Effect of transect location,transect spacing and interpolation methods on river bathymetry accuracy

Digital elevation models (DEMs) of river channel bathymetries are developed by interpolating elevations between data collected at discrete points or along transects. The accuracy of interpolated bathymetries depends on measurement error, the density and distribution of point data, and the interpolation method. Whereas point measurement errors can be minimized by selecting the most efficient equipment, the effect of data density and interpolation method on river bathymetry is relatively unknown. Thus, this study focuses on transect‐based collection methods and investigates the effects of transect location, the spacing between transects, and interpolation methods on the accuracy of interpolated bathymetry. This is accomplished by comparing four control bathymetries generated from accurate and high resolution, sub‐meter scale data to bathymetries interpolated from transect data extracted from the control bathymetries using two transect locating methods and four interpolation methods. The transect locating methods are a morphologically‐spaced and an equally‐spaced model. The four interpolation methods are Ordinary Kriging, Delaunay Triangulation, and Simple Linear, which are applied in curvilinear coordinates (Delaunay Triangulation is also applied in Cartesian coordinates), and Natural Neighbor only in Cartesian Coordinates. The bathymetric data were obtained from morphologically simple and complex reaches of a large (average bankfull width = 90 m) and a small (average bankfull width = 17 m) river. The accuracy of the developed DEMs is assessed using statistical analysis of the differences between the control and interpolated bathymetries and hydraulic parameters assessed from bankfull water surface elevations. Results indicate that DEM accuracy is not influenced by the choice of transect location method (with same averaged cross‐section spacing) or a specific interpolation method, but rather by the coordinate system for which the interpolation method is applied and the spacing between transects. They also show negligible differences between the mean depths and surface areas calculated from bathymetries with dense or coarse spacing. Copyright © 2016 John Wiley & Sons, Ltd.     

Interactions between freshwater input, light, and phytoplankton dynamics on the Louisiana continental shelf

We examined the effects of freshwater flow and light availability on phytoplankton biomass and production along the Louisiana continental shelf in the region characterized by persistent spring–summer stratification and widespread summer hypoxia. Data were collected on 7 cruises from 2005 to 2007, and spatially-averaged estimates of phytoplankton and light variables were calculated for the study area using Voronoi polygon normalization. Shelf-wide phytoplankton production ranged from 0.47 to 1.75 mg C m⁻² d⁻¹ across the 7 cruises. Shelf-wide average light attenuation (k_d) ranged from 0.19–1.01 m⁻¹ and strongly covaried with freshwater discharge from the Mississippi and Atchafalaya Rivers (R²=0.67). Interestingly, we observed that the euphotic zone (as defined by the 1% light depth) extended well below the pycnocline and to the bottom across much of the shelf. Shelf-wide average chlorophyll a (chl a) concentrations ranged from 1.4 to 5.9 mg m⁻³ and, similar to k_d, covaried with river discharge (R²=0.83). Also, chl a concentrations were significantly higher in plume versus non-plume regions of the shelf. When integrated through the water-column, shelf-wide average chl a ranged from 26.3 to 47.6 mg m⁻², but did not covary with river discharge, nor were plume versus non-plume averages statistically different. The high integrated chl a in the non-plume waters resulted from frequent sub-pycnocline chl a maxima. Phytoplankton production rates were highest in the vicinity of the Mississippi River bird's foot delta, but as with integrated chl a were not statistically different in plume versus non-plume waters across the rest of the shelf. Based on the vertical distribution of light and chl a, a substantial fraction of phytoplankton production occurred below the pycnocline, averaging from 25% to 50% among cruises. These results suggest that freshwater and nutrient inputs regulate shelf-wide k_d and, consequently, the vertical distribution of primary production. The substantial below-pycnocline primary production we observed has not been previously quantified for this region, but has important implications about the formation and persistence of hypoxia on the Louisiana continental shelf.     

Evaluation of factors controlling smectite transformation and fluid production in subduction zones: Application to the Nankai Trough

Abstract The transformation of smectite‐group clay minerals to illite has garnered considerable interest as a potentially important process affecting both the mechanical and hydrologic behavior of subduction zones. Illitization can generate fluid overpressure by release of bound water, and the mineralogical change and associated cementation may increase intrinsic frictional strength while decreasing the sliding stability of faults. Released bound water also contributes to pore water freshening observed in boreholes at numerous margins. Here the authors combine data from Ocean Drilling Program drill sites along two transects at the Nankai subduction zone with numerical models of smectite transformation, to (i) quantify the distribution of smectite transformation and fluid production downdip of the trench; and (ii) evaluate its hydrologic and mechanical implications. High heat flow (ca 180 mW/m²) along the axis of the Kinan Seamount Chain (Muroto transect) initiates clay mineral transformation outboard of the trench, whereas lower heat flow (70–120 mW/m²) 100 km to the SW (Ashizuri transect) results in negligible presubduction diagenesis. As a result, considerably more bound fluid is subducted along the Ashizuri transect; simulated peak fluid sources down‐dip of the trench are considerably higher than for the Muroto transect (ca 1.2–1.3 × 10^?14/s vs ca 6 × 10^?15/s), and are shifted ca 10 km further from the trench. More generally, sensitivity analysis illustrates that heat flow, taper angle, incoming sediment thickness, and plate convergence rate all systematically affect reaction progress and the distribution of bound water release down‐dip of the trench. These shifts in the loci and volume of fluid release are important for constraining fluid flow pathways, and provide insight into the links between clay transformation and fault mechanics.     

Compound‐Specific Isotope Analyses to Assess TCE Biodegradation in a Fractured Dolomitic Aquifer

The potential for trichloroethene (TCE) biodegradation in a fractured dolomite aquifer at a former chemical disposal site in Smithville, Ontario, Canada, is assessed using chemical analysis and TCE and cis‐DCE compound‐specific isotope analysis of carbon and chlorine collected over a 16‐month period. Groundwater redox conditions change from suboxic to much more reducing environments within and around the plume, indicating that oxidation of organic contaminants and degradation products is occurring at the study site. TCE and cis‐DCE were observed in 13 of 14 wells sampled. VC, ethene, and/or ethane were also observed in ten wells, indicating that partial/full dechlorination has occurred. Chlorine isotopic values (δ³⁷Cl) range between 1.39 to 4.69‰ SMOC for TCE, and 3.57 to 13.86‰ SMOC for cis‐DCE. Carbon isotopic values range between ?28.9 and ?20.7‰ VPDB for TCE, and ?26.5 and ?11.8‰ VPDB for cis‐DCE. In most wells, isotopic values remained steady over the 15‐month study. Isotopic enrichment from TCE to cis‐DCE varied between 0 and 13‰ for carbon and 1 and 4‰ for chlorine. Calculated chlorine‐carbon isotopic enrichment ratios (?_Cl/?_C) were 0.18 for TCE and 0.69 for cis‐DCE. Combined, isotopic and chemical data indicate very little dechlorination is occurring near the source zone, but suggest bacterially mediated degradation is occurring closer to the edges of the plume.     

滆湖水体光学性质初步研究

基于2009年7月至2010年6月滆湖全湖15个采样点的水体光学参数及相关水质理化因子数据,分析滆湖水体周年光合有效辐射(PAR)衰减特性,以期为滆湖沉水植物生态修复提供相关水体光学资料.结果表明,滆湖水体PAR衰减系数(Kd)周年变化范围为1.32～17.42 m-1.秋季Kd相对最小,平均值为2.35 m-1,变化范围为1.32 ～3.70 m-1;夏季Kd相对最大,平均值为6.23 m-1,变化范围为3.68～17.42 m-1.春、秋、冬季,滆湖水体真光层平均深度均满足沉水植物的生长需求,而在夏季滆湖水体真光层平均深度仅为0.84m,小于全湖平均水深(1.20 m),因此夏季PAR是限制沉水植物恢复的因子之一.滆湖水体Kd与透明度(SD)在秋、冬季的关系为:Kd =2.089 +0.705/SD.叶绿素a浓度和悬浮物浓度是影响滆湖水体Kd的重要因子之一.     

Using a transient infiltrometric technique for intensively sampling field‐saturated hydraulic conductivity of a clay soil in two runoff plots

The point measurement of soil properties allows to explain and simulate plot scale hydrological processes. An intensive sampling was carried out at the surface of an unsaturated clay soil to measure, on two adjacent plots of 4 × 11 m² and two different dates (May 2007 and February–March 2008), dry soil bulk density, ρ_b, and antecedent soil water content, θ_i, at 88 points. Field‐saturated soil hydraulic conductivity, K_fs, was also measured at 176 points by the transient Simplified Falling Head technique to determine the soil water permeability characteristics at the beginning of a possible rainfall event yielding measurable runoff. The ρ_b values did not differ significantly between the two dates, but wetter soil conditions (by 31%) and lower conductivities (1.95 times) were detected on the second date as compared with the first one. Significantly higher (by a factor of 1.8) K_fs values were obtained with the 0.30‐m‐diameter ring compared with the 0.15‐m‐diameter ring. A high K_fs (> 100 mm h^?1) was generally obtained for low θ_i values (< 0.3 m³m^?3), whereas a high θ_i yielded an increased percentage of low K_fs data (1–100 mm h^?1). The median of K_fs for each plot/sampling date combination was not lower than 600 mm h^?1, and rainfall intensities rarely exceeded 100 mm h^?1 at the site. The occurrence of runoff at the base of the plot needs a substantial reduction of the surface soil permeability characteristics during the event, probably promoted by a higher water content than the one of this investigation (saturation degree = 0.44–0.62) and some soil compaction due to rainfall impact. An intensive soil sampling reduces the risk of an erroneous interpretation of hydrological processes. In an unstable clay soil, changes in K_fs during the event seem to have a noticeable effect on runoff generation, and they should be considered for modeling hydrological processes. Copyright © 2012 John Wiley & Sons, Ltd.     

Surface area, porosity and water adsorption properties of fine volcanic ash particles

Our understanding on how ash particles in volcanic plumes react with coexisting gases and aerosols is still rudimentary, despite the importance of these reactions in influencing the chemistry and dynamics of a plume. In this study, six samples of fine ash (<100 m) from different volcanoes were measured for their specific surface area, a_s, porosity and water adsorption properties with the aim to provide insights into the capacity of silicate ash particles to react with gases, including water vapour. To do so, we performed high-resolution nitrogen and water vapour adsorption/desorption experiments at 77 K and 303 K, respectively. The nitrogen data indicated a_s values in the range 1.1–2.1 m²/g, except in one case where a a_s of 10 m²/g was measured. This high value is attributed to incorporation of hydrothermal phases, such as clay minerals, in the ash surface composition. The data also revealed that the ash samples are essentially non-porous, or have a porosity dominated by macropores with widths >500 Å. All the specimens had similar pore size distributions, with a small peak centered around 50 Å. These findings suggest that fine ash particles have relatively undifferentiated surface textures, irrespective of the chemical composition and eruption type. Adsorption isotherms for water vapour revealed that the capacity of the ash samples for water adsorption is systematically larger than predicted from the nitrogen adsorption a_s values. Enhanced reactivity of the ash surface towards water may result from (i) hydration of bulk ash constituents; (ii) hydration of surface compounds; and/or (iii) hydroxylation of the surface of the ash. The later mechanism may lead to irreversible retention of water. Based on these experiments, we predict that volcanic ash is covered by a complete monolayer of water under ambient atmospheric conditions. In addition, capillary condensation within ash pores should allow for deposition of condensed water on to ash particles before water reaches saturation in the plume. The total mass of water vapour retained by 1 g of fine ash at 0.95 relative water vapour pressure is calculated to be ~10^–2 g. Some volcanic implications of this study are discussed.Editorial responsibility: J. Gilbert     

Visual characterization technique for gravel‐cobble river bed surface sediments; validation and environmental applications Contribution to the programme of CIRSA (Centre Interuniversitaire de Recherche sur le Saumon Atlantique)

This paper presents an evaluation of the feasibility and the reliability of a visual characterization technique for gravel–cobble river bed surface substrate. Based on principal axis regressions, using phi scale (ϕ), comparisons of visual estimation and grid sampling techniques show that useful predictive relations (R² = 0·78–0·88) exist between visual estimates of the surface d₁₆, d₅₀ and d₈₄ and estimates obtained for the same percentiles with the grid sampling technique. Comparisons of visual estimation and the surface‐bulk sampling technique also indicate a predictive relation (R² = 0·70) between the d₅₀ of the two methods. Trained operators can visually estimate gravel–cobble bed surface d₁₆ to uncertainties of 41 per cent, d₅₀ to 15 per cent and d₈₄ to 11 per cent (for example, there is a 5·5 mm error on a d₈₄ size of 50 mm). Furthermore, evidence shows that if operators are properly trained, a calibration relation for each percentile can be applied independently of operators. This visual characterization allows effective detailed mapping of spatial patterns in substrate size distribution along extensive reaches of gravel‐bed rivers. The technique can be very useful in creating terrain models for various geomorphological, hydrological and biological applications such as the determination of entrainment thresholds, hydraulic roughness and substrate suitability for benthic insects or salmonid habitat. Copyright © 2001 John Wiley & Sons, Ltd.     

Carbonate sedimentation in seagrass beds on Ishigaki‐jima,Ryukyu Islands,southwestern Japan

In order to investigate biota and sedimentary facies, and to delineate processes of carbonate sedimentation in seagrass beds, we conducted sedimentological investigations along three onshore–offshore transects at two sites (Nagura and Yoshihara) on Ishigaki‐jima, Ryukyu Islands. Along the transects, the seagrass beds extended seaward 20–40 m from shore, and their widths parallel to the shore ranged from 60 to >110 m. The seagrass was dominated by Thalassia hemprichii, Cymodocea rotundata and subordinate C. serrulata. Seasonal changes in seagrass coverage were evident, with mean coverage relatively higher in summer and fall (July and October) than in winter and spring (January and April). The surface sediment throughout the seagrass beds was dominated by medium to very coarse sand‐sized bioclasts displaying grainstone/packstone fabrics. Bioclasts were dominated by corals and coralline algae, with lesser benthic foraminifers, mollusks, echinoids, and Halimeda. The grainstone/packstone was underlain by gravelly sediment with coral clasts, showing a rudstone fabric, at the Nagura Site. The lower part of the core sediment was blackened, indicating a reducing environment. Two dates of corals collected at the Nagura and Yoshihara sites (24.5 cm and 16.5 cm below the sea bottom) were 2781–2306 and 4374–3805 cal BP (2σ age range), respectively, suggesting extremely low sedimentation rates (<0.1 mm/year). Sediment influx was higher during July–January than during January–July. The relatively large influx during summer and fall is caused by massive sediment transport during typhoons and storms. The total sediment influx (i.e., suspension‐load sediment transportation) is 74–96 kg CaCO₃/m²/year at the Nagura Site and 21–57 kg CaCO₃/m²/year at the Yoshihara Site. Sediment influx was significantly greater in the seagrass beds than in surrounding areas, providing supporting evidence for an sediment trapping function of seagrass beds. Our data indicate that seagrass beds in the Ryukyu Islands are characterized by high sediment fluxes and extremely low sedimentation rates.     

Cone Penetrometer Tests and HydroPunch® Sampling: A Screening Technique for Plume Definition

Cone penetrometer tests and HydroPunch® sampling were used to define the extent of volatile organic compounds in ground water. The investigation indicated that the combination of these techniques is effective for obtaining ground water samples for preliminary plume definition. HydroPunch samples can be collected in unconsolidated sediments and the analytical results obtained from these samples are comparable to those obtained from adjacent monitoring wells. This sampling method is a rapid and cost-effective screening technique for characterizing the extent of contaminant plumes in soft sediment environments. Use of this screening technique allowed monitoring wells to be located at the plume boundary, thereby reducing the number of wells installed and the overall cost of the plume definition program.     

Small scale turbulent diffusion determined with underwater flow visualization

Dye plumes were generated at three depths in the seasonal thermocline between 7 and 11 m, 22 km south of Key West on 21 August 1980 and photographed at about 10 second intervals with an underwater camera system. Eleven pairs of consecutive pictures are analyzed to determine the mean current vertical shear and the width of the plumes by positioning reference points relative to the rod attached to the camera system. The relative distances of reference points are calibrated with the stereophotogrammetric method for one pair. The eddy diffusivity is calculated by use of a model of turbulent diffusion developed byTaylor (1921). Its values range from 5 to 25 cm²s^–1 for the plume widths ranging from 33 to 132 cm. The Richardson number is calculated for each pair of pictures with the vertical density gradient estimated from temperature profiles. Its values are higher than the critical value of 0.25 except for one case. The diffusivity was higher by orders of magnitude than the molecular one and indicates the presence of turbulence together with billow like features of the plumes in spite of high Richardson numbers. This suggests that the billow turbulence might be caused by effects of surface gravity waves and not by the Kelvin-Helmholtz instability.     

Determination of bare surface soil moisture from combined temporal evolution of land surface temperature and net surface shortwave radiation

Land surface soil moisture (SSM) is an important variable for hydrological, ecological, and meteorological applications. A multi‐linear model has recently been proposed to determine the SSM content from the combined diurnal evolution of both land surface temperature (LST) and net surface shortwave radiation (NSSR) with the parameters TN (the LST mid‐morning rising rate divided by the NSSR rising rate during the same period) and t_d (the time of daily maximum temperature). However, in addition to the problem that all the coefficients of the multi‐linear model depend on the atmospheric conditions, the model also suffers from the problems of the nonlinearity of TN as a function of the SSM content and the uncertainty of determining the t_d from the diurnal evolution of the LST. To address these problems, a modified multi‐linear model was developed using the logarithm of TN and normalizing t_d by the mid‐morning temperature difference instead of using the TN and t_d. Except for the constant term, the coefficients of all other variables in the modified multi‐linear model proved to be independent of the atmospheric conditions. Using the relevant simulation data, results from the modified multi‐linear model show that the SSM content can be determined with a root mean square error (RMSE) of 0.030m³/m³, provided that the constant term is known or estimated day to day. The validation of the model was conducted using the field measurements at the Langfang site in 2008 in China. A higher correlation is achieved (coefficient of determination: R² = 0.624, RMSE = 0.107m³/m³) between the measured SSM content and the SSM content estimated using the modified multi‐linear model with the coefficients determined from the simulation data. Another experiment is also conducted to estimate the SSM content using the modified model with the constant term calibrated each day by one‐spot measurements at the site. The estimation result has a relatively larger error (RMSE = 0.125m³/m³). Additionally, the uncertainty of the determination of the coefficients is analysed using the field measurements, and the results indicate that the SSM content obtained using the modified model accurately characterizes the surface soil moisture condition. Copyright © 2012 John Wiley & Sons, Ltd.     

Spatially distributed denitrification in a karst springshed

Karst spring measurements assess biogeochemical processes occurring within groundwater contributing areas to springs (springsheds) but can only provide aggregated information. To better understand spatially distributed processes that comprise these aggregated measures, we investigated aquifer denitrification evidence in groundwater wells (n = 16) distributed throughout a springshed in the Upper Floridan aquifer in northern Florida. Aquifer geochemistry, nitrate isotopes, and dissolved gases were compared against similar measurements at the spring outlet to evaluate spatial heterogeneity of denitrification evidence in relation to land surface–aquifer connectivity. Sample locations spanned spatial variation in recharge processes (i.e., diffuse vs. focused recharge) and proximity to sources of denitrification reactants (e.g., wetlands). Although no distinct spatial pattern in denitrification was uncovered, excess dissolved N₂ gas measurements were only above detection in the unconfined springshed, with some evidence of a wetland proximity effect. Measured oxidation–reduction potential and dissolved oxygen poorly predicted denitrification, indicating that measured denitrification may be occurring upgradient from sampled wells. Despite dramatic spatial chemical heterogeneity across wells, mean values for recharge nitrate concentrations (0.02 to 5.56 mg N L^?1) and excess N₂ from aquifer denitrification (below detection to 1.37 mg N L^?1) corresponded reasonably with mean spring outlet measurements for initial nitrate (0.78 to 1.36 mg N L^?1) and excess N₂ (0.15 to 1.04 mg N L^?1). Congruence between groundwater and spring measurements indicates that combining sampling at the spring outlet and across the springshed is useful for understanding spatial aquifer denitrification. However, this approach would be improved with a high‐density sampling network with transects of wells along distinct groundwater flow paths.     

Review of Quantitative Surveys of the Length and Stability of MTBE,TBA, and Benzene Plumes in Groundwater at UST Sites

Quantitative information regarding the length and stability condition of groundwater plumes of benzene, methyl tert‐butyl ether (MTBE), and tert‐butyl alcohol (TBA) has been compiled from thousands of underground storage tank (UST) sites in the United States where gasoline fuel releases have occurred. This paper presents a review and summary of 13 published scientific surveys, of which 10 address benzene and/or MTBE plumes only, and 3 address benzene, MTBE, and TBA plumes. These data show the observed lengths of benzene and MTBE plumes to be relatively consistent among various regions and hydrogeologic settings, with median lengths at a delineation limit of 10 µg/L falling into relatively narrow ranges from 101 to 185 feet for benzene and 110 to 178 feet for MTBE. The observed statistical distributions of MTBE and benzene plumes show the two plume types to be of comparable lengths, with 90th percentile MTBE plume lengths moderately exceeding benzene plume lengths by 16% at a 10‐µg/L delineation limit (400 feet vs. 345 feet) and 25% at a 5‐µg/L delineation limit (530 feet vs. 425 feet). Stability analyses for benzene and MTBE plumes found 94 and 93% of these plumes, respectively, to be in a nonexpanding condition, and over 91% of individual monitoring wells to exhibit nonincreasing concentration trends. Three published studies addressing TBA found TBA plumes to be of comparable length to MTBE and benzene plumes, with 86% of wells in one study showing nonincreasing concentration trends.     

Probabilistic assessment of one‐step‐ahead rainfall variation by Split Markov Process

In this paper, Split Markov Process (SMP) is developed to assess one‐step‐ahead variation of daily rainfall at a rain gauge station. SMP is an advancement of general Markov Process and specially developed for probabilistic assessment of change in daily rainfall magnitude. The approach is based on a first‐order Markov chain to simulate daily rainfall variation at a point through state/sub‐state transitional probability matrix (TPM). The state/sub‐state TPM is based on the historical transitions from a particular state to a particular sub‐state, which is the basic difference between SMP and general Markov Process. The cumulative state/sub‐state TPM is represented in a contour plot at different probability levels. The developed cumulative state/sub‐state TPM is used to assess the possible range of rainfall in next time step, in a probabilistic sense. Application of SMP is investigated for daily rainfall at four rain gauge stations – Khandwa, Jabalpur, Sambalpur, and Puri, located at various parts in India. There are 99 years of record available out of which approximately 80% of data are used for calibration, and 20% of data are used to assess the performance. Thus, 80 years of daily monsoon rainfall is used to develop the state/sub‐state TPM, and 19 years data are used to investigate its performance. Model performance is assessed in terms of hit rate (HR), false alarm rate (FAR), and percentage captured. It is found that percentage captured is maximum for Khandwa (70%) and minimum for Sambalpur (44%) whereas hit rate is maximum for Sambalpur and minimum for Khandwa (73%). FAR is around 30% or below for Jabalpur, Sambalpur, and Puri. FAR is maximum for Khandwa (37%). Overall, the assessed range, particularly the upper limit, provides a quantification possible extreme value in the next time step, which is a very useful information to tackle the extreme events, such as flooding, water logging and so on. Copyright © 2011 John Wiley & Sons, Ltd.     

青藏高原典型湖库光学吸收特性与光合有效辐射衰减系数初步研究

青藏高原地区分布的湖泊数量众多、面积较大、分布范围广泛.受制于恶劣的自然条件,对该地区湖泊的光学吸收特性以及光合有效辐射衰减系数(Kd(PAR))的研究鲜有成果.本文依据2014和2015年间采集的13个典型高海拔、湖泊面积较大的湖库的现场实测数据和实验室测定数据,分析了采样湖库各个采样点的Kd(PAR)特征以及有色可溶性有机物(CDOM)、藻类颗粒物吸收及非色素颗粒物吸收特性,计算并分析了Kd(PAR)与透明度以及光学活性物质的关系.研究结果表明:青藏高原地区各湖库平均各项颗粒物吸收系数均较低,总颗粒物吸收系数在400~700 nm波段内不超过0.14 m~(-1)、CDOM吸收系数在355 nm波长处最高,为1.23 m~(-1)、最低接近于0、藻类颗粒物吸收特性不明显;实验数据完整的巴木错、格仁错和班公错的主导吸收组分各异,其中巴木错为CDOM吸收主导,格仁错与班公错为非色素颗粒物吸收主导;青藏高原采样湖泊总体Kd(PAR)平均值较小,仅为0.26 m~(-1),样点最大值出现在可鲁克湖(1.17 m~(-1)),最小值出现在普莫雍错(0.10 m~(-1));在采样湖泊中Kd(PAR)与透明度呈显著相关;Kd(PAR)与CDOM的相关性最强,叶绿素a浓度次之,与总悬浮颗粒物浓度的相关性最不显著.     

抚仙湖秋、冬季光衰减特征及其与有色可溶性有机物的关系

为了研究抚仙湖紫外辐射(UVR)和光合有效辐射(PAR)衰减的时空特征及其与有色可溶性有机物(CDOM)、悬浮物(SS)、浮游植物(叶绿素a表征)等因子的关系,于2014年10月(秋季)、2015年1月(冬季)开展现场调查,结果显示:秋季不同波长(段)的漫射衰减系数Kd(305)、Kd(340)和Kd(PAR)分别为1.27±0.12、0.68±0.11和0.32±0.13 m-1,冬季分别为1.13±0.10、0.63±0.07和0.36±0.07 m-1;秋季CDOM的不同波长吸收系数ag(254)、ag(305)和ag(340)分别为4.09±0.26、1.18±0.09和0.57±0.05 m-1,冬季分别为2.95±0.24、0.61±0.11和0.11±0.07 m-1,秋季ag(254)、ag(305)和ag(340)显著高于冬季;秋季Kd(305)显著大于冬季,这与秋季(雨季)较高的CDOM丰度、浮游植物生物量(及SS浓度)有关.秋季ag(305)/Kd(305)、ag(340)/Kd(340)均显著高于冬季;秋季及秋冬季整体而言,ag(254)与Kd(305)、Kd(340)呈显著正相关,各多元逐步回归方程中均包含ag(254),说明CDOM吸收对UVR的衰减有重要贡献.空间差异方面,秋季北部的ag(254)、Kd(305)和Kd(340)显著高于南部,冬季南北部无明显差异,或与雨旱季北岸河流输入的CDOM和SS的情况有关.此外,浮游植物对UV-B衰减的影响和SS(与CDOM的交互作用)对UV-A衰减的影响更在于季节变化方面,而影响UVR、PAR衰减的各因子的相对贡献有待进一步量化.     

One-station estimates of seismic moments from the mantle magnitudeM m: The case of the regional field (1.5°≤Δ≤15°)

We extend to the regional field of distances the procedure of one-station estimation of seismic moments using the mantle magnitudeM _m, as introduced earlier in the case of teleseismic events. A theoretical analysis of the validity of the asymptotic expansion of normal modes in terms of surface waves, which was used in the development ofM _m, upholds the validity of the algorithm for distances as short as 1.5°. This is confirmed by the analysis of a dataset of 149 GEOSCOPE records obtained at distances ranging from 1.5 to 15°, from earthquakes with moments between 10²⁴ and 2.5×10²⁷ dyn-cm. The performance ofM _m as measured in terms of average residual with respect to published values ofM ₀, and standard deviation of the residuals, is not degraded in this distance range, with respect to the teleseismic case. This indicates that the mantle magnitudeM _mcan be reliably used at regional distances, notably for tsunami warning applications.     

Monitoring and modeling dissolved oxygen dynamics through continuous longitudinal sampling: a case study in Wen‐Rui Tang River,Wenzhou, China

Synoptic water sampling at a fixed site monitoring station provides only limited ‘snap‐shots’ of the complex water quality dynamics within a surface water system. However, water quality often changes rapidly in both spatial and temporal dimensions, especially in highly polluted urban rivers. In this study, we designed and applied a continuous longitudinal sampling technique to monitor the fine‐scale spatial changes of water quality conditions, assess water pollutant sources, and determine the assimilative capacity for biochemical oxygen demand (BOD) in an urban segment of the hypoxic Wen‐Rui Tang River in eastern China. The continuous longitudinal sampling was capable of collecting dissolved oxygen (DO) data every 5 s yielding a ~11 m sampling interval with a precision of ±0.1 mg L^?1. The Streeter and Phelps BOD‐DO model was used to calculate: (1) the oxygen consumption coefficient (K₁) required for calibration of water quality models, (2) BOD assimilative capacity, and (3) BOD source and load identification. In the 2014 m river segment sampled, the oxygen consumption coefficient (K₁) was 0.428 d^?1 (20°C), the total BOD discharge was 916 kg d^?1, and the BOD assimilative capacity was 382 kg d^?1 when the minimum DO level was set to 2 mg L^?1. In addition, the longitudinal analysis identified eight major drainage outlets (BOD point sources), which were verified by field observations. This new approach provides a simple, cost‐effective method of evaluating BOD‐DO dynamics over large spatial areas with rapidly changing water quality conditions, such as urban environments. It represents a major breakthrough in the development and application of water quality sampling techniques to obtain spatially distributed DO and BOD in real time. Copyright © 2012 John Wiley & Sons, Ltd.     

Hydrogeologic Controls on Induced Seismicity in Crystalline Basement Rocks Due to Fluid Injection into Basal Reservoirs

A series of M_b 3.8–5.5 induced seismic events in the midcontinent region, United States, resulted from injection of fluid either into a basal sedimentary reservoir with no underlying confining unit or directly into the underlying crystalline basement complex. The earthquakes probably occurred along faults that were likely critically stressed within the crystalline basement. These faults were located at a considerable distance (up to 10 km) from the injection wells and head increases at the hypocenters were likely relatively small (～70–150 m). We present a suite of simulations that use a simple hydrogeologic‐geomechanical model to assess what hydrogeologic conditions promote or deter induced seismic events within the crystalline basement across the midcontinent. The presence of a confining unit beneath the injection reservoir horizon had the single largest effect in preventing induced seismicity within the underlying crystalline basement. For a crystalline basement having a permeability of 2 × 10^?17 m² and specific storage coefficient of 10^?7/m, injection at a rate of 5455 m³/d into the basal aquifer with no underlying basal seal over 10 years resulted in probable brittle failure to depths of about 0.6 km below the injection reservoir. Including a permeable (k_z = 10^?13 m²) Precambrian normal fault, located 20 m from the injection well, increased the depth of the failure region below the reservoir to 3 km. For a large permeability contrast between a Precambrian thrust fault (10^?12 m²) and the surrounding crystalline basement (10^?18 m²), the failure region can extend laterally 10 km away from the injection well.