40Ar‐39Ar chronology of lunar meteorites Northwest Africa 032 and 773

Abstract— The ⁴⁰Ar‐³⁹Ar dating technique has been applied to the lunar meteorites Northwest Africa 032 (NWA 032), an unbrecciated mare basalt, and Northwest Africa 773 (NWA 773), (composed of cumulate and breccia lithologies), to determine the crystallization age and timing of shock events these meteorites may have experienced. Stepped heating analyses of several different samples of NWA 032 gave complex age spectra but indistinguishable total ages with a mean of 2.779 ± 0.014 Gyr. Possible causes of the complex age spectra obtained from NWA 032 include recoil of ³⁹Ar, or the presence of pre‐shock ⁴⁰Ar incorporated into shock‐melt veins. The effects of shock veins were investigated by laser fusion of 20 small samples expected to contain varying proportions of the shock veins. The laser ages show a narrow age distribution between 2.61–2.86 Gyr and a mean of 2.73 ± 0.03 Gyr, identical to the total age of ?2.80 Gyr obtained for the bulk sample. Diffusion calculations based on the stepped heating data indicate that Ar release can be reconciled by release from feldspar (and possibly shock veins) at low temperatures followed by pyroxene at higher temperatures. The exposure age of NWA 032 is 212 ± 11 Myr, and it contains low trapped solar Ar. Stepped heating of cumulate and breccia portions of NWA 773 also give a relatively young age of 2.91 Gyr. The presence of trapped Ar in the breccia makes the age determination of this component less precise, but release of Ar appears to be from the same mineral phase, assumed to be plagioclase, in both lithologies. A marked difference in exposure age between the 2 lithologies also exists, with the breccia having spent 81 Myr longer at the lunar surface; this finding is consistent with the higher trapped Ar content of this lithology. Assuming that 2.80 Gyr and 2.91 Gyr are the crystallization ages of NWA 032 and NWA 773 respectively, these two meteorites are the youngest lunar mare basalts available for study.     

39Ar‐40Ar chronology of R chondrites

Abstract— This study presents the first determinations of ³⁹Ar‐⁴⁰Ar ages of R chondrites for the purpose of understanding the thermal history of the R chondrite parent body. The ³⁹Ar‐⁴⁰Ar ages were determined on whole‐rock samples of four R chondrites: Carlisle Lakes, Rumuruti, Acfer 217, and Pecora Escarpment #91002 (PCA 91002). All samples are breccias except for Carlisle Lakes. The age spectra are complicated by recoil and diffusive loss to various extents. The peak ³⁹Ar‐⁴⁰Ar ages of the four chondrites are 4.35, ?4.47 ± 0.02, 4.30 ± 0.07 Ga, and 4.37 Ga, respectively. These ages are similar to Ar‐Ar ages of relatively unshocked ordinary chondrites (4.52–4.38 Ga) and are older than Ar‐Ar ages of most shocked ordinary chondrites («4.2 Ga). Because the meteorites with the oldest (Rumuruti, ?4.47 Ga) and the youngest (Acfer 217, ?4.30 Ga) ages are both breccias, these ages probably do not record slow cooling within an undisrupted asteroidal parent body. Instead, the process of breccia formation may have differentially reset the ages of the constituent material, or the differences in their age spectra may arise from mixtures of material that had different ages. Two end‐member type situations may be envisioned to explain the age range observed in the R chondrites. The first is if the impact(s) that reset the ages of Acfer 217 and Rumuruti was very early. In this case, the ?170 Ma maximum age difference between these meteorites may have been produced by much deeper burial of Acfer 217 than Rumuruti within an impact‐induced thick regolith layer, or within a rubble pile type parent body following parent body re‐assembly. The second, preferred scenario is if the impact that reset the age of Acfer 217 was much later than that which reset Rumuruti, then Acfer 217 may have cooled more rapidly within a much thinner regolith layer. In either scenario, the oldest age obtained here, from Rumuruti, provides evidence for relatively early (?4.47 Ga) impact events and breccia formation on the R chondrite parent body.     

Geochemistry and 40Ar‐39Ar geochronology of impact‐melt clasts in feldspathic lunar meteorites: Implications for lunar bombardment history

Abstract— We studied 42 impact‐melt clasts from lunar feldspathic regolith breccias MacAlpine Hills (MAC) 88105, Queen Alexandra Range (QUE) 93069, Dar al Gani (DaG) 262, and DaG 400 for texture, chemical composition, and/or chronology. Although the textures are similar to the impactmelt clasts identified in mafic Apollo and Luna samples, the meteorite clasts are chemically distinct from them, having lower Fe, Ti, K, and P, thus representing previously unsampled impacts. The ⁴⁰Ar‐³⁹Ar ages on 31 of the impact melts, the first ages on impact‐melt samples from outside the region of the Apollo and Luna sampling sites, range from ～4 to ～2.5 Ga. We interpret these samples to have been created in at least six, and possibly nine or more, different impact events. One inferred impact event may be consistent with the Apollo impact‐melt rock age cluster at 3.9 Ga, but the meteorite impact‐melt clasts with this age are different in chemistry from the Apollo samples, suggesting that the mechanism responsible for the 3.9 Ga peak in lunar impact‐melt clast ages is a lunar‐wide phenomenon. No meteorite impact melts have ages more than 1s? older than 4.0 Ga. This observation is consistent with, but does not require, a lunar cataclysm.     

Ar‐Ar ages and thermal histories of enstatite meteorites

Abstract– Compared with ordinary chondrites, there is a relative paucity of chronological and other data to define the early thermal histories of enstatite parent bodies. In this study, we report ³⁹Ar‐⁴⁰Ar dating results for five EL chondrites: Khairpur, Pillistfer, Hvittis, Blithfield, and Forrest; five EH chondrites: Parsa, Saint Marks, Indarch, Bethune, and Reckling Peak 80259; three igneous‐textured enstatite meteorites that represent impact melts on enstatite chondrite parent bodies: Zaklodzie, Queen Alexandra Range 97348, and Queen Alexandra Range 97289; and three aubrites, Norton County, Bishopville, and Cumberland Falls Several Ar‐Ar age spectra show unusual ³⁹Ar recoil effects, possibly the result of some of the K residing in unusual sulfide minerals, such as djerfisherite and rodderite, and other age spectra show ⁴⁰Ar diffusion loss. Few additional Ar‐Ar ages for enstatite meteorites are available in the literature. When all available Ar‐Ar data on enstatite meteorites are considered, preferred ages of nine chondrites and one aubrite show a range of 4.50–4.54 Ga, whereas five other meteorites show only lower age limits over 4.35–4.46 Ga. Ar‐Ar ages of several enstatite chondrites are as old or older as the oldest Ar‐Ar ages of ordinary chondrites, which suggests that enstatite chondrites may have derived from somewhat smaller parent bodies, or were metamorphosed to lower temperatures compared to other chondrite types. Many enstatite meteorites are brecciated and/or shocked, and some of the younger Ar‐Ar ages may record these impact events. Although impact heating of ordinary chondrites within the last 1 Ga is relatively common for ordinary chondrites, only Bethune gives any significant evidence for such a young event.     

40Ar‐39Ar ages of H‐chondrite impact melt breccias

Abstract— ⁴⁰Ar‐³⁹Ar analyses of a total of 26 samples from eight shock‐darkened impact melt breccias of H‐chondrite affinity (Gao‐Guenie, LAP 02240, LAP 03922, LAP 031125, LAP 031173, LAP 031308, NWA 2058, and Ourique) are reported. These appear to record impacts ranging in time from 303 ± 56 Ma (Gao‐Guenie) to 4360 ± 120 Ma (Ourique) ago. Three record impacts 300–400 Ma ago, while two others record impacts 3900–4000 Ma ago. Combining these with other impact ages from H chondrites in the literature, it appears that H chondrites record impacts in the first 100 Ma of solar system history, during the era of the “lunar cataclysm” and shortly thereafter (3500–4000 Ma ago), one or more impacts ?300 Ma ago, and perhaps an impact ?500 Ma ago (near the time of the L chondrite parent body disruption). Records of impacts on the H chondrite parent body are rare or absent between the era of planetary accretion and the “lunar cataclysm” (4400‐4050 Ma), during the long stretch between heavy bombardment and recent breakup events (3500‐1000 Ma), or at the time of final breakup into meteorite‐sized bodies (<50 Ma).     

39Ar‐40Ar chronology of the enstatite chondrite parent bodies

Ar‐Ar isochron ages of EL chondrites suggest closure of the K‐Ar system at 4.49 ± 0.01 Ga for EL5 and 6 chondrites, and 4.45 ± 0.01 Ga for EL3 MAC 88136. The high‐temperature release regimes contain a mixture of radiogenic ⁴⁰Ar* and trapped primordial argon (solar or Q‐type) with ⁴⁰Ar/³⁶Ar_TR ~ 0 , which does not affect the ⁴⁰Ar budget. The low‐temperature extractions show evidence of an excess ⁴⁰Ar component. The ⁴⁰Ar/³⁶Ar is 180–270; it is defined by intercept values of isochron regression. Excess ⁴⁰Ar is only detectable in petrologic types >4/5. These lost most of their primordial ³⁶Ar from low‐temperature phases during metamorphism and retrapped excess ⁴⁰Ar. The origin of this excess ⁴⁰Ar component is probably related to metamorphic Ar mobilization, homogenization of primordial and in situ radiogenic Ar, and trapping of Ar by distinct low‐temperature phases. Ar‐Ar ages of EH chondrites are more variable and show clear evidence of a major impact‐induced partial resetting at about 2.2 Ga ago or alternatively, prolonged metamorphic decomposition of major K carrier phases. EH impact melt LAP 02225 displayed the highest Ar‐Ar isochron age of 4.53 ± 0.01 Ga. This age sets a limit of about 25–45 Ma for the age bias between the K‐Ar and U‐Pb decay systems.     

40Ar‐39Ar age determinations of lunar basalt meteorites Asuka 881757, Yamato 793169, Miller Range 05035, La Paz Icefield 02205, Northwest Africa 479, and basaltic breccia Elephant Moraine 96008

Abstract— ⁴⁰Ar‐³⁹Ar data are presented for the unbrecciated lunar basaltic meteorites Asuka (A‐) 881757, Yamato (Y‐) 793169, Miller Range (MIL) 05035, LaPaz Icefield (LAP) 02205, Northwest Africa (NWA) 479 (paired with NWA 032), and basaltic fragmental breccia Elephant Moraine (EET) 96008. Stepped heating ⁴⁰Ar‐³⁹Ar analyses of several bulk fragments of related meteorites A‐881757, Y‐793169 and MIL 05035 give crystallization ages of 3.763 ± 0.046 Ga, 3.811 ± 0.098 Ga and 3.845 ± 0.014 Ga, which are comparable with previous age determinations by Sm‐Nd, U‐Pb Th‐Pb, Pb‐Pb, and Rb‐Sr methods. These three meteorites differ in the degree of secondary ⁴⁰Ar loss with Y‐793169 showing relatively high Ar loss probably during an impact event ?200 Ma ago, lower Ar loss in MIL 05035 and no loss in A‐881757. Bulk and impact melt glass‐bearing samples of LAP 02205 gave similar ages (2.985 ± 0.016 Ga and 2.874 ± 0.056 Ga) and are consistent with ages previously determined using other isotope pairs. The basaltic portion of EET 96008 gives an age of 2.650 ± 0.086 Ga which is considered to be the crystallization age of the basalt in this meteorite. The Ar release for fragmental basaltic breccia EET 96008 shows evidence of an impact event at 631 ± 20 Ma. The crystallization age of 2.721 ± 0.040 Ga determined for NWA 479 is indistinguishable from the weighted mean age obtained from three samples of NWA 032 supporting the proposal that these meteorites are paired. The similarity of ⁴⁰Ar‐³⁹Ar ages with ages determined by other isotopic systems for multiple meteorites suggests that the K‐Ar isotopic system is robust for meteorites that have experienced a significant shock event and not a prolonged heating regime.     

39Ar‐40Ar dating of the Zagami Martian shergottite and implications for magma origin of excess 40Ar

Abstract— The Zagami shergottite experienced a complex, petrogenetic formation history (McCoy et al. 1992, 1999). Like several shergottites, Zagami contains excess ⁴⁰Ar relative to its formation age. To understand the origin of this excess ⁴⁰Ar, we made ³⁹Ar‐⁴⁰Ar analyses on plagioclase and pyroxene minerals from two phases representing different stages in the magma evolution. Surprisingly, all these separates show similar concentrations of excess ⁴⁰Ar, ?1 × 10^?6 cm³/g. We present arguments against this excess ⁴⁰Ar having been introduced from the Martian atmosphere as impact glass. We also present evidence against excess ⁴⁰Ar being a partially degassed residue from a basalt that actually formed ?4 Gyr ago. We utilize our experimental data on Ar diffusion in Zagami and evidence that it was shock‐heated to only ?70 °C, and we assume this heating occurred during an ejection from Mars ?3 Myr ago. With these constraints, thermal considerations necessitates either that its ejected mass was impossibly large, or that its shock‐heating temperature was an order of magnitude higher than that measured. We suggest that this excess ⁴⁰Ar was inherited from the Zagami magma, and that it was introduced into the magma either by degassing of a larger volume of material or by early assimilation of old, K‐rich crustal material. Similar concentrations of excess ⁴⁰Ar in the analyzed separates imply that this magma maintained a relatively constant ⁴⁰Ar concentration throughout its crystallization. This likely occurred through volatile degassing as the magma rose toward the surface and lithostatic pressure was released. These concepts have implications for excess ⁴⁰Ar in other shergottites.     

39Ar‐40Ar “ages” and origin of excess 40Ar in Martian shergottites

Abstract— We report new ³⁹Ar‐⁴⁰Ar measurements on 15 plagioclase, pyroxene, and/or whole rock samples of 8 Martian shergottites. All age spectra suggest ages older than the meteorite formation ages, as defined by Sm‐Nd and Rb‐Sr isochrons. Employing isochron plots, only Los Angeles plagioclase and possibly Northwest Africa (NWA) 3171 plagioclase give ages in agreement with their formation ages. Isochrons for all shergottite samples reveal the presence of trapped Martian ⁴⁰Ar (⁴⁰Ar_xs), which exists in variable amounts in different lattice locations. Some ⁴⁰Ar_xs is uniformly distributed throughout the lattice, resulting in a positive isochron intercept, and other ⁴⁰Ar_xs occurs in association with K‐bearing minerals and increases the isochron slope. These samples demonstrate situations where linear Ar isochrons give false ages that are too old. After subtracting ⁴⁰Ar*that would accumulate by ⁴⁰K decay since meteorite formation and small amounts of terrestrial ⁴⁰Ar, all young age samples give similar ⁴⁰Ar_xs concentrations of ?1–2 × 10^?6cm³/g, but a variation in K content by a factor of ?80. Previously reported NASA Johnson Space Center data for Zagami, Shergotty, Yamato (Y‐) 000097, Y‐793605, and Queen Alexandra Range (QUE) 94201 shergottites show similar concentrations of ⁴⁰Ar_xs to the new meteorite data reported here. Similar ⁴⁰Ar_xs in different minerals and meteorites cannot be explained as arising from Martian atmosphere carried in strongly shocked phases such as melt veins. We invoke the explanation given by Bogard and Park (2008) for Zagami, that this ⁴⁰Ar_xs in shergottites was acquired from the magma. Similarity in ⁴⁰Ar_xs among shergottites may reveal common magma sources and/or similar magma generation and emplacement processes.     

40Ar/39Ar and (U‐Th)/He model age signatures of elusive Mercurian and Venusian meteorites

No meteorites from Mercury and Venus have been conclusively identified so far. In this study, we develop an original approach based on extensive Monte Carlo simulations and diffusion models to explore the radiogenic argon (⁴⁰Ar*) and helium (⁴He*) loss behavior and the range of ⁴⁰Ar/³⁹Ar and (U‐Th)/He age signatures expected for a range of crystals if meteorites from these planets were ever to be found. We show that we can accurately date the crystallization age of a meteorite from both Mercury and Venus using the ⁴⁰Ar/³⁹Ar technique on clinopyroxene (± orthopyroxene) and that its ⁴⁰Ar/³⁹Ar age should match the Pb‐Pb age. At the surface of Mercury, phases like albite and anorthite will exhibit a complete range of ⁴⁰Ar* loss ranging from 0% to 100%, whereas merrillite and apatite will show 100% ⁴He* loss. By measuring the crystal size and diffusion parameters of a series of plagioclase crystals, one can inverse the ⁴⁰Ar* loss value to estimate the maximum temperature experienced by a rock, and narrow down the possible pre‐ejection location of the meteorite at the surface of Mercury. At the surface of Venus, plagioclase and phosphate phases will only record the age of ejection. The (U‐Th)/He systematics of merrillite and apatite will be, respectively, moderately and strongly affected by ⁴He* loss during the transit of the meteorite from its host planet to Earth. Finally, meteorites from Mercury or Venus will each have their own ⁴⁰Ar/³⁹Ar and (U‐Th)/He isotopic age and ³⁸Ar_c cosmic ray exposure age signatures over a series of different crystal types, allowing to unambiguously recognize a meteorite for any of these two planets using radiogenic and cosmogenic noble gases.     

39Ar‐40Ar ages of eucrites and thermal history of asteroid 4 Vesta

Abstract— Eucrite meteorites are igneous rocks that derived from a large asteroid, probably 4 Vesta. Past studies have shown that after most eucrites formed, they underwent metamorphism in temperatures up to ≥800°C. Much later, many were brecciated and heated by large impacts into the parent body surface. The less common basaltic, unbrecciated eucrites also formed near the surface but, presumably, escaped later brecciation, while the cumulate eucrites formed at depths where metamorphism may have persisted for a considerable period. To further understand the complex HED parent body thermal history, we determined new ³⁹Ar‐⁴⁰Ar ages for 9 eucrites classified as basaltic but unbrecciated, 6 eucrites classified as cumulate, and several basaltic‐brecciated eucrites. Precise Ar‐Ar ages of 2 cumulate eucrites (Moama and EET 87520) and 4 unbrecciated eucrites give a tight cluster at 4.48 ± 0.02 Gyr (not including any uncertainties in the flux monitor age). Ar‐Ar ages of 6 additional unbrecciated eucrites are consistent with this age within their relatively larger age uncertainties. By contrast, available literature data on Pb‐Pb isochron ages of 4 cumulate eucrites and 1 unbrecciated eucrite vary over 4.4–4.515 Gyr, and ¹⁴⁷Sm‐¹⁴³Nd isochron ages of 4 cumulate and 3 unbrecciated eucrites vary over 4.41–4.55 Gyr. Similar Ar‐Ar ages for cumulate and unbrecciated eucrites imply that cumulate eucrites do not have a younger formation age than basaltic eucrites, as was previously proposed. We suggest that these cumulate and unbrecciated eucrites resided at a depth where parent body temperatures were sufficiently high to cause the K‐Ar and some other chronometers to remain as open diffusion systems. From the strong clustering of Ar‐Ar ages at ?4.48 Gyr, we propose that these meteorites were excavated from depth in a single large impact event ?4.48 Gyr ago, which quickly cooled the samples and started the K‐Ar chronometer. A large (?460 km) crater postulated to exist on Vesta may be the source of these eucrites and of many smaller asteroids thought to be spectrally or physically associated with Vesta. Some Pb‐Pb and Sm‐Nd ages of cumulate and unbrecciated eucrites are consistent with the Ar‐Ar age of 4.48 Gyr, and the few older Pb‐Pb and Sm‐Nd ages may reflect an isotopic closure before the large cratering event. One cumulate eucrite gives an Ar‐Ar age of 4.25 Gyr; 3 additional cumulate eucrites give Ar‐Ar ages of 3.4–3.7 Gyr; and 2 unbrecciated eucrites give Ar‐Ar ages of ?3.55 Gyr. We attribute these younger ages to a later impact heating. Furthermore, the Ar‐Ar impact‐reset ages of several brecciated eucrites and eucritic clasts in howardites fall within the range of 3.5–4.1 Gyr. Among these, Piplia Kalan, the first eucrite to show evidence for extinct ²⁶Al, was strongly impact heated ?3.5 Gyr ago. When these data are combined with eucrite Ar‐Ar ages in the literature, they confirm that several large impact heating events occurred on Vesta between ?4.1–3.4 Gyr ago. The onset of major impact heating may have occurred at similar times for both Vesta and the moon, but impact heating appears to have persisted for a somewhat later time on Vesta.     

Ar‐Ar and I‐Xe ages and the thermal history of IAB meteorites

Abstract— Studies of several samples of the large Caddo County IAB iron meteorite reveal andesitic material enriched in Si, Na, Al, and Ca, which is essentially unique among meteorites. This material is believed to have formed from a chondritic source by partial melting and to have further segregated by grain coarsening. Such an origin implies extended metamorphism of the IAB parent body. New ³⁹Ar‐⁴⁰Ar ages for silicate from three different Caddo samples are consistent with a common age of 4.50‐4.51 Gyr. Less well‐defined Ar‐Ar degassing ages for inclusions from two other IABs, EET (Elephant Moraine) 83333 and Udei Station, are ?4.32 Gyr, whereas the age for Campo del Cielo varies considerably over about 3.23‐4.56 Gyr. New ¹²⁹I‐¹²⁹Xe ages for Caddo County and EET 83333 are 4557.9 ± 0.1 Myr and 4557–4560 Myr, respectively, relative to an age of 4562.3 Myr for Shallowater. Considering all reported Ar‐Ar degassing ages for IABs and related winonaites, the range is ?4.32‐4.53 Gyr, but several IABs give similar Ar ages of 4.50‐4.52 Gyr. We interpret these older Ar ages to represent cooling after the time of last significant metamorphism on the parent body and the younger ages to represent later ⁴⁰Ar diffusion loss. The older Ar‐Ar ages for IABs are similar to Sm‐Nd and Rb‐Sr isochron ages reported in the literature for Caddo County. Considering the possibility that IAB parent body formation was followed by impact disruption, reassembly, and metamorphism (e.g., Benedix et al. 2000), the Ar‐Ar ages and IAB cooling rates deduced from Ni concentration profiles in IAB metal (Herpfer et al. 1994) are consistent if the time of the postassembly metamorphism was as late as about 4.53 Gyr ago. However, I‐Xe ages reported for some IABs define much older ages of about 4558–4566 Myr, which cannot easily be reconciled with the much younger Ar‐Ar and Sm‐Nd ages. An explanation for the difference in radiometric ages of IABs may reside in combinations of the following: a) I‐Xe ages have very high closure temperatures and were not reset during metamorphism about 4.53 Gyr ago; b) a bias exists in the ⁴⁰K decay constants which makes these Ar‐Ar ages approximately 30 Myr too young; c) the reported Sm‐Nd and Rb‐Sr ages for Caddo are in error by amounts equal to or exceeding their reported 2‐sigma uncertainties; and d) about 30 Myr after the initial heating that produced differentiation of Caddo silicate and mixing of silicate and metal, a mild metamorphism of the IAB parent body reset the Ar‐Ar ages.     

The bombardment history of the Moon as recorded by 40Ar‐39Ar chronology

New petrography and ⁴⁰Ar‐³⁹Ar ages have been obtained for 1–3 mm sized rock fragments from Apollo 16 Station 13 soil 63503 (North Ray crater ejecta) and chips from three rocks collected by Apollo 16 and Apollo 17 missions. Selection of these samples was aimed at the old ⁴⁰Ar‐³⁹Ar ages to understand the early history of the lunar magnetic field and impact flux. Fifteen samples were studied including crustal material, polymict feldspathic fragmental breccias, and impact melts. The impact ages obtained range between approximately 3.3 and 4.3 billion years (Ga). Polymict fragmental breccia 63503,1 exhibits the lowest signs of recrystallization observed and a probable old relic age of 4.547 ± 0.027. The plateau age of 4.293 ± 0.044 Ga obtained for impact melt rock 63503,13 represents the oldest known age for such a lithology. Possibly, this age represents the minimum age for the South Pole‐Aitken (SPA) Basin. In agreement with literature data, these results show that impact ages >3.9 Ga are found in lunar rocks, especially within soil 63503. Impact exhumation of deep‐seated warm crustal material onto the lunar surface is considered to explain the common 4.2 Ga ages obtained for weakly shocked samples from soil 63503 and Apollo 17. This would directly imply that one or more basin‐forming events occurred at that time. Some rock fragments showing none to limited petrologic features indicate thermal annealing. These rocks may have lost Ar while resident within the hot‐ejecta of a large basin. Concurrent with previous studies, these results lead us to advocate for a complex impact flux in the inner solar system during the initial approximately 1.3 Ga.     

40Ar‐39Ar studies of whole rock nakhlites: Evidence for the timing of formation and aqueous alteration on Mars

Abstract— 20–25 mg whole rock samples of the nakhlites Lafayette and Nakhla have been analyzed via the ⁴⁰Ar‐³⁹Ar technique, in part to verify their formation ages, but primarily, in an attempt to determine the timing of aqueous alteration in these martian meteorites. As in previous studies, plateaus in apparent age are observed at about 1300 Ma (1322 ± 10 for Lafayette, 1332 ± 10 and 1323 ± 11 for Nakhla), presumably corresponding to crystallization ages. The plateaus are not entirely flat, perhaps reflecting the effects of recoil during creation of ³⁹Ar in the nuclear irradiation. The first 5–20% of the K‐derived Ar released from all three samples give apparent ages <1300 Ma. Coupled with the fact that chronometric isotopic studies of nakhlites typically show some disturbance, we believe the low temperature pattern represents more recent (than 1300 Ma) formation of martian aqueous alteration products such as iddingsite. No low temperature plateaus are observed. This is consistent with petrographic evidence for multiple formation events, although the lack of low temperature plateaus is far from conclusive. On the other hand, if there was a single time of alteration, we believe that it will be difficult, if not impossible, to determine it using the K‐Ar system.     

Shocked meteorites: Argon-40-argon-39 evidence for multiple impacts

Abstract— To contribute to the understanding of the impact history of asteroids, we performed a high-resolution ⁴⁰Ar-³⁹Ar study of ten moderately to highly shocked chondrites, which we selected according to the shock classification given by Stöffler et al. (1991). Two recent shocked chondrite falls and two highly shocked eucrites completed our sample suite. When possible, we separated impact melt from host rock for separate analysis. In total, we studied 28 samples from 14 meteorites. In some cases, atmospheric Ar that we associate with terrestrial weathering was identified and corrected for. The ages we obtained range between ～100 Ma and ～4.1 Ga and are clearly distinct from primordial ages that correspond to solar system formation. We reproduced the previously reported cluster of L-chondrite ages, ～500 Ma. The most prominent result of our study is that, in the case of chondrites, melts generally are older than host rocks or melt-embedded unmolten rocks. To solve this apparent paradox, we propose that the melt-forming event, which was the most severe shock episode in the history of these meteorites, has not been the only occasion affecting their K-Ar systems. At least one later impact metamorphism must have occured. The response of the K-Ar clock to this second event was more severe in the host rock than in the previously (in the first event) generated melt veins and pockets because of different Ar retention rates. Hence, impact metamorphism on meteorite parent bodies indeed was a multistage process extending in time over billions of years.     

L‐chondrite asteroid breakup tied to Ordovician meteorite shower by multiple isochron 40Ar‐39 Ar dating

Abstract— Radiochronometry of L chondritic meteorites yields a rough age estimate for a major collision in the asteroid belt about 500 Myr ago. Fossil meteorites from Sweden indicate a highly increased influx of extraterrestrial matter in the Middle Ordovician ～480 Myr ago. An association with the L‐chondrite parent body event was suggested, but a definite link is precluded by the lack of more precise radiometric ages. Suggested ages range between 450 ± 30 Myr and 520 ± 60 Myr, and can neither convincingly prove a single breakup event, nor constrain the delivery times of meteorites from the asteroid belt to Earth. Here we report the discovery of multiple ⁴⁰Ar‐³⁹Ar isochrons in shocked L chondrites, particularly the regolith breccia Ghubara, that allow the separation of radiogenic argon from multiple excess argon components. This approach, applied to several L chondrites, yields an improved age value that indicates a single asteroid breakup event at 470 ± 6 Myr, fully consistent with a refined age estimate of the Middle Ordovician meteorite shower at 467.3 ± 1.6 Myr (according to A Geologic Time Scale 2004). Our results link these fossil meteorites directly to the L‐chondrite asteroid destruction, rapidly transferred from the asteroid belt. The increased terrestrial meteorite influx most likely involved larger projectiles that contributed to an increase in the terrestrial cratering rate, which implies severe environmental stress.     

The L3–6 chondritic regolith breccia Northwest Africa (NWA) 869: (I) Petrology,chemistry, oxygen isotopes,and Ar‐Ar age determinations

Abstract– Northwest Africa (NWA) 869 consists of thousands of individual stones with an estimated total weight of about 7 metric tons. It is an L3–6 chondrite and probably represents the largest sample of the rare regolith breccias from the L–chondrite asteroid. It contains unequilibrated and equilibrated chondrite clasts, some of which display shock‐darkening. Impact melt rocks (IMRs), both clast‐free and clast‐poor, are strongly depleted in Fe,Ni metal, and sulfides. An unequilibrated microbreccia, two different light inclusions and two different SiO₂‐bearing objects were found. Although the matrix of this breccia appears partly clastic, it is not a simple mixture of fine‐grained debris formed from the above lithologies, but mainly represents an additional specific lithology of low petrologic type. We speculate that this material stems from a region of the parent body that was only weakly consolidated. One IMR clast and one SiO₂‐bearing object show Δ¹⁷O values similar to bulk NWA 869, suggesting that both are related to the host rock. In contrast, one light inclusion and one IMR clast appear to be unrelated to NWA 869, suggesting that the IMR clast is contaminated with impactor material. ⁴⁰Ar‐³⁹Ar analyses of a type 4 chondrite clast yield a plateau age of 4402 ± 7 Ma, which is interpreted to be the result of impact heating. Other impact events are recorded by an IMR clast at 1790 ± 36 Ma and a shock‐darkened clast at 2216 ± 40 Ma, demonstrating that NWA 869 escaped major reset in the course of the event at approximately 470 Ma that affected many L–chondrites.     

40Ar‐39Ar and cosmic‐ray exposure ages of nakhlites—Nakhla,Lafayette, Governador Valadares—and Chassigny

Abstract– We present ⁴⁰Ar‐³⁹Ar dating results of handpicked mineral separates and whole‐rock samples of Nakhla, Lafayette, and Chassigny. Our data on Nakhla and Lafayette and recently reported ages for some nakhlites and Chassigny ( Misawa et al. 2006 ; Park et al. 2009 ) point to formation ages of approximately 1.4 Ga rather than 1.3 Ga that is consistent with previous suggestions of close‐in‐time formation of nakhlites and Chassigny. In Lafayette mesostasis, we detected a secondary degassing event at approximately 1.1 Ga, which is not related to iddingsite formation. It may have been caused by a medium‐grade thermal event resetting the mesostasis age but not influencing the K‐Ar system of magmatic inclusions and the original igneous texture of this rock. Cosmic‐ray exposure ages for these meteorites and for Governador Valadares were calculated from bulk rock concentrations of cosmogenic nuclides ³He, ²¹Ne, and ³⁸Ar. Individual results are similar to literature data. The considerable scatter of T₃, T₂₁, and T₃₈ ages is due to systematic uncertainties related to bulk rock and target element chemistry, production rates, and shielding effects. This hampers efforts to better constrain the hypothesis of a single ejection event for all nakhlites and Chassigny from a confined Martian surface terrain ( Eugster 2003 ; Garrison and Bogard 2005 ). Cosmic‐ray exposure ages from stepwise release age spectra using ³⁸Ar and neutron induced ³⁷Ar from Ca in irradiated samples can eliminate errors induced by bulk chemistry on production rates, although not from shielding conditions.     

A Middle‐Late Triassic 40Ar/39Ar age for the Paasselkä impact structure (SE Finland)

Abstract– ⁴⁰Ar/³⁹Ar dating of recrystallized feldspar glass particles separated from clast‐rich impact melt rocks from the approximately 10 km Paasselkä impact structure (SE Finland) yielded a Middle to Late Triassic (Ladinian‐Karnian) pseudo‐plateau age of 228.7 ± 3.0 (3.4) Ma (2σ). This new age makes Paasselkä the first known Triassic impact structure dated by isotopic methods on the Baltic Shield. The new Paasselkä impact age is, within uncertainty, coeval with isotopic ages recently obtained for the Lake Saint Martin impact structure in Canada, indicating a new Middle to Late Triassic impact crater population on Earth. The comparatively small crater size, however, suggests no relationship between the Paasselkä impact and a postulated extinction event at the Middle/Late Triassic boundary.     

40Ar/39Ar dating and cosmic‐ray exposure time of desert meteorites: Dhofar 300 and Dhofar 007 eucrites and anomalous achondrite NWA 011

Abstract— We performed high‐resolution ⁴⁰Ar‐³⁹Ar dating of mineral separates and whole‐rock samples from the desert meteorites Dhofar 300, Dhofar 007, and Northwest Africa (NWA) 011. The chronological information of all samples is dominated by plagioclase of varying grain size. The last total reset age of the eucrites Dhofar 300 and Dhofar 007 is 3.9 ± 0.1 Ga, coeval with the intense cratering period on the Moon. Some large plagioclase grains of Dhofar 007 possibly inherited Ar from a 4.5 Ga event characteristic for other cumulate eucrites. Due to disturbances of the age spectrum of NWA 011, only an estimate of 3.2–3.9 Ga can be given for its last total reset age. Secondary events causing partial ⁴⁰Ar loss ≤3.4 Ga ago are indicated by all age spectra. Furthermore, Ar extractions from distinct low temperature phases define apparent isochrons for all samples. These isochron ages are chronologically irrelevant and most probably caused by desert alterations, in which radiogenic ⁴⁰Ar and K from the meteorite and occasionally K induced by weathering are mixed, accompanied by incorporation of atmospheric Ar. Additional uptake of atmospheric Ar by the alteration phase(s) was observed during mineral separation (i.e., crushing and cleaning in ultrasonic baths). Consistent cosmic‐ray exposure ages were obtained from plagioclase and pyroxene exposure age spectra of Dhofar 300 (25 ± 1 Ma) and Dhofar 007 (13 ± 1 Ma) using the mineral's specific target element chemistry and corresponding ³⁸Ar production rates.