稀土钇、镧掺杂TiO2薄膜的拉曼谱分析

采用溶胶-凝胶法在石英玻璃衬底上用旋涂法制备了未掺杂、掺杂钇和掺杂镧的TiO₂薄膜样品,对样品在700—1100 ℃范围内进行退火处理,并对样品的拉曼光谱进行了分析.分析表明:随着退火温度的升高,未掺杂TiO₂薄膜发生了从锐钛矿相经混相最终向金红石相的转换,掺杂钇和掺杂镧对TiO₂薄膜的晶相转换起阻碍作用,掺杂镧的阻碍作用更强;稀土掺杂能使TiO₂薄膜晶粒细化,并使晶粒内部应力增大从而阻碍晶格振动,掺杂镧比掺杂钇的效果     

Amorphous Er2O3 films for antireflection coatings

This paper reports that stoichiometric, amorphous, and uniform Er₂O₃ films are deposited on Si(001) substrates by a radio frequency magnetron sputtering technique. Ellipsometry measurements show that the refractive index of the Er₂O₃ films is very close to that of a single layer antireflection coating for a solar cell with an air surrounding medium during its working wavelength. For the 90-nm-thick film, the reflectance has a minimum lower than 3% at the wavelength of 600 nm and the weighted average reflectances (400--1000 nm) is 11.6%. The obtained characteristics indicate that Er₂O₃ films could be a promising candidate for antireflection coatings in solar cells.     

CdTe太阳电池前电极SnO2 :F/SnO2复合薄膜性能分析

减薄CdS窗口层是提高CdS/CdTe太阳电池转换效率的有效途径之一,减薄窗口层会对器件造成不利的影响,因此在减薄了的窗口层与前电极之间引入过渡层非常必要.利用反应磁控溅射法在前电极SnO₂:F薄膜衬底上制备未掺杂的SnO₂薄膜形成过渡层,并将其在N₂/O₂=4 ∶1,550 ℃环境进行了30 min热处理,利用原子力显微镜、X射线衍射仪、紫外分光光度计对复合薄膜热处理前后的形貌、结构、光学性能进行了表征,同时分析了复     

相变存储材料Ge1Sb2Te4和Ge2Sb2Te5薄膜的结构和电学特性研究

采用射频磁控溅射方法制备了两种用于相变存储器的Ge₁Sb₂Te₄和Ge₂Sb₂Te₅相变薄膜材料,对其结构、电学输运性质和恒温下电阻随时间的变化关系进行了比较和分析.X射线衍射(XRD)和原子力显微镜(AFM)的结果表明:随着退火温度的升高,Ge₁Sb₂Te₄薄膜逐步晶化,由非晶态转变为多晶态,表面出现均匀的、     

基于等离子体增强化学气相沉积技术的光电子器件多层抗反膜的设计和制作

针对光电子器件端面抗反镀膜的要求,研究了基于等离子体增强化学气相沉积(PECVD)技术的多层抗反膜的设计和制作.首先,对影响SiN_x折射率的因素进行了实验研究,确定了具有大折射率差的SiO₂/SiN_x材料的PECVD沉积条件.根据理论计算分析,设计了四层SiO₂/SiN_x抗反膜结构,能够在70 nm的波长范围内实现低于10^-4的反射率     

Structures and magnetic behaviours of TiO2—Mn—TiO2 multilayers

The TiO₂--Mn--TiO₂ multilayers are successfully grown on glass and silicon substrates by alternately using radio frequency reactive magnetron sputtering and direct current magnetron sputtering. The structures and the magnetic behaviours of these films are characterised with x-ray diffraction, transmission electron microscope (TEM), vibrating sample magnetometer, and superconducting quantum interference device (SQUID). It is shown that the multi-film consists of a mixture of anatase and rutile TiO₂ with an embedded Mn nano-film. It is found that there are two turning points from ferromagnetic phase to antiferromagnetic phase. One is at 42 K attributed to interface coupling between ferromagnetic Mn₃O₄ and antiferromagnetic Mn₂O₃, and the other is at 97 K owing to the interface coupling between ferromagnetic Mn and antiferromagnetic MnO. The samples are shown to have ferromagnetic behaviours at room temperature from hysteresis in the M--H loops, and their ferromagnetism is found to vary with the thickness of Mn nano-film. Moreover, the Mn nano-film has a critical thickness of about 18.5 nm, which makes the coercivity of the multi-film reach a maximum of about 3.965times 10 ^{- 2} T.     

基于反转法的O2 -CO2 输运性质预测

采用反转法计算得到了O₂-CO₂混合气体新的势能参数.在此基础上,根据分子动力学理论,计算了混合气体在零密度下的输运性质,包括黏度系数、热扩散系数和热扩散因子,计算的温度范围为273.15—3273.15 K.与实验值比较表明,计算结果可以满足实际工程应用.     

Processes governing the carbon chemistry during the SAGE experiment

Measurements of pCO₂, pH and alkalinity in the surface waters of an iron fertilised patch of sub-Antarctic water were made during SAGE (SOLAS SAGE: Surface-Ocean Lower Atmosphere Studies Air-Sea Gas Experiment). The iron addition induced a minor phytoplankton bloom, however the patch dynamics were dominated by physical processes which suppressed and masked the biological effects. The Lagrangian nature of the experiment allowed the carbonate chemistry in the patch to be followed for 15.5 days, and the relative importance of the biological and physical factors influencing the surface water pCO₂ was estimated. The pCO₂ of the surface waters of the patch increased from 327 ??atm prior to iron addition to 338 ??atm on Day 14, effects of vertical and horizontal mixing offset the 15 ??atm drawdown that would have occurred had the induced biological uptake been the sole factor to influence the pCO₂. The air-sea carbon flux calculated using the measured skin temperature and a piston velocity parameterisation determined during SAGE (Ho et al., 2006) was 98.5% of the flux determined using conventional bulk temperature measurement and the Wanninkhof (1992) piston velocity parameterisation. The skin temperature alone contributed to an 8% increase in the flux compared with that determined using bulk temperature.     

不同粒径TiO_2颗粒对海洋微藻的毒性效应

本实验以新月菱形藻为受试生物,研究了低浓度不同粒径TiO2颗粒(21nm、60nm和400nm)对海洋微藻生长、抗氧化酶活性(超氧化物歧化酶SOD、过氧化氢酶CAT和过氧化物酶POD)、脂质过氧化产物(MDA)含量的影响,并测定了相应的活性氧自由基(ROS)的含量,初步探讨了TiO2颗粒对海洋微藻的作用机制。结果表明,1mg/L TiO2颗粒对新月菱形藻生长的抑制作用随着粒径的减小而逐渐增强,第48h、72h、96h呈现出显著的纳米效应。TiO2颗粒可以诱导藻细胞内ROS的含量增加,对藻细胞产生氧化胁迫,新月菱形藻的抗氧化酶活性发生应激响应,以清除过量的ROS,但剩余的ROS对藻细胞产生氧化损伤,导致MDA含量升高,并且纳米级TiO2颗粒对新月菱形藻的氧化损伤大于微米级颗粒。在不同粒径TiO2颗粒的胁迫下,藻细胞SOD和CAT活性的响应也存在差异。本研究将为开展人工纳米材料对海洋生态系统影响的潜在风险评估提供科学依据。     

Satellite observations of the partial pressure of carbon dioxide in the surface water of the Huanghai Sea and the Bohai Sea

Based on 5 831 continuous in situ measurements of the partial pressure of carbon dioxide on the sea surface p(CO2),related parameters of the sea surface temperature(SST) and chlorophyll-a(Chl a) concentration in 2010 winter,spring and summer of the Huanghai Sea and the Bohai Sea,the inherent relations among them are investigated preliminarily.This study reveals that the seasonal variability of SST and Chl a concentration has a significant influence on p(CO2).The authors have proposed a new algorithm to estimate p(CO2) from SST and Chl a concentration measurements.Compared with the vessel data,the root mean square error(RMSE) of p(CO2) retrieved by using the new model is 13.45 μatm(1atm=101.325 kPa) and the relative error is less than 4%.Then,SST and Chl a concentration data observed by satellite are used to retrieve p(CO2) in the Huanghai Sea and the Bohai Sea;and a better accuracy can be obtained if the quality control for sea surface chlorophyll-a concentration observed by satellite is used.The RMSE of retrieved p(CO2) data with quality control and that without quality control are 15.82 μatm and 31.74 μatm,respectively.     

Seasonal Variations in Nutrient Budgets of Hakata Bay, Japan

Seasonal variations in freshwater, salt, phosphorus and nitrogen budgets of Hakata Bay, Japan were investigated from April 1993 until March 1994. The internal sink of dissolved inorganic phosphorus (DIP) and nitrogen (DIN), and the internal source of dissolved organic phosphorus (DOP) and nitrogen (DON) predominate in the bay. This means that the production of organic matter is larger than respiration, and atmospheric CO₂ is absorbed in the water column of Hakata Bay. Denitrification is more dominant than nitrogen fixation in the bay. Compared to Tokyo and Mikawa Bays, Hakata Bay is harder to eutrophicate, mainly due to the shorter residence time of freshwater.     

Structure, room-temperature magnetic and optical properties of Mn-doped TiO2 nano powders prepared by the sol-gel process

TiO₂ nano powders with Mn concentration of 0 at%-12 at% were synthesized by the sol-gel process, and were annealed at 500 ℃ and 800 ℃ in air for 2 hrs. X-ray diffraction (XRD) measurements indicate that the Mn-TiO₂ nano powders with Mn concentration of 1 at% and 2 at% annealed at 500 and 800 ℃ are of pure anatase and rutile, respectively. The scanning electron microscope (SEM) observations reveal that the crystal grain size increases with the annealing temperature, and the high resolution transmission electron microscopy (HRTEM) investigations further indicate that the samples are well crystallized, confirming that Mn has doped into the TiO₂ crystal lattice effectively. The room temperature ferromagnetism, which could be explained within the scope of the bound magnetic polaron (BMP) theory, is detected in the Mn-TiO₂ samples with Mn concentration of 2 at%, and the magnetization of the powders annealed at 500 ℃ is stronger than that of the sample treated at 800 ℃. The UV-VIS diffuse reflectance spectra results demonstrate that the absorption of the TiO₂ powders could be enlarged by the enhanced trapped electron absorption caused by Mn doping.     

生物固氮速率测定中15N2同位素示踪剂的引入

生物固氮作用是一个重要的海洋新氮来源,在海洋生物地球化学循环中扮演着不可替代的角色。基于稳定同位素（15N₂）示踪吸收法,是目前直接测定海洋生物固氮速率最有效的手段。其中,高效、洁净地将15N₂引入海水培养体系,并准确定量培养体系底物的同位素示踪水平,是同位素示踪吸收法准确获取固氮速率的关键。本研究针对15N₂同位素示踪剂引入这一关键环节进行了探讨,确认改进气泡法是将15N₂引入海水培养体系的首选操作。在对培养体系造成的较小扰动的情况下,可将培养体系氮气底物的15N原子丰度提升至10%以上,相对于另一种导入同位素示踪剂的手段——预溶解海水法,改进气泡法将培养瓶中氮气底物的15N原子丰度提升了近200%。此外,改进气泡法还具有最小化痕量金属沾污、操作简便等优点。将改进气泡法结合与稳定同位素比值质谱测定结合,是准确测定水体生物固氮速率的推荐方法。     

Spectroscopic ellipsometric study of the optical properties of Ag2O film prepared by direct-current magnetron reactive sputtering

The Ag₂O film, as-deposited by direct-current magnetron reactive sputtering at a substrate temperature of 150 °C, clearly shows a preferential orientation (111), and is capable of lowering the threshold value of the thermal decomposition temperature to about 200 °C, which is helpful to its application in optical and magneto-optical storage. This paper fits its optical constants in terms of a general oscillator model by using measured ellipsometric parameters. The fitted oscillator energy 2.487 eV is close to the optical direct interband transition energy value of the Ag₂O film determined by Tauc equation; whereas, the fitted oscillator energy 4.249 eV is far from the fitted plasma oscillator energy 4.756 eV by single-oscillator energy. The photoluminescence spectrum centred at about 2.31 eV indicates a direct-energy gap photoluminescence mechanism of the Ag₂O film.     

Carbonate chemistry and projected future changes in pH and CaCO3 saturation state of the South China Sea

To study the dissolved carbonate system in the South China Sea (SCS) and to understand the water mass exchange between the SCS and the West Philippine Sea (WPS), pH, total alkalinity and total CO₂ were measured aboard the R/V Ocean Researcher 1. Because of the sill that separates these two seas in the Luzon Strait with a maximum depth of 2200 m, the SCS Deep Water has characteristics similar to those of water at about 2200 m in the WPS. The minimum pH and the maxima of normalized alkalinity and total CO₂ commonly found in the open oceans at mid-depth also prevail in the WPS but are, however, very weak in the SCS. Rivers and inflows from Kuroshio Surface and Deep Waters through the Luzon Strait as well as those through the Mindoro Strait transport carbon to the SCS year-round. Meanwhile, the outflowing Taiwan Strait water as well as the SCS Surface and Intermediate Waters of the Luzon Strait transports carbon out of the SCS year-round. The Sunda Shelf is also a channel for carbon transport into the SCS in the wet season and out of the SCS in the dry season.fCO₂ data and mass balance calculations indicate that the SCS is a weak CO₂ source in the wet season but an even weaker CO₂ sink in the dry season. With these facts taken together, the SCS is likely a very weak CO₂ source. Anthropogenic CO₂ penetrates to about 1500 m in depth in the SCS, and the entire SCS contains 0.60 ± 0.15 × 10¹⁵ g of excess carbon. Typical profiles of pH as well as the degree of saturation of each of calcite and aragonite in 1850 and 1997 are presented, and those for 2050 AD are projected. The maximum decrease in pH is estimated to be 0.16 pH units in the surface layer when the amount of CO₂ is doubled. It is anticipated that aragonite in the upper continental slope will likely start to dissolve, thereby neutralizing excess CO₂ by around 2050 AD. This paper is unique in that it presents the results of the first attempt ever to estimate the past, present and future physico-chemical properties of the world's largest marginal sea.     

The concentration of total dissolved CO2 in surface water in ENSO event——The results of investigation during TOGA expeditions

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东太平洋海隆热液活动区原位观测数据的小波分析和热液指标的周期性变化

洋中脊热液流体供养了特殊的生物群落.热液扩散流中的生物群从流体中汲取基本代谢组分(如H₂S,CH₄,CO₂,O₂等),将它们供给共生菌,通过共生菌将它们转化成机体能够利用的有机质[1-2].热液中的硫化氢一方面提供营养给化学自养菌,另一方面对许多海底生物又具有毒性[3-4],因此热液中溶解硫化氢的浓度是制约生物群空间分布和组合特征的重要因素[5-8].     

南海北部春季非水华期的CO_2分压及其调控

针对南海北部和吕宋海峡附近海域的海-气CO2通量及其调控问题,研究了2009年3月底至4月中旬在这些海域通过走航观测的方法取得的海-气CO2分压和海表温度、盐度等相关数据。结果表明,在河口、沿岸流以外的南海北部开阔海域,与大气平衡的CO2分压分布在368~380μatm,南低北高,平均值为371μatm;而海表CO2分压分布在293~405μatm,南高北低。南海北部开阔海域的海表CO2分压主要受温度效应调控,也在一定程度上受水团混合、海-气交换、生物活动等非温度效应的影响。在相同水温条件下,黑潮区的海表CO2分压比南海北部的海表CO2分压低。本研究和大多数前人研究的结果都表明,南海北部海盆区域和吕宋海峡西侧海域在春季与大气CO2接近源汇平衡,而非大气CO2的显著源区。     

The Air-Sea Exchange of CO2 in the East Sea (Japan Sea)

During CREAMS expeditions, fCO₂ for surface waters was measured continuously along the cruise tracks. The fCO₂ in surface waters in summer varied in the range 320–440 μatm, showing moderate supersaturation with respect to atmospheric CO₂. In winter, however, fCO₂ showed under-saturation of CO₂ in most of the area, while varying in a much wider range from 180 to 520 μatm. Some very high fCO₂ values observed in the northern East Sea (Japan Sea) appeared to be associated with the intensive convection system developed in the area. A gas-exchange model was developed for describing the annual variation of fCO₂ and for estimating the annual flux of CO₂ at the air-sea interface. The model incorporated annual variations in SST, the thickness of the mixed layer, gas exchange associated with wind velocity, biological activity and atmospheric concentration of CO₂. The model shows that the East Sea releases CO₂ into the atmosphere from June to September, and absorbs CO₂ during the rest of the year, from October through May. The net annual CO₂ flux at the air-sea interface was estimated to be 0.032 (±0.012) Gt-C per year from the atmosphere into the East Sea. Water column chemistry shows penetration of CO₂ into the whole water column, supporting a short turnover time for deep waters in the East Sea. This revised version was published online in August 2006 with corrections to the Cover Date.     

琼胶/SiO2复合纤维的制备及性能研究

利用湿法纺丝技术制备了琼胶/SiO₂复合纤维,对琼胶分子在溶液中的分散性、纺丝液流变性、纤维的形貌、化学结构分别用DLS、旋转黏度计、SEM、FTIR和XRD进行了表征,并对纤维的力学性能、热性能和吸湿性能进行了测定。研究结果表明:琼胶分子在溶液中呈纳米尺度分布,纺丝液具有良好的流动性;琼胶/纳米SiO₂复合纤维具有良好的形态。随着纳米SiO₂的添加量逐渐提高,复合纤维的力学拉伸强度先增强后降低,复合纤维的吸水性降低,复合纤维的热稳定性逐渐增强。结合复合纤维综合性能,纳米SiO₂的最佳添加质量分数为0.5%。