共查询到20条相似文献,搜索用时 31 毫秒
1.
R.J. Pankhurst S. Moorbath D.C. Rex G. Turner 《Earth and Planetary Science Letters》1973,20(2):157-170
KAr,40Ar39Ar and RbSr dates are reported for minerals from the ca. 3700 my-old Amîtsoq and Isua gneisses of the Godthaabsfjord area of West Greenland. KAr dates on biotites and hornblendes range from about 1900 to 3500 my, with hornblendes having a much narrower range (ca. 2250–2750 my) than biotites. One biotite from Isua gives an impossibly high KAr date of 4940 my.40Ar39Ar mineral dates are in close agreement with conventional KAr dates over the entire range of apparent age values. The presence of minor amounts of excess argon is observed in the hornblendes, but radiogenic and excess argon in the biotites are completely homogenised and cannot be differentiated.Rb-Sr measurements on biotites are closely concordant and show that all biotites were completely open to diffusion of radiogenic87Sr at about 1600–1700 my. This is the first proof of a regional thermal event at this time in the Archaean of West Greenland, although similar dates are well known from the Proterozoic belts to the north and south.The evidence suggests that those KAr biotite dates greater than about 2700–2800 my result from excess radiogenic argon incorporated during a thermal event of about this age or, more probably, during the 1600–1700 my Sr isotope homogenisation event. Scatter of mineral dates below about 2700 my could also be due, at least in part, to overprinting by the 1600–1700 my event.KAr mineral dates and an Rb-Sr mineral isochron from a pegmatite associated with the last major rock-forming event in the Godthaabsfjord area, namely the Qo?rqut granite, indicate an age of emplacement of 2580 ± 30 my. 相似文献
2.
Jackson M. Barton 《Earth and Planetary Science Letters》1975,27(3):427-435
RbSr isotopic analyses of the intensely deformed Hebron gneiss, Labrador, yield an isochron of approximately 3.6 b.y. with an initial87Sr/86Sr ratio of 0.7044, and chemical analyses show these rocks to be granodioritic in composition. It is believed that the isochron reflects a metamorphic event and that the Hebron gneiss was either derived from a compositionally anomalous zone in the mantle or from previously existing sialic crustal material. The Hebron gneiss is compositionally similar to some of the oldest rocks in the Archean cratons of Labrador, West Greenland, Rhodesia, South Africa and Minnesota (U.S.A.). 相似文献
3.
KAr age determination on whole rocks, biotites, quartz-feldspar separates and pegmatitic muscovites from a small quartz dioritic stock give a complex discordant age pattern. KAr dates from whole rocks and mineral separates define a single 116 my isochron with positive intercept, whereas muscovites from pegmatites fit a 180 my isochron with a probable negative intercept.Both ages are younger than the probable crystallization age of the stock (around 300 my), indicating a complex post-crystallization history. The fit of different mineral phases and whole rocks to a single isochron with positive intercept suggests that a thermal event caused rehomogenization of Ar among different mineral phases. 相似文献
4.
Urs Schärer 《Earth and Planetary Science Letters》1984,67(2):191-204
Comparative UPb dating of zircon, xenotime and monazite from two different samples of the Himalayan “Makalu” granite shows the two U decay series to be in disequilibrium, particularly in monazite. This disequilibrium is due to excess or deficit amounts of radiogenic206Pb which originate from an excess or deficit of230Th, respectively, occurring initially in the mineral. Such an initial disequilibrium is caused by UTh fractionation between the crystallising mineral and the magma. Therefore, the UPb ages of Th-rich minerals such as monazite (and allanite) have to be corrected for excess206Pb due to excess230Th, whereas Th-poor minerals such as zircon and xenotime require a correction for a deficit of206Pb due to deficiency of230Th. The extent of this correction depends on the degree of ThU fractionation and on the age of the rock. For the two monazite populations analysed here, these excess amounts of206Pb were, with reference to the amount of radiogenic206Pb, 8–10% and 15–20% respectively, and less than 1% for zircon and xenotime. The varying degrees of Th enrichment relative to U in monazite show that the ThU partition coefficients for this mineral are not constant within a single granite. Furthermore, for monazite there is evidence for excess amounts of radiogenic207Pb originating from the decay of initial excess231Pa, also enriched during crystal growth.The very low Th/U ratios of 0.196 and 0.167, determined for thetwo whole rocks from which the minerals have been extracted, substantiate the view that granite formation is a fundamental mechanism for ThU fractionation in continental crust.The different ages of 21.9 ± 0.2m.y. and24.0 ± 0.4m.y., obtained by averaging the corrected238U206Pb ages of the monazites, suggest that the apparently homogeneous Makalu granite was generated over a period of at least 2 m.y. 相似文献
5.
A well-defined internal RbSr isochron has been determined for the unbrecciated Nakhla achondrite, defining an age T = (1.24 ± 0.01) AE and an initial 87Sr/86Sr ratio of 0.70254 ± 0.00003. The excellence of fit to the isochron shows that a very thorough Sr isotopic equilibration took place at this time between all phases of the meteorite. Recent petrological observations indicate that the age most probably represents the time of an igneous crystallization event on the parent body of Nakhla. The age shows that we may no longer assume that major chemical and physical differentiation processes took place only in early solar system history. The RbSr systematics are shown not to require late formation of the Nakhla parent body. Geochemical similarities between Nakhla and the earth are discussed. 相似文献
6.
M.S. Chyi D.A. Crerar R.W. Carlson R.F. Stallard 《Earth and Planetary Science Letters》1984,71(1):31-45
Major element, trace element and Sr, Nd, Pb and O isotopic data for a Franciscan Mn-deposit suggest an origin by seafloor hydrothermal circulation. Based onQ-mode factor analysis the cherts and Mn-lenses of the Blue Jay mine formed from a combination of 4 components representing 1 biogenic, 1 hydrothermal, and 2 detrital sources. RbSr, UThPb and O isotopic systematics in the Mn-lenses were affected by input from the hydrothermal circulation of material leached from the underlying basalts. Nd isotopic compositions in both cherts and Mn-lenses are identical and within the range measured for Pacific Ocean water suggesting the REE were not mobilized by hydrothermal activity. Correlation of δ18O with SiO2 and MnO2 in the Mn-lenses implies the lenses formed by simple mixing of hydrothermally derived Mn-oxides with seawater and biogenic silica. δ18O of the cherts is both uniform and depleted relative to DSDP Jurassic cherts but similar to microquartz-bearing cherts of the Monterey Formation: this suggests that diagenetic activity exerted more control on oxygen isotope compositions then hydrothermal alteration or metamorphism. Finally, a well defined RbSr isochron of158 ± 5Myr was obtained for these cherts and opens the possibility of determining absolute radiometric ages for similar cherts throughout the geologic record. 相似文献
7.
D.P. Windrim M.T. McCulloch B.W. Chappell W.E. Cameron 《Earth and Planetary Science Letters》1984,70(1):27-39
Lower Proterozoic sapphirine-bearing and associated granulites from Central Australia exhibit the greatest range of present-day143Nd/144Nd ratios (∈Nd(O)= ?26.5 to +112.3) yet reported for rocks believed to be cogenetic. The Nd isotopic data and REE abundances of these rocks demonstrate extreme fractionation of the rare earths during the formation of stratiform CuPbZn sulfide deposits with which they are closely associated. Field relationships, petrography and chemistry of the sapphirine granulites suggest that their protoliths comprised chlorite-rich rocks which were generated by hydrothermal alteration of a range of rock types prior to metamorphism; calculations employing REE abundances of the sapphirine granulites and associated rocks, combined with bulk solid-fluid distribution coefficient data yield high fluid/rock ratios, consistent with a pre-metamorphic hydrothermal origin for the unusual REE patterns. The SmNd data for these rocks define an age of 1760±75Ma, which is significantly younger than the crust formation age of the terrain ( 2070±125Ma) but indistinguishable from the RbSr whole rock age for granulite facies metamorphism (1790±35Ma). These data are interpreted in terms of major hydrothermal fractionation of the rare earths shortly (perhaps tens of millions of years) before granulite facies metamorphism, followed by redistribution of Nd isotopes or small fractionations of the Sm/Nd ratio during the granulite facies event, and possibly also during intense retrogression which reset RbSr whole rock and UPb zircon and monazite systematics at about 1700 Ma. 相似文献
8.
Rb
Sr whole-rock ages of Precambrian metamorphic rocks in the Kamiaso conglomerate from central Japan
Whole-rock samples of metamorphic and granitic cobbles and boulders from the Kamiaso conglomerate in central Japan yield well-defined RbSr isochron ages of 1985 ± 25 my and 1820 ± 40 my. These ages are the oldest yet obtained for rocks in the Japanese Islands, and provide key evidence for the middle Precambrian metamorphic and igneous events in the provenance of these rocks. The age of 1985 my defined by six samples of quartzo-feldspathic gneiss may be the time of emplacement of the original granitic rocks. The 1820 my age indicates the time of extensive regional metamorphism and igneous activity. Precambrian episodes in the provenance of the Kamiaso conglomerate are summarized as follows: (1) 2000 my — formation of granitic rocks, (2) 1800–1600 my — high grade metamorphism accompanied by igneous activity, (3) 1200–1000 my — some significant thermal event.Judging from rock types and geochronological data, it can be said that metamorphic rocks in the Kamiaso conglomerate are remarkably similar to those of the Matenrei and Nangnim systems in North Korea. The Precambrian complex from which the metamorphic and granitic rocks were derived, was exposed to the north not far from the present site of the Kamiaso conglomerate in the late Paleozoic time, and it was probably a part of the large Precambrian continent in East Asia. 相似文献
9.
RbSr and UPb isotope analyses are reported for two pre-metamorphic Caledonian granites which intrude Dalradian rocks in the Central Highlands of Scotland. These data indicate that the origin of the granitic magmas involved partial fusion of old crustal material.UPb systems of zircon size and magnetic fractions from the Ben Vuirich granite are strongly discordant. However, U/Pb isotopic ratios precisely define a chord which intersects concordia at 514?7+6 m.y. and 1316?25+26 m.y. Geological constraints suggest that the lower intersection records the post-F2, pre-M3 emplacement age of the granite. The upper intersection reflects the presence of old zircon xenocrysts incorporated into the granite magma without complete isotopic resetting. The ultimate source of these xenocrysts is probably a metamorphic basement complex which formed about 1320 m.y. ago, but the immediate source region of the granites could have been Dalradian sediments derived therefrom.RbSr whole-rock systems of the Ben Vuirich granite are also strongly discordant, although 8 out of 13 data points scatter about an “errorchron” of 564 ± 24 m.y. with an initial87Sr/86Sr ratio of about 0.716. This is interpreted as a spurious result due to incomplete homogenization of Sr isotopes in the source region during partial fusion. Initial87Sr/86Sr ratios at the time of emplacement indicated by the zircon data ranged from 0.7173 to 0.7191. Whole-rock samples from the Dunfallandy Hill granite have Rb/Sr ratios 2–3 times higher than those from Ben Vuirich and define a reasonably good isochron age of 491 ± 15 m.y. with an initial87Sr/86Sr of 0.7185 ± 0.0008. This may date granite emplacement or subsequent resetting of the high Rb/Sr rocks during Caledonian metamorphism. RbSr systematics indicate that the crustal source regions of these and other Caledonian granites separated from the upper mantle at least ca. 800 m.y. ago and probably ca. 1300 m.y. ago, thus confirming the interpretation of the upper intersection age of the zircon UPb data. 相似文献
10.
A. Stettler 《Earth and Planetary Science Letters》1977,34(3):432-438
Rb and Sr concentrations and Sr isotopic composition have been measured in thermo-mineral waters from the Massif Central in France. Rocks and mineral fractions which are thought to be important Sr contributors were also analyzed. The results suggest the waters to be mixtures of two or three components from different reservoirs, which can be associated with possible source rock types like granite and syenodiorite occurring in the region. The strontium isotopic ratios found in the separated minerals of the syenodiorite stratum indicate no chemical fractionation during the water-rock interaction. A RbSr internal isochron age of(265 ± 10) × 106yr is inferred for the Roche d'Enval syenodiorite. 相似文献
11.
Portions of highland breccia boulder 7 collected during the Apollo 17 mission were studied using UThPb and RbSr systematics. A RbSr internal isochron age of3.89 ± 0.08b.y. with an initial87Sr/86Sr of0.69926 ± 0.00008 was obtained for clast 1 (77135,57) (a troctolitic microbreccia). A troctolitic portion of microbreccia clast 77215,37 yielded a UPb internal isochron of3.8 ± 0.2b.y. and an initial206Pb/207Pb of 0.69. These internal isochron age are interpreted as reflecting metamorphic events, probably related to impacts, which reset RbSr and UPb mineral systems of older rocks.Six portions of boulder 7 were analyzed for U, Th, and Pb as whole rocks. Two chemical groups appear to be defined by the U, Th, and Pb concentration data. Chemical group A is characterized by U, Th, and Pb concentrations and238U/204Pb values which are higher than those of group B. Group A rocks have typical232Th/238U ratios of ~ 3.85, whereas-group B rocks have unusually high Th/U values of ~ 4.1.Whole-rock UPb and PbPb ages are nearly concordant. Two events appear to be reflected in these data — one at ~ 4.4 b.y. and one at ~ 4.5 b.y. The chemical groupings show no correlation with documented ages. The old ages of ~ 4.4 b.y. and ~ 4.5 b.y. may, like the younger ~ 4.0 b.y. ages, be related to basin excavation events. 相似文献
12.
P.J. Betton 《Earth and Planetary Science Letters》1979,45(2):263-274
RbSr and Pb isotopic data are reported for some of the Karroo volcanics from Swaziland. Linear arrays of Karroo data are found in the RbSr and Pb/Pb isochron diagrams. Certain of these linear arrays, if interpreted as isochrons, give ages considerably in excess of the age normally accepted for the Karroo and must be interpreted as “erupted isochrons”. It is argued that these “erupted isochrons” represent mixing lines resulting from contamination of mantle-derived magma by continental crust. It is unlikely that the RbSr “erupted isochron” has any age significance because the Rb/Sr ratios were probably fractionated at the time or eruption, both during the contamination event and during subsequent fractionation. “Erupted isochrons” in the Pb/Pb isochron diagram are much more likely to have time significance because relatively recent U/Pb fractionation events do not significantly affect the Pb isotopic compositions. The Pb/Pb “erupted isochron” has an apparent age of 3260 ± 60 m y. This age is very similar to that of the Kaapvaal craton on which the volcanics rest and it is argued that the “erupted isochron” approximately dates the formation of the Kaapvaal craton.Six Pb isotope analyses of separated feldspar crystals are also reported. Three of these were demonstrably out of isotopic equilibrium with the magma at the time of eruption. This shows that isotopic heterogeneities on the scale of a few millimetres may be preserved between crystals and their host magma.The nature of the crust which contaminated the magma is considered and it seems most likely that the magma was contaminated by heterogeneous crust of uniform age. 相似文献
13.
Measurements of143Nd/144Nd and147Sm/144Nd are reported for whole rocks and mineral separates from granulites of the Napier Complex at Fyfe Hills. Charnockites, leuconorites and gabbros yield a whole rock SmNd isochron age of3060 ± 160m.y. and an initial143Nd/144Nd ratio of0.50776 ± 10 (?Nd(3060m.y.) = ?2.0 ± 1.8). The negative ?Nd value and the presence of geologically induced dispersion in the data suggest that the isochron age does not represent the time of primary crystallization of the complex but instead indicates a time of later redistribution of Sm and Nd and partial re-equilibration of143Nd/144Nd ratios. This probably occurred during the upper granulite facies metamorphism which has also been dated at~ 3100m.y. by RbSr and UPb zircon studies [1]. Coexisting clinopyroxene, apatite and total rock fractions in two adjacent samples define an approximately linear array corresponding to an age of 2300 ± 300 m.y. This array indicates that redistribution of Sm and Nd and re-equilibration of143Nd/144Nd ratios occurred on an intermineral scale during the upper amphibolite to lower granulite facies metamorphism at~ 2450m.y.Due to the resetting of the SmNd system on both whole rock and mineral scales, the primary crystallization age of the igneous protolith is not well constrained by the present data, although it is clearly3100m.y. If it is assumed that the complex was derived initially from a depleted mantle reservoir(?Nd(T) ? 2), evolution of the negative ?Nd value of ?2.0 with the observed Sm/Nd ratios requires a prehistory of~ 380m.y. This implies a primary age of~ 3480m.y. However, substantially older primary ages can be inferred if the source reservoirs had?Nd(T) > 2 and/or substantial reductions in the Sm/Nd ratio occurred in whole rocks during the granulite facies metamorphism at 3100 m.y. Such an inferred reduction in the Sm/Nd ratio may have been the result of preferential loss of Sm relative to Nd, or introduction of a low Sm/Nd fluid with?Nd ≥ 0 during granulite facies metamorphism. 相似文献
14.
《Earth and Planetary Science Letters》1985,72(4):389-404
The Urals contain a 2000 km belt of mafic-ultramafic bodies. The SmNd and RbSr systematics of two of these bodies, the Kempersai Massif in the South Ural Mountains and the Voykar-Syninsky Ophiolite Complex in the Polar Ural Mountains have been examined. These data confirm the hypothesis that these bodies represent fragments of pre-collision oceanic crust and establish constraints on the nature and timing of events in the Uralian Orogeny. Two Kempersai gabbros define SmNd internal isochrons of397 ± 20My and396 ± 33My withεNd(T) = +8.7 ∓ 0.6 and+8.4 ∓ 1.3, respectively. Whole rock samples of pillow basalt, diabase, gabbros, troctolite, and a metasediment give SmNd values which lie on this isochron indicating that these rocks are genetically related and have an igneous crystallization age of 397 My. Whole rock samples of Voykar-Syninsky diabase, gabbros, and clinopyroxenite give SmNd values which lie on or within∼ 1 ε-unit of this isochron indicating an age andεNd(T) virtually identical to those of Kempersai.εNd(T) for the Kempersai and Voykar-Syninsky mafic samples range from +7.3 to +9.0 with an average value of +8.4. This indicates that the Urals ophiolites are derived from an ancient depleted mantle source and are most plausibly pieces of the oceanic crust and lithosphere. The fact that a metasediment has the sameεNd(397 My) as the other samples indicates derivation from an oceanic source with negligible continental input.εNd(T) for the massifs is∼ 1.5 ε-units lower than the average for modern MORBs. This may be due to the differential evolution of the MORB source over the past 397 My and in conjunction with data for other ophiolites and Mesozoic MORB suggests that over the past 750 My the source for MORB has evolved at a rate less than or equal to its rate of evolution averaged over the age of the earth. Initial87Sr86Sr ratios are highly variable ranging fromεSr(T) = −25.2 for a gabbro to +70.3 for a highly serpentinized harzburgite. This reflects the effects of seawater alteration which is particularly strong on ultrabasic rocks. We conclude that the long belt of mafic-ultramafic rocks in the Urals, which includes the Kempersai and Voykar-Syninsky Massifs, represents segments of Siluro-Devonian oceanic crust. Our igneous age for Kempersai in conjunction with other age constraints suggest that these segments of oceanic crust formed at least 80 My before the collision that produced the Urals. 相似文献
15.
UPb analyses of fractions of zircon and monazite (3–8 grains each) and of single zircon grains resolve a lower Ordovician age of 470 ±4m.y. for the Palung granite which occurs in the High Himalayan nappes south of Kathmandu. Its thrusting during the Alpine orogeny under lower greenschist facies conditions did not affect the UPb systems in zircon and monazite. The granite crystallized from a magma which was mainly generated by anatexis of Precambrian continental crust. The magma was heterogeneous with respect to primary ages and/or metamorphic histories of the magma source rocks. This indicates either a derivation from (meta-) sediments or an intense mixing of different crustally derived magmas. The genesis of the Palung granite is possibly related to an orogeny which affected the Indian shield in lower Palaeozoic times. The detected inherited radiogenic lead in the Palung zircons occurs in perfectly homogeneous, transparent crystals; i.e. this radiogenic (“excess”) lead is not related to the presence of old, microscopically visible, overgrown zircon cores. The minimum ages of the inherited lead components range from about 800 to 1700 m.y. 相似文献
16.
Field evidence indicates that the Trinity peridotite was partially melted during its rise as a part of the upwelling convecting mantle at a spreading center. A SmNd mineral isochron for a plagioclase lherzolite yields an age,T = 427 ± 32 Ma and initialεNd = + 10.4 ? 0.4 which is distinctly higher than that expected for typical depleted mantle at this time. This age is interpreted as the time of crystallization of trapped melt in the plagioclase lherzoliteP-T field. This time of crystallization probably represents the time when the massif was incorporated as a part of the oceanic lithosphere. The SmNd model age of the plagioclase lherzolite totalrock isTCHURNd = 3.4 AE. This suggests that the Trinity peridotite was derived from a mantle that was depleted rather early in earth history. The peridotite contains many generations of pyroxenite dikes and some microgabbro dikes. We report data for two dikes that clearly crosscut the main metamorphic fabric of the peridotite. A microgabbro dike yields a SmNd mineral isochron age ofT = 435 ± 21 Ma andεNd = + 6.7 ? 0.3. A pyroxenite dike yields an initialεNd = + 7.3 ± 0.4. The initialεNd values for the pyroxenite and gabbro dikes are fairly similar to those for the depleted mantle at this time and are distinct from the lherzolite—demonstrating that they are not genetically related. RbSr data do not give any coherent pattern. However, some bounds can be put on initial Sr values ofεSr ? ?21 for the plagioclase lherzolite andεSr ? ?8.7 for the microgabbro dike. It is plausible that the dikes represent cumulates left behind from island arc magmas that rose through the the oceanic lithosphere within the vicinity of a subduction zone. Major and trace elements and SmNd isotopic data indicate a multiple stage history for the Trinity peridotite; a small melt fraction was extracted from an undepleted source ~ 3.4 AE or more ago to produce the proto-lherzolite; a large fraction of melt (~ 12 to 23%) was extracted from the proto-lherzolite to produce the present rock; the lherzolite was then crosscut by dikes from average depleted mantle ~ 0.44 AE ago. The data are compatible with the depleted mantle source being formed very early in earth history. Although most available data indicate that the depleted upper mantle has been relatively well stirred through time, the Trinity data suggest that very ancient Nd isotopic values are preserved and thus chemical and physical heteorgeneities are sometimes preserved in the depleted source of mid-ocean ridge basalts as well as the oceanic lithosphere which they intrude. 相似文献
17.
Sm-Nd data for the Archean granulite and amphibolite facies migmatites of Langøy and Hinnøy in Vesterålen are presented which indicate that their protoliths formed ~2.6 AE ago. Rubidium and U loss during a granulite facies metamorphism at ~1.8 AE caused serious disturbance of total-rock U-Pb and Rb-Sr systems. Therefore these systems do not provide any precise age information for the granulite facies migmatites. For the amphibolite facies migmatites of Vesterålen both SmNd, RbSr and PbPb total-rock systems give model ages of ~2.6 AE. The results on both granulite and amphibolite facies rocks are thus in agreement. Previous interpretations based on PbPb data, which indicated an age of 3.41 AE for the Archean terrane of Vesterålen, are not valid.One SmNd model age from the granulite facies migmatites at Moskenesøy in Lofoten indicates that the protoliths of these migmatites formed ~2.0 AE ago and are thus not related to the Vesterålen migmatites. 相似文献
18.
Ten whole-rock samples from the Tudor Gabbro, Grenville Province, Ontario, Canada have been dated by the KAr method. The ages calculated by the conventional method range from 900 m.y. to 2040 m.y. On an isochron plot, three samples from a sampling site near the northern border of the gabbro lie along a 670-m.y. isochron with an initial40Ar/36Ar ratio of about 17,300 whereas all other samples lie along another 670-m.y. isochron with an initial ratio of about 5000. Although it is not certain yet as to what geological event the isochron age represents, the results clearly demonstrate that the effect of initial argon can be significant even on old samples such as these. 相似文献
19.
《Earth and Planetary Science Letters》1986,78(4):368-378
The Neogene sediments from DSDP site 341 on the Vøring Plateau, Norwegian Sea, contain a thin glauconitic pellet-bearing subunit, which separates underlying pelagic clays from overlying glacial-marine sediments. Oxygen isotope measurements of benthic foraminifera show aδ18O shift of + 1%. during deposition of this subunit, probably a combined effect of a drop in bottom water temperature and a rise in seawaterδ18O. The chronology of this sedimentological and O isotope transition is, however, poorly constrained by fossil evidence.RbSr dating of glauconitic pellets indicates that the lower part of the glauconitic subunit was deposited 11.6 ± 0.2 Ma ago. Further geochronological evidence, derived from the Sr and C isotopic compositions of foraminifera compared with known seawater-time variations, indicates that the lower pelagic clays are early to middle Miocene, deposited at a mean rate of ∼ 15 m/Ma. The glauconitic subunit contains part of the middle Miocene and probably all of the late Miocene in a condensed sequence with a very low mean depositional rate (∼ 0.2 m/Ma). The overlying glacial marine sediments are probably Pliocene, with a high mean rate of deposition, ∼ 45 m/Ma.This is the first application of C, O and Sr isotopic stratigraphy combined with RbSr dating of glauconitic minerals, and it illustrates the applications of this integrated approach in geochronology. 相似文献
20.
《Earth and Planetary Science Letters》1985,74(1):58-68
Graphite occurs as a major rock-forming constituent in pyroxenitic pegmatites near the platiniferous Merensky Reef in the western Bushveld. It is associated with amphibole, biotite, low-K phyllosilicates, chlorite, sulphides and platinum-group minerals (RhAsS-IrAsS). Locally, rocks with up to 80% graphite occur. Chlorine is a significant constituent in both, hydrous silicates (0.1–0.3% Cl) and graphite (0.2–1.9%). Magnetite and quartz also occur with the above association. This facilitates estimation ofT (500–600°C) andfO2 (10−21 to 10−23 bar) during graphite deposition, which took place from COHS fluids at an oxygen fugacity in the vicinity of QMF in equilibrium with maximum H2O mole fraction. The latter accounts for the widespread association of graphite with hydrous silicates. There is evidence for buffering offO2 of the melt by fluid phase; this process may be more widespread than hitherto assumed. COHS fluids are considered instrumental not only in the formation of graphite-rich pegmatites and associated mineralization, but also in the genesis of pothole depressions, and in the general development of stratiform pegmatites (such as the Merensky Reef) in layered igneous complexes. 相似文献