Composition of brines in halite‐hosted fluid inclusions in the Upper Ordovician,Canning Basin,Western Australia: new data on seawater chemistry

Analyses of primary and early diagenetic fluid inclusions in the halite from the Late Ordovician Mallowa Salt, Canning Basin, Western Australia indicate a Ca‐rich composition and high concentration of parent brines in the basin which were close to sylvite and carnallite precipitation. The salt‐bearing series in the sampled interval was overheated up to 62 °C. The recorded differences in gas compositions result from the input of several gas sources including dispersed organic matter in the salt series and hydrocarbon deposits in the underlying rocks. The high concentration of the brines in fluid inclusions does not allow quantitative reconstruction of the chemical composition of Late Ordovician parent seawater. Using the information from Early Cambrian and Late Silurian basins as a proxy, however, the new data indicate that Late Ordovician seawater was undoubtedly Ca‐rich and, in comparison with modern seawater, had a similar K content, considerably lower Mg content (c. 30%), approximately three times the Ca content and one‐third the SO₄ content.     

Halite cementation and carbonate diagenesis of intra-salt reservoirs from the Late Neoproterozoic to Early Cambrian Ara Group (South Oman Salt Basin)

Late Neoproterozoic to Early Cambrian carbonates of the Ara Group form important intra‐salt ‘stringer’ reservoirs in the South Oman Salt Basin. Differential loading of thick continental clastics above the six carbonate to evaporite cycles of the Ara Group led to the formation of salt diapirs, encasing a predominantly self‐charging hydrocarbon system within partly highly overpressured carbonate bodies (‘stringers’). These carbonates underwent a complex diagenetic evolution, with one stage of halite cementation in a shallow (early) and another in a deep (late) burial environment. Early and late halite cements are defined by their microstructural relationship with solid bitumen. The early phase of halite cementation is post‐dated by solid reservoir bitumen. This phase is most pervasive towards the top of carbonate stringers, where it plugs nearly all available porosity in facies with initially favourable poroperm characteristics. Bromine geochemistry revealed significantly higher bromine contents (up to 280 p.p.m.) in the early halite compared with the late halite (173 p.p.m.). The distribution patterns and the (high) bromine contents of early halite are consistent with precipitation caused by seepage reflux of highly saturated brines during deposition of the overlying rock salt interval. Later in burial history, relatively small quantities of early halite were dissolved locally and re‐precipitated as indicated by inclusions of streaky solid bitumen within the late halite cements. Late halite cement also seals fractures which show evidence for repeated reopening. Initially, these fractures formed during a period of hydrothermal activity and were later reopened by a crack‐seal mechanism caused by high fluid overpressures. Porosity plugging by early halite cements affects the poroperm characteristics of the Ara carbonates much more than the volumetrically less important late halite cement. The formation mechanisms and distribution patterns of halite cementation processes in the South Oman Salt Basin can be generalized to other petroliferous evaporite basins.     

Using sedimentology to address the marine or continental origin of the Permian Hutchinson Salt Member of Kansas

The Permian Hutchinson Salt Member of the Wellington Formation of the Sumner Group of Kansas (USA) has multiple scientific and industrial uses. Although this member is highly utilized, there has not been a sedimentological study on these rocks in over 50 years, and no study has investigated the full thickness of this member. Past publications have inferred a marine origin as the depositional environment. Here, this marine interpretation is challenged. The goals of this study are to fully document sedimentological and stratigraphic characteristics of the Permian Hutchinson Salt Member in the Atomic Energy Commission Test Hole 2 core from Rice County, Kansas. This study documents colour, mineralogy, sedimentary textures, sedimentary structures, diagenetic features and stratigraphic contacts in core slab and thin sections. The Hutchinson Salt Member is composed of five lithologies: bedded halite, siliciclastic mudstone, displacive halite, bedded gypsum/anhydrite and displacive gypsum/anhydrite. These lithologies formed in shallow surface brines and mudflats that underwent periods of flooding, evapoconcentration and desiccation. Of note are the paucity of carbonates, lack of marine-diagnostic fossils, absence of characteristic marine minerals and lithofacies, and the stratigraphic context of the Hutchinson with associated continental deposits. The Hutchinson Salt Member was most likely deposited in an arid continental setting. This new interpretation offers a refined view of Pangaea during the middle Permian time.     

蔡希斯坦盆地二叠纪钾盐成矿条件和资源开发利用

笔者对德国几个在产钾盐矿山实地考,察以及与德国钾盐研究机构的技术交流,并结合大量文献资料,对德国钾盐地质条件、开发现状以及开采技术的发展进行综述,为国内找钾和钾盐的综合开发利用提供借鉴。德国钾盐产于上二叠纪蔡希斯坦盆地(Zechstein Basin),位于相对稳定的陆块浅海陆架区,主要通过浅陆棚阶段和次深陆棚阶段形成。蔡希斯坦盆地已识别出8个盐沉积旋回(Z1-Z8),每个旋回的沉积方式大致相同,沉积层序自下而上通常为:碎屑岩→碳酸盐→硬石膏→岩盐→钾盐层→硬石膏顶板。德国二叠纪超大型钾盐盆地的发现,表明海相沉积盆地是地球的可溶性钾盐主要储存库,印证了海相钾盐常形成于次盆地中。同时,通过对钾盐层顶底板和钾盐样品的化学分析,研究特定元素(Br、Rb)的变化,作为国内找钾的指标。钾盐的开采主要分为旱采法和水采法2种,传统上以旱采法为主,但随着技术的进步,水采法相对旱采法有诸多优势。     

溴的地球化学习性及其在四川找钾工作中的应用

溴随海水蒸发成盐发展进程,于固液相中的分布会不断提高,呈线型函数关系。石盐中的 Br·10~3/Cl 值与戍化阶段关系密切,具有找钾标志意义;可判别石盐的海、陆相和原、次生成因及进行盐系韵律划分对比。在四川盆地三叠系成钾预测应用中取得了相应的效果,提供了找钾线索及工作范例。     

Phanerozoic history of Western Australia related to continental drift

From north to south, the sedimentary basins of Western Australia change from broad platforms of wholly marine strata that span the entire Phanerozoic (Bonaparte Gulf and Canning Basins) through the intermediate Carnarvon Basin to rifts of nonmarine Permian and Mesozoic strata (Perth Basin). These contrasts in age, facies, and structure reflect different positions of the basins in Gondwanaland: the Bonaparte Gulf and Canning Basins have lain at the continental margin facing an open ocean during the entire Phanerozoic, whereas the Perth Basin lay in the interior of Gondwanaland until India and Australia moved apart in the Cretaceous.

The Eucla Basin came about by events connected with the dispersal of Antarctica and Australia in the Eocene. The northwest part of the Australian Block (Timor and the Timor Sea) was deformed in the Miocene when Australia collided with southeast Asia.     

滨里海盆地的岩相古地理特征及其演化

滨里海盆地内充填了巨厚的古生代、中生代和新生代沉积物。在剖面上可分为三套地层组合，即盐下层系、含盐层系和盐上层系。盐下层系为下古生界-下二叠统，包括巨厚的碎屑岩和碳酸盐岩沉积，在泥盆纪-早二叠世，滨里海盆地周缘广大地区普遍发育碳酸盐岩，在许多古隆起上还发育生物礁体，说明这一时期盆地的滨、浅海地带具有浅、清、暖的沉积环境，盆外陆源碎屑供应较少。含盐层系为下二叠统上部孔谷阶。早二叠世中-后期由于持续构造抬升，盆地气候变得干旱，海水变浅，潮上带蒸发环境发育，以致这一时期广泛发育盐类沉积，形成含盐层系，主要由盐岩和硬石膏层构成，并形成许多大小不等的盐丘构造。盐上层系为上二叠统-第四系。晚二叠世-三叠纪盆地又经历了一次大的海侵，为浅海陆棚环境，局部为海陆过渡三角洲相。侏罗纪-白垩纪在总的浅海陆棚环境下，盆地不同地区也形成了湖泊和瀉湖环境。晚二叠世以后形成的盐上层系沉积，主要为碎屑岩，在局部地区有碳酸盐岩。     

Salt Crystallization Sequences of Nonmarine Brine and Their Application for the Formation of Potassium Deposits

The salt assemblages precipitated during evaporation of concentrated brine collected from Gasikule Salt Lake (GSL) were studied to better understand the formation of potassium deposits in the Qaidam Basin. The study included isothermal evaporation at 25 °C in the laboratory and solar evaporation in the ponds at GSL field. Brines increased in density and became moderately acidic (pH?≈?5.30) while major ion geochemistry and precipitate mineralogy all showed broad agreement between both systems. Four salt assemblages were identified in the isothermal evaporation experiment: halite?→?halite?+?hexahydrite?→?halite?+?bischofite?+?carnallite?→?bischofite. Alternately, three salt assemblages were recognized in the solar evaporation: halite?→?halite?+?epsomite?+?carnallite?→?halite?+?carnallite?+?bischofite. The key difference in salt assemblages between the two systems is attributed to differences in relative humidity and temperature conditions. Although the GSL has deep spring inflow recharge, the high abundance of MgSO₄ salts demonstrates that the salt assemblages are similar to normal seawater evaporation. Thus, different proportions of deep spring inflow and river water could form both MgSO₄-deficient potassium evaporite and normal seawater potassium evaporites. Therefore, nonmarine water may form diverse potassium evaporite deposits in continental basins when the geological structure as well as hydrogeological and climatic conditions is appropriate.     

The origins of the Mengye potash deposit in the Lanping–Simao Basin,Yunnan Province,Western China

The Lanping–Simao Basin (LSB) is a Mesozoic–Cenozoic continental margin rift basin in Western China. It formed during the opening and closing of the Tethys Ocean. This basin is also known as a “metal belt” as it hosts several metal deposits, besides, the Mengye potash deposit. However, the exact dates of the formation either in the Paleocene or the Cretaceous, and thus the origins of the marine, continental or mixed origins of the Mengye deposits, remain disputed. Based on the basin's evolution, materials of marine origin and/or remnant seawater should be present, but instead the salt layers of the Mengye potash deposit present typically continental lithological features. This study examines and reviews evaporative minerals, Br/Cl and I/Cl molar ratios, and isotopes of S, B, and Sr·I and I/Cl data for this area has not been previously reported. The basin's evaporative minerals are dominated by halite and sylvite. The amounts of anhydrite, chlorocalcite, langbeinite, glaserite, tachyhydrite and glauberite are small. All of these form in both marine and continental environments. The values of I and the I/Cl molar ratios of halite and sylvite are from 0.07 to 0.27 ppm, and from 0.03 to 0.11 × 10^− 6, respectively, dependent on organic substances. Br and molar Br/Cl values are from 89.08 to 555.45 ppm and from 0.06 × 10^− 3 to 0.38 × 10^− 3, respectively. All of the Br/Cl molar ratios are lower than those of seawater, and most of them are < 0.1, suggesting continental or mixed origin. Previously published δ³⁴S, δ¹¹B and ⁸⁷Sr/⁸⁶Sr values for evaporative minerals indicate a continental origin for the Mengye potash deposit. However, materials of hydrothermal origin are widely distributed in the basin and may have played an active role for the formation of the potash deposit. Thus the Mengye potash deposit could be of continental origin, with a remnant seawater trace.     

Sedimentary organic matter in condensed sections from distal oxic environments: examples from the Mesozoic of SE France

A detailed analysis of sedimentary organic matter (or palynofacies) was carried out on thermally immature to early mature Upper Jurassic and Hauterivian condensed intervals in deep-sea carbonate–marl alternations outcropping in the Vocontian Basin (SE France). All the condensed sections studied are characterized by intense bioturbation and very low organic carbon content (< 0·25 wt.%), indicative of oxic depositional conditions. Oxic condensed sections display variable palynofacies signatures, which are best illustrated by: (1) the ratio of continental to marine constituents; (2) the ratio of opaque to translucent phytoclasts (i.e. woody debris) and (3) the preservation of palynomorphs (based on fluorescence intensity and morphological preservation state in transmitted light microscopy). Both of the ratios increase with the degree of palynomorph degradation, which shows that phytoclasts, especially the opaque ones, become relatively concentrated in the most degraded facies. These observations lead to the classification of oxic condensed sections into three organic facies types showing different degrees of preservation and palynofacies signatures. Type 1 organic facies display intense degradation and are characterized by high values of the ratio of continental to marine fraction. They record unfavourable depositional environments for preservation of organic matter. Type 2 organic facies are most common and are characterized by a decreasing value of the ratio of continental to marine fraction. Type 3 organic facies display the same trend of the ratio of continental to marine fraction as type 2, but the palynomorph assemblage is better preserved. Type 1 and type 3 organic facies are relatively rare. Recognizing these organic facies types is important when analysing the relationship between sedimentary organic matter and sequence stratigraphy, because it allows the use of the appropriate palynofacies parameters. In particular, the use of the ratio of continental to marine constituents, usually a very good indicator of regressive–transgressive trends, becomes questionable in highly degraded intervals. Moreover, distinguishing between well-preserved or highly degraded palynofacies in condensed intervals provides valuable information on the oxicity of the depositional environment.     

Preliminary correlation of palynological assemblages from Oman with the Granulatisporites confluens Oppel Zone of the grant formation (lower Permian), Canning Basin, Western Australia

The presence of Granulatisporites confluens Archangelsky and Gamerro indicates an Asselian-Tastubian (lowermost Permian) age for glaciogene sediments in the Amal-6 borehole, Oman. This suggests that the Al Khlata Formation is in part coeval with glaciogene sediments of the Canning Basin, Western Australia, and sediments of the Chacoparana Basin, Argentina.     

Mesozoic stratigraphy and history of the Canning Desert and Fitzroy Valley,Western Australia

Abstract

Large outcrop areas in the Canning Desert and the Fitzroy Valley of northwestern Australia consist of marine Jurassic and Upper Triassic rocks, not of Permian as formerly believed. On present knowledge, outcrops of the Triassic formations are restricted to parts of the Fitzroy and Bonaparte Gulf Basins, whereas the distribution of Jurassic (Kimmeridgian to Tithonian) rocks provides evidence for a major marine invasion that affected the Canning Desert area and may have advanced into the centre of the Australian continent and beyond. The late Jurassic transgression did not enter the Fitzroy Basin area.

From the distribution and nature of the Mesozoic formations it is concluded that the main phase of post-Permian folding in the Fitzroy Basin is early Triassic. Later movements affected minor northern parts of the Canning Desert area in early Jurassic and in early Cretaceous time.

As an alternative working hypothesis to the traditional basin concept it is suggested that during the Mesozoic the Canning Desert area was an epicontinental shelf platform.     

The transition between the two major Permian tectono-stratigraphic cycles in the central Southern Alps: results from facies analysis and U/Pb geochronology

The Val Daone Conglomerate (VDC) is a continental clastic unit that crops out eastwards of the central Southern Alps, from the NE sector of the Collio Basin to the W as far as the Tione Basin to the E. This significant but as yet relatively unknown formation lies just above the regional unconformity that marks the boundary between the two Permian major tectono-sedimentary cycles (TSU1 and TSU2) and grades upwards paraconformably (?) to the fluvial red beds of Verrucano Lombardo/Val Gardena Sandstone, generally associated with Late Permian times. Recent palynological investigations on the VDC suggested a Guadalupian age (late Roadian–early Wordian), owing to the remarkable presence of diversified pollen associations; therefore, this sedimentary unit is to date the first one ascribed, on a palaeontological basis, to the Middle Permian in the entire Southern Alps domain. A detailed facies analysis of VDC shows deposition in amalgamated alluvial fan-braided and fluvial environments with wide channels and longitudinal bars. In its type area and Val Rendena, the VDC rests unconformably above the last volcanic episode of the TSU1. LA ICP-MS U–Pb dating on zircon from two samples of such topmost Lower Permian volcanic rocks, known as Ponte Murandin dacitic lava and Malga Plan rhyodacitic Ignimbrites (Tione Basin), provided Concordia ages of 278 ± 2 Ma (MSWD = 0.01) and 279 ± 2 Ma (MSWD = 0.16), respectively. As well as allowing us to better define the duration of the time gap between the two Permian megacycles in the central Southern Alps in almost 10 Ma, these radiometric age determinations are also significant because they enable us to regionally link the coeval volcanic bodies which crop out in the Collio Basin to the SW and in the “Athesian Volcanic Group” to the NE, respectively.     

Geochemistry of deep formation waters in the Canning Basin,Western Australia,and their relationship to Zn‐Pb mineralization

The Canning Basin contains several Mississippi Valley‐type Zn‐Pb sulphide prospects and deposits in Devonian carbonate reef complexes on the northern edge of the Fitzroy Trough, and in Ordovician and Silurian marine sequences on the northern margin of the Willara Sub‐basin. This study uses the ionic composition and 5D, δ¹⁸O, δ³⁴S, ⁸⁷Sr/⁸⁶Sr isotopic data on present‐day deep formation waters to determine their origin and possible relationship to the Zn‐Pb mineralizing palaeofluids.

The present‐day Canning Basin formation waters have salinity ranging from typically less than 5000 mg/L up to 250 000 mg/L locally. The brines are mixtures of highly saline water, formed by seawater which evaporated beyond halite saturation (bittern water), with meteoric water ranging in salinity from low (<5000 mg/L) to hypersaline water (up to about 50 000 mg/L) formed by re‐solution of halite and calcium sulphate minerals. The original marine chemical composition of the bittern‐dominated brines was changed to that of a Na‐Ca‐Cl water by addition of Ca and removal of Mg and SO₄, initially by bacterial sulphate reduction and later by dolomitization of carbonate. Other reactions with terrigenous components of the sediment have provided additional Ca and Sr, including a small proportion of ⁸⁷Sr‐rich material. The δ³⁴S values of the bittern‐containing waters are within the range over which marine sulphate has fluctuated from the Ordovician to the Holocene, although one of the hypersaline waters has a value of +6.8%, indicating SO₄ of non‐marine origin. The pH of the bittern‐containing waters is low (about 5) and they contain significant concentrations of dissolved Fe (up to 120 mg/L).

The Canning Basin bitterns appear similar in origin and chemical composition to highly saline marine brines in the Mississippi Salt Dome Basin, USA, which are known to be either metal or sulphide‐rich depending on the organic content of the host rock. In the Canning Basin, mixing of the bittern water with the various types of meteoric water has resulted in decreases in salinity, Na, Ca, Mg, K, Sr, Li and Fe, and increases in HCO₃, SO₄ and pH.

Mixing of the bitterns with other types of metalliferous fluids and/or with sulphate‐containing hypersaline meteoric waters formed from the same marine evaporite sequence should produce ore‐precipitating fluids which are relatively hot and saline, and the resulting ore deposit should be of high grade and contain abundant sulphate minerals. In the southern Canning Basin, this type of mixing and the corresponding style of ore deposit is evident in the evaporite‐associated areas of Zn‐Pb mineralization near the Admiral Bay Fault. If the bitterns mix with low salinity HCO₃‐waters in near‐surface environments, then the ore‐precipitating fluids should have relatively low salinities and carbonate minerals would precipitate during later stages of mixing. In the Lennard Shelf, the present‐day formation waters, the style of the Zn‐Pb deposits, and range of salinity and temperature of the ore‐forming palaeofluids are consistent with this type of mixing.     

四川盆地东部垫江盐盆早三叠世嘉陵江组四段杂卤石成因及对成钾的指示

四川盆地三叠纪是主要的成钾期,目前发现的主要含钾矿物为杂卤石,有关早三叠世嘉陵江组四段石盐岩中杂卤石成因一直存在争议.采用薄片鉴定、扫描电镜、稀土元素和锶同位素等手段,分析了四川盆地东部垫江盐盆长寿地区嘉陵江组四段石盐岩中杂卤石矿物形态特征,初步探讨了该杂卤石成因及对寻找海相钾盐的指示意义.扫描电镜下与石盐岩共生的杂卤...     

湖北Q凹陷第三纪含盐系Br、Rb、B、Li的地球化学研究

地球化学是研究盐类沉积和钾盐矿床的重要手段。但过去的工作往往带有一定的局限性,多偏重于盐类沉积物本身微量元素的研究,对组成含盐系中的泥质岩地层缺乏应有的注意。欲更好地了解Q凹陷含盐系的形成条件,古盐湖发展史及成钾规律,就必须对含盐系沉积进行比较全面的地球化学研究。     

柴达木盆地昆特依盐湖含杂卤石地层高分辨率矿物学研究

柴达木盆地昆特依盐湖杂卤石资源丰富,是开展现代内陆盐湖杂卤石成因机制研究的良好载体。精细刻画沉积特征对阐释沉积矿床成因具有重要作用。本研究以昆特依盐湖大盐滩矿区ZK3608钻孔岩芯14.08-25.48 m段碎屑-杂卤石沉积韵律为研究对象,开展高分辨率矿物学研究,结合石盐流体包裹体化学组成和石盐中微量元素分析,尝试从高分辨率沉积学和矿物学的角度探讨杂卤石的成因。研究结果显示,石盐层产出的杂卤石含量低但分布范围广,为原生矿物;碎屑层中的杂卤石主要为次生矿物。石盐层与碎屑层之间存在一个过渡层位,该层位的杂卤石高度富集且矿物组成复杂,推测是由于原生与准同生杂卤石短时间内先后形成导致的。结合石盐流体包裹体化学组成所代表的古卤水变化特征分析表明,Ca-Cl型深部油田卤水的补给对研究区不同时期杂卤石的形成有重要影响。地球化学特征综合分析指示,石盐层的原生杂卤石由富钾镁的浓缩卤水与Ca-Cl型深部油田卤水混合直接生成;而过渡层位的杂卤石受到气候变化与Ca-Cl型深部油田卤水补给的共同作用。     

IX. The St. Vincent Basin

Late Palaeozoic glaciation in Australia, discovered over a century ago, is now known to have covered a large part of the continent. In South Australia, tillite and outwash debris lie upon clearly striated pavements within glacial valleys, and show that ice sheets with valley tongues moved northward from sources now occupied by deep ocean south of the continent. These glaciers reached into the Cooper, Arckaringa, and Pedirka Basins at the end of the Carboniferous and laid down patches of till in the Early Permian, now preserved largely in the subsurface. In Tasmania, an ice sheet waxed in the latest Carboniferous from sources to the west of the island, and deposited till and “drop‐stones” into fossiliferous marine strata until well into the Late Permian. In Victoria, the ice cap laid down till on a striated floor, and here and there sequences of outwash, including boulder pavements. In New South Wales, continental glaciation expanded eastward to the sea early in the Permian, and left a record intercalated with volcanics and coal beds into the Late Permian. Bordering the Tamworth Trough of northern New South Wales, and occurring also in the highlands of New England, alpine glaciers left a record in the form of striated stones and dropstones, in very thick sequences of fluviatile, lacustrine, and marine clastic sediments. The mountains existed in Middle and early Late Carboniferous times, and were largely worn down to gentle relief when continental glaciers expanded northward in the Early Permian. A non‐glacial interval at the end of the Carboniferous therefore probably occurred in New South Wales. In Queensland, alpine glaciers occupied mountains at the western rim of the Bowen Basin at the end of the Carboniferous. Large blocks carried by icebergs from glaciers of unknown locations were dropped into Lower and Upper Permian strata of the Bowen Basin as well. In Western Australia Early Permian ice centres were located on the Yilgarn Block, east of the Perth Basin, on the Pilbara Block southwest of the Canning Basin, and on the Kimberley Block. Evidence for this glaciation consists mostly of ice‐rafted debris and fluvial‐glacial and glacial‐marine strata that reached as far north as the Bonaparte Gulf Basin.

The rapid growth northward of continental glaciers in Australia near the end of the Carboniferous corresponds with a rapid shift of palaeolatitude as judged from Irving's palaeomagnetic studies. The ice sheet grew quickly upon upland areas when Gondwanaland moved to a near polar position and the unfrozen Palaeo‐Pacific lay near at hand to provide an abundant source of moisture.     

Glauberite–halite association of the Zaragoza Gypsum Formation (Lower Miocene, Ebro Basin, NE Spain)

Glauberite is the most common mineral in the ancient sodium sulphate deposits in the Mediterranean region, although its origin, primary or diagenetic, continues to be a matter of debate. A number of glauberite deposits of Oligocene–Miocene age in Spain display facies characteristics of sedimentologic significance, in particular those in which a glauberite–halite association is predominant. In this context, a log study of four boreholes in the Zaragoza Gypsum Formation (Lower Miocene, Ebro Basin, NE Spain) was carried out. Two glauberite–halite lithofacies associations, A and B, are distinguished: association (A) is composed of bedded cloudy halite and minor amounts of massive and clastic glauberite; association (B) is made up of laminated to thin‐bedded, clear macrocrystalline, massive, clastic and contorted lithofacies of glauberite, and small amounts of bedded cloudy halite. Transparent glauberite cemented by clear halite as well as normal‐graded and reverse‐graded glauberite textures are common. This type of transparent glauberite is interpreted as a primary, subaqueous precipitate. Gypsum, thenardite or mirabilite are absent in the two associations. The depositional environment is interpreted as a shallow perennial saline lake system, in which chloride brines (association A) and sulphate–(chloride) brines (association B) are developed. The geochemical study of halite crystals (bromine contents and fluid inclusion compositions) demonstrates that conditions for co‐precipitation of halite and glauberite, or for precipitation of Na‐sulphates (mirabilite, thenardite) were never fulfilled in the saline lake system.     

Geochemistry of modern seawater and brines from salt pans: Main components and bromine distribution

Seawater at different stages of evaporation from the salt works of Seovlje near Portoro (Yugoslavia) was analyzed geochemically. The seawater there passes through 20 stages of concentration until the first halite crystallizes. All important parameters were determined at all stages: concentrations of Cl, SO₄, Na, K, Ca, Mg, and Br, temperature, pH, Eh, oxygen content and titration alkalinity. With increasing evaporation calcium carbonate crystallizes first followed by calcium sulphate as gypsum and after these halite. All three components crystallize from supersaturated solutions. The pH of the initial seawater is 8.32; it falls abruptly to 6.65 when the first calcium carbonate precipitates. Eh in the original seawater is +393 mv; negative values were found in the halite crystallization pans, which contain an anaerobic mud as a reducing agent. The oxygen content of the solution decreases parallel to the drop in Eh. In the pans in which NaCl crystallizes Eh is zero. Apparently the mud also adsorbs K, as can be inferred from a change in the Mg/K ratio.The bromine partition between crystallizing halite and the brine in the salt pans of Seovlje is discussed with regard to some genetic problems of marine salt deposits. In the conditions in the salt pans the bromine partition coefficient at the beginning of NaCl crystallization from seawater—expressed as b=wt.-% Br (mineral)/wt.-% Br (solution)—is 0.12 to 0.14 or—expressed as D=Br/Cl(mineral)/Br/Cl(solution)—0.030 to 0.034 at temperatures between 33° C and 42° C. The conclusion is that a Br content of about 60 to 75 ppm is to be expected for the first halite that crystallizes from evaporating seawater.