Differences in the quality of polishing between sound and weathered granites

Aesthetic characteristics are important when rocks are used as construction materials. Among all the surface finishes available, the polished finish is the one which best enhances the rock attractiveness. Colour (C), roughness (R) and gloss (G) are surface properties usually used to assess the rock polishing. In this research, the CRG properties were assessed in polished samples of three ornamental granites with different textures and physical–mechanical properties, one weathered and two sound. C was evaluated in CIE-L ^* a ^* b ^* and CIE-L ^* C ^* _ab h _ab systems, R with R _a and R _z parameters and G using the 20°, 60° and 85° geometries. The weathered granite presents a noticeable colour variation, especially in the b ^* parameter, while the sound ones have a more homogeneous colour. Sound and more textural homogeneous granites have a low surface roughness and high gloss, which are uniformly distributed. The weathered granite shows a higher surface roughness and lower gloss, with scattered distribution. The mineral contacts are the main cause of the surface irregularities. The results show the interdependence between the CRG properties and stress the importance of the polishing process for enhancing the aesthetic characteristics of the granites. CRG properties could be used for quality control in granite processing plants, thus avoiding noticeable differences in the facades of buildings, particularly when weathered granites are used.     

Fixation of radionuclides in the 238U decay series in the vicinity of mineralized zones: 1. The Austatom Uranium Prospect,Northern Territory,Australia

The minimum age of a zone of secondary uranium mineralization, located at the Austatom Prospect in the Alligator Rivers region of Australia, is estimated to be 3.6 × 10⁵y. This is derived from a geochronological model based on retarded leaching of ²³⁴U with respect to ²³⁸U and on ratios within the ore of these members of the ²³⁸U decay series. Although kaolinite is a dominant mineral in the weathered schist-host-rocks, retarded dissolution of ²³⁴U occurs only in the presence of the clay minerals illite and montmorillonite. In their absence the reverse occurs. A model is proposed to explain the results. Ratios of ²³⁰Th to ²³⁸U indicate that the mineralization has probably remained stationary within the weathered schist for at least 1 to 2 × 10⁵y. Future use of clay minerals as buffers in radioactive waste repositories is supported by the excellent long-term retention obtained for oxidized uranium, probably due in part to isomorphic substitution into the clay crystal lattice.     

A tectono-geomorphic model of the hydrogeology of deeply weathered crystalline rock: Evidence from Uganda

Deeply weathered crystalline rock forms important aquifers for public water supply throughout low-latitude regions of Africa, South America, and Asia, but these aquifers have considerable heterogeneity and produce low well yields. Aquifers occur in the bedrock and overlying weathered mantle and are the products of geomorphic activity of meteoric water, principally deep weathering and stripping. The fundamental relationship between the hydrogeology and geomorphology of these terrains has, however, remained unresolved. This study demonstrates the ability of a recently developed tectono-geomorphic model of landscape evolution in Uganda to explain the hydrogeological characteristics of two basins, as determined using a combination of textural analysis, slug tests, packer tests, and pumping tests. The geopetal imprint of long-term deep weathering and erosional unloading is identified in the vertical heterogeneity of the fractured-bedrock and weathered-mantle aquifers; horizontal heterogeneity is lithologically controlled. The two units form an integrated aquifer system in which the more transmissive (5–20 m²/d) and porous weathered mantle provides storage to underlying bedrock fractures (transmissivity, T, ≈1 m²/d). The thickness and extent of the more productive weathered-mantle aquifer are functions of contemporary geomorphic processes. The utility of the tectono-geomorphic model, applicable to deeply weathered environments, is that it coherently describes the basin-scale hydrogeological characteristics of these complex terrains. Received, June 1999/Revised, January 2000/Accepted, January 2000     

Dissolution and transport of manganese by organic acids and their role in sedimentary Mn ore formation

Dissolution experiments of Mn and Fe under natural conditions from fresh basalt, weathered basalt and Mn laterite by different organic acids show that Mn is highly enriched over Fe in solutions from the weathered rocks but that more Fe than Mn is dissolved from the fresh basalt. The enrichment of Mn is caused by sparingly soluble Fe-oxides and hydroxides and more soluble Mn-oxides. In addition from the weathered rocks the Mn concentration dissolved by the organic acids is up to 1000 times higher than in inorganic solutions. Mn enrichment is caused by acid attack, organic reduction of Mn⁴+ to Mn²+ and complexing by the organic acids. The complexed Mn is not attacked as easily by oxidation as free Mn ions. Higher concentrations of manganese in the organic dissolved stage can therefore be transported by rivers over greater distances. Organic complexed Mn, derived from lateritic weathered rocks may therefore contribute to the formation of low iron marine sedimentary Mn deposits.     

An integrated hydrogeological study to support sustainable development and management of groundwater resources: a case study from the Precambrian Crystalline Province,India

The rapid expansion of agriculture, industries and urbanization has triggered unplanned groundwater development leading to severe stress on groundwater resources in crystalline rocks of India. With depleting resources from shallow aquifers, end users have developed resources from deeper aquifers, which have proved to be counterproductive economically and ecologically. An integrated hydrogeological study has been undertaken in the semi-arid Madharam watershed (95 km²) in Telangana State, which is underlain by granites. The results reveal two aquifer systems: a weathered zone (maximum 30 m depth) and a fractured zone (30–85 m depth). The weathered zone is unsaturated to its maximum extent, forcing users to tap groundwater from deeper aquifers. Higher orders of transmissivity, specific yield and infiltration rates are observed in the recharge zone, while moderate orders are observed in an intermediate zone, and lower orders in the discharge zone. This is due to the large weathering-zone thickness and a higher sand content in the recharge zone than in the discharge zone, where the weathered residuum contains more clay. The NO₃ ^? concentration is high in shallow irrigation wells, and F^? is high in deeper wells. Positive correlation is observed between F^? and depth in the recharge zone and its proximity. Nearly 50 % of groundwater samples are unfit for human consumption and the majority of irrigation-well samples are classed as medium to high risk for plant growth. Both supply-side and demand-side measures are recommended for sustainable development and management of this groundwater resource. The findings can be up-scaled to other similar environments.     

Groundwater flow dynamics of weathered hard-rock aquifers under climate-change conditions: an illustrative example of numerical modeling through the equivalent porous media approach in the north-western Pyrenees (France)

A numerical groundwater model of the weathered crystalline aquifer of Ursuya (a major water source for the north-western Pyrenees region, south-western France) has been computed based on monitoring of hydrological, hydrodynamic and meteorological parameters over 3 years. The equivalent porous media model was used to simulate groundwater flow in the different layers of the weathered profile: from surface to depth, the weathered layer (5?·?10^?8?≤?K?≤?5?·? 10^?7 m s^?1), the transition layer (7?·?10^?8?≤?K?≤?1?·? 10^?5 m s^?1, the highest values being along major discontinuities), two fissured layers (3.5?·?10^?8?≤?K?≤?5?·?? 10^?4 m s^?1, depending on weathering profile conditions and on the existence of active fractures), and the hard-rock basement simulated with a negligible hydraulic conductivity (K = 1 10 ^?9 ). Hydrodynamic properties of these five calculation layers demonstrate both the impact of the weathering degree and of the discontinuities on the groundwater flow. The great agreement between simulated and observed hydraulic conditions allowed for validation of the methodology and its proposed use for application on analogous aquifers. With the aim of long-term management of this strategic aquifer, the model was then used to evaluate the impact of climate change on the groundwater resource. The simulations performed according to the most pessimistic climatic scenario until 2050 show a low sensitivity of the aquifer. The decreasing trend of the natural discharge is estimated at about ?360 m³ y^?1 for recharge decreasing at about ?5.6 mm y^?1 (0.8 % of annual recharge).     

Engineering geological studies of the diversion tunnel, focusing on stabilization analysis and support design, Iran

In this paper a detailed engineering geological assessment of rock masses and support design studies at Garmi Chay dam site, has been carried out. This project is located in the northwest of Iran and will be used for flow control and water storage. The diversion tunnel of the dam has a diameter of 5.5 m and a length of 420 m and will be driven in slightly to highly weathered micaschist and trachy andesite rock units. The geological studies include field and laboratory investigations that based on the results; for more exact investigation, tunnel alignment was divided into three geotechnical zones. These zones consist mainly of highly weathered gray micaschists, dark red trachy andesites and slightly weathered gray micaschists, respectively. Then, for every zone, support capacity of rock masses was evaluated by means of empirical and numerical methods. The rock mass classification systems (RMR, Q, GSI, RSR, SRC and RMi), the convergence–confinement method and a 2D finite element computer software, Phase² were used for empirical and numerical method, respectively. According to the results acquired from these methods some stability problems were expected in the tunnel especially in highly weathered micaschist zone, so that in practice two big collapses occurred. Because of high weathering, low constants of rock masses and their soil-like behavior, the stability analysis by analytical method does not give illogical results in lightly weathered micaschist zone. The support system, suggested by empirical method, was applied and its performance was evaluated by means of numerical modeling. After installation the support suggested by Phase² program, the thickness of plastic zone and deformations around the tunnel decreased significantly. Consequently the agreement of these methods with each other was resulted and using combination of them was recommended for more reliable support design.     

Last Glacial Maximum ice sheet dynamics in Arctic Canada inferred from young erratics perched on ancient tors

A long-standing debate regarding the reconstruction of former ice sheets revolves around the use of relative weathering of landscapes, i.e., the assumption that highly weathered landscapes have not been recently glaciated. New cosmogenic isotope measurements from upland bedrock surfaces and erratics along the northeastern margin of the Laurentide Ice Sheet (LIS) shed light on this debate. ¹⁰Be and ²⁶Al concentrations from three perched erratics, yielding cosmogenic exposure ages of 17–11 ka, are much lower than those measured in two unmodified, highly weathered tors upon which they lie, which yield cosmogenic exposure ages of >60 ka. These findings suggest that non-erosive ice covered weathered upland surfaces along the northeastern margin of the LIS during the last glacial maximum. These data challenge the use of relative weathering to define the margins of Pleistocene ice sheets. The juxtaposition of non-erosive ice over upland plateaus and erosive ice in adjacent fiords requires strong gradients in basal thermal regimes, suggestive of an ice-stream mode of glaciation.     

Iron weathering products in a CO2 + (H2O or H2O2) atmosphere: Implications for weathering processes on the surface of Mars

Various iron-bearing primary phases and rocks have been weathered experimentally to simulate possible present and past weathering processes occurring on Mars. We used magnetite, monoclinic and hexagonal pyrrhotites, and metallic iron as it is suggested that meteoritic input to the martian surface may account for an important source of reduced iron. The phases were weathered in two different atmospheres: one composed of CO₂ + H₂O, to model the present and primary martian atmosphere, and a CO₂ + H₂O + H₂O₂ atmosphere to simulate the effect of strong oxidizing agents. Experiments were conducted at room temperature and a pressure of 0.75 atm. Magnetite is the only stable phase in the experiments and is thus likely to be released on the surface of Mars from primary rocks during weathering processes. Siderite, elemental sulfur, ferrous sulfates and ferric (oxy)hydroxides (goethite and lepidocrocite) are the main products in a water-bearing atmosphere, depending on the substrate. In the peroxide atmosphere, weathering products are dominated by ferric sulfates and goethite. A kinetic model was then developed for iron weathering in a water atmosphere, using the shrinking core model (SCM). This model includes competition between chemical reaction and diffusion of reactants through porous layers of secondary products. The results indicate that for short time scales, the mechanism is dominated by a chemical reaction with second order kinetics (k = 7.75 × 10⁻⁵ g⁻¹/h), whereas for longer time scales, the mechanism is diffusion-controlled (De_A = 2.71 × 10⁻¹⁰ m²/h). The results indicate that a primary CO₂- and H₂O-rich atmosphere should favour sulfur, ferrous phases such as siderite or Fe²⁺-sulfates, associated with ferric (oxy)hydroxides (goethite and lepidocrocite). Further evolution to more oxidizing conditions may have forced these precursors to evolve into ferric sulfates and goethite/hematite.     

Redistribution of uranium and thorium series isotopes during isovolumetric weathering of granite

Previous studies of the distribution of U and Th in parent versus weathered granites have shown both depletion and enrichment of these elements during weathering. In this study, the distribution of U and Th decay series isotopes was determined in a weathering profile of a granitic saprolite, which showed textural preservation indicating isovolumetric weathering. Two types of dissolution methods were used: a whole-rock dissolution and a sodium-citrate dithionite leach to preferentially attack noncrystalline phases of weathering products. Using volume-based activities, 45–70 percent of the total ²³²Th was gradually removed during weathering. Although the whole-rock ${}^{228}\text{Th}{}^{232}\text{Th}$ activity ratios were in equilibrium, there were large excesses of ²²⁸Th in the leachable fraction of both parent rock (${}^{228}\text{Th}{}^{232}\text{Th}\text{= 2.06}$) and partially weathered saprolite (${}^{228}\text{Th}{}^{232}\text{Th}\text{= 3–6.5}$), due to alpha recoil and release of daughter ²²⁸Th to the weathering rind of the mineral grain. For the most weathered sample, 81 percent of the thorium was in the teachable fraction and ${}^{228}\text{Th}{}^{232}\text{Th}\text{= 1}$, indicating that even the more resistant minerals were attacked.The total U activities showed as much variation in the six parent rock samples as in the weathered profile, and ${}^{234}\text{U}{}^{238}\text{U}$ were in equilibrium in both the whole-rock and leachable fractions. ²³⁰Th was deficient relative to ²³⁴U and ²²⁶Ra in both fractions, suggesting recent addition of U and Ra to the entire profile. The large variation in U was not from absorption onto the intermediate weathering products, because only 11–23 percent of the U was in the leachable fraction.     

Weathering of phosphorus-bearing mineral powder and calcium phosphate by Aspergillus niger

The weathering of phosphorus-bearing mineral powder(PBMP) and calcium phosphate(CP) by Aspergillus niger was compared,and the mechanism involved was analyzed for the comprehensive utilization of PBMP.The concentration of water-soluble phosphorus(WSP),Mg2+,and Ca2+at different culture times,microstructures of particles,and mineral compositions was examined by ultraviolet-visible spectrometer(UV),atomic absorption spectrometry(AAS),scanning electron microscopy(SEM),and X-ray diffraction(XRD).Results showed that the change in the concentrations of WSP,Mg2+,and Ca2+were related to the growth of A.niger and the different mineral compositions.Compared with CP,PBMP was weathered harder by fungi.Traces of the weathered mineral were found through SEM.CP not only showed traces of erosion damage but also appeared as a rhombohedron-like substance.The XRD test indicated that the weathering minerals can form water calcium oxalate.Further analysis revealed that the mechanism of PBMP and CP weathering by A.niger was the collaborative result of mycelium biomechanical effects and the acid-soluble role of acidic metabolites.The phosphorus dissolution rate of PBMP after 20 d was 46.83%,whereas that of CP after 12 d was 91.01%.The findings of this study are significant to the effective use of waste PBMP and to the exploitation of low-grade phosphate rock resources.     

Stratigraphy and structural summary of the Cooma Metamorphic Complex

A technique for obtaining age estimates for regolith profiles in Australia, based on the oxygen‐isotope composition of the clay mineral assemblage in a profile, is applied to a variety of regolith profiles and kaolinitic sediments from across Australia. Excluding monsoonal regions in the north of the continent, it is possible to distinguish profiles formed in the Late Mesozoic‐Early Tertiary (δ¹⁸O values between +15 and +17.5%δō) from profiles formed in post‐mid‐Tertiary times (>+17.5%ō). In addition it is concluded that there remain widespread remnants of a deep‐weathered regolith which developed in pre‐Late Mesozoic (Early Cretaceous or Jurassic?) times when Australia was at high latitude. The low δ¹⁸O values associated with clays formed in pre‐Late Mesozoic times (+10 to +15%o) suggest that deep weathering took place in a cool to cold and presumably humid climate, contrary to the traditional belief that deep weathering requires tropical to subtropical temperatures. The formation of deep‐weathered profiles at high latitude in a comparatively cold climate may be linked in part to higher past atmospheric CO₂ levels.     

Characterizing the vadose zone and a perched aquifer near the Vosges ridge at the La Soutte experimental site,Obernai, France

We consider a series of hydrogeophysical techniques that provide a multiscale investigation of the water content in the vadose zone and of the perched aquifer at the experimental site of “La Soutte” in the Vosges Mountains (France). It is located in a catchment area where several springs and streams occur along fractured volcanic and weathered plutonic rocks. The site is the object of a long-term study that uses both continuous and repeated measurements to monitor hydrogeological processes. The main results from AMT and DC resistivity techniques allow the determination of a high-resolution 3D resistivity model over a large range of depths (from 10⁰ to 10³ m). We discuss their use and propose a hydrogeological model (porosity, water conductivity and water content). We also use MRS and GPR for a detailed investigation of the shallow part of the catchment that consists of soil and weathered rocks of highly varying thickness (0 to 15 m). MRS is used to map the thickness and total water volume content by unit surface of the saturated weathered zone. It also yields estimates of the vadose zone thickness through the depth to the top of the saturated zone. Moreover, we show results from GPR CMP measurements that yield estimates of the water content and porosity in the shallowest layer (0–30 cm) by simple interpretation of the ground direct wave.     

Investigation on causes of the Siruyeh Landslide, West Semirom (Iran)

The Siruyeh landslide occurred at the eastern side of the Siruyeh valley, 22 km west of Semirom city, south of Esfahān on 25th March, 2005 with large dimensions (2,400 m long, 450 m wide with total area of 1 km²). The sliding mass blocked the Siruyeh River making a 35-m-high natural dam and 6-acre lake 570,000 m³ in volume that poses a potential threat for the area. The landslide occurred in soil and intensely weathered marls of the Tarbur and Kashkan Formations (upper Cretaceous–Paleocene age). The overall comparison and interpretation of the gathered evidence from satellite images, field trips, and laboratory tests show that the most important factors involved in triggering the Siruyeh landslide in order of importance are heavy precipitation and snow melt and intense concentration of faults and fractures as well as weathered and weak lithology.     

Characterization of hydrogeologic properties for a multi-layered alluvial aquifer using hydraulic and tracer tests and electrical resistivity survey

A multi-layered aquifer, typical of riverbank alluvial deposits in Korea, was studied to determine the hydrologic properties. The geologic logging showed that the subsurface of the study site was comprised of four distinctive hydrogeologic units: silt, sand, highly weathered and fresh bedrock layers. The electrical resistivity survey supplied information on lateral extension of hydrogeologic strata only partially identified by a limited number of the geologic loggings. The laboratory column tracer test for the recovered core of the sand layer resulted in a hydraulic conductivity of 5.00×10⁻² cm/s. The slug tests performed in the weathered rock layer yielded hydraulic conductivities of 4.32–7.72×10⁻⁴ cm/s. Hydraulic conductivities for the sand layer calculated from the breakthrough curves of bromide ranged between 2.08×10⁻³ and 2.44×10⁻² cm/s with a geometric mean of 6.89×10⁻³ cm/s, which is 7 times smaller than that from the laboratory column experiment. The trend of increasing hydraulic conductivity with an increase in tracer travel length is likely a result of the increased likelihood of encountering a high conductivity zone as more of the aquifer is tested. The combined hydrogeologic site characterization using hydraulic tests, tracer tests, and column test with geologic loggings and geophysical survey greatly enhanced the understanding of the hydrologic properties of the multi-layered alluvial aquifer.     

Organic chemical characterization of sediment-trap particulates from San Nicolas,Santa Barbara,Santa Monica and San Pedro Basins,California

Particulate matter was collected during September–October, 1977, in particle traps suspended 30–60 m above the floor of San Nicolas, Santa Barbara, Santa Monica and San Pedro Basins, off the coast of southern California. The trap particulates were analyzed for C₁₅–C₃₅ hydrocarbons using gas chromatography (GC) and GC-mass spectrometry. Kerogens and humic acids were characterized by H/C, N/C, δ¹³C, δ¹⁵N and δ³⁴S ratios, and by electron-spin resonance. Hydrocarbons arising from fresh and weathered petroleum, marine autochthonous and terrestrial sources were identified. The rates of petroleum deposition during the collection period followed the order: San Nicolas Basin < Santa Barbara Basin ~ Santa Monica Basin < San Pedro Basin, with the largest amount of weathered petroleum being deposited in San Pedro Basin. The rates of petroleum deposition are correlated more strongly with human activities such as shipping, and the discharge of municipal and industrial wastes, than with natural submarine oil seepage. Analyses of kerogens and humic acids indicate that the majority of the organic matter in the trap particulates is of marine origin. The water column overlying Santa Barbara Basin appears to have the highest marine productivity of the four basins studied.     

Glaciations of the West Coast Range,Tasmania

Geomorphic, stratigraphic, palynologic and ¹⁴C evidence indicates that the West Coast Range, Tasmania, was glaciated at least three times during the late Cenozoic. The last or Margaret Glaciation commenced after 30,000 yr B.P., culminated about 19,000 yr B.P., and ended by 10,000 yr B.P. During this period a small ice cap, ca. 250 m thick, and cirque and valley glaciers covered 108 km². The glacial deposits show little chemical weathering or erosional dissection. The snow line ranged from 690 to 1000 m with an average of 830 m for the ice cap. Mean temperature was 6.5°C below the present temperature. During the preceding Henty Glaciation a 300- to 400-m-thick ice cap and outlet glaciers exceeded 1000 km². The glacial deposits are beyond ¹⁴C assay. They are more weathered chemically and more dissected than Margaret age deposits, and the degree suggests a pre-last interglaciation age (> 130,000 yr B.P.). The snow line of the ice cap lay at 740 m, and annual temperature was reduced by 7°C. Ice of the earliest Linda Glaciation slightly exceeded that of the Henty Glaciation but had a similar distribution. The glacial deposits are intensely weathered, have reversed magnetization, and overlie a paleosol containing pollen of Tertiary type. An early Pleistocene or Tertiary age is indicated.     

Geochemical and mineralogical characteristics of ion-adsorption type REE mineralization in Phuket, Thailand

Geochemical and mineralogical studies were conducted on the 12-m-thick weathering profile of the Kata Beach granite in Phuket, Thailand, in order to reveal the transport and adsorption of rare earth elements (REE) related to the ion-adsorption type mineralization. The parent rock is ilmenite-series biotite granite with transitional characteristics from I type to S type, abundant in REE (592 ppm). REE are contained dominantly in fluorocarbonate as well as in allanite, titanite, apatite, and zircon. The chondrite-normalized REE pattern of the parent granite indicates enrichment of LREE relative to HREE and no significant Ce anomaly. The upper part of the weathering profile from the surface to 4.5 m depth is mostly characterized by positive Ce anomaly, showing lower REE contents ranging from 174 to 548 ppm and lower percentages of adsorbed REE from 34% to 68% compared with the parent granite. In contrast, the lower part of the profile from 4.5 to 12 m depth is characterized by negative Ce anomaly, showing higher REE contents ranging from 578 to 1,084 ppm and higher percentages from 53% to 85%. The negative Ce anomaly and enrichment of REE in the lower part of the profile suggest that acidic soil water in an oxidizing condition in the upper part mostly immobilized Ce⁴⁺ as CeO₂ and transported REE³⁺ downward to the lower part of the profile. The transported REE³⁺ were adsorbed onto weathering products or distributed to secondary minerals such as rhabdophane. The immobilization of REE results from the increase of pH due to the contact with higher pH groundwater. Since the majority of REE in the weathered granite are present in the ion-adsorption fraction with negative Ce anomaly, the percentages of adsorbed REE are positively correlated with the whole-rock negative Ce anomaly. The result of this study suggests that the ion-adsorption type REE mineralization is identified by the occurrence of easily soluble REE fluorocarbonate and whole-rock negative Ce anomaly of weathered granite. Although fractionation of REE in weathered granite is controlled by the occurrence of REE-bearing minerals and adsorption by weathering products, the ion-adsorption fraction tends to be enriched in LREE relative to weathered granite.     

Preferential solution of234U from recoil tracks and234U/238U radioactive disequilibrium in natural waters

A mathematical model to calculate the²³⁴U/²³⁸U activity ratio (AR) in an aqueous phase in contact with rock/soil is presented. The model relies on the supply of²³⁸U by dissolution and that of²³⁴U by dissolution and preferential release from radiation damaged regions (recoil tracks). The model predicts that values of²³⁴U/²³⁸U AR>1 in the aqueous phase can be obtained only from weathering “virgin” surfaces. Thus, to account for the observed steady-state supply of²³⁴U excess to the oceans by the preferential leaching model, ‘virgin’ rock/soil surfaces would have to be continually exposed and weathered. The²³⁸U concentration and²³⁴U/²³⁸U AR in continental waters allow us to estimate the exposure rates of “virgin” rock/soil surfaces.     

Natural analogues for the transuranic actinide elements: An investigation in Minas Gerais,Brazil

A highly weathered deposit of thorium and rare earth elements located near the summit of a hill in the state of Minas Gerais, Brazil, is being studied as an analogue for a radioactive waste repository that sometime in the distant future may be eroded to the surface or intruded by groundwater Thorium serves as an analogue for Pu⁴⁺, and La³⁺ as an analogue for Cm³⁺ and Am³⁺ The mobilization rate constants of the analogue elements by groundwater are so slow (of the order of 10⁻⁹ per year) as to suggest that essentially complete radioactive decay of the transuranic actinides would occur in place even under the relatively unfavorable conditions that exist at a site such as this