Speleothems in a north Cuban cave register sea‐level changes and Pleistocene uplift rates

A flight of marine terraces along the Cuban coast records Quaternary sea‐level highstands and a general slowly uplifting trend during the Pleistocene. U/Th dating of these limestone terraces is difficult because fossil reef corals have been affected by open system conditions. Terrace ages are thus often based on geological and geomorphological observations. In contrast, the minimum age of the terraces can be constrained by dating speleothems from coastal mixing (flank margin) caves formed during past sea‐level highstands and carving the marine limestones. Speleothems in Santa Catalina Cave have ages >360 ka and show various cycles of subaerial–subaqueous corrosion and speleothem growth. This suggests that the cave was carved during the MIS 11 sea‐level highstand or earlier. Some stalagmites grew during MIS 11 through MIS 8 and were submerged twice, once at the end of MIS 11 and then during MIS 9. Phreatic overgrowths (POS) covering the speleothems suggest anchialine conditions in the cave during MIS 5e. Their altitude at 16 m above present sea level indicates a late Pleistocene uplift rate of <0.1 mm/ka, but modelling also shows uplift to have been insignificant over a long timespan during the middle Pleistocene since the cave was carved. Our study shows that some flank margin caves in the region of Matanzas are older than commonly believed (i.e. MIS 11 rather than MIS 5). These caves not only can be preserved but are good markers of interglacial sea‐level highstands, more reliable than marine abrasion surfaces. Copyright © 2018 John Wiley & Sons, Ltd.     

New evidence of sea‐level lowstands and paleoenvironment during MIS 6 and 4 in the Cantabrian coastal karst: the Cobiheru cave (North Iberia)

The geomorphological evolution of the Cobiheru Cave shows the influence of the non‐carbonate coastal mountain ranges on coastal karst evolution, as well as the temporal distribution of the cold‐adapted fauna sites in the Cantabrian Coast. Geomorphological observation and uranium/thorium (U/Th) dating lead to the construction of an evolution model. The model comprises two episodes of cave deposition occurring at c. 60–70 and 130–150 ka, linked to cold climate conditions, global sea‐level lowstands and the erosion of alluvial fans that covered the karst. Moreover, the comparison between the Cobiheru record and some raised beaches identified in previous studies sets the beginning of the sea‐level lowering in the Cantabrian Sea during the marine isotope stages (MIS) 5–4 transition. Two palaeoenvironments are inferred based on finding Equus ferus and Elona quimperiana. A wet deciduous forest would have developed on the emerged marine terrace of the Cobiheru Cave since at least the Middle Pleistocene, and an open landscape with scarce vegetation would have been present at c. 65 ka. The erosional event identified in the Cobiheru Cave helps to understand the temporal distribution of cold‐adapted mammals located in the Asturias region. The probable sites of cold‐adapted fauna developed in caves and alluvial fans would have disappeared after 65 ka. Therefore, palaeontological and palaeoclimate research based on cold‐adapted mammals suggests the occurrence of an hiatus in the palaeontological record prior to 50 ka. Copyright © 2017 John Wiley & Sons, Ltd.     

Modern stable isotopic (δ18O, δ2H, δ13C) variation in terrestrial,fluvial, estuarine and marine waters from north‐central Sarawak,Malaysian Borneo

Stable isotope data on humid tropical hydrology are scarce and, at present, no such data exist for Borneo. Delta¹⁸O, δ²H and δ¹³C were analysed on 22 water samples from different parts of the Sungai (river) Niah basin (rain, cave drip, rainforest pool, tributary stream, river, estuary, sea) in north‐central Sarawak, Malaysian Borneo. This was done to improve understanding of the modern stable isotope systematics of the Sungai Niah basin, essential for the palaeoenvironmental interpretation of the Late Quaternary stable isotope proxies preserved in the Great Cave of Niah. The Niah hydrology data are put into a regional context using the meteoric water line for Southeast Asia, as derived from International Atomic Energy Agency/World Meteorological Organization isotopes in precipitation network data. Although the Niah hydrological data‐set is relatively small, spatial isotopic variability was found for the different subenvironments of the Sungai Niah basin. A progressive enrichment occurs towards the South China Sea (δ¹⁸O ?4·6‰; δ²H ?29·3‰; δ¹³C ?4·8‰) from the tributary stream (δ¹⁸O ?8·4‰; δ²H ?54·7‰; δ¹³C ?14·5‰) to up‐river (δ¹⁸O c. ?8‰; δ²H c. ?51‰; δ¹³C c. ?12‰) and down‐river values (δ¹⁸O c. ?7·5‰; δ²H c. ?45‰; δ¹³C c. ?11‰). This is thought to reflect differential evaporation and mixing of different components of the water cycle and a combination of depleted biogenic δ¹³C (plant respiration and decay) with enriched δ¹³C values (due to photosynthesis, atmospheric exchange, mixing with limestone and marine waters) downstream. Cave drip waters are relatively enriched in δ¹³C as compared to the surface waters. This may indicate rapid degassing of the cave drips as they enter the cave atmosphere. Copyright © 2005 John Wiley & Sons, Ltd.     

Formation of phreatic caves in an eogenetic karst aquifer by CO2 enrichment at lower water tables and subsequent flooding by sea level rise

Formation of extensive phreatic caves in eogenetic karst aquifers is widely believed to require mixing of fresh and saltwater. Extensive phreatic caves also occur, however, in eogenetic karst aquifers where fresh and saltwater do not mix, for example in the upper Floridan aquifer. These caves are thought to have formed in their modern settings by dissolution from sinking streams or by convergence of groundwater flow paths on springs. Alternatively, these caves have been hypothesized to have formed at lower water tables during sea level low‐stands. These hypotheses have not previously been tested against one another. Analyzing morphological data and water chemistry from caves in the Suwannee River Basin in north‐central Florida and water chemistry from wells in the central Florida carbonate platform indicates that phreatic caves within the Suwannee River Basin most likely formed at lower water tables during lower sea levels. Consideration of the hydrological and geochemical constraints posed by the upper Floridan aquifer leads to the conclusion that cave formation was most likely driven by dissolution of vadose CO₂ gas into the groundwater. Sea level rise and a wetter climate during the mid‐Holocene lifted the water table above the elevation of the caves and placed the caves tens of meters below the modern water table. When rising water tables reached the land surface, surface streams formed. Incision of surface streams breached the pre‐existing caves to form modern springs, which provide access to the phreatic caves. Phreatic caves in the Suwannee River Basin are thus relict and have no causal relationship with modern surficial drainage systems. Neither mixing dissolution nor sinking streams are necessary to form laterally extensive phreatic caves in eogenetic karst aquifers. Dissolution at water tables, potentially driven by vadose CO₂ gas, offers an underappreciated mechanism to form cavernous porosity in eogenetic carbonate rocks. Copyright © 2012 John Wiley & Sons, Ltd.     

Multi‐method (14C, 36Cl, 234U/230Th) age bracketing of the Tschirgant rock avalanche (Eastern Alps): implications for absolute dating of catastrophic mass‐wasting

Correct and precise age determination of prehistorical catastrophic rock‐slope failures prerequisites any hypotheses relating this type of mass wasting to past climatic regimes or palaeo‐seismic records. Despite good exposure, easy accessibility and a long tradition of absolute dating, the age of the 230 million m³ carbonate‐lithic Tschirgant rock avalanche event of the Eastern Alps (Austria) still is relatively poorly constrained. We herein review the age of mass‐wasting based on a total of 17 absolute ages produced with three different methods (¹⁴C, ³⁶Cl, ²³⁴U/²³⁰Th). Chlorine‐36 (³⁶Cl) cosmogenic surface exposure dating of five boulders of the rock avalanche deposit indicates a mean event age of 3.06 ± 0.62 ka. Uranium‐234/thorium‐230 (²³⁴U/²³⁰Th) dating of soda‐straw stalactites formed in microcaves beneath boulders indicate mean precipitation ages of three individual soda straws at 3.20 ± 0.26 ka, 3.04 ± 0.10 ka and 2.81 ± 0.15 ka; notwithstanding potential internal errors, these ages provide an ‘older‐than’ (ante quam) proxy for mass‐wasting. Based on radiocarbon ages (nine sites) only, it was previously suggested that the present rock avalanche deposit represents two successive failures (3.75 ± 0.19 ka bp , 3.15 ± 0.19 ka bp ). There is, however, no evidence for two events neither in surface outcrops nor in LiDAR derived imagery and drill logs. The temporal distribution of all absolute ages (¹⁴C, ³⁶Cl, ²³⁴U/²³⁰Th) also does not necessarily indicate two successive events but suggest that a single catastrophic mass‐wasting took place between 3.4 and 2.4 ka bp . Taking into account the maximum age boundary given by reinterpreted radiocarbon datings and the minimum U/Th‐ages of calcite precipitations within the rock avalanche deposits, a most probable event age of 3.01 ± 0.10 ka bp can be proposed. Our results underscore the difficulty to accurately date catastrophic rock slope failures, but also the potential to increase the accuracy of age determination by combining methods. Copyright © 2016 John Wiley & Sons, Ltd.     

Paleoflood events recorded by speleothems in caves

Speleothems are usually composed of thin layers of calcite (or aragonite). However, cemented detrital materials interlayered between laminae of speleothemic carbonate have been also observed in many caves. Flowstones comprising discontinuous carbonate layers form due to flowing water films, while flood events introduce fluviokarstic sediments in caves that, on occasion, are recorded as clayey layers inside flowstones and stalagmites. This record provides a potential means of understanding the frequency of palaeofloods using cave records. In this work, we investigate the origin of this type of detrital deposit in El Soplao Cave (Northern Spain). The age of the lowest aragonite layer of a flowstone reveals that the earliest flood period occurred before 500 ka, though most of the flowstone formed between 422 +69/‐43 ka and 400 +66/‐42 ka. This suggests that the cave was periodically affected by palaeoflood events that introduced detrital sediments from the surface as a result of occasional extreme rainfall events, especially at around 400 ka. The mineralogical data enable an evolutionary model for this flowstone to be generated based on the alternation of flood events with laminar flows and carbonate layers precipitation that can be extrapolated to other caves in which detrital sediments inside speleothems have been found. Copyright © 2014 John Wiley & Sons, Ltd.     

U–Th dating of carbonate nodules from methane seeps off Joetsu, Eastern Margin of Japan Sea

We performed U–Th radioactive disequilibrium analyses of carbonate nodules and sediment samples recovered from methane seep sites off Joetsu, of the eastern margin of Japan Sea, to decipher the active period of the methane seep. The carbonates contain ²³⁰Th, part of which is located in detritus such as silicate and organics, at the time of precipitation. The initial ²³⁰Th renders accurate dating with U–Th radioactive disequilibrium method difficult. We assessed the feasibility of correction using radioactive disequilibrium data of ambient sediment to overcome this difficulty. A (²³⁰Th/²³²Th)–(²³⁴U/²³²Th) isochron drawn by three chips divided from a carbonate nodule (PC05-04-50) passed through data points of local sediments. We conclude that the problem of initial ²³⁰Th can be resolved by measurements of local sediments. Results show that carbonate nodules include local sediment as impurities. Furthermore, the results of trace element analyses such as Rb, Zr, Nb, REE, Pb, and Th also support the idea.In all, 18 carbonate samples were dated with correction of initial ²³⁰Th using the mean value of local sediment in this study. The U–Th correction ages show 12–35ka with an isochron age of 26 ± 3ka. Results indicate that during the time interval of U–Th ages, from 12ka to 35ka, environmental conditions must have been favorable for enhanced methane flux through sediment. The extensive methane flow period at 20ka accords with the lowest-stand sea level during the last glacial age. Results of this study also suggest that U–Th ages of carbonate are useful as a reliable chronometer with regard to methane seep activation. In order to acquire U–Th ages of carbonate at methane seep sites, however, it is important to evaluate the amount of initial ²³⁰Th accurately using the value of sediment.     

From subsurface to surface: a multidisciplinary approach to decoding uplift histories in tectonically-active karst landscapes

We present an integrated study of subsurface and surficial karst landforms to unravel the uplift history of karst landscape in a tectonically-active area. To this end, we apply a multidisciplinary approach by combining cave geomorphology and Th/U dating of speleothems with remote sensing plus geophysical imaging of surface landforms. We use as an example Mt. Menikio in northern Greece where four caves share well-defined epiphreatic/shallow phreatic characteristics that are related to the distribution of surface and buried doline fields and provide evidence for three distinct water table stillstands (e.g. expressed as cave levels) now lying at ~130 m, ~800 m and ~1600 m a.m.s.l. Our dating constraints delimit the age of the lower water table stillstand prior to 77 ka ago and imply a maximum rate of relative base level drop of 0.45 mma^-1, which is consistent with relative tectonic uplift rate estimates along currently active normal faults. We interpret the elevation of the higher water table stillstands to reflect earlier phases of uplift related to the regional tectonic events associated with the development of the North Anatolian Fault and the Northern Aegean area. Our analysis shows that the combined study of epiphreatic/shallow phreatic caves and surficial karst landforms together, is a robust way to investigate the uplift history of a karst landscape in a tectonically-active setting. © 2019 John Wiley & Sons, Ltd.     

Isotopic composition (δ18O and δD) of precipitation and groundwater in a semi‐arid,mountainous area (Guadiana Menor basin,Southeast Spain)

We characterize the precipitation and groundwater in a mountainous (peaks slightly above 3000 m a.s.l.), semi‐arid river basin in SE Spain in terms of the isotopes ¹⁸O and ²H. This basin, with an extension of about 7000 km², is an ideal site for such a study because fronts from the Atlantic and the Mediterranean converge here. Much of the land is farmed and irrigated both by groundwater and runoff water collected in reservoirs. A total of approximately 100 water samples from precipitation and 300 from groundwater have been analysed. To sample precipitation we set up a network of 39 stations at different altitudes (800–1700 m a.s.l.), with which we were able to collect the rain and snowfall from 29 separate events between July 2005 and April 2007 and take monthly samples during the periods of maximum recharge of the aquifers. To characterize the groundwater we set up a control network of 43 points (23 springs and 20 wells) to sample every 3 months the main aquifers and both the thermal and non‐thermal groundwater. We also sampled two shallow‐water sites (a reservoir and a river). The isotope composition of the precipitation forms a local meteoric water line (LMWL) characterized by the equation δD = 7·72δ¹⁸O + 9·90, with mean values for δ¹⁸O and δD of − 10·28‰ and − 69·33‰, respectively, and 12·9‰ for the d‐excess value. To correlate the isotope composition of the rainfall water with groundwater we calculated the weighted local meteoric water line (WLMWL), characterized by the equation δD = 7·40δ¹⁸O + 7·24, which takes into account the quantity of water precipitated during each event. These values of (dδD/dδ¹⁸O)< 8 and d‐excess (δD–8δ¹⁸O)< 10 in each curve bear witness to the ‘amount effect’, an effect which is more manifest between May and September, when the ground temperature is higher. Other effects noted in the basin were those of altitude and the continental influence. The isotopic compositions of the groundwater are represented by the equation δD = 4·79δ¹⁸O − 18·64. The groundwater is richer in heavy isotopes than the rainfall, with mean values of − 8·48‰ for δ¹⁸O and − 59·27‰ for δD. The isotope enrichment processes detected include a higher rate of evaporation from detrital aquifers than from carbonate ones, the effects of recharging aquifers from irrigation return flow and/or from reservoirs' leakage and enrichment in δ¹⁸O from thermal water. Copyright © 2010 John Wiley & Sons, Ltd.     

Overexploitation and continuous drought effects on groundwater yield and marine intrusion: considerations arising from the modelling of Mamora coastal aquifer,Morocco

This paper studies the effect of drought and pumping discharge on groundwater supplies and marine intrusion. The investigation concerns the Mamora coastal aquifer, northwest of Morocco. A large‐scale groundwater model was established to model (a) the amount of freshwater discharge towards the ocean and the sea water volumes flowing inland as a consequence of the inverse hydraulic gradient, (b) the impact of drought and pumping discharge on the water table level and, as a consequence, on marine water intrusion. In fact, the simulated submarine groundwater discharge (SGWD) would decrease from 864 m³/d/km in 1987 to 425 m³/d/km in 2000. The simulated volumes of sea water intruding the aquifer as a result of inverse hydraulic gradient would increase from 0·25 Mm³/y in 1987 to 0·3 Mm³/y in 2000. As a consequence of a negative rainfall gradient of −5 mm/y, the simulated SGWD would decline to 9 m³/d/km and the sea water intrusion (SWI) would increase to 0·35 Mm³/y since the year 2010. Due to insufficient data on the trend of pumping discharge, a hypothetical increase of this latter from 38·3 Mm³/y to 53·2 Mm³/y is simulated to induce an increase of marine water intrusion from 0·25 Mm³/y to 0·9 Mm³/y. Consequently, to optimally exploit this seemingly fragile coastal aquifer, a plan of future actions to implement is proposed. Copyright © 2005 John Wiley & Sons, Ltd.     

Tectonic uplift,sea level changes and Plio‐Pleistocene evolution of a coastal karst system: the Mount Saint Paul (Palawan,Philippines)

The St. Paul karst (Palawan, Philippines) is a tropical coastal karst, consisting of towers, cones, huge depressions and large caves. This area hosts the Puerto Princesa Subterranean River (PPSR, 24 km long), whose main entrance is a large spring along the coast and which is one of the largest cave complexes in eastern Asia. A geomorphological study performed by several field surveys and a morphometric analysis of the digital terrain model (DTM) and 3D cave models, allowed formulation of a first evolutionary framework of the karst system. The DTM was extracted from maps and aerial photographs in order to find different generations of ‘relict’ landforms, through the morphometric analysis of topographic surface and karst landforms. Several features suggest a long and multi‐stage evolution of the karst, whose age ranges from Pliocene to present. The southern and northern sectors of the area differ in their altimetric distribution of caves. In the southern sector, some large caves lie between 300 and 400 m asl and were part of an ancient system that developed at the base level of a past river network. In the northern sector, some mainly vadose caves occur, with a phreatic level at 120–130 m asl. An important phase of base‐level cave development is well documented in the inactive passages of PPSR at 50–80 m asl. Morphological features, such as horizontal solution passages and terraced deposits, suggest a phase of stillstand of the base level, which is recorded in the topography as low‐relief surfaces at 40–50 m asl. The age of this phase is probably Early Pleistocene, on the basis of assumed uplift rates. The more recent caves are still active, being located at the current sea level, but they show more than one cycle of flooding and dewatering (with calcite deposition). In the PPSR, several morphologic features, such as two main water level notches at +12·4 and +7·7 m asl and terraced alluvial deposits, suggest that the lower and active level passed through more than two high‐stands of sea level and so it could have formed throughout most of the Middle‐Late Pleistocene. Copyright © 2010 John Wiley & Sons, Ltd.     

Complex exposure histories of chert clasts in the late Pleistocene shorelines of Lake Lisan,southern Israel

Activities of ²⁶Al and ¹⁰Be in five chert clasts sampled from two beach ridges of late Pleistocene Lake Lisan, precursor of the Dead Sea in southern Israel, indicate low rates of chert bedrock erosion and complex exposure, burial, and by inference, transport histories. The chert clasts were derived from the Senonian Mishash Formation, a chert‐bearing chalk, which is widely exposed in the Nahal Zin drainage basin, the drainage system that supplied most of the material to the beach ridges. Simple exposure ages, assuming only exposure at the beach ridge sampling sites, range from 35 to 354 ky; using the ratio ²⁶Al/¹⁰Be, total clast histories range from 0·46 to 4·3 My, unrelated to the clasts' current position and exposure period on the late Pleistocene beach ridges, 160–177 m below sea level. Optically stimulated luminescence dating of fine sediments from the same and nearby beach ridges yielded ages of 20·0 ± 1·4 ka and 36·1 ± 3·3 ka. These ages are supported by the degree of soil development on the beach ridges and correspond well with previously determined ages of Lake Lisan, which suggest that the lake reached its highest stand around 27 000 cal. years BP . If the clasts were exposed only once and than buried beyond the range of significant cosmogenic nuclide production, then the minimum initial exposure and the total burial times before delivery to the beach ridge are in the ranges 50–1300 ky and 390–3130 ky respectively. Alternatively, the initial cosmogenic dosing could have occurred during steady erosion of the source bedrock. Back calculating such rates of rock erosion suggests values between 0·4 and 12 m My^?1. The relatively long burial periods indicate extended sediment storage as colluvium on slopes and/or as alluvial deposits in river terraces. Some clasts may have been stored for long periods in abandoned Pliocene and early Pleistocene routes of Nahal Zin to the Mediterranean before being transported again back into the Nahal Zin drainage system and washed on to the shores of Lake Lisan during the late Pleistocene. Copyright © 2003 John Wiley & Sons, Ltd.     

Multi‐phase evolution of gnammas (weathering pits) in a Holocene deglacial granite landscape,Minnesota (USA)

The morphometry of 85 gnammas (weathering pits) from Big Stone County in western Minnesota allows the assessment of the relative ages of the gnamma population. The ratio between maximum and minimum depths is independent of the initial size of the cavity and only depends on the weathering evolution. Therefore, the distribution of depth ratios can be used to assess the gnamma population age and the history of weathering. The asymmetrical distribution of depth ratios measured in Big Stone County forms three distinct populations. When these sets are analyzed independently, the correlation (r²) between maximum and minimum depths is greater than 0·95. Each single population has a normal distribution of depth ratios and the average depth ratios (δ‐value) for each population are δ₁ = 1·60 ± 0·05, δ₂ = 2·09 ± 0·04 and δ₃ = 2·42 ± 0·08. The initiation of gnamma formation followed the exhumation of the granite in the region. This granite was till and saprolite covered upon retreat of the ice from the Last Glacial Maximum. Nearby outcrops are striated, but the study site remained buried until it was exhumed by paleofloods issuing from a proglacial lake. These Holocene‐aged gnammas in western Minnesota were compared with gnammas of other ages from around the world. Our new results are in accordance with the hypothesis that δ‐values represent the evolution of gnammas with time under temperate‐ to cold‐climate dynamics. Phases of the formation of new gnammas may result from changes in weathering processes related to climate changes. Copyright © 2007 John Wiley & Sons, Ltd.     

Dating of Late Pleistocene terrace deposits of the River Rhine using Uranium series and luminescence methods: Potential and limitations

Uranium-series dating of pedogenic carbonate crusts from fluvial gravels is tested using Optically Stimulated Luminescence (OSL) ages as references. OSL dating yielded ages of 30–15 ka and 13–11 ka, which correlate with the cold periods of the Last Glacial Maximum and the Younger Dryas. These ages are internally coherent and consistent with the geological background and are thus regarded as reliable. Most of the U/Th results scatter widely in the ²³⁰Th/²³²Th vs. ²³⁴U/²³²Th isochron diagram, making regression unrealistic. Semiquantitative age estimates from the data were found to be mostly older than the OSL ages and the geological context. It is suggested that a heterogeneous initial ²³⁰Th input, not relatable to a detrital component, is responsible for the observed discrepancies. This input may be due to bacterial activities and Th transport on organic colloids. It appears necessary to avoid samples where bacteria could have contributed to carbonate precipitation. Further, the relative importance of this problem decreases with sample age, so that U/Th dating of sinters is expected to be more reliable in the >100 ka age range.     

Geochemistry of meteoric diagenesis in carbonate islands of the northern Bahamas: 2. Geochemical modelling and budgeting of diagenesis

Geochemical characterization and numerical modelling of surface water and ground water, combined with hydrological observations, provide quantitative estimates of meteoric diagenesis in Pleistocene carbonates of the northern Bahamas. Meteoric waters equilibrate with aragonite, but water‐ rather than mineral‐controlled reactions dominate. Dissolutional lowering of the undifferentiated bedrock surface is an order of magnitude slower than that within soil‐filled topographic hollows, generating small‐scale relief at a rate of 65–140 mm ka^?1 and a distinctive pocketed topography. Oxidation of organic matter within the subsoil and vadose zones generates an average P of 4·0 × 10^?3 atm, which drives dissolution during vadose percolation and/or at the water table. However, these dissolution processes together account for <60% of the average rock‐derived calcium in groundwaters pumped from the freshwater lens. The additional calcium may derive from oxidation of organic carbon within the lens, accounting for the high P of the lens waters. Mixing between meteoric waters of differing chemistry is diagenetically insignificant, but evapotranspiration from the shallow water table is an important drive for subsurface cementation. Porosity generation in the shallow vadose zone averages 1·6–3·2% ka^?1. Phreatic meteoric diagenesis is focused near the water table, where dissolution generates porosity at 1·4–2·8% ka^?1. Maximum dissolution rates, however, are similar to those of evaporation‐driven precipitation, which occludes porosity of 4·0 ± 0·6% ka^?1. This drives porosity inversion, from primary interparticle to secondary mouldic, vug and channel porosity. In the deeper freshwater lens, oxidation of residual organic carbon and reoxidation of reduced sulphur species from deeper anaerobic oxidation of organic carbon may generate porosity up to 0·06% ka^?1. Meteoric diagenesis relies critically on hydrological routing and vadose thickness (controlled by sea level), as well as the geochemical processes active. A thin vadose zone permits direct evaporation from the water table and drives precipitation of meteoric phreatic cements even where mineral stabilization is complete. Copyright © 2007 John Wiley & Sons, Ltd.     

Carbonate eolianites,quartz sands,and Quaternary sea-level cycles,Western Australia: A chronostratigraphic approach

Marine and eolian carbonate deposits, grouped under the name “Tamala Limestone”, have been investigated along thousands of kilometers of coastal Western Australia (WA). Relative-age diagenetic features of carbonate sand dunes or “eolianites” indicate that coastal ridges decrease in age seaward, reflecting coastal accretion during successive sea-level stands. Yellow- to red-stained quartz sands are associated with eolianites as pits, lenses, extensive beds, and even 40-m-high dunes.A regional survey using whole-rock and land snail amino acid epimerization geochronology confirms the eolianite succession and provides a means of correlating widespread deposits along a steep climatic gradient and 16° of latitude. AMS ¹⁴C and uranium–thorium (U/Th) ages provide independent radiometric calibration of the amino acid ratios, and eolianite ages can be estimated using a parabolic kinetic model.Over 90% of the sampled eolianite deposits comprise Aminozones A, C, E (125 ka), F?, G, and H, and correlate with interglacials from <10 ka (Holocene) to ca. 500 ka. In contrast, at the type locality of the Tamala Limestone along the Zuytdorp Cliffs, the upper eolianite-paleosol units are characterized by advanced stages of cavernous weathering, pedogenesis, and recrystallization. In the same units, sediment and snail samples generally yield very low or non-detectable levels of amino acids. These factors along with the stratigraphic complexity of the deposits reflect an age much greater than a large majority of sites along the WA coastline. These findings encourage a revision of the existing classification and nomenclature of Quaternary carbonate deposits in WA, as well as a reexamination of the underlying mechanisms related to the formation and emplacement of both carbonate and quartz dunes.     

Testing a new combined (U,Th)–He and U/Th dating approach on Plio-Pleistocene calcite speleothems

The geochronology of cave deposits in the Cradle of Humankind UNESCO World Heritage Site in South Africa provides a timeframe essential for the interpretation of its fossils. The uranium-lead (U–Pb) and uranium-thorium disequilibrium (U/Th) dating of speleothems, mostly flowstones that underlie and blanket the fossil-bearing sediments, have been effective in this sense, but U–Pb is limited by the requirement of ∼1 ppm U concentrations and low common Pb contents, and U/Th has a c. 500 ka limit of applicability. Here we report age results for calcite-aragonite speleothems obtained using a new combined uranium-thorium-helium ((U,Th)–He) and U/Th dating routine. We reproduced within analytical uncertainty, the published U–Pb or U/Th ages for (a) flowstone in three drill core samples in the range 2000–3000 ka, (b) a flowstone hand sample taken at surface with an age of 1800 ka, and (c) five underground flowstone samples in the range 100–800 ka. Calcite retentivity for He under cave conditions is thus demonstrated. In the few cases where helium loss was observed in speleothems, only some of the subsamples were affected, and to varying degrees, suggesting loss by lattice damage not related to diagenetic processes, rather than volume diffusion. In the 100 to 800 ka range, the combined U/Th disequilibrium and (U,Th)–He method also yielded reliable values for initial (²³⁰Th/²³⁸U) and (²³⁴U/²³⁸U) activity ratios. Importantly, most subsamples had high initial (²³⁰Th/²³⁸U) values, ranging from 1.0 to 19.7, although having low Th/U ratios. This is probably due to incorporation of Fe–Mn oxides-hydroxides dust, on which ²³⁰Th was previously adsorbed. Such samples are mostly not dateable by U/Th without the additional input from the He analysis. If not detected and corrected for, such high initial (²³⁰Th/²³⁸U) values can lead to inaccurate U/Th and U–Pb ages. Our study shows that the incorporation of He analysis in U/Th dating has broad potential application, with four methods for calculating the ages, in carbonates from different environments where U-Pb or U/Th dating would not work.     

Benthic foraminifera and bottom water evolution in the middle-southern Okinawa Trough during the last 18 ka

Changes of the deep-water circulation and chemicalcompositions in related water masses in the oceanshave played a significant role in the evolution of theglobal climate system[1].Many studies have shownthat the characteristics of the deep-water during theglaciations were distinctly different from that of to-day[2,3].In the northern Pacific,Duplessy et al.[4]foundthat the ventilation of the deep-water(at water depthbetween700―2600m)during the last glaciation wasstronger than that of today,and …     

ENSO related decadal scale climate variability from the Indo-Pacific Warm Pool

The El Niño–Southern Oscillation (ENSO) is a climatic phenomenon that affects socio-economical welfare in vast areas in the world. A continuous record of Holocene ENSO related climate variability of the Indo-Pacific Warm pool (IPWP) is constructed on the basis of stable oxygen isotopes in shells of planktic foraminifera from a sediment core in the western Pacific Ocean. At the centennial scale, variations in the stable oxygen isotope signal (δ¹⁸O) are thought be a representation of ENSO variability, although an imprint of local conditions cannot be entirely excluded. The record for the early Holocene (10.3–6 ka BP) shows, in comparison with the mid- to late Holocene, small amplitude variations in the δ¹⁸O record of up to 0.3‰ indicating relatively stable and warm sea surface conditions. The mid- to late Holocene (6–2 ka BP) exemplified higher variability in δ¹⁸O and thus in oceanic IPWP conditions. Climatically, we interpret this change (5.5–4.2 ka BP) as a phenomenon induced by variability in frequency and/or intensity changes of El Niño. In the period 4.2–2 ka BP we identified several periods, centred on 1.9, 2.1, 2.7, 3.3, 3.7 and 4.2 ka BP, with in general heavy δ¹⁸O values. During these periods, the IPWP was relocated to a more eastward position, enhancing the susceptibility for El Niño-like conditions at the core site. Over the last 2000 yr precipitation increased in the area as a response to an increase in Asian monsoon strength, resulting in a freshening of the surface waters. This study corroborates previous findings that the present-day ENSO activity started around 5.5 ka BP.     

Hydrogeological and hydrogeochemical control of groundwater salinity in an arid inland basin: Dunhuang Basin,northwestern China

High groundwater salinity has become a major concern in the arid alluvial plain of the Dunhuang Basin in northwestern China because it poses a significant challenge to water resource management. Isotopic and geochemical analyses were conducted on 55 water samples from springs, boreholes and surface water to identify potential sources of groundwater salinity and analyse the processes that control increasing salinity. The total dissolved solid (TDS) content in the groundwater ranged from 400 to 41 000 mg/l, and high TDS values were commonly associated with shallow water tables and flow‐through and discharge zones in unconfined aquifers. Various groundwater contributions from rainwater, agricultural irrigation, river water infiltration and lateral inflows from mountains were identified by major ions and δD and δ¹⁸O. In general, HCO₃^? and SO₄^2? were the dominant anions in groundwater with a salinity of <2500 mg/l, whereas Cl^? and SO₄^2? were the dominant anions in groundwater with a salinity of >2500 mg/l. The major ion concentrations indicated that mineral weathering, including carbonate and evaporite dissolution, primarily affected groundwater salinity in recharge areas. Evapotranspiration controlled the major ion concentration evolution and salinity distribution in the unconfined groundwaters in the flow‐through and discharge areas, although it had a limited effect on groundwater in the recharge areas and confined aquifers. Agricultural irrigation increased the water table and enhanced evapotranspiration in the oasis areas of the basin. TDS and Cl became more concentrated, but H and O isotopes were not enriched in the irrigation district, indicating that transpiration dominated the increasing salinity. For other places in the basin, as indicated by TDS, Cl, δD and δ¹⁸O characteristics, evaporation, transpiration and water–rock interactions dominated at different hydrogeological zones, depending on the plant coverage and hydrogeological conditions. Groundwater ages of ³H, and δD and δ¹⁸O compositions and distributions suggest that most of the groundwaters in Dunhuang Basin have a paleometeoric origin and experienced a long residence time. These results can contribute to groundwater management and future water allocation programmes in the Dunhuang Basin. Copyright © 2015 John Wiley & Sons, Ltd.