Time and density-dependent properties of fluid mud suspensions,NE brazilian continental shelf

Fluid mud suspensions, defined as containing between 10 to 480 g/liter, occur in numerous estuarine and nearshore continental shelf environments. The quantities of sediment incorporated in fluid mud are enormous, and they must be considered to be of major importance in the transport and deposition of fine-grained sediment in these environments.This study was performed on the NE Brazilian Continental Shelf, a muddy coastline that reaches from the Amazon to the Orinoco, a distance of 1600 km. The fluid mud forms a thick (3 to 5 m) boundary layer that extends 100-km offshore and generally coincides with the 10-m depth contour.The fluid muds appear well-adjusted to the current regime on the NE Brazilian continental shelf. Near-bottom current velocities were seldom greater than 50 cm/sec during the sampling interval. Consequently, yield stress in fluid muds of 1.20 × 10³ kg/m³ and greater was seldom exceeded, and consolidation proceeded without interruption.     

Pathways of clay mineral transport in the coastal zone of the Brazilian continental shelf from Ceará to the mouth of the Amazon River

The transport pathways of fine sediments (fraction <2 μm) along the Brazilian continental shelf from Ceará to the Amazon River mouth were studied by means of clay mineral analyses. On the continental shelf southeast of the Amazon mouth, fluctuations in clay mineral compositions reflect simple mixing between the suspended load of the North Brazil Current and sediment from several smaller rivers. Previously, clay mineral variations west of the Amazon mouth have been explained by variable settling velocities of different grain-size classes within the <2 μm fraction or by selective coagulation of individual clay mineral groups. By contrast, our experiments with river bank samples show that selective coagulation does not occur in Amazon River sediments. A more appropriate explanation for observed variations in clay mineral composition off the Amazon mouth seems to be, similarly to that for the shelf between Ceará and the Amazon mouth, a mixing of Amazon sediments with suspended material of the North Brazil Current. This interpretation is supported by data on clay mineral composition east and south of the Amazon mouth, showing more affinity to sediments of the North Brazil Current than to the suspended load of the Amazon River. Additionally, relatively low sedimentation rates and low concentrations of fine-grained sediments on the shelf suggest that high riverine input by the Amazon River does not overprint the sediments of the North Brazil Current in this region. The strong North Brazil Current shunts the Amazon suspended load in a north-westerly direction along the north-eastern coast of South America. Hence, stronger sedimentation of Amazon sediments would occur only west of the river mouth.     

Subaqueous deltaic formation on the Atchafalaya Shelf,Louisiana

The Atchafalaya River in Louisiana shares the third largest drainage basin in the world with the Mississippi River. Sediment cores and seismic profiles were used to examine the development and impact on land accretion of an early-stage subaqueous delta accumulating on the shallow (<25 m water depth) continental shelf seaward of the Atchafalaya River mouths in the period (∼100 years) since the Atchafalaya has captured a significant fraction of the overall Mississippi discharge. The subaqueous clinoform is muddy (70–100% finer than 63 μm) and extends approximately 21–26 km seaward of the shell reef (to 8 m water depth) across the mouth of the Atchafalaya Bay, with a discontinuous, and, in places, mobile modern mud layer <20 cm thick covering a relict deltaic shoal area further seaward. The sigmoidal clinoform has a topset surface that steepens from east to west (1:2500 to 1:1600), a foreset with maximum slopes of about 1:550, and a limited bottomset region (<0.5 km wide). ²¹⁰Pb and ¹³⁷Cs geochronology show maximum sediment accumulation rates (>3 cm/year) correspond to the foreset and bottomset region, with rates decreasing to as low as 0.9 cm/year on the shelf topset region and its extension inside Atchafalaya Bay. Seven sedimentary facies are observed in the subaqueous delta, with differences created by degree of biological destruction of physical stratification, which is inversely related to sediment accumulation rate, and by the proximity of an area to the riverine sand source. There is a marked alongshore sediment dispersal pattern observed by the progressive winnowing of sand and coarse silt to the west. There is also a significant increase in shell content in Atchafalaya Bay relative to shelf facies. The resulting sigmoidal clinoform deposit (<3 m thick) more closely resembles strata geometries of subaqueous mud deltas associated with energetic systems (e.g., Amazon, Ganges–Brahmaputra, Fly), than it does the mature Mississippi delta 180 km to the east, albeit on a smaller scale and in shallow water.     

Recent sediment accumulation and origin of shelf mud deposits in the Yellow and East China Seas

Modern (last 100 yr) accumulation rates of shelf mud deposits in the Yellow and East China Seas were investigated using the distribution of excess ²¹⁰Pb (²¹⁰Pb_ex) in sediment core samples. Compilation and merger of new and previously published data helped clarify sediment accumulation in these seas. The estimated accumulation rates, together with data of suspended sediment concentrations, provided findings on the sediment budget, origin, and transport pathway of the mud deposits. The overall accumulation distribution in the Yellow and East China Sea shelf revealed a general, cross-shelf decreasing trend along the sediment dispersal system away from the rivers, except for the South Sea (SSM) and southeastern Yellow Sea (SEYSM) mud patches found along the Korean coast. Notably, ²¹⁰Pb_ex activity profiles within the SSM and the SEYSM yielded a relatively high accumulation rate of 2-5 mm/yr, implying a sedimentation rate of 4-15 × 10⁷ tons per year in this coastal zone. Such an annual accumulation rate is about one order of magnitude greater than the total sediment discharge (6-20 × 10⁶ tons/yr) from Korean rivers, suggesting an additional offshore source. The distribution pattern of the well-defined suspended plume clearly showed the possible transport and exchange of fine-grained sediments between the ECS shelf and the coastal area of Korea, especially during winter. Such a high accumulation in Korean coastal areas is attributable to the sediments supplied from the mud deposit of the ECS (i.e., SWCIM), with origins in Chinese rivers. Therefore, the Korean coastal area may be an important sink for some of Chinese river sediments being transported from the south by the Yellow Sea Warm Current.     

Sulfur diagenesis and burial on the Amazon shelf: Major control by physical sedimentation processes

Early diagenetic properties of Amazon shelf muds are dominated by nonsulfidic Fe and Mn cycling, resulting in relatively little S deposition compared to previously studied marine margin environments. Despite abundant potential reactants typical of sulfidic deposits, authigenic sulfides represent only ~ 10% of diagenetically reduced Fe, and DOP (degree of pyritization) is only ~0.02. The average C/S (wt wt^–1) ratio of buried sediment below the zone of SO₄ ^2- reduction is ~ 7.4, ~ 2.6 times more than the commonly assumed modern shelf average of ~ 2.8. The deltaic burial rate forS is ~ 0.65 × 10⁶ tons yr^–1. Relatively lowS deposition is promoted by terrestrial weathering that delivers reactive oxide debris, but apparently depends most strongly on reoxidation and rapid burial by intense physical reworking and fluid-mud formation. Diagenetic models of S distributions demonstrate rapid sediment reworking (~ 10–100 cm yr^–1 as apparent advection), substantialS reoxidation (84–98%), and in one case, massive sediment deposition of up to ~ 5 m of sediment in ~ 1 year. Extremely low DOP coupled with dominance by nonsulfidic reduced-Fe minerals and lack of biogenic sedimentary structures may be an indicator in marine organic-rich muds of intense physical reworking under oxygenated waters.     

Phytoplankton biomass and nutrient distributions in the Amazon River plume: Environmental correlates

The distribution of phytoplankton biomass in the plume of the Amazon River over the Brazilian continental shelf is analyzed by the use of multiple regression. Previous attempts to assess how different parameters control phytoplankton biomass have used pairwise correlations. A multiple regression approach, however, allows the elucidation of collinearity between these parameters. This approach reveals that phytoplankton biomass may be predicted largely by the following three groups of collinear variables that resemble the factors of factor analysis: suspended-sediment concentration and transparency (which generally describe irradiance availability), salinity and temperature (which describe vertical stratification, a measure of water-column stability), and the ambient concentrations of nutrients (phosphate, nitrate, silicic acid, and nitrite). The effects of water clarity and nutrients have been previously described, but the importance of vertical stability has never been separated from the other two. Additional important single variables were oxygen, ammonia, and urea. The strength of the contribution of particular variables to a regression model depends on the season of the cruise and hence on the volume of riverine discharge.     

River flooding, storm resuspension, and event stratigraphy on the northern California shelf: observations compared with simulations

Coast-hugging surface flood plumes occur on the inner shelf of northern California during the winter season, generating dense, near-bottom suspensions which may attain fluid mud concentrations as particles settle. The period of storm-heightened waves may continue into the flood period, leading to gravity-driven seaward displacement of the bottom suspension; or the wave regime may ameliorate, leaving the suspension to consolidate as a short-lived, inner-shelf flood bed. Such beds tend to be resuspended within days or weeks by subsequent storm events that may recreate the original high concentrations. The sediment is thus dispersed seaward by gravity flows, to be deposited as a muddy flood bed on the central shelf. The locus of deposition of these “high-concentration regimes” is a function of the relative intensities of river discharge and storm wave height. Greater discharge piles thicker storm beds nearer shore, while intense wave regimes allow deposition of the fluid mud further seaward. During events with high values of both parameters, large amount of fluid mud may bypass over the shelf edge. In contrast, “low-concentration regimes” occur during storm periods when there has been no recent flood deposition on the inner shelf. The shelf floor is better consolidated than in the previous case, and the resulting suspended sediment concentrations are lower. As a consequence, low-concentration regimes are winnowing and bypassing regimes, and the beds deposited are thinner and sandier. Algorithms describing deposition by high and low-concentration regimes have been embedded in a probabilistic model. A simulation of a 400-year sequence of beds deposited by winter storms and floods suggests that on the Eel shelf, the Holocene transgressive systems tract consists of back-stepping, seaward-fining event beds, whose timelines (bedding planes) dip more gently than do their gradational facies boundaries. At these longer time scales, flood beds dominate over storm beds.     

东海陆架中北部沉积物粒度特征及其沉积环境

通过对东海陆架表层沉积物粒级组成、粒度参数、14C年龄和微体古生物组合的综合分析,绘制了东海陆架的沉积物类型分布图;运用Folk等(1970)沉积物分类方法将东海表层沉积物分成砂、粉砂、粉砂质砂、砂质粉砂、砂质泥5种类型,其中粉砂质砂分布最广,砂质泥分布最少;沉积物由陆向海粒度变粗,反映沉积过程中的物源和沉积动力控制作用。根据沉积环境及成因分析,可将东海陆架沉积分为3类:分别是长江口外席状砂沉积区、现代泥质沉积区和陆架中部砂质沉积区。长江口外砂质沉积是全新世冰消期晚期潮流作用及风暴潮流共同作用的产物,是高海平面以来太平洋潮波系统作用下的潮流沙沉积,沙波地貌仍在发生变化。现代泥质沉积区包括长江前三角洲沉积、浙闽沿岸流沉积和济州岛西南泥质沉积三个区域,不同沉积区的成因机制不同。陆架中部砂质沉积是末次冰盛期之后海侵作用下发育的砂质沉积物,在海侵的不同阶段中沉积物被冲刷改造,具有不等时性特征,沉积环境与现代陆架海洋环流的动力特征不一致,现代沉积作用较弱,仅接受悬浮体细粒沉积。     

239,240Pu and137Cs in the East China and the Yellow Seas

The distribution and inventory of artificial radionuclides,^239,240Pu and¹³⁷Cs were determined in the East China and the Yellow Seas in 1987. Almost all of^239,240Pu and 50 to 80% of¹³⁷Cs in the continental shelf area are retained in the sediment column.^239,240Pu sediment inventory in the sea area is larger than the fallout input and tends to increase southwardly. This excess^239,240Pu and the lateral distribution are attributable to the supply of^239,240Pu by the Yangtze River discharge. On the contrary,¹³⁷Cs sediment inventory shows a decrease to the south, and the fact can be accounted for by the southward dispersion of fine silt particles discharged from the Yellow River. Total¹³⁷Cs inventory is smaller than the estimated fallout input, and the fact seems to indicate dispersion of¹³⁷Cs out of the shelf region. Vertical profiles of^239,240Pu and¹³⁷Cs contents in sediments differ from that of natural²¹⁰Pb, implying the effect of varied accumulation rates of the artificial radionuclides over the sediment particle mixing by benthic organisms. Apparent maximum sediment particle mixing coefficient (D _B ) calculated from the excess²¹⁰Pb profiles in stations located between the inner and outer shelves ranged from 1.4 to 8.3 cm²y^–1. ThisD _B value is higher than that in the Okinawa Trough (1.0 cm²y^–1), but lower than previously estimatedD _B value (26 cm²y^–1) in the outer shelf mud.     

A budget for modern‐Holocene sediment on the South Otago continental shelf

A sediment budget for the South Otago continental shelf and coast, between Nugget Point and Otago Peninsula, reveals modern (post 6500 y) sediment input is dominated by the Clutha River (total 3.14 Mt y^‐1; Mt = 10⁶ tonnes). Contributions from the Taieri River (0.6 Mt y^‐1), the adjacent Southland shelf (0.4 Mt y^‐1), and the biogenic production of calcareous shell debris (0.25 Mt y^‐1) account for only 28% of the input. About half of the bedload (sand and gravel) reaching the Otago shelf is stored within a large nearshore sand wedge in the protected waters of Molyneux Bay, off the Clutha River. Bedload that escapes storage (1.1 Mt y^‐1) is transported north‐eastwards to be deposited on beach and inner shelf environments just north of Otago Peninsula. Suspended load (mud) accounts for over half of the sediment input (2.33 Mt y^‐1) and is nearly all transported from the study area to accumulate in north‐easterly shelf and slope depocentres.     

Phosphorus fractionation in surface sediments of the Amazon continental shelf

The aim of this study is to separate various fractions of phosphorus in surface sediments of the Amazon continental shelf and compare them with other areas of the Brazilian shelf. Surface sediments were collected from the river-mouth transect (RMT) and open-self transect (OST). The extraction techniques available in the literature have been used to separate the following forms: Fe-PO₄, Al-PO₄, Ca-PO₄, and associated organic matter. The results indicate that the concentrations of phosphorus are uniform in the study area and may be compared with many other nonpolluted environments. Among the inorganic forms, Ca-PO₄ is dominant in all the samples, and Fe-PO₄ is present in lower concentrations. Al-PO₄ is more significant on the Amazon continental shelf than other parts of the Brazilian coast and other coastal environments of the world.     

A snapshot of suspended sediment and fluid mud occurrence in a mixed-energy embayment, Tijucas Bay, Brazil

Along the southern Brazilian coast, Tijucas Bay is known for its unique muddy tidal flats associated with chenier plains. Previous field observations pointed to very high suspended sediment concentrations (SSCs) in the inner parts of the bay, and in the estuary of the Tijucas River, suggesting the presence of fluid mud. In this study, the occurrences of suspended sediments and fluid mud were examined during a larger-scale, high-resolution 2-day field campaign on 1–2 May 2007, encompassing survey lines spanning nearly 80 km, 75 water sampling stations for near-bottom density estimates, and ten sediment sampling stations. Wave refraction modeling provided qualitative wave energy estimates as a function of different incidence directions. The results show that SSC increases toward the inner bay near the water surface, but seaward near the bottom. This suggests that suspended sediment is supplied by the local rivers, in particular the Tijucas. Near-surface SSCs were of the order of 50 mg l⁻¹ close to the shore, but exceeded 100 mg l⁻¹ near the bottom in the deeper parts of the bay. Fluid mud thickness and location given by densimetry and echo-sounding agreed in some places, although being mostly discordant. The best agreement was observed where wave energy was high during the campaign. The discrepancy between the two methods may be an indication for the existence of fluid mud, which is recorded by one method but not the other. Agreement is considered to be an indication of fluidization, whereas disagreement indicates more consolidation. Wave modeling suggests that waves from the ENE and SE are the most effective in supplying energy to the inner bay, which may induce the liquefaction of mud deposits to form fluid mud. Nearshore mud resuspension and weak horizontal currents result in sediment-laden offshore flow, which explains the higher SSCs measured in the deeper parts of the bay, besides providing a mechanism for fine-sediment export to the inner shelf.     

东海内陆架泥质沉积体研究进展

陆架海现代泥质沉积研究具有重要的地质学、环境科学和气候学意义,数十年来一直受到海洋科学家的关注,尤其是近年来在我国兴起了一股研究陆架泥质沉积体的热潮,取得一大批重要成果。本文对我国最大的东海内陆架泥质沉积体的研究进展进行回顾,作为典型区域呈献给读者。东海内陆架泥质沉积区从长江口水下三角洲向南,沿闽浙近岸浅海一直延伸到台湾海峡中部,全长800km,宽约100km,面积约80000km2,相当于两个台湾岛的大小,实属我国乃至亚洲浅海规模最大(体积排第二)的楔式泥质沉积体和现代沉积区。该区中晚全新世沉积地层厚度较大,局部厚达40—80m,总体上呈近岸厚、向海方向逐渐变薄,一般在50—60m等深线、局部可达75m甚至90m等深线附近尖灭。该区泥质沉积物粒度较细,主要由黏土和粉砂组成(大于90%),砂含量很低(小于10%),黏土和粉砂含量在泥质沉积区外缘急剧降低,而砂含量突然增加。沉积物类型为粉砂质黏土和黏土质粉砂,外侧与黏土-粉砂-砂(混合沉积)或泥质砂为界。粒度分布南北有一定差异,北段(长江口外至瓯江口外)近岸较粗外侧较细,近岸为黏土质粉砂,外侧为粉砂质黏土;而南段(自瓯江口至台湾海峡北部)...     

Sedimentary carbon-isotope systematics on the Amazon shelf

Sedimentary carbon systematics on the Amazon continental shelf were investigated using¹⁴C and ¹³C measurements of sedimentary organic materials. Mass balance calculations indicate that the¹⁴C content of modern shelf muds results from burial of old (~ 5000 yr BP) terrestrial soil carbon and bomb-¹⁴C-enriched marine carbon, implying that most of the bomb-labeled riverine particulate carbon is not buried on the shelf. The¹⁴C signature of Amazon shelf deposits records the effects of both biogeochemical and sedimentary processes active in this dynamic environment.     

Sediment texture,distribution and transport on the Ayeyarwady continental shelf,Andaman Sea

The Ayeyarwady continental shelf is a complex sedimentary system characterized by large sediment influx (> 360 million ton/yr), a wide shelf (> 170 km), a strong tidal regime (7 m maximum tidal range), and incised by the Martaban Canyon. Grain size distribution on the Ayeyarwady shelf reveals three distinct areas in terms of sediment texture (i) a near-shore mud belt in the Gulf of Martaban and adjacent inner shelf (ii) outer shelf relict sands and (iii) mixed sediments with varying proportions of relict sand and modern mud in the Martaban Canyon. The bulk of the terrigenous sediment discharged by the Ayeyarwady River is displaced eastwards by a combination of tidal currents and clockwise flowing SW monsoon current and deposited in the Gulf of Martaban resulting in shoaling of its water depths. Part of the sediment discharge reaches the deep Andaman Sea via the Martaban Canyon and the rest is transported westward into the Bay of Bengal by the counter-clockwise flowing NE monsoon currents.     

Mud volcanoes and gas hydrates in the Black Sea: new data from Dvurechenskii and Odessa mud volcanoes

Meteor cruise M52/1 documented the presence of gas hydrates in sediments from mud volcanoes in the Sorokin Trough of the Black Sea. In a mud flow on the Odessa mud volcano, a carbonate crust currently forms in association with anaerobic methane oxidation. Dvurechenskii mud volcano (DMV), a flat-topped mud pie-type structure, appeared to be very active. Pore water in sediments of DMV is enriched in several constituents, such as ammonium and chloride, which seem to originate at depth. High sediment temperatures of up to 16.5 °C in close contact to the ambient bottom water of 9 °C also suggest strong advective transport of material from greater depth. Steep temperature gradients indicate a high fluid and/or mud flux within DMV, which is confirmed by the shape of the pore water profiles. Active fluid expulsion sites are evidenced by direct seafloor observation, and a potential flux of methane from the sediment to the bottom water is indicated by water-column methane measurements.     

Photoreactivity of chromophoric dissolved organic matter transported by the Mackenzie River to the Beaufort Sea

The photoreactivity of chromophoric dissolved organic matter (CDOM) transported to Arctic shelf environments by rivers has only recently been studied and its quantitative role in Arctic shelf biogeochemistry has received little attention. Sunlight exposure experiments were performed on CDOM collected over a three year period (2002 to 2004) from river, estuary, shelf, and gulf regions of the Western Canadian Arctic. Decreases in CDOM absorption, synchronous fluorescence (SF), and dissolved organic carbon (DOC) concentration were followed after 3 days of exposure, and in two experiments, six optical cutoff filters were used to incrementally remove ultraviolet radiation incident on the samples. Apparent quantum yields for CDOM photobleaching (AQY_ble) and for DOC photomineralization (AQY_min) were computed, as were two AQY spectra (_ble and _min) for the Mackenzie River and a sample from the Mackenzie Shelf. The photoreactivity of Mackenzie River CDOM was highest after break-up and peak discharge and lowest in late summer. The half-lives of CDOM and DOC were estimated at 3.7 days and 4.8 days, respectively, when Mackenzie River water was exposed to full sunlight. Photobleaching of Mackenzie River CDOM fluorescence after most UV-B wavelengths were removed increased the correlation between the river and offshore waters in the Beaufort Sea. When light attenuation from particle- and CDOM-rich river water was considered for the Mackenzie Shelf, our photodegradation models estimated around 10% loss of absorption and < 1% DOC loss, suggesting that sunlight exposure does not substantially degrade CDOM on Arctic shelves.     

The distribution of suspended particles in the Southern Beaufort Sea

The Mackenzie River estuary serves as an avenue for suspended particles to pass seaward. The horizontal distribution of surface suspended particles is compartible with the distribution of low-salinity surface waters. The water structure in the shelf area is highly stratified in summer due to a thin upper layer of low-salinity which has a high concentration of suspended particles. The concentration of suspended particles decreases with depth, but near the bottom a turbid layer had often been observed. It is likely that bottom current energy high enough to erode and maintain in suspension the bottom sediments below 15m in diameter does occur over this shelf area.     

The Shandong mud wedge and post-glacial sediment accumulation in the Yellow Sea

Two well-defined deltaic sequences in the Bohai Sea and in the South Yellow Sea represent post-glacial accumulation of Yellow River-derived sediments. Another prominent depocenter on this epicontinental shelf, a pronounced clinoform in the North Yellow Sea, wraps around the northeastern and southeastern end of the Shandong Peninsula, extending into the South Yellow Sea. This Shandong mud wedge is 20 to 40 m thick and contains an estimated 300 km3 of sediment. Radiocarbon dating, shallow seismic profiles, and regional sea-level history suggest that the mud wedge formed when the rate of post-glacial sea-level rise slackened and the summer monsoon intensified, at about 11 ka. Geomorphic configuration and mineralogical data indicate that present-day sediment deposited on the Shandong mud wedge comes not only from the Yellow River but also from coastal erosion and local rivers. Basin-wide circulation in the North Yellow Sea may transport and redistribute fine sediments into and out of the mud wedge.     

Benthic remineralization at the land–ocean interface: A case study of the Rhône River (NW Mediterranean Sea)

Biogeochemical processes in sediments under the influence of the Rhône River plume were studied using both in situ microelectrodes and ex situ sediment core incubations. Organic carbon (OC) and total nitrogen (TN) content as well as stable carbon isotopic composition of OC (δ¹³C_OC) were analysed in 19 surface sediments to determine the distribution and sources of organic matter in the Rhône delta system. Large spatial variations were observed in both the total O₂ uptake (5.2 to 29.3 mmol m⁻² d⁻¹) and NH₄⁺ release (−0.1 to −3.5 mmol m⁻² d⁻¹) rates at the sediment–water interface. The highest fluxes were measured near the Rhône River mouth where sedimentary OC and TN contents reached 1.81% and 0.23% respectively. Values of δ¹³C_OC ranged from −26.83‰ to −23.88‰ with a significant seawards enrichment tracing the dispersal of terrestrial organic matter on the continental shelf. The amount of terrestrial-derived OC reaches 85% in sediments close to the Rhône mouth decreasing down to 25% in continental shelf sediments. On the prodelta, high terrestrial OC accumulation rates support high oxygen uptake rates and thus indicating that a significant fraction of terrestrial OC is remineralized. A particulate organic carbon (POC) mass balance indicates that only 3% of the deposited POC is remineralized in prodelta sediments while 96% is recycled on the continental shelf. It was calculated that a large proportion of the Rhône POC input is either buried (52%) or remineralized (8%), mostly on the prodelta area. The remaining fraction (40%) is either mineralized in the water or exported outside the Rhône delta system in dissolved or particulate forms.