The importance of energetic particle precipitation on the chemical composition of the middle atmosphere

An assessment is made of the relative contribution of certain classes of energetic particle precipitation to the chemical composition of the middle atmosphere with emphasis placed on the production of odd nitrogen and odd hydrogen species and their subsequent role in the catalytic removal of ozone. Galactic cosmic radiation is an important source of odd nitrogen in the lower stratosphere but since the peak energy deposition occurs below the region where catalytic removal of O₃ is most effective, it is questionable whether this mechanism is important in the overall terrestrial ozone budget. The precipitation of energetic solar protons can periodically produce dramatic enhancement in upper stratospheric NO. The long residence time of NO in this region of the atmosphere, where catalytic interaction with O₃ is also most effective, mandates that this mechanism be included in future modelling of the global distribution of O₃. Throughout the mesosphere the precipitation of energetic electrons from the outer radiation belt (60°70°) can sporadically act as a major local source of odd hydrogen and odd nitrogen leading to observable O₃ depletion. Future satellite studies should be directed at simultaneously measuring the precipitation flux and the concomitant atmosphere modification, and these results should be employed to develop more sophisticated models of this important coupling.     

The atmospheric effects of October 2003 solar proton event simulated with the chemistry–climate model SOCOL using complete and parameterized ion chemistry

October 2003 solar proton events (SPE) is rather well covered by the observations; therefore its studies represent a good way for model validation and intercomparison. Here we apply chemistry–climate model (CCM) SOCOL with complete (SOCOLⁱ) and parameterized ion chemistry to evaluate the accuracy of a commonly used ion chemistry parameterization scheme. We performed ensemble experiments with and without SPE to characterize the effect of the October 2003 SPE on the NO_x, HO_x, ClO_x and O₃ in the middle atmosphere. Preliminary comparison of the simulated effects against MIPAS observations revealed rather good general agreement for most of the species. Comparison of the results obtained with complete and parameterized ion chemistry representation showed that the model with parameterized ion chemistry underestimates the effect of SPE on chemical composition of the middle atmosphere by up to 40% for NO_x and N₂O, up to 70% for HO_x and ClO_x and up to 600% for HNO₃. The parameterization is more accurate for ozone, however the model with parameterized ion chemistry underestimates ozone depletion by up to 15% during the SPE in the mesosphere and by 10% 2 weeks later in the stratosphere, which can be important for the long-term effects of SPE on the ozone layer.     

Photodissociation rates in the atmosphere below 100km

In this survey we consider the atmospheric photodissociation rates of the molecules, O₂, O₃, NO, NO₂, N₂O, N₂O₅, HNO₃, HO₂, H₂O, H₂O₂, CO₂, CH₄, CH₂O, SO₂, and H₂S. Data for the absorption cross sections and quantum yields of these molecules are assembled here along with other information pertinent to the determination of photodissociation rates. The most recent techniques for computing atmospheric photodissociation rates are discussed. Photodissociation rates for all of the molecules are given at several solar zenith angles for altitudes up to 100 kilometres. A knowledge of the photodissociation rates of atmospheric molecules is essential to the resolution of many important atmospheric problems. Pollution of the stratosphere by high-flying aircraft, and of the troposphere by other anthropogenic activities, can only be described in terms of complex photochemical-dynamical models in which photolytic processes have a dominant role. A great deal of scientific effort is presently being spent in determining the mechanisms which control ozone, nitric oxide, and excited molecular oxygen concentrations in the mesosphere. Photolytic processes are already known to be important to all of these species. The photodissociation rates presented here can be applied directly to atmospheric problems such as these, or the methodology and data contained in this work can be used to compute photorates as needed.     

SMLTM simulations of the diurnal tide: comparison with UARS observations

Wind and temperature observations in the mesosphere and lower thermosphere (MLT) from the Upper Atmosphere Research Satellite (UARS) reveal strong seasonal variations of tides, a dominant component of the MLT dynamics. Simulations with the Spectral mesosphere/lower thermosphere model (SMLTM) for equinox and solstice conditions are presented and compared with the observations. The diurnal tide is generated by forcing specified at the model lower boundary and by in situ absorption of solar radiation. The model incorporates realistic parameter-izations of physical processes including various dissipation processes important for propagation of tidal waves in the MLT. A discrete multi-component gravity-wave parameterization has been modified to account for seasonal variations of the background temperature. Eddy diffusion is calculated depending on the gravitywave energy deposition rate and stability of the background flow. It is shown that seasonal variations of the diurnal-tide amplitudes are consistent with observed variations of gravity-wave sources in the lower atmosphere.     

On the latitudinal variations of the non-periodic response of minor species induced by a dissipative gravity-wave packet in the MLT region

A spectral full-wave model and a two dimensional (2-D), time dependent, fully nonlinear chemistry model were used to investigate the latitudinal variations of the wave effects on the minor species in the OH chemistry in the mesosphere/lower thermosphere region. A dissipative gravity-wave packet is launched at three different latitudes propagating upward through the OH nightglow emission layer in the northern hemisphere. In addition to causing the minor species densities to fluctuate, the wave packet also causes non-periodic secular variations of the minor species densities as a consequence of violation of the non-acceleration conditions due to wave transience and dissipation. The associated fluxes of minor species are downward, and consequently minor species densities typically decrease at higher altitudes and increase at lower altitudes. The downward flux and subsequent chemical recombination of atomic oxygen is particularly important and can itself cause large secular variations of other less abundant minor species. Our studies indicate that the wave-induced non-periodic, secular variations are largest at high latitudes, second largest at low latitudes, and smallest at mid-latitudes.     

On the application of a proposed global system for measuring meteor winds

Summary This paper discusses the need for a global network of meteor wind stations for determining the general circulation of the upper mesosphere and lower thermosphere. Continuous observations of horizontal motions from such a network would permit resolution of planetary scale eddy winds, tides, and gravity waves, and hypotheses that such motions propagate vertically from the lower atmosphere or are generated in situ by solar activity could be examined critically with observational data. The observed mean winds from the lower stratosphere to the meteor wind level are summarized to support the hypothesis that a standing wave pattern in the winds extends into the lower thermosphere. Data on tidal meridional momentum transports from meteor wind stations suggest that tides in the lower thermosphere are important for the maintenance of mean winds. Some of the geomagnetic and photochemical processes in the lower thermosphere that could be investigated with meteor wind data are briefly reviewed.This paper is adapted from our presentation at the 1966 Fall URSI meeting at Palo Alto, California     

Observation of the shadow of O3 on the D Layer in the lonospheric VLF guide over the atlantic ocean

Abstract

Detailed studies have been made of the sudden increase of the phase velocity of radio waves observed at sunrise in the 10 kH band, when optical path and terminator are crossing together at a small angle along the 12,000 km line between the ground based station of Caen (France) and the Loran transmitter at Trelew (Argentina). Assuming that the increase of electron density in the lower part of the E layer at twilight is mainly due to electron detachment of O^? ₂ by collision with newly created O(³P) and O₂(¹Δg), we analyse the specific contributions of the hard and soft components of the Hartley band and the far end of Schumann-Runge band to the amount of these constituents by action on molecular O₂ and O₃ between 80 and 90 kilometers. Using an exponential distribution of O₃ supposed to be responsible for the U.V. screening above 60 km, we discuss preliminary results of daily measurements of the mean total mass of O₃ in the mesosphere between 49°N and 45°S, by the end of every December night (in 1975 and 1976).     

Sensitivity of the Earth’s middle atmosphere to short-term solar variability and its dependence on the choice of solar irradiance data set

We simulate the time evolution of the neutral and charged species in the terrestrial middle atmosphere using a 1-D radiative-convective model with interactive neutral and ion chemistry driven by four different sets of daily spectral solar irradiance (SSI) available in the literature for the year 2000. Obtained daily time series of ozone, hydroxyl and electron densities are used to calculate their sensitivity to the short-term SSI variability at 205 nm. All applied SSI data sets possess 27-day solar rotation cycle; however, its amplitude and phase as well as the correlation between considered SSI time series differ among data sets leading to the different behavior of the atmospheric response. Contrary, the ozone and hydroxyl sensitivities to the SSI changes during solar rotation cycle are almost identical for all applied SSI data sets in the stratosphere. In the mesosphere, the difference in correlation between SSI in Herzberg continuum and Lyman-α line in considered SSI data sets leads to substantial scatter of the sensitivity estimates based on 205 nm. Our results show that for the sensitivity analysis in the stratosphere based on the SSI at 205 nm any considered SSI data sets can be applied. For the mesosphere, where the sensitivity strongly varies among applied SSI data sets more robust results can be obtained using the sensitivity calculations based on the SSI in Lyman-α line.     

O2 density and temperature profiles retrieving from direct solar Lyman-alpha radiation measurements

The resonance transition ²P-²S of the atomic hydrogen (Lyman-alpha emission) is the strongest and most conspicuous feature in the solar EUV spectrum. The Lyman-alpha radiation transfer depends on the resonance scattering from the hydrogen atoms in the atmosphere and on the O₂ absorption. Since the Lyman-alpha extinction in the atmosphere is a measure for the column density of the oxygen molecules, the atmospheric O₂ density and temperature profiles can be calculated thereof. A detector of solar Lyman-alpha radiation was manufactured in the Stara Zagora Department of the Solar-Terrestrial Influences Laboratory (STIL). Its basic part is an ionization camera, filled in with NO. A 60 V power supply is applied to the chamber. The produced photoelectric current from the sensor is fed to a two-channel amplifier, providing analog signal. The characteristics of the Lyman-alpha detector were studied. It passed successfully all tests and the results showed that the so-designed instrument could be used in rocket experiments to measure the Lymanalpha flux. From the measurements of the detector, the Lyman-alpha vertical profile can be obtained. Programs are created to compute the O₂ density, atmospheric power and temperature profiles based on Lymanalpha data. The detector design appertained to ASLAF project (Attenuation of the Solar Lyman-Alpha Flux), a scientific cooperation between STIL—Bul.Acad.Sci., Stara Zagora Department and the Atmospheric Physics Group at the Department of Meteorology (MISU), Stockholm University, Sweden. The joint project was part of the rocket experiment HotPay I, in the ALOMAR eARI Project, EU’s 6th Framework Programme, Andøya Rocket Range, Andenes, Norway. The project is partly financed by the Bulgarian Ministry of Science and Education.     

Changes in the chemical composition of the atmosphere in the polar regions of the Earth after solar proton flares (3d modeling)

The paper presents the results of numerical photochemical simulations of the impact of the most powerful solar proton flares during the 23rd solar cycle on the ozonosphere in the polar regions of the Earth. A global 3D photochemical model, CHARM, developed at Central Aerological Observatory (CAO) was used in the simulations. The model introduces an additional source of nitrogen atoms and OH radicals. These components are formed due to the ionization effect of solar protons in the Earth’s atmosphere. The ionization rate was determined from data on proton fluxes measured by GOES satellites. The production rate of additional NO _x and HО _x molecules per ion pair was based on published theoretical studies. It is shown that the most intense flares in the 23rd solar cycle (2000, 2001, and 2003) destroyed ozone in the mesosphere to a great extent (sometimes completely, for example, during the July 14, 2000, event). It is found that the response of ozone to solar proton events follows a seasonal pattern. For the first time, the long-term effect of solar proton events is identified; it is approximately one year.     

On the theoretical model for vertical ozone density distributions in the mesosphere and upper stratosphere

Diurnal variations in the vertical ozone density distribution have been calculated for the height range 40–150 km by extending our existing computer programs. The steady-state profiles were first calculated for fifteen constituents in the original program and three additional constituents (CH₄, CO and CO₂); the result was used as the initial condition for the time-dependent solution. The profile of the eddy diffusion coefficient used in this study was determined by comparing the model profile with the observations for CH₄, whose density distribution is verysenstive to the eddy diffusion coefficient The effects of hydrogen and nitrogen compounds on the ozone density are discussed somewhat quantitatively; they reduce the ozone density mainly in the mesosphere and stratosphere, respectively. Special attention is given to the large depression of the ozone density at around 70–85 km, which has been obtained in many theoretical models but has neither been explained nor definitely confirmed by observations. Our time-dependent model indicates that the depression develops at night by the effect of hydrogen-oxygen and nitrogen-oxygen reactions and of eddy diffusion transports. The latter effect also produces an increase of the ozone density after midnight at some heights in the depression region.     

Middle atmosphere dynamics with gravity wave interactions in the numerical spectral model: Zonal-mean variations

It is generally accepted that small-scale gravity waves (GW) produce the observed reversals in the zonal circulation and temperature variations of the upper mesosphere (e.g., Lindzen, 1981). There is evidence that GW also play an important role in the quasi-biennial oscillation (QBO) of the lower stratosphere, which can be generated by planetary waves (Lindzen and Holton, 1968). In the present paper, we summarize the modeling studies with the mechanistic numerical spectral model (NSM), which incorporates the Doppler spread parameterization for GW (Hines, 1997a, Hines, 1997b). Our studies illuminate the importance of GW filtering and momentum deposition associated with critical level absorption and wave braking. Numerical results from the 2D and 3D versions of the NSM show how these wave interactions generate in the zonal-mean: (a) annual and semi-annual oscillations, (b) QBO with related semi-decadal oscillation and solar cycle effects, and (c) monthly intra-seasonal oscillations.     

On the Use of VLF Narrowband Measurements to Study the Lower Ionosphere and the Mesosphere–Lower Thermosphere

The ionospheric D-region (~60 km up to ~95 km) and the corresponding neutral atmosphere, often referred to as the mesosphere–lower thermosphere (MLT), are challenging and costly to probe in situ. Therefore, remote sensing techniques have been developed over the years. One of these is based on very low frequency (VLF, 3–30 kHz) electromagnetic waves generated by various natural and man-made sources. VLF waves propagate within the Earth–ionosphere waveguide and are extremely sensitive to perturbations occurring in the D-region along their propagation path. Hence, measurements of these signals serve as an inexpensive remote sensing technique for probing the lower ionosphere and the MLT region. This paper reviews the use of VLF narrowband (NB) signals (generated by man-made transmitters) in the study of the D-region and the MLT for over 90 years. The fields of research span time scales from microseconds to decadal variability and incorporate lightning-induced short-term perturbations; extraterrestrial radiation bursts; energetic particle precipitation events; solar eclipses; lower atmospheric waves penetrating into the D-region; sudden stratospheric warming events; the annual oscillation; the solar cycle; and, finally, the potential use of VLF NB measurements as an anthropogenic climate change monitoring technique.     

Seasonal features in the response of the mesopause temperature and emission intensities to solar activity variations

The seasonal dependences of the response of the hydroxyl ((6–2) band) and molecular oxygen O₂(b ¹Σ _g ⁺ ) ((0–1) band) emission intensities, temperature, and density indicator in the region of the hydroxyl emission maximum (87 km) to solar activity have been obtained based on the spectral observations of the mesopause emissions at Zvenigorod observatory during 2000–2007. The ratio of the OH (7–3) and (9–4) band intensities, characterizing the behavior of the vibrational temperature, has been used as an indicator of density. It has been established that the response of the studied mesopause characteristics to solar activity is positive in all seasons. In winter the response is maximal in the intensities and temperature and is minimal in the density indicator. The main mechanisms by which solar activity affects the mesopause characteristics have been considered. The behavior of the internal gravity waves with periods of 0.33–7 h depending on solar activity has been studied. It has been noted that these waves become more active at a minimum of the 11-year solar cycle.     

Solar eclipse of the 29 March 2006: Results of the optical measurements by MORTI over Almaty (43.03°N, 76.58°E)

The observations of the upper mesosphere region (∼95 km altitude) in the period of 27–30 March 2006 using mesopause oxygen rotational temperature imager (MORTI) at Almaty (43.03°N, 76.58°E) are presented in this report to illustrate the mesosphere response to the solar eclipse (SE) event, which occurred on 29 March 2006. The nighttime volume emission rates and rotational temperatures, obtained from MORTI measurements, show appreciable differences in the pattern of wave-like oscillations observed during the period of interest. These oscillations are possibly due to the SE. Using a periodogram method the spectra of the observed wave-like oscillations, observed in the mesosphere, are examined. A physical mechanism is proposed to interpret the effects observed in terms of the mesosphere response to the total SE.     

Forcing of the ionosphere from above and below during the Arctic winter of 2005/2006

The present paper focuses on planetary wave type responses of the thermosphere/ionosphere system to forcing from above and below during the Arctic winter of 2005/2006. The forcing from above is described by the sunspot numbers, the solar wind speed, the B_z-component of the IMF and the geomagnetic Kp-index, while the forcing from below, i.e. by upward propagating atmospheric waves, is represented by the SABER/TIMED temperatures. The observed global ionospheric zonally symmetric oscillations with periods of ～9, ～14 and ～24–27 days were approved to be of solar origin. The most persistent ～9-day oscillation is linked to a triad of solar coronal holes distributed roughly 120° apart in solar longitude. The ～18-day westward propagating wave with zonal wavenumber 1, observed in the ionospheric currents (detected by magnetometer data), and in the F-region plasma (foF2 and TEC) could be allocated to a simultaneous 18-day westward propagating planetary wave observed in the stratosphere/mesosphere/lower thermosphere region with large (～70 km) vertical wavelength.     

Ozone Weekend Effect Analysis in Three European Urban Areas

This paper aims to apply statistical procedures to analyse the ozone weekend effect (OWE) in three European urban areas: Lisbon, Oporto and London. Seasonal variations of surface ozone (O₃) and total oxidant species (O_x) concentrations are presented. The studied period was from January 2007 to December 2009. The O₃ annual average profile in London was significantly different from the ones achieved for Lisbon and Oporto, due to the high emissions of nitrogen oxides and low temperatures (associated with low solar radiations). The influence of nitrogen oxides in atmospheric chemistry of London was analysed by linear correlations between O₃ concentrations and NO₂/NO ratio. High values during almost all period showed that O₃ concentrations are mainly influenced by NO? NO₂? O₃ chemical reaction. On the other hand, the linear correlations between O₃ and NO₂ concentrations only presented positive values in Lisbon and Oporto. This behaviour is associated with photo‐dissociation of NO₂, producing O₃ during the spring and summer periods. Additionally, cluster analysis was applied to group the days of week according the correspondent O₃ behaviour. The weekend and some weekdays (immediately after or before) were grouped in the same cluster, showing that OWE occurs in all urban areas selected in this study. These findings suggest that the applied statistical procedures should be used to analyse the OWE and that the causes for the different O₃ behaviours during the week may be influenced by meteorological variables.     

Effects of geomagnetic activity on the mesospheric electric fields

The results of three series of rocket measurements of mesospheric electric fields carried out under different geomagnetic conditions at polar and high middle latitudes are analysed. The measurements show a clear dependence of the vertical electric fields on geomagnetic activity at polar and high middle latitudes. The vertical electric fields in the lower mesosphere increase with the increase of geomagnetic indexes K_p and K_p. The simultaneous increase of the vertical electric field strength and ion conductivity was observed in the mesosphere during geomagnetic disturbances. This striking phenomenon was displayed most clearly during the solar proton events of October, 1989 accompanied by very strong geomagnetic storm (K_p = 8+). A possible mechanism of generation of the vertical electric fields in the mesosphere caused by gravitational sedimentation of charged aerosol particles is discussed. Simultaneous existence in the mesosphere of both the negative and positive multiply charged aerosol particles of different sizes is assumed for explanation of the observed V/m vertical electric fields and their behaviour under geomagnetically disturbed conditions.Paper Presented at the Second IAGA/ICMA (IAMAS) Workshop on Solar Activity Forcing of the Middle Atmosphere, Prague, August 1997     

DO-Process Models for Shallow Systems. Part 1: Ponds and Lakes

Model statements are presented for describing the oxygen concentration in dependence on various system quantities and five different shallow water bodies. A nonlinear model in the form of a polynomial and with parameter estimation by means of recursive regression proves suitable. It is a blackbox model in which the water temperature, the biomass of phytoplankton and zooplankton and the solar irradiation are the most important input quantities. The model applications to the five water bodies reach measures of determinateness of 0.6 … 0.74 and mean square deviations between the measured and calculated oxygen concentrations of 3 … 4 mg/l O₂. Simulations of the model output by changed input data are discussed.