Implications of measurement metrics on soil freezing curves: A simulation of freeze–thaw hysteresis

Soil freeze–thaw events have important implications for water resources, flood risk, land productivity, and climate change. A property of these phenomena is the relationship between unfrozen water content and sub-freezing temperature, known as the soil freezing characteristic curve (SFC). It is documented that this relationship exhibits hysteretic behaviour when frozen soil thaws, leading to the definition of the soil thawing characteristic curve (STC). Although explanations have been given for SFC/STC hysteresis, the effect that ‘scale’ – particularly ‘measurement scale’ – may have on these curves has received little attention. The most commonly used measurement scale metric is the ‘support’, which is the spatial (or temporal) unit within which the measured variable is integrated or soil volume sampled. We show (a) measurement support can influence the range and shape of the SFC and (b) hysteresis can be attributed, in part, to the support and location of the measurements comprising the SFC/STC. We simulated lab measured temperature, volumetric water content (VWC), and permittivity from soil samples undergoing freeze–thaw transitions using Hydrus-1D and a modified Dobson permittivity model. To assess the effect of measurement support and location on SFC/STC, we masked the simulated temperature and VWC/permittivity extent to match the instrument's support and location. By creating a detailed simulation of the intra- and inter-support variability associated with the penetration of a freezing front, we demonstrate how measurement support and location can influence the temperature range over which water freezing events are captured. We show it is possible to simulate hysteresis in homogenous media with purely geometric considerations, suggesting that SFC/STC hysteresis may be more of an apparent phenomenon than mechanistically real. Lastly, we develop an understanding of how the location and support of soil temperature and VWC/permittivity measurements influence the temperature range over which water freezing events are captured.     

The nature and pattern of debris liberation by salt weathering: A laboratory study

A laboratory simulation of salt weathering was used to ascertain the effects of sodium sulphate and sodium carbonate under ‘Negev’ conditions using a single immersion technique. Three main points were addressed: what are the grain size and textural characteristics of the debris liberated from limestones and a sandstone, what do scanning electron microscope observations of the weathered samples tell us about the decay processes involved, and how does the rate of debris liberation change during the course of 100 cycles? The grain size characteristics of the liberated debris tended to be multimodal and were related to the original petrological characteristics of the rock. Large amounts of fines were produced which are believed to be analogous to the ‘rock flour’ of arid areas. Blistering was also observed. Scanning electron microscope analysis revealed differences in the style of attack for different rock types and salt treatments, and revealed the pattern of salt crystallization in pores and the nature of cracking. The rate of debris liberation tended to decline or remain constant through time. The reasons for this remain obscure, but it is evident that diurnal cycles of temperature and humidity change can cause continuing rock weathering long after the initial input of salt to the rock has taken place.     

The role of debris supply conditions in predicting debris flow activity

Debris flow frequency and magnitude were determined for 33 basins in southwest British Columbia. Basins were first classified as either weathering-limited or transport-limited using a discriminant function based on debris-contributing area, an area-weighted terrain stability number, and drainage density. Multiple regression was used to predict magnitude, peak discharge, frequency and activity (frequency times magnitude) within each group of basins. Model performance was improved by stratifying the total sample of debris flow basins into weathering-and transport-limited groups. Explained variance increased by an average of 15 per cent in the transport-limited sample, indicating that sediment supply conditions in the more active basins are fundamental in predicting debris flow activity. An independent test of the regression models with 11 basins yielded generally good results for debris flow magnitude and peak discharge. Prediction of debris flow frequency proved problematical in weathering-limited basins. The methods developed here provide estimates of debris flow attributes in basins for which few data on past events are available. Copyright © 1999 John Wiley & Sons, Ltd.     

Possible effect of ENSO on annual sediment discharge of debris flows in the Jiangjia Ravine based on Morlet wavelet transforms

The multi-time-scale structures of an annual sediment discharge series of debris flow in the Jiangjia Ravine and the Southern Oscillation index are analysed using the method of Morlet wavelet transformations. The possible effects of E1 Nirio episodes on the annual sediment discharge are discussed by comparing the period variations of ENSO and the discharge. The results show that the annual sediment discharge series of debris flow is related to E1 Nifio episodes. Generally, the annual sediment discharge of debris flow is less than usual during an E1 Nifio episode and debris flow is less active. On the contrary, the annual sediment discharge of debris flows is greater than usual during a La Nifia episode and debris flows are more frequent. There is a relationship between the annual sediment discharges of debris flow in the Jiangjia Ravine and the summer Southern Oscillation index, with both having quasi-periodic variations of 2 and 5-6 years.     

Weathering of coastal defensive structures in southwest England: a 500 year stone durability trial

Historic structures can be viewed as exposure trials of the stone of which they are constructed. As such, they represent a geomorphological weathering experiment. Several structures of Henrician (sixteenth century) and greater age on the coast of southwest England have been exposed to coastal salt weathering for 500–600 years. Long‐term weathering rates on five different rock groups are derived from careful study of weathering depths and forms. There is significant variation in weathering rate between five major rock groups. Rank ordering of weathering rate values reveals a durability order of these rock groups, which is confirmed by local juxtapositions. Controls on rock durability in the coastal weathering environment include both mechanical and mineralogical characteristics. Specific density, and combined quartz and muscovite content, are positively related to durability; high feldspar and chlorite content are associated with low durability. Copyright © 2000 John Wiley & Sons, Ltd.     

Weathering of sandstone by the combined action of frost and salt

Preliminary results from a continuing series of laboratory experiments designed to examine the combined effects of salt and frost weathering indicate that some salts greatly enhance the breakdown of rocks by frost. Samples of Ardingly Sandstone from southeast England were soaked in saturated solutions of sodium chloride or sodium sulphate and subjected to alternating cycles of freezing and thawing. Rapid disintegration of the sandstone occurred within twenty cycles, in each of the salt solutions. In contrast, samples subjected to freezing and thawing in deionized water suffered very little damage unless they were saturated under vacuum. When samples were subjected to twenty cycles of wetting and drying at temperatures above 0°C, those soaked in deionised water or sodium chloride suffered no appreciable damage but those soaked in sodium sulphate rapidly disintegrated. Tentative explanations of these results are offered. The enhancement of frost weathering by salt appears to have been overlooked by many writers yet it is likely to be an important geomorphological process in those areas of mid and high latitudes where rocks are saturated with sodium salts.     

Entanglement of grey seals Halichoerus grypus at a haul out site in Cornwall,UK

Entanglement in marine debris has been internationally recognised as a potential threat to marine species. Sightings records and a photo identification catalogue from a haul out site in southwest England were used to establish entanglement records for grey seals Halichoerus grypus. Between 2004 and 2008 the annual mean entanglement rates varied from 3.6% to 5%. The maximum recapture period for entangled seals compared to paired control seals was significantly less (p = 0.045) suggesting an increased mortality rate for affected seals. Of the 58 entangled cases in the catalogue, 64% had injuries that were deemed serious. Of the 15 cases where the entangling debris was visible, 14 were entangled in fisheries materials. The entanglement reported at this site could indicate a high rate of mortality and should be monitored carefully. On a more immediate level, entanglement represents a welfare issue for the affected animals.     

Observation of Sea Breeze Front and its Induced Convection over Chennai in Southern Peninsular India Using Doppler Weather Radar

Sea breeze, the onshore wind over a coastal belt during daytime, is a welcoming weather phenomenon as it modulates the weather condition by moderating the scorching temperature and acts as a favourable mechanism to trigger convection and induce precipitation over coastal and interior locations. Sea breeze aids dispersal of pollutants as well. Observational studies about its onset, depth of circulation and induced precipitation have been carried out in this paper for the period April to September, 2004–2005 using a S-band Doppler Weather Radar functioning at Cyclone Detection Radar Station, India Meteorological Department, Chennai, India. The onset of sea breeze has been observed to be between 0900 and 1000 UTC with the earliest onset at 0508 UTC and late onset at 1138 UTC. The frequency is greater during the southwest monsoon season, viz., June – September and the frequency of initial onset is greater in north Chennai. The modal length of sea breeze is between 20 and 50 km with extreme length as high as 100 km also having been observed. Though the inland penetration is on average 10 to 20 km, penetration reaching 100 km was also observed on a number of cases. The induced convection could be seen in the range 50–100 km in more than 53% of the cases. The mean depth of sea breeze circulation is 300–600 m but may go well beyond 1000 m on conducive atmospheric conditions.     

The freeze-thaw weathering regime at a section of the Niagara escarpment on the Bruce Peninsula,Southern Ontario,Canada

The bedrock freeze-thaw and moisture regimes at an actively eroding site on the Niagara Escarpment, Bruce Peninsula, southern Ontario, were monitored between December 1983 and April 1984, and the results compared with amounts of debris collected in an adjacent rock trap. Frost wedging in pre-existing rock fissures is the primary mechanism responsible for the observed rockfall events; hydration effects are negligible. Debris production was more closely related to the duration of the freezing leg of the freeze-thaw cycle than to intensity or to cycle frequency. Release also coincided with periods of high pore saturation (> 60 per cent) and the seepage of water from cracks and fissures. Fewer freeze-thaw cycles were recorded in the air than at 1 and 3.5 cm in the bedrock. The number of cycles that could be declared geomorphologically effective according to established temperature criteria was normally less than half the total number of freeze-thaw cycles recorded in both air and bedrock. Under the current temperature regime at the field site, few effective cycles are capable of penetrating more than 5 cm into the free face.     

温度作用下煤层瓦斯解吸渗流规律数值模拟

如何提高煤层气渗透率是目前煤层气开采研究中的重要课题。基于煤层瓦斯渗流规律数学模型,利用COMSOL Multiphysics软件,对流-固-热耦合条件下的非等温煤层气解吸、渗流变化规律进行了数值模拟。结果表明,在注热条件下,煤层气渗流压力随着温度的增加而下降,且下降速度加剧,压力差越大,气体从高压区域流向低压区域的渗流速度越快。气体在煤层中径向流向井口,井口附近压力的梯度增大,气体渗流速度较快;在未受到加热影响的区域,煤层气不受外加热量影响,煤层气解吸速率保持不变;注热后煤层温度升高,可以加快煤层气渗流速度、提高渗透率、增加煤层气产量。研究成果可为煤层中注热开采煤层气的工程实践提供相应的理论依据。     

Chemical textures on quartz grains: An experimental approach using salts

Two groups of fresh crushed Brazilian quartz grains (0.4–0.6 mm) were placed in 10 ml of various saturated salt solutions (sodium sulphate, sodium chloride, magnesium sulphate, sodium carbonate, and sodium carbonate and soil). One group was placed in an environmental cabinet programmed to simulate summer diurnal temperature and relative humidity values recorded in Wheeler Valley, a dry valley in southern Victoria Land, Antarctica. The other group was allowed to remain at normal laboratory conditions. Quartz grains from both groups were removed at pre-selected intervals for examination using the scanning electron microscope. After 50 hours chemical surface textures were formed on the quartz grains in all but the sodium sulphate solution. At the 140 hour interval all the salt solutions used were producing chemical surface textures on the quartz grains. This paper demonstrates that chemical surface textures can be produced on quartz grain surfaces by saturated salt solutions in a short period of time and may prove to be representative of chemical surface textures produced in a saturated saline environment.     

Characterization of marine debris in North Carolina salt marshes

Marine debris composition, density, abundance, and accumulation were evaluated in salt marshes in Carteret County, North Carolina seasonally between 2007 and 2009. We assessed relationships between human use patterns and debris type. Wave effects on marine debris density were examined using a GIS-based forecasting tool. We assessed the influence of site wave exposure, period, and height on debris quantity. Presence and abundance of debris were related to wave exposure, vegetation type and proximity of the strata to human population and human use patterns. Plastic pieces accounted for the majority of all debris. Small debris (0–5 cm) was primarily composed of foam pieces and was frequently affiliated with natural wrack. Large debris (>100 cm) was encountered in all marsh habitat types surveyed and was primarily composed of anthropogenic wood and derelict fishing gear. Marsh cleanup efforts should be targeted to specific habitat types or debris types to minimize further damage to sensitive habitats.     

基于双曲线模型的冻土中锚杆荷载传递特性研究

为研究不同冻结温度及含水率对冻结粉土中锚杆抗拔性能的影响,根据冻土与混凝土接触面的力学特性和变形规律,采用双曲线模型描述锚杆-冻土接触面的剪切特性。基于荷载传递法,建立考虑温度和含水率影响的锚杆荷载传递方程,采用有限差分法进行求解,得到锚固段的剪应力、轴力及承载力计算式;通过ABAQUS数值模拟验证荷载传递方程的合理性,结合算例分析表明：冻土中锚杆抗拔承载力大于常温土,且温度越低承载力越高;在相同荷载作用下,冻土温度越低,轴力沿深度衰减越快,剪应力分布越不均匀;相同冻结温度下,锚杆承载力随含水率的增大呈先增大后减小的趋势;增加锚固体直径能有效地提高锚杆的极限承载力。     

Effects of macro-pores on water flow in coastal subsurface drainage systems

Leaching through subsurface drainage systems has been widely adopted to ameliorate saline soils. The application of this method to remove salt from reclaimed lands in the coastal zone, however, may be impacted by macro-pores such as crab burrows, which are commonly distributed in the soils. We developed a three-dimensional model to investigate water flow in subsurface drainage systems affected by macro-pores distributed deterministically and randomly through Monte Carlo simulations. The results showed that, for subsurface drainage systems under the condition of continuous surface ponding, macro-pores increased the hydraulic head in the deep soil, which in turn reduced the hydraulic gradient between the surface and deep soil. As a consequence, water infiltration across the soil surface was inhibited. Since salt transport in the soil is dominated by advection, the flow simulation results indicated that macro-pores decreased the efficiency of salt leaching by one order of magnitude, in terms of both the elapsed time and the amount of water required to remove salt over the designed soil leaching depth (0.6 m). The reduction of the leaching efficiency was even greater in drainage systems with a layered soil stratigraphy. Sensitivity analyses demonstrated that with an increased penetration depth or density of macro-pores, the leaching efficiency decreased further. The revealed impact of macro-pores on water flow represents a significant shortcoming of the salt leaching technique when applied to coastal saline soils. Future designs of soil amelioration schemes in the coastal zone should consider and aim to minimize the bypassing effect caused by macro-pores.     

Plastic debris collars on juvenile carcharhinid sharks (Rhizoprionodon lalandii) in southwest Atlantic

Three juvenile Brazilian sharpnose sharks (Rhizoprionodon lalandii) caught in gillnets in southeast Brazil, southwest Atlantic, were found with plastic debris rings around their gill or mouth region. The rings caused severe abrasion on the sharks' tissues as the animal grew, the collars probably hampering normal feeding and/or ventilation since two of the collared individuals were emaciated. The rings were identified as detachable lid parts from plastic bottles, likely thrown overboard by fishery and/or recreation boats. As several carcharhinid shark species dwells and reproduce in shallow waters, the impact of discarded plastic debris likely is greater on this shark type.     

ANNUAL SEA LEVEL VARIABILITY INDUCED BY CHANGES IN SEA ICE EXTENT AND ACCUMULATION ON ICE SHEETS: AN ASSESSMENT BASED ON REMOTELY SENSED DATA

Changes of mean annual net accumulation at the surface on the grounded ice sheets of East Antarctica, West Antarctica and Greenland in response to variations in sea ice extent are estimated using grid-point values 100 km apart. The data bases are assembled principally by bilinear interpolation of remotely sensed brightness temperature (Nimbus-5 ESMR, Nimbus-7 SMMR), surface temperature (Nimbus-7 THIR), and surface elevation (ERS-1 radar altimeter). These data, complemented by field data where remotely sensed data are not available, are used in multivariate analyses in which mean annual accumulation (derived from firn emissivity) is the dependent variable; the independent variables are latitude, surface elevation, mean annual surface temperature, and mean annual distance to open ocean (as a source of energy and moisture). The last is the shortest distance measured between a grid point and the mean annual position of the 10% sea ice concentration boundary, and is used as an index of changes in sea ice extent as well as of mean concentration. Stepwise correlation analyses indicate that variations in sea ice extent of ± 50 km would lead to changes in accumulation inversely of ± 4% on East Antarctica, ± 10% on West Antarctica, and ±4% on Greenland. These results are compared with those obtained in a previous study using visually interpolated values from contoured compilations of field data; they substantiate the findings for the Antarctic ice sheets (±4% on East Antarctica, ±9% in West Antarctica), and suggest a reduction by one half of the probable change of accumulation on Greenland (from ±8%). The results also suggest a reduction of the combined contribution to sea level variability to ±0.19 mm a-1 (from ±0.22 mm a-1).     

Enhanced bedrock weathering in association with late-lying snowpatches: Evidence from Livingston Island,Antarctica

An indication of the extent of weathering on different aspects of rock outcrops on Livingston Island, Antarctica, was obtained by means of a Schmidt hammer, a cone indenter and measurement of weathering rind thickness. Results show that weathering, particularly chemical weathering, is enhanced on the lee side of outcrops where snow accumulates as a result of prolonged wetting by the melting snow. Rock moisture and temperature data indicate that the south-facing, snow-accumulation side of obstacles have high rock moisture levels and maintain relatively high temperatures. Whilst chemical weathering is greater on the leeward side of outcrops, mechanical processes are greater on the windward side. The presence of late-lying snow thus appears to exert a strong influence on weathering.     

Deglacial sea surface temperature and salinity increase in the western tropical Atlantic in synchrony with high latitude climate instabilities

A sediment core from the western tropical Atlantic covering the last 21,000 yr has been analysed for centennial scale reconstruction of sea surface temperature (SST) and ice volume-corrected oxygen isotopic composition of sea water (δ¹⁸O_ivc-sw) using Mg / Ca and δ¹⁸O of the shallow dwelling planktonic foraminifer Globigerinoides ruber (white). At a period between 15.5 and 17.5 kyr BP, the Mg / Ca SST and δ¹⁸O_ivc-sw, a proxy for sea surface salinity (SSS), reveals a warming of around 2.5 °C along with an increase in salinity. A second period of pronounced warming and SSS increase occurred between 11.6 and 13.5 kyr BP. Within age model uncertainties, both warming intervals were synchronous with air temperature increase over Antarctica and ice retreat in the southern South Atlantic and terminated with abrupt centennial scale SSS decrease and slight SST cooling in conjunction with interglacial reactivation of the meridional overturning circulation (MOC). We suggest that during these warm intervals, production of saline and warm water of the North Brazil Current resulted in pronounced heat and salt accumulation, and was associated with warming in the southern Atlantic, southward displacement of the intertropical convergence zone and weakened MOC. At the termination of the Younger Dryas and Heinrich event 1, intensification of cross-equatorial heat and salt transport caused centennial scale cooling and freshening of the western tropical Atlantic surface water. This study shows that the western tropical Atlantic served as a heat and salt reservoir during deglaciation. The sudden release of accumulated heat and salt at the end of Younger Drays and Heinrich event 1 may have contributed to the rapid reinvigoration of the Atlantic MOC.     

An investigation on stream temperature analysis based on evolutionary computing

The data‐driven technique, evolutionary polynomial regression, has been tested and used for the study of water temperature behaviour in the River Barle (south‐west England). The study aimed to produce multiple models for forecasting water temperature, using air temperature as input. In addition, river discharge data were used to describe the hydrological regime of the study stream, even if they are not involved in the modelling phase. The availability of data sampled at hourly intervals allowed behaviour to be studied at several time scales, including short‐term lags between air temperature and water temperature. The approach to model building differs from previous studies in that the relationship between air temperature and water temperature is not evaluated on the basis of a multi‐parameter regression, nor does it identify particular structures; rather the evolutionary technique identifies the model by itself. In fact, the non‐linear relationship between air temperature and water temperature is investigated by an evolutionary search in the space of particular pseudo‐polynomials structures. Copyright © 2007 John Wiley & Sons, Ltd.     

Composition of widespread volcanic glass in deep-sea sediments of the Southern Pacific Ocean: an Antarctic source inferred

Widespread Plio-Pleistocene (2.43-0.06 Ma) tephra zones recognised in deep-sea cores from high latitudes (>60°) in the Southern Pacific Ocean were thought to have originated from calc-alkaline rhyolitic eruptions in New Zealand, some 5000 km distant. Electron microprobe analyses of the glasses reveal a wide diversity of alkalic felsic compositions, as well as minor components of basic and intermediate glasses, incompatible with a New Zealand Neogene source but similar to contemporaneous eruptives from the Antarctic region. Most tephra zones are trachytic; seven zones are peralkaline rhyolite. The rhyolitic zones represent a deep-sea record of widespread silicic eruptions from continental Antarctica, possibly Marie Byrd Land. The extent of these rhyolitic zones suggest a greater frequency of large explosive eruptions in Antarctica than previously documented. The coarse grain size of some of the shards (up to 3 mm), their great distance from the closest sources (>1600 km for some cores), and the presence of nonvolcanic ice-rafted debris indicate some of the glasses, especially the more basic compositions, may have been ice-rafted, contrary to previous suggestions of a fallout origin.