大气微量气体人为扰动的气候效应

众所周知,微量气体的存在能影响大气的热力结构。微量气体的主要作用是调节太阳辐射和热发射。太阳辐射的主要气体吸收介质是对流层的水汽(H_2O)和平流层的臭氧(O_3)。水汽吸收主要是在近红外谱区,而O_3的有效区是在紫外和可见光区(图1)。     

Parameterization of the Absorption of the H2O Continuum, CO2, O2, and Other Trace Gases in the Fu-Liou Solar Radiation Program

The absorption properties of the water vapor continuum and a number of weak bands for H2O, O2, CO2, CO, N2O, CH4, and O3 in the solar spectrum are incorporated into the Fu-Liou radiation parameterization program by using the correlated k-distribution method (CKD) for the sorting of absorption lines. The overlap absorption of the H2O lines and the H2O continuum (2500-14500 cm^-1) are treated by taking the two gases as a single-mixture gas in transmittance calculations. Furthermore, in order to optimize the computation efforts, CO2 and CH4 in the spectral region 2850-5250 cm^-1 are taken as a new singlemixture gas as well. For overlap involving other absorption lines in the Fu-Liou spectral bands, the authors adopt the multiplication rule for transmittance computations under which the absorption spectra for two gases are assumed to be uncorrelated. Compared to the line-by-line (LBL) computation, it is shown that the errors in fluxes introduced by these two approaches within the context of the CKD method are small and less than 0.48% for the H20 line and continuum in the 2500-14500 cm^-1 solar spectral region, -1% for H2O (line) H2O (continuum) CO2 CH4 in the spectral region 2850-5250 cm^-1, and -1.5% for H2O (line) H2O (continuum) O2 in the 7700-14500 cm^-1 spectral region. Analysis also demonstrates that the multiplication rule over a spectral interval as wide as 6800 cm^-1 can produce acceptable errors with a maximum percentage value of about 2% in reference to the LBL calculation. Addition of the preceding gases increases the absorption of solar radiation under all sky conditions. For clear sky, the increase in instantaneous solar absorption is about 9%-13% (-12 W m^-2) among which the H20 continuum produces the largest increase, while the contributions from O2 and CO2 rank second and third, respectively. In cloudy sky, the addition of absorption amounts to about 6-9 W m^-2. The new, improved program with the incorporation of the preceding gases produces a smaller solar absorption in clouds due to the reduced solar flux reaching the cloud top.     

Managing atmospheric CO2

A coupled carbon cycle-climate model is used to compute global atmospheric CO₂ and temperature variation that would result from several future CO₂ emission scenarios. The model includes temperature and CO₂ feedbacks on the terrestrial biosphere, and temperature feedback on the oceanic uptake of CO₂. The scenarios used include cases in which fossil fuel CO₂ emissions are held constant at the 1986 value or increase by 1% yr^–1 until either 2000 or 2020, followed by a gradual transition to a rate of decrease of 1 or 2% yr^–1. The climatic effect of increases in non-CO₂ trace gases is included, and scenarios are considered in which these gases increase until 2075 or are stabilized once CO₂ emission reductions begin. Low and high deforestation scenarios are also considered. In all cases, results are computed for equilibrium climatic sensitivities to CO₂ doubling of 2.0 and 4.0 °C.Peak atmospheric CO₂ concentrations of 400–500 ppmv and global mean warming after 1980 of 0.6–3.2 °C occur, with maximum rates of global mean warming of 0.2–0.3 °C decade^–1. The peak CO₂ concentrations in these scenarios are significantly below that commonly regarded as unavoidable; further sensitivity analyses suggest that limiting atmospheric CO₂ to as little as 400 ppmv is a credible option.Two factors in the model are important in limiting atmospheric CO₂: (1) the airborne fraction falls rapidly once emissions begin to decrease, so that total emissions (fossil fuel + land use-induced) need initially fall to only about half their present value in order to stabilize atmospheric CO₂, and (2) changes in rates of deforestation have an immediate and proportional effect on gross emissions from the biosphere, whereas the CO₂ sink due to regrowth of forests responds more slowly, so that decreases in the rate of deforestation have a disproportionately large effect on net emission.If fossil fuel emissions were to decrease at 1–2% yr^–1 beginning early in the next century, emissions could decrease to the rate of CO₂ uptake by the predominantly oceanic sink within 50–100 yrs. Simulation results suggest that if subsequent emission reductions were tied to the rate of CO₂ uptake by natural CO₂ sinks, these reductions could proceed more slowly than initially while preventing further CO₂ increases, since the natural CO₂ sink strength decreases on time scales of one to several centuries. The model used here does not account for the possible effect on atmospheric CO₂ concentration of possible changes in oceanic circulation. Based on past rates of atmospheric CO₂ variation determined from polar ice cores, it appears that the largest plausible perturbation in ocean-air CO₂ flux due to changes of oceanic circulation is substantially smaller than the permitted fossil fuel CO₂ emissions under the above strategy, so tieing fossil fuel emissions to the total sink strength could provide adequate flexibility for responding to unexpected changes in oceanic CO₂ uptake caused by climatic warming-induced changes of oceanic circulation.     

A numerical method for determining the dry deposition of atmospheric trace gases

A diagnostic deposition model based on generally accepted micrometeorological ideas on the transfer of momentum, sensible heat and matter near the Earth's surface is presented. The parameterization of fluxes is based on the flux-gradient relationships in the turbulent region of the surface layer and the sublayer Stanton number as well as the Reynolds analogy between concentration, temperature and wind velocity distributions in the underlying sublayer. The model requires only vertical profile data of wind velocity, dry- and wet-bulb temperatures and trace gas concentrations from the turbulent part of the surface layer.The method has been applied to vertical profile data collected in field experiments such as the GREIV I 1974 project and the Great Plains Turbulence Project. In order to illustrate the way in which the model can be used to evaluate deposition fluxes and velocities of reactive trace gases, it has been applied to observed concentrations of NO, NO₂ and ozone.Presented at the Symposium on Environmental Meteorology, Würzburg, FRG, September 29 to October 1, 1987.     

Siberian CO2 efflux in winter as a CO2 source and cause of seasonality in atmospheric CO2

Over three years, we found a consistent CO₂ efflux from forest tundra of the Russian North throughout the year, including a large (89 g C m^–2 yr^–1) efflux during winter. Our results provide one explanation for the observations that the highest atmospheric CO₂ concentration and greatest seasonal amplitude occur at high latitudes rather than over the mid-latitudes, where fossil fuel sources are large, and where high summer productivity offset by winter respiration should give large seasonal oscillations in atmospheric CO₂. Winter respiration probably contributed substantially to the boreal winter CO₂ efflux. Respiration is an exothermic process that produces enough heat to warm soils and promote further decomposition. We suggest that, as a result of this positive feedback, small changes in surface heat flux, associated with human activities in the North or with regional or global warming, could release large quantities of organic carbon that are presently stored in permafrost.     

Interannual variation of atmospheric CO2 concentration

A method is described for the analysis of the interannual variability of background atmospheric carbon dioxide concentration. The analysis is carried out on the data from 6 observatories for which records of >8 years were available.A global-scale interannual variation of CO₂ concentration in the troposphere with a characteristic time-scale of 2–3 years has been confirmed throughout the period of the records. These variations are estimated to be associated with carbon cycle imbalances of 2–3 Gt or annual net exchanges between the atmosphere and another carbon reservoir(s) at a rate of about 1.2 Gt of carbon per year. Lag correlations and amplitude comparisons between the records suggests a low latitude southern hemisphere origin to this phenomenon.The interannual variations of CO₂ increase are found to be correlated with those observed in data for Pacific sea surface temperatures and Pacific witd stress, the Southern Oscillation Index and the Quasi-Biennial Oscillation. However multiple regression studies found that once the Southern Oscillation index is used as an explanatory variable for CO₂ variations, the inclusion of additional geophysical variables does not give any significant improvement in the regression.     

Spatial gradients in ratios of atmospheric trace gases: a study stimulated by experiments on bird navigation

Numerous experiments with homing pigeons and other birds strongly suggest that birds displaced to unfamiliar remote areas are able to determine their position relative to home by deducing relevant information from atmospheric trace gases perceived by olfaction. These findings induced the hypothesis that ratios between several airborne compounds show roughly monotonic spatial gradients, differently in different directions, over distances of some hundreds of kilometres. To test this hypothesis, 192 air samples were collected, successively in 3 summers, at 96 sites regularly distributed over an area covering a radius of 200 km around Würzburg, Germany. Statistical analysis of the gas chromatographic measurements on these samples revealed that such gradients in the ratios between a number of omnipresent hydrocarbons do in fact exist. The gradients are noisy, but not beyond the range that is compatible with the homing behaviour of pigeons which is noisy as well. The directions of the gradients are remarkably robust against changes of weather, especially of winds. Winds, however, shift the levels of ratios in the whole area without dramatically changing the directional relationships. A systematic angular correlation between variations in space and variations caused by winds could theoretically be utilized by birds for navigational purposes. Our analysis dealt mainly with the most abundant anthropogenic hydrocarbons, which are the best‐suited tracers to detect spatio‐temporal distribution patterns. It is very likely that equivalent patterns exist in naturally emitted volatile compounds as well, given that they are subject to similar variability in the distribution of sources and sinks and similar transport patterns.     

景德镇地区大气CO2浓度变化特征

利用景德镇温室气体监测站CO_2观测数据,分析了景德镇地区2017年12月—2018年11月大气CO_2浓度变化特征,同时对其浓度进行了筛分,以剔除污染数据,使其更具区域代表性。研究表明:景德镇地区大气CO_2浓度昼降夜升,早上最高,傍晚最低;春季最高,秋季最低;春、夏季NNE、NE、ENE风向,秋季NE、ENE风向以及冬季W、WSW、SW、SSW、S风向上CO_2浓度较高。同时,春、夏和秋季大气CO_2浓度大致随风速的增加而不断降低,冬季风速对大气CO_2浓度无明显影响。筛分后数据显示景德镇地区年均大气CO_2浓度为422.1×10~(-6),浓度日均值年振幅73.96×10~(-6),夏半年CO_2浓度低于冬半年。     

The dynamic greenhouse: Feedback processes that may influence future concentrations of atmospheric trace gases and climatic change

The sensitivity of the climate system to anthropogenic perturbations over the next century will be determined by a combination of feedbacks that amplify or damp the direct radiative effects of increasing concentrations of greenhouse gases. A number of important geophysical climate feedbacks, such as changes in water vapor, clouds, and sea ice albedo, are included in current climate models, but biogeochemical feedbacks such as changes in methane emissions, ocean CO₂ uptake, and vegetation albedo are generally neglected. The relative importance of a wide range of feedbacks is assessed here by estimating the gain associated with each individual process. The gain from biogeochemical feedbacks is estimated to be 0.05–0.29 compared to 0.17–0.77 for geophysical climate feedbacks. The potentially most significant biogeochemical feedbacks are probably release of methane hydrates, changes in ocean chemistry, biology, and circulation, and changes in the albedo of the global vegetation. While each of these feedbacks is modest compared to the water vapor feedback, the biogeochemical feedbacks in combination have the potential to substantially increase the climate change associated with any given initial forcing.The views expressed are the author's: They do not express official views of the U.S. Government or the Environmental Protection Agency.     

大气中微量气体增加对气候及环境的影响——Villach 国际会议对CO2问题的评价

文章综述了国际Villach会议关于CO_2问题的评价及主要结论,展望了今后CO_2问题的研究重点。     

Tunable diode laser measurements of trace gases during the 1988 Polarstern cruise and intercomparisons with other methods

Measurements of NO₂, HCHO, and H₂O₂ were made by the highly specific method of mid infra-red absorption spectroscopy using tunable diode lasers (TDLAS) during the 1988 Polarstern expedition. The TDLAS data are compared to those obtained during the cruise using less direct methods. Southern Hemisphere NO₂ levels suggest nett photochemical destruction of O₃ in the boundary layer. Northern Hemisphere HCHO averaged 0.47±0.2 ppbv; the HCHO measurements are used in a simple calculation to estimate OH noontime maxima of 3–6×10⁶ cm^-3.     

Ecological consequences of atmospheric and climate change

The ecological outcome of atmospheric and climate change will depend on the rate of such change relative to the rate at which the biota can respond. Change in community structure and composition, and in landscapes and soils, will mostly come about through changes in the frequencies of extreme events. Much of the Southern Hemisphere has incomplete vegetative cover and landscape dynamics (horizontal redistribution of water and nutrients) is a primary ecological determinant which will be significantly altered under a shifting rainfall regime. Predicting vegetation change requires resolving the problems of lag effects, extreme events, the direct effects of increased CO₂, secondary effects (e.g. changed fire regimes) and interactive effects of spatial variation. Some Southern Hemisphere examples are presented. Changes in fauna will depend mostly on changes to habitat. In the case of many invertebrate pest species, however, including disease vectors, an increase in minimum temperatures will have significant effects on their distribution and abundance (e.g. locusts, screw-worm fly, the cotton pest Heliothus, tsetse fly, malaria).     

A robust sequential CO2 emissions strategy based on optimal control of atmospheric CO2 concentrations

This paper formally introduces the concept of mitigation as a stochastic control problem. This is illustrated by applying a digital state variable feedback control approach known as Non-Minimum State Space (NMSS) control to the problem of specifying carbon emissions to control atmospheric CO₂ concentrations in the presence of uncertainty. It is shown that the control approach naturally lends itself to integrating both anticipatory and reflexive mitigation strategies within a single unified framework. The framework explicitly considers the closed-loop nature of climate mitigation, and employs a policy orientated optimisation procedure to specify the properties of this closed-loop system. The product of this exercise is a control law that is suitably conditioned to regulate atmospheric CO₂ concentrations through assimilating online information within a 25-year review cycle framework. It is shown that the optimal control law is also robust when faced with significant levels of uncertainty about the functioning of the global carbon cycle.     

The impact of doubled CO2 on the energetics and hydrologic processes of mid-latitude transient eddies

The Northern Hemisphere winter (DJF) stationary eddy response of a general circulation model (GCM) to a doubling of atmospheric CO₂ is simulated with a linear steady state model as a response to anomalies in diabatic heating (latent, sensible and radiative), mountain and transient eddy effects. For this analysis the doubled CO₂ experiment performed by Wilson and Mitchell (1987) is used. The linear simulations of the control and perturbation climate capture most of the important features of the GCMs stationary eddies. The simulation of the anomalous stationary eddy pattern in the Northern Hemisphere captures only some of the important features of the GCMs anomalies. The climate anomalies in the Southern Hemisphere are poorly simulated. In the Northern Hemisphere the climate anomalies are dominated by the effect of transient eddies and mountains. In low latitudes also the contribution of latent heating is important. The contributions of sensible and radiative heating are small.     

Equilibrium and transient climatic warming induced by increased atmospheric CO2

The change in the Earth's equilibrium global mean surface temperature induced by a doubling of the CO₂ concentration has been estimated as 0.2 to 10 K by surface energy balance models, 0.5 to 4.2 K by radiative-convective models, and 1.3 to 4.2 K by general circulation models. These wide ranges are interpreted and quantified here in terms of the direct radiative, forcing of the increased CO₂, the response of the climate system in the absence of feedback processes, and the feedbacks of the climate system. It is the range in the values of these feedbacks that leads to the ranges in the projections of the global mean surface warming. The time required for a CO₂-induced climate change to reach equilibrium has been characterized by an e-folding time _e with values estimated by a variety of climate/ocean models as 10 to 100 years. Analytical and numerical studies show that this wide range is due to the strong dependence of _e on the equilibrium sensitivity of the climate model and on the effective vertical thermal diffusivity of the ocean model. A coupled atmosphere-ocean general circulation model simulation for doubled CO₂ suggestes that, as a result of the transport of the CO₂-induced surface heating into the interior of the ocean, _e 50 to 100 years. Theoretical studies for a realistic CO₂ increase between 1850 and 1980 indicate that this sequestering of heat into the ocean's interior is responsible for the concomittant warming being only about half that which would have occurred in the absence of the ocean. These studies also indicate that the climate sytem will continue to warm towards its as yet unrealized equilibrium temperature change, even if there is no further increase in the CO₂ concentration.