Volcanological evolution of the Rivi–Capo Volcanic Complex at Salina,Aeolian Islands: magma storage processes and ascent dynamics

Critical to understanding explosive eruptions is establishing how accurately representative pyroclasts are of processes during magma vesiculation and fragmentation. Here, we present data on densities, and vesicle size and number characteristics, for representative pyroclasts from six silicic eruptions of contrasting size and style from Raoul volcano (Kermadec arc). We use these data to evaluate histories of bubble nucleation, coalescence, and growth in explosive eruptions and to provide comparisons with pumiceous dome carapace material. Density/vesicularity distributions show a scarcity of pyroclasts with ～65–75 % vesicularity; however, pyroclasts closest to this vesicularity range have the highest bubble number density (BND) values regardless of eruptive intensity or style. Clasts with vesicularities greater than this 65–75 % “pivotal” vesicularity range have decreasing BNDs with increasing vesicularities, interpreted to reflect continuing bubble growth and coalescence. Clasts with vesicularities less than the pivotal range have BNDs that decrease with decreasing vesicularity and preserve textures indicative of processes such as stalling and open system degassing prior to vesiculation in a microlite-rich magma, or vesiculation during slow ascent of degassing magma. Bubble size distributions (BSDs) and BNDs show variations consistent with 65–75 % representing the vesicularity at which vesiculating magma is most likely to undergo fragmentation, consistent with the closest packing of spheres. We consider that the observed vesicularity range may reflect the development of permeability in the magma through shearing as it flows through the conduit. These processes can act in concert with multiple nucleation events, generating a situation of heterogeneous bubble populations that permit some regions of the magma to expand and bubbles to coalesce with other regions in which permeable networks are formed. Fragmentation preserves the range in vesicularity seen as well as any post-fragmentation/pre-quenching expansion which may have occurred. We demonstrate that differing density pyroclasts from a single eruption interval can have widely varying BND values corresponding to the degree of bubble maturation that has occurred. The modal density clasts (the usual targets for vesicularity studies) have likely undergone some degree of bubble maturation and are therefore may not be representative of the magma at the onset of fragmentation.     

Particle fallout,thermal disequilibrium and volcanic plumes

We develop a model of a volcanic eruption column that includes the effects of fallout of pyroclasts and thermal disequilibrium. We show that clast fallout, with no thermal disequilibrium, has only a small effect upon the column. However, disequilibrium changes column behaviour significantly, and can even induce collapse. Our results may explain the lower plume heights and less widely dispersed fallout of cone-forming eruptions contrasted with sheet-forming eruptions. The model also predicts that the transition from the gas thrust to the convective region in a column results in an inflection in dispersal curves, that some features of the stratigraphy common to many fall deposits may result from column velocity structure, and that there may exist a region near the volcanic vent in which maximum pyroclast size does not decrease significantly with distance.     

Quench rates in air, water, and liquid nitrogen, and inference of temperature in volcanic eruption columns

We apply a geospeedometer previously developed in this lab to investigate cooling rate profiles of rhyolitic samples initially held at 720–750°C and quenched in water, liquid nitrogen, and air. For quench of mm-size samples in liquid nitrogen and in air, the cooling rate is uniform and is controlled by heat transfer in the quench medium instead of heat conduction in the sample. The heat transfer coefficient in ‘static’ air decreases with increasing sample size. For quench of mm-size samples in water, heat transfer in water is rapid and the cooling rate is largely controlled by heat conduction in the sample. Our experimental results are roughly consistent with previous calculations for cooling in air and in water (although constant heat transfer coefficients were used in these calculations), but cooling rate in liquid nitrogen is only 1.8–2.3 times that in ‘static’ air, and slower by a factor of 2 than calculated by previous authors. Cooling rate in compressed airflow is about the same as that in liquid nitrogen. The experimental results are applied to interpret cooling rates of pyroclasts in ash beds of the most recent eruptions of the Mono Craters. Cooling rates of pyroclasts are inversely correlated with sample size and slower than those in air. The results indicate that the hydrous species concentrations of the pyroclasts were frozen in the eruption column, rather than inside ash beds or in flight in ambient air. From the cooling rates, we infer eruption column temperature in a region where and at a time when hydrous species concentrations in a pyroclast were locked in. The temperature ranges from 260 to 570°C for the most recent eruptions of Mono Craters. These are the first estimates of temperatures in volcanic eruption columns. The ability to estimate cooling rates and eruption column temperatures from eruptive products will provide constraints to dynamic models for the eruption columns.     

Formation of high-grade ignimbrites Part II. A pyroclastic suspension current model with implications also for low-grade ignimbrites

 Analogue experiments in part I led to the conclusion that pyroclastic flows depositing very high-grade ignimbrite move as dilute suspension currents. In the thermo–fluid–dynamical model developed, the degree of cooling of expanded turbulent pyroclastic flows dynamically evolves in response to entrainment of air and mass loss to sedimentation. Initial conditions of the currents are derived from column-collapse modeling for magmas with an initial H₂O content of 1–3 wt.% erupting through circular vents and caldera ring-fissures. The flows spread either longitudinally or radially from source up to a runout distance that increases with higher mass flux but decreases with higher gas content, temperature, bottom slope and coarser initial grain size. Progressive dilution by entrainment and sedimentation causes pyroclastic currents to transform into buoyant ash plumes at the runout distance. The ash plumes reach stratospheric heights and distribute 30–80% of the erupted material as widespread co-ignimbrite ash. Pyroclastic suspension currents with initial mass fluxes of 10⁷-10¹² kg/s can spread for tens of kilometers with only limited cooling, although they move as supercritical, strongly entraining currents for the eruption conditions considered here. With increasing eruption mass flux, cooling during passage through the fountain diminishes while cooling during flow transport increases. The net effect is that eruption temperature exerts the prime control on emplacement temperature. Pyroclastic suspension currents can form welded ignimbrite across their entire extent if eruption temperature is T_o>1.3^.T_mw, the minimum welding temperature. High eruption rates, a large fraction of fine ash, and a ring-fissure vent favor the formation of extensive high-grade ignimbrite. For very hot eruptions producing sticky, partially molten pyroclasts, analysis of particle aggregation systematics shows that factors favoring longer runout also favor more efficient aggregation, which reduces runout. As a result, very high-grade ignimbrites cannot spread more than a few tens of kilometers from their source. In cooler pyroclastic currents, particles do not aggregate, and the sedimentation process may involve re-entrainment of particles, which potentially leads to more extensive cooling and longer runout; such effects, however, are only significant when net erosion of substrate occurs. Model results can be employed to estimate mass flux and duration of ignimbrite eruptions from measured ignimbrite masses and aspect ratios. The model also provides an alternative explanation of the observed decrease in H/Lratios with ignimbrite mass. Received: 10 May 1998 / Accepted: 21 October 1998     

Contrasting pyroclast density spectra from subaerial and submarine silicic eruptions in the Kermadec arc: implications for eruption processes and dredge sampling

Pyroclastic deposits from four caldera volcanoes in the Kermadec arc have been sampled from subaerial sections (Raoul and Macauley) and by dredging from the submerged volcano flanks (Macauley, Healy, and the newly discovered Raoul SW). Suites of 16–32?mm sized clasts have been analyzed for density and shape, and larger clasts have been analyzed for major element compositions. Density spectra for subaerial dry-type eruptions on Raoul Island have narrow unimodal distributions peaking at vesicularities of 80–85%, whereas ingress of external water (wet-type eruption) or extended timescales for degassing generate broader distributions, including denser clasts. Submarine-erupted pyroclasts show two different patterns. Healy and Raoul SW dredge samples and Macauley Island subaerial-emplaced samples are dominated by modes at ~80–85%, implying that submarine explosive volcanism at high eruption rates can generate clasts with similar vesicularities to their subaerial counterparts. A minor proportion of Healy and Raoul SW clasts also show a pink oxidation color, suggesting that hot clasts met air despite 0.5 to >1?km of intervening water. In contrast, Macauley dredged samples have a bimodal density spectrum dominated by clasts formed in a submarine-eruptive style that is not highly explosive. Macauley dredged pyroclasts are also the mixed products of multiple eruptions, as shown by pumice major-element chemistry, and the sea-floor deposits reflect complex volcanic and sedimentation histories. The Kermadec calderas are composite features, and wide dispersal of pumice does not require large single eruptions. When coupled with chemical constraints and textural observations, density spectra are useful for interpreting both eruptive style and the diversity of samples collected from the submarine environment.     

Eruption of kimberlite magmas: physical volcanology, geomorphology and age of the youngest kimberlitic volcanoes known on earth (the Upper Pleistocene/Holocene Igwisi Hills volcanoes, Tanzania)

The Igwisi Hills volcanoes (IHV), Tanzania, are unique and important in preserving extra-crater lavas and pyroclastic edifices. They provide critical insights into the eruptive behaviour of kimberlite magmas that are not available at other known kimberlite volcanoes. Cosmogenic ³He dating of olivine crystals from IHV lavas and palaeomagnetic analyses indicates that they are Upper Pleistocene to Holocene in age. This makes them the youngest known kimberlite bodies on Earth by >30?Ma and may indicate a new phase of kimberlite volcanism on the Tanzania craton. Geological mapping, Global Positioning System surveying and field investigations reveal that each volcano comprises partially eroded pyroclastic edifices, craters and lavas. The volcanoes stand <40?m above the surrounding ground and are comparable in size to small monogenetic basaltic volcanoes. Pyroclastic cones consist of diffusely layered pyroclastic fall deposits comprising scoriaceous, pelletal and dense juvenile pyroclasts. Pyroclasts are similar to those documented in many ancient kimberlite pipes, indicating overlap in magma fragmentation dynamics between the Igwisi eruptions and other kimberlite eruptions. Characteristics of the pyroclastic cone deposits, including an absence of ballistic clasts and dominantly poorly vesicular scoria lapillistones and lapilli tuffs, indicate relatively weak explosive activity. Lava flow features indicate unexpectedly high viscosities (estimated at >10² to 10⁶?Pa?s) for kimberlite, attributed to degassing and in-vent cooling. Each volcano is inferred to be the result of a small-volume, short-lived (days to weeks) monogenetic eruption. The eruptive processes of each Igwisi volcano were broadly similar and developed through three phases: (1) fallout of lithic-bearing pyroclastic rocks during explosive excavation of craters and conduits; (2) fallout of juvenile lapilli from unsteady eruption columns and the construction of pyroclastic edifices around the vent; and (3) effusion of degassed viscous magma as lava flows. These processes are similar to those observed for other small-volume monogenetic eruptions (e.g. of basaltic magma).     

Fragmentation in kimberlite: products and intensity of explosive eruption

The explosive eruption of kimberlite magma is capable of producing a variety of pyroclast sizes, shapes, and textures. However, all pyroclastic deposits of kimberlite comprise two main types of pyroclasts: (1) pyroclasts of kimberlite with or without enclosed olivine crystals and (2) olivine crystals which lack coatings of kimberlite. Here, we propose two hypotheses for how kimberlite magmas are modified due to explosive eruption: (1) olivine crystals break during kimberlite eruption, and (2) kimberlite melt can be efficiently separated from crystals during eruption. These ideas are tested against data collected from field study and image analysis of coherent kimberlite and fragmental kimberlite from kimberlite pipes at Diavik, NT. Olivines are expected to break because of rapid pressure changes during the explosive eruption. Disruption of kimberlite magma, and pyroclast production, is driven by ductile deformation processes, rather than by brittle fragmentation. The extent to which melt separates from olivine crystals to produce kimberlite-free crystals is a direct consequence of the relative proportions of gas, melt and crystals. Lastly, the properties of juvenile pyroclasts in deposits of pyroclastic kimberlite are used to index the relative intensity of kimberlite eruptions. A fragmentation index is proposed for kimberlite eruption based on: (a) crystal size distributions of olivine and on (b) ratios of selvage-free olivine pyroclasts to pyroclasts of kimberlite with or without olivine crystals.     

European summer temperature response to annually dated volcanic eruptions over the past nine centuries

The drop in temperature following large volcanic eruptions has been identified as an important component of natural climate variability. However, due to the limited number of large eruptions that occurred during the period of instrumental observations, the precise amplitude of post-volcanic cooling is not well constrained. Here we present new evidence on summer temperature cooling over Europe in years following volcanic eruptions. We compile and analyze an updated network of tree-ring maximum latewood density chronologies, spanning the past nine centuries, and compare cooling signatures in this network with exceptionally long instrumental station records and state-of-the-art general circulation models. Results indicate post-volcanic June–August cooling is strongest in Northern Europe 2 years after an eruption (?0.52?±?0.05 °C), whereas in Central Europe the temperature response is smaller and occurs 1 year after an eruption (?0.18?±?0.07 °C). We validate these estimates by comparison with the shorter instrumental network and evaluate the statistical significance of post-volcanic summer temperature cooling in the context of natural climate variability over the past nine centuries. Finding no significant post-volcanic temperature cooling lasting longer than 2 years, our results question the ability of large eruptions to initiate long-term temperature changes through feedback mechanisms in the climate system. We discuss the implications of these findings with respect to the response seen in general circulation models and emphasize the importance of considering well-documented, annually dated eruptions when assessing the significance of volcanic forcing on continental-scale temperature variations.     

Thermodynamics and fluid dynamics of effusive subglacial eruptions

We consider the thermodynamic and fluid dynamic processes that occur during subglacial effusive eruptions. Subglacial eruptions typically generate catastrophic floods (jökulhlaups) due to melting of ice by lava and generation of a large water cavity. We consider the heat transfer from basaltic and rhyolitic lava eruptions to the ice for typical ranges of magma discharge and geometry of subglacial lavas in Iceland. Our analysis shows that the heat flux out of cooling lava is large enough to sustain vigorous natural convection in the surrounding meltwater. In subglacial eruptions the temperature difference driving convection is in the range 10–100??°C. Average temperature of the meltwater must exceed 4??°C and is usually substantially greater. We calculate melting rates of the walls of the ice cavity in the range 1–40?m/day, indicating that large subglacial lakes can form rapidly as observed in the 1918 eruption of Katla and the 1996 eruption of Gjálp fissure in Vatnajökull. The volume changes associated with subglacial eruptions can cause large pressure changes in the developing ice cavity. These pressure changes can be much larger than those associated with variation of bedrock and glacier surface topography. Previous models of water-cavity stability based on hydrostatic and equilibrium conditions may not be applicable to water cavities produced rapidly in volcanic eruptions. Energy released by cooling of basaltic lava at the temperature of 1200??°C results in a volume deficiency due to volume difference between ice and water, provided that heat exchange efficiency is greater than approximately 80%. A negative pressure change inhibits escape of water, allowing large cavities to build up. Rhyolitic eruptions and basaltic eruptions, with less than approximately 80% heat exchange efficiency, cause positive pressure changes promoting continual escape of meltwater. The pressure changes in the water cavity can cause surface deformation of the ice. Laboratory experiments were carried out to investigate the development of a water cavity by melting ice from a finite source area at its base. The results confirm that the water cavity develops by convective heat transfer.     

Widespread strombolian eruptions of mid-ocean ridge basalt

Glassy lava fragments were collected in pushcores or using a small suction-sampler from over 450 sites along the Juan de Fuca Ridge, Blanco Transform Fault, Gorda Ridge, northern East Pacific Rise, southern East Pacific Rise, Fiji back-arc basin, and near-ridge seamounts in the Vance, President Jackson, Taney, and a seamount off southern California. The samples consist of angular glass fragments, limu o Pele, Pele's hair, and other fluidal fragments formed during pyroclastic eruptions. Since many of the sites are deeper than the critical point of seawater, fragmentation cannot be hydrovolcanic and caused by expansion of seawater to steam. The glass fragments have a wide range of MORB compositions, ranging from fractionated to primitive and from depleted to enriched. Enriched magmas, which have higher volatile contents, may form more abundant pyroclasts than depleted magmas. Eruptions with high effusion rates produce sheet flows and abundant pyroclasts whereas those with low effusion rates produce pillow ridges and few pyroclasts. This relation suggests that high effusion and conduit rise rates are coupled to high magmatic gas contents. The eruptions are mainly effusive with a minor strombolian bubble burst component. We propose that the gas phase is an added component of variable amounts of magmatic foam from the top of the magma reservoir. As the mixture of resident magma and foam rises in the conduit, the larger bubbles in the foam rise more quickly and sweep up the smaller bubbles nucleating and growing from the resident magma. On eruption, the process of bubble coalescence is more complete for the slower rising, gas-poor lavas that erupt as pillow lavas whereas the limu o Pele associated with sheet flow eruptions commonly contain several percent vesicles that avoided coalescence during ascent. The spatter erupted at the vent is quench granulated in seawater above the vent, reducing the pyroclast grainsize. The granulated spatter and limu o Pele fragments are then entrained in a rising plume of seawater heated by the eruption, which disperses them to distances as great as 5 km from the vent.     

The geology of Oldoinyo Lengai

The active volcano, Oldoinyo Lengai in the Eastern Rift in northern Tanganyika consists mainly of yellow ijolitic pyroclasts with interbedded relatively thin phonolite and nephelinite lavas, overlain by nephelinitic pyroclasts and younger ashes with marked unconformity. Ejected blocks in the pyroclasts are of rocks of the urtite-jacupirangite series with or without wollastonite, wollastonitite, fenite, carbonite, biotite pyroxenite and various lavas. Observations were made of minor activity during September–October 1960 when it was noted that soda-rich carbonate lava was extruded on the crater-floor in addition to minor emissions of ash. From examination of the rock sequence it appears that the volcano is waning and there has been a change from earlier dominantly gas eruptions to the more recent minor emissions of lava.     

The volcanic history of Ruapehu during the past 2 millennia based on the record of Tufa Trig tephras

 Tufa Trig Formation comprises a sequence of at least 19 andesitic tephras erupted from Mt. Ruapehu (Tongariro Volcanic Centre, New Zealand). Tephras of Tufa Trig Formation are the most recent eruptives from Ruapehu, dated between ca. 1850 years B.P. and the present. Members of the Formation show restricted dispersals, principally to the east of Mt. Ruapehu. Volumes calculated for the most widespread members are all less than 0.1 km³. Compared with other Mt. Ruapehu eruptives, Tufa Trig Formation tephras represent small eruptions that have contributed little tephra to the ring plain. They do, however, show a greater frequency of eruption with one event occurring on average every 100 years. Tufa Trig Formation members Tf3–Tf18 are black to dark grey, vitric, coarse-ash and lapilli-grade tephras which mantle the relief. They contain juvenile vitric particles which exhibit varying degrees of vesicularity, together with free crystals of pyroxene and feldspar, and few lithic fragments. Several morphological types of vitric pyroclasts are recognised in these tephras, the dominant type being of equant blocky morphology with fracture-bound surfaces (type-1 morphology). Field characteristics, tephra distributions, and the morphologies and textures of constituent pyroclasts suggest that these members (Tf3–Tf18) are the products of small-volume hydrovolcanic eruptions resulting from the interaction of fresh magma and meteoric water. We propose that a source of this water was an ancestral crater lake which formed within the late Holocene ca. 3000 years B.P. The morphological, compositional, and chemical (major-element) characteristics of three Tufa Trig Formation Tephras are compared with those of two new tephras erupted from Ruapehu Volcano during the October 1995 eruptions which comprise part of a newly defined member (Tf19) of Tufa Trig Formation. The comparisons support our interpretation that the majority of the Tufa Trig Formation tephras are primarily the products of hydrovolcanic eruptions. Other members of the Formation (Tf1 and Tf2) are coarse-grained scoriaceous tephras and are interpreted to be the products of strombolian events. Received: 14 September 1996 / Accepted: 6 June 1997     

3D numerical simulation of particle-particle collisions in saltation mode near stream beds

The importance of particle-particle collisions in sediment saltation in the bed-load layer is analyzed herein by means of numerical simulation. The particle saltation theoretical/numerical model follows a Lagrangian approach, and addresses the motion of sediment particles in an open channel flow described by a logarithmic velocity profile. The model is validated with experimental data obtained from the literature. In order to evaluate the importance of the phenomenon, simulations with and without particle-particle collisions were carried out. Results for two different sediment concentrations are presented, namely 0.13% and 2.33%. For each concentration of particles, three different flow intensities were considered, and trajectories of two different particle sizes, within the sand range were computed. Changes in particle rotation, particle velocity, and angle of trajectory before and after particle-particle collisions appear to be relatively important at lower shear stresses, whereas they decrease in significance with increasing flow intensities. Analyses of the evolution in time of the second order moment of particle location suggest that inter-particle collisions introduce transverse diffusion in saltating particles in the span-wise direction.     

Plinian-type eruptions in the medicine lake highland, california, and the nature of the underlying magma

Contemporaneous Plinian eruptions of rhyolite pumice from Glass Mountain and Little Glass Mountain during the last 1100 years B.P. were followed by extrusion of lava flows. 1.2 km of material was erupted and 10% by volume is tephra. All of the tephra deposits consist of very poorly sorted coarse ash and lapilli that are mostly pumice pyroclasts.Eruptive sequences, chemical composition and petrographic character of the rhyolites at Little Glass Mountain and Glass Mountain suggest that they came from the same magma body. The 1:9 ratio of tephra to lavas is typical of small silicic magma chambers. Eruption from a small chamber, 4–6 km deep, at vents 15 km apart is possible if magma rose along cone sheets with dips of 45–60°. The caldera rim and arcuate lines of vents near it may represent the surface expression of several concentric cone sheets.Pumice pyroclasts erupted at Glass Mountain and Little Glass Mountain may have formed in the following manner: (1) vesicle growth and coalescence beginning at 1–2 km depths; (2) elongation of the vesicles by flow within the cone sheets; (3) disruption of the vesiculated magma when it reached the surface by an expansion wave passing down through it; and (4) eruption of comminution products as pumice pyroclasts. Plinian activity at Little Glass Mountain and Glass Mountain continued until the volatile-rich top of the magma chamber had been depleted.     

Geology of a complex kimberlite pipe (K2 pipe,Venetia Mine,South Africa): insights into conduit processes during explosive ultrabasic eruptions

K2 is a steep-sided kimberlite pipe with a complex internal geology. Geological mapping, logging of drillcore and petrographic studies indicate that it comprises layered breccias and pyroclastic rocks of various grain sizes, lithic contents and internal structures. The pipe comprises two geologically distinct parts: K2 West is a layered sequence of juvenile- and lithic-rich breccias, which dip 20–45° inwards, and K2 East consists of a steep-sided pipe-like body filled with massive volcaniclastic kimberlite nested within the K2 pipe. The layered sequence in K2 West is present to > 900 m below present surface and is interpreted as a sequence of pyroclastic rocks generated by explosive eruptions and mass-wasting breccias generated by rock fall and sector collapse of the pipe walls: both processes occurred in tandem during the infill of the pipe. Several breccia lobes extend across the pipe and are truncated by the steep contact with K2 East. Dense pyroclastic rocks within the layered sequence are interpreted as welded deposits. K2 East represents a conduit that was blasted through the layered breccia sequence at a late stage in the eruption. This phase may have involved fluidisation of trapped pyroclasts, with loss of fine particles and comminution of coarse clasts. We conclude that the K2 kimberlite pipe was emplaced in several distinct stages that consisted of an initial explosive enlargement, followed by alternating phases of accumulation and ejection.     

Cristobalite in the 2011–2012 Cordón Caulle eruption (Chile)

Cristobalite is a low-pressure high-temperature polymorph of SiO₂ found in many volcanic rocks. Its volcanogenic formation has received attention because (1) pure particulate cristobalite can be toxic when inhaled, and its dispersal in volcanic ash is therefore a potential hazard; and (2) its nominal stability field is at temperatures higher than those of magmatic systems, making it an interesting example of metastable crystallization. We present analyses (by XRD, SEM, EPMA, Laser Raman, and synchrotron μ-cT) of representative rhyolitic pyroclasts and of samples from different facies of the compound lava flow from the 2011–2012 eruption of Cordón Caulle (Chile). Cristobalite was not detected in pyroclasts, negating any concern for respiratory hazards, but it makes up 0–23 wt% of lava samples, occurring as prismatic vapour-deposited crystals in vesicles and/or as a groundmass phase in microcrystalline samples. Textures of lava collected near the vent, which best represent those generated in the conduit, indicate that pore isolation promotes vapour deposition of cristobalite. Mass balance shows that the SiO₂ deposited in isolated pore space can have originated from corrosion of the adjacent groundmass. Textures of lava collected down-flow were modified during transport in the insulated interior of the flow, where protracted cooling, additional vesiculation events, and shearing overprint original textures. In the most slowly cooled and intensely sheared samples from the core of the flow, nearly all original pore space is lost, and vapour-deposited cristobalite crystals are crushed and incorporated into the groundmass as the vesicles in which they formed collapse by strain and compaction of the surrounding matrix. Holocrystalline lava from the core of the flow achieves high mass concentrations of cristobalite as slow cooling allows extensive microlite crystallization and devitrification to form groundmass cristobalite. Vapour deposition and devitrification act concurrently but semi-independently. Both are promoted by slow cooling, and it is ultimately devitrification that most strongly contributes to total cristobalite content in a given flow facies. Our findings provide a new field context in which to address questions that have arisen from the study of cristobalite in dome eruptions, with insight afforded by the fundamentally different emplacement geometries of flows and domes.     

Frequency-dependent susceptibility and other magnetic properties of Celtic and Mediaeval graphitic pottery from Bohemia: an introductory study

Frequency-dependent magnetic susceptibility, its anisotropy (AMS), its temperature variation, natural remanent magnetization and time-dependent isothermal remanent magnetization as well as M?ssbauer spectroscopy of a small collection of Celtic and Mediaeval graphitic pottery from Southern Bohemia were investigated. The mineral composition of the pottery is dominated by fragments of quartz, accompanied mainly by various silicates from granitoids and paragneisses, or by calcite, within the plastic component being probably illite but also graphite. No ferrimagnetic minerals were found in optical microscope, among Fe-oxides only limonite was observed, even though the bulk susceptibility of the pottery varies in the orders of 10^?4 to 10^?2 [SI]. This may indicate presence of ferromagnetic particles in the ultrafine (superparamagnetic, SP) state, which is confirmed by frequency-dependent susceptibility ranging from 3% to almost 16%. The low temperature susceptibility vs. temperature curves are only moderately sloped, showing the Verwey transition only in one case. The high temperature curves mostly show presence of two magnetic phases, maghemite and magnetite. Cooling curves show distinctly lower susceptibilities than the heating curves indicating instability of the assemblage of ferrimagnetic minerals, particularly in temperatures slightly under 700 °C. M?ssbauer spectroscopy confirmed the results of the frequency-dependent susceptibility, showing the increase of ferrimagnetic sextets in the spectra measured at 4.2K, likely indicating maghemite as the distinct ferrimagnetic phase. The frequency-dependent AMS indicates preferred orientation of SP1,16 particles, coaxiality between SP_1,16 grain AMS and whole specimen AMS indicate that all grains, ultrafine and coarser ones, were oriented by the same process, i.e. copying the pottery structure created during wheel-turning.     

Characteristics of tephra from cinder cone,Lassen volcanic National Park,California

Cinder Cone, an undissected, 200 m high Holocene cone in Lassen Volcanic National Park, California, is mantled by basaltic blocks and bombs, including abundant large spherical accretionary bombs. Types of pyroclasts, ranging from light brown sideromelane droplets to blocky, crystalline tachylite fragments, appear to reflect the vent history; when the vent was clear, an abundance of lava was erupted at higher temperature and lower viscosity, producing predominantly rapidly chilled sideromelane droplets. When the vent was blocked by pooling of lava or by slumping of talus from crater walls, intermittent Strombolian eruptions ejected more viscous, crystalline to tachylitic fragments and comminuted talus. Such activity has been observed at Mt. Etna, Italy and Heimaey, Iceland. Avalanching of debris into the crater and down outer slopes, one of the main processes in cinder cone formation, isalso responsible for thevarieties of pyroclast types formed during Strombolian eruptions.     

Phreatic eruption clouds: the activity of la Soufrière de Guadeloupe,F.W.I., August — October, 1976

From August to October, 1976, La Soufrière de Guadeloupe was observed, and recorded with an automated sequence camera and numerous handheld cameras. During the period of observation, the nature of volcanic activity ranged from mild steam emission to moderately energetic phreatic eruptions. Background fumarolic activity (steam emission) was characterized by the emission of generally tephra-free steam clouds 50 to 150 m above the summit. The clouds rose buoyantly above the vent and were blown downwind at prevailing wind velocities. Phreatic eruptions were well-documented on September 22, October 2, and October 4. In the latter two eruptions, small bursts of tephra-laden steam erupted at intervals of 30 to 45 min, and rose from 350 to 500 m above the summit. In the largest observed eruption, that of October 2, the steam and tephra cloud rose to a maximum height of 600 to 650 m in 20 min. A white vapor cloud and a medium gray, tephra-laden cloud were erupted simultaneously from the summit vent and both were surrounded by a vapor collar: the clouds were thoroughly mixed within 1 km downwind of the summit. The concurrent growth of clouds from separate vents (summit and flank) implies a common source. Simultaneous eruption of tephra-free and tephra-laden clouds from the same vent is puzzling and implies: (i) lateral changes in the degree of alteration of dome rocks along the elongate vent, hence erodability of the dome lavas, or (ii) differences in the gas velocities. These «mixed» clouds moved westward, downwind and downslope as a density current, along the watersheds of the R. Noire and R. des Pères with an approximate velocity of 10 to 25 m/sec. Upon reaching the sea the clouds continued to move forward, but at a decreased velocity, and spread laterally, having left behind the restrictions of valley walls. A thin gray veneer of moist tephra, ranging from several cm thick near the dome to less than 1 mm thick several km downwind, was deposited along a narrow corridor southwest of the summit. Tephra from the phreatic eruptions consisted mostly of hydrothermally altered lithic, mineral, and glass fragments derived from dome lavas; no fresh (juvenile) pyroclasts were present in the tephra. Absence of juvenile tephra at La Soufrière supports the view that activity was due to groundwater circulating in a vapor-dominated geothermal system, probably driven by a shallow heat source. At La Soufrière, most vapor-dominated systems are located in elevated areas of groundwater recharge where groundwater movement is downward and outward. The sporadic phreatic eruptions may be related to the rate of recharge of meteoric waters within the dome, the decrease in pore pressure during fortnightly tidal minimums or both. Whatever the triggering mechanism, vapor-dominated fluids eroded vent walls during phreatic eruptions and carried out fine-grained, hydrothermally altered, pre-existing dome material as tephra.