Saturation evaluation for fine-grained sediments

Accurate quantification of the gas hydrate content in the deep sea is useful for assessing the resource potential and understanding the role of gas hydrates in the global carbon cycle. Resistivity logging data combined with Archie's equation are often used to calculate gas hydrate saturation, but the reliability is dependent on the rationality of the empirical parameter cementation factor and saturation index. At present, an increasing number of fine-grained hydrate-rich sediment regions have been discovered worldwide through drilling efforts, and the reservoir types and hydrate distribution are diverse, which differs greatly from that of coarse-grained reservoirs of hydrate-bearing sediment. This results in vertical variations in m and n through stratigraphy. At present, the saturation evaluation effect of these reservoirs cannot be improved. In this work, a theory for the determination of the cementation factor and saturation index was first proposed to obtain reliable and variable values of the empirical parameters. Then, a hydrate saturation evaluation technique with variables m and n was formed based on the well logging data. This technique was used to evaluate complex fine-grained hydrate-bearing reservoirs in several regions worldwide. It was found that the highest n could be 16, and the log calculation results were more consistent with the core hydrate saturation. Additionally, the cause of the excessively high n values was explained from physical principles, and the result was verified with actually well log data. In future evaluations of the amount of hydrate resources in fine-grained sediment reservoirs worldwide, new saturation estimation methods should be taken into account to advance hydrate research.     

The stability of sublittoral, fine-grained sediments in a subarctic estuary

The erodibility of natural estuarine sediments was measured in sit along a longitudinal transect of Manitounuk Sound, Hudson Bay, using the benthic flume Sea Carousel. Sedimentation processes along the transect varied from continuous, rapid, post-glacial sedimentation in the inner Sound, to glacial outcrops and seabed reworking of the outer Sound. The grain size and physical bulk properties reflect changes in depositional environment and correlate with sediment erosion threshold stress (τ_c), erosion rate (E), erosion type and still-water mass settling rate. There was a steady increase in τ_c (0·8–2·0 Pa) with distance down the Sound in parallel with the decreasing sedimentation rate (0·003–0·001 m yr^?1) and increasing sediment bulk density (1650–2010 kg m^?3). The near-surface friction coefficient varied up to 68° in proportion to the clay content of post-glacial material. Glacial sediments were characterized by variable results and generally higher friction coefficients. Seabed erosion in Sea Carousel began with surface creep of loose aggregates, pellets and organic debris. This was followed by Type I bed erosion at rates that varied between 0·0002 and 0·0032 kg m^?2 s^?1 (mean 0·0015). Type I peak erosion rate was inversely related to applied bed shear stress (τ_o). Type II erosion succeeded Type I, often after a broad transitional period. Simulations of suspended sediment concentration in Sea Carousel were made using four commonly used erosion (E) algorithms. The best results were obtained using Krone's dimensionless ratio relationship: E=M(τ_o/τ_c-1). Simulations were highly sensitive to the definition of erosion threshold with sediment depth [τ_c(z)]. Small errors in definition of τ_c(z) caused large errors in the prediction of suspended sediment concentration which far exceeded differences between the methods tested.     

Time- and method-dependent size distributions of fine-grained sediments

ABSTRACT With increased interest in fine-grained sediments it is imperative that a firm basis exist for comparative studies of these cohesive sediments. In this study the size distributions of continental slope and rise muds are shown to be dependent on both method and duration of sample pretreatment. Statistical analysis of 171 size distributions indicates that of the four most frequently used sample preparation methods (soak, stir, shake and ultrasonify) the time required to reach a 'terminal' distribution beyond which no 'fine-shift' was detected varied from 15 minutes to > 90 hours for a given sample solely as a function of preparation method. Data from this study also indicate that sample preparation by simple soaking alone will probably yield fine-grained sediments which, when analysed by pipette or microsedimentation accumulation balance, undergo a continuous change in size distribution during analysis and may never reach a 'terminal' distribution during the analysis time. On the other hand stirring and ultrasonification were shown to be the most rapid and consistent methods for obtaining a sample's'terminal'distribution.     

The shot-sensor method of measuring currents in shallow estuarine waters

A current measuring device, the Shot-Sensor, was developed as a low cost alternative to measuring water flow speeds and directions using conventional, more expensive instrumentation. The device releases stainless steel shot of known size and settling speed into a flowing water mass. As the shot settles, it is dispersed by currents and ends up in settling traps. Mean current speed and direction can be calculated from the patterns of dispersal and the percentages of shot of various sizes in the traps. Determination of precision and accuracy indicate that the Shot-Sensor can measure within a few cm s^?1 of more expensive meters and may be suitable for some shallow-water applications. Speed range of the Shot-Sensor is presently limited between 3 and 40 cm s^?1, but further development could allow this range to be extended.     

Geochemical and mineralogical properties of sulfide-bearing fine-grained sediments in Finland

 The geochemical and mineralogical characteristics of bulk samples and various size fractions of sulfide-bearing fine-grained sediments in the Petalax area, western Finland, were studied with ICP-AES (aqua regia digestion and "total" digestion) and X-ray diffraction. The sediments, which are dominated by particles <0.06 mm (clay and silt size), are composed of phyllosilicates (micas, kaolinite, chlorite, vermiculite), quartz, feldspars, amphiboles, organic matter, and secondary S minerals. The chemical analyses show that Na, Ca, and Sr are enriched in the silt and sand fractions, that Zr is enriched in the silt fraction, and that the concentrations of all other studied metals (Al, Ba, Co, Cr, Cu, Fe, K, La, Mg, Mn, Nb, Ni, Sc, Th, Ti, V, Y, and Zn) increase from the sand to the clay fraction. Sodium, Ca, and Sr occur largely in poorly dissolved feldspars, which explains the distribution of these metals in the sediments. The increase in the concentrations of most metals in the clay fraction is interpreted to be the result mainly of an increase in phyllosilicates in this size fraction. A geochemical comparison between the sulfide-bearing fine-grained sediments and glacial till shows that the former are enriched in several potentially toxic metals. It is therefore argued that the hydrological and ecological problems associated with the sulfide-bearing sediments are related not only to the production of acidity in oxidized layers, but also to mobilization and dispersion of toxic metals. Strategies to minimize damage of freshwater systems in areas covered with sulfide-bearing fine-grained sediments are suggested. Received: 20 February 1997 · Accepted: 25 August 1997     

湖相深水细粒物质的混合沉积作用探讨*

沉积物的混合是自然界的普遍现象,湖盆中广泛发育的深水细粒沉积岩本身就是一类混积岩。以东营凹陷古近系沙河街组三段下亚段—沙河街组四段上亚段细粒沉积岩为研究对象,通过厘米级岩心观察描述、小型沉积构造解剖、岩石薄片观察、X射线衍射全岩矿物分析及微量元素测试等方法,研究细粒物质的产出状态和混合方式;分析湖盆流体、气候及水体性质对细粒物质迁移、混合、沉积的控制作用,尝试探讨细粒物质的混合沉积机制。结果表明,湖相深水细粒沉积岩既有物质成分上的混合,也有结构的混合,且在宏观与微观的不同尺度均存在混合;混合沉积作用有均匀混合、纹层叠置混合、不均匀团块状混合等类型。纹层叠置混合沉积是最主要的混合沉积方式,依据纹层接触关系、所占比例及矿物产出状态可分为泥砂—灰纹层叠置混合型、泥—灰纹层叠置混合型、泥砂粒序—灰纹层叠置混合型、灰—泥—云纹层叠置混合型等。湖相深水细粒物质的混合沉积作用类型多且往往受多个因素同时控制,气候及水动力条件是控制细粒混合沉积岩发育的最主要因素,不同流体(浊流和底流)作用下的细粒沉积物混合作用存在差异。气候引起湖水性质变化及水体分层,从而控制不同类型细粒物质的絮凝沉降及化学沉积。不同构造部位、不同水体深度的混合作用不同;相同构造部位在垂向上也存在混合沉积方式的差异。     

细粒沉积物及其古地理研究进展与展望*

细粒沉积物特征及其古地理研究对含油气细粒沉积物的勘探开发、评价预测、工程技术设计等意义重大。近年来,细粒沉积物,尤其是含油气细粒沉积物研究的快速发展,带来了一系列新的研究领域。在讨论细粒沉积物的定义、分类与特征的基础上,通过分析细粒沉积的文献知识群,获取细粒沉积物、页岩研究等结构、热点与发展方向。国际上细粒沉积物研究主要关注微结构和成因机制,近年来主要在具有油气意义的特殊细粒沉积物--页岩研究方面取得关键进展,对页岩的研究过程可以分为以页岩表征为代表的主知识网络和以页岩气赋存、运移等构成的延伸知识网络。细粒沉积物古地理恢复方法丰富,适用性存在差异,但量化、多因素综合、数据集成与深度挖掘、人工智能化将是细粒沉积古地理恢复方法的方向。在含油气细粒沉积物的优选评价方面,需要对沉积物本身特征与控制影响因素展开精细研究,进而延伸出“更宏观”与“更微观”2个主要发展方向。     

Sterols in interstitial waters of marine sediments

In order to attempt to elucidate the nature of biogeochemical processes occurring at the water-sediment interface, sterols have been analysed in near bottom sea and interstitial waters collected in the eastern and western intertropical Atlantic ocean. Free and esterified sterol concentrations range from 0.2 to 82 μg l^?1 and are much higher than those found in overlying sea water, which range from 0.2 to 1.7 μg l^?1 for the dissolved fraction and from 0.01 to 0.07 μg l^?1 for the particulate fraction. Cholest-5-en-3β-ol and 24-ethylcholest-5-en-3β-ol are the dominant sterols in sea and interstitial waters. The variability encountered for the relative importance of minor sterols such as 24-methylcholesta-5,24(28)-dien-3β-ol and stanols, 5α-cholest-22(E)-en-3β-ol, 5α-cholestan-3β-ol and 24-ethyl-5α-cholestan-3β-ol in interstitial water and their variation with depth is discussed in terms of diversity of inputs and bacterial activity. For sediments cored off the Mauritanian coast, a productive area characterized by an intense upwelling, the chemical signatures observed in interstitial water through stanol/stenol ratios occur at levels of very high heterotrophic aerobic bacterial biomass estimations. The study of the sterol composition of interstitial water could constitute a valuable tool in appreciating the intensity of chemical and biological processes occurring in the first few metres of recent marine sediments.     

Transient growth of an isolated bubble in muddy, fine-grained sediments

Methane bubbles in fine-grained sediments have been shown to grow initially by elastic expansion and fracture. A previous growth model assumed quasi-steady state diffusion in which the methane porewater concentration quickly adjusted to changes in bubble geometry [Gardiner B. S, Boudreau B. P and Johnson B. D. (2003a) Growth of disk-shaped bubbles in sediments. Geochim. Cosmochim. Acta, 67 (8), 1485-1494]. Here, we present a finite-element model that solves the transient form of the reaction-diffusion equation, and the coupled linear elastic fracture mechanics (LEFM). In so doing we also employ a new theory for the post-fracture bubble sizes, based upon the full principles of LEFM.Our findings indicate that the quasi-steady state assumption is flawed due to violation of conservation of mass during fracture events. When the new model is applied to sediment conditions found at Cape Lookout Bight, NC, USA, it is found that bubbles grow somewhat faster than previously thought. A reference bubble of 0.5 cm³ will form in about 6 days, 2.5 days quicker than the old model predicted. Moreover, typical bubbles of 0.04 cm³ for this site can grow in as little as a day and a half. We examined the sensitively of the finite-element model to the various parameters in order to gain an understanding of how bubbles may behave under different sediment conditions. The influence of tides on bubble growth, through the process of rectified diffusion, was also examined and it was found that this had little influence upon growth.     

Metal transport, partition and fixation in drainage waters and sediments in carbonate terrain in Southeastern Ontario

Lake sediment composition as an indicator of mineralization within the catchment area has found widespread application in recent years, particularly in Canada. Results have indicated, however, the existence of varying relationships between lake sediment composition and mineralization resulting from local features of the limnological environment. Accordingly it was considered appropriate to examine the nature of metal transport in the lake and stream environment, the partitioning of metal between the stream waters and stream sediments and between lake waters and lake sediments to obtain some understanding of the factors that affect the lake sediment-mineralization relationship. This investigation was carried out over an area containing Pb-Zn occurrences of supposed “Mississippi-Valley type” in Grenville and Paleozoic bedrock in southeastern Ontario.The headwater drainage systems comprise active streams, swamps, beaver ponds and small lake-bog systems giving way downstream to open lakes. The beaver swamps and seasonal swamps act as drainage sinks for metals, restricting the extent of geochemical dispersion in drainage systems adjacent to mineralization. Selective extraction analysis of bog, stream and lake sediments indicates that metals are preferentially concentrated with amorphous iron oxides, which readily adsorb and complex lead and zinc and are stable in the alkaline environment common in swamps adjacent to carbonate-hosted lead-zinc mineralization. The accumulation of lead and zinc with amorphous iron oxides combined with the adsorbing and chelating action of organic matter on lead and zinc makes organic-rich sediments from these small swampy areas an excellent sample medium for reflecting local mineralization. Down drainage anomalies of these elements can be accentuated by selective analysis for the amorphous iron oxide-held metal, involving selective extraction techniques.In contrast, within larger lake systems, the analysis of water samples indicates that geochemical dispersion in surface waters in the high pH environment (pH = 8.0) associated with the carbonate-hosted lead-zinc deposits is extremely restricted. In this environment, anomalous metal contents in lake water were not evident in lakes adjacent to mineralization, while anomalous lake sediment compositions exist only in lakes immediately adjacent to Pb-Zn mineralization and do not extend down the drainage system. The restricted dispersion necessitates basing geochemical reconnaissance surveys on collection and analysis of samples from the headwater organic-rich swamps at a higher sample density and resulting higher cost than in areas where a lower sample density is acceptable due to a wider dispersion.     

Grain-size characteristics of fine-grained unflocculated sediments I:'one-round' distributions

A simple physical model of gravitational settling from an unsorted, unflocculated source suspension is presented and an equation derived to describe the grain-size spectra of the resulting bottom sediment. Results of grain-size analyses of sediments from a variety of environments and geographical locations are shown to conform with the postulated model. The characteristic size spectrum, termed ‘one-round’ sediment, identifies a deposit which has settled from suspension with no subsequent reworking resulting in modification of the grain-size distribution. The distribution of settling rates of grains in the suspension may be inferred from an analytical form fit to the bottom sediment grain-size spectrum, along with knowledge of certain physical characteristics of the fluid (e.g. mean velocity profile).     

Grain-size characteristics of fine-grained unflocculated sediments II:'multi-round' distributions

The grain-size spectrum of sediment deposited by settling of a suspension with a ‘one-round’ grain size distribution is described by a power law in which the integer exponent characterizing the fine-grained limb is increased by one over that of the suspension. If this better-sorted sediment, in turn, is resuspended and settles, further sorting and steepening of the limb occurs. Each resuspension event or‘round’changes the distribution by a predictable amount. Equations describing this sorting process, based on the derivation of the one-round equation, are fitted to grain-size analyses of well-sorted sediment from a variety of locations to verify the model. A suite of sandy bottom sediment samples from the Bay of Fundy shows that the steepness of the fine-grained limbs of the sand fraction indeed increases in integral steps.     

Organic matter diagenesis in shallow water carbonate sediments

Muddy carbonate deposits near the Dry Tortugas, Florida, are characterized by high organic carbon remineralization rates. However, approximately half of the total sedimentary organic matter potentially supporting remineralization is occluded in CaCO₃ minerals (intracrystalline). While a portion of nonintracrystalline organic matter appears to cycle rapidly, intracrystalline organic matter has an approximately constant concentration with depth, suggesting that as long as its protective mineral matrix is intact, it is not readily remineralized. Organic matter in excess of intracrystalline organic matter that is preserved may have a variety of mineral associations (e.g., intercrystalline, adsorbed or detrital). In surface sediment, aspartic acid contributed ∼22 mole % and ∼50 mole % to nonintracrystalline and intracrystalline pools, respectively. In deeper sediment (1.6-1.7m), the composition of hydrolyzable amino acids in both pools was similar (aspartic acid ∼40 mole %). Like amino acids, intracrystalline and nonintracrystalline fatty acids have different compositions in surface sediments, but are indistinguishable at depth. These data suggest that preserved organic matter in the nonintracrystalline pool is stabilized by its interactions with CaCO₃. Neutral lipids are present in very low abundances in the intracrystalline pool and are extensively degraded in both the intracrystalline and nonintracrystalline pools, suggesting that mineral interactions do not protect these compounds from degradation. The presence of chlorophyll-a, but absence of phytol, in the intracrystalline lipid pool demonstrates that chloropigments are present only in the nonintracrystalline pool. Sedimentary chloropigments decrease with depth at similar rates in Dry Tortugas sediments as found in alumino-silicate sediments from the Long Island Sound, suggesting that chloropigment degradation is largely unaffected by mineral interactions. Overall, however, inclusion and protection of organic matter by biominerals is a major pathway for organic matter preservation in this low-organic carbon, biomineral-rich regime.     

Erosion and deposition of fine-grained sediments from the Bay of Fundy

Simulations of the erosion, transport and deposition of fine-grained sediment, such as that of Greenberg & Amos and the Hydraulics Research Station, have illustrated a general lack of reliable field data. Consequently, some standard equations and constants used in modelling the sedimentation character of fine-grained cohesive sediment were evaluated based on data from two field studies and a flume experiment with undisturbed sediment from the Bay of Fundy. Initial results showed that the resistance to erosion of intertidal fine-grained sediment is controlled largely by the degree of subaerial exposure and the consequent dehydration and compaction. The sediment shear strength was high (4 kPa), but generally decreased seawards across the intertidal zone. The resistance of intertidal mud to erosion can be 80 times greater than sub-tidal counterparts. The rate of sediment erosion varied as a complex function of the applied bottom shear stress. At stresses immediately above the critical, the erosion rate decreased asymptotically with time. At higher excess stresses, the erosion rate was linear with respect to time. Thus sediment erosion cannot be represented by a single coefficient. The Krone method of computing sedimentation rates of suspended material was shown, by comparisons with direct measurement, to overpredict by 29%. All variables used in his method were measured in the evaluation with the exception of the critical deposition stress (τ_d). The closest comparisons were obtained when τ_d was assigned a value of 0.1 N m^?2 following Creutzberg & Postma. The in situ still-water particle settling rate (V_o) was constant with respect to time (2.1 × 10^?3 m s^?1). However, the settling tube measures of settling rate, compared to in situ results, underpredicted particle settling by an order of magnitude (2.7 × 10^?4 m s^?1). The reason for this discrepancy is not apparent from our results.     

Evidence of across-shelf transport of fine-grained sediments: turbidite-filled shelf channels in the Campanian Aberdeen Member, Book Cliffs, Utah, USA

The shore‐normal transport of fine‐grained sediments by shelf turbidity currents has been the focus of intense debate over the last 20 years. Many have argued that turbidity currents are unlikely to be a major depositional agent on the shelf. However, sedimentological, architectural, stratigraphic and palaeogeographic data from the Campanian Aberdeen Member, Book Cliffs, eastern Utah suggests otherwise and clearly demonstrates that storm‐generated and river flood‐generated underflows can transport a significant volume of fine‐grained sediments across the shelf. These across‐shelf flowing turbidity currents cut large subaqueous channel complexes up to 7 m deep, tens of kilometres basinward of their time‐equivalent shoreface. The shelf channels were filled with organic‐rich siltstones, mudstones and very fine‐ to fine‐grained Bouma‐like sandstone beds, including wave‐modified turbidites, hyperpycnites and classical turbidites. Deposition was above storm wave base. Palaeocurrent data reveal an overwhelmingly dominant across‐shelf (east–south‐east), offshore‐directed transport trend. Tectonic activity and/or concomitant palaeogeographic reorganization of the basin may favour the generation of these turbidite‐rich shelf deposits by altering the relative balance of wave versus fluvial energy. Increased erosion and sediment supply rates, because of tectonic uplift of the hinterland, may have increased the probability of fluvial dominance along the coastline and, hence, the possibility of submarine channelization in front of the river mouths. Additionally, the coastline may have become more sheltered from direct wave energy, thus allowing the fluvial processes to dominate. Seasonal increases in rainfall and storm activity may also favour the generation of across‐shelf underflows. On wave‐dominated shorelines, isolated shelf channels and lobes are most likely to be found down‐dip of fluvial‐feeder systems in relatively high sediment supply settings. These features are also most likely to occur in systems tracts that straddle a sequence boundary, especially those which are tectonically generated, as these would enhance the potential for altering basin morphology and, hence, the balance of fluvial and wave energy. Isolated shelf channels are recognized in older and younger strata in the Book Cliffs region, implying that wave‐supported gravity flows were a recurrent phenomena in the Campanian of Utah. It is probable that isolated shelf bodies are preserved in other stratigraphic intervals in the Cretaceous Western Interior of North America, and other basins worldwide, and are currently being overlooked or misidentified. Shoreface‐to‐shelf facies models should be revised to incorporate turbidite‐rich shelf deposits in some shelf settings.     

Partitioning of transition metals in oxidised and reduced zones of sulphide-bearing fine-grained sediments

Distribution and forms of transition metals (Ti, Zn, Ni, Co, Mn, Fe, Cu, V and Cr) were investigated in oxidised, partly oxidised and reduced zones of sulphide-bearing fine-grained sediments located in the coastal areas of western Finland. Samples for the analysis and study of vertical distribution of elements were taken from each vertical 10 cm section in pits ranging in depth between 2 and 3 metres, while bulk samples for characterisation of species and forms of metals were taken from 3 zones in each pit: the acid sulphate soil (characterised by acid and oxidising conditions), transition zone (characterised by a steep pH gradient and partly oxidising conditions) and the reduced zone (pH >6). The former samples were digested in aqua regia (3:1:2 HCl:HNO₃:H₂O), while the latter were digested in aqua regia and hot concentrated acids (HClO₄–HNO₃–HCl–HF) and were subjected to extractions with acid ammonium acetate, H₂O₂ and acid ammonium oxalate. Each leachate was analysed for metals with ICP–AES.The vertical variation in the concentrations of Ti were small at all the studied sites indicating that the sediments are homogeneous and that the total losses of other elements from the soil profiles (acid sulphate soil+transition zone) are not extensive. Field observations, extractions with ammonium oxalate, and concentration–variation patterns indicated that Fe-oxide is largely precipitated and retained also in these acid soils. There are, however, indications of redistribution of Fe within the soil profiles. The results also demonstrated that Mn, Ni, Zn, Co and Cu have been lost in considerable amounts from the acid sulphate soils. However, whereas Mn in general has been lost throughout the soil profile, part of the Zn, Ni and Co released in the acid sulphate soils have migrated downward and been reimmobilised in the transition zone immediately above the reduced zone. Also Cu has been lost from the acid sulphate soil, but generally in smaller proportions than Mn, Zn, Ni and Co. Dissolved metal sulphides seem to be major sources of the mobilised metal fractions. A main part of the V and Cr in the sediments are associated with weathering-resistant minerals. These metals are therefore, like Ti, only to a limited extent mobilised by the oxidation of the sulphide-bearing sediments.     

Dissolved aluminium in interstitial waters of recent marine sediments

Measurements of the concentration and vertical distribution of dissolved aluminium and silica, and of pH. in interstitial waters of recent marine sediments from the North Sea and the Mediterranean Sea were performed to evaluate the behaviour of aluminium during early diagenesis. The results suggest that thermodynamic equilibria alone do not control the concentrations of dissolved species in the system Al-Si-O₂-H₂O during early diagenesis. Rather, these concentrations are governed by dynamic factors involving mineral dissolution-precipitation reactions and diffusion.     

Geochemistry of molybdenum in some stream sediments and waters

Elevated concentrations of Mo are present in both the waters and sediments of Tenmile Creek, downstream from the large Mo deposit at Climax. Colorado. Concentrations of Mo reach a maximum of 10mg/1 in the water and 384μ/g in the (?) 80 mesh fraction of the sediment. The Mo anomaly extends for more than 80 km downstream from Climax, and results from the mining and milling at Climax. Background Mo concentrations in the nearby mountainous area are < 10μg/l (water) and < 5μg/g (sediment). Immediately below three small unmined Mo-rich orebodies elsewhere in Colorado < 3μg/l Mo are present in the waters and 20–30μg/g Mo in the fine fraction of the sediments.The Mo in the sediment of Tenmile Creek is chiefly adsorbed on coatings of amorphous Fe oxyhydroxide. and is similar to its form below two small, unmined Mo deposits. Mining has not changed the character of the chemical processes responsible for Mo dispersion from the Climax site.A modified version of the WATEQF computer program (Plummeret al., 1976) predicts that Tenmile Creek is undersaturated with respect to ferrimolybdite. molybdenite, powellite, and ilsemannite. The Mo in the stream water occurs as the molybdate ion which can be adsorbed on amorphous Fe oxyhydroxides. These predictions are supported by the absence of Mo minerals in the sediment of Tenmile Creek.     

Rare earth elements in pore waters of marine sediments

The rare earth elements (REEs) were measured in pore waters of the upper ∼25 cm of sediment from one site off Peru and three sites on the California margin. The pore water REE concentrations are higher than sea water and show systematic down core variations in both concentration and normalized pattern. From these analyses and from comparison to other chemical species measured (dissolved Fe, Mn, Ba, oxygen, nitrate, phosphate), it is suggested that pore water REEs can be grouped into three categories: those that are from an Fe-source, those that are from a POC-source, and cerium oxide. REEs from the Fe-source appear where anoxia is reached; they have a distinctive “middle-REE (MREE) enriched” pattern. The concentrations in this source are so elevated that they dominate REE trends in the Fe-oxide reduction zone. The net result of flux from the POC-source is relative enrichment of heavy-REEs (HREEs) over light-REEs (LREEs), reflecting remineralizing POC and complexation with DOC. A common “linear” REE pattern, seen in both oxic and anoxic sediments, is associated with this POC-source, as well as a “HREE enriched” pattern that is seen in surficial sediments at the Peru site. Overall, the pore water results indicate that Mn-oxides are not an important carrier of REEs in the oceans.A REE biogeochemical model is presented which attempts to reconcile REE behavior in the water and sediment columns of the oceans. The model proposes that POC, Fe-oxide and Ce-oxide sources can explain the REE concentration profiles and relative abundance patterns in environments ranging from oxic sea water to anoxic pore water. The model is also consistent with our observation that the “Ce-anomaly” of pore water does not exceed unity under any redox condition.     

Composition of waters and sediments in the Antwerp harbor

Industrial expansion in the harbor areas of Antwerp has altered environmental conditions to a great extent. This study examines the relation between the water economy of the port of Antwerp docks and the composition of dock waters, sediments, and interstitial waters, with emphasis on trace metals and chlorides. Some conclusions are reached as to the possible use of the dredged deposits in agriculture.