Karst features discovered during motorway construction in Slovenia

 Major motorway construction is taking place in Slovenia. Almost half the country is karst and many of the new roads are in such terrain. Karst specialists are involved in road design. They explore underground karst systems and suggest how best to preserve the most important ones. These experts also provide advice on ways of protecting karst groundwater and on aspects of road construction in karst. The karst features encountered during construction provide valuable information about the development of karst systems. Received: 8 April 1996 · Accepted: 4 February 1997     

Nitrate temporal and spatial patterns in 12 water-supply wells, Yucatan, Mexico

 The nitrate concentration in 12 water-supply wells were monitored for the period April 1992 to March 1993. Each water-supply well was sampled once a month. The nitrate concentrations in the 12 wells ranged from 7 to 156 mg/l. Two water-supply wells (Chacsinkin and Peto) showed concentrations that reached 3.5 times the maximum permissible limit for the Drinking Water Standard (45 mg/l). A third water-supply well (Akil) exceeds the norm for 7 out of 12 months. The use of nitrogen-rich fertilizers are responsible for high nitrate concentrations in groundwater in the southern part of Yucatan, Mexico where intensive agricultural practices exist. Received: 14 December 1999 · Accepted: 2 May 2000     

Groundwater pollution due to sugar-mill effluent, at Sonai, Maharashtra, India

 Analyses of 126 samples collected from 18 dug wells in the shallow basaltic aquifer over a period of 7 months have revealed spatial as well as temporal changes in the chemical properties of groundwater. While the temporal changes have been attributed to dilution and concentration phenomena governed by climatic factors, the spatial variations in the geochemical characteristics of groundwater appeared to be related to pollution due to effluents from the Mula Sugar Factory. The cause of groundwater pollution is the effluent carried by a stream flowing through the area. Fluctuations in the groundwater table, influent water quality character of the stream, less capacity to accommodate large volume of effluent and occurrence of zero base flow (under natural conditions) in the stream are the factors favoring infiltration of constituents of waste water into the underlying weathered basaltic aquifer. Pollutants have entered into the shallow aquifer by downward percolation through the zone of aeration to form a recharge mound at the water table and, further, lateral movement below the water table. The plume of polluted groundwater has a lateral extent of a few meters in the upstream area and more than 400 m on either side of the stream in the downstream part. The zone of polluted groundwater has an areal extent of more than 3.5 km². Groundwater is the only source available for drinking and agricultural purposes. It is recommended that the base of the lagoons and the stream used for release of plant effluent should be waterproofed for the protection of groundwater in the Sonai area. Received: 30 April 1997 · Accepted: 23 September 1997     

Geochemistry and pollution of shallow aquifers in the Mafraq area, North Jordan

 Chemical data are used to clarify the hydrogeological regime in the Mafraq area in northern Jordan, as well as to determine the status of water quality in the area. Groundwater from the shallow aquifer in the Mafraq area can be divided into two major groups according to geographical locations and chemical compositions. Water in the basaltic eastern part of the study area is characterized by the dominance of chloride, sulfate, sodium, and potassium, whereas waters in the limestone aquifers in the west are dominated by the same cations but have higher concentrations of bicarbonate. Stable isotopes show that the shallow aquifers contain a single water type which originated in a distinct climatic regime. This water type deviates from the Global Meteoric Water Line (MWL), as well as from the eastern Mediterranean meteoric water line. The waters are poor in tritium, and thus can be considered generally older than 50 years. Chemical mass balance models suggest that water is moving from the west towards the north of the study area. This suggests that waters from the different basins are separated from each other. Degradation of water quality can be attributed to agricultural fertilizers in most cases, although the waste-water treatment plant at Khirbet es Samra is a contributor to pollution in the southwestern part of the study area. Received: 20 August 1997 · Accepted: 3 February 1998     

Groundwater quality in the Niva River basin, Chittoor district, Andhra Pradesh, India

 This study was made to assess the groundwater quality in relation to agricultural and domestic uses in a part of the Peninsular Archean granite and gneissic complex of India. Water samples were collected from the existing wells in the Niva River basin, Chittoor district, Andhra Pradesh, India and analysed for major ions. The analytical data, processed and interpreted acoording to the WHO standards, reveal that, in general, the groundwater is suitable for both agricultural and domestic uses, exept in a few locations. High concentration of nitrates were observed in some of the wells (both agricultural and domestic) that are affected by the impact of industrial effluents. Multiple regression analysis was performed and used as a positive predictive tool in understanding the chemistry of the groundwater. Received: 2 May 1996 / Accepted: 14 October 1996     

Groundwater vulnerability assessment of the SW Trans-Danubian Central Range, Hungary

 The most important karst water reservoir of Hungary is found in the SW Trans-Danubian Central Range, selected as test area for the proposed "system approach" and the application of GIS/ARC-INFO to vulnerability mapping. In addition, a case-study exemplifies the particularities of regional karst-aquifer vulnerability, and moreover the interpretation of data and maps from the very same point of view. The work has resulted in plotting an atlas to be a useful tool in the hands of land-users and waste-disposal managers, helping them to prevent groundwater deterioration. Received: 22 July 1996 · Accepted: 12 September 1997     

Groundwater nitrate pollution in an alluvium aquifer, Eskişehir urban area and its vicinity, Turkey

 A large amount of the water requirement (municipal, industrial, etc.) of Eskişehir city, Turkey, is supplied from groundwater via wells in the urban area. The groundwater in the Eskişehir Plain alluvium has been polluted by municipal and industrial wastewater, and agricultural activities. The nitrate concentrations at nine sampling points on Porsuk River, the main water course in the plain, ranged from 1.5 to 63.3 mg/l during the period from July 1986 to August 1988. In the same period, the nitrate concentrations measured in water from 51 wells ranged between 2.2–257.0 mg/l. The nitrate content of the groundwater samples was 34.2% above 45 mg/l, the upper limit for nitrate in drinking water standards. High nitrate levels were observed in water from wells in the central and eastern parts of the urban area. The nitrate content of the well water is subject to seasonal fluctuation. In general, low nitrate concentrations were observed in wet seasons, and high ones in dry seasons. Received: 16 April 1996 · Accepted: 2 October 1996     

Karst water control and management in the Hanxing mining area of North China

 The Hanxing mining area of North China includes three coalfields: Fengfeng, Handan and Xingtai. Six or seven coal seams can be commercially mined in Permo-Carboniferous strata, among which the lower three, accounting for 37% of the total reserves, are threatened with karst water from the underlain Ordovician limestone. Hundreds of water inrush accidents have occurred and over 30 mines have been flooded, resulting in heavy economic losses and casualties. In order to avoid water inrushes and keep the mines safely operational, dewatering in the karst aquifer was considered an essential measure. Unfortunately, this practice has caused serious environmental problems such as surface subsidence (sinkhole), dry spring, and water supply shortage. On the basis of a series of investigations and tests in the last 20 years, an alternative method, mining with water pressure, has been proposed and is the main focus of this paper. By using this method, the karst water in the limestone can be preserved to some extent and the coals can be mined in a relatively safe way. Received: 22 March 1996 · Accepted: 8 April 1996     

Impact of liquid waste disposal on potable groundwater resources near Perth,Western Australia

 Drilling of 15 boreholes at a disused liquid waste disposal site near Perth, Western Australia, has indicated that a contamination plume extends about 1000 m in a southerly direction from the site in the direction of groundwater flow. The plume is up to 600 m wide and 5–40 m thick. Chemical and microbiological analyses have indicated that contaminated groundwater contains high concentrations of ammonia, iron, and bacteria at levels that commonly exceed national drinking water guidelines. It is likely that a proposed water supply production well in the path of the contamination plume will have to be abandoned, and additional wells may have to be abandoned if the plume continues to extend in the direction of groundwater flow. There is currently insufficient information to indicate whether the plume is continuing to expand, but studies on similar plumes in the Perth metropolitan area have indicated that contaminated groundwater can move at rates up to 100 m yr^–1. Several other liquid waste disposal sites are now located in residential areas of Perth where wells are used for garden irrigation. Further work is required to ensure that there is no potential impact of groundwater contamination on public health in these areas. Received: 31 July 1995 · Accepted: 18 September 1995     

Paleocollapse structure as a passageway for groundwater flow and contaminant transport

 Paleocollapse structure is a rock collapse, resulting from the failure in the geological history of the bedrock overlying karstified limestone. Depending on the present hydrogeological conditions within the area of paleocollapse and the internal properties of these structures, they can provide a means to facilitate groundwater flow and contaminant transport. Inactive paleocollapse structures can be reactivated by human activities such as dam construction, mining underground minerals, pumping groundwater, and development of landfills. They can also be reactivated by natural events such as earthquakes and neotectonic movements. In the mines of northern China, sudden inflow of karst water from Ordovician limestone into drifts and mining stopes through paleocollapse structures has caused significant economic loss. Water pumping tests and accompanied dye traces are effective approaches of locating water-conducting paleocollapse structures. Grouting is probably the best means of preventing them from becoming geohazards. Received: 26 November 1996 · Accepted: 17 June 1997     

Geologic controls on porosity development in the Maynardville Limestone, Oak Ridge, Tennessee

 Understanding the geologic controls of porosity development and their relationship to the karst aquifer system in the Cambrian Maynardville Limestone is important in determining possible contaminant transport pathways and provides essential data for hydrologic models within the Oak Ridge Reservation of east Tennessee. In the Maynardville Limestone, several important factors control porosity development: (1) lithologic controls on secondary microporosity and mesoporosity are related to dissolution of evaporite minerals and dedolomitization in supratidal facies; (2) depth below the ground surface controls the formation of karst features because the most active portion of the groundwater system is at shallow depths, and karst features are rare below ≈35 m; and (3) structural controls are related to solution enlargement of fractures and faults. Received: 21 May 1996 · Accepted: 30 August 1996     

The influence of karst features on environmental studies in Turkey

 The carbonate rocks of Turkey, which underlie about one third of the country, possess major water resources with great potential for electricity generation and water supplies. The ongoing development of karst features, especially in the southern part of Turkey, demonstrates specific environmental problems that occur in many karst water supply projects. Karst aquifers, springs, sinkholes, dolines, poljes and other karst features are of great importance from the standpoint of karst water resources and environmental research studies. In karst regions, conservation and protection of groundwater resources for both qualitative and quantitative evaluations is possible only when the catchment area is determined accurately. Since the catchment area in karst terrains is not limited by the surface drainage boundaries and the groundwater flows through well-developed coduits or fissures, the equations used in non-karstic areas cannot be applied to such karstic regions. Studies on the development of karst features and its environmental impacts in Turkey are of recent origin. Therefore, many unreliable methods are being applied in karstic areas. For example, the use of "shallow holes or sinkholes and fault zones" for septic water waste disposal or as sewage by those who are not familiar with karst, sometimes causes very serious problems of extensive groundwater pollution. This paper discusses the development of different karstic features in Turkey and case studies on its environmental impacts. Received: 27 December 1995 · Accepted: 10 July 1996     

The role of karst in the genesis of sulfur deposits, Pre-Carpathian region, Ukraine

 Most of exogeneous epigenetic sulfur deposits are clearly associated with intensely karstified carbonate and sulfate rocks. This paper demonstrates, using the Pre-Carpathian region as an example, that karstification is one of the most important processes controlling the formation of sulfur deposits. This is determined by a coincidence of some major prerequisites of these two processes. In the Podol'sky and Bukovinsky regions the Miocene aquifer system is well drained by erosion valleys; the giant network caves known here in gypsum formed under past artesian conditions. In the region of sulfur deposits, associated with the same karstified gypsum strata, true artesian conditions still prevail. Hydrogeologic data show that abundant cavities detected in the vicinity of sulfur deposits can be interpreted as having the same origin as the fossil caves of the Podol'sky and Bukovinsky regions. The current widespread belief that the gypsum/anhydrite stratum in the region is aquifuge separating the Miocene aguifers is inadequate. This belief caused much controversy with regard to the genetic interpretations of sulfur deposits in the region. Caves formed by the upward water flow through the gypsum/anhydrite stratum govern the water exchange between the aquifers within the aquifer system. A new karst model for the formation of sulfur deposits is suggested. It agrees well with the hydrogeological features of the Miocene sequence and with biogeochemical mechanisms of sulfur origin in low-temperature diagenetic environments. Received: 16 February 1995 · Accepted: 4 June 1996     

Water vulnerability assessment in karst environments: a new method of defining protection areas using a multi-attribute approach and GIS tools (EPIK method)

 Groundwater resources from karst aquifers play a major role in the water supply in karst areas in the world, such as in Switzerland. Defining groundwater protection zones in karst environment is frequently not founded on a solid hydrogeological basis. Protection zones are often inadequate and as a result they may be ineffective. In order to improve this situation, the Federal Office for Environment, Forests and Landscape with the Swiss National Hydrological and Geological Survey contracted the Centre of Hydrogeology of the Neuchatel University to develop a new groundwater protection-zones strategy in karst environment. This approach is based on the vulnerability mapping of the catchment areas of water supplies provided by springs or boreholes. Vulnerability is here defined as the intrinsic geological and hydrogeological characteristics which determine the sensitivity of groundwater to contamination by human activities. The EPIK method is a multi-attribute method for vulnerability mapping which takes into consideration the specific hydrogeological behaviour of karst aquifers. EPIK is based on a conceptual model of karst hydrological systems, which suggests considering four karst aquifer attributes: (1) Epikarst, (2) Protective cover, (3) Infiltration conditions and (4) Karst network development. Each of these four attributes is subdivided into classes which are mapped over the whole water catchment. The attributes and their classes are then weighted. Attribute maps are overlain in order to obtain a final vulnerability map. From the vulnerability map, the groundwater protection zones are defined precisely. This method was applied at several sites in Switzerland where agriculture contamination problems have frequently occurred. These applications resulted in recommend new boundaries for the karst water supplies protection-zones. Received: 27 October 1997 · Accepted: 4 July 1998     

Groundwater pollution in Quaternary aquifer of Vitoria – Gasteiz (Basque Country, Spain)

 As a result of diverse changes in land use and in water-resource management in the high basin of the Zadorra River (Basque Country), an important loss of water resources and an intense contamination by nitrogen compounds has taken place. The purpose of this paper is to detail the land transformations that have taken place on the aquifer since the 1950s: increase of drainage network, change from dry to irrigated farming, and diversion of rivers at the aquifer unit inlet. Furthermore, we analyze the impact of these transformations on the hydrodynamics and water quality of this aquifer system. Received: 12 January 1996 · Accepted: 10 March 1996     

Investigation of groundwater flow in karst areas using component separation of natural potential measurements

 The natural (electrical) potential (NP) method – also known as self-potential, spontaneous potential and streaming potential (SP) – has been used to locate areas of groundwater flow in karst terrane. NP is the naturally occurring voltage at the ground surface resulting from ambient electrical currents within the earth. The measurement of NP can be used to characterize groundwater flow in karst terrane because electrical potential gradients are generated by the horizontal flow of water along fractures or conduits and the vertical infiltration of water into fractures or shafts. NP data from a site on the Mitchell Plain of southern Indiana, USA, revealed that NP data can be decomposed into three components: topographic effect, residual NP and noise. At this site, NP was inversely proportional to elevation, but the correlation varied with time. The topographic correction factor varied from –2.5 to –1.2 mV/m (NP change per unit elevation increase), with an average linear correlation coefficient (R) of 0.95. Because the site slopes toward an adjacent creek that is the local groundwater discharge zone, one possible explanation for this effect is a streaming-potential mechanism generated by groundwater movement toward the creek. The residual NP data revealed three negative anomalies at the survey area. Two of them coincide with sinkholes. A part of the third anomaly is coincident with a small valley, and concentrated infiltration does occur at this elevation in other valleys at the site, as evidenced by the existence of sinkholes. However, the dispersed, low-magnitude nature of the third anomaly does not prove the existence of concentrated groundwater recharge activity. Received: 18 March 1998 · Accepted: 27 April 1998     

Groundwater level and chemistry changes resulting from tunnel construction near Matsumoto City, Japan

 Before tunnel construction began, the groundwater chemical compositions and levels around the tunnel were studied to determine if water compositions could predict whether surface water will be influenced by tunnel construction. When the chemical composition of the well and springwater was similar to that of the tunnel seepage water, and the altitude of the well and spring was above the tunnel level, the groundwater level in the well and spring was influenced by draining tunnel seepage water. Therefore, comparing the chemical compositions of surface water and groundwater may be used for predictive purposes. However, the results of this study showed there was no noticeable chemical composition change in springwater prior to changes in groundwater level at a particular site. The changes in the hydrology of the plateau caused by tunnel construction were also studied, using measurements of the changes in groundwater chemistry as well as changes in groundwater levels. Prior to tunnel construction, river discharge was greater. Following tunnel construction, some river discharge decreased because springwater was drained as tunnel seepage water and the spring in the catchment dried up. Tritium concentration indicated that 3 years after tunnel construction, surface water did not reach tunnel levels in spite of groundwater level lowering and remaining unconfined groundwater being drained. Received: 17 January 1996 · Accepted: 10 July 1996     

Stable-isotopes of groundwaters from the Albuquerque, New Mexico, basin: one decade later

In the spring of 1995, 24 samples were collected from a widely distributed system of municipal water wells in Albuquerque, N.M., and analyzed for hydrogen (δD) and oxygen (δ¹⁸O) isotopic compositions. δD values for 15 of these samples are largely similar to those reported by Yapp in 1985, but have locally become more negative by as much as 5 per mil (ö). δD–δ¹⁸O data define two endmembers that are well aligned along the familiar meteoric water line (MWL): (1) the eastern domain (mountain precipitation runoff), having δD>–86ö (similar to the criteria of Yapp) and δ¹⁸O>–12.1ö (this work); and (2) a central basin domain, which may be in part derived from water seepage from the Rio Grande, having δD<–95ö and δ¹⁸O<–13.2ö. Only a few wells across the basin have δD values near the "baseline" value of the Rio Grande, defined by Yapp as –92ö. The proximity of these wells to the Rio Grande is consistent with recharge by seepage from the river bed under baseline conditions. Extensive pumping in the eastern domain and West Mesa areas may be partly responsible for an apparent expansion of the central-basin regime of water more depleted in δD, much as a plume migrating in response to transient perturbations in original hydraulic gradients. Vertically stacked groundwater occurrences having limited interconnection are inferred from the significant differences in isotopic compositions of samples from two wells screened at multiple depths. The central and western parts of the basin are little influenced by contributions from the eastern domain. Some groundwaters from the western part of the basin plot below the MWL and clearly cannot be mixtures solely of the eastern domain and central basin endmembers. The origins of these western groundwaters and the most depleted central basin groundwaters are as yet unknown, but we speculate they may have received recharge under climatic conditions different from the present.     

Human-induced sedimentological changes in Manzala Lagoon, Nile Delta, Egypt

 The Manzala Lagoon in Egypt's Nile Delta has become a sediment sink of reduced area and depth, with increased contaminant levels. Loss of much-needed fresh to brackish water reserves and decreased fish catches have serious ramifications. Herein, maps of temporal and regional sediment distributions in Manzala incorporate petrological and statistical analyses of 200 surficial and short core samples. These provide baseline information needed to help implement protection measures for this vital wetland. Four periods are considered: 1920s, 1940s, ∼1965, and 1990. Important depositional changes between 1940s and ∼1965 resulted from anthropogenic effects on this quasi-closed lagoon system, including industrial buildup, wetland conversion to agricultural land, and irrigation waterway development. Further modification from ∼1965 to 1990 is associated with closure of the Aswan High Dam, continued construction of waterways that discharge waste water into lagoon margins, and marine incursion into the northern lagoon. If current practices continue, the lagoon could be reduced to about one-third of its present area by 2050 AD. Received: 2 October 1997 · Accepted: 13 January 1998     

Chernobyl radiocaesium in a karst system,Marble Cave,Crimea

 Surface contamination with radioactive caesium introduced into the environment after the accident at the Chernobyl nuclear plant was high enough in the Crimean Mountains to allow using radiocaesium as an indicator of penetration of radioactive contamination into a karst system. Caesium concentrations have been studied in soils above Marble Cave, Tchatyrdag Plateau, in percolation waters and in sediments transported by percolation waters within the cave. Contamination of the daylight surface with ¹³⁷Cs is about 30 kqB m^–2 which is approximately 13 times higher than the density of global fallouts. Besides ¹³⁷Cs, almost all samples showed presence of ¹³⁴Cs with the ¹³⁷Cs/¹³⁴Cs ratio close to that of Chernobyl contaminations. Concentrations of ¹³⁷Cs range from 9 to 15 mBq l^–1 in the present percolation waters in the cave. In sediments related to percolation waters ¹³⁴Cs is detected in some samples besides ¹³⁷Cs, although the effect of ²²⁸Ac is not ruled out. Surprisingly, the highest concentrations of radiocaesium were measured in "old" sediments in the cave's lower series. These sediments are not associated with modern percolation and are represented by a clay/moonmilk alternating sequence deposited in an old dried cave lake. Moonmilk layers have higher caesium content than clay. It is assumed that Chernobyl caesium was transported into the cave with aerosols which were then deposited mainly in areas where condensation occurs. The sampling site is located just in the boundary between two microclimatic zones with a temperature gradient of 0.5  °C. Active condensation processes occur in this area. Caesium was not detected in another similar sampling site (old lake deposits) located within homogeneous microclimatic conditions. If the above interpretation is correct, these results show the geochemical significance of the aerosol-condensation mechanism of mass transport and localisation. Received: 1 June 1995 · Accepted: 4 December 1995