Visible and near-infra-red transmission and reflectance measurements of the Luna 20 soil

Visible and near-infra-red spectra of chemically analyzed grains of glass and minerals from the Luna 20 sample were compared with diffuse reflectance spectra of the bulk soil. As in the spectra of soil samples from other localities on the Moon, pyroxene contributes two broad absorption features near 1 μm and 2 μm. The soil has a high integral reflectance (or albedo) arising from plagioclase, which appears to be the dominant mineral in the lunar highlands. The Luna 20 soil curve is most similar to the reflectance curves of the non-rayed soils at Apollo 16, in agreement with the generally similar mineralogy of these samples. The average pyroxene composition in the Luna 20 soil, as determined from the absorption bands in the diffuse reflectance spectra, and analyses of single crystals, is more calcic than in the lithic fragments. Thus, the soil appears to have a few per cent of admixed material derived from mare basalts. Comparison of the soil spectrum with telescopic curves of nearby areas reveals a close similarity; however, the Luna 20 sample is slightly less mature than expected. Luna 20 may have sampled subsurface material that is fresher than the regional surface soil, or alternatively, the Luna 20 area may contain an admixture of relatively recently exposed material from a ray crater.     

The mineralogy and petrology of the Luna 20 soil sample

Fragments of igneous rocks, glasses and minerals comprise 25 per cent of the studied sample of the Luna 20 soil. Basalt fragments in the Luna 20 soil are similar to basalts from the mare regions of the Moon—in that they are characterized by the presence of iron-rich olivines and pyroxenes. On the basis of the FeO contents of plagioclases, it appears possible to distinguish between the plagioclase of the mare and highland regions of the Moon. Other igneous rock fragments are anorthosite, gabbroic anorthosite and anorthositic gabbro. The most abundant rock type (75 per cent of the sample) is microbreceia. One third of the fragments of microbreccia have undergone thermal metamorphism resulting in the homogenization of phases and the development of poikioblastic and hornfelsic textures. Excluding the basalt fragments, the dominant minerals in the Luna 20 soil are anorthite (An_93–98), magnesium-rich orthopyroxenes, intermediate clinopyroxenes and olivine (< Fa₅₀). Chemically, the Luna 20 and Apollo 16 soil samples are similar, but the Luna 20 soil is slightly depleted in aluminum and calcium and enriched in iron and magnesium relative to the Apollo 16 soils. The slight difference in bulk chemistry of the two soils may be a result of the presence of a minor amount of mare material in the Luna 20 soil and its apparent absence in the Apollo 16 soils.     

Chemical composition of Luna 20 rocks and soil and Apollo 16 soils

The abundances of 24 major, minor and trace elements have been measured by INAA in Luna 20 metaigneous rocks 22006,1 and 22007,1, breccia 22004 and soil 22001,9 and in Apollo 16 soils 62281, 66041 and 66081. An additional 12 trace meteoritic and non-meteoritic elements have also been determined in 22001 and 62281 soils by RNAA. The bulk compositions of L 20 and Ap 16 rocks and soils show close similarity between the two highland sites. There are appreciable differences in bulk compositions between the L 20 highland and the L 16 mare site (120 km apart), suggesting little intermixing of rocks and soils from either site. Luna 20 rocks 22006 and 22007 are nearly identical in chemical composition to Ap 16 metaigneous rocks 61156 and 66095. Luna 20 rocks are feldspathic and are similar to low K-type Fra Mauro basalts. Such rocks and anorthositic gabbros appear to be the major components in highland soils. Luna 20 soil can be distinguished from Ap 16 soils by lower abundances of Al₂O₃, CaO and large ion lithophilic elements. Luna 20 breccia 22004 probably is compacted soil. All L 20 samples show negative Eu anomalies with $\text{Sm}\text{Eu}$ ratios of 5.8, 7.2, 3.9 and 3.3 for rocks 22006, 22007, breccia 22004 and soil 22001, respectively. Norite-KREEP is insignificant, ≤1 per cent, at the L 20 highland site. The derivation of the L 20 soil may be explained by ≈33 per cent of L 20 metaigneous rocks and ≈ 65 per cent anorthositic gabbroic breccia rocks like 15418 (with a positive Eu anomaly) and ≈ 2 per cent meteoritic contributions. Interelement correlations observed previously for maria are also found in highland samples. Luna 20 and Ap 16 soils are low in alkalis. Both soils show an apparent Cd-Zn rich component similar to that observed at the mare sites and high 11 abundances relative to mare sites. The Ap 16 (62281) soil contains a fractionated meteoritic component (probably ancient) of ≈ 1.5 per cent in addition to ≈ 1.9 per cent Cl like material. Luna 20 soil may simply contain 1.9 per cent Cl equivalent.     

Chemistry and thermal history of metal particles in Luna 20 soils

Individual metal particles from Luna 20 thin sections 521, 513 and 514 as well as several small metallic inclusions in silicate particles from Luna 20 thin sections 501 and 502 were examined using optical microscopy and the electron microprobe. All the metallic particles and inclusions analyzed are of meteoritic Co-Ni content as are most of the metallic particles from the Fra Mauro and the Apollo 16 highlands sites. It is proposed that most of the metal at these 3 sites had its origin in the meteoritic projectiles that bombarded and accumulated in the early lunar crust. It is apparent that the metallic particles and some of the metallic inclusions in the Luna 20 soil have been subjected to reheating on the Moon and this process has removed any evidence of the original meteoritic microstructure of the metal.     

Chemical composition of Luna 20 soil and rock fragments

Abundances of 22 elements, including 9 rare earth elements (REE), have been determined by ‘monostandard’ instrumental neutron activation analysis of samples from the Luna 20 soil and in 6 rock fragments, including a crystalline rock of highland origin, a breccia of similar composition, a glass and a feldspar grain. The soil appears to have been contaminated with W and Mo. The REE content of the soil is very low, being close to 2.3 times below the level in the Luna 16 soil. Sampling errors, for most elements, are negligible in the case of analyses performed on one or several tens of mg of soil, but they become significant on crystalline rock fragments in the 1–2 mg range.     

A lunar differentiation model in light of new chemical data on Luna 20 and Apollo 16 soils

Fines from a Luna 20 soil sample and from three Apollo 16 deep drill core samples have been analyzed for major-minor element abundances by a combined, semi-micro atomic absorption spectrophotometric and colorimetric method. Both the major element and large ion lithophile trace element abundances in these soils, the first from interior highland sites, are greatly influenced by the very high normative plagioclase content, being distinctly richer in Al and Ca, and poorer in K, P, Cr, Mn, Fe, and Ti, than most bulk soil samples from previous lunar missions. The relatively large compositional variations in the Apollo 16 core can be ascribed almost entirely to decreasing plagioclase with increasing depth. The chemical composition of the Luna 20 soil indicates less plagioclase and less KREEP than in the Apollo 16 soils. A lunar differentiation model is presented in which is made the suggestion that KREEP is the result of a second fusion event in a lunar crust consisting of early feldspathic cumulates and primary aluminous ‘liquid’.     

U-Th-Pb measurements of Luna 20 soil

The concentrations of uranium, thorium and lead and the lead isotopic composition of Luna 20 soil were determined. The data indicate that the Luna 20 soil is mainly a mixture of highland anorthosites and low-K basalt, but little KREEP basalt. The U-Th-Pb systematics are discussed in comparison with other lunar soils, especially with Apollo 16 soils which were collected from a ‘typical’ highland region. The data fit well in the Apollo 16 soil array on a U-Pb evolution diagram, and they exhibit excess lead relative to uranium. This relationship appears to be a characteristic of highland localities. Considering the previous observations of lunar samples, we infer that lead enrichment in the soil relative to uranium occurred between 3.2 and 3.9 b.y. ago and that the soil was disturbed by ‘third events’ about 2.0 b.y. ago. A lunar evolution model is discussed.     

Major element compositions of Luna 20 glass particles

Major element analyses of nineteen Luna 20 glass particles indicate that most of the Luna 20 glasses have Al₂O₃ contents greater than 21 wt.% and compositions similar to Apollo 10 and Luna 20 rocks and soils. Three of the glass particles have low Al₂O₃ (< 13 wt.%) and high FeO (> 18 wt.%) contents and were probably derived from one of the adjacent maria. The low glass content of the Luna 20 soil indicates that it is relatively young or less mature than most mare soils that have been studied.     

Rare earths,other trace elements and iron in Luna 20 samples

The results of the analysis by neutron activation of six samples from the Luna 20 mission and one sample of < 1 mm fines from Apollo 16 are reported. The concentrations of the rare-earth elements (REE) in the samples of fines from Luna 20 and Apollo 16 are less than those found for corresponding materials from the mare areas but a negative Eu anomaly is still present. The concentrations of the REE in fines from Luna 20 are only about two-thirds as great as in the sample of Apollo 16 fines, but the concentrations of Co, Sc and Cr are greater by factors ranging from 1.5 to 2.3.     

The Luna 20 lithic fragments,and the composition and origin of the lunar highlands

Luna 20 soil 22003,1 (250–500 μ) is similar to Apollo 16 soil 61501,47 (250–500 μ) in terms of the percentage of different types of particles. However, among the lithic fragments, the Apollo 16 sample contains a greater percentage of fragments with more than 70 wt. % modal plagioclase and a significantly greater proportion of KREEP-rich particles. Modal analyses of non-mare lithic fragments in Luna 20 and Apollo 11, 14, 15 and 16 indicate that the KREEP-poor highland regions (the bulk of the lunar terrae), though relatively feldspathic, are compositionally inhomogeneous, ranging in plagioclase content from approximately 35 to 100 wt. %. The average plagioclase content lies in the range 45–70 wt.%. Luna 20 pyroxene analyses cluster in two groups, one more magnesian than the other. The groups persist when pyroxene analyses from KREEP-poor noritic, troctolitic and anorthositic lithic fragments from Apollo 11, 14, 15 and 16 and Luna 20 are included. Olivine compositions mimic these pyroxene groups.Within each pyroxene group Cr₂O₃ and TiO₂ decrease as $\text{Fe}\text{(Fe + Mg)}$ increases, suggesting a relationship by fractional crystallization. The two groups suggest that at least two magma compositions were involved. To account for these observations we envisage a Moon-wide magma system in which initial accretionary heterogeneities were imperfectly erased by diffusion and convection. During the cooling of this magma system fractional crystallization was effected by the flotation of plagioclase and sinking of pyroxene, olivine and perhaps ilmenite. The endproduct was an upper layer enriched in plagioclase and a lower layer enriched in mafic silicates. KREEP-rich rocks, which are predominantly noritic in major element composition, may be mechanical mixtures of KREEP-poor norite and material residual after fractional crystallization of the surface magma system.     

Fossil track and thermoluminescence studies of Luna 20 material

Track densities in 85 feldspar crystals from L-2009 range from 2.5 × 10⁶/cm² to > 10⁹/cm². This track distribution represents an intermediate case between what have been previously defined as lightly and heavily irradiated soils and suggests that the Luna 20 sample consists of a mixture of a mature, heavily irradiated component with another, lightly irradiated component. Using a two component mixing model, the age of the lightly irradiated component is ~270 × 10⁶ yr. It is possible, but by no means certain, that this is associated with the formation of the crater Apollonius C. At ~200°C the ratio of natural TL to that induced by a standard irradiation is similar to that in Apollo 12 and 14 cores below ~7 cm. This confirms that most of the Luna 20 sample represents sub-surface material.     

Oxygen and bulk element abundances in Luna 20 fines

Abundances of O, Si, Al and Mn have been determined in Luna 20 fines sample 22001,9 by instrumental neutron activation analysis. The abundances of O, Si and Al are among the highest we have observed in lunar samples and reflect a highlands origin for much of this regolith sample. The Luna 20 abundances reported here most closely resemble those we have determined in four samples of two Apollo 16 fines, rock 14310, and a clast from breccia 15459. The Luna 20 $\text{O}\text{Si}$ ratio of 1.96 ± 0.05 is similar to that in most other lunar samples, but the $\text{Al}\text{Si}$ ratio of 0.532 ± 0.024 is exceeded only by our data on the Apollo 16 fines. This $\text{Al}\text{Si}$ ratio is in agreement with the value of 0.55 ± 0.06 determined by the remote X-ray fluorescence experiment for the highlands between Mare Crisium and Mare Smythii which lie near the Luna 20 site (Adleret al., 1972).     

Compositional and X-ray data for Luna 20 feldspar

Electron-microprobe analyses of 46 feldspar grains from the 125–500 μm Luna 20 soil separate range only from 94.5 to 97.5 An (mol. %). One grain differs significantly—An₈₇. Minor element contents are low: K < 0.15 wt.%; Mg < 0.14 wt.%; Fe < 0.15 wt.%. Singlecrystal X-ray data for two analyzed grains show sharp b and c diffractions characteristic of primitive anorthite. The 46 grains are similar in composition to those in feldspar-rich fragments found in all the Apollo missions.     

Lunar surface geochemistry: Global concentrations of Th, K, and FeO as derived from lunar prospector and Clementine data

Accurate estimates of global concentrations of Th, K, and FeO have an important bearing on understanding the bulk chemistry and geologic evolution of the Moon. We present empirical ground-truth calibrations (transformations) for Lunar Prospector gamma-ray spectrometer data (K and Th) and a modified algorithm for deriving FeO concentrations from Clementine spectral reflectance data that incorporates an adjustment for TiO₂ content. The average composition of soil samples for individual landing sites is used as ground-truth for remotely sensed data. Among the Apollo and Luna sites, Apollo 12 and 14 provide controls for the incompatible-element-rich compositions, Apollo 16 and Luna 20 provide controls for the feldspathic and incompatible-element-poor compositions, and Apollo 11, 15, and 17, and Luna 16 and 24 provide controls for Fe-rich compositions. In addition to these Apollo and Luna sample data we include the composition of the feldspathic lunar meteorites as a proxy for the northern farside highlands to extend the range of the calibration points, thus providing an additional anorthositic end-member composition. These empirical ground-truth calibrations for Lunar Prospector Th and K provide self consistency between the existing derived data and lunar-sample data. Clementine spectral-reflectance data are used to construct a TiO₂-sensitive FeO calibration that yields higher FeO concentrations in areas of high-Fe, low-Ti, mare-basalt-rich surfaces than previous FeO algorithms. The data set so derived is consistent with known sample compositions and regolith mixing relationships.     

Volcanism in Mare Fecunditatis and Mare Crisium: Ar-Ar age studies

The laser ⁴⁰Ar/³⁹Ar dating technique has been applied to five Luna 16 basalt fragments and one impact glass, and nine Luna 24 basalt fragments and one breccia. The textures of these basalts are fine-grained ophitic and coarse-grained basalts. The samples contain high levels of solar and lunar atmospheric argon acquired during their residence on the lunar surface. These trapped argon components are predominantly released at low temperature steps and can be distinguished from radiogenic and cosmogenic released at intermediate and high temperature steps. The apparent ages obtained for Luna 16 samples span a narrow range of 3.29 to 3.38 Ga. A young age of 0.988 Ga was obtained for a basaltic impact glass indicating the age of an impact event in the vicinity of Luna 16 landing site. The ages obtained for Luna 24 samples suggest the existence of at least three periods of volcanism occurring over a protracted interval of between 3.45 and 2.52 Ga. The long period of volcanism suggested for the Mare Crisium was likely due to a combination of geophysical and geochemical features in the surrounding and underlying areas of the Crisium Basin. Attempts at dating three Luna 20 samples were inconclusive due to their high trapped argon contents.     

Oxygen and silicon isotope ratios of the Luna 20 soil

The δ O¹⁸ and δ Si³⁰ analyses of the Luna 20 soil sample are +6.18 and +0.22, respectively, relative to the SMOW and Rose Quartz standards. However, an anomalous δ O¹⁸ value of +8.13 was obtained on one aliquot of the Luna 20 sample. Possible reasons for this apparently erroneous result are discussed.     

Oxide minerals in lithic fragments from Luna 20 fines

One hundred and seventy-six oxide mineral grains in the Luna 20 samples were analyzed by electron microprobe. Spinel is the most abundant oxide, occurring in troctolite fragments. Next most abundant is ilmenite, which occurs in all rock types except those containing spinel. Chromite also occurs in all rock types except those containing spinel. Minor amounts of ulvöspinel, armalcolite, zirkelite, baddeleyite and an unidentified TiO₂-rich phase were also found.Spinel grains are predominantly spinel-hercynite solid solutions, commonly with very minor chromite. The $\text{Fe}\text{(Fe + Mg)}$ ratio is generally lower than in spinel from Apollo 14 rocks. Chromites in non-mare rocks are similar to those from mare rocks. Ilmenite of mare origin is Mg-poor and Zr-rich compared to non-mare ilmenite; these elements may therefore be useful in determining the origin of ilmenite grains.Phase equilibria considerations suggest that spinel troctolite crystallized from a melt high in alumina; a likely candidate is the high-alumina basalt of Prinzet al. (1973a).Sub-micron wide rods of metallic Fe occur in plagioclase grains and may have formed by sub-solidus reduction processes.     

The halogens in Luna 16 and Luna 20 soils

Cl and P₂U₅ do not appear to exhibit the same correlation in soils from the Luna 20 and possibly the Luna 16 sites as they do in samples from the Apollo 11–15 sites. Nevertheless, the coherence between labile Cl and other KREEP-related elements is maintained.     

Luna 20 soil: abundance of 17 trace elements

Luna 20 soil is remarkably similar to Apollo 16 soil, in its content of 17 mainly volatile or siderophile elements: Ag, Au, Bi, Br, Cd, Cs, Ge, In, Ir, Rb, Re, Sb, Se, Te, Tl, U, and Zn. Like other highland soils, it seems to contain an ancient meteoritic component of fractionated, volatile-poor composition. The bulk soil has a high $\text{Tl}\text{Cs}$ ratio (9.4 × 10^?2), similar to that in Apollo 16 soils (5.4 × 10^?2), but higher than that in samples from other sites (1.1 × 10^?2). It is severely contaminated with Ag, Cd, Re, and Sb, judging from a comparison with a 1.7 mg soil breccia sample from the coarse fraction of the soil.     

Mineral surface modification induced by low energy ion irradiation: Implications for solar-wind exposure effects in lunar soil

We performed ion irradiation on olivine and ilmenite to simulate solar-wind exposure effects in lunar soil. The surface morphology and microstructure after ion irradiation were characterized by field emission scanning electron microscopy. Sputtering erosion significantly modified the surface of irradiated Luobusha olivine grains. All irradiated grains show smooth surface and round shape. The cleavage fractures on the unirradiated olivine surface were widened and deeply etched after He＋ irradiation. Both of these are the consequence of ion sputtering erosion. There are no bubbles or voids foundin the irradiated olivine grains, because He＋ dose in this study is lower than saturated fluence. Irradiated Panzhihua ilmenite grains are all covered with smooth flakes with the thickness of about 400 nm. The formation of the flakes should be related with helium bubbles and their growth during He＋ implantation. Some columnar-shaped particles are found at the surface of irradiated Panzhihua ilmenite. We speculate that these particles should be sulfide because of significantly high sulfur contents.