Palaeoenvironment reconstruction,volcanic evolution and geochronology of the Cerro Blanco subcomplex,Nevados de Chillán volcanic complex,central Chile

Nevados de Chillán Volcanic Complex, central Chile, has been active for at least 640 ka—a period spanning a number of glacial and interglacial periods. Geologic mapping, radiometric dating and geochemical analysis have identified six new volcanic units and produced four new ⁴⁰Ar/³⁹Ar ages for Cerro Blanco, the northern subcomplex of Nevados de Chillán volcano. Compositions range from dacite to basaltic-andesite and a new geologic map is presented. Examination of lava fracture structures on both newly mapped lavas and those mapped during previous studies has enabled interpretations of former eruptive environments. Palaeoenvironment reconstructions, combined with ⁴⁰Ar/³⁹Ar ages and comparison with the marine oxygen isotope record, show that at least three phases of volcanic activity have occurred during the evolution of Cerro Blanco: (1) a constructive, pre-caldera collapse period; (2) a period of caldera formation and collapse; and (3) a constructive period of dome growth forming the modern day volcanic centre. This style of volcanic evolution, whereby large-scale caldera collapse is followed by growth of a new stratocone is common at Andean volcanoes.     

Metabolites in bile of fish from São Sebastião Channel, São Paulo, Brazil as biomarkers of exposure to petrogenic polycyclic aromatic compounds

This study reports the analysis of polycyclic aromatic compound (PAC) metabolites, as biomarkers of exposure to PACs in marine environment. PAC metabolites were measured in bile samples from 14 species of demersal fish caught in the São Sebastião Channel (SSC), SE Brazilian coastline. Naphthalene (NPH) equivalents, phenanthrene (PHN) equivalents, and benzo[a]pyrene (BaP) equivalents were quantified using a reverse-phase high-performance liquid chromatography coupled with fluorescence detection method. For all samples, the means (±standard deviation, n = 37) of concentrations obtained for NPH, PHN, and BaP equivalents were, respectively, 290,000 ± 200,000 ng/g, 18,000 ± 14,000 ng/g, and 970 ± 1900 ng/g. These results indicate recent exposure of these fish to PACs in their environment. In addition, two species (Cyclichthys spinosus and Prionotus nudigula) of fish were analyzed in order to investigate local sources of PAC contamination in the SSC and the influence of the petroleum terminal in fish caught in remote areas. The results showed that these fish species potentially migrate along the channel, especially P. nudigula. Correlations among groups of PAC metabolites indicate the same petrogenic source for NPH and PHN equivalents and a combustion source (e.g., automobile, ships) for BaP equivalents. The ratio BaP/PHN equivalents (0.05 ± 0.07, n = 37) confirms the predominance of petrogenic PACs for contamination by these chemicals in this region.     

Contribution of in situ geophysical methods for the definition of the São Sebastião crater model (Azores)

The area located inside the São Sebastião volcanic crater, at the southeast end of Terceira Island (Azores), is characterized by an important amplification of ground motion with respect to the surrounding area, as clearly demonstrated by the spatial distribution of the damage that occurred during the Terceira earthquake (the strongest earthquake felt in the Island during the recent decades — 01/01/1980 — M = 7.2). Geological and geophysical studies have been conducted, to characterize the volcanic crater and understand the different site effects that occurred in the village of São Sebastião. The complexity of the subsurface geology, with intercalations of compact basalt and soft pyroclastic deposits, is associated to extreme vertical and lateral velocity contrasts, and poses a serious challenge to different geophysical characterization methods. The available qualitative model did not allow a complete understanding of the site effects. A new seismic campaign has been designed and acquired, and a single, geologically consistent geophysical model has been generated integrating the existing and new data. The new campaign included two cross-line P-wave seismic refraction profiles, four short SH-wave seismic reflection profiles, and seven multichannel surface wave acquisitions. The integration and joint interpretation of geophysical and geological data allowed mutual validation and confirmation of data processing steps. In particular, the use of refraction, reflection and surface wave techniques allowed facing the complexity of a geology that can pose different challenges to all the methods when used individually: velocity inversions, limited reflectivity, and lateral variations. It is shown how the integration of seismic data from different methods, in the framework of a geological model, allowed the geometrical and dynamic characterization of the site. Correlation with further borehole information, then allowed the definition of a subsoil model for the crater, providing information that allowed a better understanding of the earthquake site effects in the São Sebastião village. The new near-surface geological model includes a lava layer within the soft infill materials of the crater. This new model matches closely with the damage distribution map, and explains the spatial variation of building stock performance in the 1980 earthquake.     

Tectono-metamorphic evolution of the Briançonnais zone (Modane-Aussois and Southern Vanoise units,Lyon Turin transect,Western Alps)

In the central Western Alps, a combined structural, petrological and ⁴⁰Ar–³⁹Ar geochronological study of the Modane-Aussois and Southern Vanoise units yields important constraints on the timing of deformation and exhumation of the Briançonnais zone. These data help to decipher the respective roles of oceanic subduction, continental subduction and collision in the burial and exhumation of the main units through time. In the Modane-Aussois unit top to the NW thrusting (D1) was followed by top to the east shearing (D2) interpreted by some as normal faulting and by others as backthrusting. Pseudosection calculations imply that D1 deformation occurred at 1.0 ± 0.1 GPa and 350 ± 30 °C. Analysis of chlorite–phengite pairs yield P–T estimates between 0.15 and 0.65 GPa and between 220 and 350 °C for the D2 event. Phengites along the D1 schistosity (sample M80) yields an ⁴⁰Ar–³⁹Ar age of 37.12 ± 0.39 Ma, while D2 phengites yield ages of 35.42 ± 0.38 (sample M173) and 31.60 ± 0.33 Ma (sample M196). It was not possible to test whether these ages are altered by excess argon or not. Our interpretation is that the D1/D2 transition occurred at ∼37 Ma at the beginning of decompression, and that D2 lasted until at least ∼32 Ma. Pseudosection calculation suggests that the Southern Vanoise unit was buried at 1.6 ± 0.2 GPa and 500–540 °C. D1 deformation occurred during exhumation until 0.7–10.5 GPa and 370 ± 30 °C. Published ages suggest that D1 deformation possibly started at ∼50 Ma and lasted until ∼37 Ma. D2 deformations started at P–T conditions close to that recorded in Modane-Aussois unit and lasted until 0.2 ± 0.1 GPa and 280 ± 30 °C at ∼28 Ma. The gap of 0.6 ± 0.3 GPa and 150 ± 130 °C between peak metamorphic conditions in the two units was concealed by thrusting of the South Vanoise unit on top of the Modane-Aussois unit during D1 Deformation. Top to the east deformation (D2) affects both units and is interpreted as backthrusting.Based on these data, we propose a geodynamic reconstruction where the oceanic subduction of the Piedmont unit until ∼50 Ma, is followed by its exhumation at the time of continental subduction of the continental Southern Vanoise unit until ∼45 Ma. The Southern Vanoise is in turn underthrusted by the Modane-Aussois unit until ∼37 Ma (D1). Between 37 and 31 Ma the Modane-Aussois and Southern Vanoise units exhume together during backthrusting to the east (D2). This corresponds to the collision stage and to the activation of the Penninic Thrust. In the ∼50 Ma to ∼31 Ma time period the main thrusts propagated westward as the tectonic context switched from oceanic to continental subduction and finally to collision. During each stage, external units are buried while internal ones are exhumed.     

Model sensitivity experiments on data assimilation,downscaling and tides for the representation of the Cape São Tomé Eddies

Ocean Dynamics - The impacts of data assimilation, downscaling, and tidal forcing were investigated with focus on the representation of the Cape São Tomé Eddy (CSTE). Sea level anomaly...     

PBDEs in the blubber of marine mammals from coastal areas of São Paulo, Brazil, southwestern Atlantic

Limited information is available in the literature on the levels of brominated flame retardants in the southern hemisphere. This study presents concentrations of polybrominated diphenyl ethers (PBDEs) in the blubber of small cetaceans from the coast of São Paulo (Brazil), southwestern Atlantic. PBDE levels were highest in Stenellafrontalis (770 ng g⁻¹ lipid) followed by Stenobredanensis (475 ng g⁻¹ lipid), Sotaliaguianensis (65.6 ng g⁻¹ lipid), Tursiopstruncatus (64.2 ng g⁻¹ lipid) and Pontoporiablainvillei (60.3 ng g⁻¹ lipid). In general, continental shelf individuals exhibited higher contamination than inshore animals. This might be related to larger prey items consumed by continental shelf dolphins. The pattern of contamination indicates that Penta-BDE commercial mixtures are a major source of PBDEs to top predators in the southwestern Atlantic. Congeners found in Octa-BDE formulations were not detected in the investigated animals.     

Seismotectonic destruction of the Earth’s crust in the zone of interaction of the northeastern side of the Baikal rift and the Aldan-Stanovoy block

The paper presents the modern structural-tectonic pattern and a tectonodynamic model of the zone of interaction of the most seismically active northeastern side of the Baikal rift zone (BRZ) and the conjugate system of seismogenic structures of the Aldan-Stanovoy block, where disastrous events with M ≥ 6.0 have been reported. Regularities in the structural formation of active faults and their kinematics are discussed. The faults form block structures accumulating significant tectonic strain. Motions between large tectonic blocks cause sudden release of the strain, which results in catastrophic events (M ≥ 6.0) with focal mechanisms of definite kinematic type.     

Ground Penetrating Radar Investigations in the Noble Hall of São Carlos Theater in Lisbon,Portugal

This paper describes a study conducted by the National Laboratory for Civil Engineering of Portugal (LNEC), in cooperation with the Defense University Center at the Spanish Naval Academy and “La Sapienza,” University of Rome, to assess the health and safety conditions of the Noble Hall floor in the São Carlos National Theater (Lisbon, Portugal). In a multidisciplinary approach, extensive fieldwork was carried out. The survey included the location and characterization of beams in the various areas of the floor by using two ground penetrating radar (GPR) systems equipped with two different ground- or air-coupled antennas, local inspection openings to visually assess the geometry, timber species and conservation state of structural members, and an assessment of the conservation state of the timber beam ends using drilling equipment. All the tests performed and the results obtained are presented. The potential of using non-destructive tests for the inspection of timber cultural heritage structures, particularly GPR, is discussed, and some practical recommendations are made.     

Rhyolites at Kerlingarfjöll, Iceland: the evolution and lifespan of silicic central volcanoes

Kerlingarfjöll central volcano is Iceland’s second largest outcrop of Quaternary rhyolite and is part of the Icelandic Western Rift Zone. Geochemical and Ar/Ar age data show that at least 21 different rhyolite eruptions have taken place at Kerlingarfjöll over the last 350 ka. Ar/Ar dating was carried out on samples of obsidian which showed variable reproducibility, illustrating the difficulty in dating young Icelandic volcanics. Nevertheless, reasonable estimates of eruption age have been derived for a number of eruptive units that are consistent with observed stratigraphy, enabling an understanding of the temporal evolution of Kerlingarfjöll. Two rhyolite magma types are present. The first is an older, low-Nb rhyolite that was erupted episodically along a cryptic curved fracture system, to form a discontinuous ring of rhyolite mountains, between 350 and 250 ka. This discontinuous ring is similar to structures observed at other volcanoes in Iceland, suggesting that the development of a curved fracture that acts as a pathway for episodic silicic eruptions is a feature of central volcano development. The second magma is a younger, high-Nb rhyolite that was erupted episodically between 250 and 68 ka in the northern part of Kerlingarfjöll, forming two clusters, both of which have areas of intense hydrothermal activity. Repose periods for rhyolite volcanism are thought to be on the order of tens of thousands of years, and it is possible that Kerlingarfjöll will erupt rhyolite again in the future.     

Geometry,kinematics and evolution of the Tongbai orogenic belt

1 Introduction spectively[2,3]. Several tectonic units such as the Bei- The Qinling-Dabie orogenic belt has attracted huaiyang, north Dabie, south Dabie and Susong belts worldwide attention by its very complex and abundant have been recognized in eastern Dabie[4]. Nine tec- geological characters, and has been a “hot point” of tonic units have been recognized in western Dabie and international geological research[1]. A vast amount of a more detailed division has been suggested especially …     

PCBs, PBDEs and organochlorine pesticides in crabs Hepatus pudibundus and Callinectes danae from Santos Bay, State of São Paulo, Brazil

The occurrence of persistent organic pollutants (POPs) as polychlorinated biphenyls (PCBs), organochlorine pesticides (OCPs) and polybrominated diphenyl ethers (PBDE) in crabs Hepatus pudibundus and Callinectesdanae was assessed from two different places inside of the Santos Bay and Moela Island near one of the most economically important metropolitan areas in Southern Brazil. Among POPs analyzed, ∑PCBs (222-923 ng g(-1)lipid weight) and ∑DDTs (154-410 ng g(-1)lw) exhibited the highest concentrations in the crabs. ∑HCHs ranged from 10.3 to 30.9 ng g(-1)lw and were found in all individuals. Other OCPs found in lower concentration was Mirex (7.6-41.6 ng g(-1)lw) and HCB (5.83-16.9 ng g(-1)lw). ∑PBDEs (24.1 ng g(-1)lw) were only found in one male individual from the species C. danae collected near to the submarine sewage of Santos. Male crabs showed higher POP concentrations than female crabs for those two species.     

Paleoclimate evolution and aridification mechanism of the eastern Tethys during the Callovian–Oxfordian: evidence from geochemical records of the Qiangtang Basin,Tibetan Plateau

Global climate during the Jurassic has been commonly described as a uniform greenhouse climate for a long time.However,the climate scenario of a cool episode during the Callovian-Oxfordian transition following by a warming trend during the Oxfordian(163.53 to157.4 Ma) is documented in many localities of the western Tethys.It is still unclear if a correlatable climate scenario also occurred in the eastern Tethys during the same time interval.In this study,a detailed geochemical analysis on the 1060 m thick successions(the Xiali and Suowa formations) from the Yanshiping section of the Qiangtang Basin,located in the eastern Tethys margin during the Callovian-Oxfordian periods,was performed.To reveal the climate evolution of the basin,carbonate content and soluble salt concentrations(SO_4~(2-),Cl~-) were chosen as climatic indices.The results show that the overall climate patterns during the deposition of the Xiali and Suowa formations can be divided into three stages:relatively humid(～164.0 to 160.9 Ma),dry(～160.9 to159.6 Ma),semi-dry(～159.6 to 156.8 Ma).A similar warming climate scenario also occurred in eastern Tethys during the Callovian-Oxfordian transition(～160.9 to159.6 Ma).Besides,we clarify that the Jurassic True polar wander(TPW),the motion of the lithosphere and mantle with respect to Earth's spin axis,inducing climatic shifts were responsible for the aridification of the Qiangtang Basin during the Callovian-Oxfordian transition with a review of the paleolatitude of the Xiali formation(19.7+2.8/-2.6° N) and the Suowa formation(20.7+4.1/-3.7° N).It is because the TPW rotations shifted the East Asia blocks(the North and South China,Qiangtang,and Qaidam blocks) from the humid zone to the tropical/subtropical arid zone and triggered the remarkable aridification during the Middle-Late Jurassic(ca.165-155 Ma).     

Comparison of the effects of soil moisture and El Niño on summer precipitation in eastern China

Science China Earth Sciences - The effects of spring soil moisture over the vast region from the lower and middle reaches of the Yangtze River valley to North China (YRNC) and El Niño on the...     

Textural variation in juvenile pyroclasts from an emergent,Surtseyan-type,volcanic eruption: The Capelas tuff cone,São Miguel (Azores)

Here I present textural data (i.e., vesicularity, vesicle size distributions (VSD), plagioclase crystallinity, crystal size distributions (CSD), combined with fractal analyses of particle outlines) from a natural succession of alternating fall and surge deposits in the emergent Capelas tuff cone (Azores).The textural variation in the Capelas succession is surprisingly small considering the wide variety of fragmentation processes, vent activity and emplacement mechanisms that are characteristic of emergent eruptions. The plagioclase crystal content varies between 24 and 33 vol.%. CSD analyses of plagioclase show near-linear trends with a slight increase in time for the smallest crystal sizes (with surge deposits having more groundmass plagioclase when compared with fall deposits). This is consistent with crystallization induced by degassing and decompression at lower eruption rates. The vesicularities of the Capelas pyroclasts are more variable (18 to 59 vol.%), with VSDs displaying kinked trends characteristic of coalescence. This is especially evident in the fall deposits, and consistent with being formed in continuous uprush (jetting) with an overall shallow fragmentation level within the conduit. Bubble coalescence can also be identified in the surge deposits, although to a much lesser extent. The amount of bubble coalescence is negatively correlated with the amount of groundmass crystallization (i.e., plagioclase) in the Capelas deposits.A relatively broad range of fractal dimensions (with average D_box = 1.744 and σ = 0.032) for the outlines of pyroclastic fragments emplaced by fall or as surges indicate that there is little difference in the fragmentation process itself at Capelas. In addition to this, the fact that the fractal dimensions for both the fall and surge end-members completely overlap suggests that shape modification due to abrasion and chipping of grain edges was minor during emplacement of base surges. These results are consistent with emergent eruptions, building tuff cones, to be a relatively low-energy phreatomagmatic landform (e.g., at least when compared with more energetic phreatomagmatic eruptions producing tuff rings and maar volcanoes).     

Acceleration and evolution of faults: An example from the Hunter Mountain–Panamint Valley fault zone,Eastern California

We present new space geodetic data indicating that the present slip rate on the Hunter Mountain–Panamint Valley fault zone in Eastern California (5.0 ± 0.5 mm/yr) is significantly faster than geologic estimates based on fault total offset and inception time. We interpret this discrepancy as evidence for an accelerating fault and propose a new model for fault initiation and evolution. In this model, fault slip rate initially increases with time; hence geologic estimates averaged over the early stages of the fault's activity will tend to underestimate the present-day rate. The model is based on geologic data (total offset and fault initiation time) and geodetic data (present day slip rate). The model assumes a monotonic increase in slip rate with time as the fault matures and straightens. The rate increase follows a simple Rayleigh cumulative distribution. Integrating the rate-time path from fault inception to present-day gives the total fault offset.     

Structure and development of the Andean system between 36° and 39°S

One of the main morphological changes along the Southern Central Andes occurs from 36° to 39°S. The northern portion is characterized by prominent basement structures and a thick-skinned orogenic front with relief of over 2000 m with a deep level of exhumation where more than 4 km of section has been eroded. Contrastingly, the southern part is formed by mildly inverted basement structures restricted mainly to the hinterland zone, which reaches only 1500–1700 m relief. We quantify the variable contributions of two main contractional stages through the construction of three regionally balanced sections across the Andes, constrained by field and geophysical data. Extensional re-activation described for this segment in late Oligocene-early Miocene and Pliocene to Quaternary times, after the two main contractional episodes, suggests only 3 km of stretching that represents 30–10% of the original longitude. We, therefore, conclude that while initial Late Cretaceous to Eocene compression was similar along strike (∼10–7 km), it is the contrasting degrees of Neogene shortening (∼16–6 km) that have played the largest role in the along strike differences in structure and morphology along this portion of the southern Andes. Variable Neogene arc expansion could be responsible for the contrasting contractional deformation: In the north, late Miocene arc-related rocks cover most of the retroarc zone (>200 km with respect to the late Miocene arc front in the south), presumably driven by a shallow subduction episode in the area, whereas to the south they remain restricted to the continental drainage divide. Other factors involving architecture of previous rift structures, are proposed as additional mechanisms that accommodated variable shortening magnitudes through inversion.     

A re-appraisal of the stratigraphy and volcanology of the Cerro Galán volcanic system,NW Argentina

From detailed fieldwork and biotite ⁴⁰Ar/³⁹Ar dating correlated with paleomagnetic analyses of lithic clasts, we present a revision of the stratigraphy, areal extent and volume estimates of ignimbrites in the Cerro Galán volcanic complex. We find evidence for nine distinct outflow ignimbrites, including two newly identified ignimbrites in the Toconquis Group (the Pitas and Vega Ignimbrites). Toconquis Group Ignimbrites (~5.60–4.51 Ma biotite ages) have been discovered to the southwest and north of the caldera, increasing their spatial extents from previous estimates. Previously thought to be contemporaneous, we distinguish the Real Grande Ignimbrite (4.68 ± 0.07 Ma biotite age) from the Cueva Negra Ignimbrite (3.77 ± 0.08 Ma biotite age). The form and collapse processes of the Cerro Galán caldera are also reassessed. Based on re-interpretation of the margins of the caldera, we find evidence for a fault-bounded trapdoor collapse hinged along a regional N-S fault on the eastern side of the caldera and accommodated on a N-S fault on the western caldera margin. The collapsed area defines a roughly isosceles trapezoid shape elongated E-W and with maximum dimensions 27 × 16 km. The Cerro Galán Ignimbrite (CGI; 2.08 ± 0.02 Ma sanidine age) outflow sheet extends to 40 km in all directions from the inferred structural margins, with a maximum runout distance of ~80 km to the north of the caldera. New deposit volume estimates confirm an increase in eruptive volume through time, wherein the Toconquis Group Ignimbrites increase in volume from the ~10 km³ Lower Merihuaca Ignimbrite to a maximum of ~390 km³ (Dense Rock Equivalent; DRE) with the Real Grande Ignimbrite. The climactic CGI has a revised volume of ~630 km³ (DRE), approximately two thirds of the commonly quoted value.