Hydrogeochemistry of Roccamonfina volcano (Southern Italy)

This is the first hydro-geochemical investigation carried out on the Roccamonfina Volcanic Complex groundwaters. The chemistry of Roccamonfina waters is defined by water–rock and water–rock–gas interactions. In fact, interactions between rocks of the first eruptive high-K formations and circulating groundwaters are recognized by high K concentrations. On the other hand, inverse concentration of calcium versus alkali metals is related to two different rock interactions occurring in different areas of the volcano: (a) within the caldera where groundwaters flow within latite and pyroclastic formations releasing calcium, and (b) similarly at the base of the volcano where groundwaters flowing from surrounding carbonates got strongly enriched in Ca. These geochemical processes are also associated with K (SE of caldera) and Mg/Ca (in sites located at the NE base of the volcano) decrease. Completely different dynamics occurs at Riardo groundwaters (SE). Here waters are the result of a mix between the Roccamonfina deep aquifer and the carbonate aquifer of the Riardo plain. Rich-CO₂ emissions make these waters strongly mineralized. Minor elements show a similar geochemical behavior of major ions and are crucial defining interactions processes. The evolution of Roccamonfina groundwaters is also evident along the simultaneous enrichment of Ba, Sr, and Ca. Ba increase is the result of deep local carbonate alteration enhanced by CO₂ emissions and, the lower Sr/Ca ratio, from 10 to 2 (ppb/ppm), is also due to the same process. In the light of our results the Roccamonfina aquifer can be schematically divided into two main reservoirs: (a) a superficial aquifer which basically follows the volcanic structure morphology and tectonics and (b) a deeper reservoir, originating within the oldest Roccamonfina volcano ultra potassic lavas and then flowing into the carbonate aquifers of the neighboring plain. Eventually, the chemistry of the Roccamonfina aquifer does not show any specific and visible pollution, contrary to what happens in the volcano surrounding plains. In fact, only 14% of the samples we collected (206) show a NO₃ content >30 mg/l. These sites are all located at the base of the volcano, near the plain.     

Trace-element behavior during weathering of leucite in potassic rocks from the Roccamonfina volcano (Campania, southern Italy) and environmental implications

Trace-element contents in leucite and its alteration mineral phases from the Quaternary potassic rocks of the Roccamonfina volcano have been determined. The dominant weathering phase of leucite is analcite. In the early stages of the conversion process, it concentrates mainly Rb and Sr with minor amounts of Ba, Ni, V, Zn, La, Ce and Zr. At more advanced stages of the conversion process, only Rb and Y persist, while all other elements (except Cu and Cr that are essentially immobile) are lost, particularly Zn and to a lesser extent La, Ce and Nd. Besides analcite, leucite may also subordinately alter to halloysite. This probably occurs by interaction of waters of low cation/H⁺ ratio. Halloysite concentrates mainly Sr and, to a lower extent, Ba. Environmental implications are significant only for K, as the release of this element to groundwaters increases greatly the fertility of soils.     

Low VS crustal zones in the Campanian Plain (Southern Italy)

Shear wave velocities of the lithospheric structure to 73 km depth have been defined along three profiles crossing the Campanian Plain (Southern Italy) from the simultaneous non linear inversion of the local and regional dispersion data. The former consist of group velocity dispersion data obtained from some seismic events which occurred at the borders of the Campanian Plain and recorded at Napoli, and the latter of group and phase dispersion data obtained in previous studies. The main features of the representative V_S models are a carbonate basement deepening to ～5 km in the central part of the Plain and a low velocity zone at a depth of ～15 km, rising to 7 km in the southern part, close to Somma-Vesuvio. The low velocity layer can be correlated with that found at ～10 km of depth below Campi Flegrei and the Neapolitan area, and at 5 km below the Somma-Vesuvio caldera area. Such regional velocity reduction can be associated to the presence of a zone with less than 5% partial melting that can be interpreted as magmatic reservoir of the Campanian volcanism.     

On the devil's tracks: unexpected news from the Foresta ichnosite (Roccamonfina volcano,central Italy)

The Foresta ichnosite is well known for preserving some of the oldest human fossil footprints recorded in Europe so far. This research aims to: i) describe new footprints that are larger than those already reported, some of which form a new trackway that moves in the opposite direction to all the others; ii) announce the discovery of some stone tools also in the surroundings of the Foresta ichnosite. The new results increase the total number of human fossil footprints to at least 81, specify the direction and the number of footprints of Trackway C, and identify three new directions of walking at the site. More compelling and complete estimates of the dimensional range of all ichnological evidence enables us, furthermore, to estimate the number of trackmakers walking on the trampled surface as a minimum of five, one of them likely being an adult male. The general shape of all the recorded footprints suggests that the Foresta trackmakers share some similarities with those at Sima de los Huesos, and belong to the same taxonomical group as the Ceprano skull. All the new evidence enables us to better understand the presence of hominin populations in the Roccamonfina volcano area during the Middle Pleistocene. © 2020 John Wiley & Sons, Ltd.     

Three-dimensional earthquake locations and upper crustal structure of the Sannio-Matese region (southern Italy)

The Sannio-Matese region is one of the most seismically active regions of Italy and has been struck by large historical earthquakes. At present, the area is characterized by low magnitude background seismicity and small seismic sequences following M4 main events. In this paper, we show Vp and Vp/Vs models and 3D locations for a complete set of earthquakes occurring in the period 1991–2001. We observe a significant crustal heterogeneity, with large scale east-verging high Vp fault-related-folds, stacked by the Pliocene compression. The relocated earthquakes cluster along a 70° east-dipping, NW-striking plane located at the border of the high Vp thrust units. Normal fault earthquakes related to the young and active extension occur within these high Vp zones, interpreted as high strength material. We expect large future earthquakes to occur within these high Vp zones actually characterized by low magnitude seismicity at their borders.     

Intractions of mantle and crustal magmas in the southern part of the Ivrea Zone (Italy)

In the southern part of the Ivrea Zone (Italy), the majority of the Mafic Formation is composed of: 1. amphibole-bearing gabbro; 2. a series of rocks ranging from norites to charnockites; 3. leucocratic charnockites. In the proximity of metasedimentary septa within the Mafic Formation, the igneous lithologies are in many places intimately and chaotically intermingled, giving rise to a marble-cake structure. Whole-rock chemistry, and oxygen and strontium isotopic compositions indicate that the mafic and felsic rocks are dominated by mantle and crustal sources respectively. The norite-charnockite suite may be modelled as the mixing product of basic and acid melts. Abundant plastic deformation structures suggest that mafic and hybrid rocks experienced an important tectonic event during or soon after their crystallization. Melting of crustal country rocks continued after the deformation event and produced the undeformed leucocratic charnockites. The study area exemplifies some of the possible effects of the intrusion of a large volume of basic magma into hot crust.     

The Brown Leucitic Tuff of Roccamonfina Volcano (Roman Region,Italy)

The Brown Leucitic Tuff (BLT) is a poorly to strongly lithified compositionally zoned pyroclastic-flow deposit with a minimum volume of 3 to 5 km³. It erupted from Roccamonfina Volcano about 385000 years ago, after formation of the summit caldera. Individual flow units are grouped into three facies (white, brown, and orange) which primarily differ in pumice color, lithic content, and matrix cementation. Pumices from the BLT range from phonolitic leucite-tephrites to leucite-trachytes (7.0 to 2.2 wt% CaO), covering over half of the total spectrum of High-K Series magmas known from Roman Region volcanoes. White-facies units dominate in lower stratigraphic levels and their pumices have the lowest CaO contents, indicating a general trend toward more basic compositions as the eruption evolved. At higher stratigraphic levels, however, orange- and brown-facies units are interbedded with other whitefacies units, indicating reversals in the dominant compositional progression.BLT pumices have crystal contents of 9.9 to 0.6 vol%, with green salite>plagioclase>sanidine>biotite>titanomagnetite>analcime (after leucite)>apatite>pyrrhotite. In most samples, plagioclase (An_85–95) and sanidine (Or_75–90) have much lower Na₂O contents than usually found in coexisting feldspars, yet these are interpreted as equilibrium pairs. Primary leucite has been almost completely replaced by analcime. All samples also contain xenocrysts of colorless diopside and forsteritic olivine (Fo_83–92). Recurrent alternations from colorless diopside to green salite are present in single clinopyroxene crystals and appear to reflect a complex history of magma mixing.Whole-rock BLT pumice compositions conform closely to High-K Series lavas from Roccamonfina for all elements except Na₂O and K₂O. The former is relatively enriched and the latter relatively depleted in mafic BLT pumices with >5.6% CaO; these differences reflect strong analcimization of abundant groundmass leucite crystals in these pumices. Otherwise, major and trace element data support fractionation of observed minerals in generating the compositional diversity among BLT pumices. Mineral assemblages and compositions of cumulate monzonite and syenite nodules carried to the surface during the BLT eruption correspond closely to the fractionated phases predicted by least-squares modeling.     

The white trachytic tuff of Roccamonfina Volcano (Roman Region,Italy)

The White Trachytic Tuff (WTT) is a compositionally-zoned, trachytic, pyroclastic-flow deposit which erupted from Roccamonfina volcano about 300,000 years ago. It was principally emplaced as unwelded, pumice-rich flow units with an estimated volume of 10 km³. These now cover the flanks of the volcano on all sides except the west, behind the highest rim of Roccamonfina's summit caldera; the caldera was probably in existence prior to the WTT activity. Eruption of the WTT generally initiated the leucite-free, second stage of Roccamonfina's development, following a long history of leucite-bearing volcanism, but minor leucite-bearing lavas and pyroclastics overlie the WTT as well. The WTT was in turn followed by progressively more basic, leucite-free magmas (latite, trachybasalt, and basalt). During the course of the eruption, the WTT evolved from white, crystal-poor pumices containing 66% SiO₂ and 1.2% CaO, to grey pumices containing higher crystal contents, 60% SiO₂, and 3% CaO. Early pumices are also relatively enriched in Mn, Na, Zn, Ga, Rb, Y, Zr, Nb, Cs, La, Ce, Yb, Lu, W, Hf, Th, and U, and depleted in Ti, Fe, Mg, K, Sc, V, Cr, Co, Sr, Ba, Nd, Sm, Eu, Tb, Dy, and Ta. The pumices are essentially bimodal in composition, with several minor intermediate types including megascopic, physical mixtures of the white and grey varieties. Certain WTT pumices, including all analyzed intra-caldera samples, are relatively enriched in Pb, Th, Zr, Rb, Ga, Zn, and Cs compared to the rest of the suite. These enrichments may reflect local assimilation of carbonates or more complex exchange processes at the magma chamber margin. All WTT pumices contain the phases sanidine, plagioclase, clinopyroxene, biotite, titanomagnetite, sphene, and apatite; grey varieties also contain magnesian olivine crystals which are probably xenocrysts. The white, crystal-poor types show relatively simple mineralogies with little compositional variability or zoning among crystals of a single phase. Other pumice types, and dark, trachyandesitic inclusions separated from white pumices, show a large compositional spectrum of individually homogeneous crystals. These compositionally diverse crystals and inclusions are interpreted as a result of widespread mixing between the trachytic magmas and more basic magmas prior to or during the WTT eruption. Major-element crystal-fractionation models can successfully derive the early trachytes from the late trachytes by 50–85% separation of a syenitic assemblage of all phases. The predicted phase proportions and compositions closely match cumulate syenite nodules found at Roccamonfina. Trace element models are permissive of syenitic fractionation within the large uncertainties allowed by published partition coefficients.     

Long-term uplift rate of the Etna volcano basement (southern Italy) based on biochronological data from Pleistocene sediments

The eastern flank of Mt. Etna volcano rests on Pleistocene marine sediments, which unconformably cover the Apenninic–Maghrebian Chain units. A quantitative biostratigraphic analysis was carried out based on the calcareous nannofossil content of the Pleistocene deposits outcropping along the S and NE periphery of the volcano. Sediments were constrained to the MNN19e and MNN19f biozones, deposited from 1.2 to 0.589 Ma. According to the depth of deposition and the present altitude of the Pleistocene succession, uplift rates are estimated between 1.1 and 1.7 mm yr⁻¹ for the northeastern sector of the Etna edifice, and between 0.36 and 0.61 mm yr⁻¹ for the southern one. This inhomogeneous long-term uplift rate affecting the Etna region, probably results from a buried thrust below the northern flank of Etna, which is related to the post-Tortonian geodynamic evolution of NE Sicily.     

The primitive lavas of Roccamonfina volcano,Roman region,Italy: new constraints on melting processes and source mineralogy

Within a large collection of lavas from the Roccamonfina volcano are rocks which represent the most mafic samples yet recorded from Roccamonfina and which are amongst the least differentiated lavas found in the Roman co-magmatic region as a whole. These rocks extend both high-K and low-K series to more primitive values. However, petrographic and geochemical considerations rule out a primary origin, and even these mafic samples appear to record the effects of repeated episodes of fractional crystallization and hybridization. Relatively potassic samples from the low-K series are apparently transitional between low-K and high-K series, as previously delineated. However, these intermediate-K samples are not transitional in their Sr isotopic composition, suggesting that there is no continuum between low-K and high-K magma source regions. Rather, the compositional range within the low-K series appears predominantly to reflect variation in the degree of melting of a common mantle source. Analysis of the low-K series data, using an inverse method suggests a source containing amphibole and garnet, and indicates that these phases were consumed during the melting processes responsible for the low-K series magmas. The role of amphibole is further indicated by the association of low K₂O with elevated Rb concentration and, for example, higher Ce/Yb. Such variations are taken to reflect the consumption of high K/Rb amphibole during the initial phase of partial melting.     

Research progress in volcanology in the Neapolitan area, southern Italy: a review and some alternative views

Comprehensive reviews are given for the major volcanic systems that occur in the greater metropolitan area of Naples, southern Italy; Mt. Somma-Vesuvius to the east and the Campi Flegrei volcanic system to the west. Also included in the review is a detailed discussion of the large, highly explosive Campania Volcanic Zone (CVZ) ignimbrite events. These volcanic areas have been studied for more than 100 years, yet significant differences of opinion exist related to fundamental issues of origin and distribution. We present some alternative views related to petrogenesis on some issues based on more than 25 years of research. The relationship between risk assessment and management that impacts the threatened society or culture and the past and ongoing fundamental volcanological research is an essential part of the science. Countries with limited resources may be forced to accept an increased risk but even highly industrialized societies may not be able to completely eliminate deaths from volcanic eruptions. Scientific studies of the hazardous regions should be comprehensive and include reasonable alternative interpretations as this information reveals the level of confidence that must be conveyed to the public officials. The authors review the state of the art of risk assessment and management of the volcanic hazards in the Neapolitan region in light of the review of research.     

Fluorine speciation in topsoils of three active volcanoes of Sicily (Italy)

Fluorine is one of the many environmental harmful elements released by volcanic activity. The content of total oxalate-extractable and water-extractable fluorine was determined in 96 topsoils of three active volcanic systems of southern Italy (Mt Etna, Stromboli and Vulcano). Total fluorine (F) content (F _TOT) ranges from 112 to 7,430 mg kg⁻¹, F extracted with oxalate (F _OX) ranges from 16 to 2,320 mg kg⁻¹ (2–93% of F _TOT) and F extracted with distilled water ( ) ranges from 1.7 to 159 mg kg⁻¹ (0.2–40 % of F _TOT). Fluorine in the sampled topsoils derives both from the weathering of volcanic rocks and ashes and from the enhanced deposition due to volcanic gas emissions either from open-conduit passive degassing (Mt Etna and Stromboli) or from a fumarolic field (Vulcano). Fluorine accumulation in the studied soils does not generally present particular environmental issues except for a few anomalous sites at Vulcano, where measured contents could be dangerous both for vegetation and for grazing animals.     

Geodetic techniques applied to the study of the Etna volcano area (Italy)

Volcanic behaviour of Mt. Etna is due to the complex interaction between both the local and the regional stress field involving the eastern Sicily. Eruptions could trigger (be triggered?) during crust extension and/or compression, which are strictly linked with the dynamics of the lower mantle. In this study, very long baseline interferometry (VLBI) space geodesy technique has been used in order to study Etna volcano’s activity by means of the crustal deformations between Noto and Matera (located on the African and the Eurasian Plates, respectively). By analysing VLBI data, we obtained the behaviour of the baseline which crosses the Etnean area, from 1990 December to 2003 March, representing the time variations of the distance between the two geodetic stations; the linear trend of the baseline shows a general increasing, pointing out an extension of the crust between them. A detailed analysis of the Noto-Matera baseline allows the identification of three parts of the VLBI curve in the considered period. In the first part of the curve (from 20/12/90 to 09/02/94), VLBI data are rather poor and therefore no reliable consideration about correlation between crust movements and volcanic and seismicity activity has been made. In the second part of the curve (from 09/02/94 to 04/09/00), VLBI data are more frequent and show slightly fluctuations in the distance. Increasing in the extension and compression were observed in the central and in the final part of this period. In the third period (from 04/09/00 to 25/03/03), VLBI data are very sparse even if the time series was quite long; therefore, to fill gaps in the information, we analysed global positioning system (GPS) data. GPS technique performs continuous observations, and we were able to highlight both extensions and compressions in detail. Comparisons between the trend of Noto-Matera baseline length variations, volcanic activity and seismicity in the Etna area show the complexity of the development over time and space of the phenomenology determined by a deep cause which can be traced, in our opinion, to the interaction between the asthenospheric mantle, deep crust and surface crust. Therefore, we state that crustal distension and compression are determined by the lower pulsating mantle.     

Recent crustal movements in the southern Black Forest (western Germany)

Precise levelling data are examined in the southern Black Forest massif by comparing them analytically along levelling profiles. Instead of generalizing regional vertical motion trends, the method emphasizes the current activity of accurately located individual structural elements. Measured recent crustal movement rates range from 0.2 to 1.1?mm/year for the 1930–1961 (1972) period, the inferred motions corresponding to aseismic fault creep. Based on the near infrared band image of a Landsat MSS scene, a lineament map of the study area is compared with the recent crustal movement (RCM) map. The Upper Rhine graben eastern border fault between Badenweiler and Freiburg displays the highest RCM: these displacements are consistent with the geological motion and the topographic expression of that structure. Within the massif, both the lineament map and the RCM map demonstrate the predominant role played by WNW/ESE- to NW/SE-striking structures in accommodating the deformation. Moreover, with the seismic dislocations in the southern Black Forest taking place also mainly on N120 and N20 faults, it is most probable that these active structures are deep-reaching zones of crustal weakness. To some extent, seismicity and RCM appear, however, to be mutually exclusive in their spatial distribution, the seismic Black Forest flexure and Dinkelberg block being opposed to the aseismically moving eastern and northern parts of the study area.     

Depth and modes of Pliocene–Pleistocene crustal extension of the Apennines (Italy)

Since early Pliocene times the Apenninic chain has been dissected by normal faults propagating towards the Adriatic foreland. In the Tyrrhenian Sea extension involved deep crustal sections, whereas in the 'Central Apennines Downfaulted Area' it affected the shallow crust. The Tyrrhenian back-arc domain is connected to the overall flexural retreat of the Adriatic–Apulia plate in front of the Apenninic collisional wedge. In the outer Apenninic belt thin-skinned delamination and gravitational collapse occurred in the hanging wall of a thickened wedge, overthrusting the uplifted, buoyant crust of the Apulia foreland. Differential sinking velocity of the foreland plate results from the inherited competence contrast between the rigid Gargano–Apulia carbonate platform to the south, and the low-competence lithology of the pelagic sequence of the Adriatic basin to the north. During late Messinian–early Pliocene times this palaeogeographical boundary acted as a lithospheric tear, separating segments of the Apulia plate subjected to different subduction modes.     

Tectonics of the Dolomites (southern alps,northern Italy)

In post-Variscan times the Dolomites underwent a number of tectonic events, which may be summarized as follows: Permian and Triassic rifting phases broke the area into NS trending basins with different degrees of subsidence. A Middle Triassic transpressive event then deformed the region along a N70°E axis, generating flower structures within the basement. Volcano-tectonic domal uplift and subsequent caldera formation occurred at the same time as the Late Ladinian magmatism. Early Jurassic rifting also controlled the subsidence which increased eastward. This long period of deformation was followed by a pre-Neogene (Late Cretaceous-Palaeogene ?) EW (ENE-WSW) compression which generated a W-vergent belt, possibly equivalent to the folded foreland of the Dinaric chain. A 70 km EW section of the Dolomites indicates shortening of at least 10 km. During the Neogene the Dolomites, as far north as the Insubric Lineament, were the innermost part of a S-vergent thrust belt: the basement of the Dolomites was thrust southwards along the Valsugana Line onto the sedimentary cover of the Venetian Prealps for at least 10 km. This caused a regional uplift of 3–5 km. The Valsugana Line and its backthrusts on the northern side of the central Dolomites generated a 60 km wide pop-up in the form of a synclinorium within which the sedimentary cover adapted itself mainly by flexural-slip often forming triangle zones. The shortening linked to this folding is about 5 km with Neogene thrusts faulting and folding pre-existing thrust-planes. On the north-eastern side of the Dolomites, Neogene deformation is apparently more strictly controlled by the transpressive effects of the Insubric Lineament and shortening of the sedimentary cover may be greater than in the central Dolomites. Minor deformation linked to the Giudicarie belt is present in the western Dolomites. The present structure of the Dolomites is thus the result of a number of tectonic events of different significance and different strike. Only a 3-dimensional restoration can unravel the true structure of the Dolomites.     

Carboniferous convergence and subsequent crustal extension in the southern Schwarzwald (SW Germany)

Abstract

Detailed structural analysis in the southwestern part of the Variscan Sehwarzwald Massif (SW Germany) indicates polyphase, synmetamorphic deformation in ductile shear zones. The tectono-melainnrphir evolution is characterized by orogenic crustal shortening and subsequent late- orogenic crustal extension in Carboniferous times. Convergence is responsible for an KSK trending, north dipping thrust zone with intense deformation in orthogneissic S-C type mylonites Superposed on schistose and folded metasediments presumably lower Carboniferous in age. Southeastward thrust-’“g parallel to pervasive stretching lineation, similar to the pre-dominant oblique convergent structures ill the central part of the massif, is related to crustal stacking. Relations of early granite intrusions with the outlasting retrograde tectonics Point to a Lower Carboniferous (Late-Visean) age of shortening.

Subsequent crustal extension is indicated by a broad N-S trending and west dipping ductile shear zone within high grade meetamorphic (I1T7LP) gneisses. Retrograde stretching lineatone marked by sillimanite to chlorite anr consistent with a top-to-the-west shearing on the western flank of a large progressively warping domai structure. Intensely sheared and boudinaged granitic rocks are syn-tectonic and seal the age of extension at about 325 Ma (Lower/ Upper Carboniferous boundary). During progressively cataclastic stages of tectonic denudation the still active detachment controlled formation of an adjacent late Paleozoic (Stephano-Pcrniian) continental basin supersedding high-grade gneiss. As elsewhere in the Varisean belt, the late extensional process in the tectono-”“‘tainorphie evolution of the southern Sehwarzwald is related rapid uplift, exhumation and thinning by a gravitational collaps of a previously thickened crust.     

Extreme-Mg olivines from venancite lavas of Pian di Celle volcano (Italy)

Olivines with a forsterite minal of up to 99.5 mol % were discovered in ultra-potassium lavas of Pian di Celle volcano (Italy). Based on high-precision analyses of these olivines and the available literature data, a new type of extreme-Mg olivines with a forsterite content of >96 mol % was distinguished. These olivines could have formed as a result of oxidation of lower Mg olivines, crystallization from the carbonatite melt, or they may represent earlier crystallized phenocrysts in skarn. Oxidized olivines are easily diagnosed on the content of typomorphic admixtures, in particular, high MgO and NiO contents. It is difficult to recognize olivines from skarns and carbonatites due to the lack of high-precision analytical data. Extreme-Mg olivines from Pian di Celle (Italy) are close to the carbonatite subtype of olivines.