Scattering by nonspherical particles and optical properties of Martian dust

Ultraviolet spectral reflectance data obtained from the Mariner 9 during the 1971 Mars dust storm were analyzed at two wavelengths to deduce the complex index of refraction of Martian dust. Martian dust particles were considered to be irregularly shaped and randomly oriented nonspherical particles. The analysis shows that the Mariner 9 data are consistent with the scattering by irregular particles with an index of refraction m = 1.59 ? 0.0015i at λ = 0.305 μm and m = 1.55 ? 0.004i at λ = 0.268 μm. Both the real and the imaginary parts of refractive index found are considerably smaller than previously reported results using a spherical shape model for Martian dust particles.     

Hapke mixture modeling applied to VNIR spectra of mafic mineral mixtures and shergottites: Implications for quantitative analysis of satellite data

The mineralogy of Mars is well understood on a qualitative level at a global scale due to satellite data. Quantitative analysis of visible and near-infrared (VNIR) satellite data is a desirable but nontrivial task, due partly to the nonlinearity of VNIR reflectance spectra from the mineral mixtures of the Martian surface. In this study, we investigated the use of the Hapke radiative transfer model to generate linearly mixed single scattering albedo data from nonlinearly mixed VNIR reflectance data and then quantitatively analyzed them using the linear spectral mixture model. Simplifications to the Hapke equation were tested accounting for variables that would be unknown when using satellite data. Mineral mixture spectra from the RELAB spectral library were degraded to test the robustness of the unmixing technique in the face of data that mimic some of the complexities of satellite spectral data collected at Mars. A final test was performed on spectra from shergottite meteorites to assess the technique against real Martian mineral mixtures. The simplified Hapke routine produced robust abundance estimates within 5–10% accuracy when applied to laboratory standard spectra from the synthetic mixtures of igneous minerals in agreement with previous studies. The results of tests involving degraded data to mimic the low spectral contrast of the Martian surface and the lack of a priori knowledge of the constituent mineral spectral endmembers, however, were less encouraging, with errors in abundance estimation greater than 25%. These results cast doubt on the utility of Hapke unmixing for the quantitative analysis of VNIR data of the surface of Mars.     

Complex refractive index of Martian dust: Wavelength dependence and composition

Mariner 9 ultraviolet spectra of the 1971 dust clouds were analyzed to obtain the phase function times single scattering albedo of the dust particles. The phase functions were matched with Mie scattering calculations for size distributions of spheres of homogeneous and isotropic material. The absorption index of the dust particles was found to increase with decreasing wavelenght from 350 nm down to about 210 nm, and drop off shortward of this wavelength. A structural shoulder occurs in the absorption spectrum between 240 and 250 nm. Titanium dioxide (anatase) has the correct transitions at 210 and 250 nm to match the absorption curve of Martian dust, and is proposed as a candidate constituent in Martian surface material. The spectral neutrality of TiO₂ between 0.5 and 4 μm is consistent with visible and infrared observations of Mars. The high refractive index of TiO₂ can explain the large refringence of Martian dust. The titanium dioxide content of the dust particles is estimated to be a few percent or less. Uncertainties in the results due to limitations in the model and data are discussed.     

A search for basaltic-to-intermediate glasses on Mars: Assessing martian crustal mineralogy

Multiple datasets have demonstrated that the crust of Mars is fundamentally basaltic. However, spectral libraries used to interrogate thermal infrared spectra of Martian dark regions through spectral deconvolution have heretofore lacked mafic glasses despite the importance of amorphous phases (or phases with amorphous-like spectral signatures) in Martian mineralogy. To establish the presence and importance of basaltic-to-intermediate glasses in Martian lithologies, we created five such glasses, obtained their thermal infrared spectra and included the spectra in a library used to deconvolve nine regional Thermal Emission Spectrometer spectra from Mars. We employed the nonnegative least squares (NNLS) deconvolution method, which yields deconvolved phase abundances and the uncertainties associated with those abundances. The basaltic-to-intermediate glasses do not appear in the deconvolution solutions, indicating they are not globally or regionally important phases. Because Martian igneous or impact processes are capable of basaltic-to-intermediate glass formation, the lack of such glasses in the deconvolved mineralogies suggests either the glasses did not form in detectable quantities or they (or their signatures) have been removed. The masking or replacement of basaltic-to-intermediate glasses through alteration is supported by the appearance in the deconvolution solutions of amorphous phases (e.g., silica-rich glasses, opal) or phases with amorphous-like spectral signatures (e.g., clays, zeolites) that commonly form through aqueous alteration of mafic glasses. The glasses may still be important to local-scale thermal infrared studies given the basaltic nature of Mars and the variety of local-scale lithologies detected by various missions. The regional mineralogies derived from the NNLS deconvolution analysis divide into five statistically separable groups, which provide insight into regional trends in mineralogy.     

Solar heating of the Martian dusty atmosphere

This paper examines the solar heating of the Martian atmosphere during the 1971 global dust storm observed by Mariner 9. Radiative scattering as well as absorption is included by utilizing the delta-Eddington approximation to the full radiative transfer equation. The necessary optical parameters are generated by a Mie program which uses a size distribution and a complex refractive index inferred from a number of sources, particularly from recent analyces of Mariner 9 UVS and TV observations. Assuming uniform mixing of the dust, the solar heating per unit mass during a Martian global dust storm is remarkably uniform with height for small solar zenith angles. Heating rates may reach 80°K day^? for overhead sunlight. Overall, 20% of the direct insolation is absorbed by the dust-laden atmosphere. Even optically thin widespread dust hazes may produce heating rates of several degrees Kelvin per day.     

Evidence for topographic effects on the Martian ionosphere

The Radio occultation experiment on board Mariner 9 has been used to demonstrate that the altitude of the main electron density peak in the Martian ionosphere is closely related to the height of Mars’ surface at the occultation point. This is direct evidence for topographic effects on the Martian ionosphere. Modeling indicates that topographic-induced modulations of the neutral density in the upper atmosphere can account for the observed ionospheric effects. The neutral density modulation is likely to be caused by nonmigrating tides in the Martian thermosphere.     

An unusual landslide feature on Mars

A flow feature on a crater wall, characteristic of a landslide, has been identified in a Mariner 9 high resolution photograph. Although other evidence of mass wasting is common in Mariner 9 photography, the case presented appears unique. A tentative conclusion is that, at least in some cases, Martian soil exhibits significant internal friction in mass movements.     

Predicted lightcurves of Phobos and Deimos

Using Mariner 9 results on the shapes, rotation periods and photometric functions of Phobos and Deimos we calculate approximate orbital lightcurves for the two Martian satellites. The prediction is that both Phobos and Deimos should show orbital brightness fluctuations detectable from Earth. For Phobos the detectable amplitude is predicted to be about 0.1 mag; for Deimos, 0.2 mag.     

Structural origin of large Martian channels

Large Martian channels have been attributed to fluvial erosion primarily because they widen in a downstream direction, appear to be braided in places, have tributaries, and may be sinuous. However, tension fractures in a variety of materials produce features that superficially resemble the Martian channels at, of course, a very different scale.Based on the morphology of these channels as viewed on Mariner 9 images, it is not possible to determine that these features have a fluvial origin. It is probable that most large Martian channels have a structural origin and reflect local or planet-wide tensional forces.     

Spectral reflectance of Martian meteorites: Spectral signatures as a template for locating source region on Mars

Abstract— We report the spectral reflectance of Martian meteorites from 0.3‐2.6 microns for the purpose of cataloguing spectra and the association of their spectral properties with mineralogy and petrology. We fit the spectra to a series of overlapping, modified Gaussian absorptions using least squares fitting. The results are validated against established relationships between photon interactions with mineral chemistry and the band parameters. These resultant band parameters can be used to constrain interpretations of Martian reflectance spectra in the search for the source region of meteorites from Mars. The limitations of the fitting method are discussed.     

Infrared reflectance spectra of Martian analogues

Reflectance spectroscopy in the infrared is a powerful tool to characterise the optical properties of analogue materials for Mars. In this work we present laboratory studies of four Martian analogues: calcite, montmordlonite, palagonite and andesite. Diffuse and specular reflectance and transmittance spectra in the IR are shown. The spectral effect produced by small grains clung to the larger ones is analysed for calcite. Significant variations in the diffuse reflectance spectrum, especially in the reststrahlen region, are observed. The diffuse reflectance spectra of the other materials show the shift of the reststrahlen features with Si content in the materials. Optical constants of andesite are retrieved, by using the Lorentz model, from the specular reflectance spectrum. These values are fundamental in performing modelling of the radiance coming from the planet Mars.     

Upper limits for the Martian exospheric number density during the Planet B/Nozomi mission

Dissociative recombination (DR) of ionospheric O₂⁺ ions is an important source of suprathermal atomic oxygen in the exosphere as previous studies about the Martian upper atmosphere have shown. Because of the weaker gravitational attraction a hot oxygen corona on Mars should be denser than that observed on Venus. Since the most important mechanism for the production of the hot oxygen atoms in the Martian exosphere is DR, we investigated the variability of this production mechanism depending of solar activity. The Japanese Nozomi spacecraft will have the possibility to detect with the neutral mass spectrometer (NMS) for the first time in-situ the theoretically predicted hot oxygen corona on Mars, if the corona number density above the cold background atmosphere is of the order of 10,000 cm⁻³. Due to a problem in the propulsion system Nozomi failed its planned arrival rendevouzs with Mars in October 1999 and will, therefore, arrive at the red planet not before January 2004. Solar activity will reach its maximum in 2001, so the related production rate of hot oxygen atoms will be in the medium range during the new arrival date of Nozomi. We used the ionospheric profiles from the Viking mission for low solar activity conditions (F_10.7≈70) and the Mariner 9 mission with a solar activity of about 120 for medium solar wind activity. The latter is comparable to the level we expect for the Mars arrival of Nozomi. The resulting influence of the hot oxygen corona number density distribution was calculated with a Monte Carlo technique. This technique is used to compute a hot particle density distribution function. We studied the atomic diffusion process in the Martian atmosphere by simulating the collision probability, particle direction and energy loss after collisions by generating random numbers. Compared to previous studies we have improved the Monte Carlo model by using more and smaller altitude steps and more detailed treatment of particles with a temporary downward motion. This has resulted in an increased amount of collisions and a shift to lower energies in the energy spectrum. Our results show that the hot oxygen component should begin to dominate above the cold background atmosphere at an altitude of about 500 km above the Martian surface. The NMS instrument on board of Nozomi should detect the hot oxygen component after its arrival at Mars in January 2004, at an altitude of about 600 km above the Martian surface. Since the solar activity will decrease during the mission the measurements during the first orbits will be the most significant ones. The first in-situ measurements of the hot oxygen number density would be very important for adjusting atmospheric escape models by separating ballistic, satellite and escape trajectories of the hot oxygen atoms, which are significant for studies of the evolution and solar wind interaction of the Martian atmosphere.     

Compton effect and solar spectral lines

A scenario for the evolution of the Martian atmosphere consistent with various data of the Viking 1 and 2 and the Mariner 9 has been presented: Mars was formed from Renazzo-type meteorites polluted by the products of supernova explosion. A dense ancient Martian atmosphere has been swept away by the solar wind and the present tenuous atmosphere was supplied recently by the volcanic gas from the Tharsis region, after the occurrence of the magnetic field.     

Albedo models for the residual south polar cap on Mars: Implications for the stability of the cap under near-perihelion global dust storm conditions

It is uncertain whether the residual (perennial) south polar cap on Mars is a transitory or a permanent feature in the current Martian climate. While there is no firm evidence for complete disappearance of the cap in the past, clearly observable changes have been documented. Observations suggest that the perennial cap lost more CO₂ material in the spring/summer season prior to the Mariner 9 mission than in those same seasons monitored by Viking and Mars Global Surveyor. In this paper we examine one process that may contribute to these changes—the radiative effects of a planet encircling dust storm that starts during late Martian southern spring on the stability of the perennial south polar cap. To approach this, we model the radiative transfer through a dusty planetary atmosphere bounded by a sublimating CO₂ surface.A critical parameter for this modeling is the surface albedo spectrum from the near-UV to the thermal-IR, which was determined from both space-craft and Earth-based observations covering multiple wavelength regimes. Such a multi-wavelength approach is highly desirable since one spectral band by itself cannot tightly constrain the three-parameter space for polar surface albedo models, namely photon “scattering length” in the CO₂ ice and the amounts of intermixed water and dust.Our results suggest that a planet-encircling dust storm with onset near solstice can affect the perennial cap's stability, leading to advanced sublimation in a “dusty” year. Since the total amount of solid CO₂ removed by a single storm may be less than the total CO₂ thickness, a series of dust storms would be required to remove the entire residual CO₂ ice layer from the south perennial cap.     

Hydrogen isotopic composition of the Martian mantle inferred from the newest Martian meteorite fall,Tissint

The hydrogen isotopic composition of planetary reservoirs can provide key constraints on the origin and history of water on planets. The sources of water and the hydrological evolution of Mars may be inferred from the hydrogen isotopic compositions of mineral phases in Martian meteorites, which are currently the only samples of Mars available for Earth‐based laboratory investigations. Previous studies have shown that δD values in minerals in the Martian meteorites span a large range of ?250 to +6000‰. The highest hydrogen isotope ratios likely represent a Martian atmospheric component: either interaction with a reservoir in equilibrium with the Martian atmosphere (such as crustal water), or direct incorporation of the Martian atmosphere due to shock processes. The lowest δD values may represent those of the Martian mantle, but it has also been suggested that these values may represent terrestrial contamination in Martian meteorites. Here we report the hydrogen isotopic compositions and water contents of a variety of phases (merrillites, maskelynites, olivines, and an olivine‐hosted melt inclusion) in Tissint, the latest Martian meteorite fall that was minimally exposed to the terrestrial environment. We compared traditional sample preparation techniques with anhydrous sample preparation methods, to evaluate their effects on hydrogen isotopes, and find that for severely shocked meteorites like Tissint, the traditional sample preparation techniques increase water content and alter the D/H ratios toward more terrestrial‐like values. In the anhydrously prepared Tissint sample, we see a large range of δD values, most likely resulting from a combination of processes including magmatic degassing, secondary alteration by crustal fluids, shock‐related fractionation, and implantation of Martian atmosphere. Based on these data, our best estimate of the δD value for the Martian depleted mantle is ?116 ± 94‰, which is the lowest value measured in a phase in the anhydrously prepared section of Tissint. This value is similar to that of the terrestrial upper mantle, suggesting that water on Mars and Earth was derived from similar sources. The water contents of phases in Tissint are highly variable, and have been affected by secondary processes. Considering the H₂O abundances reported here in the driest phases (most likely representing primary igneous compositions) and appropriate partition coefficients, we estimate the H₂O content of the Tissint parent magma to be ≤0.2 wt%.     

Topography and Geologic Characteristics of Aeolian Grooves in the South Polar Layered Deposits of Mars

The topographic and geologic characteristics of grooves and groove-like features in the south polar layered deposits near the Mars Polar Lander/Deep Space 2 landing sites are evaluated using Mariner 9 images and their derived photoclinometry, normalized using Mars Orbiter Laser Altimeter data. Although both Mariner 9 and Viking images of the south polar layered deposits were available at the time of this study, Mariner 9 images of the grooves were selected because they were generally of higher resolution than Viking images. The dimensions and slopes of the grooves, together with orientations that nearly match the strongest winds predicted in the Martian Global Circulation Model and directions inferred from other wind indicators, suggest that they formed by aeolian scour of an easily erodible surface. Most grooves are symmetric and V-shaped in transverse profile, inconsistent with an origin involving extensional brittle deformation. Although the grooves strike along slopes and terraces of the south polar layered deposits, the variable depths and lack of terracing within the grooves themselves indicate that any stratigraphy in the uppermost 100 m of the polar layered deposits is composed of layers of similar, and relatively low, resistance. The grooves do not represent landing hazards at the scale of the Mariner 9 images (72-86 m/pixel) and therefore probably would not have affected Mars Polar Lander and Deep Space 2, had they successfully reached the surface.     

A comparison of Martian albedo features with topography

Martian albedo features photographed from the Earth are compared with the topography observed by Mariner 9. We present three Lambert azimuthal equal-area charts prepared to facilitate the comparison. No correlation between large-scale albedos and topography can be generalized, but several different kinds of relationships seem to be indicated in particular regions. Examples of these are discussed.     

Martian atmospheric particulate spectral end-members recovery from PFS and IRIS data

We present an application of a multivariate analyses technique on data returned by the Planetary Fourier Spectrometer (PFS) instrument on board the ESA’s Mars Express (MEX) spacecraft in order to separate the atmospheric contribution from the observed radiation. We observe that Thermal/Far Infrared spectra returned from Mars, covering almost a whole martian year, can be represented by a linear model using a limited set of end-member spectra. We identify the end-members as the suspended mineral dust and water ice clouds, but no surface signature was found. We improve previous studies performed with data from the Thermal Emission Spectrometer (TES) thanks to the higher spectral resolution of PFS. This allows for distinguishing narrow gaseous bands present in the martian atmosphere. Furthermore, the comparison of results from PFS and TES with data collected in 1971 by the Mariner 9 Infrared Interferometer Spectrometer (IRIS) shows an atmospheric dust component with similar spectral behavior. This might indicate homogeneity of the dust source regions over a time period of more than 30 years.     

Comparison of knobs on mars to isolated hills in eolian,fluvial and glacial environments

Positive isolated features or knobs have been observed on Mars since Mariner 9 first photographed the planet in 1972. More recently, the Viking Orbiters photographed the surface at increased resolution. With the use of Viking photomosaics, a systematic search for knobs was completed. The knobs were characterized by length, width, geographic location, proximity to streaks and geologic surroundings. Similar isolated features on Earth eroded by fluvial, glacial, and eolian processes were studied and measured. Comparison of length-to-width ratios of Martian knobs to isolated hills on Earth indicate that the Martian knobs are most similar to the isolated hills formed in a hyper-arid environment. The terrestrial features were probably formed initially when solid rock was fractured, then wind erosion, starting at the fractures, continued to sweep away sediments leaving isolated hills. Such hills in fluvial and glacial environments have length-to-width ratios significantly higher than those of the Martian knobs. Other diagnostic features associated with such environments are absent in the case of the Martian knobs. Moreover, streaks, splotches, dunes and pitted and fluted rocks, all indicative of a eolian regime, are associated with the Martian knobs.     

A reply to Richard Greenberg's review of interplanetary encounters: Close range gravitational interactions

The large-scale dynamics of the Martian winter atmosphere are analyzed and discussed. Results obtained from a baroclinic instability analysis, including a Newtonian radiational damping term, are compared with the Mariner 9 data. The beta plane baroclinic poleward heat fluxes are contrasted with those produced using spherical geometry, from the stationary orographically forced long waves.