Current-scattered (?) detrital remanence directions in the Zn-rich Pennsylvanian Stark black shale, USA

Palaeomagnetic results are reported from the metalliferous Stark black shale in the Upper Pennsylvanian (Missourian/Kasimovian) Kansas City Group. Palaeomagnetic analysis of 400 specimens from 28 sites gives a characteristic remanent magnetization in 17 sites of the shale that yields a Late Mississippian to Middle Pennsylvanian palaeopole at 32.2°N 128.5°E (dp = 4.7° and dm = 8.8°). The observed palaeomagnetic age is slightly older than the host rock, indicating that the mineralization of the Stark Shale has, excluding recent alteration, a primary sedimentary or syngenetic origin. The reason for the slightly older age is likely due to trace modern hematite that slightly steepens the remanence inclination. The large oval of 95 per cent confidence is interpreted to be caused by clay–magnetite aggregates that formed during sediment transport and the biasing effect of the gentle palaeocurrent at each site acting on the large aggregates. Therefore, the scattered distribution of the site mean remanence declinations found for the Stark Shale is evidence of a detrital remanent magnetization that is formed by primary sedimentary processes with an enriched metallic content and not remagnetization with mineralization by secondary hydrothermal processes.     

Dating of thaw depths in permafrost terrain by the palaeomagnetic method: experimental acquisition of a freezing remanent magnetization

The acquisition of a freezing remanent magnetization (FRM) has been studied in controlled magnetic and thermal environments by successive freezing and thawing (−18 to +20°C) of samples of natural sediments from a frost polygon near Ny Ålesund, Spitsbergen. Successive freeze-thaw cycles cause a significant decrease in the intensity of the initially induced shock remanent magnetization (SRM), associated with directional trends towards the ambient magnetic field direction during the freezing phase. A slow increase in intensity commences after seven to 10 freeze-thaw cycles. The acquisition of a FRM in samples carrying an isothermal remanent magnetization shows a significantly smaller reduction in intensity and only minor directional variations. This result indicates that only a fraction of the magnetic grains in a natural sediment contributes to the natural remanent magnetization. Insignificant changes in lengths and directions of the principal susceptibility ellipsoid axes also indicate that magnetic fabric and remanent magnetization are carried by partly different populations of magnetic grains.
The acquisition of a FRM in nature has yet to be explored. If such a process is confirmed, however, it has the potential for obtaining age estimates of ancient thaw depths and for providing insights into material transport processes in frost polygons.     

A detailed record of normal-reversed-polarity transition obtained from a thick loess sequence at Jiuzhoutai, near Lanzhou, China

A record of normal-reversed-polarity transition has been obtained from a 4 m thickness of loess exposed at a section near Lanzhou, China. Magnetostratigraphic studies suggest it may represent a reversal bounding the onset of a reversed-polarity zone within the Jaramillo Normal Subchron. The natural remanent magnetization consists of two components: a low-coercivity (≤20mT), low-unblocking-temperature (≤300°C) component of viscous origin and a high-coercivity (>20mT), high-unblocking-temperature (250–700 °C) component carrying the characteristic remanence. Mineral magnetic analyses confirmed the presence of magnetite, its low-temperature oxidation products and haematite, each contributing to the remanence properties. Grain size and concentration showed limited variations and there was little evidence for the presence of the ultrafine magnetic phase commonly associated with palaeosol formation. Pedogenic processes appeared negligible and their effects unimportant, with detrital processes dominating the mineralogy and most probably the acquisition of the characteristic remanence. The reversal record was characterized by the decay and recovery of the geocentric axial dipole term with large directional swings occurring during periods of reduced relative palaeofield intensity. The virtual geomagnetic poles traced a complex path exhibiting no particular geographical confinement. Relative palaeofield intensity determinations were insensitive to the choice of normalization parameter and showed a distinctive asymmetry. Striking similarities were observed with the Matuyama-Jaramillo reversal record, obtained from the same section (Rolph 1993), and the Steens Mountain reversal record (Prévot el al. 1985), lending further support for the existence of unusually high post-transitional field intensities     

Gyroremanent magnetization and the magnetic properties of greigite-bearing clays in southern Sweden

The acquisition of a gyroremanent magnetization (GRM) by single-domain (SD) greigite particles during alternating-field (AF) demagnetization is demonstrated. Previous palaeomagnetic studies failed to identify the presence of authigenic greigite in the glacio-marine clays studied. These clays formed the subject of an earlier debate about the validity of a Late Weichselian geomagnetic excursion (the Gothenburg Flip) in southern Sweden. The greigite carries a stable chemical remanent magnetization (CRM), which coexists with a detrital remanent magnetization (DRM) carried by magnetite. AF demagnetization could not isolate the primary remanence in the sediments where magnetite and greigite coexist, due to the overlapping coercivity spectra of the two minerals and the inability to determine the time lag between sediment deposition and CRM formation. Thermal demagnetization removed the CRM at temperatures below 400 C, but this method was hindered by the unconsolidated nature of the sediments and the formation of secondary magnetic minerals at higher temperatures. The results suggest that the low-coercivity DRM carried by magnetite was mistaken for a 'viscous' component in the earlier studies. Hence the former debate about the record of the Gothenburg Flip may have been based on erroneous palaeomagnetic interpretations or non-reproducible results. AF demagnetization procedures applied to samples suspected of bearing SD magnetic particles (such as greigite) should be carefully selected to recognize and account for GRM acquisition.     

An investigation of the scattered remanent magnetization of the Dunnet Head sandstone

Summary. The directions of remanent magnetism of samples of the Dunnet Head sandstone from Scotland are very scattered on a scale down to a few millimetres, although an overall mean direction is reasonably well defined. The scattered directions show considerable stability against thermal demagnetization and there is evidence that haematite pigment is an important carrier of the remanence. It is concluded that the origin of the inhomogeneous magnetization is a disturbed ambient field during acquisition of chemical remanence by the pigment.     

A magnetization process of sediments: laboratory experiments on post-depositional remanent magnetization

Summary. Palaeomagnetic studies require a theory of magnetization mechanism of sediments and a method of estimating magnetic field intensity from their remanences. This paper establishes a physical basis for the generation of the remanence in deep-sea and lake sediments experimentally.
Redeposition experiments have been carried out under centrifugal force in weak magnetic fields. The centrifuging method produces post-depositional remanent magnetization (post-DRM) in the compacted sediment, and its remanence and susceptibility are compatible with those of natural sediments and reconstituted materials of other redepositional experiments. Three properties of the post-DRM have been deduced from the experiments: (1) the efficiency of acquisition of post-DRM decreases with increase in density during the compaction process, (2) the total post-DRM is equal to the sum of the partial post-DRM (addition law), and (3) time is not a substantial factor for alignment of the magnetic particles. These results lead to the conclusions that the magnetic particles do not rotate steadily but in a series of steps, and that the density change is the crucial factor giving rise to the post-DRM.
A mathematical formula representing the remanence record in sediments is proposed on the basis of the experimental results and the model. The principal equation is expressed as an integral of the product of three parameters over time when sediments have been compacted; the field intensity variation, characteristic function of the sediment and the time derivative of the density change.     

Magnetostratigraphy of mid-Cretaceous limestones from the Sierra Madre of northeastern Mexico

We present the results of a palaeomagnetic study of four mid-Cretaceous limestone sections exposed in northeastern Mexico. The limestones are weakly magnetized and exhibit two- to three-component magnetizations. These magnetization components appear to be carried by both a sulphide mineral and a magnetite-titanomagnetite mineral. The sulphide mineral carries a reverse polarity overprint that often makes it difficult to isolate definitively the higher-unblocking-temperature component. The high-unblocking-temperature component is well defined in the upper portion of the Santa Rosa Canyon section and in the Cienega del Toro section and passes the fold test. The characteristic remanent magnetization (ChRM) inclinations agree well with predicted mid-Cretaceous inclinations for these sites, although the declinations differ by more than 100°. The relative rotation between these two sites probably occurred as the thrust sheets were emplaced during Laramide deformation. At two of the sections, namely Cienega del Toro and the overturned Los Chorros sections, only normal polarity directions are observed. The La Boca Canyon and Santa Rosa Canyon sections exhibit zones of both normal and reverse polarity magnetization. Correlation of these polarity zones with the geomagnetic polarity timescale provides a time framework for lithostratigraphic and palaeoceanographic studies of these sections.     

The detection of single-domain greigite (Fe3S4) using rotational remanent magnetization (RRM) and the effective gyro field (Bg): mineral magnetic and palaeomagnetic applications

The intensity of rotational remanent magnetization (RRM) acquired by single-domain greigite at a rotation frequency of 5 rps was combined with measurements of anhysteretic remanent magnetization (ARM) to calculate the effective biasing field ( Bg ) that produced the RRM. Samples of single-domain greigite had Bg values between -137 and -84 μT, and a MDF_RRM of c. 80 mT. By contrast, a suite of natural and synthetic ferrimagnetic iron oxide samples, including single-domain magnetite and y Fe₃O₄ tape particles, acquired Bg values between -3 and -14 μT, and MDF_RRM ranged between 43 and 68 mT (when RRM was acquired). Multidomain magnetite did not acquire a RRM. Bg values at 5 rps were calculated from previously published data for magnetite particles of different grain sizes, which revealed a minimum Bg value of -24 μT and a MDF_RRM of 57 mT for the finest fraction (0.2-0.8 μm in diameter). In a geological example, measurements of Bg and MDF_RRM were used to detect the presence of greigite in a 4 m long Late Weichselian sediment core. Variations in inclination, declination and the intensity of the natural remanent magnetization (NRM) correlate with changes in magnetic mineralogy.     

Laboratory studies of depositional DRM

Summary. Acquisition of magnetic remanence in slurries of fme grained organic muds settling in long tubes is investigated using a cryogenic magnetometer. The average settling behaviour of remanence carrying grains relative to the whole sediment gives information about the relative magnetic grain size spectrum, whereas the response of settled deposits to vibration gives an indication of the degree of alignment of particles and their average shape.
Two classes of behaviour are apparent in both the time and field dependence of detrital remanent magnetization (DRM) acquisition. Dilute slurries settling in the Earth's field (analogous to detrital sedimentation) acquire a remanence which reaches a maximum after about 2 day, whereas for concentrated slurries (analogous to slumped or bioturbated sediments) this takes only a matter of minutes. The field dependence of DRM in dilute slurries is in plausible quantitative agreement with Stacey's extension of the classical Langevin expression for the susceptibility of a paramagnetic gas, whereas concentrated slurries show a quasi-linear dependence of DRM on the applied field. Inclination errors are generally absent, but do appear in fields less than about 0.5 Oe, and when the magnetic fraction settles out preferentially. A weak negative dependence of DRM on temperature is found, but the results are too crude to provide a further test of Stacey's theory.
Remanence acquisition in slurries settled in zero field indicates that short term post-depositional magnetization processes are relatively unimportant in slurries that have ceased to compact rapidly. A large increase in remanence from naturally occurring sediments to slowly redeposited long cores, to rapidly settled slurries is best explained as a feature of compaction.     

Rotational remanent magnetization (RRM) and its high temporal and thermal stability

The time and temperature stability of various types of magnetic remanence has been measured in pottery samples containing magnetite and in a clay sample containing manganese ferrite. The time decay of rotational remanent magnetization (RRM), anhysteretic remanent magnetization (ARM) and a low-field isothermal remanent magnetization (IRM) has been measured. While the decay of the last two remanences is easily measurable at about 2 and 19 per cent per decade of time, respectively, the decay of RRM is too small to be measured, being less than about 0.1 per cent per decade of time. Thermal demagnetization of thermoremanent magnetization (TRM), ARM and RRM indicates that RRM is also the most thermally stable. The implications of these experiments are that rocks which exhibit gyromagnetic effects such as RRM contain highly stable particles and therefore are likely to be most suitable for palaeomagnetism.     

Are hydrodynamic shape effects important when modelling the formation of depositional remanent magnetization?

Recent conceptual models have attributed the weak depositional remanent magnetizations observed in natural sediments to flocculation processes in the water column. Magnetic particles included into flocs have not only to rotate themselves into alignment with the geomagnetic field but also the larger particles to which they are attached, making remanence acquisition an inefficient process. Alignment is hindered further when the magnetization vectors of the particles in any given floc partially cancel, reducing the overall magnetic torque. Existing numerical simulations of flocculation effects on depositional remanence formation have been limited to spherical bodies with translational and rotational motion acting independently of each other. In the case of non-spherical flocs, the translational and rotational motion are coupled and such bodies will describe a complex trajectory through the water column. Calculations will be presented that show the torque exerted on a non-spherical floc by the surrounding water can be orders of magnitude greater than the magnetic torque. Non-spherical flocs will, therefore, align less efficiently with the geomagnetic field and hydrodynamic effects may play an important role in controlling the magnitude of sedimentary remanence.     

A PALAEOMAGNETIC STUDY OF JURASSIC AND CRETACEOUS SEDIMENTS

Summary. Representative samples of Cretaceous and Jurassic arenaceous rocks and some Jurassic limestone samples were collected. The arenaceous rocks were generally either too weakly magnetized for the measurement of their remanent magnetization, or were unstable; higher intensities of magnetization were recorded in the limestones. The magnetic directions of the few reversed Jurassic limestones indicate a pole position near Omsk. X-ray analysis indicates that the detrital iron ore mineral present was goethite. It is concluded that the palaeomagnetic unsuitability of these Jurassic and Cretaceous deltaic deposits results from the weathering conditions in the source area.     

Further reliability tests for determination of palaeointensities of the Earth's magnetic field

Summary. In palaeomagnetic studies of volcanic rocks it is often considered that, if the direction of NRM does not change much and the intensity de-creases gradually and smoothly during ac cleaning, then the remanent magnetization is stable and chiefly composed of TRM. This argument is extended as a consistency check to detect unwanted effects during laboratory heating. A simple procedure which employs orientated samples and a short heating (15 min) for TRM acquisition in the laboratory has been used for determining the ancient geomagnetic field intensity using seven volcanic rocks of Late Cenozoic age from central Mexico. The main reliability tests are based on the stability of direction, the close correspondence of the entire coercitivity spectra of both NRM and TRM to ac demagnetization, the low scatter of TRM directions, close correspondence of the TRM directions and the direction of the laboratory magnetic field, proportionality of TRM intensities to applied field, susceptibility comparison before and after heating, and the within-unit consistency of palaeointensity determinations.     

Palaeomagnetism of limestones from the Gargano Peninsula (Italy), and the implication of these data

The platform limestones of Apulia are usually too weakly magnetic for precise measurement. The East Gargano basin is an autochthonous extension of Apulia and incorporates deeper water limestones which, though weakly magnetic ( J NRM ≃ 50 nG), can be reliably measured using a cryogenic magnetometer. The magnetization is attributed to the presence of detrital magnetite and the pelagic limestones yield a mean magnetic direction for the Late Cretaceous (Dec. = 335°, Inc. = 38°, α₉₅= 6.5°). The circle of confidence associated with this direction overlaps with those associated with Late Cretaceous magnetic directions from Iblei (Sicily) and from the Vicentinian (Southern) Alps. Palaeomagnetic pole positions for Iblei, Gargano/Apulia and the Southern Alps indicate that these three autochthons need not have rotated significantly relative to each other since the Late Cretaceous. An inferred Late Cretaceous pole position for Africa coincides with the pole positions obtained from these Italian data.     

The palaeomagnetism and magnetic fabric of sediments from Peak Cavern, Derbyshire

Summary. This paper describes the magnetic remanence and susceptibility anisotropy of 42 samples of laminated clay from Peak Cavern. The sediments are shown to have acquired a stable remanent magnetization due to the depositional alignment of magnetite grains. The magnetic fabric data confirm the existence of alteration within a reddened surface layer. A record of geomagnetic secular variation in the underlying clay is compared to a dated lake sediment magnetostratigraphy to suggest that deposition occurred around 7000 yr bp . A method for estimating water current directions based on the remanence and magnetic fabric data is critically assessed before deducing the sense of palaeoflow in the cave.     

Decay of a post-depositional remanent magnetization in wet sediments due to the effect of drying

Summary. The decay of the post-depositional remanent magnetization (post-DRM) during desiccation in magnetic field free space is measured as a function of the loss of water. The decay is ascribed to the drying effect and the time decay of viscous remanent magnetization (VRM). The VRM forms only 10 per cent of the total of loss of remanent magnetization. The decay due to the drying effects depends both on the loss of water and on either the evaporation rate or the period of storage. The percentage of loss of magnetization is independent of its intensity.
A critical drying stage appears (about 60 per cent in water content on a dry basis) which is characterized as a vanishing point of mobile particles or particle units. The mobile particles or units play an important role both in acquisition and demagnetization through physical rotational motion within wet sediments before the critical drying stage. More than 80 per cent of the total loss of the post-DRM is destroyed before the desiccation proceeds to the critical drying stage. The decay of post-DRh4 is concluded to be mainly due to the physically random rotation of the magnetic particles trapped in shallow energy wells which are overcome by the torques caused by the application of the alternating magnetic field less than 200 Oe.     

An experiment relating to rotational remanent magnetization and frequency of demagnetizing field

Summary. Several tests have been carried out to investigate how the generation of rotational remanent magnetization depended on the frequency of the applied demagnetizing field. The equipment used is described. The investigation was carried out using two specimens, one being a synthetic specimen of magnetite, and the other a cylindrical rock sample. These specimens gave virtually identical behaviour with varying frequency, unlike the differing behaviours reported previously by Wilson & Lomax. For each of the separate alternating field frequencies used (ranging from 50 to 1210 Hz), as the rotational speed of each specimen was reduced from 0.1 cycle s⁻¹, the corresponding rotational remanent magnetization increased to a maximum value when the rotational speed was in each case just a little greater than 0.01 cycle s⁻¹, after which the rotational remanence decreases as the rotational speed decreases.     

Lower Cretaceous magnetic stratigraphy in Umbrian pelagic carbonate rocks

Summary. A record of geomagnetic field polarity for the Barremian, Aptian and Albian stages of the Early Cretaceous has been derived in three over-lapping sections of pelagic carbonate rocks in the Umbrian Apennines of northern Italy. The remanence carrier in the greyish-white Majolica limestone and Fucoid Marls is magnetite, with haematite also an important constituent in a zone of 'couches rouges' within the Fucoid Marls. The weak remanent magnetizations were measured with a cryogenic magnetometer. Alternating field or thermal demagnetization was used to isolate the characteristic remanent magnetization (ChRM) in 655 specimens from 248 stratigraphic levels. The samples respond positively to a tectonic fold test, indicating that the ChRM predates the Late Tertiary folding of the Umbrian sequence. The magnetic stratigraphy derived from variations of virtual geomagnetic pole latitude clearly defines the recognizable reversal pattern associated with Mesozoic marine magnetic anomalies M0 to M4. The sections have been zones palaeontologically on the basis of planktonic foraminifera and calcareous nannofossil assemblages. The ages of magnetic anomalies M0 to M4 determined in this way are somewhat older than those in the reversal time scale of Larson & Hilde (1975). Anomaly M0 is located in the Early Aptian, close to the Aptian/Barremian boundary. A long period of normal polarity in the Aptian and Albian corresponds to the early part of the Cretaceous magnetic quiet zone. It is interrupted in the Late Aptian by a reversal which we find in only one of the Fucoid Marl sections, and which has not been reported in oceanic magnetic anomaly investigations.     

Some aspects of magnetic viscosity in subaerial and submarine volcanic rocks

Summary. The magnetic viscosity of 334 Upper Tertiary and pre-Bruhnes Quaternary volcanic rocks from the Massif Central (France) and the Steens Mountain (Oregon), and of 40 basaltic cores from DSDP leg 37 has been investigated. Thellier's viscosity index follows a log normal distribution with mean values equal to 6 and 3.5 per cent for subaerial and submarine rocks respectively. For subaerial rocks, the average intensity of the viscous remanent magnetization (VRM) acquired in the Earth's field since the beginning of the Bruhnes polarity epoch ( t = 0.7 Myr) is estimated to be equal to one-quarter of the average intensity of the primary remanence. Alternating field demagnetization of VRMs acquired in low fields for acquisition times t ranging from 2 day to 32 month indicates the resistance to alternating fields is quite different from sample to sample and increases linearly with log t.
Néel's diagnostic parameter of domain structure of the grains involved in magnetic viscosity shows that hard VRM is carried by single-domain grains and soft VRM carried by multidomain particles. Single domain particles carrying hard VRM in subaerial volcanic rocks are almost equant magnetite intergrowths with size near the superparamagnetism threshold, resulting from high temperature oxidation of titanomagnetite. Soft VRM is carried by low Curie point homogeneous titanomagnetite. Unlike his single domain theory, Néel's multidomain theory of magnetic viscosity does not account quantitatively for the resistance of VRM to alternating fields.     

Palaeomagnetism of the Lower Cretaceous Sierra De Los Condores Group Cordoba Province Argentina

Measurements are described of the directions of remanent magnetization of 89 samples from nine lava flows and red beds. Stable remanent magnetization was isolated after AC demagnetizing. All the units have normal remanent magnetization, except one lava flow which yields a direction toward the north with positive inclination. From the mean direction of stable remanence, referred to the bedding, of each unit a virtual geomagnetic pole is computed; the mean of eight of these poles is 90·6 °E, 84·2° South, α₉₅= 4·7° and represents the position of the palaeomagnetic pole for the exposures of the Sierra de Los Condores group from El Estrecho-Cerro Libertad. The position of this pole is reasonably close to the positions of the South American Lower Cretaceous palaeomagnetic poles for the Serra Geral and Vulcanitas Cerro Colorado formations and the trachybasaltic dykes from Rio Los Molinos. This supports the interpretations that the South Atlantic Ocean was formed in Lower Cretaceous times and that the Earth's magnetic field was on average similar to that of a geocentric dipole in South America in the Lower Cretaceous, and suggests that there has not been substantial relative movements between Central Argentina and Southern Brazil.