Evidence of shock‐induced vaporization of matrix to form porosity in Baszkówka,a porous L5 chondrite

Baszkówka is an equilibrated, apparently low‐shock, unusually porous chondrite. Some earlier studies were undertaken to understand whether the porosity in Baszkówka, and similar porous chondrites, is a relic of a primordial feature or rather the effect of atypical reprocessing on the parent body. Neither of the studies reconstructed the accurate thermal and deformational evolution of chondrites, however, while it is known that shock‐induced compaction is the main means to affect chondritic porosity. Here we use a combination of 3‐D and 2‐D petrographic examination to understand how the evolution of pores correlates with thermal and shock history recorded in the Baszkówka chondrite. The grain framework silicates in Baszkówka contain healed shock fractures—a clear recorder of significant shock process and postshock annealing. Simultaneously, metal grains do not exhibit any preferred orientation or fabric, which would be expected to develop in response to the deformation as recorded by silicates. We interpret this as evidence for re‐agglomeration and annealing of shocked material. Pore spaces in Baszkówka are connected and decorated by fine‐grained plagioclase‐dominated mass and bulky euhedral olivine crystals, which exhibit growth steps on crystal surfaces. The euhedral olivine must have formed owing to the condensation of a vapor, while plagioclase most likely crystallized from melted chondritic matrix. During the shock event, fine‐grained matrix in Baszkówka was melted and vaporized. Vapor expansion added to ballistic velocity led to ejection and opening of the pore spaces. After re‐agglomeration in a hot ejecta blanket the rock was annealed, melted material circulated in created pore spaces and vapor condensed.     

Incompletely compacted equilibrated ordinary chondrites

Abstract— We document the size distributions and locations of voids present within five highly porous equilibrated ordinary chondrites using high‐resolution synchrotron X‐ray microtomography (μCT) and helium pycnometry. We found total porosities ranging from ～10 to 20% within these chondrites, and with μCT we show that up to 64% of the void space is located within intergranular voids within the rock. Given the low (S1‐S2) shock stages of the samples and the large voids between mineral grains, we conclude that these samples experienced unusually low amounts of compaction and shock loading throughout their entire post accretionary history. With Fe metal and FeS metal abundances and grain size distributions, we show that these chondrites formed naturally with greater than average porosities prior to parent body metamorphism. These materials were not “fluffed” on their parent body by impact‐related regolith gardening or events caused by seismic vibrations. Samples of all three chemical types of ordinary chondrites (LL, L, H) are represented in this study and we conclude that incomplete compaction is common within the asteroid belt.     

Petrology of the Baszkówka L5 chondrite: A record of surface‐forming processes on the parent body

Abstract— We review the petrology of Baszkówka, present new microprobe data on mineral constituents, and propose a model for surface properties of the parent body consistent with these data. The low shock index and high porosity of the Baszkówka L5 chondrite mean that considerable primary textural and petrographic detail is preserved, allowing insight into the structure and evolution of the parent body. This meteorite formed in a sedimentary environment resembling that in which pyroclastic rocks are deposited. The origin of the component chondrules, achondritic fragments (mostly olivine and pyroxene aggregates), chondritic‐achondritic aggregates, and compound chondrules can be explained by invoking collision of 2 melted or partially melted planetesimals, each covered with a thin crust. This could have happened at an early stage in the evolution of the solar system, between 1 and 2 Myr after its origin. The collision resulted in the formation of a cloud containing products of earlier magmatic crystallization (chondrite and achondrite fragments) from which new chondrules were created. Particle collision in this cloud produced fragmented chondrules, chondritic‐achondritic aggregates, and compound chondrules. Within this low‐density medium, these particles were accreted on the surface of the larger of the planetesimals involved in the collision. The density of the medium was low enough to prevent grain‐size sorting of the components but high enough to prevent the total loss of heat and to enable the welding of fragments on the surface of the body. The rock material was homogenized within the cloud and, in particular, within the zone close to the planetesimal surface. The hot material settled on the surface and became welded as molten or plastic metal, and sulfide components cemented the grains together. The process resembled the formation of welded ignimbrites. Once these processes on the planetesimal surface were completed, no subsequent recrystallization occurred. The high porosity of the Baszkówka chondrite indicates that the meteorite comes from a near‐surface part of the parent body. Deeper parts of the planetesimal would have been more massive because of compaction.     

The size and shape of local voids

We study the size and shape of low-density regions in the local Universe, which we identify in the smoothed density field of the PSCz flux-limited IRAS galaxy catalogue. After quantifying the systematic biases that enter the detection of voids using our data set and method, we identify, using a smoothing length of 5  h ⁻¹ Mpc, 14 voids within 80  h ⁻¹ Mpc (having volumes 10³  h ⁻³ Mpc³) and, using a smoothing length of 10  h ⁻¹ Mpc, eight voids within 130  h ⁻¹ Mpc (having volumes  8×10³ h⁻³ Mpc³)  . We study the void size distribution and morphologies and find that there is roughly an equal number of prolate and oblate-like spheroidal voids. We compare the measured PSCz void shape and size distributions with those expected in six different cold dark matter (CDM) models and find that only the size distribution can discriminate between models. The models preferred by the PSCz data are those with intermediate values of   σ ₈(≃0.83)  , independent of cosmology.     

The porosities of ordinary chondrites: Models and interpretation

Abstract— Densities and porosities for 285 ordinary chondrites have been assembled and analyzed. Measured chondrite porosities are bimodal; finds have an average porosity of <3%, whereas fall porosities average 7% but range from zero to >30%. We conclude that mild degrees of weathering fill pore spaces, lowering grain densities and porosities without significantly changing the bulk size or mass of the sample. By assuming an original pristine grain density (as a function of the meteorite's mineralogy—determined by its class), we can derive model pristine porosities. These model porosities cluster around an average value of 10% for all classes of ordinary chondrites. Ordinary chondrites do not show any correlation of porosity (model or measured) with petrographic grade or sample size (over a range from 0.2 g to 2 kg). However, we do see a correlation between shock state and porosity. Shock-blackened meteorites are less porous than other meteorites. Furthermore, less severely shocked meteorites show a much broader range of porosities, with the maximum porosity seen among meteorites of a given shock class falling linearly as a function of that shock class. This is consistent with the idea that shock compresses and closes pore space. Analysis of meteorite porosity provides a lower bound to the fine-scale porosity of asteroids. Our densities, even with 10% primordial porosity, are significantly higher than inferred densities of possible asteroid parent bodies. These asteroids are probably loose piles of rubble.     

Ancient porosity preserved in ordinary chondrites: Examining shock and compaction on young asteroids

We use a combination of 2D and 3D petrographic examination and ⁴⁰Ar‐³⁹Ar analyses to examine the impact histories of a suite of seven ordinary chondrites (Baszkówka, Miller, NWA 2380, Mount Tazerzait, Sahara 98034, Tjerebon, and MIL 99301) that partially preserve their ancient, but postaccretionary, porosity ranging from 10 to 20%. We examine whether materials that seem to be only mildly processed (as their large intergranular pore spaces suggest) may have more complex shock histories. The ages determined for most of the seven OCs studied here indicate closure of the ⁴⁰Ar‐³⁹Ar system after primary accretion, but during (Baszkówka) or shortly after (others) thermal metamorphism, with little subsequent heating. Exceptions include Sahara 98034 and MIL 99301, which were heated to some degree at later stages, but retain some evidence for the timing of thermal metamorphism in the ⁴⁰Ar‐³⁹Ar system. Although each of these chondrites has olivine grains with sharp optical extinction (signaling an apparent shock stage of S1), normally indicative of an extremely mild impact history, all of the samples contain relict shock indicators. Given the high porosity and relatively low degree of compaction coupled with signs of shock and thermal annealing, it seems plausible that impacts into materials that were already hot may have produced the relict shock indicators. Initial heating could have resulted from prior collisions, the decay of ²⁶Al, or both processes.     

Catastrophic fragmentation of asteroids: evidence from meteorites

Meteorites are impact-derived fragments from ≈ 85 parent bodies. For seven of these bodies, the meteorites record evidence suggesting that they may have been catastrophically fragmented. We identify three types of catastrophic events: (a) impact and reassembly events > 4.4 Gy ago, involving molten or very hot parent bodies(> 1200°C); this affected the parent bodies of the ureilites, Shallowater, and the mesosiderites. In each case, the fragments cooled rapidly (≈ 1–1000°C day⁻¹) and then reassembled, (b) Later impacts involving cold bodies which, in some cases, reassembled; this occurred on the H and L ordinary chondrite parent bodies. The L parent body probably suffered another catastrophic event about 500 My ago. (c) Recent impacts of cold, multi-kilometer-sized bodies that generated meter-sized meteoroids; this occurred on the parent bodies of the IIIAB irons (650 My ago), the IVA irons (400 My ago), and the H ordinary chondrite (7 My ago).     

Origin and history of chondrite regolith,fragmental and impact-melt breccias from Spain

Abstract— Six ordinary chondrite breccias from the Museo Nacional de Ciencias Naturales, Madrid (Spain), are described and classified as follows: the solar gas-rich regolith breccia Oviedo (H5); the pre-metamorphic fragmental breccias Cabezo de Mayo (type 6, L-LL), and Sevilla (LL4); the fragmental breccias Cañellas (H4) and Gerona (H5); and the impact melt breccia, Madrid (L6). We confirm that chondrites with typical light-dark structures and petrographic properties typical of regolith breccias may (Oviedo) or may not (Cañellas) be solar gas-rich. Cabezo de Mayo and Sevilla show convincing evidence that they were assembled prior to peak metamorphism and were equilibrated during subsequent reheating. These meteorites contain small melt rock clasts that were incorporated into the host chondrite while still molten and/or plastic and cooled rapidly and, yet, are totally equilibrated with their hosts. Compositions of olivine and low-Ca pyroxene in host chondrite and breccia clasts in Cabezo de Mayo are transitional between groups L and LL. It is suggested, based on mineralogic and oxygen isotopic compositions of host and clasts, that the rock formed on the L parent body by mixing, prior to peak metamorphism. This was followed by partial equilibration of two different materials: the indigenous L chondrite host and exotic LL melt rock clasts.     

An Estimate of Eros's Porosity and Implications for Internal Structure

Earth-based spectral measurements and NEAR Shoemaker magnetometer, X-ray, and near-infrared spectrometer data are all consistent with Eros having a bulk composition and mineralogy similar to ordinary chondrite meteorites (OC). By comparing the bulk density of 433 Eros (2.67±0.03 g/cm³) with that of OCs (3.40 g/cm³), we estimate the total porosity of the asteroid to be 21-33%. Macro (or structural) porosity, best estimated to be ∼20%, is constrained to be between 6 and 33%. We conclude that Eros is a heavily fractured body, but we find no evidence that it was ever catastrophically disrupted and reaccumulated into a rubble pile.     

The Greenwell Springs LL4 Chondrite: A New Fall from Louisiana,USA

Abstract— A 664 gm stone fell into suburban Baton Rouge in November 1987. The stone has a nearly complete fusion crust and was undamaged upon impact. The ordinary chondrite contains equilibrated olivine, Fa₂₈, and largely equilibrated bronzite, Fs₂₃. Some bronzite is still compositionally zoned and polysynthetically twinned, thus requiring petrologic classification of the meteorite as a type 4. A major element analysis of the meteorite falls exclusively into the field for the LL compositional group.     

Revised model calculations for the thermal histories of ordinary chondrite parent bodies

Abstract— Recent measurements of ordinary chondrite physical and thermal properties along with new geothermometry studies have provided the necessary parameters for updating a previously proposed model (Miyamoto et al., 1981) for the thermal evolution and internal structure of ordinary chondrite parent bodies. Model calculations assumed a heat source term derived from the decay of ²⁶Al (justification is provided). Differences from the previous model include: varying the thermal diffusivity parameter with increasing temperature (and decreasing porosity), using variable physical and thermal parameters to provide end member models, and incorporating a shortened thermal history of 60 Ma (obtained from new Pb-Pb chronology of phosphates) rather than 100 Ma. Times of isotopic closure in chondrite phosphates overlap the thermal model estimates, and postmetamorphic cooling rates from the model approximately coincide, in both trend and magnitude, with metallographic and fission track cooling rate data. Model calculations attempt to match peak metamorphic conditions in the central portions of these bodies and yield accretion ages between 1.4 to 3.1 Ma after calcium-aluminum inclusion (CAI) formation. Model calculations also predict that both the H and the L chondrite parent asteroids consisted of ～80% equilibrated and 20% unequilibrated chondritic material and that their original radii ranged from 80 to 95 km.     

Chondritic micrometeorites from the Transantarctic Mountains

Abstract– On the basis of morphological and petrographic characteristics, eight “giant” unmelted micrometeorites in the 300–1100 μm size range were selected from the Transantarctic Mountain micrometeorite collection, Victoria Land, Antarctica. Mineralogical and geochemical data obtained by means of scanning electron microscopy, electron probe microanalyses, and synchrotron X‐ray diffraction allow their classification as chondritic micrometeorites. The large size of the micrometeorites increases considerably the amount of mineralogical and geochemical information compared to micrometeorites in smaller size fractions, therefore allowing a better definition of their parent material. A large variety of material is observed: five micrometeorites are related to unequilibrated and equilibrated ordinary chondrite, one to CV chondrite, one to CM chondrite, and one to CI chondrite parent materials. Besides reporting the first occurrence of a CV‐like micrometeorite, our study shows that the abundance of chondritic material supports observations from recent studies on cosmic spherules that a large part of the micrometeorite flux in this size range is of asteroidal origin.     

The porosity and permeability of chondritic meteorites and interplanetary dust particles

Abstract— We have investigated the porosity of a large number of chondritic interplanetary dust particles (IDPs) and meteorites by three techniques: standard liquid/gas flow techniques, a new, noninvasive ultrasonic technique, and image processing of backscattered images. The latter technique is obviously best-suited to sub-kilogram sized samples. We have also measured the gas and liquid permeabilities of some chondrites by two techniques: standard liquid/gas flow techniques, and a new, nondestructive pressure release technique. We find that chondritic IDPs have a somewhat bimodal porosity distribution. Peaks are present at 0 and 4% porosity; a tail then extends to 53%. Type 1–3 chondrite matrix porosities range up to 30%, with a peak at 2%. The bulk porosities for type 1–3 chondrites have the same approximate range as exhibited by the matrix, which indicates that other components of the bulk meteorites (including chondrules and aggregates) have the same average porosity as the matrix. These results reveal that the porosities of primitive materials at scales ranging from nanogram to kilogram are similar, which implies that similar accretion dynamics operated through 12 orders of size magnitude. Permeabilities of the investigated chondrites vary by several orders of magnitude, and there appears to be no simple dependence of permeability with degree of aqueous alteration, chondrite type or porosity.     

Meteorites from the Nullarbor Region,Western Australia: II. Recovery and classification of 34 new meteorite finds from the Mundrabilla,Forrest, Reid and Deakin areas

Abstract— The discovery of 34 new stony meteorites is reported from those areas of the Nullarbor Region, Western Australia named after Mundrabilla, Forrest, Reid and Deakin sidings on the Trans Australian Railway line. The recoveries include 15 H-, and 15 L-group equilibrated (types 4–6) ordinary chondrites, two distinct H3 chondrites (Mundrabilla 003 and Forrest 003), a genomict H-group chondrite breccia (Reid 011) comprising types 3–6, and one structurally anomalous chondrite (Deakin 001). Seventy-eight distinct meteorites are now known from the region.     

Phosphate control on the thorium/uranium variations in ordinary chondrites: Improving solar system abundances

Abstract— Isotope dilution thorium and uranium analyses by inductively‐coupled plasma mass spectrometry of 12 samples of Harleton (L6) show a much larger scatter than was previously observed in equilibrated ordinary chondrites. Th/U linearly correlates with 1/U in Harleton and in the total equilibrated ordinary chondrite data set as well. Such a correlation suggests a two component mixture and this trend can be quantitatively modeled as reflecting variations in the mixing ratio between two phosphate phases: chlorapatite and merrillite. The major effect is due to apatite variations, which strongly control the whole rock U concentrations. Phosphorous variations will tend to destroy the Th/U vs. 1/U correlation, and measured P concentrations on exactly the same samples as U and Th show a factor of 3 range. It appears that the P variations are compensated by inverse variations in U (a dilution effect) to preserve the Th/U vs. 1/U correlation. Because variations in whole rock Th/U are consequences of phosphate sampling, a weighted average of high accuracy Th/U measurements in equilibrated ordinary chondrites should converge to a significantly improved average solar system Th/U. Our best estimate of this ratio is 3.53 with σ_mean = 0.10.     

Mineralogical interpretation of reflectance spectra of Eros from NEAR near‐infrared spectrometer low phase flyby

Abstract— High signal‐to‐noise near‐infrared spectrometer (NIS) spectra acquired during the low phase flyby of the near‐Earth asteroid rendezvous (NEAR) mission to 433 Eros are analyzed to determine mineral chemistry and proportions of mafic silicates across the asteroid's surface at 2.68 × 5.50 km spatial resolution. Spectral band parameters are derived, and compared with those of laboratory samples of known mineral composition, grain size distribution and terrestrial, meteoritic and lunar pyroxene spectral properties. The NIS derived band parameters are consistent with ordinary chondrite meteorites. We invoke the presence of a clinopyroxene component in the spectra, which is consistent with ordinary chondrite mineralogy and/or some degree of partial melting of ordinary chondritic material. Spectra measured across the surface of Eros can reveal small but real spectral variations. Most relative spectra are uniform to within 1–2%. Some areas suggest compositional variations of a few percent. Spectral slope variations of a few percent are seen indicating a non‐uniform distribution of materials affecting the slope parameter but with no resolved absorption bands. We find no correlation of slope with viewing geometry or compositional variation. The band parameter values do not consistently indicate a specific ordinary chondrite class but Eros is definitely undifferentiated with possible compositional variations of no more than 1–2%.     

Petrogenesis of Miller Range 07273, a new type of anomalous melt breccia: Implications for impact effects on the H chondrite asteroid

Miller Range 07273 is a chondritic melt breccia that contains clasts of equilibrated ordinary chondrite set in a fine‐grained (<5 μm), largely crystalline, igneous matrix. Data indicate that MIL was derived from the H chondrite parent asteroid, although it has an oxygen isotope composition that approaches but falls outside of the established H group. MIL also is distinctive in having low porosity, cone‐like shapes for coarse metal grains, unusual internal textures and compositions for coarse metal, a matrix composed chiefly of clinoenstatite and omphacitic pigeonite, and troilite veining most common in coarse olivine and orthopyroxene. These features can be explained by a model involving impact into a porous target that produced brief but intense heating at high pressure, a sudden pressure drop, and a slower drop in temperature. Olivine and orthopyroxene in chondrule clasts were the least melted and the most deformed, whereas matrix and troilite melted completely and crystallized to nearly strain‐free minerals. Coarse metal was largely but incompletely liquefied, and matrix silicates formed by the breakdown during melting of albitic feldspar and some olivine to form pyroxene at high pressure (>3 GPa, possibly to ~15–19 GPa) and temperature (>1350 °C, possibly to ≥2000 °C). The higher pressures and temperatures would have involved back‐reaction of high‐pressure polymorphs to pyroxene and olivine upon cooling. Silicates outside of melt matrix have compositions that were relatively unchanged owing to brief heating duration.     

Three‐dimensional microstructure of samples recovered from asteroid 25143 Itokawa: Comparison with LL5 and LL6 chondrite particles

In this study, the three‐dimensional (3‐D) microstructure of 48 Itokawa regolith particles was examined by synchrotron microtomography at SPring‐8 during the preliminary examination of Hayabusa samples. Moreover, the 3‐D microstructure of particles collected from two LL6 chondrites (Ensisheim and Kilabo meteorites) and an LL5 chondrite (Tuxtuac meteorite) was investigated by the same method for comparison. The modal abundances of minerals, especially olivine, bulk density, porosity, and grain size are similar in all samples, including voids and cracks. These results show that the Itokawa particles, which are surface materials from the S‐type asteroid Itokawa, are consistent with the LL chondrite materials in terms of not only elemental and isotopic composition of the minerals but also 3‐D microstructure. However, we could not determine whether the Itokawa particles are purely LL5, LL6, or a mixture of the two. No difference between the particles collected from Rooms A and B of the sample chamber, corresponding to the sampling sequence of the spacecraft's second and first touchdowns, respectively, was detected because of the statistically small amount of particles from Room B.     

The MEMIN research unit: Scaling impact cratering experiments in porous sandstones

Abstract– The MEMIN research unit (Multidisciplinary Experimental and Modeling Impact research Network) is focused on analyzing experimental impact craters and experimental cratering processes in geological materials. MEMIN is interested in understanding how porosity and pore space saturation influence the cratering process. Here, we present results of a series of impact experiments into porous wet and dry sandstone targets. Steel, iron meteorite, and aluminum projectiles ranging in size from 2.5 to 12 mm were accelerated to velocities of 2.5–7.8 km s^?1, yielding craters with diameters between 3.9 and 40 cm. Results show that the target’s porosity reduces crater volumes and cratering efficiency relative to nonporous rocks. Saturation of pore space with water to 50% and 90% increasingly counteracts the effects of porosity, leading to larger but flatter craters. Spallation becomes more dominant in larger‐scale experiments and leads to an increase in cratering efficiency with increasing projectile size for constant impact velocities. The volume of spalled material is estimated using parabolic fits to the crater morphology, yielding approximations of the transient crater volume. For impacts at the same velocity these transient craters show a constant cratering efficiency that is not affected by projectile size.     

GOBABEB,A NEW CHONDRITE: THE COEXISTENCE OF EQUILIBRATED SILICATES AND UNEQUILIBRATED SPINELS

Gobabeb, an ordinary chondrite, was found near Gobabeb, South West Africa in 1969. Chemically and petrographically it belongs in the H4 group. But, in addition to almost homogeneous silicates and chromites, it contains rare, non-opaque spinels that vary greatly in composition from grain to grain. A similar association in an “almost equilibrated” portion of the Mezö-Madaras chondrite has been interpreted as evidence against the hypothesized metamorphic homogenization of ordinary chondrites. A comparison of the chromites and variable spinels from Mezö-Madaras and Gobabeb suggests, instead, that cation exchange is simply slower in the variable spinels than in the chromites. Based on the evidence to date, the survival of these highly variable spinels is not incompatible with a metamorphic episode for both these meteorites.