Integration of VNIR and SWIR spectral reflectance for mapping mineral resources; A case study,north east of Hajjah,Yemen

Laboratory reflectance spectra of 18 rock samples from the Precambrian basement of north east of Hajjah were measured and analyzed using the instrument of FieldSpec3 with spectral range 0.250–2.500 μm. The aim of this study is to use the spectral reflectance of rocks for mapping the mineral resources in the north east of Hajjah. The altered system in the study area comprises of silicification, sericitification, oxidation, clay minerals and carbonatization. Silicified alteration is not distinguishable in the regions of Visible-Near Infrared (VNIR) and Short wave Infrared (SWIR) of the electromagnetic spectrum, because of lack of diagnostic spectral absorption features in silica in this wavelength. Although the arsenopyrite and pyrite are wide spread in the whole study area their features do not appear in any range of spectra because they exhibit trans-opaque behavior and often lack distinction in VNIR and SWIR. The entire spectral reflectance curves of samples show alteration. Based on the examination of laboratory spectra all samples in the study area show promise in the field of mineral resources.     

Spatial distribution of altered minerals in the Gadag Schist Belt (GSB) of Karnataka,Southern India using hyperspectral remote sensing data

Spatial distribution of altered minerals in rocks and soils in the Gadag Schist Belt (GSB) is carried out using Hyperion data of March 2013. The entire spectral range is processed with emphasis on VNIR (0.4–1.0 μm) and SWIR regions (2.0–2.4 μm). Processing methodology includes Fast Line-of-sight Atmospheric Analysis of Spectral Hypercubes correction, minimum noise fraction transformation, spectral feature fitting (SFF) and spectral angle mapper (SAM) in conjunction with spectra collected, using an analytical spectral device spectroradiometer. A total of 155 bands were analysed to identify and map the major altered minerals by studying the absorption bands between the 0.4–1.0-μm and 2.0–2.3-μm wavelength regions. The most important and diagnostic spectral absorption features occur at 0.6–0.7 μm, 0.86 and at 0.9 μm in the VNIR region due to charge transfer of crystal field effect in the transition elements, whereas absorption near 2.1, 2.2, 2.25 and 2.33 μm in the SWIR region is related to the bending and stretching of the bonds in hydrous minerals (Al-OH, Fe-OH and Mg-OH), particularly in clay minerals. SAM and SFF techniques are implemented to identify the minerals present. A score of 0.33–1 was assigned for both SAM and SFF, where a value of 1 indicates the exact mineral type. However, endmember spectra were compared with United States Geological Survey and John Hopkins University spectral libraries for minerals and soils. Five minerals, i.e. kaolinite-5, kaolinite-2, muscovite, haematite, kaosmec and one soil, i.e. greyish brown loam have been identified. Greyish brown loam and kaosmec have been mapped as the major weathering/altered products present in soils and rocks of the GSB. This was followed by haematite and kaolinite. The SAM classifier was then applied on a Hyperion image to produce a mineral map. The dominant lithology of the area included greywacke, argillite and granite gneiss.     

Visible-Near Infrared Reflectance Spectroscopy for Rapid Characterization of Salt-Affected Soil in the Indo-Gangetic Plains of Haryana,India

Management of salt-affected soils is a challenging task in the input intensive rice-wheat cropping zone of the Indo-Gangetic plains (IGP). Timely detection of salt-affected areas and assessment of the degree of severity are vital in order to narrow down the potential gap in yield. Conventional laboratory techniques of saturation extract electrical conductivity (EC_e) and sodium adsorption ration (SAR) for soil salinity assessment are time-consuming and labour intensive; the VNIR (visible-near infrared) reflectance spectroscopy technique provides ample information on salinity and its attributes in an efficient and cost-effective way. This study aims to develop robust soil reflectance spectral models for rapid assessment of soil salinity in the salt affected areas of the IGP region of Haryana using VNIR reflectance spectroscopy. The results indicated that the spectral region between 1390 and 2400 nm was highly sensitive to measure changes in salinity. The developed hyperspectral models explained more than 80 % variability in EC_e, and other salinity related attributes (saturated extract Na⁺, Ca²⁺ + Mg²⁺, Cl^? and SAR) in the validation datasets. With the increasing availability of data from hyperspectral sensors in near future, the study will be very useful in real time monitoring of soils in the spatio-temporal context; enabling the farmers of IGP area to deal with salt degradation more effectively and efficiently.     

Hyperspectral Radiometry to Quantify the Grades of Iron Ores of Noamundi and Joda Mines,Eastern India

This paper present the results of a preliminary study to assess the potential of the visible, NIR and SWIR energy of the EMR in differentiating iron ores of different grades in a rapid manner using hyperspectral radiometry. Using different iron ore samples from Noamundi and Joda mines, Jharkhand and Orissa, states of India, certain spectro-radiometric measurements and geochemical analysis were carried out and the results have been presented. It was observed that the primary spectral characteristics of these iron ores lie in the 850 to 900 nm and 650–750 nm regions. The spectral parameters for each curve used for studying the iron ores are: (i) the slopes of the spectral curve in 685–725 nm region; (ii) position of the peak with respect to wavelength in 730–750 nm region and (iii) radius of curvature of the absorption trough in the 850–900 nm region. Comparison of these spectral parameters and the geochemistry of the samples indicates that the position of the peak of the curve in 730–750 nm region shifts towards longer wavelength with increasing iron oxide content, while the slope of the curvature in the 685–725 nm region has a strong negative correlation with the iron oxide content of the samples. Similarly, a strong negative correlation is observed between the radius of curvature of the 850–900 nm absorption trough and the iron oxide content. Such strong correlations indicate that hyperspectral radiometry in the visible and NIR regions can give a better estimate and quantification of the grades of iron ores. This study has demonstrated that generation of empirical models using hyperspectral radiometric techniques is helpful to quantify the grade of iron ores with limited geochemical analysis.     

A Spectro-radiometric Analysis of Ocean Colour Sensors and Proposal for a Miniature Hyper Spectral Imager for Future

Ocean colour sensors traditionally are of fixed spectral channel systems with specified bandwidth of about 20 nm in the visible region and about 40 nm in Near Infrared region. In these systems, it is known that a radiometric error of 1% in the measurement of top of the atmosphere signal may lead to an error of 10% in the retrieved ocean upwelling radiance. In this paper we investigated the range of wavelengths participating in signal collection (effective spectral pass band, ESPB) using relative spectral response data of various sensors flown earlier. ESPB values were computed for each spectral channel for various percentages of signal and the results showed that they are quite high compared to bandwidths specified. These values were found to vary with sensor and channel. ESPB shall be small for accurate computation of spectral radiance. As the knowledge of spectral profile of the signal in the range of ESPB helps in better estimation of spectral radiance at the intended wavelengths, a miniature high performance linear variable filter based hyperspectral sensor is proposed as an alternative. We present here the design concept and report the estimated performance of such sensor that can be realized even with commercial off the shelf components for operational implementation.     

Spectral studies of lunar equivalent rocks — A prelude to lunar mineral mapping

Hyperspectral remote sensing technique is widely applied for geological studies including the study of extra-terrestrial rocks. Since it has many spectral bands, discrimination between rocks and minerals can be done more precisely. To perform chemical and mineralogical mapping and to study the rocks on the lunar surface, India has proposed to launch its first lunar remote sensing satellite Chandrayaan-1 in the year 2008. For mineralogical mapping, the mission will carry a Hyperspectral Imager (HySI) instrument, which operates in the VNIR region. This paper presents-an attempt to study the spectral response of lunar-akin terrestrial rocks, in the VNIR region (as in the case of the proposed HySI on-board Chandrayaan-1). For this purpose, rocks similar to those present on the lunar surface were collected and their spectral response in the 64 simulated bands of HySI sensor were studied using a spectro-radiometer. Petrographic studies and modal analysis were carried out using thin sections of the rock samples. On studying the spectral response of the lunar-like rock samples in the 64 HySI bands, it is seen that there are distinct absorption features in bands 58 (923.75nm-927.5nm) and 63 (942.5nm-946.25nm) of the NIR wavelength ranges, for basalt rocks; distinct reflectance features in band 20 (590nm to 600nm) for ganmbbro: distinct reflectance features in band 19 (580nm to 590nm) and absorption in band 18 (570-580nm) for gabbroic anorthosite and distinct reflection features in band 63 (942.5nm to 946.25nm) for anorthosite. Thus, this study demonstrates the possibility of identifying the minerals and rocks on lunar surface using the hyperspectral approach and the spectral signatures of lunar-like rocks present on Earth.     

Spectral reflectance pattern study of some Indian landuse/landcover features

To utilize the full potential of multispectral data acquired from aerial photographs/satellite imagery increased knowledge of the spectral reflectance characteristics of Landuse/Landcover features are required. Spectro-Radiometer was used to collect the spectral reflectance values in wavelength regions ranging from 0.48 to 0.96 u m, of some Landuse/Landcover features, in Roorkee and its surrounding areas. Spectral reflectance values, thus collected, were used to draw spectral reflectance curves of each feature separately and to determine the optimum wavelength regions for identifying each Landuse/Landcover feature. The wavelength regions, in which two dissimilar Landuse/Landcover features exhibit nearly same tonal variation in B&W aerial photographs/satellite imagery, were also determined from these curves.     

Sensitivity of spectral reflectance values to different burn and vegetation ratios: A multi-scale approach applied in a fire affected area

The aim of our study was to explore the spectral properties of fire-scorched (burned) and non fire-scorched (vegetation) areas, as well as areas with different burn/vegetation ratios, using a multisource multiresolution satellite data set. A case study was undertaken following a very destructive wildfire that occurred in Parnitha, Greece, July 2007, for which we acquired satellite images from LANDSAT, ASTER, and IKONOS. Additionally, we created spatially degraded satellite data over a range of coarser resolutions using resampling techniques. The panchromatic (1 m) and multispectral component (4 m) of IKONOS were merged using the Gram-Schmidt spectral sharpening method. This very high-resolution imagery served as the basis to estimate the cover percentage of burned areas, bare land and vegetation at pixel level, by applying the maximum likelihood classification algorithm. Finally, multiple linear regression models were fit to estimate each land-cover fraction as a function of surface reflectance values of the original and the spatially degraded satellite images.The main findings of our research were: (a) the Near Infrared (NIR) and Short-wave Infrared (SWIR) are the most important channels to estimate the percentage of burned area, whereas the NIR and red channels are the most important to estimate the percentage of vegetation in fire-affected areas; (b) when the bi-spectral space consists only of NIR and SWIR, then the NIR ground reflectance value plays a more significant role in estimating the percent of burned areas, and the SWIR appears to be more important in estimating the percent of vegetation; and (c) semi-burned areas comprising 45–55% burned area and 45–55% vegetation are spectrally closer to burned areas in the NIR channel, whereas those areas are spectrally closer to vegetation in the SWIR channel. These findings, at least partially, are attributed to the fact that: (i) completely burned pixels present low variance in the NIR and high variance in the SWIR, whereas the opposite is observed in completely vegetated areas where higher variance is observed in the NIR and lower variance in the SWIR, and (ii) bare land modifies the spectral signal of burned areas more than the spectral signal of vegetated areas in the NIR, while the opposite is observed in SWIR region of the spectrum where the bare land modifies the spectral signal of vegetation more than the burned areas because the bare land and the vegetation are spectrally more similar in the NIR, and the bare land and burned areas are spectrally more similar in the SWIR.     

Assessment of Late Blight Induced Diseased Potato Crops: A Case Study for West Bengal District Using Temporal AWiFS and MODIS Data

Remote sensing technology becomes an effective and inexpensive technique for detecting disease in vegetation. In this study, an attempt has been done to discriminate healthy and late blight affected crop using remote sensing based indices such as NDVI and LSWI. NDVI and LSWI spectral profiles between healthy and late blight affected crop shows large difference. Mean difference in reflectance between two acquired dates Jan. 10 and 29, 2009 crop clusters varied from 31.28 % in red band, 7.7 % in NIR band and 6.23 % in SWIR bands in healthy crops while in late blight affected crops it is ?15.5 % in red, 44.4 % in NIR and ?14.61 % in SWIR bands. Negative percentage differences in reflectance indicate reflectance increases from Jan. 10, 2009 to Jan. 29, 2009, while positive difference indicate decrease in reflectance between the two dates. Since potato is an irrigated crop, these differences in reflectance are attributed to prevalent disease at that time. It is found that severely affected areas are Bardhman, Arambag, Bishnupur, Ghatal and Hugli taluka with crop damage areas are 4036.66, 1138.68, 2025.23, 469.15, and 380.08 ha, respectively.     

Surface Reflectance Climate Data Records (CDRs) is a Reliable Landsat ETM+ Source to Study Chlorophyll Content in Pecan Orchards

We evaluated the relationships among three Landsat Enhanced Thematic Mapper (ETM+) datasets, top-of-atmosphere (TOA) reflectance, surface reflectance climate data records (surface reflectance-_CDR) and atmospherically corrected images using Fast Line-of-Sight atmospheric analysis of Spectral Hypercubes model (surface reflectance-_FLAASH) and their linkto pecan foliar chlorophyll content(chl-cont). Foliar chlorophyll content as determined with a SPAD meter, and remotely-sensed data were collected from two mature pecan orchards (one grown in a sandy loam and the other in clay loam soil) during the experimental period. Enhanced vegetation index derived from remotely sensed data was correlated to chl-cont. At both orchards, TOA reflectance was significantly lower than surface reflectance within the 550–2400 nm wavelength range. Reflectance from atmospherically corrected images (surface reflectance-_CDR and surface reflectance-_FLAASH) was similar in the shortwave infrared (SWIR: 1550–1750 and 2080–2350 nm) and statistically different in the visible (350–700 nm). Enhanced vegetation index derived from surface reflectance-_CDR and surface reflectance-_FLAASH had higher correlation with chl-cont than TOA. Accordingly, surface reflectance is an essential prerequisite for using Landsat ETM+  data and TOA reflectance could lead to miss-/or underestimate chl-cont in pecan orchards. Interestingly, the correlation comparisons (Williams t test) between surface reflectance-_CDR and chl-cont was statistically similar to the correlation between chl-cont and commercial atmospheric correction model. Overall, surface reflectance-_CDR, which is freely available from the earth explorer portal, is a reliable atmospherically corrected Landsat ETM+ image source to study foliar chlorophyll content in pecan orchards.     

Estimating soil zinc concentrations using reflectance spectroscopy

Soil contamination by heavy metals has been an increasingly severe threat to nature environment and human health. Efficiently investigation of contamination status is essential to soil protection and remediation. Visible and near-infrared reflectance spectroscopy (VNIRS) has been regarded as an alternative for monitoring soil contamination by heavy metals. Generally, the entire VNIR spectral bands are employed to estimate heavy metal concentration, which lacks interpretability and requires much calculation. In this study, 74 soil samples were collected from Hunan Province, China and their reflectance spectra were used to estimate zinc (Zn) concentration in soil. Organic matter and clay minerals have strong adsorption for Zn in soil. Spectral bands associated with organic matter and clay minerals were used for estimation with genetic algorithm based partial least square regression (GA-PLSR). The entire VNIR spectral bands, the bands associated with organic matter and the bands associated with clay minerals were incorporated as comparisons. Root mean square error of prediction, residual prediction deviation, and coefficient of determination (R²) for the model developed using combined bands of organic matter and clay minerals were 329.65 mg kg⁻¹, 1.96 and 0.73, which is better than 341.88 mg kg⁻¹, 1.89 and 0.71 for the entire VNIR spectral bands, 492.65 mg kg⁻¹, 1.31 and 0.40 for the organic matter, and 430.26 mg kg⁻¹, 1.50 and 0.54 for the clay minerals. Additionally, in consideration of atmospheric water vapor absorption in field spectra measurement, combined bands of organic matter and absorption around 2200 nm were used for estimation and achieved high prediction accuracy with R² reached 0.640. The results indicate huge potential of soil reflectance spectroscopy in estimating Zn concentrations in soil.     

面向土壤分类的高光谱反射特征参数模型

提出了一种无损、快速、成本低的土壤分类方法,选取松嫩平原4种典型土壤(黑土、黑钙土、风砂土和草甸土)耕层(0—20 cm)土样的实验室反射光谱数据作为研究对象,采用重采样、包络线消除法处理光谱数据,提取反映反射光谱特征的光谱特征参数,利用K均值聚类(K-means clustering)和决策树(decision tree)分别进行聚类分析和分类模型构建,实现土壤的快速分类。结果表明,利用表层土壤反射光谱特征参数构建的决策树分类模型可以对研究区土壤进行分类。研究成果有望加快土壤制图,为土壤理化性质的时空变化研究提供技术支持。     

Assessment of Aphid Infestation in Mustard by Hyperspectral Remote Sensing

Field experiment was conducted during 2009–10 and 2010–11 rabi season at research farm of IARI, New Delhi for assessing the aphid infestation in mustard. In aphid infested plant the LAI was 67 to 94% lower than healthy plant. Chlorophyll concentration decreased to 50% in infested plant as compared to healthy plant. Infestation was more severe in late sown crop and due to aphid infestation the percentage oil content and yield was reduced significantly. The spectral reflectance of aphid infested canopy and healthy canopy taken in the laboratory had significant difference in NIR region. In the visible region, the reflectance peak occurred in healthy canopy at around 550–560 nm while this peak was lower by 31% in the aphid infested canopy. The reflectance for healthy crop was found to be more in visible as well as NIR region as compared to aphid infested canopy. The most significant spectral bands for the aphid infestation in mustard are in visible (550–560 nm) and near infrared regions (700–1250 nm and 1950–2450 nm). The different level of aphid infestation can be identified in 1950–2450 nm spectral regions. Spectral indices viz NDVI, RVI, AI and SIPI had significant correlation with aphid infestation. Hence these indices could be used for identifying aphid infestation in mustard.     

Using in situ hyperspectral reflectance data to distinguish nine aquatic plant species

In situ hyperspectral reflectance data were studied at 50 bands (10 nm bandwidth) over the 400–900 nm spectral range to determine their potential for distinguishing among nine aquatic plant species: American lotus [Nelumbo lutea (Willd.) Pers.], American pondweed (Potamogeton nodusus Poir.), giant duckweed [Spirodela polyrrhiza (L.) Schleid.], Mexican waterlily (Nymphaea mexicana Zucc.), white waterlily (Nymphaea odorata Aiton), spatterdock [Nuphar lutea (L.) Sm.], giant salvinia (Salvinia molesta Mitchell), waterhyacinth [Eichhornia crassipes (Mart.) Solms] and waterlettuce (Pistia stratiotes L.). The species were studied on three dates: 30 May, 1 July and 3 August 2009. All nine species were studied in July and August, while only eight species were studied in May; giant duckweed was not studied in May due to insufficient availability. Two procedures were used to determine the optimum bands for discriminating among species: multiple comparison range tests and stepwise discriminant analysis. Multiple comparison range tests results for May showed that most separations among species occurred at bands 795–865 nm in the near-infrared (NIR) spectral region where up to six species could be distinguished. For July, few species could be distinguished amongthe 50 bands; most separations occurred at the 715 nm red-NIR edge band where four species could be differentiated. The optimum bands in August occurred in the green (525–595 nm), red (605–635 nm) and red-NIR edge (695–705 nm) spectral regions where up to six species could be distinguished. Stepwise discriminant analysis identified 11 bands in the blue, green, red-NIR edge and NIR spectral regions to be significant to discriminate among the eight species in May. For July and August, stepwise discriminant analysis identified 15bands and 13 bands, respectively, from the blue to NIR regions to be significant for discriminating among the nine species.     

Hyper-spectral data based investigations for snow wetness mapping

Spatial information on snow wetness content (SWC) is important for hydrology, climatology applications. Limited work is available on estimation of SWC using optical sensors. In present work, spectral signature characteristics of snow (~145 samples) acquired in winters of three years, using field spectral-radiometer (350–2500 nm) were correlated with synchronized SWC measurements. Correlation is found stronger in Near-Infra-Red (NIR) and Short-Wave-Infrared (SWIR) regions than Visible (VIS). Spectral peak width at 905 and 1240 nm is found negatively correlated with SWC, while positively correlated at 1025 nm. Asymmetry tends towards right as SWC increases and has stable positive correlations as compared to other characteristics. Sensitivity of widely used snow-related indices to SWC is also analyzed. Based on analysis, new ratio method at selected wavelengths is proposed to discriminate dry and wet snow zones using air/ground borne sensors. Proposed methodology is evaluated on air-borne hyper-spectral (AVIRIS-NG) data and 88% overall accuracy with kappa coefficient 77.6 observed after validation with reference observations.     

An Improved Band Selection Technique for Hyperspectral Data Using Factor Analysis

This paper discusses a statistical and band transformation based approach to select bands for hyperspectral image analysis. Hyperspectral images contain large number of spectral bands with redundant information about the spectral classes in the image scene. It is necessary to reduce the high dimensionality of the data for the processing of hyperspectral data. We report a feature selection technique that removes correlated spectral bands using band decorrelation technique and obtains maximum variance image bands based on factor analysis. Factor analysis method of band selection technique is also validated against existing methods of band selection. The study is carried out for the agriculturally rich area of Musiri region of South India that has varied landcover types. Evaluation of the band selection procedure is done using signature separability measures such as Euclidean distance, Divergence, Transformed divergence and Jeffries Matusita distance. Results indicated that selected bands exhibited maximum separability and also occurred predominantly at wavelength 700 nm, 850, 1000 nm, 1200 nm, 1648 nm and 2200 nm.     

用近红外及短波红外反射波谱编码方法识别蚀变粘土矿物

本文介绍一种根据蚀变粘土矿物的近红外及短波红外反射波谱的特征吸收峰识别粘土矿物的方法。该方法的原理是根据不同蚀变粘土矿物的近红外、短波红外反射波谱均存在一些特征吸收峰,而且不同粘土矿物,其吸收峰个数、波长位置及吸收强度不同。首先用IRIS红外智能波谱仪对样品进行测试,然后,将测得的样品的近红外、短波红外反射波谱吸收峰波长和吸收强度进行数字编码,再用此编码与存贮于数据库中的标准蚀变粘土矿物的近红外-短波红外反射波谱吸收峰波长和吸收强度编码进行对比,来进行矿物识别。该方法主要包括①求外壳曲线(包络曲线);②求外壳系数；③求吸收峰极小值及波长位置；④对吸收峰波长及吸收强度进行编码；⑤与标准蚀变粘土矿物吸收峰波长和吸收强度编码进行对比来识别粘土矿物等5个步骤。     

Spatially Explicit Estimation of Leaf Area Index Using EO-1 Hyperion and Landsat ETM+ Data: Implications of Spectral Bandwidth and Shortwave Infrared Data on Prediction Accuracy in a Tropical Montane Environment

This study evaluated the utility of narrowband (EO-1 Hyperion) and broadband (Landsat ETM+) remote sensing data for the estimation of leaf area index (LAI) in a tropical environment in Sulawesi, Indonesia. LAI was inferred from canopy gap fraction measurements taken in natural tropical forest and cocoa plantations. Single and multiple spectral bands and spectral indices were used as predictor variables in reduced major axis (RMA) and ordinary least squares (OLS) regression models. The predictive power of most regression models was notably higher when employing narrowband data instead of broadband data. Highly significant relationships between LAI and spectral reflectance were observed near the red-edge region and in most shortwave infrared (SWIR) bands. In contrast to most near-infrared (NIR) narrow bands, the correlation between SWIR reflectance and LAI was not confounded when including both vegetation types and did not suffer from saturation. The results demonstrate that leaf area index of a challenging tropical environment can be estimated with satisfactory accuracy from hyperspectral remote sensing data.     

Confirmation of soil physiographic units through soil mineralogy studies in Yamuna alluvial plain,India

A confirmatory study of soil physiographic units identified through aerial photo interpretation technique, in Yamuna alluvial plain, Haryana is presented here. The area under study is part of Yamuna alluvial plain in Sonepat district, Haryana. Shanwal and Malik (1980) studied and mapped this area (semi-detailed) on 1:25,000 scale through areial photo interpretation technique. The soil profile samples of major soil physiographic units of the area were fractionated into sand, silt and clay. Detail mineralagical studies were carried out through electron microscopic and X-ray diffractometer studies in order to know their nature and origin of the parent material. X-ray diffraction data shows that mineralogy of different fractions (Sand, silt and clay) of soils samples, of different physiographic units were similar except Lavee. In this area mica is the dominant day mineral in the soils followed by Kaolinite, chlorite, vermiculite and smectite in decreasing order of their abundances. The occurance of fibrous minerals in coarse clay and silt fraction of soil samples of Lavee physiographic unit is the interesting feature of this area. The presence of fibrous minerals indicates that this overlain material designated as natural Levee in this area is not the alluvium brought down by the river Yamuna but is aeolian material flown from adjoining deseret of Rajasthan and deposited as stabilized sand dune. The fibrous minerals have been reported earlier in the desert of Rajasthan.     

Assessing Metal-Induced Changes in the Visible and Near-Infrared Spectral Reflectance of Leaves: A Pot Study with Sunflower (<Emphasis Type="Italic">Helianthus annuus</Emphasis> L.)

The aim of this study was to monitor changes in leaf spectral reflectance due to phytoaccumulation of trace elements (Cd, Pb, and As) in sunflower mutant (M5 mutant line 38/R4-R6/15-35-190-04-M5) grown in spiked and in situ metal-contaminated potted soils. Reflectance spectra (350–2500 nm) of leaves were collected using portable ASD spectroradiometer, and respective leaves sample were analyzed for total metal contents. The spectral changes were quite noticeable and showed increased visible and decreased NIR reflectance for sunflower grown in soil spiked with 900 mg As kg^?1, and in in situ metal-contaminated soils. These changes also involved a blue-shift feature of red-edge position in the first derivatives spectra, studied vegetation indices and continuum removed absorption features at 495, 680, 970, 1165, 1435, 1780, and 1925 nm wavelength. Correlograms of leaf-metal concentration and reflectance values show highest degrees of overall correlation for visible, near-infrared, and water-sensitive wavelengths. Partial least square and multiple linear regression statistical models (cross-validated), respectively, based on Savitzky–Golay filter first-order derivative spectra and combination of spectral feature such as vegetation indices and band depths yielded good prediction of leaf-metal concentrations.