古全球变化与非等时韵律沉积及前寒武纪条带状铁矿建造形成的终止

前寒武纪各种地质记录表明了太古代－元古代早期古全球天南环境具有显著的陆少洋多和大气富ＣＯ２，盆Ｏ２的特征。ＢＩＦｓ大气－海洋系统中Ｆｅ＾２＋的氧化是铁质发生沉淀的一个重要过程，在前寒武纪早期缺Ｏ２的环境，生物－无氧氧化和日光－紫外线为主的宇宙射线光致氧化作用产生的直接非生物－无氧氧化过程，在前寒武幻早期缺Ｏ２环境对Ｆｅ＾２＋的氧化可能起着重要和主导的作用。     

外束离子感生发光法及其应用研究初探

基于外束质子激发Ｘ荧光分析（ＰｒｏｔｏｎＩｎｄｕｃｅｄＸｒａｙＥｍｉｓｓｉｏｎ———ＰＩＸＥ法）的外束离子感生发光（ＩｏｎＢｅａｍＩｎｄｕｃｅｄＬｕｍｉｎｅｓｃｅｎｃｅ，ＩＢＩＬ）实验装置，实现了ＩＢＩＬ对地质样品斜长石（钙长石）中元素铁的化学价态的直接分析。实验结果表明，Ｆｅ２＋和Ｆｅ３＋光谱峰分别位于５５３ｎｍ和６８２ｎｍ清晰分离，Ｆｅ３＋光谱峰清晰突出，Ｆｅ２＋峰也可确认     

对用Fe^3＋／Fe^2＋探讨庐山地区第四纪古温度的讨论

本文认为用Ｆｅ＾３＋／Ｆｅ＾２＋值推算庐山地区第四纪古温度是可行的，但认为在推算方法上必须严谨合理，文中论证了用Ｆｅ２Ｏ３／ＦｅＯ值代替Ｆｅ＾３＋／Ｆｅ＾２＋值推算古温度，且用少量样品的实验分析结果来划分庐山地区第四纪冰期和间冰期地层是欠妥的，其计算结果误差达０．４１－４．３５。据笔者采用容量法对庐山大校场部面１０个样品Ｆｅ＾３＋和Ｆｅ＾２＋含量的测试，发现这些样品反映的第四纪古温度值未有低达０℃     

凤太泥盆纪拉分盆地中硅质铁白云岩—硅质岩特征及成岩成矿方式

从岩石学、矿物学、地球化学等叫结秦岭凤太地区泥盆纪硅质白云岩－硅质岩的地质地球化学特征。硅质岩类中,ＳｉＯ２〉８０％,（ＦｅＯ＋Ｆｅ２Ｏ３＋ＭｇＯ）〈１０％;硅质铁白云岩类中,ＳｉＯ２为３０％～５０％,（ＦｅＯ＋ＦｅＯ３＋ＭｇＯ）大于２０％,提出该类热水沉积岩热水同生沉积作用、热水温合同生沉积作用,热水同生沉积交代作用,热水爆炸－液压致裂作用及热水充填－交代作用形成。     

浙江西裘晚元古代层状硅质岩热水沉积地球化学标志及其沉积环境意义

在浙江西裘地区晚元古界地层中存在与地层整合产出的层状硅质岩。硅质岩富Ｆｅ、Ｍｎ，相对贫Ａ１，富集Ａｓ、Ｓｂ、Ｂｉ、Ｇａ，稀土元素总量低，铈负异常，重稀土相对富集，具热水沉积硅质岩的地球化学特征。在Ａ１－Ｆｅ－Ｍｎ和Ｆｅ－Ｍｎ－（Ｎｉ＋Ｃｏ＋Ｃｕ）三角图上均属于热水沉积硅质岩。硅质岩硅、氧同位素地球化学也显示其热水成因之特点。硅质岩的ＭｎＯ／ＴｉＯ２、δＣｅ和δ３０Ｓｉ值分析表明本区层状硅质岩主要是在深海环境下沉积的。硅质岩形成温度较高，约为８２－１６５℃。     

兴神磷矿含磷岩系地球化学特征与沉积环境分析

兴神磷矿含磷岩系各类岩（矿）石Ｓｒ／Ｂａ，Ｍｎ／Ｆｅ，Ｃｏ／Ｎｉ，Ａｓ，Ｃｅ／Ｃｅ“，Ｅｕ／Ｅｌｌ刮，异常Ｃｅ，６“Ｃ，６１‘Ｏ等地球化学特点表明，含磷岩系沉积早期受冰）Ｉ淡水影响形成合锰白云岩；中期海馒规模扩大，水体加深，在半封闭的低能还原一弱氧化环境中．生物大量繁殖形成磷块岩堆积；晚期出现海退，在大气淡水影响下形成混合岩化白云岩结束整个成磷历史。     

催化动力学光度法测定痕量铁的研究

研究了在ｐＨ８．５的Ｎａ２Ｂ４Ｏ７－ＨＣｌ介质中,Ｆｅ＾３＋催化Ｈ２Ｏ２氧化茜素红褪色,建立了动力学光度法测定痕量Ｆｅ＾３＋的方法。方法检出限０．０４３μｇ／ｍｌ,线性范围０￣０．１７μｇ／ｍｌ,除Ｍｎ＾２＋、Ｃｏ＾２＋等离子外,其余共存离子基本无干扰,实测了天然水和化学试剂中痕量Ｆｅ＾３＋,结果满意。     

Gt－Opx－Cord－Qz新压力计的建立及其应用

依据反应２Ｇｔ＋３Ｑｚ＝２Ｏｐｘ＋Ｃｏｒｄ，在平衡热力学原理的基础上，建立一种新的地质压力计，该压力计的Ｍｇ、Ｆｅ各端员组分矿物相的热力学资料取之于Ｈｅｉｇｇｓｏｎ等、Ｓａｘｅｎａ和Ｅｒｉｋｓｏｎ文献等。采用新建立的地质压力计公式，对世界４个孔兹岩系或变泥质岩地区出现Ｇｔ＋Ｏｘｐ＋Ｃｏｒｄ＋Ｑｚ组合的压力进行估算，ｐＭｇ与ｐＦｅ差值较小，且与几个可靠的Ｇｉ－Ｃｏｒｄ压力计估算结果基本吻合，表明这一新的压力计具有较好的应用价值。     

铁—磺基水杨酸—2,4—二甲氧基苯基荧光酮荧光熄灭体系的研究

研究了在Ｂｒｉｊ－３５存在下，Ｆｅ＾３＋－ｄａｍｗａｄ ｉｉ ｓｎ ｓｇｃｔ－２，ｍ４     

2-[2-(5-甲基苯并噻唑)偶氮]-5-二乙氨基苯甲酸的离解平衡及其与铁的显色反应

研究了新显色剂２－［２－（５－甲基苯并噻唑）偶氮］－５－二乙氨基苯甲酸（５－Ｍｅ－ＢＴＡＥＢ）的离解平衡及与Ｆｅ２＋形成配合物的条件。在十二烷基硫酸钠的存在下,５－Ｍｅ－ＢＴＡＥＢ与Ｆｅ２＋形成稳定的蓝紫色２∶１配合物,其最大吸收波长为６４０ｎｍ,表观摩尔吸光系数为１．０３×１０５Ｌ·ｍｏｌ－１·ｃｍ－１。Ｆｅ２＋的质量浓度在０～４８０μｇ／Ｌ时服从比尔定律。方法用于部级铝合金标样中微量铁的测定,结果与推荐值相符,对ｗ（Ｆｅ）为０．１％～０．５％的样品测定１０次,ＲＳＤ在０．８５％～１．９５％,用于测定矿泉水中ｗ（Ｆｅ）／１０－６铁的测定,ＲＳＤ＜１．５％（ｎ＝７）,加标回收率９８．９％～９９．４％     

Boron in chert and Precambrian siliceous iron formations

In order to assess the importance of siliceous sediments as a sink for oceanic B and to determine the effect of diagenesis on the mobilization of B, samples were analysed from chert nodules, bedded cherts, and siliceous banded iron formations from a variety of sedimentary environments and geologic ages. Boron analyses on bulk samples were made by prompt gamma neutron activation analysis. The distribution of B in rocks was mapped using α-track methods.Nodular Phanerozoic cherts typically contain 50–150 ppm B, and bedded cherts somewhat less. The B is initially concentrated in tests of silica-secreting organisms, but some is lost in early diagenesis as silica progressively recrystallises to quartz.Banded iron formation silica of Archean and Proterozoic age usually contains < 2 ppm B. This conforms with the view that such silica is not of biogenic origin but, since many iron formations are undoubtedly of marine origin, raises the question whether Precambrian oceans were impoverished in B. Analyses of Precambrian marine argillaceous sediments, averaging 70 ppm B, do not resolve this question.     

冀东马兰庄条带状硅铁建造的变质时代及地质意义

前寒武纪条带状硅铁建造(BIF)是世界,也是中国最重要的铁矿资源类型,无论是储量,还是开采量,均居首位.前寒武纪条带状硅铁建造是地球早期特有的化学沉积建造类型,广泛分布于太古代—早元古代(3.2～1.8 Ga),记录了地球早期大气和海洋的化学成分、氧化还原状态及演化,是广大地质工作者长期关注的焦点之一.在国外,与BIF...     

Iron in Precambrian rocks: implications for the global oxygen budget of the ancient Earth

Banded iron formations (BIF) are prominent in sediments older than 2 Ga. However, little is known about the absolute abundance of BIF in Archean and Early Proterozoic sediments, and the source of the Fe is still somewhat uncertain. Also unknown is the role that Fe may have played in the maintenance of low oxygen pressures in the Archean and Early Proterozoic atmosphere. An analysis of the chemical composition of Precambrian rocks provides some insight into the role of Fe in Precambrian geochemical cycles. The Fe content of igneous rocks is well correlated with their Ti content. Plots of Fe vs. Ti in Precambrian sandstones and graywackes fall very close to the igneous rock trend. Plots of Fe vs. Ti in Precambrian shales also follow this trend but show a definite scatter toward an excess of Fe. Phanerozoic shales and sandstones lie essentially on the igneous rock trend and show surprisingly little scatter. Mn/Ti relations show a stronger indication of Precambrian Mn loss, perhaps due to weathering under a less oxidizing early atmosphere. These data show that Fe was neither substantially added to nor significantly redistributed in Archean and early Proterozoic sediments. Enough hydrothermal Fe was added to these sediments to increase the average Fe content of shales by at most a factor of 2. This enrichment would probably not have greatly affected the near-surface redox cycle or atmospheric oxygen levels. Continued redistribution of Fe and mixing with weathered igneous rocks during the recycling of Precambrian sediments account for the excellent correlation of Fe with Ti in Phanerozoic shales and for the similarity between their Fe/Ti ratio and that of igneous rocks.     

Microbiological processes in banded iron formation deposition

Banded iron formations have been studied for decades, particularly regarding their potential as archives of the Precambrian environment. In spite of this effort, the mechanism of their deposition and, specifically, the role that microbes played in the precipitation of banded iron formation minerals, remains unresolved. Evidence of an anoxic Earth with only localized oxic areas until the Great Oxidation Event ca 2·45 to 2·32 Ga makes the investigation of O₂‐independent mechanisms for banded iron formation deposition relevant. Recent studies have explored the long‐standing proposition that Archean banded iron formations may have been formed, and diagenetically modified, by anaerobic microbial metabolisms. These efforts encompass a wide array of approaches including isotope, ecophysiological and phylogeny studies, molecular and mineral marker analysis, and sedimentological reconstructions. Herein, the current theories of microbial processes in banded iron formation mineral deposition with particular regard to the mechanisms of chemical sedimentation and post‐depositional alteration are described. The main findings of recent years are summarized and compared here, and suggestions are made regarding cross‐disciplinary information still required to constrain the role of the biosphere in banded iron formation deposition.     

浅谈前寒武纪条带状铁建造的沉积-变质成矿过程

条带状铁建造(BIF)是3.5～1.8Ga前陆架和洋盆的常见沉积物.前寒武纪条带状铁建造构成了世界上重要的铁矿资源.虽然它们成矿过程及其演化的许多方面的问题仍未解决,但人们普遍认为,它们沉积方式的长期变化与地球的环境和地球化学演化有关.条带状铁建造记录了前寒武纪古海洋、古环境、大气条件和细菌代谢条件以及铁的来源和沉积过...     

The Bedded Chert,banded iron‐formation problem

The characteristics of Bedded Cherts and Banded Iron‐Formations are summarised. As, following O'Rourke's work, the latter are considered as not confined to the Precambrian, the only significant difference between the two formations is shown to be the low iron content of Bedded Cherts. This difference it is suggested is due to Bedded Cherts having been deposited in a virtually continuously acid to weakly alkaline environment, whereas Banded Iron‐Formation was precipitated under an alternation of acid and alkaline conditions yielding siliceous and iron‐rich layers respectively. Such chemical precipitation of either Bedded Chert or Banded Iron‐Formation was in some examples of each type of formation rhythmically interrupted by the deposition of clastic sediment.     

微生物参与前寒武纪条带状铁建造沉积的研究进展

地球演化早期太古代和早元古代大规模的条带状铁建造(BIF)是目前世界上最重要的铁矿资源。已有的稳定同位素组成、分子化石以及岩石磁学性质等证据支持早期微生物广泛参与了BIF的形成。本文评述了微生物参与BIF形成过程中铁搬运和沉淀及其同位素分馏、生物标志物和岩石磁学证据。深入地研究BIF成矿中的微生物矿化贡献,有助于解释BIF形成机制,反演前寒武纪大气-海洋环境演化,以及理解地球早期生命的过程。     

Banded iron formations in Proterozoic greenstone belts: Call for further studies

Banded iron formations occur in greenstone belts in which volcanic rocks are predominant. Greenstone belts are not restricted to the Archaean (>2500 Ma), as is commonly perceived, but they continued to form, albeit in lesser abundance, in the Proterozoic. Thus, banded iron formations which are closely associated with volcanic sequences occur in several well-documented early-mid Proterozoic greenstone belts. Examples are the Yavapai belts at Jerome in Arizona, the Trans-Amazonian belts in Guiana, and the Dalma belts of the Singhbhum region of NE India. Stratigraphic and sedimentological studies are needed to establish the similarities and differences of these iron formations with those in Archaean greenstone belts, and with the banded iron formations which were common in cratonic-shelf environments in the early-mid Proterozoic.     

Siderite formation and evolution of sedimentary iron ore deposition in the Earth’s history

The role of siderite in Phanerozoic and Precambrian iron formations is discussed. Various types of iron formations are characterized, and their place in the evolution of sedimentary iron ore deposition is outlined. In Precambrian iron ore deposition, siderite is a primary mineral, whereas in Phanerozoic iron formations it becomes a secondary mineral and is commonly related to diagenetic and catagenetic processes.     

青藏高原前寒武纪岩石地层划分、对比──兼论“三江”构造带基底特征

根据岩石地层划分、对比理论和原则，对青藏高原主体范围内的前寒武纪地层进行了岩石地层和地质年代的划分，建立了岩石组合特征的标志及其上、下序列关系，提出了划分、对比意见。最后讨论了本区元古宙重大地质事件和基底性质，得出了本区无古宙地层纵向四分、横向二分的结论。