The influence of global dust storms on the mean seasonal daily insolations at the Martian surface

In this paper, we compare changes in the mean seasonal daily insolations at the Martian surface caused by global dust storms characterized by various atmospheric optical thickness (). The calculations, made for optical depths equal to 0, 0.1, 0.5, 1.0, 2.0, and 3.0, are based on the assumption of planet encircling storms lasting one season or one year. The variations in the latitudinal and seasonal surface insolation distributions are important, mainly at the poles where e.g. the mean annual and summer daily insolations decrease by nearly a factor of 3000 as goes from 0 to 3.0. At equatorial latitudes the corresponding loss is much smaller, reaching a value of approximately 40. Concerning the mean wintertime solar radiations it is found that the decrease is even more spectacular, especially at high latitudes.     

Martian atmospheric water vapor observations: 1972–1974 apparition

The patrol of Martian water vapor carried out with the echelle-coudé scanner at McDonald Observatory during the 1972–1974 apparition has produced 469 individual photoelectric scans of Doppler-shifted Martian H₂O lines. Almost an entire Martian year was covered during the 1972–1974 period (L_s = 118?269° and 301?80°). Three types of coverage have been obtained: (1) regular—the slit placed pole to pole on the central meridian; (2) latitudinal—the slit placed parallel to the Martian equator at various latitudes; (3) diurnal—the slit placed parallel to the terminator at several times during a Martian day measured from local noon.Both the seasonal and diurnal effects seem to be controlled by the insolation and not the local topography with respect to the 6.1 mb surface. A slight negative correlation with elevation was noted which improved during the seasons of greater H₂O content. The previous seasonal behavior has been confirmed and amplified. The following are the primary conclusions: (1) The planetwide abundance is low (5?15 μm of ppt H₂O) during both equinoctical periods. (2) The maximum abundance of about 40 μm occurs in each hemisphere after solstice at about 40° latitude in that hemisphere. (3) The latitude of the maximum amount in the N-S distribution precedes the latitude of maximum insolation by 10–20° of latitude. (4) During the “drier” seasons (5–20 μm) near the equinoxes on Mars, the atmospheric water vapor changes by a factor of 2–3x over a diurnal cycle with the maximum near local noon. (5) The effects of the 1973 dust storm during the southern summer reduced the amount of water vapor over the southern hemisphere regions to 3–8 μm.     

Slope angle and frost formation on Mars

The low partial pressure of water vapor in the Martian atmosphere implies a low (～200K) frost point for water on the surface. This, in turn, has made it difficult to accept the traditional water frost explanation of bright patches that sometimes occur near the equator. We show that, because insolation and surface albedo are so important in determining surface temperature, nighttime frost deposits on steep slopes facing away from the Sun during local winter may persist throughout the day, even at the equator. Above about 25° north latitude, permanent frost deposits may form on steep north-facing slopes. Frost deposits on slopes could explain some bright features, as well as act as a reservoir for atmospheric H₂O.     

Response of the intermediate complexity Mars Climate Simulator to different obliquity angles

A climate model of intermediate complexity, named the Mars Climate Simulator, has been developed based on the Portable University Model of the Atmosphere (PUMA). The main goal of this new development is to simulate the climate variations on Mars resulting from the changes in orbital parameters and their impact on the layered polar terrains (also known as permanent polar ice caps). As a first step towards transient simulations over several obliquity cycles, the model is applied to simulate the dynamical and thermodynamical response of the Martian climate system to different but fixed obliquity angles. The model is forced by the annual and daily cycle of solar insolation. Experiments have been performed for obliquities of φ=15^° (minimum), φ=25.2^° (present), and φ=35^° (maximum). The resulting changes in solar insolation mainly in the polar regions impact strongly on the cross-equatorial circulation which is driven by the meridional temperature gradient and steered by the Martian topography. At high obliquity, the cross-equatorial near surface flow from the winter to the summer hemisphere is strongly enhanced compared to low obliquity periods. The summer ground temperature ranges from 200 K (φ=15^°) to 250 K (φ=35^°) at 80^°N in northern summer, and from 220 K (φ=15^°) to 270 K (φ=35^°) at 80^°S in southern summer. In the atmosphere at 1 km above ground, the respective range is 195-225 K in northern summer, and 210-250 K in southern summer.     

History of Martian volatiles: Implications for organic synthesis

A theoretical reconstruction of the history of Martian volatiles indicates that Mars probably possessed a substantial reducing atmosphere at the outset of its history and that its present tenous and more oxidized atmosphere is the result of extensive chemical evolution. As a consequence, it is probable that Martian atmospheric chemical conditions, now hostile with respect to abiotic organic synthesis in the gas phase, were initially favorable. Evidence indicating the chronology and degradational history of Martian surface features, surface mineralogy, bulk volatile content, internal mass distribution, and thermal history suggests that Mars catastrophically developed a substantial reducing atmosphere as the result of rapid accretion. This atmosphere probably persisted—despite the direct and indirect effects of hydrogen escape—for a geologically short time interval during, and immediately following, Martian accretion. That was the only portion of Martian history when the atmospheric environment could have been chemically suited for organic synthesis in the gas phase. Subsequent gradual degrassing of the Martian interior throughout Martian history could not sustain a reducing atmosphere due to the low intensity of planet-wide orogenic activity and the short atmospheric mean residence time of hydrogen on Mars. During the post-accretion history of Mars, the combined effects of planetary hydrogen escape, solar-wind sweeping, and reincorporation of volatiles into the Martian surface produced and maintained the present atmosphere.     

The oblateness effect on the mean seasonal daily insolations at the martian surface during global dust storms

In this short paper, the combined effect of global dust storms and the oblateness on the mean seasonal daily insolations at the Martian surface is investigated. Due to the flattening, the mean summertime insolation is increased at equatorial and low latitudes, decreased at mid- and high latitudes. When comparing a spherical with an oblate planet Mars, it is found that the percentage differences of the mean summer daily insolations are dependent upon the optical depths () considered. For an atmosphere without aerosols, the maximum percentage differences are respectively equal to + 0.05 and – 0.2%; at = 3.0 the corresponding values amount to about 0.1 and 2%. In winter, the mean daily insolations are decreased over the entire latitudinal interval, where the maximum values are found at polar region latitudes; at e.g. a latitude of 85 the loss of solar energy enhances from 2 ( = 0.0) to more than 30% ( = 3.0). The mean annual daily insolation is maximally reduced by about 0.5 and 2% for optical thicknesses of 0.0 and 3.0, respectively.     

Evaporation of ice in planetary atmospheres: Ice-covered rivers on mars

The evaporation rate of water ice on the surface of a planet with an atmosphere involves an equilibrium between solar heating and radiative and evaporative cooling of the ice layer. The thickness of the ice is governed principally by the solar flux which penetrates the ice layer and then is conducted back to the surface. These calculations differ from those of Lingenfelter et al. [(1968) Science161, 266–269] for putative lunar channels in including the effect of the atmosphere. Evaporation from the surface is governed by two physical phenomena: wind and free convection. In the former case, water vapor diffuses from the surface of the ice through a lamonar boundary layer and then is carried away by eddy diffusion above, provided by the wind. The latter case, in the absence of wind, is similar, except that the eddy diffusion is caused by the lower density of water vapor than the Martian atmosphere. For mean Martian insolations the evaporation rate above the ice is ～ 10^?8 g cm^?2 sec^?1. Thus, even under present Martian conditions a flowing channel of liquid water will be covered with ice which evaporates sufficiently slowly that the water below can flow for hundreds of kilometers even with quite modest discharges. Evaporation rates are calculated for a wide range of frictional velocities, atmospheric pressures, and insolations and it seems clear that at least some subset of observed Martian channels may have formed as ice-choked rivers. Typical equilibrium thicknesses of such ice covers are ～ 10 to 30 m; typical surface temperatures are 210 to 235°K. Ice-covered channels or lakes on Mars today may be of substantial biological interest. Ice is a sufficiently poor conductor of heat that sunlight which penetrates it can cause melting to a depth of several meters or more. Because the obliquity of Mars can vary up to some 35°, the increased polar heating at such times seems able to cause subsurface melting of the ice caps to a depth which corresponds to the observed lamina thickness and may be responsible for the morphology of these polar features.     

The oblateness effect on the solar radiation incident at the top of the atmospheres of the outer planets

Calculations of the daily solar radiation incident at the top of the atmospheres of Jupiter, Saturn, Uranus, and Neptune, with and without the effect of the oblateness, are presented in a series of figures illustrating the seasonal and latitudinal variation of the ratio of both insolations. It is shown that for parts of the summer, the daily insolation of an oblate planet is increased, the zone of enhanced solar radiation being strongly dependent upon the obliquity, whereas the rate of increase is fixed by both the flattening and the obliquity. In winter, the oblateness effect results in a more extensive polar region, the daily solar radiation of an oblate planet always being reduced when compared to a spherical planet. In addition, we also numerically studied the mean daily solar radiation. As previously stated by A.W. Brinkman and J. McGregor (1979, Icarus, 38, 479–482), it is found that in summer the horizon plane is tilted toward the Sun for latitudes less than the subsolar point, but is titled away from the Sun beyond this latitude. It follows that the mean summer daily insolation is increased between the equator and the subsolar point, but decreased poleward of the above-mentioned limit. In winter, however, the horizon plane is always tilted away from the Sun, causing the mean winter daily insolation to be reduced. The partial gain of the mean summertime insolation being much smaller than the loss during winter season evidently yields a mean annual daily insolation which is decreased at all latitudes.     

Comparison between infrared Martian disk spectra and optical properties of terrestrial analogs

Medium spectral resolution (20 cm^?1) infrared measurements of the Martian disk made between 2900 and 5600 cm^?1 from the NASA Lear Airborne Observatory have been successfully compared with predictions derived from a model of the Martian soil and atmosphere. Modeling of the Martian atmosphere permitted the extraction of Martian soil reflectance in the CO₂ bands centered at 3657 cm^?1. Three previously considered acceptable Martian soil analogs, limonite, montmorillonite, and basalt, were analyzed to determine the optical complex indices of refraction in the same range as the airborne observations, for mathematical modeling. A characteristic surface particle size ～1 to 3 μm diameter is indicated. It is concluded that the Martian soil surface near-infrared optical properties are consistent with a soil composition similar to montmorillonite or limonite, mixed with a basalt.     

Interannual and seasonal behavior of Martian residual ice-cap albedo

The Mars Orbiter Laser Altimeter (MOLA), functioning as a high-resolution radiometer, has observed several appearances of the Martian residual ice caps. We examine these data to quantify both seasonal behavior and interannual differences. The northern residual cap (NRC) was found to be mostly stable with the exception of one, previously identified, region of strong variability. Interannual change in the extent of the NRC appears to be small and reversible on timescales of 1 or 2 years. The NRC has an elaborate seasonal evolution of albedo. Annuli of fine-grained CO₂ and water frost, which track the inner and outer edges of the seasonal CO₂ cap, cause large temporary brightenings. The NRC albedo is stable from just after solstice to L_s 150°, after which albedo decreases steadily. This late-summer darkening can be explained by shadowing within the rough topography of the NRC, leading to a lower limit on topographic relief of 80 cm. The southern residual cap (SRC) appears stable in extent. As has been previously discovered, its seasonal frost albedo behavior appears to be correlated with insolation. However, residual CO₂ appears not to share this characteristic; we use this behavioral difference to infer net deposition of CO₂ ice on the SRC during 1 out of 3 years. Uncharacteristically, the SRC abruptly darkens at L_s 320° in 1 Martian year (year beginning April 2002). Circumstantial evidence suggests atmospheric scattering by dust is responsible. The 2001 global dust-storm appears, either, to have had no effect on the polar cap albedos, or, resulted in slightly brighter ice deposits.     

Noble gases in mineral separates from three shergottites: Shergotty,Zagami, and EETA79001

Abstract— This study provides a complete data set of all five noble gases for bulk samples and mineral separates from three Martian shergottites: Shergotty (bulk, pyroxene, maskelynite), Zagami (bulk, pyroxene, maskelynite), and Elephant Moraine (EET) A79001, lithology A (bulk, pyroxene). We also give a compilation of all noble gas and nitrogen studies performed on these meteorites. Our mean values for cosmic‐ray exposure ages from ³He, ²¹Ne, and ³⁸Ar are 2.48 Myr for Shergotty, 2.73 Myr for Zagami, and 0.65 Myr for EETA79001 lith. A. Serious loss of radiogenic ⁴He due to shock is observed. Cosmogenic neon results for bulk samples from 13 Martian meteorites (new data and literature data) are used in addition to the mineral separates of this study in a new approach to explore evidence of solar cosmic‐ray effects. While a contribution of this low‐energy irradiation is strongly indicated for all of the shergottites, spallation Ne in Chassigny, Allan Hills (ALH) 84001, and the nakhlites is fully explained by galactic cosmic‐ray spallation. Implanted Martian atmospheric gases are present in all mineral separates and the thermal release indicates a near‐surface siting. We derive an estimate for the ⁴⁰Ar/³⁶Ar ratio of the Martian interior component by subtracting from measured Ar in the (K‐poor) pyroxenes the (small) radiogenic component as well as the implanted atmospheric component as indicated from ¹²⁹Xe, * excesses. Unless compromised by the presence of additional components, a high ratio of ～2000 is indicated for Martian interior argon, similar to that in the Martian atmosphere. Since much lower ratios have been inferred for Chassigny and ALH 84001, the result may indicate spatial and/or temporal variations of ⁴⁰Ar/³⁶Ar in the Martian mantle.     

Terrestrial and Martian weathering signatures of xenon components in shergottite mineral separates

Abstract– Xenon‐isotopic ratios, step‐heating release patterns, and gas concentrations of mineral separates from Martian shergottites Roberts Massif (RBT) 04262, Dar al Gani (DaG) 489, Shergotty, and Elephant Moraine (EET) 79001 lithology B are reported. Concentrations of Martian atmospheric xenon are similar in mineral separates from all meteorites, but more weathered samples contain more terrestrial atmospheric xenon. The distributions of xenon from the Martian and terrestrial atmospheres among minerals in any one sample are similar, suggesting similarities in the processes by which they were acquired. However, in opaque and maskelynite fractions, Martian atmospheric xenon is released at higher temperatures than terrestrial atmospheric xenon. It is suggested that both Martian and terrestrial atmospheric xenon were initially introduced by weathering (low temperature alteration processes). However, the Martian component was redistributed by shock, accounting for its current residence in more retentive sites. The presence or absence of detectable ¹²⁹Xe from the Martian atmosphere in mafic minerals may correspond to the extent of crustal contamination of the rock’s parent melt. Variable contents of excess ¹²⁹Xe contrast with previously reported consistent concentrations of excess ⁴⁰Ar, suggesting distinct sources contributed these gases to the parent magma.     

Elements of comparison between Martian and terrestrial mesoscale meteorological phenomena: Katabatic winds and boundary layer convection

Terrestrial and Martian atmospheres are both characterised by a large variety of mesoscale meteorological events, occurring at horizontal scales of hundreds of kilometres and below. Available measurements from space exploration and recently developed high-resolution numerical tools have given insights into Martian mesoscale phenomena, as well as similarities and differences with their terrestrial counterparts. The remarkable intensity of Martian mesoscale events compared to terrestrial phenomena mainly results from low density and strong radiative control. This is exemplified in the present paper by discussing two mesoscale phenomena encountered in the lowest atmospheric levels of both planets with notable differences: nighttime katabatic winds (drainage flow down sloping terrains) and daytime boundary layer convection (vertical growth of mixed layer over heated surfaces). While observations of katabatic events are difficult on Earth, except over vast ice sheets, intense clear-cut downslope circulations are expected to be widespread on Mars. Convective motions in the daytime Martian boundary layer are primarily driven by radiative contributions, usually negligible on Earth where sensible heat flux dominates, and exhibit turbulent variances one order of magnitude larger. Martian maximum heat fluxes are not attained close to the surface as on Earth but a few hundreds of metres above, which implies generalised definitions for mixing layer scales such as vertical velocity w_?. Measurements on Mars of winds in uneven topographical areas and of heat fluxes over flat terrains could be useful to assess general principles of mesoscale meteorology applicable to both terrestrial and Martian environments.     

On the variations in the insolation at Mercury resulting from oscillations of the orbital eccentricity

This paper describes variations in the insolation on Mercury resulting from fluctuations of the orbital eccentricity (0.11≤e≤0.24) of the planet. Equations for the instantaneous and the daily insolation are briefly discussed and several numerical examples are given illustrating the sensitivity of the solar radiation to changes ine. Special attention is paid to the behavior of the solar radiation distribution curves near sunrise and sunset which at the warm pole of Mercury (longitudes ±90°) occur as the planet goes through perihelion. It has been found that for eccentricities larger than about 0.194 there exists two permanent thermal bulges on opposite sides of the Mercurian surface that alternately point to the Sun at every perihelion passage. The critical value ofe past which the Sun shortly sets after perihelion is near 0.213.     

Martian atmospheric and indigenous components of xenon and nitrogen in the Shergotty,Nakhla, and Chassigny group meteorites

Abstract— In a study of the isotopic signatures of trapped Xe in shock-produced glass of shergottites and in ALH 84001, we observe three components: (1) modern Martian atmospheric Xe that is isotopically mass fractionated relative to solar Xe, favoring the heavy isotopes, (2) solar-like Xe, as previously observed in Chassigny, and (3) an isotopically fractionated (possibly ancient) component with little or no radiogenic ¹²⁹Xe_rad. In situ-produced fission and spallation components are observed predominantly in the high-temperature steps. Heavy N signatures in ALH 84001, EET 79001 and Zagami reveal Martian atmospheric components. The low-temperature release of ALH 84001 shows evidence for the presence of a light N component (δ¹⁵N ≤ -21%), which is consistent with the component observed in the other Shergotty, Nakhla and Chassigny (SNC) group meteorites. The highest observed ¹²⁹Xe/¹³⁰Xe ratio of 15.60 in Zagami and EET 79001 is used here to represent the present Martian atmospheric component, and the isotopic composition of this component is compared with other solar system Xe signatures. The ¹²⁹Xe/¹³⁰Xe ratios in ALH 84001 are lower but appear to reflect varying mixing ratios with other components. The consistently high ¹²⁹Xe/¹³⁰Xe ratios in rocks of different radiometric ages suggest that Martian atmospheric Xe evolved early on. As already concluded in earlier work, only a small fission component is observed in the Martian atmospheric component. Assuming that a chondritic ²⁴⁴Pu/¹²⁹I initial ratio applies to Mars, this implies that either Pu-derived fission Xe is retained in the solid planet (in fact, in situ-produced fission Xe is observed in ALH 84001) or may reflect a very particular degassing history of the planet.     

Multiple emission angle surface-atmosphere separations of thermal emission spectrometer data

A method for separating the spectral signatures of the Martian surface and atmosphere was developed and is applied to multiple emission angle data returned from the MGS TES instrument. This method includes correlated-k and index gas removal algorithms that may be applied to all nadir-pointing TES data. Initial results have provided new and refined measurements of the spectral shapes of atmospheric dust and the Martian surface. Surface temperatures and atmospheric dust opacities are also retrieved with improved accuracy over single observation temperature and opacity retrievals. Low-albedo surfaces display absorptions consistent in both shape and depth with previous studies. These surfaces may be closely modeled using a combination of previously derived basalt, andesitic, and high-albedo surface spectral shapes. Short wavelengths display no significant absorptions, indicating both the coarse particulate nature of the surface and the lack of significant amounts of carbonate. Moderate- and high-albedo surfaces have spectral shapes distinctive of fine particulate silicate materials. No single material can match the entire high-albedo surface spectrum, though there are clear indications of a material that closely matches intermediate to calcic plagioclase and an emission peak at ∼1620 cm⁻¹ due to bound water. The lack of residual restrahlen silicate absorptions indicates that minerals such as olivine or pyroxene are not present in high-albedo surfaces at significant (but unknown) abundances. High-albedo surface results presented here are in agreement with and complementary to shorter wavelength observations. The Martian dust is composed of both primary and secondary minerals. Either chemical weathering has not completely altered its source material or the soil is a mixture of altered and unaltered sources. Further laboratory studies are needed to better establish detection limits and behavior of mineral mixtures of fine particulates in the thermal infrared portion of the spectrum.     

Argon-39-argon-40 “ages” and trapped argon in Martian shergottites,Chassigny, and Allan Hills 84001

Abstract— Argon-isotopic abundances were measured in neutron-irradiated samples of Martian meteorites Chassigny, Allan Hills (ALH) 84001, ALH 77005, Elephant Moraine (EET) 79001, Yamato (Y) 793605, Shergotty, Zagami, and Queen Alexandra Range (QUE) 94201, and in unirradiated samples of ALH 77005. Chassigny gives a ³⁹Ar-⁴⁰Ar age of 1.32 ± 0.07 Ga, which is similar to radiometric ages of the nakhlites. Argon-39-Argon-40 data for ALH 84001 indicate ages between 3.9 and 4.3 Ga. A more precise definition of this age requires detailed characterization of the multiple trapped Ar components in ALH 84001 and of ³⁹Ar recoil distribution. All six shergottite samples show apparent ³⁹Ar-⁴⁰Ar ages substantially older than the ～165–200 Ma range in ages given by other isotope dating techniques. Shergottites appear to contain ubiquitous Ar components acquired from the Martian atmosphere, the Martian mantle, and commonly terrestrial atmospheric contamination. Zagami feldspar also suggests inherited radiogenic ⁴⁰Ar. These data analyses indicate that the recent Martian atmospheric component trapped in shergottites has a ⁴⁰Ar/³⁶Ar ratio possibly as low as ～1750 and no greater than ～1900. These ratios are less than the value of 3000 ± 500 reported by Viking. The ⁴⁰Ar/³⁶Ar ratio for the Martian mantle component is probably <500 but is poorly constrained. The correlation between trapped ⁴⁰Ar/³⁶Ar and ¹²⁹Xe/¹³²Xe ratios in shergottite impact glasses and unirradiated samples of ALH 77005 shows considerable scatter and suggests that the ³⁶Ar/¹³²Xe ratio in the Martian components may vary. Resolution of Martian atmospheric ⁴⁰Ar/³⁶Ar ratio at different time periods (i.e., at ～4.0 and 0.2 Ga) is also difficult without an understanding of the composition of various trapped components.     

Martian thermal history,core segregation,and tectonics

A series of calculated thermal histories of Mars is presented, and their possible relation to surface tectonic history is discussed. The models include convective heat transport through an empirical approximation, and heating by radioactivity and core segregation. Initial temperature, T_i, and the timing and duration of core segregation are treated as free parameters. T_i is the main determinant of Martian thermal evolution: as it is varied from 20 to 100% of the present mean temperature, the maximum in surface heat flux moves from very recent to very early in Martian history. For the latter cases, the details of core segregation control the detailed timing of a peak in the thermal flux that exceeded 100 mW/m². It is suggested that the early disruption of cratered terrain crust in the northern hemisphere and subsequent volcanic resurfacing may have been related to core segregation. This would be consistent with a scenario in which an early period of core segregation generated a marked peak in the thermal flux that may have lead to extensivev partial melting and volcanism. This scenario would require Mars to have had an initial mean temperature comparable to the present value.     

Isotopic composition of trapped and cosmogenic noble gases in several Martian meteorites

Abstract— Isotopic abundances of the noble gases were measured in the following Martian meteorites: two shock glass inclusions from Elephant Moraine (EET) 79001, shock vein glass from Shergotty and Yamato (Y) 793605, and whole-rock samples of Allan Hills (ALH) 84001 and Queen Alexandra Range (QUE) 94201. These glass samples, when combined with literature data on a separate single glass inclusion from EET 79001 and a glass vein from Zagami, permit examination in greater detail of the isotopic composition of Ne, Ar, Kr, and Xe trapped from the Martian atmosphere. The isotopic composition of Martian Ne, if actually present in these glasses, remains poorly defined. The ⁴⁰Ar/³⁶Ar ratio of trapped Martian atmospheric Ar is probably considerably lower than the nominal ratio of 3000 measured by Viking, and data on impact glasses suggest a value of ～1900. The atmospheric ³⁶Ar/³⁸Ar ratio is ≤4.0. Martian atmospheric Kr may be enriched in lighter isotopes by ～0.5%/amu compared to both solar-wind Kr and to the Martian composition previously reported. The isotopic composition of Xe in these glasses agrees with that previously reported in the literature. The Martian atmospheric ³⁶Ar/¹³²Xe and ⁸⁴Kr/¹³²Xe elemental ratios are higher than those reported by Viking by factors of ～2.5–1.6 (depending on the ⁴⁰Ar/³⁶Ar ratio adopted) and ～1.8, respectively, and are discussed in a separate paper. Cosmogenic gases indicate space exposure ages of 2.7 ± 0.6 Ma for QUE 94201 and Shergotty and 14 ± 1 Ma for ALH 84001. Small amounts of ²¹Ne produced by energetic solar protons may be present in QUE 94201 but are not present in ALH 84001 or Y-793605. The space exposure age for Y-793605 is 4.9 ± 0.6 Ma and appears to be distinctly older than the ages for basaltic shergottites. However, uncertainties in cosmogenic production rates still makes somewhat uncertain the number of Martian impact events required to produce the exposure ages of Martian meteorites.     

Noble gases and chemical composition of Shergotty mineral fractions,Chassigny, and Yamato 793605: The trapped argon-40/argon-36 ratio and ejection times of Martian meteorites

Abstract— We report the elemental and isotopic composition of the noble gases as well as the chemical abundances in pyroxene, maskelynite/mesostasis glass, and bulk material of Shergotty and of bulk samples from Chassigny and Yamato 793605. The ⁴⁰K-⁴⁰Ar isochron for the Shergotty minerals yields a gas retention age of 196 Ma, which is, within errors, in agreement with previously determined Rb-Sr internal isochron ages. Argon that was trapped at this time has a ⁴⁰Ar/³⁶Ar ratio of 1100. For Chassigny and Y-793605, we obtain trapped ⁴⁰Ar/³⁶Ar ratios of 1380 and 950, respectively. Using these results and literature data, we show that the three shergottites, Shergotty, Zagami, and QUE 94001; the lherzolites ALH 77005, LEW 88516, and Y-793605; as well as Chassigny and ALH 84001 contain a mixture of Martian mantle and atmospheric Ar; whereas, the trapped ⁴⁰Ar/³⁶Ar ratio of the nakhlites, Nakhla, Lafayette, and Governador Valadares cannot be determined with the present data. We show that Martian atmospheric trapped Ar in Martian meteorites is correlated with the shock pressure that they experienced. Hence, we conclude that the Martian atmospheric gases were introduced by shock into the meteoritic material. For the Shergotty minerals, we obtain ³He-, ²¹Ne-, and ³⁸Ar-based cosmic-ray exposure ages of 3.0 Ma, and for the lherzolite Y-793605, 4.0 Ma, which confirms our earlier conclusion that the lherzolites were ejected from Mars ～1 Ma before the shergottites. Chassigny yields the previously known ejection age of 11.6 Ma.