Geochemical evolution of groundwater in southern Bengal Basin: The example of Rajarhat and adjoining areas,West Bengal,India

Detailed geochemical analysis of groundwater beneath 1223 km² area in southern Bengal Basin along with statistical analysis on the chemical data was attempted, to develop a better understanding of the geochemical processes that control the groundwater evolution in the deltaic aquifer of the region. Groundwater is categorized into three types: ‘excellent’, ‘good’ and ‘poor’ and seven hydrochemical facies are assigned to three broad types: ‘fresh’, ‘mixed’ and ‘brackish’ waters. The ‘fresh’ water type dominated with sodium indicates active flushing of the aquifer, whereas chloride-rich ‘brackish’ groundwater represents freshening of modified connate water. The ‘mixed’ type groundwater has possibly evolved due to hydraulic mixing of ‘fresh’ and ‘brackish’ waters. Enrichment of major ions in groundwater is due to weathering of feldspathic and ferro-magnesian minerals by percolating water. The groundwater of Rajarhat New Town (RNT) and adjacent areas in the north and southeast is contaminated with arsenic. Current-pumping may induce more arsenic to flow into the aquifers of RNT and Kolkata cities. Future large-scale pumping of groundwater beneath RNT can modify the hydrological system, which may transport arsenic and low quality water from adjacent aquifers to presently unpolluted aquifer.     

The geochemistry of Boron-rich groundwater of the Karlovassi Basin, Samos Island, Greece

The upper Miocene of Karlovassi Basin, Samos Island, Greece, contain continental evaporites such as colemanite, ulexite, celestite, gypsum and thenardite. These evaporites are related with volcanic tuffs, diagenetically altered in a saline-alkaline lake environment. The aim of the present paper is to: a) define the impact of the already known and possible buried borates and other evaporites to the geochemistry of the hydrogeological system of Karlovassi Basin, and; b) to assess the correlation between surface and underground evaporite deposits considering the spatial changes in the concentrations of the examined physicochemical parameters. Fieldwork, laboratory measurements and literature data revealed elevated boron values (2136–33012 ?/L) in the central part of Karlovassi Basin. In the same area, high amounts of strontium, sodium, lithium and sulfates also occur. It is proposed that these ions originate from the leaching of evaporites and authigenic minerals such as the Sr-rich clinoptilolite and the boron-bearing potassium feldspar. Boron values are abnormally high for freshwater aquifers, and are indicative of the presence of buried evaporites in the basin with unknown significance.     

Arsenic in groundwater of the Bengal Basin, Bangladesh: Distribution, field relations, and hydrogeological setting

Arsenic contaminates groundwater across much of southern, central and eastern Bangladesh. Groundwater from the Holocene alluvium of the Ganges, Brahmaputra and Meghna Rivers locally exceeds 200 times the World Health Organisation (WHO) guideline value for drinking water of 10 µg/l of arsenic. Approximately 25% of wells in Bangladesh exceed the national standard of 50 µg/l, affecting at least 25 million people. Arsenic has entered the groundwater by reductive dissolution of ferric oxyhydroxides, to which arsenic was adsorbed during fluvial transport. Depth profiles of arsenic in pumped groundwater, porewater, and aquifer sediments show consistent trends. Elevated concentrations are associated with fine-sands and organic-rich sediments. Concentrations are low near the water table, rise to a maximum typically 20–40 m below ground, and fall to very low levels between about 100 and 200 m. Arsenic occurs mainly in groundwater of the valley-fill sequence deposited during the Holocene marine transgression. Groundwater from Pleistocene and older aquifers is largely free of arsenic. Arsenic concentrations in many shallow hand-tube wells are likely to increase over a period of years, and regular monitoring will be essential. Aquifers at more than 200 m below the floodplains offer good prospects for long-term arsenic-free water supplies, but may be limited by the threats of saline intrusion and downward leakage of arsenic.

---

Resumen El arsénico ha contaminado gran parte de las aguas subterráneas en el Sur, centro y Este de Bangla Desh. Su concentración en las aguas subterráneas del aluvial Holoceno de los ríos Ganges, Brahmaputra y Meghna supera localmente en un factor 200 el valor guía del arsénico en el agua potable, establecido por la Organización Mundial de la Salud (OMS) en 10 µg/L. Aproximadamente, el 25% de los pozos de Bangla Desh superan el estándar nacional de 50 µg/L, afectando al menos a 25 millones de personas. El arsénico ha llegado a las aguas subterráneas por la disolución reductora de hidróxidos férricos a los que se adsorbe durante el transporte fluvial. Los perfiles del arsénico en las aguas subterráneas bombeadas, agua de poro y sedimentos del acuífero muestran tendencias coherentes. Las concentraciones elevadas están asociadas a arenas finas y sedimentos ricos en materia orgánica. Las concentraciones de arsénico son bajas cerca del nivel freático, se incrementan hasta un máximo que se localiza generalmente a entre 20 y 40 m bajo la cota del terreno, y disminuyen a valores muy pequeños entre alrededor de 100 y 200 m. El arsénico se encuentra sobretodo en las aguas subterráneas existentes en la secuencia de sedimentación que tuvo lugar en el valle durante la transgresión marina del Holoceno. Las aguas subterráneas del Pleistoceno y acuíferos más antiguos están mayoritariamente libres de arsénico. Es probable que las concentraciones de arsénico aumenten en los próximos años en muchos pozos de tipo tubo perforados manualmente, por lo que será esencial efectuar un muestreo regular. Los acuíferos ubicados a más de 200 m bajo las llanuras de inundación ofrecen buenas perspectivas de abastecimiento a largo plazo sin problemas de arsénico, pero pueden estar limitados por las amenazas de la intrusión salina y de la precolación de arsénico desde niveles superiores.

---

Résumé Larsenic contamine les eaux souterraines dans la plus grande partie du sud, du centre et de lest du Bangladesh. Les eaux des nappes alluviales holocènes du Gange, du Brahmapoutre et de la Meghna dépassent localement 200 fois la valeur guide donnée par lOMS pour leau de boisson, fixée à 10 µg/l darsenic. Environ 25% des puits du Bangladesh dépassent la valeur standard nationale de 50 µg/l, affectant au moins 25 millions de personnes. Larsenic a été introduit dans les nappes par la dissolution par réduction doxy-hydroxydes ferriques sur lesquels larsenic était adsorbé au cours du transport fluvial. Des profils verticaux darsenic dans leau souterraine pompée, dans leau porale et dans les sédiments des aquifères montrent des tendances convergentes. Les concentrations élevées sont associées à des sédiments à sable fin et riches en matières organiques. Les concentrations sont faibles au voisinage de la surface de la nappe, atteignent un maximum typiquement entre 20 et 40 m sous le sol, puis tombent à des niveaux très bas entre 100 et 200 m. Larsenic est surtout présent dans les eaux souterraines de la séquence de remplissage de vallée déposée au cours de la transgression marine holocène. Les eaux souterraines des aquifères pléistocènes et plus anciens sont très largement dépourvus darsenic. Les concentrations en arsenic dans de nombreux puits creusés à la main doivent probablement augmenter au cours des prochaines années ; aussi un suivi régulier est essentiel. Les aquifères à plus de 200 m sous les plaines alluviales offrent de bonnes perspectives pour des alimentations en eau sans arsenic à long terme, mais ils peuvent être limités par les risques dintrusion saline et la drainance descendante de larsenic.

     

Hydrogeology of the Kabul Basin (Afghanistan), part II: groundwater geochemistry

Shallow groundwater is the main source for drinking water in Kabul, Afghanistan. It comes from a multitude of shallow hand-pumped wells spread over the whole city area. The groundwater is characterised by slightly oxic redox conditions. Interactions with aquifer carbonates lead to near-neutral pH and high degrees of hardness. The mostly negative water budget of the Kabul Basin is the result of strong evaporation which leads to an increase in salt and also of some undesirable constituents, e.g. borate. Several years of drought have aggravated this problem. The shallow groundwater in the city has received tremendous amounts of pollution due to a lack of proper waste disposal and sewage treatment. Common indicators are elevated concentrations of nutrients such as nitrate and faecal bacteria. The high infant mortality can at least partially be attributed to the insufficient water hygiene. Acid generated during the mineralisation of the wastewater is hidden due to the strong pH buffering capacity of the groundwater system. Redox and pH conditions preclude significant mobilisation of trace metals and metalloids.     

Suboxic trace metal geochemistry in the Eastern Tropical North Pacific

We analyzed Al, Ti, Fe, Mn, Cu, Ba, Cd, U, Mo, V, and Re in water column, settling particulate, and sediment (0 to 22 cm) samples from the intense oxygen minimum zone (OMZ) of the eastern tropical North Pacific near Mazatlán, Mexico. The goal was to determine how the geochemistry of these elements was influenced by suboxic water column conditions and whether the sediments have a unique “suboxic” geochemical signature.The water column was characterized by a Mn maximum, reaching ∼8 nmol kg⁻¹ at 400 m. Concentrations of Cu, Ba, Cd, Mo, Re, U, and V were unaffected by the low O₂ conditions and were comparable to those of the open ocean. Sinking particles were composed of lithogenic particles of detrital origin and nonlithogenic particles of biogenic origin. Al, Ti, and Fe were mostly (at least 79%) lithogenic. About 75% of the Mn was nonlithogenic. Significant amounts (at least 58%) of Cu, Ba, Cd, and Mo were nonlithogenic.Sediment geochemistry varied across the continental shelf and slope. Cadmium, U, and Re have prominent maxima centered at 310 m, with 12.3 ppm, 10.9 ppm, and 68.3 ppb, respectively, at the core top. High values of Mo (averaging 6.8 ppm) and V (averaging 90 ppm) are seen in OMZ surface sediment. Additional down-core enrichment occurs for all redox-sensitive elements in the top 10 cm. For U, Mo, V, and Re, surface sediments are a poor indicator of metal enrichment. Comparison of the nonlithogenic composition of sediments with sinking particles suggests that direct input of plankton material enriched in metals makes a significant contribution to the total composition, especially for Cd, U, and Mo.We evaluated Re/Mo and Cd/U ratios as tracers for redox environments. Rhenium and Mo concentrations and Re/Mo ratios do not lead to consistent conclusions. Concurrent enrichments of Re and Mo are an indicator of an anoxic depositional environment. In contrast, high Re/Mo ratios are an indicator of suboxic conditions. Cadmium is enriched in surface sediments, while U has considerable down-core enrichment. The concentrations of Cd and U and the Cd/U ratio do not follow patterns predicted from thermodynamics. Though the water column is suboxic, these four redox-sensitive elements indicate that the sediments are anoxic. The implication for paleostudies is that a trace metal sediment signature that indicates anoxic conditions is not necessarily attributable to an anoxic water column.     

Soil geochemistry and groundwater contamination in an arsenic-affected area of the Datong Basin,China

This study describes the geochemistry of the topsoils from an arsenic (As)-affected area of the Datong Basin and identifies the possible sources and the enrichment mechanisms of As in groundwater. A total of 122 soil samples were collected from the study area. Analytical results indicate that soil As is higher than the average value of the Shanxi province topsoils. Fertilizer application and weathering of the bedrock both contributed to the presence of elements, including As, in the soil of the area. Furthermore, these elements may be strongly bound to Fe and Mn oxides/hydroxides. In addition, the depletion of K indicates that this element is readily leached into the groundwater rather than being retained in the soils. A groundwater area with high As levels corresponding spatially to soil samples with no As accumulation clearly shows the effects of irrigation or salt flushing on the soil compositions. Arsenic can be mobilized under reducing condition due to organic matter input or changes in redox conditions induced by irrigation or salt flushing and can be transported with vertically recharged water into shallow, unconfined aquifers, thus elevating the As concentration in groundwater.     

Controls on groundwater flow in the Bengal Basin of India and Bangladesh: regional modeling analysis

Groundwater for domestic and irrigation purposes is produced primarily from shallow parts of the Bengal Basin aquifer system (India and Bangladesh), which contains high concentrations of dissolved arsenic (exceeding worldwide drinking water standards), though deeper groundwater is generally low in arsenic. An essential first step for determining sustainable management of the deep groundwater resource is identification of hydrogeologic controls on flow and quantification of basin-scale groundwater flow patterns. Results from groundwater modeling, in which the Bengal Basin aquifer system is represented as a single aquifer with higher horizontal than vertical hydraulic conductivity, indicate that this anisotropy is the primary hydrogeologic control on the natural flowpath lengths. Despite extremely low hydraulic gradients due to minimal topographic relief, anisotropy implies large-scale (tens to hundreds of kilometers) flow at depth. Other hydrogeologic factors, including lateral and vertical changes in hydraulic conductivity, have minor effects on overall flow patterns. However, because natural hydraulic gradients are low, the impact of pumping on groundwater flow is overwhelming; modeling indicates that pumping has substantially changed the shallow groundwater budget and flowpaths from predevelopment conditions.     

Estimation of regional-scale groundwater flow properties in the Bengal Basin of India and Bangladesh

Quantitative evaluation of management strategies for long-term supply of safe groundwater for drinking from the Bengal Basin aquifer (India and Bangladesh) requires estimation of the large-scale hydrogeologic properties that control flow. The Basin consists of a stratified, heterogeneous sequence of sediments with aquitards that may separate aquifers locally, but evidence does not support existence of regional confining units. Considered at a large scale, the Basin may be aptly described as a single aquifer with higher horizontal than vertical hydraulic conductivity. Though data are sparse, estimation of regional-scale aquifer properties is possible from three existing data types: hydraulic heads, ¹⁴C concentrations, and driller logs. Estimation is carried out with inverse groundwater modeling using measured heads, by model calibration using estimated water ages based on ¹⁴C, and by statistical analysis of driller logs. Similar estimates of hydraulic conductivities result from all three data types; a resulting typical value of vertical anisotropy (ratio of horizontal to vertical conductivity) is 10⁴. The vertical anisotropy estimate is supported by simulation of flow through geostatistical fields consistent with driller log data. The high estimated value of vertical anisotropy in hydraulic conductivity indicates that even disconnected aquitards, if numerous, can strongly control the equivalent hydraulic parameters of an aquifer system.     

Effect of mining on geochemistry of groundwater in Permo-carboniferous Gondwana coalfields: Raniganj Basin, India

Lack of proper reclamation strategy and indiscriminate mining of various economic resources, particularly coal from Permo-carboniferous Gondwana coalfields affects the groundwater quality of the concerned regions. Leaching from mine-tailings along with seasonal fluctuation of water table caused a significant change in groundwater geochemistry of Raniganj coalfield area. Gondwana sequences, developed in intracratonic rift basin, are characterized by numerous longitudinal and cross faults. This results in the formation of many small aquifer systems which may be interconnected laterally as well as vertically providing the conduit for homogenization of aquifers. Although the predominance of major cations (Ca>Na>Mg>K) and anions (HCO₃>Cl>SO₄>NO₃) remain same irrespective of season, the dominance of Na and SO₄ have significantly increased in post-monsoon season. The types of groundwater in pre-monsoon and postmonsoon seasons are CaMgCl and CaHCO₃ respectively. Leaching of SO₄ from surface sources (mine tailings) has increased TDS in post-monsoon. Base exchange (direct and reverse) reactions have taken place between aquifer materials and groundwater.     

Mechanism of arsenic release to groundwater,Bangladesh and West Bengal

In some areas of Bangladesh and West Bengal, concentrations of As in groundwater exceed guide concentrations, set internationally and nationally at 10 to 50 μg l⁻¹ and may reach levels in the mg l⁻¹ range. The As derives from reductive dissolution of Fe oxyhydroxide and release of its sorbed As. The Fe oxyhydroxide exists in the aquifer as dispersed phases, such as coatings on sedimentary grains. Recalculated to pure FeOOH, As concentrations in this phase reach 517 ppm. Reduction of the Fe is driven by microbial metabolism of sedimentary organic matter, which is present in concentrations as high as 6% C. Arsenic released by oxidation of pyrite, as water levels are drawn down and air enters the aquifer, contributes negligibly to the problem of As pollution. Identification of the mechanism of As release to groundwater helps to provide a framework to guide the placement of new water wells so that they will have acceptable concentrations of As.     

Deeper groundwater chemistry and geochemical modeling of the arsenic affected western Bengal basin,West Bengal,India

A regional scale hydrogeochemical study of a ∼21,000-km² area in the western Bengal basin shows the presence of hydrochemically distinct water bodies in the main semiconfined aquifer and deeper isolated aquifers. Spatial trends of solutes and geochemical modeling indicate that carbonate dissolution, silicate weathering, and cation exchange control the major-ion chemistry of groundwater and river water. The main aquifer water has also evolved by mixing with seawater from the Bay of Bengal and connate water. The isolated aquifers contain diagenetically altered water of probable marine origin. The postoxic main aquifer water exhibits overlapping redox zones (metal-reducing, sulfidic and methanogenic), indicative of partial redox equilibrium, with the possibility of oxidation in micro-scale environments. The redox processes are depth-dependent and hydrostratigraphically variable. Elevated dissolved As in the groundwater is possibly related to Fe(III) reduction, but is strongly influenced by coupled Fe–S–C redox cycles. Arsenic does not show good correlations with most solutes, suggesting involvement of multiple processes in As mobilization. The main river in the area, the Bhagirathi–Hoogly, is chemically distinctive from other streams in the vicinity and probably has little or no influence on deep groundwater chemistry. Arsenic in water of smaller streams (Jalangi and Ichamati) is probably introduced by groundwater discharge during the dry season.     

The geochemistry of trace elements in geothermal fluids,Iceland

Trace element geochemistry was studied in geothermal fluids in Iceland. The major and trace element compositions of hot springs, sub-boiling, and two-phase (liquid and vapor) wells from 10 geothermal areas were used to reconstruct the fluid composition in the aquifers at depth. Aquifer fluid temperatures ranged from 4 to 300 °C, pH values between 4.5 and 9.3, and fluids typically contained total dissolved solids <1000 ppm, except in geothermal areas that have seawater and seawater-meteoric water mixtures. Trace alkali elements Li, Rb and Cs are among the most mobile elements in aquifer fluids, with concentrations in the range of <1 ppb to 3.49 ppm Li, <0.01 to 57 ppb Cs, and <1 ppb to 3.77 ppm Rb. Their chemistry is thought to be dominated by rock leaching and partitioning into Na- and K-containing major alteration minerals. Arsenic, Sb, Mo and W are typically present in concentrations in the range of 1–100 ppb. They are relatively mobile, yet Mo may be limited by molybdenite solubility. The alkaline earth elements Ba and Sr are quite immobile with concentrations in the range of <0.1–10 ppb Ba and <1–100 ppb Sr in the dilute fluids, but up to 5.9 ppm Ba and 8.2 ppm Sr in saline fluids. These elements show a systematic relationship with Ca, possibly due to substitution for Ca in Ca-containing major alteration minerals like calcite, epidote and anhydrite. Incorporation into major Ca-minerals may also be important for Mn. Many metals including Fe, Cr, Ni, Zn, Cu, Co, Pb and Ag have low mobility and concentrations, typically <1 ppb for Ag, Cd, Co, Cr, Cu, Ni, and Pb, <10 ppb for Zn and < 100 ppb for Fe, although for some metals higher concentrations are associated with saline fluids. Based on the metals assessed, saturation is approached with respect to many sulfide minerals and in some cases oxide minerals but Cu, Ni and Pb minerals are slightly but systematically undersaturated, and Ag phases significantly undersaturated. Evaluation of mineral-fluid equilibria for these metals is problematic due to their low concentrations, problems associated with assessing the aqueous species distribution by thermodynamic calculations, and uncertainties concerning the exact minerals possibly involved in such reactions. Reaction path calculations, poor comparison of concentrations measured in the samples collected at the wellhead and published downhole data as well as boiling, cooling and mass precipitation calculations suggest removal of many metals due to changes upon depressurization boiling and conductive cooling of the aquifer fluids as they ascend in wells. These results imply that processes such as mass precipitation upon fluid ascent may be highly important and emphasize the importance of considering mass movement in geothermal systems.     

Regional hydrostratigraphy and groundwater flow modeling in the arsenic-affected areas of the western Bengal basin, West Bengal, India

The first documented interpretation of the regional-scale hydrostratigraphy and groundwater flow is presented for a ～21,000-km² area of the arsenic-affected districts of West Bengal [Murshidabad, Nadia, North 24 Parganas and South 24 Parganas (including Calcutta)], India. A hydrostratigraphic model demonstrates the presence of a continuous, semi-confined sand aquifer underlain by a thick clay aquitard. The aquifer thickens toward the east and south. In the south, discontinuous clay layers locally divide the near-surface aquifer into several deeper, laterally connected, confined aquifers. Eight 22-layer model scenarios of regional groundwater flow were developed based on the observed topography, seasonal conditions, and inferred hydrostratigraphy. The models suggest the existence of seasonally variable, regional, north–south flow across the basin prior to the onset of extensive pumping in the 1970s. Pumping has severely distorted the flow pattern, inducing high vertical hydraulic gradients across wide cones of depression. Pumping has also increased total recharge (including irrigational return flow), inflow from rivers, and sea water intrusion. Consequently, downward flow of arsenic contaminated shallow groundwater appears to have resulted in contamination of previously safe aquifers by a combination of mechanical mixing and changes in chemical equilibrium.     

Characterization and appraisal of facets influencing geochemistry of groundwater in the Kulpawn sub-basin of the White Volta Basin, Ghana

Groundwater composition in the Kulpawn basin is largely controlled by aluminosilicates dissolution and cation exchange resulting in mainly Ca-Mg-HCO₃ and NaHCO₃ water types. Principal component analysis, Piper graphical classification, and stable isotope (¹⁸O and ²H) of groundwater and surface-water samples were used to delineate geochemical processes and groundwater facies. The groundwater is mildly acid to neutral and low in conductivity. Chemical constituents except HCO₃ ⁻ and SiO₂ have low concentration. No cation shows clear majority, however, the order of relative abundance is Na⁺ > Ca²⁺ > Mg²⁺ > K⁺. HCO₃ ⁻ is the predominant anion and the order of abundance is HCO₃ ⁻ > NO₃ ⁻ > SO₄ ²⁻ > Cl⁻. SiO₂ concentration is high compared with the major cations. Dissolution of plagioclase, pyroxene and biotite and cation exchange are responsible for groundwater composition. Isotopic data suggest integrative, smooth and rapid recharge from meteoric origin. The groundwater quality is generally good for domestic usage; however, 18 and 47% of boreholes respectively have NO₃ ⁻ and F⁻ levels outside WHO recommended limits suggesting potential physiological problems in some localities. The groundwater has low sodium absorption ratio and low to moderate salinity hazard but significant magnesium hazard partially limiting its use for irrigation.     

Geochemistry of groundwater,Burdwan District,West Bengal,India

Hydrogeochemical investigations are carried out in the different blocks of Burdwan district, West Bengal, India in order to assess its suitability for drinking as well as irrigation water purpose. Altogether 49 representative groundwater samples are collected from bore wells and the water chemistry of various ions viz. Ca²⁺, Mg²⁺, Na⁺, K⁺, CO₃²⁻, HCO₃⁻, Cl⁻, SO₄²⁻ and NO₃⁻ are carried out. The chemical relationships in Piper and Gibbs diagram suggest that the groundwater mainly belongs to alkali type and Cl⁻ group and are controlled by rock dominance. A comparison of groundwater quality in relation to drinking water quality standards proves that most of the water samples are suitable for drinking water purpose whereas groundwater in some areas of the district has high salinity and high sodium adsorption ratio (SAR), indicating unsuitability for irrigation water and needs adequate drainage.     

Weathering of the zinc-lead lode, Dugald River, northwest Queensland: II. surface mineralogy and geochemistry

Gossans associated with the Dugald River zinc-lead lode contain anomalous concentrations of Zn, Pb, Ag, As, Cd, Cu, Sb, Se, Tl and Ba and differ from those on the more pyritic Western Lode (Zn, Pb, Cu, As, Tl) and those associated with copper mineralization in the hanging wall (As, Bi, Co, Cu, Mo, Ni, Sb). Mineralogical and geochemical variations in gossans along strike reflect changes in primary ore and gangue mineralogy, particularly towards the north, where the Dugald River lode and hanging wall copper mineralization merge. Leaching of more soluble elements from the surface and re-precipitation below have resulted in large geochemical variations in the top metre of the profile.Dispersion into wall rocks has occurred over two distinct periods: hydromorphic dispersion, before erosion removed much of the gossan and surrounding Corella Formation, has resulted in very high Zn contents (up to 9%) in the footwall, whereas a more even dispersion of target and pathfinder elements into hanging and footwall rocks is from recent weathering of the slightly elevated gossan.     

西北天山吐拉苏盆地火山岩SHRIMP年代学和微量元素地球化学研究

吐拉苏盆地位于西北天山西段,盆地中大面积出露晚古生代火山—沉积岩地层,该地层的火山—沉积岩是区内阿希、京希—伊尔曼德金矿的主要赋矿围岩,由凝灰岩、流纹岩、安山岩和少量玄武岩组成。对火山岩剖面下部流纹岩中锆石开展的SHRIMP年代学研究表明,火山喷发开始的时间早于386Ma(中泥盆世晚期)。因此,下石炭统地层单位“大哈拉军山组”不再适合代表吐拉苏盆地中广泛出露的这套火山—沉积岩地层,本文建议创建中-上泥盆统“伊尔曼德组”。京希—伊尔曼德金矿区及其外围火山熔岩富集大离子亲石元素和轻稀土元素,亏损Nb、Ta、Zr和Hf等高场强元素,具有典型大陆岛弧火山岩的地球化学特征。因此,吐拉苏盆地晚古生代火山岩代表北天山洋洋壳向伊犁板块俯冲过程中形成的火山岛弧,该岛弧的演化至少持续到晚泥盆世晚期(~363Ma)。受俯冲带流体交代的地幔楔是吐拉苏岛弧火山岩(玄武岩和安山岩)的岩浆源区,大量流纹岩应该是大陆地壳物质熔融的产物。     

Salinization of groundwater in the North German Basin: results from conjoint investigation of major, trace element and multi-isotope distribution

Conjoint consideration of distribution of major, rare earth elements (REE) and Y (combined to REY) and of H, O, C, S, Sr isotopes reveals that four types of groundwater are distinguishable by their chemical composition presented by spider patterns. REY patterns indicate thermo-saline deep water and two types of shallow saline groundwaters. Presence of connate waters is not detectable. Sr isotope ratios distinguish three sources of Sr: fast and slow weathering of biotite and K-feldspar in Pleistocene sediments, respectively, and dissolution of limestones. δ¹³C(DIC) indicate dissolution of limestone under closed and open system conditions. Numerous samples show δ¹³C(DIC) > 13‰ which is probably caused by incongruent dissolution of calcite and dolomite. The brines from below 1,000 m represent mixtures of pre-Pleistocene seawater or its evaporation brines and infiltrated post-Pleistocene precipitation. The shallow waters represent mixtures of Pleistocene and Recent precipitation salinized by dissolution of evaporites or by mixing with ascending brines. The distribution of water types is independent on geologic units and lithologies. Even the Tertiary Rupelian aquiclude does not prevent salinization of the upper aquifer.     

Study of subsurface geology in locating arsenic-free groundwater in Bengal delta,West Bengal,India

Over a large area of the Bengal delta in West Bengal, India, arsenic distribution patterns in groundwater were studied. One hundred and ten boreholes at different target locations were made, subsurface sediments were logged and analysed, and arsenic values in sediments vis-à-vis groundwater were compared. The study elucidates the subsurface geology of the western part of Bengal delta and characterises the sediments that were intersected in different boreholes with contrasting values of arsenic in groundwater. It reveals an existence of multiple aquifers stacked over each other. Depending on the color and nature of aquifer-sands and their overlying clay beds six aquifer types (Type-1 to Type-6) are classified and described. Sediment-arsenic for all the varieties of aquifer sands are near similar but the groundwater-arsenic of these six aquifers varies widely. Type-2 and Type-5 aquifers host arsenic-contaminated groundwater whereas the other four aquifers are arsenic-free. Type-2 and Type-5 aquifers are capped by a grey to dark grey soft organic matter-rich clay unit which makes these aquifers semi-confined to leaky-confined. These contribute in releasing arsenic from the sediments. The results of this study are employed in a proposed georemedial measure against this hazardous toxic element.