Theoretical interpretation of the 0.7820 μm CO2 band and 0.8226 μm H2O line on Venus

We have analyzed the P6, P8, and P10 lines in the 0.7820 μm CO₂ band of Venus using a scattering model. Our new results compare favorably with previous results from the 1.05 μm CO₂ band. We considered nonabsorbing and absorbing clouds. We found that the anisotropic scattering mean free path for both models at the 0.2atm level is between 0.55 and 0.73km, a range close to the value of 1 km for terrestrial hazes. We used our scattering models to synthesize the 0.8226 μm H₂O line, assuming that the clouds are composed of sulfuric acid drops, and found our nonabsorbing cloud required a sulfuric acid concentration of 82% by weight, while our thicker absorbing cloud required a concentration of 89%. A comparison of the variation of optical depth with height for our cloud models with the variation reported by Prinn (1973, Science182, 1132–1134) showed that, within a factor of 2, the variation for Prinn's thinnest cloud agreed with ours. Whitehill and Hansen (1973, Icarus20, 146–152) have recently confirmed the work of Regas et al. (1973a, J. Quant. Spectry. Radiative Transfer13, 461–463) which showed that two cloud layers are not required to explain the CO₂ phase variation of Venus. Prinn's recent photochemical study of sulfuric acid clouds further supports a single, continuous cloud layer in the line formation region instead of two cloud layers with an extensive clear region between. The single layer model appears more likely because the maximum particle density in Prinn's cloud occurs in the clear region between the two layers in the models of Hunt (1972, J. Quant. Spectry. Radiative Transfer12, 405–419) and Carleton and Traub (1972, Bull. Amer. Astron. Soc.4, 362.).     

First observation of 628 CO2 isotopologue band at 3.3 μm in the atmosphere of Venus by solar occultation from Venus Express

The new ESA Venus Express orbiter is the first mission applying the probing technique of solar and stellar occultation to the atmosphere of Venus, with the SPICAV/SOIR instrument. SOIR is a new type of spectrometer used for solar occultations in the range 2.2-4.3 μm. Thanks to a high spectral resolving power R∼15,000-20,000 (unprecedented in planetary space exploration), a new gaseous absorption band was soon detected in the atmospheric transmission spectra around 2982 cm⁻¹, showing a structure resembling an unresolved Q branch and a number of isolated lines with a regular wave number pattern. This absorption could not be matched to any species contained in HITRAN or GEISA databases, but was found very similar to an absorption pattern observed by a US team in the spectrum of solar light reflected by the ground of Mars [Villanueva, G.L., Mumma, M.J., Novak, R.E., Hewagama, T., 2008. Icarus 195 (1), 34-44]. This team then suggested to us that the absorption was due to an uncatalogued transition of the ¹⁶O¹²C¹⁸O molecule. The possible existence of this band was soon confirmed from theoretical considerations by Perevalov and Tashkun. Some SOIR observations of the atmospheric transmission are presented around 2982 cm⁻¹, and rough calculations of line strengths of the Q branch are produced, based on the isotopic ratio measured earlier in the lower atmosphere of Venus. This discovery emphasizes the role of isotopologues of CO₂ (as well as H₂O and HDO) as important greenhouse gases in the atmosphere of Venus.     

High dispersion observations of Venus during 1972: The CO2 band at 7820Å

Forty-seven well exposed photographic plates of Venus which show the spectrum of the carbon dioxide band at 7820Å were obtained at Table Mountain Observatory in September and October 1972. These spectra showed a semiregular four-day variation in the CO₂ abundance over the disk of the planet (Young et al., 1974). We also find evidence for temporal variations in the rotational temperature of this band and temperature variations over the disk. The two quantities, CO₂ abundance and temperature, do not show any obvious relationship; however, an increase in the temperature usually is accompanied by a decrease in the abundance of CO₂. The average temperature, found from a curve-of-growth analysis assuming a constant CO₂ line width, is 249±1.4K (one standard deviation). This temperature is noticeably higher than the rotational temperature of 242±2K found for this same band in 1967 (Schorn et al., 1969) and of 242±1.2K in 1968–1969 (Young et al., 1971).     

Multiple scattering and the phase variation of equivalent widths for phase functions of typeP(cosθ)=ϖ+ϖ1 P 1(cosθ)+ϖ2 P 2(cosθ)

After computing theH-functions for 21 different phase functions corresponding to various combinations of \(\bar \varpi \) ₁=?₁/?and \(\bar \varpi \) ₂=?₂/?along with 15 values of ?, variations of equivalent widths with phase angle have been obtained for these cases for lines with Lorentz profile with the continuum albedo ? _c =0.99. It is found that: (i) The absolute values of equivalent width at any phase angle are Inversely related to the value of phase function for that angle; (ii) The usual inverse phase effect occurs whenever the phase function has a maximum at α=0 and a dip somewhere between α=0 and α=180; (iii) Whenever the phase function has minima at α=0 and α=180 one obtains an incipient inverse phase effect at large phase angles; and (iv) The total variations are larger for weaker lines.     

Distributions of the Venus 1.27-μm O2 airglow and rotational temperature

Imaging spectroscopic observations of the Venus 1.27-μm O₂ airglow were carried out with ground-based telescopes from 2002 to 2007. Spectral image cubes were taken with the Okayama Astrophysical Observatory/infrared imaging spectrometer (superOASIS), the Gunma Astronomical Observatory/near-infrared camera and NASA's Infrared Telescope Facility/cryogenic echelle spectrograph (CSHELL). The rotational temperature shows weak positive correlation with the airglow intensity. However, there are some regions that have almost same intensities but different temperatures. The intensities tend to decrease from the anti-solar point to the terminator besides local features. These results indicate that there are local strong downward flows superimposed on the subsolar-to-antisolar circulation.     

On the impact of the Yarkovsky effect on Apophis’ orbit

In October 2009, a new set of optical observations of Apophis, a potentially hazardous asteroid, was published. These data have significantly expanded the interval of observations and their total number. In the article we compare the results of refinement of Apophis’ orbit made at the Jet Propulsion Laboratory (JPL, United States), the University of Pisa (Italy), and the Institute of Applied Astronomy (IAA) of the Russian Academy of Sciences with consideration for new observations. New orbits lead to a significant decrease in the probability of Apophis’ collision with the Earth in 2036. As a result of processing a large number of observations of asteroids approaching the Earth and main belt asteroids less than 40 km in size, with a large number of optical and, in many cases, radar observations in different oppositions, one of the authors revealed that additional acceleration affects their motion. This acceleration can be represented by the transversal component A ₂ in the orbital coordinate system. The presence of this acceleration can be interpreted as the Yarkovsky effect. The statistical properties of distribution of A ₂ for asteroids, for which it is determined quite reliably, evidence in favor of this interpretation. The value of additional acceleration for bodies the size of Apophis falls in the range ±10⁻¹³ AU/day². In this paper we have calculated the probability of Apophis colliding with the Earth in 2036 at different values of the transversal component of additional acceleration A ₂. For the resulting points, a plot of the probability of the collision against the A ₂ value has been constructed. At A ₂ = −8.748 × 10⁻¹⁴ AU/day² (and zero values of the radial A ₁ and normal A ₃ components) the nominal solution for Apophis’ orbit on April 13, 2029, is only 90 m from the middle of a “keyhole” 600 m in width, which leads to a collision of Apophis with the Earth in 2036. Since the scattering ellipse in the target plane in 2029 significantly overlaps the keyhole, the probability of collision at the given additional acceleration value is 0.0022. This result has been verified by the Monte Carlo method. Tests of 10000 random sets of orbital elements, which were found taking into account their correlation, have shown that 22 cases have resulted in virtual asteroids colliding with Earth in 2036. A plot of the probability of the collision against the value of A ₂ has been constructed.     

Modelling the atmospheric CO2 10-μm non-thermal emission in Mars and Venus at high spectral resolution

A study of the CO₂ atmospheric emissions at 10-μm in the upper atmospheres of Mars and Venus is performed in order to explain a number of ground-based measurements of these emissions recently taken at very high spectral resolution in both planets. The measurements are normally used to derive atmospheric temperatures and winds, but uncertainties on the actual emission layers were so far a serious drawback for their correct interpretation. The non-LTE models used for Mars and Venus in the present analysis are entirely similar in order to perform consistent comparisons between the two planets. In particular, the same scheme of CO₂ states and ro-vibrational bands are used, with similar assumptions on collisional routes and rate coef?cients, and also the same radiative transfer approximations. The emissions at 10-μm are produced in both atmospheres by the same excitation mechanism: radiative pumping of the CO₂(00⁰1) vibrational state by direct solar absorption(at 4.3 μm) and indirect absorption (at 2.7 μm, followed by collisional quenching). The computed radiances are specially strong in the upper mesosphere and lower thermosphere of the two planets during maximum solar illumination, producing a population inversion in such conditions with the lower states of the bands, the CO₂ (10⁰0) and CO₂(02⁰0). We obtained that other population inversions are also possible, involving higher energy CO₂ states. The larger solar ?ux available on Venus is found to produce larger vibrational populations and stronger emissions than equivalent atmospheric layers on Mars, in agreement with the observations. A number of perturbation studies were used to determine the exact emission altitudes, or weighting function peaks, for usual nadir sounding. The sensitivity of the emission to non-LTE model uncertainties and to atmospheric variations in temperature and CO₂ density is also presented. The dependence with the solar zenith angle and with the emission angle, as obtained with this model, could also be useful for guiding future observations.     

Modeling the atmospheric limb emission of CO2 at 4.3 μm in the terrestrial planets

The MIPAS instrument on board Envisat, in Earth orbit, the PFS and OMEGA instruments on Mars Express, and VIRTIS on board Venus Express are currently providing a dataset of limb measurements of the CO₂ atmospheric fluorescence emission at 4.3‐μm from the upper atmosphere of the three planets. These measurements represent an excellent dataset to perform comparative studies between the terrestrial planets’ upper atmospheres, and also to test our theoretical understanding of these emissions. In order to exploit these datasets, we apply a set of non-local thermodynamic equilibrium (non-LTE) models developed at the IAA/CSIC, in Granada, Spain, to a selection of data. In general, the models can explain the main spectral features of the measurements, and also the altitude and solar zenith angle variations. However, the simulations for Mars and Venus give an incorrect ratio of the emissions at two wavelengths, 4.4 and . In order to explain this deficiency, a revision of the most uncertain non-LTE energy transfer parameters has been performed. The quenching rate of ν₃ quanta of high-energy CO₂ states by CO₂ itself could reduce the model-data discrepancy if increased by a factor 2-4, still within its current uncertainty range. This factor, however, is subject to the uncertainty in the thermal structure. A number of simulations with the non-LTE models were also used to study and compare the role of radiative transfer in this spectral region in the three terrestrial planets. Sensitivity studies of density and temperature are also presented, and they permit an analysis of how the differences between the planets and between the three instruments affect their sounding capabilities.     

Identification of a new band system of isotopic CO2 near 3.3 μm: Implications for remote sensing of biomarker gases on Mars

We present the discovery of a new vibrational band system of isotopic CO₂ (carbon dioxide) near 3.3 μm, with multiple strong P, Q and R lines in the prime spectral region used to search for Mars CH₄ (methane). The band system was discovered on Mars using high-resolution spectrometers (λ/δλ>40,000, CSHELL and NIRSPEC) at telescopes (NASA-IRTF and Keck-2) atop Mauna Kea, HI. The observed line intensities and frequencies agree very well with values predicted by a vibrational band model that we developed using known parameters for the molecular levels involved. Using this model, we synthesized spectra for different observing conditions (from Space and ground-based telescopes) and for different spectral resolving powers (5000 to 40,000). Although the total atmospheric burden on Mars is more than 150 times smaller than on Earth, the greater mixing ratio of CO₂ ensures that its column abundance on Mars is almost 20 times greater than on Earth. Thus, weak telluric CO₂ band systems appear much stronger on Mars. Many molecules of possible biological and geothermal interest have strong signatures at these wavelengths, in particular hydrocarbons owing to their strong ro-vibrational CH stretching modes. For example, the new isotopic CO₂ band-system encompasses lines of CH₄, C₂H₆ (ethane), CH₃OH (methanol) and H₂O (water). Implications for previous and future searches of biomarker gases are presented.     

N2 2P Fluorescence from scattering of N22σg photoelectrons

N₂ 2P fluorescent intensity was monitored as a function of incident photon energy from 40 to 70 eV. A structure was seen near 52.2 eV. This feature is attributed to the scattering of photoelectrons originating from the N₂ 2σ_g molecular orbital with a binding energy of about 37.7 eV. The kinetic energy of these photoelectrons corresponds to the peak of the 2P excitation cross section at 14.5 eV.     

Evidence for the effect of sunspot activity on the El Niño/Southern Oscillation

The El Niño No. 3 area index (5°S∼ 5°N, 150°W∼ 90°W) and yearly sunspot number (SSN) from 1408 to 1978 are used to investigate the influence of solar activity on the El Niño/Southern Oscillation (ENSO), through periodicity analysis, cross wavelet transform (XWT), cross correlation and ensemble empirical mode decomposition (EEMD) analyses. The solar activity period, the Hale period, and the Gleissberg period are determined in the El Niño index time series, but of weak statistical significance. Cross correlation analysis of the index with SSN, and that of its low-frequency components decomposed by EEMD clearly indicate that solar activity may take effect on the ENSO, and such an impact should undergo an accumulation procedure (phase delay). XWT also indicates the existence of the impact. It is found that the index is negatively correlated with SSN when SSN is large during a certain long-term interval, and positively when SSN is small. Strong El Niño is inferred to be taken place in decade(s) to come.     

Observations of Venus water vapor over the disk of Venus: The 1972–1974 data using the H2O lines at 8197 Å and 8176 Å

The Venus water vapor line at 8197.71 Å has been monitored at several positions on the disk of Venus and at phase angles between 21° and 162°. Variations in the abundance have been found with spatial location, phase angle and time. During the 1972–1974 period, the total two-way absorption has varied from less than 1 to 77 μm of water vapor. The dependence on phase angle indicates 20 to 50 μm over the disk between 30° and 110° and small, but detectable amounts present during the rest of the observations. The spatial distribution with respect to the intensity equator is uniform with no location on the disk having systematically a higher or lower abundance. Comparisons made between the water vapor abundandances and the CO₂ abundances determined from near-simultaneous observations of CO₂ bands at the same positions on the disk of Venus show no correlation for the majority of the samples.     

On the role of transition region on the Alfvén wave phase mixing in solar spicules

Alfvénic waves are thought to play an important role in coronal heating and solar wind acceleration. Here we investigate the dissipation of standing Alfvén waves due to phase mixing at the presence of steady flow and sheared magnetic field in the stratified atmosphere of solar spicules. The transition region between chromosphere and corona has also been considered. The initial flow is assumed to be directed along spicule axis, and the equilibrium magnetic field is taken 2-dimensional and divergence-free. It is determined that in contrast to propagating Alfvén waves, standing Alfvén waves dissipate in time rather than in space. Density gradients and sheared magnetic fields can enhance damping due to phase mixing. Damping times deduced from our numerical calculations are in good agreement with spicule lifetimes. Since spicules are short living and transient structures, such a fast dissipation mechanism is needed to transport their energy to the corona.     

On the Study of Spatial Variability of the Composition of the Substance of Mars in Experiments on Gamma-Ray Spectroscopy on Board the Mobile Vehicle using the Method of “Tagged Charged Particles”

Solar System Research - Methods are discussed for studying the variability in space of the substance composition of the surface of Mars in experiments on gamma-ray spectroscopy on board a mobile...     

On the regime of the Earth’s polar motion based on data for the period 1962–2007

The view of the Earth’s polar motion as a completely deterministic process has been called into question in the past decades, because no long-term prediction can be made. At the same time, no fundamental restrictions currently exist in the problem of a long-term prediction of the Earth’s rotation. Determining the boundaries of predictability is related to identifying the regime of the Earth’s polar motion. IERS data for the period 1962–2007 have been used to study the regime of the Earth’s polar motion. Analysis of the plots of polhodes reveals peculiarities in the variations of the pole’s coordinates X and Y in certain intervals along the time axis. The data in the interval from 2003 to 2006 have been analyzed in greatest detail: a model for the Chandler and annual oscillations has been constructed and relations between the parameters of these oscillations have been determined; the shift of the instantaneous pole on the phase plane and the Poincare plane has been investigated. As a result, we have found features inherent in chaotic motion (intermittency) and calculated the period (32 years) of the possible repetitions of such anomalies, as confirmed by our analysis of the plots of polhodes. The intervals where the peculiarities in the motion of the Earth’s instantaneous pole manifest themselves are compared with the intervals of the inflections on the plots of variations in the length of the day (LOD).     

Study on Properties of the k − ω Model for Stellar Convection

For applying the k − ω model proposed by Li to the general stellar environment, it is necessary to study the physical meanings of the parameters in this model, in order to set a limit for the range of their values. It is indicated by the study that the variation of the parameter c^l_μ impacts all the Péclet number, kinetic energy, characteristic timescale and characteristic length of turbulent ?ows. Besides, as the model parameter c^l_μ increases, the damping rate of turbulent kinetic energy in the bottom convective overshoot region can be accelerated evidently. Both the model parameter c^l_μ and the equivalent mixing length parameter α are proportional to the effciency of convective heat transfer in the convection zone, and their logarithms have a linear relation. There is also a linear relation between the logarithms of the model parameter c^l_μ and the damping index θ of turbulent kinetic energy in the convective overshoot region. For the Sun, a group of appropriate model parameters are obtained to be: c^l_μ = 0.004, and α = 1.7.     

A Study of the [OII]λ3727/Hα Flux Ratio of Emission Line Galaxies

With the sample of 10⁵ emission line galaxies selected from the Sloan Digital Sky Survey Data Release 4 (SDSS DR4), we have investigated the relations of the [O_II]λ3727/H_α flux ratio with the dust extinction, the ionization state of interstellar gas and the metal abundance of galaxies. It is found that the dust extinction correction has a significant effect on the [O_II]λ3727/H_α flux ratio. Before and after the dust distinction correction is made, the mean [O_II]λ3727/H_α flux ratios are 0.48 and 0.89, respectively. After the dust extinction is corrected, the dispersion of the distribution of F([O_II]λ3727) as a function of F(H_α) is obviously reduced. The [O_II]λ3727/H_α flux ratio of metal-poor galaxies decreases with the increasing ionization degree of interstellar gas, but this relation does not exist in metal-rich galaxies. Besides, it is found that the [O_II]λ3727/H_α flux ratio is correlated with the metal abundance. When 12 + lg(O/H) > 8.5, the [O_II]λ3727/H_α flux ratio decreases with the increasing metal abundance; for the galaxies of 12 + lg(O/H) > 8.5, the spectral flux ratio correlates positively with the metal abundance. Finally, by using the parameters of gas ionization degree and metal abundances of galaxies, the formulae for calculating the [O_II]λ3727/H_α flux ratios of different types of galaxies are given. With the [O_II]λ3727/H_α flux ratio given by these formulae, the star formation rate can be derived by using the [O_II]λ3727-line flux, for the galaxies of the redshift z > 0.4, such as the large number of galaxies to be observed by the LAMOST telescope.