SHRIMP U–Pb zircon chronology of ultrahigh‐temperature spinel–orthopyroxene–garnet granulite from South Altay orogenic belt,northwestern China

Diagnostic mineral assemblages, mineral compositions and zircon SHRIMP U–Pb ages are reported from an ultrahigh‐temperature (UHT) spinel–orthopyroxene–garnet granulite (UHT rock) from the South Altay orogenic belt of northwestern China. This Altay orogenic belt defines an accretionary belt between the Siberian and Kazakhstan–Junggar Plates that formed during the Paleozoic. The UHT rock examined in this study preserves both peak and retrograde metamorphic assemblages and microstructures including equilibrium spinel + quartz, and intergrowth of orthopyroxene, spinel, sillimanite, and cordierite formed during decompression. Mineral chemistry shows that the spinel coexisting with quartz has low ZnO contents, and the orthopyroxene is of high alumina type with Al₂O₃ contents up to 9.3 wt%. The peak temperatures of metamorphism were >950°C, consistent with UHT conditions, and the rocks were exhumed along a clockwise P–T path. The zircons in this UHT rock display a zonal structure with a relict core and metamorphic rim. The cores yield bimodal ages of 499 ± 8 Ma (7 spots), and 855 Ma (2 spots), with the rounded clastic zircons having ages with 490–500 Ma. Since the granulite was metamorphosed at temperatures >900°C, exceeding the closure temperature of U–Pb system in zircon, a possible interpretation is that the 499 ± 8 Ma age obtained from the largest population of zircons in the rock marks the timing of formation of the protolith of the rock, with the zircons sourced from a ～500 Ma magmatic provenance, in a continental margin setting. We correlate the UHT metamorphism with the northward subduction of the Paleo‐Asian Ocean and associated accretion‐collision tectonics of the Siberian and Kazakhstan–Junggar Plates followed by rapid exhumation leading to decompression.     

Orthopyroxene–cordierite mafic gneiss from the Nomamisaki metamorphic rocks,Southern Kyushu,Japan: Implication for western continuation of the Usuki–Yatsushiro Tectonic Line

We describe an orthopyroxene–cordierite mafic gneiss from the Nomamisaki metamorphic rocks in the Noma Peninsula, southern Kyushu, Japan. The mineral assemblage of the gneiss is orthopyroxene, cordierite, biotite, plagioclase, and ilmenite. Thermometry based on the Fe–Mg exchange reaction between orthopyroxene and biotite yields a peak metamorphic temperature of 680°C. The stability of cordierite relative to garnet, quartz, and sillimanite defines the upper limit of the peak metamorphic pressure as 4.4 kbar. These features indicate that the Nomamisaki metamorphic rocks underwent low‐pressure high‐temperature type metamorphism. Although a chronological problem still remains, the Nomamisaki metamorphic rocks can be regarded as a western continuation of the Higo Belt. The Usuki–Yatsushiro Tectonic Line, which delineates the southern border of the Higo Belt, is therefore located on the east of the Nomamisaki metamorphic rocks in southern Kyushu.     

Petrology and geochemistry of ultrahigh‐temperature granulites from the South Altay orogenic belt,northwestern China: Implications for metamorphic evolution and protolith composition

Ultrahigh‐temperature (UHT) granulites in the South Altay orogenic belt of Northwestern China provide important clues for the lower crustal components and tectonic evolution of the Central Asian Orogenic Belt during the Paleozoic. In this paper, we studied whole‐rock geochemistry and mineral characteristics to understand the protolith and metamorphic evolution of the Altay UHT granulite. The Altay granulite shows negative discriminant function values (DF) of ?9.27 to ?3.95, indicating a sedimentary origin, probably an argillaceous rock. The peak metamorphic temperature–pressure conditions of 920–1010 °C and > 9 kbar were estimated from the geothermobarometry, together with the stability of spinel (low ZnO) + quartz and orthopyroxene (Al₂O₃ up to 9.2 wt.%) + sillimanite + quartz in the Altay UHT rock, indicate a UHT metamorphic condition has been achieved. Two stages of retrograde conditions are recognized in these rocks; the first is an isothermal decompression to approx. 750 °C at 5.2–5.8 kbar at the early stage, and the second is the cooling down to 520–550 °C at 4.8–5.2 kbar. Combined with previous study, the formation of the Altay UHT pelitic granulite with a clockwise retrograde P–T path is inferred to be related with collisional and accretional orogenic process between the Siberian and Kazakhstan–Junggar plates.     

CHIME monazite dating as a tool to detect polymetamorphism in high‐temperature metamorphic terrane: Example from the Aoyama area,Ryoke metamorphic belt,Southwest Japan

Chemical Th–U–total Pb isochron method (CHIME) monazite dating was carried out for pelitic–psammitic migmatites and the Ao granite (one of the Younger Ryoke granites) from the Aoyama area, Ryoke metamorphic belt, Southwest Japan. The Ao granite gives an unequivocal age of 79.8 ± 3.9 Ma. The monazite grains in migmatites yield an age of 96.5 ± 1.9 Ma with rims and patchy domains of 83.5 ± 2.4 Ma. The 83.5 ± 2.4‐Ma overprinting on migmatites over the garnet–cordierite zone suggests a wide and combined effect of thermal input and fluid activity on the monazite grains caused by the contact metamorphism by the Younger Ryoke granites including the Ao granite. This contact metamorphism has not been detected from the major metamorphic mineral assemblage previously, possibly because the migmatites already possessed the high‐temperature mineral assemblage before the granite intrusions and were immune from contact metamorphism in terms of major metamorphic minerals. However, monazite records contact metamorphism clearly. Therefore, the field mapping of the CHIME monazite age is a powerful tool for recognition of polymetamorphism in high‐temperature metamorphic terrains where later thermal effects can not be easily detected by the growth of new major metamorphic minerals.     

A metamorphic history from micron-scale Pb/Pb chronometry of Archean monazite

Ion microprobe measurements of Pb isotope ratios in monazites have been obtained, in situ, from thin sections using the Cambridge ISOLAB 120. Molecular interferences are sufficiently resolved at an RP of 6500 to allow ²⁰⁷Pb/²⁰⁶Pb dating of monazite with precisions as low as 4–5 Ma (2σ). The results presented here provide important information on the chronological history of the Late Archean metamorphism of the Wind River Range, Wyoming (USA).

Matrix monazites and monazite inclusions in garnets from a metapelite from the northern Wind River Range have been analysed by SIMS. In a previous study peak metamorphic conditions (T = 800°C; P = 8 ± 1 kb^*) were estimated using inclusion assemblages in garnets from this same sample. Isolated monazite inclusions in garnet yield ²⁰⁷Pb/²⁰⁶Pb age estimates of 2781 ± 6 to 2809 ± 10 Ma. Those along fractures yield lower ages (2603–2687 Ma) which are similar to TIMS and SIMS ages of matrix monazites. A single large (500 μm) monazite grain locally preserves growth zoning, but has a recrystallised core and a resorbed (recrystallised?) rim. Age estimates for these three regions are 2788 ± 9 Ma, 2663 ± 4 and 2523 ± 6 Ma, respectively. Thus the inclusion assemblages of Sharp and Essene^* may record peak metamorphic conditions at ca. 2.8 Ga, and indicate a phase of metamorphism that predates by over 100 Ma the emplacement of the Bridger Batholith, the major lithologic component of the northern Wind River Range.

The analysed monazite grains appear to preserve ca. 300 Ma history, even within a single grain. Monazite inclusions in garnet that are fully armoured may provide estimates for the time of garnet growth, even in high grade terranes where most chronometers are reset. The age pattern preserved by the large monazite grain cannot be simply related to diffusion controlled closure. Instead, a chronology is preserved which can be related to the petrographic setting of indicidual grains through in situ analysis.     

U–Pb ages of zircons from metamorphic rocks in the upper sequence of the Hidaka Metamorphic Belt,Hokkaido, Japan: Identification of two metamorphic events and implications for regional tectonics

The Hidaka Metamorphic Belt is a well-known example of island-arc crustal section, in which metamorphic grade increases westwards from unmetamorphosed sediment up to granulite facies. It is divided into lower (granulite to amphibolite facies) and upper (amphibolite to greenschist facies) metamorphic sequences. The metamorphic age of the belt was considered to be ~55 Ma, based on Rb – Sr whole-rock isochron ages for granulites and related S-type tonalities. However, zircons from the granulites in the lower sequence yield U – Pb ages of ~21 – 19 Ma, and a preliminary report on zircons from pelitic gneiss in the upper sequence gives a U – Pb age of ~40 Ma. In this paper we provide new zircon U – Pb ages from two pelitic gneisses in the upper sequence to assess the metamorphic age and also the maximum depositional age of the sedimentary protolith. The weighted mean ²⁰⁶Pb/²³⁸U ages from a biotite gneiss in the central area of the belt yield 39.6 ± 0.9 Ma for newly grown metamorphic rims and 53.1 ± 0.9 Ma for the youngest detrital cores. The ages of zircons from a cordierite–biotite gneiss in the southern area are 35.9 ± 0.7 Ma for metamorphic rims and 46.5 ± 2.8 Ma for the youngest detrital cores. These results indicate that metamorphism of the upper sequence took place at ~40 – 36 Ma, and that the sedimentary protolith was deposited after ~53 – 47 Ma. These metamorphic ages are consistent with the reported ages of ~37–36 Ma plutonic rocks in the upper sequence, but contrast with the ~21–19 Ma ages of metamorphic and plutonic rocks in the lower sequence. Therefore, we conclude that the upper and lower metamorphic sequences developed independently but coupled with each other before ~19 Ma as a result of dextral reverse tectonic movement.     

Metamorphic characteristics and geotectonic implications of the high-pressure granulites from Namjagbarwa, eastern Tibet

A large area of high-pressure garnet-kyanite granulite is exhumed in the Namjagbarwa area, which provides a window for observing the deep crust rocks and structures of the Tibetan Plateau. Three mineral assemblages can have been distinguished in the garnet-kyanite HP granulites by petrography, i.e. M₁. Mus+Bi+P1+Q, M₂. Gt+Ky +perphite/antiperphite+Rt+Q, M₃. Gt+Sill+Cord+Sp+Ilm ± Opx. Metamorphic conditions of the peak granulite assemblages (M₂) formatted by thickening of crusts, with available isotopic ages of 45–69 Ma, are at 1.4—1.8 Gpa and 750—850°. Their retrograde assemblages overprinted by decompressure during the uplift, with available isotopic ages of 18—23 Ma, were formed at 0.60—0.70 Gpa, 621—726°. The thermobarometric evaluation, petrogenetic grid and corresponding isotopic ages indicate a clockwise isothermal decompression metamorphic path. The HP granulite metamorphic history indicates that the collision of the Indian Plate with the Eurasian Plate had begun at 70 Ma, far earlier than the widely accepted 45 Ma. Project supported by the National Natural Science Foundation of China (Grant No. 49732100), the National Key Project for Basic Research, and the Chinese Academy of Sciences Project for Tibetan Research Project (GrantNos. KZ951-A1-204, KZ95T-06).     

Sm–Nd, Rb–Sr and K–Ar geochronology of the Higo metamorphic terrane, west-central Kyushu, Japan

The Higo metamorphic terrane situated in west-central Kyushu island, southwest Japan, is composed of greenschist- to granulite-facies metamorphic rocks. The southern part of the metamorphic terrane consists mainly of garnet–biotite gneiss and garnet–cordierite–biotite gneiss, and orthopyroxene or cordierite-bearing S-type tonalite with subordinate amounts of hornblende gabbro. Rb–Sr, Sm–Nd and K–Ar isotopic ages for these rocks have been determined here. The garnet–biotite gneiss gives an Sm–Nd age of 227.1 ± 4.9 Ma and a Rb–Sr age of 101.0 ± 1.0 Ma. The hornblende gabbro has an Sm–Nd age of 257.9 ± 2.5 Ma and a K–Ar age of 103.4 ± 1.1 Ma. These age differences of the same samples are due to the difference in the closure temperature for each system and minerals. The garnet-cordierite–biotite gneiss contains coarse-grained garnet with a zonal structure conspicuously distinguished in color difference (core: dark red; rim: pink). Sm–Nd internal isochrons of the garnet core and the rim give ages of 278.8 ± 4.9 Ma (initial ¹⁴³Nd/¹⁴⁴Nd ratio = 0.512311 ± 0.000005) and 226.1 ± 28.4 Ma (0.512277 ± 0.000038), respectively. These ages are close to formation of the garnet core and the rim. It has been previously suggested that the Higo metamorphic terrane belongs to the Ryoke metamorphic belt. But Sr and Nd isotopic features of the rocks from the former are different from those of the Ryoke metamorphic rocks, and are similar to those of the granulite xenoliths contained in the Ryoke younger granite.     

Sm-Nd and zircon SHRIMP U-Pb dating of Huilanshan mafic granulite in the Dabie Mountains and its zircon trace element geochemistry

Granulites in the Dabie Mountains are mainly ob-served in northern Dabie complex zone. Huangtuling intermediate-acid granulites and Huilanshan mafic granulites in the Luotian dome are two famous out-crops (Fig. 1)[1]. It is important to know the genesis and metamorphic age of these granulites for under-standing tectonic evolution and exhumation history of the Dabie Mountains. Previous geochemical and geo-chronological work[2―8]1) on the Huangtuling granu-lites indicates that their protoli…     

Extensive normal faulting during exhumation revealed by the spatial variation of phengite K–Ar ages in the Sambagawa metamorphic rocks,central Shikoku,SW Japan

Metamorphic rocks experience change in the mode of deformation from ductile flow to brittle failure during their exhumation. We investigated the spatial variation of phengite K–Ar ages of pelitic schist of the Sambagawa metamorphic rocks (sensu lato) from the Saruta River area, central Shikoku, to evaluate if those ages are disturbed by faults or not. As a result, we found that these ages change by ca 5 my across the two boundaries between the lower‐garnet and albite–biotite, and the albite–biotite and upper‐garnet zones. These spatial changes in phengite K–Ar ages were perhaps caused by truncation of the metamorphic layers by large‐scale normal faulting at D₂ phase under the brittle‐ductile transition conditions (ca 300°C) during exhumation, because an actinolite rock was formed along a fault near the former boundary. Assuming that the horizontal metamorphic layers and a previously estimated exhumation rate of 1 km/my before the D₂ phase, the change of 5 my in phengite K–Ar ages is converted to a displacement of about 10 km along the north‐dipping, low‐angle normal fault documented in the previous study. Phengite ⁴⁰Ar–³⁹Ar ages (ca 85 to 78 Ma) in the actinolite rock could be reasonably comparable to the phengite K–Ar ages of the surrounding non‐faulted pelitic schist, because the K–Ar ages of pelitic schist could have been also reset at temperatures close to the brittle–ductile transition conditions far below the closure temperature for thermal retention of argon in phengite (about 500–600°C).     

Regional-Scale Excess Ar wave in a Barrovian type metamorphic belt, eastern Tibetan Plateau

Laser step heating ⁴⁰Ar/³⁹Ar analysis of biotite and muscovite single crystals from a Barrovian type metamorphic belt in the eastern Tibetan plateau yielded consistent cooling ages of ca. 40 Ma in the sillimanite zone with peak metamorphic temperatures higher than 600°C and discordant ages from 46 to 197 Ma in the zones with lower peak temperatures. Chemical Th‐U‐Total Pb Isochron Method (CHIME) monazite (65 Ma) and sensitive high mass‐resolution ion microprobe (SHRIMP) apatite (67 Ma) dating give the age of peak metamorphism in the sillimanite zone. Moderate amounts of excess Ar shown by biotite grains with ages of 46 to 94 Ma at metamorphic grades up to the high‐grade part of the kyanite zone probably represent incomplete degassing during metamorphism. In contrast, the high‐grade part of the kyanite zone yields biotite ages of 130 to 197 Ma. The spatial distribution of these older ages in the kyanite zone along the sillimanite zone boundary suggests they reflect trapped excess argon that migrated from higher‐grade regions. The most likely source is muscovite that decomposed to form sillimanite. The zone with extreme amounts of excess argon preserves trapped remnants of an ‘excess argon wave’. We suggest this corresponds to the area where biotite cooled below its closure temperature in the presence of an elevated Ar wave. Extreme excess Ar is not recognized in muscovite suggesting that the entrapment of the argon wave by biotite took place when the rocks had cooled down to temperatures lower than the closure temperature of muscovite. The breakdown of phengite during ultrahigh‐pressure (UHP) metamorphism may be a key factor in accounting for the very old apparent ages seen in many UHP metamorphic regions. This is the first documentation of a regional Ar‐wave spatially associated with regional metamorphism. This study also implies that resetting of the Ar isotopic systems in micas can require temperatures up to 600°C; much higher than generally thought.     

New SHRIMP U–Pb zircon ages of granitic rocks in the Hida Belt,Japan: Implications for tectonic correlation with Jiamushi massif

Granitoids in the Hida region of Japan encompass two main rock types: younger type‐1 granites and older type‐2 granites. Sensitive high mass‐resolution ion microprobe (SHRIMP) U–Pb zircon dating of older type‐2 granites collected from the Tateyama area show similar ages of 245 ± 2 Ma and 248 ± 5 Ma for two gneissose granites, while a significantly younger intrusion age of 197 ± 3 Ma was determined for the younger type‐1 granites collected from the Hayatsukigawa River which belongs to the Okumayama pluton. A felsic gneiss sample (07HI‐3) collected from the right bank of the Hayatsukigawa River yielded multiple complex ages at 330 ± 6 Ma, indicating the timing of the Hida regional tectono‐thermal events that formed the Hida gneisses; 243 ± 8 Ma, representing the timing of intrusion of the augen granite; and 220 Ma, indicating the timing of regional dextral ductile shearing that caused a repeated recrystallization of metamorphic rocks in the study area. Considering the geochronological data, the rock types and assemblages, basement, and Sr–Nd isotopic constraints, we propose that the Hida Belt separated from the Jiamushi massif, which is located in the eastern margin of the Central Asian Orogenic Belt.     

Mineral chemistry,P-T-t paths and exhumation processes of mafic granulites in Dinggye,Southern Tibet

Lower crustal high grade metamorphic rocks have been successively found at Pamirs nearby the western Himalayan syntaxis, Namjagbarwa and Dinggye nearby the eastern Himalayan syntaxis and the central segment of the Himalayan Orogenic Belt, respec-tively[1―4]. In particular, some researchers deduced that there were probably eclogites at some locations[5]. Moreover, some geochronological data of these lower crustal granulites also have been accumulated. For example, the high-pressure granulit…     

Ultra-high pressure metamorphic rocks in the Dabie-Su-Lu region, China: Their formation and exhumation

Abstract Based on petrological, structural, geological and geochronological research, the authors summarize the progress of ultra-high pressure (UHP) metamorphic rock study since 1989 by Chinese geoscientists and foreign geoscientists in the Dabie-Su-Lu region. The authors introduce and discuss a two-stage exhumation process for the UHP metamorphic rocks that have various lithologies; eclogite, ultramafics, jadeitic quartzite, gneiss, schist and marble. The metamorphic history of UHP metamorphic rocks is divided into three stages, that is, the pre-eclogite stage, coesite eclogite stage, and retrograde stage. Prior to UHP metamorphism, the ultramafics had a high temperature environment assemblage of mantle and others had blueschist facies assemblages. The granulite facies assemblages, which have recorded a temperature increase event with decompression, have developed locally in the Weihai basaltic rocks. Isotopic ages show a long range from > 700 Ma to 200 Ma. The diversity in protoliths of UHP metamorphic rocks may be related to the variation of isotopic ages older than 400 Ma. The Sm-Nd dating of ~ 220 Ma could reflect the initial exhumation stage after the peak UHP metamorphism in relation to the collision between the Sino-Korean and Yangtze blocks and subsequent events. Petrological and structural evidence imply a two-stage exhumation process. During the initial exhumation, the UHP metamorphic rocks were sheared and squeezed up in a high P/T regime. In the second exhumation stage the UHP metamorphic rocks were uplifted and eventually exposed with middle crustal rocks.     

Fission track and U–Pb zircon ages of psammitic rocks from the Harushinai unit,Kamuikotan metamorphic rocks,central Hokkaido,Japan: constraints on metamorphic histories

Accurate pressure–temperature–time (P–T–t) paths of rocks from sedimentation through maximum burial to exhumation are needed to determine the processes and mechanisms that form high‐pressure and low‐temperature type metamorphic rocks. Here, we present a new method combining laser ablation–inductively coupled plasma–mass spectrometry (LA–ICP–MS) U–Pb with fission track (FT) dates for detrital zircons from two psammitic rock samples collected from the Harushinai unit of the Kamuikotan metamorphic rocks. The concordant zircon U–Pb ages for these samples vary markedly, from 1980 to 95 Ma, with the youngest age clusters in both samples yielding Albian‐Cenomanian weighted mean ages of 100.8 ± 1.1 and 99.3 ± 1.0 Ma (2σ uncertainties). The zircon U–Pb ages were not reset by high‐P/T type metamorphism, because there is no indication of overgrowth within the zircons with igneous oscillatory zoning. Therefore, these weighted mean ages are indicative of the maximum age of deposition of protolithic material. By comparison, the zircon FT data yield a pooled age of ca. 90 Ma, which is almost the same as the weighted mean age of the youngest U–Pb age cluster. This indicates that the zircon FT ages were reset at ca. 90 Ma while still at their source, but have not been reset since. This conclusion is supported by recorded temperature conditions of less than about 300 °C (the closure temperature of zircon FTs), as estimated from microstructures in the deformed detrital quartz grains in psammitic rocks, and no shortening of fission track lengths in the zircon. Combining these new data with previously reported white mica K–Ar ages indicates that the Harushinai unit was deposited after ca. 100 Ma, and underwent burial to its maximum depth before being subjected to a localized thermal overprint during exhumation at ca. 58 Ma.     

Geology of the Grove Mountains in East Antarctica

Grove Mountains consists mainly of a series of high-grade (upper amphibolite to granulite facies) metamorphic rocks, including felsic granulite, granitic gneiss, mafic granulite lenses and charnockite, intruded by late tectonic gneissic granite and post-tectonic granodioritic veins. Geochemical analysis demonstrates that the charnockite, granitic gneiss and granite belonged to aluminous A type plutonic rocks, whereas the felsic and mafic granulite were from supracrustal materials as island-arc, oceanic island and middle oceanic ridge basalt. A few high-strained shear zones disperse in regional stable sub-horizontal foliated metamorphic rocks. Three generations of ductile deformation were identified, in which D₁ is related to the event before Pan-African age, D₂ corresponds to the regional granulite peak metamorphism, whereas D₃ reflects ductile extension in late Pan-African orogenic period. The metamorphic reactions from granitic gneiss indicate a single granulite facies event, but 3 steps from mafic granulite, with P-T condition of M1 800°C, 9.3×10⁵ Pa; M₂ 800–810°C, 6.4 × 10⁵ Pa; and M₃ 650°C have been recognized. The U-Pb age data from representative granitic gneiss indicate (529±14) Ma of peak metamorphism, (534±5) Ma of granite emplacement, and (501±7) Ma of post-tectonic granodioritic veins. All these evidences suggest that a huge Pan-African aged mobile belt exists in the East Antarctic Shield extending from Prydz Bay via Grove Mountains to the southern Prince Charles Mountains. This orogenic belt could be the final suture during the Gondwana Land assemblage.     

Ultrahigh-pressure metamorphic records hidden in zircons from amphibolites in Sulu Terrane, eastern China

Abstract The amphibolites occur sporadically as thin layers and blocks throughout the Sulu Terrane, eastern China. All analyzed amphibolite from outcrop and drill cores from prepilot drill hole CCSD‐PP1 and CCSD‐PP2, Chinese Continental Scientific Drilling Project in the Sulu Terrane, are retrograded eclogites overprinted by amphibolite‐facies retrograde metamorphism, with characteristic mineral assemblages of amphibole + plagioclase + epidote ± quartz ± biotite ± ilmenite ± titanite. However, coesite and coesite‐bearing ultrahigh‐pressure (UHP) mineral assemblages are identified by Raman spectroscopy and electron microprobe analysis as inclusions in zircons separated from these amphibolites. In general, coesite and other UHP mineral inclusions are preserved in the cores and mantles of zircons, whereas quartz inclusions occur in the rims of the same zircons. The UHP mineral assemblages consist mainly of coesite + garnet + omphacite + rutile, coesite + garnet + omphacite, coesite + garnet + omphacite + phengite + rutile + apatite, coesite + omphacite + rutile and coesite + magnesite. Compositions of analyzed mineral inclusions are very similar to those of matrix minerals from Sulu eclogites. These UHP mineral inclusion assemblages yield temperatures of 631–780°C and pressures of ≥2.8 × 10³ MPa, representing the P–T conditions of peak metamorphism of these rocks, which are consistent with those (T = 642–726°C; P ≥ 2.8 × 10³ MPa) deduced from adjacent eclogites. These data indicate that the amphibolites are the retrogressive products of UHP eclogites.     

Age gap between the intrusion of gneissose granitoids and regional high‐temperature metamorphism in the Ryoke belt (Mikawa area), central Japan

The relationships between the intrusion of gneissose granitoids and the attainment of regional high‐T conditions recorded in metamorphic rocks from the Ryoke belt of the Mikawa area, central Japan, are explored. Seven gneissose granitoid samples (tonalite, granodiorite, granite) were collected from three distinct plutonic bodies that are mapped as the so‐called “Older Ryoke granitoids.” Based on bulk‐rock compositions and U–Pb zircon ages obtained by laser ablation inductively coupled plasma mass spectrometry, the analyzed granitoids can be separated into two groups. Gneissose granitoids from the northern part of the area give weighted mean ²⁰⁶Pb/²³⁸U ages of 99 ±1 Ma (two samples) and 95 ±1 Ma (one sample), whereas those from the southern part yield 81 ±1 Ma (two samples) and 78–77 ±1 Ma (two samples). Regional comparisons allow correlation of the northern granitoids (99–95 Ma) with the Kiyosaki granodiorite, and mostly with the Kamihara tonalite found to the east. The southern granitoids are tentatively renamed as “78–75 Ma (Hbl)?Bt granite” and “81–75 Ma Hbl?Bt tonalite” (Hbl, hornblende; Bt, biotite). and seem to be broadly coeval members of the same magmatic suite. With respect to available age data, no gneissose granitoid from the Mikawa area shows a U–Pb zircon age which matches that of high‐T metamorphism (ca 87 Ma). The southern gneissose granitoids (81–75 Ma), although they occur in the highest‐grade metamorphic zone, do not seem to represent the heat source which produced the metamorphic field gradient with a low dP/dT slope.     

In situ LA-ICP-MS zircon U-Pb age of ultrahigh-pressure eclogites in the Yukahe area,northern Qaidam Basin

Zircon grains were selected from two types of ultrahigh-pressure (UHP) eclogites, coarse-grained phengite eclogite and fine-grained massive eclogite, in the Yukahe area, the western part of the North Qaidam UHP metamorphic belt. Most zircon grains show typical metamorphic origin with residual cores in some irregular grains and sector, planar or misty internal textures on the cathodoluminescence (CL) images. The contents of REE and HREE of the core parts of grains range from 173 to 1680 μg/g and 170 to 1634 μg/g, respectively, in phengite eclogite, and from 37 to 2640 μg/g and 25.7 to 1824 μg/g, respectively, in massive eclogite. The core parts exhibit HREE-enriched patterns, representing the residual zircons of protolith of the Yukahe eclogite. The contents of REE and HREE of the rim parts and the grains free of residual cores are much lower than those for the core parts. They vary from 13.1 to 89.5 μg/g and 12.5 to 85.7 μg/g, respectively, in phengite eclogite, and from 9.92 to 45.8 μg/g and 9.18 to 43.8 μg/g, respectively, in massive eclogite. Negative Eu anomalies and Th/U ratios decrease from core to rim. Positive Eu anomalies are shown in some grains. These indicate that the presence of garnet and the absence of plagioclase in the peak metamorphic mineral assemblage, and the zircons formed under eclogite facies conditions. LA-ICP-MS zircon U-Pb age data indicate that phengite eclogite and massive eclogite have similar metamorphic age of 436±3Ma and 431±4Ma in the early Paleozoic and magmatic protolith age of 783–793 Ma and 748–759 Ma in the Neo-proterozoic. The weighted mean age of the metamorphic ages (434±2 Ma) may represent the UHP metamorphic age of the Yukahe eclogites. The metamorphic age is well consistent with their direct country rocks of gneisses (431±3 Ma and 432±19 Ma) and coesite-bearing pelitic schist in the Yematan UHP eclogite section (423–440 Ma). These age data together with field observation and lithology, allow us to conclude that the Yukahe eclogites were Neo-proterozoic igneous rocks and may have experienced subduction and UHP metamorphism with continental crust at deep mantle during the early Paleozoic, therefore the metamorphic age of 434±2 Ma of the Yukahe eclogites probably represents the continental deep subduction time in this area.

     

Time constraints for Mesoproterozoic upper amphibolite facies metamorphism in NW Namibia: a multi-isotopic approach

This study presents the chronological evolution of the upper amphibolite facies Orue Unit in NW Namibia. Metasedimentary and meta-igneous rocks of the Orue Unit were investigated using the Pb–Pb stepwise leaching technique on garnet and rutile, U–Pb multi-grain analysis on rutile, Sm–Nd–Lu–Hf leaching technique on garnet, SHRIMP analysis on zircon and Ar–Ar dating on amphibole. Each of these techniques pertains to different processes that occurred before, during, or after the metamorphic peak. Our age data can be integrated with petrological constraints to provide a more complete understanding of the metamorphic cycle. Our pre-peak metamorphic zircon ages, peak metamorphic garnet ages and peak to late peak metamorphic amphibole ³⁹Ar–⁴⁰Ar ages bracket the upper amphibolite facies metamorphic event including hydration or dehydration processes into a time span of only ca. 20 Ma. The age data obtained by peak metamorphic mineral analyses cluster around 1340–1320 Ma. Based on age data and field observation, we interpret the upper amphibolite facies metamorphism as a large-scale regional mid-crustal event. Spot analyses of inherited zircon cores obtained by SHRIMP reflect the sedimentary origin of the respective rocks of the Orue Unit and derivation from Palaeoproterozoic protoliths. The metamorphic rocks south of the anorthositic Kunene Intrusive Complex (KIC) have previously been ascribed to the Palaeoproterozoic Epupa Complex at the SW margin of the Congo craton and were thus thought to be older than the Mesoproterozoic KIC. Our data show that the high-grade metamorphic overprint took place 30–50 Ma after emplacement of the KIC. Rutile growth ages of 1248 Ma in one sample reflect fluid activity which seems to be a local phenomenon since there is no other evidence of geological activity throughout the Orue Unit at that time. The rutile ages predate the emplacement of satellite intrusions in that area by 30 Ma and there is no causal relation between these two events.