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1.
Continuous measurements of speciated atmospheric mercury(Hg), including gaseous elemental mercury(GEM), particulate mercury(PHg), and reactive gaseous mercury(RGM) were conducted in Guizhou Province, southwestern China. Guiyang Power Plant(GPP),Guiyang Wujiang Cement Plant, Guizhou Aluminum Plant(GAP), and Guiyang Forest Park(GFP) in Guiyang were selected as study sites. Automatic Atmospheric Mercury Speciation Analyzers(Tekran 2537A) were used for GEM analysis. PHg and RGM were simultaneously collected by a manual sampling system, including elutriator, coupler/impactor, KCl-coated annular denuder, and a ?lter holder.Results show that different emission sources dominate different species of Hg. The highest average GEM value was 22.2 ± 28.3 ngám~(-3)and the lowest 6.1 ± 3.9 ngám~(-3),from samples collected at GPP and GAP, respectively. The maximum average PHg was 1984.9 pgám~(-3)and the minimum average 55.9 pgám~(-3), also from GPP and GAP,respectively. Similarly, the highest average RGM of 68.8pgám~(-3)was measured at GPP, and the lowest level of20.5 pgám~(-3)was found at GAP. We conclude that coal combustion sources are still playing a key role in GEM;traf?c contributes signi?cantly to PHg; and domestic pollution dominates RGM.  相似文献   

2.
3.
Selected volatile organic compounds (VOCs) emitted from commercial activities and industrial processes have been classified as hazardous air pollutants, posing a potential health risk in the urban environment. In this respect, perchloroethylene (PCE), a suspected human carcinogen, is the most noticeable compound because it is widely used in laundries and hotels as a dry‐cleaning solvent. The objective of this paper was to quantify the emissions of PCE and other petroleum‐based solvents from dry cleaning business in illustration of the regulatory infrastructure of reducing PCE exposure in the environment of Taiwan. Based on the Emission Factors (AP‐42) method, the emissions of the non‐methane hydrocarbons (NMHCs) from dry cleaning business had decreased from 5100 metric tons in 1997 to 2800 metric tons in 2007. The success of significant reduction of NMHCs in Taiwan has been ascribed to the fact that Taiwan established the relevant regulations at the end of the 1990s. From the data on the industrial/commercial demand for PCE and the emission inventories of NMHCs from dry cleaning business, the reduction of PCE emissions will show a declining trend in the near future.  相似文献   

4.
Based on the results of multipurpose regional geochemical surveys of the Guizhou Province, geochemical characteristics of soil Se and Se-rich land resources in the central area of Guiyang City were studied and evaluated.Major conclusions are as follows:(1) the Se content in surface soil of the central area of Guiyang City was 0.17–2.89 mg kg~(-1), and the average was 0.78 mg kg~(-1), which were respectively 2.6 and 3.9 times of the national background value of soil and the world background value of soil.The Se content in deep soil was 0.11–1.48 mg kg~(-1), and the average was 0.44 mg kg~(-1), which were respectively 1.5 and2.2 times of the national background value of soil and the world background value of soil. The soil Se content decreased with the increase in the soil depth on the vertical profile, and the surface soil had a higher Se content.(2)Distribution of Se content was mainly affected by parent material, physicochemical properties of soil and other components, soil type, and land use type. Parent material played a key role, as the soil Se content was mainly originated from parent rock and increased with the background value of Se in parent rock, physicochemical properties of soil and other components had certain influences upon the Se content. Se was shown to have a significant linear positive correlation with S and organic carbon but no significant correlation with p H value. Se content varied with different types of soil as follows: skeleton soil yellow soil paddy soil limestone soil purple soil. Land use type also hadcertain influences upon the soil Se content as follows: dry land construction land garden plot grassland =garden plot forest land.(3) Taking 0.4 mg kg~(-1)B x(Se) 3.0 mg kg~(-1) as the standard for Se-rich soil, Se-rich soil of the study area covered an area of 2224 km~2 and 92.5% of the total area; the remaining is general soil. The study area had no Se-excess soil. Therefore, the central area of Guiyang City has a high proportion of Se-rich land, a large area of Serich land resources, and a moderate selenium enrichment strength, which have been rarely seen anywhere and provide advantageous resources for the development of Se-rich featured agriculture.  相似文献   

5.
This study investigated the distribution of six pollutant elements(Cr, Cu, Pb, Zn, Cd, and As), and their relationship to soil organic carbon(SOC) in five soil profiles in the Puding area. Results show SOC content decreased exponentially to the depth of soil profiles; the vertical distribution patterns of SOC in soil profiles were partially controlled by land use. The concentrations of these pollutant elements in most soils were lower than background values, indicating that the local soil was less likely to be contaminated by foreign inputs. Geo-accumulation index values of these elements in most soil samples were less than 1, suggesting that the soil of this area may not be polluted. The concentrations of Cr, Cu, As, and Zn in soils from all land use types were significantly negatively correlated with SOC contents. Geochemical approaches confirmed that the soil of this area was less influenced by pollutant elements.  相似文献   

6.
Long-term atmospheric water vapour hydrogen (δ2H), oxygen (δ18O) and deuterium excess (d-excess) can provide unique insights into the land-atmosphere coupling processes. The in-situ measurements of atmospheric water vapour δ2H, δ18O and d-excess were conducted above a reed wetland of Liaodong Bay (2019–2020). We found significant inter-annual variations in atmospheric water vapour isotopes between the two growing (May–September) seasons. The δ2H, δ18O and d-excess of atmospheric water vapour exhibited different seasonal and diurnal cycles concerning the vertical measurement heights, especially in 2019. The isotopic differences of atmospheric water vapour among vertical measurement heights were more evident in the daytime. Rainfall events directly impacted the diurnal patterns of water vapour isotopes, and the influences depended on rainfall intensities. However, only weak correlations existed between water vapour isotopes and local meteorological factors (R2 = 0.01–0.16, p < 0.001), such as water vapour concentration (w), Relative Humidity (RH) and surface air temperature (Ta). Based on the back-air trajectory analyses, the spatial–temporal dynamics of atmospheric water vapour isotopes are highly synchronized with monsoon activities. Different water vapour sources influence the water vapour isotope in this region and the higher d-excess value is related to the intense convection brought by the monsoon. High-resolution measurements of atmospheric water vapour isotopes will improve our understanding of the hydrological cycles in coastal areas.  相似文献   

7.
The objective of the present study is the assessment of Jeddah ambient air quality in terms of PM2.5, and the associated lead 7 years after phasing out leaded gasoline in Saudi Arabia. Twenty‐four air samples were collected at four locations throughout Jeddah during the period from December 23, 2008 to April 6, 2009. The collected PM2.5‐samples were analyzed by ICP‐MS for determination of lead. The average atmospheric PM2.5 concentration was 50.8 µg/m3. Atmospheric PM2.5‐concentrations were higher than the 24‐h U.S. National Ambient Air Quality Standards (NAAQS) in 14 sample events. The average lead concentration for all samples was 0.07326 µg/m3. Atmospheric lead concentration was dependent on the sampling location. Concentrations at the two southern locations were higher than at the two northern locations. Southern locations had higher lead concentrations due to very high traffic density, in addition to their proximity to industrial zone. In general, the results of this study show a considerable decrease in atmospheric lead concentration 7 years after phasing out leaded gasoline. The study recommends further studies to accurately determine the current sources of atmospheric lead.  相似文献   

8.
The Krusné hory (Erzgebirge or Ore Mountains) has been heavily affected by high atmospheric pollutant deposition caused by fossil fuel combustion in an adjacent Tertiary coal basin. Long‐term routine sampling of bulk precipitation (1977–1996) and stream water (1977–1998) in a forested area on the south‐eastern slope of the mountains were used to evaluate trends and patterns in solute concentration and flux with respect to controlling processes. From 1977 to 1996, the annual volume‐weighted Ca2+ and SOconcentrations decreased in bulk precipitation. However, after 1989, when a pronounced and continuous decrease occurred in coal production, annual volume‐weighted concentrations decreased for most solutes, except H+. The concentration decreases were marked, with 1996 levels at or below 50% of those in 1989. The lack of a trend in H+ is attributed to similar decreases in both acid anions and neutralizing base cations. Stream water concentrations of most solutes, i.e. H+, Ca2+, Mg2+, SONOwere highest at the onset of sampling in 1977, decreased markedly from 1977 to 1983 and decreased more gradually from 1983 to 1998. The spruce forest die‐back and removal reduced dry deposition of these solutes by reducing the filtering action, which was provided by the forest canopy. A notable decrease in stream water Ca2+ concentrations occurred after 1995 and may be due to the depletion of Ca2+, which was provided by catchment liming in 1986, 1988 and 1989. Solute flux trends in bulk atmospheric deposition and stream water generally were not significant and the lack of trend is attributed to the large interannual variability in precipitation quantity and runoff, respectively. All solutes except Na+ varied seasonally. The average seasonal concentrations varied between the solutes, but for most solutes were highest in winter and spring and lowest in summer, correlating with the seasonal trend in runoff. For Ca2+, Mg2+ and SOthe concentration minimum occurs in September and the maximum occurs in February or March, correlating with the seasonal baseflow. These solutes are primarily controlled by the contribution of soil water and groundwater to stream flow. During snowmelt, the meltwater generally causes concentrations to decrease as soil water and groundwater are diluted. For NO3 , average minimum concentrations occur in August at the end of the growing season concurrent with the lowest stream flow, and the maximum occurs in February and March with high stream flow during snowmelt. Seasonal stream water NOconcentration variations are large compared with the long‐term decrease. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

9.
137Cs质量平衡法测算青海湖现代沉积速率的尝试   总被引:4,自引:0,他引:4  
张信宝  曾奕  龙翼 《湖泊科学》2009,21(6):827-833
本文是~(137)Cs质量平衡法测算青海湖现代沉积速率的尝试.青海湖和其他低沉积速率湖泊沉积物剖面中,深度数cm处的~(137)Cs蓄积峰,也可能是沉降到底泥表面的~(137)Cs尘埃,以扩散和迁移的方式向下入渗形成.因此,将沉积剖面中的~(137)Cs蓄积峰解释为1963年的沉积,并据此计算沉积速率,未必合理.青海湖湖滨草地测得的2005年~(137)Cs本底值为1 17.7mBq/cm~2.湖泊中部海心山到东南部渔场一线的6个孔的~(137)Cs面积活度介于92.9-325.0mBq/cm~2,其中青海湖东南部两个孔的~(137)Cs面积活度较高,分别为本底值的155%和270%;湖泊中部4个孔的~(137)Cs面积活度略高于或低于本底值.显然,湖泊东南部有明显沉积发生,特别是位于江西沟冲积扇前缘水下部分的QHH02孔,沉积强烈,水深也最小;湖泊中部沉积轻微.根据表层底泥样品的~(137)Cs浓度,入湖河流泥沙的~(137)Cs浓度和流域内草地表层土壤~(137)Cs浓度的分析,初步确定C=30mBq/g,为1963年以来青海湖沉积泥沙的平均~(137)Cs浓度.利用~(137)Cs质量平衡模型求得的湖泊中部的平均沉积速率为0.020cm/a,和根据布哈河输沙模数求算出的青海湖平均沉积速率0.018cm/a吻合,远低于已报导的断代法测定的青海湖沉积速率.湖泊东南部的沉积速率大于湖泊中部,QHH02孔的沉积速率高达0.229cm/a,是已报导的青海湖沉积速率的两倍.  相似文献   

10.
Based on the well water level data in Majiagou Mine in Tangshan City since 2000, it is suggested that the water level rise from 2008-2014 is possibly associated with reduced infiltration caused by less precipitation, together with the effect of less groundwater exploitation. However, the water level rise from 1992-1998 cannot be interpreted properly if we extend the data source back to 1991. After comparing the data with long-term water level data of five wells with different hydro-geological units in Tangshan and Qinhuangdao, the study indicates that the long-term water level variation cannot be only attributed to the effect of less precipitation and the control of groundwater exploitation, but also with the influence of regional stress field change. With the support of regional geological and tectonic information, combined with the comprehensive analysis of CBM data obtained from the coal field, new understandings of the dynamic characteristics of annual variation are obtained.  相似文献   

11.

南海地区岩石圈资料稀少,阻碍了其形成演化过程的研究.为此,本次研究结合大地热流、空间重力异常、高程、大地水准面和地震数据,在南海西南次海盆反演了两条2.5维岩石圈剖面.本次计算基于三种假设:岩石圈地幔的密度取决于岩石温度;研究区岩石圈处于热稳定状态;研究区处于重力均衡状态.在剖面A-E中,岩石圈底界面从珠江口盆地的105 km迅速抬升到西沙海槽处的50 km,在西沙海槽、西沙-中沙群岛和西南次海盆变化不大,为50~60 km.在剖面F-I中,岩石圈底界面从西沙群岛-中建地块处的88 km向海盆逐渐抬升,在西南次海盆处为46~50 km,到郑和隆起再逐渐变深至64 km.我们比较了西南次海盆岩石圈的冷却模型和热稳定模型,根据冷却模型由水深和热流数据所推断的西南次海盆年龄比实际年龄差很多,说明冷却模型不适用于西南次海盆.通过对比剖面A-E和剖面F-I,说明了剖面A-E经历了更长时间的拉伸,证明南海西南次海盆在形成演化过程中是从北东向南西逐步打开的渐进式扩张.最后,我们综合分析西南次海盆及其大陆边缘的岩石圈结构、减薄陆壳区范围、碳酸盐台地的分布、下地壳韧性流动、流变结构和沉积层特征等多方面资料,认为西南次海盆在形成演化过程中岩石圈地幔首先破裂而地壳后破裂,属于type Ⅱ型非火山型大陆边缘.

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12.
The annual changes of sediment deposition-scour on the riverbed in the Sanhuhekou-Toudaoguai Reach of the upper Yellow River during the years 1952-2010 were investigated based on runoff and sediment transport observations from the Sanhuhekou and Toudaoguai hydrological stations. Multiple influencing factors such as reservoir operations, tributary inflows, as well as runoff and sediment loads from the Shidakongdui area were analyzed. The results show that even though the sediment loads from the major sources, the Shidakongdui area as well as the upstream tributaries such as the Qingshui River and the Zuli River have reduced especially since the 2000 s as a result of enhanced water-soil conservation measures and improvement of vegetation cover, the study reach was still generally in a status of cumulative aggradation. This is mainly due to the joint operations of the Liujiaxia Reservoir and the Longyangxia Reservoir, which significantly reduced the annual runoff and sediment loads at the Sanhuhekou Crosssection. The reservoirs also remarkably altered the summer flood characteristics of the study reach, inducing the shape of the annual flow curve changing from a 'single-peak' into a 'doublepeak'. These alternations sharply decreased the sediment transport capacity of flooding in the summer flood season which yields more than 90% of the sediment loads, leading to an unbalanced relation between the water and sediment. In addition, the estimated incoming sediment coefficient of the Sanhuhekou Crosssection ranged from 0.003 to 0.014 kg s/m~6, of which 0.004 kg s/m~6 was suggested as a rough critical value to determine the scour or deposition status of the study reach.  相似文献   

13.
洱海是位于我国西南亚热带高原地区的重要淡水生态系统,在高强度的人类活动与气候变化的影响下出现了较为严重的水质退化与富营养化现象,其中北部湖区的问题最为突出。本文以北部湖区为对象,设置了喜洲等5个样点,于2020年3、6、9和12月对该湖北部的轮虫群落及环境因子进行了季节性调查,分析了轮虫群落的季节演替特征及主要影响因子。本次调查共检出26属48种轮虫,多数种类为广布种或暖水种,其中无柄轮属、晶囊轮属、胶鞘轮属、须足轮属、龟甲轮属、多肢轮属在4个季节均出现。异尾轮属的种类数最多,共计9种。螺形龟甲轮虫、长肢多肢轮虫和前节晶囊轮虫是主要的优势种类。其中,螺形龟甲轮虫在4个季节均为丰度优势种,而前节晶囊轮虫在4个季节均为生物量优势种。非度量多维尺度分析表明,洱海北部湖区轮虫群落结构存在显著的季节差异。这种季节差异主要反映了水温的直接与间接影响,后者主要表现为鱼类捕食压力与食物资源的季节性。冗余分析表明,透明度、温度和浮游植物丰度为解释轮虫群落结构变化的重要变量。群落的物种组成与季节变化反映了主要轮虫优势种类对水温和水质变化的敏感性。  相似文献   

14.
Petrogeochemical data indicate that after the end of seafloor spreading,residual magmatic activity still exists in the deep basin of the South China Sea.By using different viscous structure models beneath the fossil spreading center of the Southwest sub-basin we simulated the amount of melt produced,the length of the melting period,and the thermal evolution process in terms of geothermics and the buoyant decompression melting mechanism.We compared the results of our model with observed heat flow,seismic,and petrogeochemistry data.The results show that depletion buoyancy induced by buoyant decompression melting plays an important role in the melting process,while retention buoyancy,thermal buoyancy,and viscous shear force have only a weak influence on the melting process.From the length of the melting period,we determined that for the three viscous structures models the magmatic activity lasted about 5,12,and 15 Ma.Under the effect of buoyant depression melting,local high-temperature areas will develop under the basin,which can explain the low-velocity layer detected by seismic exploration in the middle and upper lithosphere of the Southwest sub-basin.We also simulated the possible lithology distribution beneath the fossil spreading center with the physical conditions of different viscous structure,different temperature structure,and different melting fraction,which provided a greater understanding of the rock petrogeochemical data of the deep sea basin in the South China Sea.  相似文献   

15.
Soil samples are collected from 74 sites in Shenyang city, northeast China, and the concentrations, spatial distribution, enrichment factors (EF), and potential ecological and human health risk (Er) of potentially toxic metals (Sr, Zn, Cr, Pb, Cu, Ni, and As) are investigated. The mean concentrations of potentially toxic metals in topsoil follow the order Sr > Zn > Cr > Pb > Cu > Ni > As. Compared with 2011, the contamination magnitude has improved in 2017, but the pollution status still exists, especially for As and Cr. EF and the mean Er of potentially toxic metals decrease following the order As > Pb > Cu > Ni > Zn > Cr > Sr and As > Cu > Zn > Pb > Sr > Ni > Cr, suggesting that the potentially toxic metals in the topsoil of Shenyang city mainly come from natural sources, and the potential ecological risk for potentially toxic metals is low. There are potentially non‐carcinogenic and carcinogenic health risks, but they are not considered significant. For non‐carcinogenic health risks, oral ingestion is the main exposure pathway, and Cr and Pb are the major pollutants. Finally, As is found to be the main carcinogenic contamination metal.  相似文献   

16.
Located in Liaoning Province, one of the traditional heavy industrial areas in China, Dahuofang Reservoir provides drinking water for nearly 30 000 000 citizens, as well as industrial and agricultural water for dozens of several cities and rural areas. The distribution of hazardous heavy metals is described in several types of soil, crops, and in different industrial or mining areas and main sewage irrigation areas. Five possible reasons that may cause the pollution are analyzed and listed. Also we provide some pragmatic suggestions for the remediation of heavy metals in contaminated soils.  相似文献   

17.
管锡东  蒋宏忱  姜颖  陈旭 《湖泊科学》2021,33(6):1940-1950
大气酸沉降会导致地表水体酸化和富营养化,同时气候变暖也会影响湖泊水体环境,湖泊生态系统如何响应二者相互作用是全球变化研究的热点之一.我国西南地区是全球酸沉降负荷最高的地区之一,然而目前对酸沉降影响下地表水环境变化规律知之甚少.本文以重庆四面山龙潭湖为研究对象,通过沉积岩芯的210Pb测年和硅藻分析,并结合流域历史资料数据,揭示龙潭湖过去近百年来水环境变化及其主要驱动因子.结果表明,1926-1968年,龙潭湖以Achnanthidium minutissimumEncyonema silesiacum占优势;随后,Lindavia bodanica快速增加至峰值后逐渐减少,伴随Aulacoseira alpigenaAulacoseira ambigua含量上升.硅藻组合中以适应中性和弱碱性水体的属种为主,嗜酸性属种含量很少,表明目前水体总体维持弱碱性,这得益于当地紫色砂页岩和森林土壤对于酸沉降的缓冲作用.尽管目前龙潭湖仍维持弱碱性,1980s以来硅藻推导水体酸碱度下降、中富营养种增加,表明酸沉降降低水体碱度并提高营养水平.气候变暖加剧水体热力分层和营养富集,导致适应扰动、贫营养环境的L.bodanica减少.2010年以来,中富营养属种略有减少反映湖泊富营养化有所减缓.  相似文献   

18.
To quantify the changes in flow energy, sediment yield and surface landform impacted by headcut height during bank gully erosion, five experimental platforms were constructed with different headcut heights ranging from 25 to 125 cm within an in situ active bank gully head. A series of scouring experiments were conducted under concentrated flow and the changes in flow energy, sediment yield and surface landform were observed. The results showed that great energy consumption occurred at gully head compared to the upstream area and gully bed. The flow energy consumption at gully heads and their contribution rates increased significantly with headcut height. Gully headcuts also contributed more sediment yield than the upstream area. The mean sediment concentrations at the outlet of plots were 2.3 to 7.3 times greater than those at the end of upstream area. Soil loss volume at gully heads and their contribution rates also increased with headcut height significantly. Furthermore, as headcut height increased, the retreat distance of gully heads increased, which was 1.7 to 8.9 times and 1.1 to 3.2 times greater than the incision depth of upstream area and gully beds. Positive correlations were found between energy consumption and soil loss, indicating that energy consumption could be used to estimate soil loss of headcut erosion. Headcut height had a significant impact on flow energy consumption, and thus influenced the changes in sediment yield and landform during the process of gully headcut erosion. Headcut height was one of the important factors for gully erosion control in this region. Further studies are needed to identify the role of headcut height under a wide condition. Copyright © 2018 John Wiley & Sons, Ltd.  相似文献   

19.
Based on the earthquake activity characteristics of the diamond block in the Sichuan-Yunnan region and by using the method of the meso-scope damage dynamics and damage evolution,we studied the damage evolution process for moderately strong earthquakes along two seismicbelts.The original combination patterns of all the units which illuminate the changes from stable state to destroyed state are given.All these patterns can direct the earthquake prediction practice in this region  相似文献   

20.
百花湖是贵阳市重要的城市饮用水源地,并且近年来经常发生水质异常现象.本文利用2009-2018年百花湖长时间序列的监测数据,采用综合营养状态指数法和Pearson相关性分析,研究了百花湖10年间的水质变化特征和影响因素.结果表明:1)库区叶绿素a(Chl.a)、总磷(TP)、总氮(TN)、高锰酸盐指数(CODMn)和透明度(SD)的浓度范围分别是3.43~39.72 mg/m3、0.034~0.115 mg/L、1.200~2.759 mg/L、1.41~5.51 mg/L和0.75~2.07 m,且高氮磷比(12~63)表明百花湖是磷限制型.2)在空间上,TP、TN、氨氮、CODMn和Chl.a浓度沿水体流向逐渐降低,SD呈相反变化趋势.3)10年来,百花湖水质由Ⅳ类转变为Ⅲ类,综合营养状态由轻度富营养化状态转变为中营养状态,水质整体向好.4)入库支流是影响百花湖库区水质的主要因素,长期以来,东门桥河、南门河水质TP和TN等超标严重,给库区水质稳定达标带来威胁.5)百花湖Chl.a浓度与气温、水位、风速和TP等指标显著相关,是受水文、气象及营养盐因素的综合控制.未来在百花湖水环境保护治理过程中,应加大对东门桥河、南门河等重点支流的污染治理,加强对水动力学、气候变化等水文气象因素影响库区水质(藻类水华)的机制研究.  相似文献   

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