability, as well as the steeply sloping trends on REE process identification diagrams suggest that the Adak volcanic suite was not formed predominantly by closed-system crystal fractionation, but must be the product of a complex open-system process(es). The significant isotopic variability displayed by the suite suggests that contamination by an isotopically distinct contaminant must also have been an important petrologic component in the evolution of the suite. REE data are also suggestive of a role for magma mixing. Such a complex petrologic evolution is consistent with an immature lithospheric plumbing system. Based on REE systematics, the xenolith suites of Adak cannot, as previously proposed, be related to the host lavas or the rest of the Adak suite through crystal fractionation schemes. Rather they are probably accidental fragments derived from various depths along lithospheric conduits. In light of their relation to xenolith-bearing units, the mafic andesites of Adak presumably represent hybrid magmas formed during the interaction of ascending magmas with lithospheric wall rock. They are, therefore, characteristic of immature volcanic centers and unlikely to be related directly to the magmatic processes responsible for the generation of primary arc magmas. Because of the close proximity of the vents and the subtle compositional differences between their lavas, the Adak volcanic center was probably supplied by a single, deep lithospheric plumbing system that fed separate crustal magma chambers. The absence of historic volcanic activity on Adak suggests this plumbing system was abandoned before complete conduit development. This decline in magmatism may reflect a re-adjustment of volcano spacing within this part of the Aleutian arc.     

Cosmogenic 3He exposure dating of the Quaternary basalts from Fogo,Cape Verdes: Implications for rift zone and magmatic reorganisation

We have used cosmogenic ³He to date pre- and post-collapse lava flows from southwestern Fogo, Cape Verdes, in order to date rift zone magmatic reorganisation following the lateral collapse of the flank of the Monte Amarelo volcano. The post-collapse flows have exposure ages ranging from 62 to 11 ka. The analysis of multiple flow tops on each lava flows, often at different elevations, provides an internal check for age consistency and the exposures ages conform with stratigraphic level. The exposure ages suggest that volcanic activity along the western branch of the triple-armed rift zone was more or less continuous from before 62 ka to approximately 11 ka. The absence of magmatic activity for the last 11 kyr reflects a structural reconfiguration of the volcano and may be related to renewed flank instability. This volcanic hiatus is similar in duration to that observed in the Canary Islands. Replicate ³He exposure ages of a pre-collapse flow (123.0 ± 5.2 ka) brackets the time of the Monte Amarelo collapse between 62 ka and 123 ka. Reproducible cosmogenic ³He exposure ages of less than 123 ka from flows away from major erosion features demonstrates that the technique is a viable alternative to the radiocarbon, K/Ar and ⁴⁰Ar/³⁹Ar chronometers for dating recent volcanism in arid climate zones.     

Preservation of the last aggradation phase in climate-driven terraces: Evidence from Late Quaternary reach-specific fluvial dynamics of the Allier River (France)

There is limited knowledge about the preservation of aggradation phases in Quaternary fluvial records. Previous numerical modelling of erosion and deposition in Late Quaternary Allier River (France) generated the prediction that this river has reach-specific fluvial dynamics related to climate-driven tributary sediment-flux dynamics. To test this prediction, new optically stimulated luminescence (OSL) samples were collected of the Late Quaternary Fx terrace at five locations along a stretch of 60 km. OSL dates of both quartz and feldspar sand grains indicate that all relatively basalt-poor sediments display significantly different ages for each reach (ranging from 36.3 ± 2.0 to 21.1 ± 2.3 ka). The more basalt-rich terrace body consistently yields ages in the range 21.1 ± 1.7 to 16.1 ± 1.5 ka, suggesting contemporaneous aggradation along the whole studied Allier reach during this interval. Our own new OSL date of a Tartaret eruption around 16.8 ± 2.5 ka also fits this time window, suggesting a direct link with volcanic activity. However, there are many more dated volcanic events that coincide with the older basalt-poor units, making it less likely that a direct link between terrace-sediment basalt content and volcanic activity exists. The timings of the dated depositional events in MIS 3 and 2 all match with simulated climate drivers and published landscape erosion rates. Counterintuitively, the volcanic Chaîne des Puys area supplied more sediment during the cold and dry Last Glacial Maximum. Basalt content in the Allier terrace sediments reflects climate-related sediment-flux dynamics upstream. The scarcity of older basalt-poor sediment bodies from MIS 4 and 3 in the Fx terrace suggests that less sediment was supplied and/or the intermittent erosional phases in the Allier were very effective at removing them. We hypothesize that this observation of predominant preservation of the last aggradation phase could be a common phenomenon in most climate-driven terraces. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd