Formation of spectral lines in planetary atmosphere IV. Theoretical evidence for structure of the jovian clouds from spectroscopic observations of methane and hydrogen quadrupole lines

The theory of formation of pressure-broadened methane lines and collision-narrowed hydrogen quadrupole lines in a Jovian atmosphere is studied in detail for a physically realistic model of the planet's lower atmosphere. Only observations of the center-to-limb (CTL) variations of the equivalent width of absorption lines for both of these molecules can identify the structure of the visible cloud layers. Observations of the CTL variation of methane and hydrogen quadrupole lines are the most suitable for studying the Jovian atmosphere. The CTL variations for hydrogen are much greater and more sensitive to variations of the properties of the thin upper tropospheric cloud layer than the corresponding observations of methane lines. A detailed comparison of hydrogen quadrupole with methane lines is made for the same continuum conditions, enabling us to develop a detailed understanding of the formation of the collision-narrowed hydrogen quadrupole lines in a Jovian atmosphere.     

Jupiter: An inhomogeneous atmospheric model analysis of spatial variations of the H2 4-0 S(1) line

An analysis of the structure of the Jovian atmosphere, primarily based on center-to-limb variations (CTLV) of the equivalent width of the hydrogen quadrupole 4-0 S(1) line, is presented. These data require that the atmosphere have regions of both long- and short- scattering mean free paths. Two alternative cloud structures which fit the data are developed. The first is a two-cloud model (TCM) consisting of a thin upper cloud and a lower semi-infinite cloud, with absorbing gas between the clouds and above the upper cloud. The second model is a reflecting-scattering model (RSM), in which a gas layer lies above a haze consisting of scattering particles and absorbing gas. The cloud-scattering phase function in both models must have a strong forward peak. The CTLV data require, however, the presence of a backscattering lobe on the phase function, with the backscattering intensity about 4% of the forward scattering. The decrease in reflectivity of all regions from the visible to the ultraviolet is explained by the presence of dust particles mixed with the gas. Most of the ultraviolet absorption in the atmosphere must occur above the upper cloud layer. Particles with a uniform distribution of radii from 0.0 to 0.1 μm with a complex index of refraction varying as λ^?2.5 are used. The contrast in reflectivity between belts and zones may be explained by the larger concentration of dust in the belts than in the zones. Spatially resolved ultraviolet limb-darkening curves will help to determine the dust distribution of the Jovian atmosphere. The visible methane bands at λλ 6190, 5430, and 4860 Å are analyzed in terms of these models. We derive a methane-to-hydrogen mixing ratio of 2.8 × 10^?3, which is about 4.5 times the value for solar composition.     

Voyager 1 imaging and IRIS observations of Jovian methane absorption and thermal emission: Implications for cloud structure

Images from three filters of the Voyager 1 wide-angle camera were used to measure the continuum reflectivity and spectral gradient near 6000 Å and the 6190-Å band methane/continuum ratio for a variety of cloud features in Jupiter's atmosphere. The dark “barge” features in the North Equatorial Belt have anomalously strong positive continuum spectral gradients suggesting unique composition, probably not elemental sulfur. Methane absorption was shown at unprecedented spatial scales for the Great Red Spot and its immediate environment, for a dark barge feature in the North Equatorial Belt, and for two hot spot and plume regions in the North Equatorial Belt. Some small-scale features, unresolvable at ground-based resolution, show significant enhancement in methane absorption. Any enhancement in methane absorption is conspicuously absent in both hot spot regions with 5-μm brightness temperature 255°K. Methane absorption and 5-μm emission are correlated in the vicinity of the Great Red Spot but are anticorrelated in one of the plume hot spot regions. Methane absorption and simultaneously maps of 5-μm brightness temperature were quantitatively compared to realistic cloud structure models which include multiple scattering at 5 μm as well as in the visible. A curve in parameter space defines the solution to any observed quantity, ranging from a shallow atmosphere and thin NH₃ cloud to a deep atmosphere with a thick ammonia cloud. Without additional constraints, such as center-to-limb information, it is impossible to specify the NH₃ cloud optical depth and pressure of a deeper cloud top independently. Variability in H₂ quadrupole lines was also investigated and it was found that the constancy of the 4-0 S(1)-line equivalent width is consistent with the constancy of the methane 6190-Å band equivalent width at ground-based resolution, but the much greater variability of the 3-0 S(1) line is inconsistent with either the methane band or 4-0 S(1) line. In hot spot regions the 255°K brightness temperature requires a cloud optical depth of about 2 or less at 5 μm in the NH₃ cloud layer. To be consistent with the observed 6190-Å methane absorption in hot spot regions, the NH₃ cloud optical depth in the visible is about 7.5, implying that aerosols in hot spot regions have effective radii near 1 μm or less.     

Electromagnetic radiation outbursts from the collision of P/Shoemaker-Levy 9 comet with Jupiter

The forthcoming collision by debris of P/Shoemaker-Levy 9 comet with Jupiter during the week of July 18, 1994 has generated considerable scientific and public interest. This collision may release an amount of energy ranging from 10²⁵-10³¹ ergs in the Jovian atmosphere. Two possible phenomena associated with this event are described in this Letter to the Editor. The first one is the likely display of deformed Jovian magnetic field lines as the comet interacts with the Jovian magnetosphere. The second one is electromagnetic radiation outbursts during comet explosions over a wide frequency range from radio up to gamma ray emissions. If relativistic electrons with energies up to ~ 1000 MeV could be produced during comet explosions, then synchrotron radiations with frequencies from radio up to infrared range could be detectable. Hard X-rays and gamma rays could be produced by bremsstrahlung and inverse Compton processes. Since one cannot exclude the possible transient presence of relativistic electrons with Lorentz factor 2 × 10⁶, synchrotron radiation component might even be extended into gamma ray frequency range during intermittent short time intervals.     

The near-IR spectrum of Titan modeled with an improved methane line list

We have obtained spatially resolved spectra of Titan in the near-infrared J, H and K bands at a resolving power of ∼5000 using the near-infrared integral field spectrometer (NIFS) on the Gemini North 8 m telescope. Using recent data from the Cassini/Huygens mission on the atmospheric composition and surface and aerosol properties, we develop a multiple-scattering radiative transfer model for the Titan atmosphere. The Titan spectrum at these wavelengths is dominated by absorption due to methane with a series of strong absorption band systems separated by window regions where the surface of Titan can be seen. We use a line-by-line approach to derive the methane absorption coefficients. The methane spectrum is only accurately represented in standard line lists down to ∼2.1 μm. However, by making use of recent laboratory data and modeling of the methane spectrum we are able to construct a new line list that can be used down to 1.3 μm. The new line list allows us to generate spectra that are a good match to the observations at all wavelengths longer than 1.3 μm and allow us to model regions, such as the 1.55 μm window that could not be studied usefully with previous line lists such as HITRAN 2008. We point out the importance of the far-wing line shape of strong methane lines in determining the shape of the methane windows. Line shapes with Lorentzian, and sub-Lorentzian regions are needed to match the shape of the windows, but different shape parameters are needed for the 1.55 μm and 2 μm windows. After the methane lines are modeled our observations are sensitive to additional absorptions, and we use the data in the 1.55 μm region to determine a D/H ratio of 1.77 ± 0.20 × 10⁻⁴, and a CO mixing ratio of 50 ± 11 ppmv. In the 2 μm window we detect absorption features that can be identified with the ν₅ + 3ν₆ and 2ν₃ + 2ν₆ bands of CH₃D.     

Laboratory absorption strengths and line shape parameters in the 4-0, 5-0, and 6-0 vibration bands of HD

Uncertainties in the fundamental line profiles and absorption strengths in HD are among the most important sources of error in the analysis of the spectra of HD in the atmosphere of the outer planets. Measurements of the 4-0, 5-0, and 6-0 vibrational bands of HD, taken at room temperature and a range of densities from 0.3 to 1.7 amagat are reported. High S/N spectra have been obtained at a spectral resolution finer than the natural line widths, allowing analysis of spectral profiles, absorption strengths, and pressure shifts in the HD lines. Line profiles are interpreted in terms of the theoretical Galatry approximation, and the HD pressure-broadening and self-diffusion coefficients are determined as free parameters.     

Limb-darkening scans of Jupiter

An area scanning photometer has been used to obtain photometrically calibrated limb-darkening scans of Jupiter at four wavelengths: 6190, 6300, 7250, and 8200 Å. The first and third of these correspond to methane absorptions and the second and fourth to continuum regions near the 4-0 and 3-0 H₂ quadrupole bands, respectively. Single-scattering albedos have been calculated for several areas on the planet at all four wavelengths assuming a semi-infinite, homogeneous, isotropically scattering atmosphere. The values obtained at the wavelengths of the quadrupole bands range from 0.98 over the NEB to ? 0.99 over the NTrZ and the bright band in the southern hemisphere. The single-scattering albedo values are used to show that the 5μm-emitting equatorial regions of the planet may be relatively clear and the tropical regions relatively cloudy.     

Measurements of methane absorption by the descent imager/spectral radiometer (DISR) during its descent through Titan's atmosphere

New low-temperature methane absorption coefficients pertinent to the Titan environment are presented as derived from the Huygens DISR spectral measurements combined with the in-situ measurements of the methane gas abundance profile measured by the Huygens Gas Chromatograph/Mass Spectrometer (GCMS). The visible and near-infrared spectrometers of the descent imager/spectral radiometer (DISR) instrument on the Huygens probe looked upward and downward covering wavelengths from 480 to 1620 nm at altitudes from 150 km to the surface during the descent to Titan's surface. The measurements at continuum wavelengths were used to determine the vertical distribution, single-scattering albedos, and phase functions of the aerosols. The gas chromatograph/mass spectrometer (GCMS) instrument on the probe measured the methane mixing ratio throughout the descent. The DISR measurements are the first direct measurements of the absorbing properties of methane gas made in the atmosphere of Titan at the pathlengths, pressures, and temperatures that occur there. Here we use the DISR spectral measurements to determine the relative methane absorptions at different wavelengths along the path from the probe to the sun throughout the descent. These transmissions as functions of methane path length are fit by exponential sums and used in a haze radiative transfer model to compare the results to the spectra measured by DISR. We also compare the recent laboratory measurements of methane absorption at low temperatures [Irwin et al., 2006. Improved near-infrared methane band models and k-distribution parameters from 2000 to 9500 cm⁻¹ and implications for interpretation of outer planet spectra. Icarus 181, 309-319] with the DISR measurements. We find that the strong bands formed at low pressures on Titan act as if they have roughly half the absorption predicted by the laboratory measurements, while the weak absorption regions absorb considerably more than suggested by some extrapolations of warm measurements to the cold Titan temperatures. We give factors as a function of wavelength that can be used with the published methane coefficients between 830 and 1620 nm to give agreement with the DISR measurements. We also give exponential sum coefficients for methane absorptions that fit the DISR observations. We find the DISR observations of the weaker methane bands shortward of 830 nm agree with the methane coefficients given by Karkoschka [1994. Spectrophotometry of the jovian planets and Titan at 300- to 1000-nm wavelength: the methane spectrum. Icarus 111, 174-192]. Finally, we discuss the implications of our results for computations of methane absorption in the atmospheres of the outer planets.     

Formation depths of lithium resonance absorption lines in the atmospheres of late-type stars and brown dwarfs

A numerical technique for determining absorption line formation depths in the atmospheres of late-type stars and substellar-mass subdwarfs is proposed. The technique is based on estimating individual absorptions contributed by certain layers of the stellar model atmosphere to the resulting equivalent width of a spectral line. In particular, the proposed technique can be used when considering lithium absorption lines formed at the background of molecular bands. The technique is applied to the formation of lithium lines in stellar atmospheres, specifically, in the atmosphere of the Sun (spectral type G2V) and those of the red giant star in the binary system RS Oph (M2III), the giant carbon star WZ Cas (C6), and the brown dwarf LP944-20 (M9V).     

Is there methane on Mars?

There have been several reports of methane on Mars at the 10-60 ppbv level. Most suggest that methane is both seasonally and latitudinally variable. Here we review why variable methane on Mars is physically and chemically implausible, and then we critically review the published reports. There is no known mechanism for destroying methane chemically on Mars. But if there is one, methane oxidation would deplete the O₂ in Mars’s atmosphere in less than 10,000 years unless balanced by an equally large unknown source of oxidizing power. Physical sequestration does not raise these questions, but adsorption in the regolith or condensation in clathrates ignore competition for adsorption sites or are inconsistent with clathrate stability, respectively. Furthermore, any mechanism that relies on methane’s van der Waals’ attraction is inconsistent with the continued presence of Xe in the atmosphere at the 60 ppbv level. We then use the HITRAN database and transmission calculations to identify and characterize the absorption lines that would be present on Earth or Mars at the wavelengths of the published observations. These reveal strong competing telluric absorption that is most problematic at just those wavelengths where methane’s signature seems most clearly seen from Earth. The competing telluric lines must be removed with models. The best case for martian methane was made for the ¹²CH₄ν₃ R0 and R1 lines seen in blueshift when Mars was approaching Earth in early 2003 (Mumma, M.J., Villanueva, G.L., Novak, R.E., Hewagama, T., Bonev, B.P., DiSanti, M.A., Mandell, A.M., Smith, M.D. [2009]. Science 323, 1041-1045). For these the Doppler shift moves the two martian lines into near coincidence with telluric ¹³CH₄ν₃ R1 and R2 lines that are 10-50× stronger than the inferred martian lines. By contrast, the ¹²CH₄ν₃ R0 and R1 lines when observed in redshift do not contend with telluric ¹³CH₄. For these lines, Mumma et al.’s observations and analyses are consistent with an upper limit on the order of 3 ppbv.     

彗木相撞中的惯性引力波

苏梅克-列维9号彗星(SL9)与木星相撞后，在木星上观测到的以常速度(～450m／s)向外扩展的圆环意味着这是碰撞在木星大气中引起的线性波动．我们选取：非旋转、无粘性、密度分层、不可压缩的木星大气模型，而且木星大气以水平速度U=b az运动；给出初始扰动压力P(r；0)作为碰撞的初始条件，用流体力学方程组求解了彗木相撞中的惯性引力波．结果表明：当木星大气以速度U=U0(～170m／s)运动时，彗星碎片的大部分能量都用来产生内波，同时还得到彗星碎片的撞击深度H与水平相速Vp的关系式．当木星大气以速度为U=b az运动时，木星大气的扰动能量不再是在动能和势能间均分。     

Possible H2staggered+ ultraviolet spectrum of Jupiter

An ultraviolet spectral probe for a hydrogen-rich planetary atmosphere, such as that of Jupiter, is suggested, utilizing discrete lines in the H₂^staggered+ 2pπ_u?1sσ_g electronic transition. For the Jovian atmosphere, the dominant mechanism for exciting H₂⁺ to its 2pπ_u state appears to be photoexcitation, principally through absorption of the solar Lyman-α line. We estimate that the Jovian column emission rate of the H₂⁺ 2pπ_u(ν′ = 2, J′ = 1) →1sσ_g(ν″ = 18,J″ = 0) fluorescent line at 1236.6 Å is if1 photon cmsu-2 secsu-1; i.e., that if1 photon secsu-1 of this radiation would strike a 15-cm diameter mirror in a Jupiter fly-by at an impact parameter of 3 × 10⁵km. The critical role of corrections to the Born-Oppenheimer approximation in the use of an H₂⁺ probe is discussed.     

New determination of monochromatic methane absorption coefficients with regard to the thermal conditions in the atmospheres of giant planets. IV. Jupiter and Saturn

Based on the data on the wavelength dependence of geometrical albedo for the disks of Jupiter and Saturn, we determined the trends in the height variation of the aerosol optical depth in the upper atmospheric layers of these planets, the fractional methane concentration in the Jovian atmosphere (0.00125), and the monochromatic methane absorption coefficients (or the superposition of these coefficients for methane and ammonia) typical of the thermal conditions in the atmospheres of Jupiter and Saturn in the wavelength range from 527 to 956 nm.     

Pressure-induced absorption by H2 in the atmosphere of Jupiter and Saturn

The S(1) line of the pressure-induced fundamental band of H₂ was identified and measured in the spectra of Saturn and Jupiter. This broad line at 4750 cm^?1 lies in a region free from telluric and planetary absorptions. It is about 99% absorbing in the core; the high-frequency wing extends to at least 5100 cm^?1. We compare the obseved line shape to the predictions of both a reflecting-layer model (RLM) and a homogeneous scattering model (HSM). The RLM provides a good fit to the Saturn line profile for temperatures near 150K; the derived base-level density is 0.52 (+0.26, ?0.17) amagat and the H₂ abundance is 25 (+10, ?9) km-amagat, assuming a scale height of 48 km. The Jupiter line profile is fit by both the RLM and HSM, but for widely differing temperatures, neither of which seems probable. The precise fitting of the observed S(1) line profile to computed models depends critically on the determination of the true continuum level; difficulties encountered in finding the continuum, especially for Jupiter, are discussed. Derived RLM densities and abundances for both planets are substantially lower than those derived from RLM analyses of the H₂ quadrupole lines, the 3ν₃ band of CH₄, and from other sources.     

Penetration of solar uv radiation and photodissociation in the Jovian atmosphere

We present computations of the photodissociation coefficients for NH₃, N₂H₄, PH₃, and H₂S in the Jupiter atmosphere. The calculations take into account multiple scattering and absorption using the radiative-transfer method known as δ-Eddington approximation. The atmospheric models include two cloud layers of variable thickness and haze layers above the upper cloud and between the clouds. One of the results of the radiative computations deal with the reflectivity of the Jovian atmosphere as a function of wavelength. A comparison with available data on the albedo of the planet gives some important indications about mixing ratios and distributions of gases and aerosols. The results for the photolysis rates are compared with similar rates obtained by considering either the direct flux or the flux determined by the molecular gas absorption alone. The latter is usually the approximation used in aeronomic models. The results of this comparison show that a considerable difference exists with direct flux photodissociation but significant differences with molecular absorption flux exist only in atmospheric regions where photodissociation is relatively small.     

Line formation in spherical media with partial frequency redistribution

Lines formed in a differentially expanding atmosphere have been calculated by using the angle averaged redistribution functionR _I (Hummer, 1962). We have compared these lines, in a few cases, with those formed by complete redistribution in the observer's frame of reference. We have considered an atmosphere whose ratios of inner to outer radii are 2 and 10, and it is assumed that the gas in the atmosphere is expanding uniformly with a maximum velocity of 3 mean thermal units. We have presented lines formed in spherical symmetry and those obtained by integrating over the apparent disc. Three types of physical situations are considered with a 2-level atom with non-LTE approximation (1) =10^–4, =10^–4, (2) =10^–4, =0 and (3) ==0, where is the probability per scatter that a photon is destroyed by collisional de-excitation, and is the ratioKc/Kl of absorption in the continuum per unit frequency interval to that in the line centre.It is found that there are noticeable differences between the profiles formed by partial redistribution (PRD) and complete redistribution (CRD). The profiles integrated over the stellar disc from the first type of the media are box type with flat top, which are similar to those observed in WC stars and those from the second type of media show emission peaks on red and blue sides with emission on the red side larger than the one on the blue side. The profiles from the third type of media with pure scattering, show some emission on the red side and deep absorption on the blue side. Large geometrical extensions of the atmosphere and higher gas velocities seem to enhance these two effects.     

Radiation chemistry in the Jovian stratosphere: laboratory simulations

Low-pressure continuous-flow laboratory simulations of plasma induced chemistry in H2/He/CH4/NH3 atmospheres show radiation yields of hydrocarbons and nitrogen-containing organic compounds that increase with decreasing pressure in the range 2-200 mbar. Major products of these experiments that have been observed in the Jovian atmosphere are acetylene (C2H2), ethylene (C2H4), ethane (C2H6), hydrogen cyanide (HCN), propane (C3H8), and propyne (C3H4). Major products that have not yet been observed on Jupiter include acetonitrile (CH3CN), methylamine (CH3NH2), propene (C3H6), butane (C4H10), and butene (C4H8). Various other saturated and unsaturated hydrocarbons, as well as other amines and nitriles, are present in these experiments as minor products. We place upper limits of 10(6)-10(9) molecules cm-2 sec-1 on production rates of the major species from auroral chemistry in the Jovian stratosphere, and calculate stratospheric mole fraction contributions. This work shows that auroral processes may account for 10-100% of the total abundances of most observed organic species in the polar regions. Our experiments are consistent with models of Jovian polar stratospheric aerosol haze formation from polymerization of acetylene by secondary ultraviolet processing.     

Interpretation of spatial and temporal variations of hydrogen quadropole absorptions in the Jovian atmosphere observed during the 1972 apparition

During the 1972 apparition of Jupiter, we carried out a patrol of the (3,0) S(1) and (4,0) S(1) quadrupole lines of molecular hydrogen in the equatorial region and in bands bounded by ±15 and ±49° zenographic latitude from the McDonald and Table Mountain Observatories. At the center of the Jovian disk, we found evidence of temporal variability of both lines over the duration of our observing period. We employ a technique which takes into account all radiative transfer processes in an inhomogeneous model of Jupiter's atmosphere, and use it to derive the effective level of formation of the spectral lines and the relative abundance of hydrogen. In this way, we are able to correlate measured changes in the equivalent widths of the hydrogen lines with variations in cloud structure. The effective pressure level at which the (4,0) S(1) line is formed varies in the range 2 ± 0.5 to 1.3 ± 0.2 atm, while for the (3,0) S(1) line, the pressure varies between 1.6 ± 0.5 and 1 ± 0.4 atm. If these variations are interpreted in terms of changes in elevation of the top of a dense lower cloud deck, the elevation apparently varied with an amplitude of 25 km during the observational period.Spatial variations in the strengths of both lines were also found. Both lines are weaker at the east limb than at the center of the disk (15–19%) while the variations toward the west limb are less pronounced (5%). Similar center-to-limb variations were found in the latitude bands bounded by ±15 and ±49°, although the lines were stronger in the northern component at the time of the observations.     

Abundance of organic compounds photochemically produced in the atmospheres of the outer planets

Organic photochemical syntheses in the Jovian atmosphere were simulated by irradiating, at 147 nm, gaseous mixtures of methane and ammonia with varying quantities of hydrogen. An excess of H₂ did not eliminate organic synthesis but did affect the yields quantitatively and qualitatively.